US1887290A - Blasting cap - Google Patents

Blasting cap Download PDF

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Publication number
US1887290A
US1887290A US485557A US48555730A US1887290A US 1887290 A US1887290 A US 1887290A US 485557 A US485557 A US 485557A US 48555730 A US48555730 A US 48555730A US 1887290 A US1887290 A US 1887290A
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US
United States
Prior art keywords
nitromaltose
charge
blasting cap
primer
cap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US485557A
Inventor
Willard De C Crater
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hercules Powder Co
Original Assignee
Hercules Powder Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules Powder Co filed Critical Hercules Powder Co
Priority to US485557A priority Critical patent/US1887290A/en
Application granted granted Critical
Publication of US1887290A publication Critical patent/US1887290A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B37/00Compositions containing a metal fulminate
    • C06B37/02Compositions containing a metal fulminate with a nitrated organic compound or an inorganic oxygen-halogen salt

Definitions

  • My invention relates to an improvement in charges for blasting caps such as are customarily used in connection with commercial explosives.
  • blasting caps are used to efiect the detonation or firing of commercial explosives, such as dynamites, permissible explosives, etc., which require for their detonation or firing a primer charge as compared with mere ignition, as in the case of firing, for example, black powder.
  • commercial explosives such as dynamites, permissible explosives, etc.
  • a primer charge as compared with mere ignition, as in the case of firing, for example, black powder.
  • various substances and mixtures of substances have been utilized in the charging of blasting caps; however, the prior caps have not been entirely satisfactory from all standpoints.
  • nitromaltose is associated with some substance capable of acting as an initial primer,the initial primer being superimposed on the nitromaltose or being admixed therewith, or both.
  • the nitromaltose used in accordance with my invention may be produced by nitrating maltose, a sugar, in any convenient way, as, for example, by adding dry maltose to a suitable mixture of nitric and sulphuric acids, then pouring the mixture into water to efiect dilution of the acids and separation of the nitromaltose.
  • the nitromaltose is then Washer with dilute sodium carbonate solution and water until it is free from acid and stable under suitable heat tests.
  • the nitromaltose in association with any desired substance or compound which will be elIect-ive as an initial primer such as, for example, fulminatechlorate, diazodinitrophenol, lead azide, etc. and, as has been indicated, the substance or compound used as an initial primer may be superimposed on the nitromaltose, or may be admixed therewith, or both.
  • the cap shell may be first charged with say about .20 g. of nitromaltose and there may then Application filed September 30, 1930. Serial No. 485,557.
  • the nitromaltose and fulminate-chlorate may be intermixed, preferably intimately, and the mixture charged into the ca shell and suitably compressed.
  • the mixture may comprise 40% nitromaltose and 60% fulminate-chlorate.
  • cap in accordance withmy invention will possess characteristics equal to or superior to caps heretofore known, and particularly as regards grams of sand crushed in the sand test and in their capacity for eiiiciently detonating commercial explosives, as for example, dynamites, etc; and it Will be further noted that the nitromaltose will be found to be dense and free flowing, which renders it especially adaptable to mechanical loading. I It will be.
  • nitromaltose as a charge for blasting caps, the nitromaltose being associated in a practical manner with a substance adapted to act as an initial primer, as for example, in admixture therewith, or as a base charge thereunder, or both.
  • nitromaltose inay be used in association, as in admixture with another explosive not neces sarily a primer, as for example, tetryl, trinitrotoluene, nitrostarch, etc.
  • a blasting cap a charge including crystallized nitromaltose and a substance capable of acting as a primer for the nitromaltose.
  • a blasting cap in a blasting cap a charge including in admixture nitromaltose and a substance capable of acting as a primer for the nitromaltose.
  • a blasting cap in a blasting cap a charge including crystallized nitromaltose and diazodinitrophenol in admixture as a base charge and a primer charge of diazodinitrophenol superimposed thereon.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Patented Nov. 8, 1932 WILLARD DE C. CRATER, OF SUCCASUNNA, NEW JERSEY, ASSIGNOB, TO HERCULES POWDER COHIPANY, OF WILMINGTON, DELAWARE, A CORPORATION OF DELAWARE I BLASTING CAP No Drawing.
My invention relates to an improvement in charges for blasting caps such as are customarily used in connection with commercial explosives.
As is well known, blasting caps are used to efiect the detonation or firing of commercial explosives, such as dynamites, permissible explosives, etc., which require for their detonation or firing a primer charge as compared with mere ignition, as in the case of firing, for example, black powder. Heretofore various substances and mixtures of substances have been utilized in the charging of blasting caps; however, the prior caps have not been entirely satisfactory from all standpoints.
