US1932050A - Explosive coating material - Google Patents
Explosive coating material Download PDFInfo
- Publication number
- US1932050A US1932050A US1932050DA US1932050A US 1932050 A US1932050 A US 1932050A US 1932050D A US1932050D A US 1932050DA US 1932050 A US1932050 A US 1932050A
- Authority
- US
- United States
- Prior art keywords
- explosive
- coating
- ethyl methane
- trinitrate
- ingredients
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 76
- 239000000463 material Substances 0.000 title description 72
- 239000011248 coating agent Substances 0.000 title description 70
- 238000000576 coating method Methods 0.000 title description 70
- 239000000203 mixture Substances 0.000 description 58
- RXSYUCZAOIWNLH-UHFFFAOYSA-N O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O.CCC(CO)(CO)CO Chemical compound O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O.CCC(CO)(CO)CO RXSYUCZAOIWNLH-UHFFFAOYSA-N 0.000 description 48
- 239000004615 ingredient Substances 0.000 description 44
- 150000001875 compounds Chemical class 0.000 description 32
- DVARTQFDIMZBAA-UHFFFAOYSA-O Ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 description 14
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N Sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N Calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- HMWPNDNFTFSCEB-UHFFFAOYSA-N Hexamethylene triperoxide diamine Chemical compound C1OOCN2COOCN1COOC2 HMWPNDNFTFSCEB-UHFFFAOYSA-N 0.000 description 4
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N Potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 238000005422 blasting Methods 0.000 description 4
- -1 chemical compound trimethylol ethyl methane trinitrate Chemical class 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M isothiocyanate Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 4
- 238000011068 load Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000010344 sodium nitrate Nutrition 0.000 description 4
- 239000004317 sodium nitrate Substances 0.000 description 4
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 2
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 2
- HHEFNVCDPLQQTP-UHFFFAOYSA-N Ammonium perchlorate Chemical compound [NH4+].[O-]Cl(=O)(=O)=O HHEFNVCDPLQQTP-UHFFFAOYSA-N 0.000 description 2
- 239000004264 Petrolatum Substances 0.000 description 2
- 229940066842 Petrolatum Drugs 0.000 description 2
- AGUIVNYEYSCPNI-UHFFFAOYSA-N Tetryl Chemical group [O-][N+](=O)N(C)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O AGUIVNYEYSCPNI-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- AYTGUZPQPXGYFS-UHFFFAOYSA-N Urea nitrate Chemical compound NC(N)=O.O[N+]([O-])=O AYTGUZPQPXGYFS-UHFFFAOYSA-N 0.000 description 2
- HXCPCFDPCPDEDZ-UHFFFAOYSA-N [N+](=O)(O)[O-].[N+](=O)(O)[O-].[N+](=O)(O)[O-].C(C)C Chemical compound [N+](=O)(O)[O-].[N+](=O)(O)[O-].[N+](=O)(O)[O-].C(C)C HXCPCFDPCPDEDZ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000003975 dentin desensitizing agent Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- VRNINGUKUJWZTH-UHFFFAOYSA-L lead(2+);dithiocyanate Chemical compound [Pb+2].[S-]C#N.[S-]C#N VRNINGUKUJWZTH-UHFFFAOYSA-L 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 238000006396 nitration reaction Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 230000001737 promoting Effects 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 230000001235 sensitizing Effects 0.000 description 2
- 231100000202 sensitizing Toxicity 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000015 trinitrotoluene Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/02—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
- C06B29/16—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with a nitrated organic compound
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0033—Shaping the mixture
- C06B21/0075—Shaping the mixture by extrusion
Definitions
- My invention relates to a new and improved coating material for explosive compounds and explosive'ingredients and more particularly to an explosive coating material comprising trimethylol ethyl methane trinitrate.
- coated ammonium nitrate has been in use for a great many years.
- the ammonium nitrate granules are covered with a thin coating of paraflin, petrolatum, or other suitable material.
- the object of such coating on the ammonium nitrate is to reduce the tendency of the ammonium nitrate to take up moisture from the surroundingatmosphere, due to the great hygroscopicity of the material.
