US1908273A - Sweetening petroleum distillates - Google Patents
Sweetening petroleum distillates Download PDFInfo
- Publication number
- US1908273A US1908273A US445207A US44520730A US1908273A US 1908273 A US1908273 A US 1908273A US 445207 A US445207 A US 445207A US 44520730 A US44520730 A US 44520730A US 1908273 A US1908273 A US 1908273A
- Authority
- US
- United States
- Prior art keywords
- acid
- petroleum distillates
- chlorite
- sweetening
- distillates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003209 petroleum derivative Substances 0.000 title description 9
- 239000002253 acid Substances 0.000 description 10
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 10
- 229910001919 chlorite Inorganic materials 0.000 description 7
- 229910052619 chlorite group Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229940077239 chlorous acid Drugs 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- -1 alkali-metal chlorites Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- QXIKMJLSPJFYOI-UHFFFAOYSA-L calcium;dichlorite Chemical compound [Ca+2].[O-]Cl=O.[O-]Cl=O QXIKMJLSPJFYOI-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000019980 sodium acid phosphate Nutrition 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/02—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with halogen or compounds generating halogen; Hypochlorous acid or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/06—Metal salts, or metal salts deposited on a carrier
Definitions
- salts of chlorous acid such as sodium chlorite and calcium chlorite
- sodium chlorite and calcium chlorite are effective refining agents for petroleum distillates and may be used to produce petroleum distillates of good color, odor and stability.
- degree of acidity is not important, I have found solutions having a pH value of about 4 to be advantageous.
- the rapidity and extent of reaction between the chlorites and the objectionableconstituents of crude petroleum distillates such as sulfur compounds may be largely controlled by regulating the amount of acid agent, acid or acid salt, used in conjunction with the chlorite. With some distillates a pH of 4 in the treating solution may be sufficient. With other distillates it is preferable to use N/lO acid or stronger.
- the acidity of the treating solution may be controlled by the additionof an acid or acid salt, such as hydrochloric acid or sulphuric acid or sodium acid sulfate or sodium acid phosphate.
- an acid or acid salt such as hydrochloric acid or sulphuric acid or sodium acid sulfate or sodium acid phosphate.
- the amount of the chlorite required for refining varies with and is determined by the character of the distillate being refined.
- the concentration of the treating solution is not critical; in general lower concentrations of the chlorite are de sirable in conjunction with higher acidity.
- the refining operation may be carried out as a batch operation or as a continuous operation in any convenient manner.
- Acid chlorite solutions apparently react with many of the sulphur compounds occurring in petroleum distillates to convert the sulphur of such compounds into reaction products soluble in water and thus susceptible of removal in the water of the treating solu- Application filed April 17,
- alkali-metal chlorites or alkalineearth-metal chlorites are particularly useful in carrying out my invention, the other salts of chlorous acid and chlorous acid'itself are also useful in carrying out my invention, the
- chlorite radical being the essential component.
- the improvement which comprises subjecting the distillate to treatment with an acid aqueous solution of a chlorite of a metal of the group comprising the alkali-metals and the alka line-earth-metals.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
Description
Patented May 9, 1933 UNITED STATES MAURICE G. TAYLOR, OF NIAGARA FALLS, NEW YORK, ASSIG-NOR TO THE MATHIESON PATENT OFFICE ALKALI WORKS, INC., OF NEW YORK, N. Y., A CORPORATION OF VIRGINIA SWEETENING PETROLEUM DISTILLATES No Drawing.
of salts of chlorous acid, such as sodium chlorite and calcium chlorite, are effective refining agents for petroleum distillates and may be used to produce petroleum distillates of good color, odor and stability. Although the exact degree of acidity is not important, I have found solutions having a pH value of about 4 to be advantageous. The rapidity and extent of reaction between the chlorites and the objectionableconstituents of crude petroleum distillates such as sulfur compounds may be largely controlled by regulating the amount of acid agent, acid or acid salt, used in conjunction with the chlorite. With some distillates a pH of 4 in the treating solution may be sufficient. With other distillates it is preferable to use N/lO acid or stronger. The acidity of the treating solution may be controlled by the additionof an acid or acid salt, such as hydrochloric acid or sulphuric acid or sodium acid sulfate or sodium acid phosphate. The amount of the chlorite required for refining varies with and is determined by the character of the distillate being refined. The concentration of the treating solution is not critical; in general lower concentrations of the chlorite are de sirable in conjunction with higher acidity. The refining operation may be carried out as a batch operation or as a continuous operation in any convenient manner.
For example: 100 parts of a gasolene distillate are placed in a suitable agitator with 40 parts of N/ 10 hydrochloric acid. The agitator is started and 2 parts of a calcium chlorite solution containing 68 grams of Ca (C10 2 per liter are added every 15 minutes until 24 parts have been added. A gasolene sweet to the Doctor test and of good color is produced.
Acid chlorite solutions apparently react with many of the sulphur compounds occurring in petroleum distillates to convert the sulphur of such compounds into reaction products soluble in water and thus susceptible of removal in the water of the treating solu- Application filed April 17,
1930. Serial No. 445,207.
tion or in the water of subsequent washes. Acid chlorite solutions, however, react to but a very slight extent, if at all, upon those hydrocarbon constituents of the petroleum distillate suitable as components of the refined product."
While alkali-metal chlorites or alkalineearth-metal chlorites are particularly useful in carrying out my invention, the other salts of chlorous acid and chlorous acid'itself are also useful in carrying out my invention, the
chlorite radical being the essential component.
I claim: 1. In sweetening petroleum distillates, the improvement which comprises subjecting the distillate to treatment with an acid aqueous solution of a chlorite of a metal of the group comprising the alkali-metals and the alka line-earth-metals.
2. In sweetening petroleum distillates, the
improvement which comprises subjecting the distillate to treatment with an acid aqueous
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US445207A US1908273A (en) | 1930-04-17 | 1930-04-17 | Sweetening petroleum distillates |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US445207A US1908273A (en) | 1930-04-17 | 1930-04-17 | Sweetening petroleum distillates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1908273A true US1908273A (en) | 1933-05-09 |
Family
ID=23767999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US445207A Expired - Lifetime US1908273A (en) | 1930-04-17 | 1930-04-17 | Sweetening petroleum distillates |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1908273A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2527176A (en) * | 1946-10-04 | 1950-10-24 | Standard Oil Dev Co | Treatment of oils corrosive to copper |
| EP0389150A1 (en) * | 1989-03-21 | 1990-09-26 | Baker Hughes Incorporated | Removal of sulphides |
-
1930
- 1930-04-17 US US445207A patent/US1908273A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2527176A (en) * | 1946-10-04 | 1950-10-24 | Standard Oil Dev Co | Treatment of oils corrosive to copper |
| EP0389150A1 (en) * | 1989-03-21 | 1990-09-26 | Baker Hughes Incorporated | Removal of sulphides |
| US5082576A (en) * | 1989-03-21 | 1992-01-21 | Bp Chemicals Limites | Removal of sulfides using chlorite and an amphoteric ammonium betaine |
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