US186654A - Improvement in processes and apparatus for treating ores - Google Patents
Improvement in processes and apparatus for treating ores Download PDFInfo
- Publication number
- US186654A US186654A US186654DA US186654A US 186654 A US186654 A US 186654A US 186654D A US186654D A US 186654DA US 186654 A US186654 A US 186654A
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- ore
- retort
- mass
- steam
- pipe
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- 238000000034 method Methods 0.000 title description 28
- 238000002485 combustion reaction Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 239000005864 Sulphur Substances 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 8
- 239000011707 mineral Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 229920002456 HOTAIR Polymers 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 230000036633 rest Effects 0.000 description 6
- 235000009324 Pinus caribaea Nutrition 0.000 description 4
- 235000008568 Pinus coulteri Nutrition 0.000 description 4
- 240000006736 Pinus coulteri Species 0.000 description 4
- 235000017339 Pinus palustris Nutrition 0.000 description 4
- 235000007738 Pinus rigida Nutrition 0.000 description 4
- 229910000754 Wrought iron Inorganic materials 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 239000003517 fume Substances 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000001264 neutralization Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 230000001105 regulatory Effects 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 235000009781 Myrtillocactus geometrizans Nutrition 0.000 description 2
- 240000009125 Myrtillocactus geometrizans Species 0.000 description 2
- 238000005267 amalgamation Methods 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000003467 diminishing Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003415 peat Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 229910052904 quartz Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/0038—Obtaining aluminium by other processes
- C22B21/0053—Obtaining aluminium by other processes from other aluminium compounds
- C22B21/0061—Obtaining aluminium by other processes from other aluminium compounds using metals, e.g. Hg or Mn
Definitions
- My invention is mainly for the purpose of desulphurizing the ores of metals, or for expelling from minerals such matters as may be volatilized by heat and chemical reaction.
- the ore Before subjecting the minerals to treatment by this process, the ore is reduced to a fine powder, and any usual means may be used to concentrate the ore and separate from it the barren matters that may be associated with it, to avoid the expense of their treatment.
- FIG. 1 is an elevation of the furnace.
- Fig. 2 is a vertical section through the center of the same.
- Fig. 3 is a horizontal section, part above and part below the bottom of the retort.
- Fig. 4 is a vertical section at a right angle to Fig. 2.
- A is the brick-work of the furnace.
- B is the grate.
- O is the fire-door.
- D is the ashpit door.
- E is the retort, which, by preference, is made of wrought-iron plate riveted. It is about five feet, more or less, in diameter, and about two feet deep in the clear, and will contain a charge of about two tons of ore. It is suspended from the under side of the plate G, which rests upon the top of the brick-work and forms the top of the furnace. The retort extends downward within the furnace to within about two feet from the grate, depending upon the kind of fuel used.
- a perforated plate, B which is filled with small holes, say, one-sixteenth of an inch in diameter, or less, and an inch, more or less, apart, and said plate is supported in r the retort sufficiently to carry the whole charge of ore that is treated, leaving a free open space below it, into which is admitted 2.
- current of hot air, or air and steam as will be described.
- the top of the retort is covered in part by the plate G, to which the retort is attached, and the opening through which is covered by the hood or cover K, which is raised up out of the way when it is necessary to empty or charge the retort, which hood is provided with a large upright pipe, K, to conduct away the fumes that may be produced in the retort during the operation.
- the lower edge of the hood K rests in the trough or channel L formed around the opening through the top plate G, which is partly filled with dry sand or powdered treated ore, which closes the joint of the cover sufficiently to carry off the fumes produced in the retort through the pipe K.
- the pipe K extends upward about six feet, and enters an exterior pipe, M, which is a little larger in diameter than the pipe K, and in which said pipe K slides telescope fashion.
- the pipe M leads to a chimney or to the open air. Or, in case it should be desired to save any of the volatile products of the operation, this pipe would be led to suitable condensing or depositing chambers; but these form no part of the present process.
- the cover-K and pipe K are count'erpoised by a weight, 0, and chain 0, which work over pulleys placed above, by which the cover K can be raised up out of the way of the workman in emptying or charging the retort.
- P is an opening through the side of the retort, even at the bottom with the top of the perforated plate B, through which opening the contents of the retort are removed. This opening is provided with a spout, P, which extends outside of the wall of the furnace, as shown, and at the inside of the retort is provided with a sliding door, Q, which closes it.
- F is a coil of wrought-iron pipe, which is coiled spirally in a plane with its convolutions close together, and placed but a little distance from the bottom of the retort, and the exterior diameter of the coil is about the same as that of the retort.
- the inner end of this coiled pipe is inserted into the bottom of the retort at the center, and projects about an inch above the bottom, and the outer end of this pipe is extended outward through the wall of the furnace, and is connected with a blowingmachine of some kind by the pipe R that will drive a current of air under pressure through the mass of ore above the perforated plate B in the retort, which current is controlled by the stop-valve H.
