US1913299A - Sulphur lubricant - Google Patents

Sulphur lubricant Download PDF

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Publication number
US1913299A
US1913299A US633541A US63354132A US1913299A US 1913299 A US1913299 A US 1913299A US 633541 A US633541 A US 633541A US 63354132 A US63354132 A US 63354132A US 1913299 A US1913299 A US 1913299A
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United States
Prior art keywords
sulphur
gel
lubricant
cutting
powdered
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Expired - Lifetime
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US633541A
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English (en)
Inventor
Victor R Abrams
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ARTHUR H BALLARD
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ARTHUR H BALLARD
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Priority to BE410885D priority Critical patent/BE410885A/xx
Application filed by ARTHUR H BALLARD filed Critical ARTHUR H BALLARD
Priority to US633541A priority patent/US1913299A/en
Priority to US644503A priority patent/US1913300A/en
Application granted granted Critical
Publication of US1913299A publication Critical patent/US1913299A/en
Priority claimed from US740005A external-priority patent/US2016532A/en
Priority to GB21978/35A priority patent/GB449592A/en
Priority to FR793603D priority patent/FR793603A/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/043Sulfur; Selenenium; Tellurium
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/20Rosin acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12Polysaccharides, e.g. cellulose, biopolymers
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044Polyamides
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045Polyureas; Polyurethanes
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    • C10N2010/00Metal present as such or in compounds
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    • C10N2010/02Groups 1 or 11
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    • C10N2010/04Groups 2 or 12
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    • C10N2010/06Groups 3 or 13
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/241Manufacturing joint-less pipes
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    • C10N2040/242Hot working
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    • C10N2040/243Cold working
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    • C10N2040/247Stainless steel
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles
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    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

Definitions

  • My invention aims to provide an improved lubricant, whereby a stable admixture of free sulphur in a water vehicle is made available for lubricating purposes.
  • This application is a division of my co-pending application, Serial No. 603,445, filed April 5, 1932, the latter being acontinuation in part of myco-p'ending application, Serial No. 594,741, filed February 23, 1932.
  • My lubricant is of especial value in the art of cutting and machining metals. 7
  • the sulphur is advantageously in a liquid vehicle, so that it may be readily introduced into the zone of action. If finely divided sulphur flowers of sulphur) is stirred with oil, wa r or other liquid vehicles, it will not stay in suspension but will settle out and hence would have to be stirred until almost the time for hightly inconvenient and therefore impractical as a general proposition.
  • I may employ water as a vehicle.
  • I employ various stabilizers, which have the property of actually sustaining the sulphur particles, or causing them to be sustained, in the liquid vehicle or carrier for long periods of time.
  • these stabilizing substances do increase the viscosity of the vehicle somewhat, this is purely incidental.
  • the eifect with which I am concerned is not that of merely delaying the settling out of the sulphur particles but that of causing them to be sustained for indefinitely long periods of time so as to obtain stable suspensions of free sulphur.
  • stable I do not mean necessarily absolute-stability but stability in the sense that there is little or no separation or settling out of the sulphur partic es.
  • Example 1% to 5% ofstarch is mixed with water and the whole heated, as by ,blowing in steam, to they boiling point.
  • a germicide, or ungicide, such as carbolic acid, may be added to inhibit coagulation of the starch, v
  • a reely flowing lubricant By a reely flowing lubricant is meant a lubricant ,which will flow freely at normal temperatures through circulating pi es that are used in the machine tool art or applying cutting fluids to the cutting point, and ,which is not viscous enough to support sulphur in stable suspensions by 'virtue of the apparent bulk viscosity-in other words, one which is not a paste or a cake. Attention is called to my co-pending ap- Q plication' Serial No. 644,503, filed November 26, 1 932. 4 'The invention is obviously not restricted to the embodiments described, but what is claimed is as follows: 1.
  • a cutting lubricant gel freely flowing at ordinary tem eratures comprising ng a water vehicle gelle with a small amount of a gel-forming substance selected from the class typified by starch, gum, dextrin, glue and casein; and'containing powdered sulphur of greater than colloidal size distributed therethrough inamount to function as a lubricating ingredient and be stably suspended therein.
  • a cuttinglubricant' gel freely flowing I at ordinary temperatures comprising a .water vehicle gelled with a small amount of starch and having powdered sulphur of greater than colloidal size distributed therethrough in amount to function as a lubricating ingredient and be stably. suspended thereln.
  • a cutting lubricant gel "freely flowing at ordinary temperatures comprising a water vehicle gelled with a small amount of. gum and having powdered sul hur of greater than colloidal size distributed there through in amount to function as a lubricating ingredient and. be stably suspended therein.
  • a cutting lubricant gel freely flowing at ordinary temperatures comprising a wa 'ter vehicle gelled with a small amount of casein and having powdered sulphur in greater than colloidal size distributed therethrough in amount to function as a lubricating ingredient and be stably suspended 7 therein.
  • a cutting lubricant gel freely flowing at ordinary temperatures comprislng a water vehicle gelled with about 1%- -5% of starch and having about 5% 25% of powdered sulphur of greater than colloidal size distributed therethrough and stably sus pended therein.
  • a cutting lubricant freely flowing at ordinary temperatures consisting of a water vehice and a gel formed of water and a substance selected from the class typified by starch, gum, dextrin, g e d' casein d-isr' ..tributed the'rethrough and carrying in stable suspension dispersed free sulphur particles of greater than colloidal size in sufiicient amount to function-as the lubricating ingredient, thereby permitting exceptionally ing cuttin high speed cutting, and said gel'serving to minimlze the corrosive-action of the sulphur when thelatter is not actually being emplo ed to producelubrication ofthe cutting too where it engages the work.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
US633541A 1932-04-05 1932-09-16 Sulphur lubricant Expired - Lifetime US1913299A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BE410885D BE410885A (enrdf_load_stackoverflow) 1932-04-05
US633541A US1913299A (en) 1932-04-05 1932-09-16 Sulphur lubricant
US644503A US1913300A (en) 1932-04-05 1932-11-26 Sulphur lubricant
GB21978/35A GB449592A (en) 1932-04-05 1935-08-02 Improvements in suspensions for lubrication and other purposes
FR793603D FR793603A (fr) 1932-04-05 1935-08-09 Procédé de mise en suspension en milieu liquide de particules y distribuées et produits ou <suspensions>, en résultant, pour le graissage et autres usages

