US1913299A - Sulphur lubricant - Google Patents
Sulphur lubricant Download PDFInfo
- Publication number
- US1913299A US1913299A US633541A US63354132A US1913299A US 1913299 A US1913299 A US 1913299A US 633541 A US633541 A US 633541A US 63354132 A US63354132 A US 63354132A US 1913299 A US1913299 A US 1913299A
- Authority
- US
- United States
- Prior art keywords
- sulphur
- gel
- lubricant
- cutting
- powdered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title description 52
- 239000005864 Sulphur Substances 0.000 title description 51
- 239000000314 lubricant Substances 0.000 title description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000007788 liquid Substances 0.000 description 11
- 229920002472 Starch Polymers 0.000 description 10
- 235000019698 starch Nutrition 0.000 description 10
- 239000008107 starch Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 230000001050 lubricating effect Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000005018 casein Substances 0.000 description 6
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 6
- 235000021240 caseins Nutrition 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 229920001353 Dextrin Polymers 0.000 description 4
- 239000004375 Dextrin Substances 0.000 description 4
- 235000019425 dextrin Nutrition 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- 238000009877 rendering Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000002173 cutting fluid Substances 0.000 description 2
- 239000007863 gel particle Substances 0.000 description 2
- 229920000591 gum Polymers 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 210000002966 serum Anatomy 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 241001305576 Eriogonum umbellatum Species 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 239000010699 lard oil Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000010070 molecular adhesion Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
- C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/043—Sulfur; Selenenium; Tellurium
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/20—Rosin acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/044—Polyamides
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- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
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- C10N2010/00—Metal present as such or in compounds
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- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C10N2010/06—Groups 3 or 13
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10N2040/241—Manufacturing joint-less pipes
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- C10N2040/246—Iron or steel
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- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
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- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Definitions
- My invention aims to provide an improved lubricant, whereby a stable admixture of free sulphur in a water vehicle is made available for lubricating purposes.
- This application is a division of my co-pending application, Serial No. 603,445, filed April 5, 1932, the latter being acontinuation in part of myco-p'ending application, Serial No. 594,741, filed February 23, 1932.
- My lubricant is of especial value in the art of cutting and machining metals. 7
- the sulphur is advantageously in a liquid vehicle, so that it may be readily introduced into the zone of action. If finely divided sulphur flowers of sulphur) is stirred with oil, wa r or other liquid vehicles, it will not stay in suspension but will settle out and hence would have to be stirred until almost the time for hightly inconvenient and therefore impractical as a general proposition.
- I may employ water as a vehicle.
- I employ various stabilizers, which have the property of actually sustaining the sulphur particles, or causing them to be sustained, in the liquid vehicle or carrier for long periods of time.
- these stabilizing substances do increase the viscosity of the vehicle somewhat, this is purely incidental.
- the eifect with which I am concerned is not that of merely delaying the settling out of the sulphur particles but that of causing them to be sustained for indefinitely long periods of time so as to obtain stable suspensions of free sulphur.
- stable I do not mean necessarily absolute-stability but stability in the sense that there is little or no separation or settling out of the sulphur partic es.
- Example 1% to 5% ofstarch is mixed with water and the whole heated, as by ,blowing in steam, to they boiling point.
- a germicide, or ungicide, such as carbolic acid, may be added to inhibit coagulation of the starch, v
- a reely flowing lubricant By a reely flowing lubricant is meant a lubricant ,which will flow freely at normal temperatures through circulating pi es that are used in the machine tool art or applying cutting fluids to the cutting point, and ,which is not viscous enough to support sulphur in stable suspensions by 'virtue of the apparent bulk viscosity-in other words, one which is not a paste or a cake. Attention is called to my co-pending ap- Q plication' Serial No. 644,503, filed November 26, 1 932. 4 'The invention is obviously not restricted to the embodiments described, but what is claimed is as follows: 1.
- a cutting lubricant gel freely flowing at ordinary tem eratures comprising ng a water vehicle gelle with a small amount of a gel-forming substance selected from the class typified by starch, gum, dextrin, glue and casein; and'containing powdered sulphur of greater than colloidal size distributed therethrough inamount to function as a lubricating ingredient and be stably suspended therein.
- a cuttinglubricant' gel freely flowing I at ordinary temperatures comprising a .water vehicle gelled with a small amount of starch and having powdered sulphur of greater than colloidal size distributed therethrough in amount to function as a lubricating ingredient and be stably. suspended thereln.
- a cutting lubricant gel "freely flowing at ordinary temperatures comprising a water vehicle gelled with a small amount of. gum and having powdered sul hur of greater than colloidal size distributed there through in amount to function as a lubricating ingredient and. be stably suspended therein.
- a cutting lubricant gel freely flowing at ordinary temperatures comprising a wa 'ter vehicle gelled with a small amount of casein and having powdered sulphur in greater than colloidal size distributed therethrough in amount to function as a lubricating ingredient and be stably suspended 7 therein.
