US1870306A - Cathode for electron discharge devices - Google Patents

Cathode for electron discharge devices Download PDF

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US1870306A
US1870306A US112180A US11218026A US1870306A US 1870306 A US1870306 A US 1870306A US 112180 A US112180 A US 112180A US 11218026 A US11218026 A US 11218026A US 1870306 A US1870306 A US 1870306A
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cathode
electron
coating
current
alternating current
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US112180A
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Widell Emil Gideon
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Westinghouse Lamp Co
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Westinghouse Lamp Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/13Solid thermionic cathodes
    • H01J1/14Solid thermionic cathodes characterised by the material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/90Magnetic feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/294Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/2958Metal or metal compound in coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/298Physical dimension

Definitions

  • This invention relates to a cathode for an electron discharge device and more particularly to a cathode adapted to be heated by alternating current without the drawbacks normally incident to the employment of such heating currents.
  • the objects of the present invention is to produce an electron-emitting cathode for an electron discharge device which :lo may be heated from an alternating current,
  • Another object is to produce an electronemitting cathode operable on an alternating current heating source which will have a low power consumption.
  • Another object is to produce a cathode ⁇ tor an electron discharge device adapted to be heated by alternatingacnrrent in which the troublesome edects caused by the changing magnetic held produced by the passage or the alternating current through the cathode will be reduced to a negligible degree.
  • Another object is to provide a cathode operable on alternating current which is simple in construction and edective in operation and which will have a long lite and uniform operating characteristics.
  • a still further cause of this noise incident to the use of alternating current for heating the filament is due to the constantly changing magnetic eld surrounding the larnent set up b a passage of current therethrough.
  • This fie d exerts an irregular edect on the emitted electrons, causing them to travel in various and constantly changed directions and periodically repulsing and accelerating the electron stream in such manner as to produce an irregular and pulsating current.
  • Another method which has been proposed to overcome the diculty incident to using alternating current-as a heating source is to employ an auxiliary heater .for heating the cathode by induction and radiation.
  • One method which'has been suggested is to employ a refractory core having a heatingcoilor electrica-l resistor therein, said core having a metal sheath coated with the oxides of the alkaline earth metals.
  • Such a cathode is of complicated construction and expensive to manufacture. Moreover, it requires a high heating current usually about 11/2 amperes and due to the large diameter thereof, there is an appreciable capacity effect between the cathode and the other electrodes which, to some extent, affects the obtaining of clear reception.
  • the present invention aims to avoid all of the above mentioneddifliculties or to reduce the effects thereof to a negligible degree so that the hum incident to the use of alternating current for heating the cathode is not detectable in the output circuit.
  • I construct a cathode having a metal core of small cross section and consequently small current consumption and coat the same with an extremely heavy layer of a non-metallic refractory material of poor heat conductivity but high electron emissivity.
  • a non-metallic refractory material of poor heat conductivity but high electron emissivity.
  • Such a material may consist of a mixture of the oxides of the alkaline earth metals such as barium. and strontium or a mixture of such oxides with other refractory oxides such' as magnesia and alumina.
  • the oxide coat ing acts as an extremely efficient medium for storing up the heat supplied by the metallic core and maintaining the temperature of the cathode substantially uniform throughout the alterations in the heating current so that the emission obtained from the filament is substantially uniform.