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US60344532A 1932-04-05 1932-04-05
US633541A US1913299A (en) 1932-04-05 1932-09-16 Sulphur lubricant
US740005A US2016532A (en) 1934-08-15 1934-08-15 Lubricant mixture

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US1913299A true US1913299A (en) 1933-06-06

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US633541A Expired - Lifetime US1913299A (en) 1932-04-05 1932-09-16 Sulphur lubricant

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US (1) US1913299A (enrdf_load_stackoverflow)
BE (1) BE410885A (enrdf_load_stackoverflow)
FR (1) FR793603A (enrdf_load_stackoverflow)
GB (1) GB449592A (enrdf_load_stackoverflow)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2469473A (en) * 1943-08-02 1949-05-10 Gilron Products Company Method of lubricating metal surfaces during cold working
US2524017A (en) * 1950-09-26 Metalworking lubricant
US3126313A (en) * 1964-03-24 Certificate of correction
US3311555A (en) * 1961-09-29 1967-03-28 Niemann Method for running-in gear wheels and an agent therefor
FR2693470A1 (fr) * 1992-07-07 1994-01-14 Roquette Freres Compositions pour fluides d'usinage aqueux et fluides d'usinage aqueux à base de corps gras et de cyclodextrine.

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102326484B1 (ko) * 2020-02-03 2021-11-17 한전원자력연료 주식회사 냉간 필거용 외면 윤활제 조성물
KR102326485B1 (ko) * 2020-02-03 2021-11-17 한전원자력연료 주식회사 냉간 필거용 내면 윤활제 조성물

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2524017A (en) * 1950-09-26 Metalworking lubricant
US3126313A (en) * 1964-03-24 Certificate of correction
US2469473A (en) * 1943-08-02 1949-05-10 Gilron Products Company Method of lubricating metal surfaces during cold working
US3311555A (en) * 1961-09-29 1967-03-28 Niemann Method for running-in gear wheels and an agent therefor
FR2693470A1 (fr) * 1992-07-07 1994-01-14 Roquette Freres Compositions pour fluides d'usinage aqueux et fluides d'usinage aqueux à base de corps gras et de cyclodextrine.
WO1994001518A1 (fr) * 1992-07-07 1994-01-20 Roquette Freres Compositions pour fluides d'usinage aqueux et fluides d'usinage aqueux a base de corps gras et de cyclodextrine

Also Published As

Publication number Publication date
GB449592A (en) 1936-06-30
FR793603A (fr) 1936-01-28
BE410885A (enrdf_load_stackoverflow)

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