Now, in accordance with my invention, I have discovered that a superior blasting cap is provided where the cap is charged with nitromaltose. In accordance with my invention the nitromaltose is associated with some substance capable of acting as an initial primer,the initial primer being superimposed on the nitromaltose or being admixed therewith, or both.
The nitromaltose used in accordance with my invention may be produced by nitrating maltose, a sugar, in any convenient way, as, for example, by adding dry maltose to a suitable mixture of nitric and sulphuric acids, then pouring the mixture into water to efiect dilution of the acids and separation of the nitromaltose. The nitromaltose is then Washer with dilute sodium carbonate solution and water until it is free from acid and stable under suitable heat tests.
In producing a blasting cap in accordance with my invention, the nitromaltose in association with any desired substance or compound which will be elIect-ive as an initial primer, such as, for example, fulminatechlorate, diazodinitrophenol, lead azide, etc. and, as has been indicated, the substance or compound used as an initial primer may be superimposed on the nitromaltose, or may be admixed therewith, or both.
In the production of a cap in accordance with my invention, for example, the cap shell may be first charged with say about .20 g. of nitromaltose and there may then Application filed September 30, 1930. Serial No. 485,557.
If desired, in chargmg a cap with nitromaltose and, for example, fulminate-chlorate, the nitromaltose and fulminate-chlorate may be intermixed, preferably intimately, and the mixture charged into the ca shell and suitably compressed. For examp e, the mixture may comprise 40% nitromaltose and 60% fulminate-chlorate.
It will be noted that the cap in accordance withmy invention will possess characteristics equal to or superior to caps heretofore known, and particularly as regards grams of sand crushed in the sand test and in their capacity for eiiiciently detonating commercial explosives, as for example, dynamites, etc; and it Will be further noted that the nitromaltose will be found to be dense and free flowing, which renders it especially adaptable to mechanical loading. I It will be. understood that my invention from the broad standpoint involves the use of nitromaltose as a charge for blasting caps, the nitromaltose being associated in a practical manner with a substance adapted to act as an initial primer, as for example, in admixture therewith, or as a base charge thereunder, or both.
It will also be understood that the nitromaltose inay be used in association, as in admixture with another explosive not neces sarily a primer, as for example, tetryl, trinitrotoluene, nitrostarch, etc.
What I claim and desire to protect by Letters Patent is:
1. In a blasting cap a charge including crystallized nitromaltose.
2. In a blasting cap a charge including crystallized nitromaltose and a substance capable of acting as a primer for the nitromaltose.
3. In a blasting cap a charge including in admixture nitromaltose and a substance capable of acting as a primer for the nitromaltose.
4. In a blasting cap a charge including crystallized nitromaltose as a case charge and a substance capable of acting as a primer for 8. In a blasting cap a charge including I crystallized nitromaltose as a base charge and a primer charge superimposed thereon.
9. in a blasting cap a charge including crystallized nitromaltose and fulminatechlorate in admixture as a base charge and a primer charge of fulminate-chlorate superimposed thereon.
10. In a blasting cap a charge including crystallized nitromaltose and diazodinitrophenol. r
11. In a blasting cap a charge including crystallized nitromaltose and diazodinitrophenol in admixture.
12. In a blasting cap a charge including crystallized nitromaltose as a base charge and a primer charge of diazodinitrophenol super-- imposed thereon.
13. In a blasting cap a charge including crystallized nitromaltose and diazodinitrophenol in admixture as a base charge and a primer charge of diazodinitrophenol superimposed thereon.
14%. In a blasting cap a charge including crystallized nitromaltose and lead azide.
15. In a blasting cap a charge including crystallized nitromaltose and lead azide in admixture.
16. In a blasting cap a charge including crystallized nitromaltose as a base charge and a primer charge of lead azide superimposed thereon.
17 In a blasting cap a charge including crystallized nitromaltose and lead azide in admixture as a base charge and a primer charge of lead azide superimposed thereon.
In testimony of which invention, I have hereunto set my hand at Kenvil, N. J on this 26th day of Sept, 1930.
WILLIARD DE G. CRATER.
US485557A 1930-09-30 1930-09-30 Blasting cap Expired - Lifetime US1887290A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US485557A US1887290A (en) 1930-09-30 1930-09-30 Blasting cap

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2495868A (en) * 1946-01-30 1950-01-31 Atlas Powder Co Detonator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2495868A (en) * 1946-01-30 1950-01-31 Atlas Powder Co Detonator

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