  • a coating of the oxides of barium and strontium is applied and sufficient thickness to constitute about 10 milligrams of the coating material per square centimeter of surface area of the cathode. This Weight of coating is many times that employed in the ordinary construction of oxide coated cathode. Good results are obtainable with from 3 to 4 milligrams of the coating per square centimeter but 1n order to insure the elimination of the 120 cycle hum obtained from the G0 cycle alternating current heating source I prefer to employ the heavier coating.
  • the coating may be applied in the form of a carbonate of the alkaline earth metal although I do not desire to be limited to any particular method of producing such heavy coating.
  • One method which may be employed for producing the cathode is that described in application Serial No. 587,270 of Duncan MacRae, filed Sept. 11, 1922, Patent No. 1,812,103 entitled Electron emitting cathode and method of making and assigned to the lVestinghouse Lamp Company. Briefly, such method consists in applying a number of coatings of the carbonates of barium and strontium from an aqueous suspension thereof, the cathode being heated after each application of the coating material in carbon dioxide at a sufficiently high temperature to fuse the coat-ing thereto.
  • the filament is mounted in a discharge device in the usual manner and heated preferably during exhaustion to decompose the carbonate to the oxide,'the liberated gases being withdrawn by the exhaust system.
  • I preferably employ a metallic core which is operable at about 1A@ ampere to produce the requisite heat for obtaining emission from the oxide coating.
  • smaller metallic cores may be employed if desired. It has been determined, however, that when a metallic core consuming about 1A@ ampere is employed that the magnetic field produced by suchpcurrent does not appreciably effect the electron stream so as to produce irregular current flow in the output circuit.
  • it may be composed in part of other inert refractory non-conduct- 100 ing material such as the oxides of magnesium or aluminum either mixed With the electronemiting material or applied as separate layers.
  • the inert oxides do not interfere with the Ielectron emission from the alkaline earth 105 oxides and serve as an extremely efficient heat reservoir for maintaining the temperature of the cathode uniform.
  • End losses are substantially eliminated when employing a thin metallic core since 110 the loss of heat by conduction through the thin core to the lead wires is negligible as compared to such loss in heavy metallic cores.
  • the capacity effect between the cathode and the other electrodes is also small when em- 115 ploying thin metal cores for the cathode and the alternating current hum caused by this capacity effect is thereby lessened.
  • Fig. 1 illustrates a conventional type o threeelectrode tube employing the cathode described herein and circuit arrangement therefor;
  • dFig. 2 is a cross sectional View of the cath- 125 o e. v
  • the tube shown in Fig. 1 comprises the usual envelope 1 containing a cathode 2 constructed in accordance with the foregoing description, a grid 3 and an anode or plate 1.30
  • Electrodes 4 are supported from the press 5 in the usual manner and are provided with current conductors 6 secured to contact posts 7 carried by the base 8 oi the tube.
  • rlhe cathode is heated to an electron-emitting temperature by any convenient source of alternating current., as the secondary 9 of a transformer l0. rlhe circuit arrangement shown is of the conventional type of detector circuit.
  • the cathode consists of a thin metallic core l1 of. suitable metal, such as platinum or platinum-iridium, and a heavy layer 12 of a refractory electron-emitting oxide such as an oxide of an alkaline earth metal. It will be appreciated that the view shown in Fig. 2 is enlarged many times the core preferably being of such diameter that it consumes not more than one-half ampere of current.
  • a cathode for an electron discharge device comprlsing an electrically conducting core member and a coating of a thermionically active material on the outer surface of said core member', with a substantial portion of said surface having on each square centimeter thereof a coating of about three to ten milligrams of the thermionically active material, said metallic core operable at no greater than about one-half ampere to produce the requisite heat for obtaining electron emission from said coating.
  • An electron emitting cathode composed EML GDEON WllDELL.