- the use of the coating material has brought about many advantages. Similarly other coating materials have been used both for protection against moisture and for other reasons.
- One of the objects. of my invention is to bring about a coating of ingredients for explosive compositions by a new and improved material, which is itself an: explosive. Another object is the use of a compound as a coating material for ingreclients of explosive compositions which will reduce their tendency to absorb moisture.
- a further object is the use of a compound as a coating material, having itself 'such properties as an explosive that relatively insensitive explosive materials will have increased sensitiveness.
- a still further object is the use of a compound which, when distributed as a coating on explosives of unduly high sensitiveness, will bring about a desensitizing efiect;
- Another object is .the use of a compound as a binder in the prepa-' ration of free running granules from a finely divided, non-free running explosive material; or as a binder for holding in intimate contact a mixture of several ingredients used in explosive compositions. Further objects will be apparent as my invention is more fully described hereinafter.
- trimethylol ethyl methane trinitrate is highly desirableas a coating material for. other ingredients of explosives 'and particularly so for other explosive compounds. Because of its intermediate .degree of sensitiveness, it is adapted for use either as a coating for insensitive materials, in which case it functions as a'sensitizing agent, or as a coating for materials that are so highly sensitive as to be undesirable for use alone, in which case it serves as a desensitizing agent.
- Trimethylol ethyl methane trinitrate As for an example of the use of trimethylol ethyl methane trinitrate as a coating material for insensitive materials, I will cite its use in the coating of ammonium nitrate. Trimethylol ethyl methane trinitrate has the necessary properties for use as a coating ingredient, having as it does a waxy nature and a meltingpoint of about 48 C. As a result of this, it is readily applied as a. surface coating to the granules of ammonium nitrate. While it has all the advantages of parafiin and similar coating materials as a waterproofing agent, trimethylol ethylmethane trinitrate is free from the disadvantages of paraffin. While paraflin has a decided desensitizing efiect ethyl methane trinitr'ate is itself an explosive compound of an intermediate degree of sensitive.
- Trimethylol ethyl methane trinitrate may be used to coat other insensitive ingredients of dynamite, as for example sodium nitrate, potassium nitrate, calcium nitrate, urea nitrate, ammonium perchlorate,.and the like.
- Trimethylol ethyl methane trinitrate may also be used to advantage in the coating of explosive materials having too high a degree of sensitiveness for safe use in practice.
- Trimethylol ethyl methane trinitrate has itself an intermediate degree of sensitiveness so that its use as a coating material confers its own degree of s'ensitiveness on the ingredient coated.
- An illustration of such 5 use lies in its application as a coating material for compounds adapted for use as primary detonating compounds, as well as materials suitable for use as ignition ingredients in blasting caps, which, however, are undesirably sensitive for use by themselves, as for example hexamethylenetriperox-idediamine, trinitrotriazidobenzene, and
- Dusty, non-free running materials when mixed in suitable amounts with trimethylol ethyl methane trinitrate, may be made into granules or pellets of a desirable size, which are free running, non-dusty and suitable-for mixing, .loading, and packing as a constituent of any explosive composition.
- I may mention nitrostarch, pentaerythrite tetranitrate, cyclotrimethylene trinitramine, tetryl, and like compounds.
- caps which may comprise, for example, lead sulphocyanate, potassium chlorate, and groundsmokeless powder.
- coating should be used of sufiicient thickness so that the desired degree of sensitiveness is obtained for the material coated.
- the coating may be applied in the form of liquid trimethylol ethyl methane trinitrate' at an increased'temperature for example 50-60 C., or the coating material may be dissolved in a suitable solvent or mixture of solvents and applied at room temperature, the solvent or solvents being subsequently removed by evaporation.
- a new composition of matter comprising an ingredient of an explosive composition coated with trimethylol ethyl methane trinitrate.
- a new composition of matter comprising an inorganic ingredient of an explosive composition coated with trimethylol ethyl methane trinitrate.
- a new composition of matter comprising an inorganic explosive salt coated with trimethylol ethyl methane trinitrate.
- a new composition of matter comprising am- I monium nitrate coated with trimethylol ethyl methane trinitrate.
