US1896353A - Washable printed leather - Google Patents

Washable printed leather Download PDF

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Publication number
US1896353A
US1896353A US360606A US36060629A US1896353A US 1896353 A US1896353 A US 1896353A US 360606 A US360606 A US 360606A US 36060629 A US36060629 A US 36060629A US 1896353 A US1896353 A US 1896353A
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US
United States
Prior art keywords
leather
washable
printed leather
hides
skins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US360606A
Inventor
Charles S Friedman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anciens A Combe & Fils & Cie Ets Ste
Anciens Ets A Combe & Fils
Original Assignee
Anciens Ets A Combe & Fils
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US631954A external-priority patent/US1716120A/en
Application filed by Anciens Ets A Combe & Fils filed Critical Anciens Ets A Combe & Fils
Priority to US360606A priority Critical patent/US1896353A/en
Application granted granted Critical
Publication of US1896353A publication Critical patent/US1896353A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/32Material containing basic nitrogen containing amide groups leather skins
    • D06P3/326Material containing basic nitrogen containing amide groups leather skins using metallisable or mordant dyes

Definitions

  • the present application which is a division of my Patent 1,716,120, dated June 4, 1929, relates to a process for producing washable printings upon leather. with the purpose of obtaining articles, which besides being adapted for the above mentioned purposes, may compete with the polychromatic fabrics as used actually for shoes, slippers and the like, which they imitate in appearance and of which they possess the softness.
  • the hide or skin is first tanned with formol in the usual manner, this tanning operation enabling the hide orskin to subsequently withstand, after printing, a temperature sufficiently high to fix the dye-stuffs used for printing fabrics.
  • the hides or skins are submitted to a new tanning operation in a bath of powdered sumach or any other similar substance, for an hour, at a temperature of C.
  • the hides or skins are placed in a steam room, for about one hour, at a temperature of 75 C. a v
  • This steaming has for its purpose, the thorough penetration of the dye-stuff which, prior to this operation, was but superficial. Moreover this-treatment in the steam room means a step towards the fixing which is effected by employing the usual pigments or mordants and is completed in a bath of emetic such as tartar emetic or of acid, according to the nature of the dye-stuffs used.
  • the hides or skins are then washed in clear water; they are thus ready to be used for the manufacture of the articles for which they are intended.
  • the leather thus printed retains, after washing all its properties as to softness and strength; moreover the penetration of the dye-stuff is deep enough, so that the colours will not fade after a certain time of use.
  • the tanning with formol could easily be re laced by a tawing process with the use ofiformol or alum.
  • a leather provided with decorative colored design e acid or metallic mordants are emsin thickness of the leather, both said leather and saidcoloring being adapted to withstand washing.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Description

: plates, with the employment for Patented Feb. 7, 1933 UNITED STATES PATENT OFFICE CHARLES S. FRIEDMAN, OF
NEUILLY-SUR-SEINE, FRANCE, ASSIGNOR T0 socIE'rE ANGIENS ETABLISSEMENTS COMBE & FILS & CIE., OF IPARIS, FRANCE, A CORPORA- TION OF FRANCE WASHABLE PRINTED LEATHER No Drawing. Original applicationfiled April 13, 1923, Serial No. 631,954, Patent No. 1,716,120, and in France November 30, 1922. Divided and this application filed May 4, 1929. Serial No. 860,606.
Heretofore, the only hides or skins used for the production of printings were those which have been tanned with vegetal substances, like those which are used for making moroccoleather goods, for furniture, book-bindings, fancy articles, millinery and dress-making. Besides this, the leather and the printing would not resist washing.
The present application which is a division of my Patent 1,716,120, dated June 4, 1929, relates to a process for producing washable printings upon leather. with the purpose of obtaining articles, which besides being adapted for the above mentioned purposes, may compete with the polychromatic fabrics as used actually for shoes, slippers and the like, which they imitate in appearance and of which they possess the softness.
According to the invention, the hide or skin is first tanned with formol in the usual manner, this tanning operation enabling the hide orskin to subsequently withstand, after printing, a temperature sufficiently high to fix the dye-stuffs used for printing fabrics.
After the operation of tanning with formol, the hides or skins are submitted to a new tanning operation in a bath of powdered sumach or any other similar substance, for an hour, at a temperature of C.
They are for instance mechanically treated in the usual manner in order to give them the appearance of velvet, or suede leather; in other words, ooze or suede, or any other finish.
After having been dried at 35 0., the hides or skins are then ready to be printed. This operation is performed by means of engraved example, of the following mixture Dye-stufi' (Rhodamine) Tragacanth Acetate of chrome Tannic acid Glycerine Water The printin 25 to 30 grams 200 to 500 grams 40 to 60 grams 5 to 10 grams 5 to 10 grams 2 liters colours can be applied upon any ground co or or the ground color can be obtained after printing. I
After the printingbperation has taken the hides or skins receive an place, the hides or skins are placed in a steam room, for about one hour, at a temperature of 75 C. a v
This steaming has for its purpose, the thorough penetration of the dye-stuff which, prior to this operation, was but superficial. Moreover this-treatment in the steam room means a step towards the fixing which is effected by employing the usual pigments or mordants and is completed in a bath of emetic such as tartar emetic or of acid, according to the nature of the dye-stuffs used.
T ployed to temporarily fix the dyestuffs which have been applied; but their main purpose is to form a chemical combination which intimately associates itself with the fibres of the leather, after a stay in the emetic and acid baths.
Any colour may be used in carrying out the process and as may be readily understood by those skilled in the art, the mordant employed will depend upon the colour used.
The hides or skins are then washed in clear water; they are thus ready to be used for the manufacture of the articles for which they are intended.
The leather thus printed, retains, after washing all its properties as to softness and strength; moreover the penetration of the dye-stuff is deep enough, so that the colours will not fade after a certain time of use.
It must be observed that the above figures and details for carrying out the invention have been given only by way of example and that they can be modified withoutdeparting from the principle ofthe invention.
For instance, the tanning with formol could easily be re laced by a tawing process with the use ofiformol or alum.
What I claimis':
As a new article of manufacture, a leather provided with decorative colored design e acid or metallic mordants are emsin thickness of the leather, both said leather and saidcoloring being adapted to withstand washing.
In testimony whereof I have signed this specification.
CHARLES s. FRIEDMAN.
US360606A 1923-04-13 1929-05-04 Washable printed leather Expired - Lifetime US1896353A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US360606A US1896353A (en) 1923-04-13 1929-05-04 Washable printed leather

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US631954A US1716120A (en) 1922-11-30 1923-04-13 Process for the production of washable printings on leather
US360606A US1896353A (en) 1923-04-13 1929-05-04 Washable printed leather

Publications (1)

Publication Number Publication Date
US1896353A true US1896353A (en) 1933-02-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
US360606A Expired - Lifetime US1896353A (en) 1923-04-13 1929-05-04 Washable printed leather

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