- a cutting lubricant gel freely flowing at ordinary temperatures comprislng a water vehicle gelled with about 1%- -5% of starch and having about 5% 25% of powdered sulphur of greater than colloidal size distributed therethrough and stably sus pended therein.
- a cutting lubricant freely flowing at ordinary temperatures consisting of a water vehice and a gel formed of water and a substance selected from the class typified by starch, gum, dextrin, g e d' casein d-isr' ..tributed the'rethrough and carrying in stable suspension dispersed free sulphur particles of greater than colloidal size in sufiicient amount to function-as the lubricating ingredient, thereby permitting exceptionally ing cuttin high speed cutting, and said gel'serving to minimlze the corrosive-action of the sulphur when thelatter is not actually being emplo ed to producelubrication ofthe cutting too where it engages the work.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE410885D BE410885A (enrdf_load_stackoverflow) | 1932-04-05 | ||
US633541A US1913299A (en) | 1932-04-05 | 1932-09-16 | Sulphur lubricant |
US644503A US1913300A (en) | 1932-04-05 | 1932-11-26 | Sulphur lubricant |
GB21978/35A GB449592A (en) | 1932-04-05 | 1935-08-02 | Improvements in suspensions for lubrication and other purposes |
FR793603D FR793603A (fr) | 1932-04-05 | 1935-08-09 | Procédé de mise en suspension en milieu liquide de particules y distribuées et produits ou <suspensions>, en résultant, pour le graissage et autres usages |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60344532A | 1932-04-05 | 1932-04-05 | |
US633541A US1913299A (en) | 1932-04-05 | 1932-09-16 | Sulphur lubricant |
US740005A US2016532A (en) | 1934-08-15 | 1934-08-15 | Lubricant mixture |
Publications (1)
Publication Number | Publication Date |
---|---|
US1913299A true US1913299A (en) | 1933-06-06 |
Family
ID=27416882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US633541A Expired - Lifetime US1913299A (en) | 1932-04-05 | 1932-09-16 | Sulphur lubricant |
Country Status (4)
Country | Link |
---|---|
US (1) | US1913299A (enrdf_load_stackoverflow) |
BE (1) | BE410885A (enrdf_load_stackoverflow) |
FR (1) | FR793603A (enrdf_load_stackoverflow) |
GB (1) | GB449592A (enrdf_load_stackoverflow) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2469473A (en) * | 1943-08-02 | 1949-05-10 | Gilron Products Company | Method of lubricating metal surfaces during cold working |
US2524017A (en) * | 1950-09-26 | Metalworking lubricant | ||
US3126313A (en) * | 1964-03-24 | Certificate of correction | ||
US3311555A (en) * | 1961-09-29 | 1967-03-28 | Niemann | Method for running-in gear wheels and an agent therefor |
FR2693470A1 (fr) * | 1992-07-07 | 1994-01-14 | Roquette Freres | Compositions pour fluides d'usinage aqueux et fluides d'usinage aqueux à base de corps gras et de cyclodextrine. |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102326484B1 (ko) * | 2020-02-03 | 2021-11-17 | 한전원자력연료 주식회사 | 냉간 필거용 외면 윤활제 조성물 |
KR102326485B1 (ko) * | 2020-02-03 | 2021-11-17 | 한전원자력연료 주식회사 | 냉간 필거용 내면 윤활제 조성물 |
-
0
- BE BE410885D patent/BE410885A/xx unknown
-
1932
- 1932-09-16 US US633541A patent/US1913299A/en not_active Expired - Lifetime
-
1935
- 1935-08-02 GB GB21978/35A patent/GB449592A/en not_active Expired
- 1935-08-09 FR FR793603D patent/FR793603A/fr not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2524017A (en) * | 1950-09-26 | Metalworking lubricant | ||
US3126313A (en) * | 1964-03-24 | Certificate of correction | ||
US2469473A (en) * | 1943-08-02 | 1949-05-10 | Gilron Products Company | Method of lubricating metal surfaces during cold working |
US3311555A (en) * | 1961-09-29 | 1967-03-28 | Niemann | Method for running-in gear wheels and an agent therefor |
FR2693470A1 (fr) * | 1992-07-07 | 1994-01-14 | Roquette Freres | Compositions pour fluides d'usinage aqueux et fluides d'usinage aqueux à base de corps gras et de cyclodextrine. |
WO1994001518A1 (fr) * | 1992-07-07 | 1994-01-20 | Roquette Freres | Compositions pour fluides d'usinage aqueux et fluides d'usinage aqueux a base de corps gras et de cyclodextrine |
Also Published As
Publication number | Publication date |
---|---|
GB449592A (en) | 1936-06-30 |
FR793603A (fr) | 1936-01-28 |
BE410885A (enrdf_load_stackoverflow) |
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