- a new composition of matter comprising an organic ingredient of an explosive composition coated with trimethylol ethyl methane trinitrate.
- a new composition of matter comprising an explosive compound coated with trimethylol ethyl methane trinitrate.
- a new, composition of matter comprising hexamethylenetriperoxidediamine coated with trimethylol ethyl methane trinitrate.
- a new composition of matter comprising an explosive mixture, the ingredients of which are coated with trimethylol ethyl methane trinitrate.
- An explosive composition comprising a mixture of a sulfocyanate, an oxidizing agent, and a fuel, said ingredients being coated with trimeth- 1 ylol ethyl methane trinitrate.
- An explosive composition comprising lead sulfocyanate, potassium chlorate, and ground smokeless powder, said ingredients beingcoated with trimethylol ethyl methane trinitrate.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
- Air Bags (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Patented Get. 24, 1933 LOSIVE COATING MATERIAL Charles P. Spaeth, Woodbury, N. J., assignor to E. 1. du Pont de Nemours- & Company, Wilmington, DeL, acorporation of Delaware No Drawing. Application November 20, 1931 Serial N0. 576,435
11 Claims. (oi; 52-11) My invention relates to a new and improved coating material for explosive compounds and explosive'ingredients and more particularly to an explosive coating material comprising trimethylol ethyl methane trinitrate.
- In the high explosive industry, it is a frequent practice to use coated ingredients in order to modify and control the physical characteristics .of such ingredients. For example, coated ammonium nitrate has been in use for a great many years. In this case, the ammonium nitrate granules are covered with a thin coating of paraflin, petrolatum, or other suitable material. The object of such coating on the ammonium nitrate is to reduce the tendency of the ammonium nitrate to take up moisture from the surroundingatmosphere, due to the great hygroscopicity of the material. The use of the coating material has brought about many advantages. Similarly other coating materials have been used both for protection against moisture and for other reasons.
-Ammonium nitrate has frequently been coated 'with trinitrotoluene for example, in such manner that the coating not only gave protection against moisture but also increased the sensitiveness of the ammonium nitrate.
One of the objects. of my invention is to bring about a coating of ingredients for explosive compositions by a new and improved material, which is itself an: explosive. Another object is the use of a compound as a coating material for ingreclients of explosive compositions which will reduce their tendency to absorb moisture.
A further object is the use of a compound as a coating material, having itself 'such properties as an explosive that relatively insensitive explosive materials will have increased sensitiveness. A still further object is the use of a compound which, when distributed as a coating on explosives of unduly high sensitiveness, will bring about a desensitizing efiect; Another object is .the use of a compound as a binder in the prepa-' ration of free running granules from a finely divided, non-free running explosive material; or as a binder for holding in intimate contact a mixture of several ingredients used in explosive compositions. Further objects will be apparent as my invention is more fully described hereinafter.
In my copending application, Serial No. 576,434, filed November 20, 1931 I have disclosedthe new chemical compound trimethylol ethyl methane trinitrate which has highly valuable properties ,as an explosive compound. This substance is obtained by the nitration, in any suitable way, of
the trihydroxy compound, trimethylol ethyl methane. The nitrated product has the followingformula:-
CHzNOa CzHs-C-CHzNOz CHzNOa I- have discovered. that trimethylol ethyl methane trinitrate is highly desirableas a coating material for. other ingredients of explosives 'and particularly so for other explosive compounds. Because of its intermediate .degree of sensitiveness, it is adapted for use either as a coating for insensitive materials, in which case it functions as a'sensitizing agent, or as a coating for materials that are so highly sensitive as to be undesirable for use alone, in which case it serves as a desensitizing agent.