- a smaller steampipe, J which connects with a steam-boiler
- the pulverized ore is then mixed with about its bulk of pitch-pine saw-dust, uniformly incorporated with the mass, when the whole is moistened with salt water, by preference seawater, or water of the same saltness, but not made so wet as to drip.
- salt water I do not regard as indispensable, as the process of desulphurization may be carried on without it; but it is better done with it, as the action of the chlorine, or soda, or both, supplied by the salt, serves to render the gold eliminated by the process bright and clean, and in good condition for amalgamation, if that method is employed for saving the precious metals.
- This moistened mass is placed in the retort just described upon the perforated plate B, first strewing some sawdust or fine shavings upon it, to prevent the powdered ore from falling through the holes in the plate.
- the hood or cover K When the retort is charged full, the hood or cover K is lowered, so that its lower edge rests in the dry sand or treated powdered ore which is placed in the groove or channel L, which sufficiently closes the joint.
- the air from the blowing-machine is gradually let on by the air-cock H, and flows into the heatingcoil F, by which the air is heated to, say, 500 or 600 Fahrenheit, and discharged into the space or chamber in the retort below the ore.
- the effect of the hot-blast is to heat up the mass of the ore uniformly, and dry out the moisture, and, as soon as the ore is hot enough, to ignite the sulphur in the ore.
- the carbon of the sawdust also aids in the decomposition of the water of the steam mixed with the air while within the mass of ore itself, and produces a set of interactions among the matters present by the sublimation and ignition of the sulphur, the destructive distillation and combustion of the sawdust, and the production of chlorine from the salt, which I am not able to explain, but which experiment has shown are very efiicicnt in liberating the precious metals from their connection with the sulphurous and volatile matters with' which they are associated.
- the destruction, also, of the sawdust within the mass of ore, leaves the latter porous and permeable throughout to the circulation of the current of hot air and steam through it, and enables them to lift out and carry away from the mass of ore all the vaporized matters as fast as they are liberated from the ore.
- This operation goeson until the combustion ceases of itself by the exhaustion of the combustible matters, when the operation is finished, and the retort is ready to be discharged and-filled again.
- the time of treatment varies with the nature of the ore, say from five to eight hours.
- pitchpine sawdust as the kind of carbonaceous and hydrogenous material to be mixed with the i ore to be treated
- other similar materials may be used insteadsuch as other kinds of? sawdust, or chips, leaves, peat, &c.
- steam mixed with the hot air in this process enables the heat in the mass of ore to be so graduated as to prevent the slagging of the ore by the excessive combustion of the sulphur, which would interrupt the operation.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
ZSheets-Sheetl. 'Z. A. WILLARD.
PROCESS AND APPARATUS FOR TREATING ORES. No.186,654. Patented .Ian.23,1877.
N. PETERS. PHOTO-LITHOGRAPNER. WASHINGTON. D C.
UNITED STATES PATENT OFFICE.
ZABDIEL A. WILLARD, OF BOSTON, MASSACHUSETTS.
IMPROVEMENT IN PROCESSES AND APPARATUS FOR TREATING ORES.
Specification forming part of Letters Patent No: 186,654., dated January 23,1877 application filed July 27. 1876.
To all whom it may concern.-
Be it known that I, ZABDIEL A. WILLARD, of Boston, in the county of Suffolk and State of Massachusetts, have invented an Improved Process and Apparatus for Treating Ores, of which the following is a specification:
My invention is mainly for the purpose of desulphurizing the ores of metals, or for expelling from minerals such matters as may be volatilized by heat and chemical reaction.
The nature of my new process and the several operations which constitute it, may, perhaps, be best understood by the practical metallurgist from a description of the apparatus used, and from a description of the operations performed in connection with it.
Before subjecting the minerals to treatment by this process, the ore is reduced to a fine powder, and any usual means may be used to concentrate the ore and separate from it the barren matters that may be associated with it, to avoid the expense of their treatment.
The apparatus for carrying on this process is substantially represented in one form in the accompanying drawings, in which- Figure 1 is an elevation of the furnace. Fig. 2 is a vertical section through the center of the same. Fig. 3 is a horizontal section, part above and part below the bottom of the retort. Fig. 4 is a vertical section at a right angle to Fig. 2.
A is the brick-work of the furnace. B is the grate. O is the fire-door. D is the ashpit door. E is the retort, which, by preference, is made of wrought-iron plate riveted. It is about five feet, more or less, in diameter, and about two feet deep in the clear, and will contain a charge of about two tons of ore. It is suspended from the under side of the plate G, which rests upon the top of the brick-work and forms the top of the furnace. The retort extends downward within the furnace to within about two feet from the grate, depending upon the kind of fuel used. At say two inches from the bottom of the retort is placed a perforated plate, B, which is filled with small holes, say, one-sixteenth of an inch in diameter, or less, and an inch, more or less, apart, and said plate is supported in r the retort sufficiently to carry the whole charge of ore that is treated, leaving a free open space below it, into which is admitted 2. current of hot air, or air and steam, as will be described. The top of the retort is covered in part by the plate G, to which the retort is attached, and the opening through which is covered by the hood or cover K, which is raised up out of the way when it is necessary to empty or charge the retort, which hood is provided with a large upright pipe, K, to conduct away the fumes that may be produced in the retort during the operation. The lower edge of the hood K rests in the trough or channel L formed around the opening through the top plate G, which is partly filled with dry sand or powdered treated ore, which closes the joint of the cover sufficiently to carry off the fumes produced in the retort through the pipe K. The pipe K extends upward about six feet, and enters an exterior pipe, M, which is a little larger in diameter than the pipe K, and in which said pipe K slides telescope fashion.