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  • Solid Thermionic Cathode (AREA)

Description

ATTORNEY Aug. 9, 1932.v E. G. WIDELL CATHODE FOR ELECTRON DISCHARG DEVICES Filed May 27, 192e Patented Aug. 9, 1932 UNITED s'r'ivrr-:s Pmizlwrl OFFICE EMIL' eIDEoN WIDELL, or BLoomnLD, NEW JERSEY, AssrGNoB. 'ro wEsrINGHoUsE LAMP COMPANY, A CORPORATION or PENNSYLVANIA CATHODE FOB ELECTBON DISCHARGE DEVICES Application mea uay 27,
This invention relates to a cathode for an electron discharge device and more particularly to a cathode adapted to be heated by alternating current without the drawbacks normally incident to the employment of such heating currents.
@ne ot the objects of the present invention is to produce an electron-emitting cathode for an electron discharge device which :lo may be heated from an alternating current,
source and in which the usual alternating current hum will be eliminated.
Another object is to produce an electronemitting cathode operable on an alternating current heating source which will have a low power consumption. a
Another object is to produce a cathode `tor an electron discharge device adapted to be heated by alternatingacnrrent in which the troublesome edects caused by the changing magnetic held produced by the passage or the alternating current through the cathode will be reduced to a negligible degree.
Another object is to provide a cathode operable on alternating current which is simple in construction and edective in operation and which will have a long lite and uniform operating characteristics.
@ther objects and advantages will hereinafter appear.
` Heretotore great dithculty has been experienced in utilizing alternating current for heating the cathode of an electron discharge device tor use in radio receiving apparatus due to the hum which is produced in the -receiving apparatus by the alternating currentand which seriouslydnterferes with the recaption.
1928. Serial No. 112,180.
ing current and the consequent fluctuations in the electron emission-from the cathode.
A still further cause of this noise incident to the use of alternating current for heating the filament is due to the constantly changing magnetic eld surrounding the larnent set up b a passage of current therethrough. This fie d exerts an irregular edect on the emitted electrons, causing them to travel in various and constantly changed directions and periodically repulsing and accelerating the electron stream in such manner as to produce an irregular and pulsating current.
It has been proposed heretofore, to construct a cathode adapted to be heated by alternating current, of a heavy metal core, the function oi which is to serve as a heart reservoir to obtain a more uniform temperature ci the cathode and thus eliminate the variations in the electron emission, due to ductuating temperature. Such filaments, however7 require large heating currents, due to their large cross section, the minimum current iiow obtainable with such cathodes being about lll/2 amperes. This heavy current Citi induces a strong magnetic tield about the v cathode which is constantly fluctuating and which largely overcomes the beneficial ed'ect of the uniform heating or the cathode. Moreover, in employing thiol; heavy metallic filaments of this nature there is a large loss of power at the ends of the filament, known as end losses due to the rapid conduction et heat vfrom the lament by the leading-in and support Wires.
Another method which has been proposed to overcome the diculty incident to using alternating current-as a heating source is to employ an auxiliary heater .for heating the cathode by induction and radiation. One method which'has been suggested is to employ a refractory core having a heatingcoilor electrica-l resistor therein, said core having a metal sheath coated with the oxides of the alkaline earth metals. Such a cathode is of complicated construction and expensive to manufacture. Moreover, it requires a high heating current usually about 11/2 amperes and due to the large diameter thereof, there is an appreciable capacity effect between the cathode and the other electrodes which, to some extent, affects the obtaining of clear reception.
The present invention aims to avoid all of the above mentioneddifliculties or to reduce the effects thereof to a negligible degree so that the hum incident to the use of alternating current for heating the cathode is not detectable in the output circuit. In accordance with my invention I construct a cathode having a metal core of small cross section and consequently small current consumption and coat the same with an extremely heavy layer of a non-metallic refractory material of poor heat conductivity but high electron emissivity. Such a material may consist of a mixture of the oxides of the alkaline earth metals such as barium. and strontium or a mixture of such oxides with other refractory oxides such' as magnesia and alumina. I have found that when au sufliciently heavy layer of alkaline earth oxides, for instance, are applied to a small platinum or platinum-iridium wire that the oxide coat ing acts as an extremely efficient medium for storing up the heat supplied by the metallic core and maintaining the temperature of the cathode substantially uniform throughout the alterations in the heating current so that the emission obtained from the filament is substantially uniform. Preferably, a coating of the oxides of barium and strontium is applied and sufficient thickness to constitute about 10 milligrams of the coating material per square centimeter of surface area of the cathode. This Weight of coating is many times that employed in the ordinary construction of oxide coated cathode. Good results are obtainable with from 3 to 4 milligrams of the coating per square centimeter but 1n order to insure the elimination of the 120 cycle hum obtained from the G0 cycle alternating current heating source I prefer to employ the heavier coating.