As for an example of the use of trimethylol ethyl methane trinitrate as a coating material for insensitive materials, I will cite its use in the coating of ammonium nitrate. Trimethylol ethyl methane trinitrate has the necessary properties for use as a coating ingredient, having as it does a waxy nature and a meltingpoint of about 48 C. As a result of this, it is readily applied as a. surface coating to the granules of ammonium nitrate. While it has all the advantages of parafiin and similar coating materials as a waterproofing agent, trimethylol ethylmethane trinitrate is free from the disadvantages of paraffin. While paraflin has a decided desensitizing efiect ethyl methane trinitr'ate is itself an explosive compound of an intermediate degree of sensitive.
ness so that it both protects ammonium nitr'ate against moisture and increases its sensitiveness. Likewise paraifin', and other of the organic coating materials commonly. used for coating explosive ingredients, are-very deficient in oxygen. Trimethylol ethyl methane trinitrate, however, is only slightly deficient in oxygen, hence considerable more ofthis material may be used as a coating when desirable Without disturbing the balance of oxygfin for complete combustion of the explosive mixture. Trimethylol ethyl methane trinitrate may be used to coat other insensitive ingredients of dynamite, as for example sodium nitrate, potassium nitrate, calcium nitrate, urea nitrate, ammonium perchlorate,.and the like.
Trimethylol ethyl methane trinitrate may also be used to advantage in the coating of explosive materials having too high a degree of sensitiveness for safe use in practice. Trimethylol ethyl methane trinitrate has itself an intermediate degree of sensitiveness so that its use as a coating material confers its own degree of s'ensitiveness on the ingredient coated. An illustration of such 5 use lies in its application as a coating material for compounds adapted for use as primary detonating compounds, as well as materials suitable for use as ignition ingredients in blasting caps, which, however, are undesirably sensitive for use by themselves, as for example hexamethylenetriperox-idediamine, trinitrotriazidobenzene, and
like compounds.
A further illustration of the use of trimethylol ethyl methane trinitrate as a coating ingredient of the second class,.is its'use with pentaerythrite tetranitrate. This compound is used frequently with considerable satisfaction as the filling material for detonating fuse. However, the sensi tiveness of fuses filled with pentaerythrite tetranitrate is undesirably high for use in rough work where the material may be exposed to shock and heavy blows. The coating of the pentaerythrite tetranitrate core of such fuse with trimethylol ethyl methane trinitrate obviates the above dif- \ficulties, and gives a satisfactory fuse material.
It is well known that certain explosive ingredients are prepared insuch a way that they comprise finely divided, non-free running, dusty materials which are inferior as constituents of explosive compositions on account of the difliculty in mixing, loading and packing, and which are dangerous because of the dust hazard. I
find that my new explosive coating material may 4 be used quite successfully in removing these difficulties. Dusty, non-free running materials, when mixed in suitable amounts with trimethylol ethyl methane trinitrate, may be made into granules or pellets of a desirable size, which are free running, non-dusty and suitable-for mixing, .loading, and packing as a constituent of any explosive composition. As examples of this, I may mention nitrostarch, pentaerythrite tetranitrate, cyclotrimethylene trinitramine, tetryl, and like compounds.
451 Likewise, it is often desirable to combine in a more intimately associated form a mixture of I several explosive ingredients. This hasthedesirable feature -of preventing the segregation of a mixture of materials having-varying densities. It has the additional advantage of promoting more rapid and more complete combustion of this mixture, with consequent improvement in explosive propagation. It likewise allows an improved method of governing the size and form of the grains or pellets, with-the result that the properties of the explosive may be modified and im proved. For example, I may bind together. a mixture ofammonium nitrate, sodium nitrate,
and an organic combustible material for use,,
so by itself or with other ingredients; as a blasting explosive. Again it is useful in preparing a mixture suitable as an ignition agent in caps which may comprise, for example, lead sulphocyanate, potassium chlorate, and groundsmokeless powder.
It will be understood that in the use of trimethylol ethyl methane trinitrate as .a coating material for, explosive ingredients and compounds, the thickness of the coating will vary in accordance with the necessities of the case. A
coating should be used of sufiicient thickness so that the desired degree of sensitiveness is obtained for the material coated.
It will be further understood that the coating may be applied in the form of liquid trimethylol ethyl methane trinitrate' at an increased'temperature for example 50-60 C., or the coating material may be dissolved in a suitable solvent or mixture of solvents and applied at room temperature, the solvent or solvents being subsequently removed by evaporation.
While I have described 'my invention in detail' in the foregoing, I wish it to be understood that many variations may be made 'without departure from the spirit of the invention, and'that I do not intend to be limited except as indicated in the following patent claims:
I claim:
I. A new composition of matter comprising an ingredient of an explosive composition coated with trimethylol ethyl methane trinitrate.
