US1896606A - Purifying tungsten - Google Patents

Purifying tungsten Download PDF

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Publication number
US1896606A
US1896606A US317493A US31749328A US1896606A US 1896606 A US1896606 A US 1896606A US 317493 A US317493 A US 317493A US 31749328 A US31749328 A US 31749328A US 1896606 A US1896606 A US 1896606A
Authority
US
United States
Prior art keywords
silver
tungsten
thoria
reduction
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US317493A
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English (en)
Inventor
Bates Charles Frederic William
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OHIO INSTR Manufacturing Co
OHIO INSTRUMENT MANUFACTURING Co
Original Assignee
OHIO INSTR Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OHIO INSTR Manufacturing Co filed Critical OHIO INSTR Manufacturing Co
Priority to US317493A priority Critical patent/US1896606A/en
Priority to BE365022D priority patent/BE365022A/xx
Application granted granted Critical
Publication of US1896606A publication Critical patent/US1896606A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
    • C22F1/18High-melting or refractory metals or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/045Alloys based on refractory metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/929Electrical contact feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/936Chemical deposition, e.g. electroless plating

Definitions

  • This invention relates to the production and purification of tungsten, and to electric conducting elements made therefrom, especially those which become highly heated in use such as electrical make-and-break contact points, incandescent filaments, etc.
  • the customary procedure is first to reduce tungstic oxide by hydrogen with the production or" a granular metallic powder, and next to sin ter the resulting granular substance together into the form of a somewhat porous rod or ingot by the use of a very high tem perature, after which the same is wrought by swaging, drawing, etc., the procedure being substantially the same as was employed in the making of wrought iron in the days when a sufficiently high temperature for the complete fusion of the iron was unattainable.
  • Such a metal is silver; and it is within my invention to mix finely divided silver with the previously reduced granular tungsten, and afterwards to compact and sinter the whole, finally raising the temperature to such a degree as wholly to volatilize the silver which takes with it all traces of oxygen.
  • the resulting bar or ingot shows no trace Application filed November 5, 1928. Serial No. 317,493.
  • Another way of securing the intimate admixture of metals necessary to the performance of this process is to reduce them simultaneously by hydrogen.
  • One way in which this can be done is to mix silver chloride intimately with the tungsten or other oxide, prior to the reduction by hydrogen, since silven chloride is likewise reduced under these conditions.
  • a still better way is to precipitate the silver compound into the tungstic oxide so as to obtainthe most complete incorporation at all stages of the process.
  • This reduction serves merely to change the thorium nitrate to oxide and I find that with the presence of silver as herein described I can work the resulting metal into filament form successfully even with a thoria content up to 3% although the silver is wholly volatilized during the sintering operation. This advantage is present whether or not special additional steps are taken to reduce the thoria to metallic form.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Powder Metallurgy (AREA)
US317493A 1928-11-05 1928-11-05 Purifying tungsten Expired - Lifetime US1896606A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US317493A US1896606A (en) 1928-11-05 1928-11-05 Purifying tungsten
BE365022D BE365022A (fr) 1928-11-05 1929-11-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US317493A US1896606A (en) 1928-11-05 1928-11-05 Purifying tungsten

Publications (1)

Publication Number Publication Date
US1896606A true US1896606A (en) 1933-02-07

Family

ID=23233894

Family Applications (1)

Application Number Title Priority Date Filing Date
US317493A Expired - Lifetime US1896606A (en) 1928-11-05 1928-11-05 Purifying tungsten

Country Status (2)

Country Link
US (1) US1896606A (fr)
BE (1) BE365022A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2476208A (en) * 1943-10-28 1949-07-12 Int Nickel Co Sintered precious metal product
US2669008A (en) * 1951-06-30 1954-02-16 Philips Lab Inc Method of manufacturing tungsten articles of predetermined shape and dimensions
US3091525A (en) * 1959-05-01 1963-05-28 Stauffer Chemical Co Deoxidation of refractory metal

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2476208A (en) * 1943-10-28 1949-07-12 Int Nickel Co Sintered precious metal product
US2669008A (en) * 1951-06-30 1954-02-16 Philips Lab Inc Method of manufacturing tungsten articles of predetermined shape and dimensions
US3091525A (en) * 1959-05-01 1963-05-28 Stauffer Chemical Co Deoxidation of refractory metal

Also Published As

Publication number Publication date
BE365022A (fr) 1929-12-31

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