The coating may be applied in the form of a carbonate of the alkaline earth metal although I do not desire to be limited to any particular method of producing such heavy coating. One method which may be employed for producing the cathode is that described in application Serial No. 587,270 of Duncan MacRae, filed Sept. 11, 1922, Patent No. 1,812,103 entitled Electron emitting cathode and method of making and assigned to the lVestinghouse Lamp Company. Briefly, such method consists in applying a number of coatings of the carbonates of barium and strontium from an aqueous suspension thereof, the cathode being heated after each application of the coating material in carbon dioxide at a sufficiently high temperature to fuse the coat-ing thereto.
Another method is that disclosed in co-pending application Serial No. 108,235, Widell et al., filed May 11, 1926 entitled Oxide coated cathodes and method of making the same, and assigned to the lVestinghouse Lamp Company. This method consists in suspending the carbouates of the alkaline earth metals in a solution of a cellulose ester dissolved in alcohol and ether and baking the coatings on at about 200o C. to drive out the volatile solvent. Thismethod is preferable to the former in some respects since it permits heavier coatings being obtained at each application of the carbonate, thereby reducing somewhat the number of coatings required to produce the requisite thickness on the metal core.
After the carbonate coating of the desired thickness has been formed, the filament is mounted in a discharge device in the usual manner and heated preferably during exhaustion to decompose the carbonate to the oxide,'the liberated gases being withdrawn by the exhaust system.
I preferably employ a metallic core which is operable at about 1A@ ampere to produce the requisite heat for obtaining emission from the oxide coating. However', smaller metallic cores may be employed if desired. It has been determined, however, that when a metallic core consuming about 1A@ ampere is employed that the magnetic field produced by suchpcurrent does not appreciably effect the electron stream so as to produce irregular current flow in the output circuit. Instead of making the coating entirely of the oxides ofbarium and strontium, it may be composed in part of other inert refractory non-conduct- 100 ing material such as the oxides of magnesium or aluminum either mixed With the electronemiting material or applied as separate layers. The inert oxides do not interfere with the Ielectron emission from the alkaline earth 105 oxides and serve as an extremely efficient heat reservoir for maintaining the temperature of the cathode uniform.
End losses are substantially eliminated when employing a thin metallic core since 110 the loss of heat by conduction through the thin core to the lead wires is negligible as compared to such loss in heavy metallic cores. The capacity effect between the cathode and the other electrodes is also small when em- 115 ploying thin metal cores for the cathode and the alternating current hum caused by this capacity effect is thereby lessened.
Reference is made to the accompanying drawing in which:
Fig. 1 illustrates a conventional type o threeelectrode tube employing the cathode described herein and circuit arrangement therefor; and,
dFig. 2 is a cross sectional View of the cath- 125 o e. v
The tube shown in Fig. 1 comprises the usual envelope 1 containing a cathode 2 constructed in accordance with the foregoing description, a grid 3 and an anode or plate 1.30
electrode 4. These electrodes are supported from the press 5 in the usual manner and are provided with current conductors 6 secured to contact posts 7 carried by the base 8 oi the tube.
rlhe cathode is heated to an electron-emitting temperature by any convenient source of alternating current., as the secondary 9 of a transformer l0. rlhe circuit arrangement shown is of the conventional type of detector circuit.
The cathode consists of a thin metallic core l1 of. suitable metal, such as platinum or platinum-iridium, and a heavy layer 12 of a refractory electron-emitting oxide such as an oxide of an alkaline earth metal. It will be appreciated that the view shown in Fig. 2 is enlarged many times the core preferably being of such diameter that it consumes not more than one-half ampere of current.
lt will be noted that by the present invention all of the material causes of humming due to the alternating current heating source are eliminated or reduced. The irregular eii'ect of the alternating heating current is eliminated by providing' a heat reservoir of considerable capacity and low thermal conductivity. The hum caused by the magnetic field surrounding the cathode is reduced to a 4 negligible amount by employing a metallic core which requires a small heating current to raise it to the required temperature and the hum due to capacity between the grid andsaid core member, with a substantial portion of said surface having on each square centimeter thereof a coating of about three to ten milligrams of the thermionically active material.
2. A cathode for an electron discharge device comprlsing an electrically conducting core member and a coating of a thermionically active material on the outer surface of said core member', with a substantial portion of said surface having on each square centimeter thereof a coating of about three to ten milligrams of the thermionically active material, said metallic core operable at no greater than about one-half ampere to produce the requisite heat for obtaining electron emission from said coating.
3. An electron emitting cathode composed EML GDEON WllDELL.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2848635A (en) * 1954-11-16 1958-08-19 Vacuum Electronic Engineering Ionization gauges

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2848635A (en) * 1954-11-16 1958-08-19 Vacuum Electronic Engineering Ionization gauges

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