2. A new composition of matter comprising an inorganic ingredient of an explosive composition coated with trimethylol ethyl methane trinitrate.
3. A new composition of matter comprising an inorganic explosive salt coated with trimethylol ethyl methane trinitrate.
4. A new composition of matter comprising am- I monium nitrate coated with trimethylol ethyl methane trinitrate.
5 A new composition of matter comprising an organic ingredient of an explosive composition coated with trimethylol ethyl methane trinitrate.
6. A new composition of matter comprising an explosive compound coated with trimethylol ethyl methane trinitrate.
7. A new composition of matter comprising an organic explosive compound coated with trimethylol ethyl methane trinitrate.- I
8. A new, composition of matter comprising hexamethylenetriperoxidediamine coated with trimethylol ethyl methane trinitrate.
9. A new composition of matter comprising an explosive mixture, the ingredients of which are coated with trimethylol ethyl methane trinitrate.
10. An explosive composition comprising a mixture of a sulfocyanate, an oxidizing agent, and a fuel, said ingredients being coated with trimeth- 1 ylol ethyl methane trinitrate.
11. An explosive composition comprising lead sulfocyanate, potassium chlorate, and ground smokeless powder, said ingredients beingcoated with trimethylol ethyl methane trinitrate.
CHARLES P. SPAETH.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1932050A true US1932050A (en) | 1933-10-24 |
Family
ID=3425861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US1932050D Expired - Lifetime US1932050A (en) | Explosive coating material |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1932050A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2606109A (en) * | 1943-07-16 | 1952-08-05 | George B Kistiakowsky | Plastic nonhardening explosive composition and method of forming same |
| US2709130A (en) * | 1953-06-26 | 1955-05-24 | Trojan Powder Co | Blasting explosives |
| US2821466A (en) * | 1954-12-28 | 1958-01-28 | Trojan Powder Co | Nitrate explosives and method of making |
| DE1180294B (en) * | 1961-11-17 | 1964-10-22 | Aerojet General Co | Explosive mixture |
| US3342814A (en) * | 1962-01-15 | 1967-09-19 | Union Carbide Corp | Adducts of metal borohydrides and organic polynitrogen compounds |
| US3347893A (en) * | 1961-12-27 | 1967-10-17 | Union Carbide Corp | Adducts |
| US6345577B1 (en) | 2000-09-27 | 2002-02-12 | The United States Of America As Represented By The Secretary Of The Navy | Energetic deterrent coating for gun propellant |
| US20040221934A1 (en) * | 1999-06-09 | 2004-11-11 | Royal Ordnance Plc. | Desensitisation of energetic materials |
-
0
- US US1932050D patent/US1932050A/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2606109A (en) * | 1943-07-16 | 1952-08-05 | George B Kistiakowsky | Plastic nonhardening explosive composition and method of forming same |
| US2709130A (en) * | 1953-06-26 | 1955-05-24 | Trojan Powder Co | Blasting explosives |
| US2821466A (en) * | 1954-12-28 | 1958-01-28 | Trojan Powder Co | Nitrate explosives and method of making |
| DE1180294B (en) * | 1961-11-17 | 1964-10-22 | Aerojet General Co | Explosive mixture |
| US3347893A (en) * | 1961-12-27 | 1967-10-17 | Union Carbide Corp | Adducts |
| US3342814A (en) * | 1962-01-15 | 1967-09-19 | Union Carbide Corp | Adducts of metal borohydrides and organic polynitrogen compounds |
| US20040221934A1 (en) * | 1999-06-09 | 2004-11-11 | Royal Ordnance Plc. | Desensitisation of energetic materials |
| US20110108171A1 (en) * | 1999-06-09 | 2011-05-12 | Bae Systems Land Systems (Munitions & Ordnance) Limited | Desensitisation of energetic materials |
| US6345577B1 (en) | 2000-09-27 | 2002-02-12 | The United States Of America As Represented By The Secretary Of The Navy | Energetic deterrent coating for gun propellant |
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