' The pipe M leads to a chimney or to the open air. Or, in case it should be desired to save any of the volatile products of the operation, this pipe would be led to suitable condensing or depositing chambers; but these form no part of the present process.
The cover-K and pipe K are count'erpoised by a weight, 0, and chain 0, which work over pulleys placed above, by which the cover K can be raised up out of the way of the workman in emptying or charging the retort. P is an opening through the side of the retort, even at the bottom with the top of the perforated plate B, through which opening the contents of the retort are removed. This opening is provided with a spout, P, which extends outside of the wall of the furnace, as shown, and at the inside of the retort is provided with a sliding door, Q, which closes it. F is a coil of wrought-iron pipe, which is coiled spirally in a plane with its convolutions close together, and placed but a little distance from the bottom of the retort, and the exterior diameter of the coil is about the same as that of the retort. The inner end of this coiled pipe is inserted into the bottom of the retort at the center, and projects about an inch above the bottom, and the outer end of this pipe is extended outward through the wall of the furnace, and is connected with a blowingmachine of some kind by the pipe R that will drive a current of air under pressure through the mass of ore above the perforated plate B in the retort, which current is controlled by the stop-valve H. To this pipe also, exterior to the furnace, is attached a smaller steampipe, J, which connects with a steam-boiler,
v and the flow of steam through this pipe is controlled by the stop-valve I. By this arrangement a mixture of airand steam in any desired proportion can be forced into the lower part of the retort, and diffused through the mass of ore upon the perforated plate B under the control of the Workman, both as to its volume and mixture; and by this means the rate of combustion of the sulphurcan be so regulated by increasing or diminishing the proportion of steam to the air-current, that the slagging of the snlphuret-can be entirely prevented. S is a pet-cock to carry away the condensed water produced from the steam, and prevent it from flowing into the heatingcoil F and producing an explosion. T is a flue, which leads from the upper part of the furnace to a chimney, anttsuitable tire-doors are fitted to the brick-work in the usual manner.
With an apparatus thus constructed 1 will now describe the process of desulphurizing a sulphur-ct of iron or copper, or other base metal, charged more or less with the precious metalssuch, for instance, as the gold ores of Colorado. The ore is to be reduced to a fine powder that will pass through a sieve of about forty to fifty mesh, or finer, and should contain, say, twenty-five per cent. of neutral matter, such as quartz, alumina, &c. If the ore is clear sulphuret, about twenty to twentyfive per cent. of some neutral or inert mineral should be mixed with it to prevent the sulphuret from slaggiug or running together. The pulverized ore is then mixed with about its bulk of pitch-pine saw-dust, uniformly incorporated with the mass, when the whole is moistened with salt water, by preference seawater, or water of the same saltness, but not made so wet as to drip. This use of salt water I do not regard as indispensable, as the process of desulphurization may be carried on without it; but it is better done with it, as the action of the chlorine, or soda, or both, supplied by the salt, serves to render the gold eliminated by the process bright and clean, and in good condition for amalgamation, if that method is employed for saving the precious metals. This moistened mass is placed in the retort just described upon the perforated plate B, first strewing some sawdust or fine shavings upon it, to prevent the powdered ore from falling through the holes in the plate.
When the retort is charged full, the hood or cover K is lowered, so that its lower edge rests in the dry sand or treated powdered ore which is placed in the groove or channel L, which sufficiently closes the joint. As soon as the retort is properly heated up, the air from the blowing-machine is gradually let on by the air-cock H, and flows into the heatingcoil F, by which the air is heated to, say, 500 or 600 Fahrenheit, and discharged into the space or chamber in the retort below the ore. The effect of the hot-blast is to heat up the mass of the ore uniformly, and dry out the moisture, and, as soon as the ore is hot enough, to ignite the sulphur in the ore. This burns slowly with its peculiar blue flame, and in turn ignites the sawdust, which thus supplies additional fuel to support the combustionor vol-utilization of the sulphur or other volatile matter in the ore. The carbon of the sawdust also aids in the decomposition of the water of the steam mixed with the air while within the mass of ore itself, and produces a set of interactions among the matters present by the sublimation and ignition of the sulphur, the destructive distillation and combustion of the sawdust, and the production of chlorine from the salt, which I am not able to explain, but which experiment has shown are very efiicicnt in liberating the precious metals from their connection with the sulphurous and volatile matters with' which they are associated.
The destruction, also, of the sawdust within the mass of ore, leaves the latter porous and permeable throughout to the circulation of the current of hot air and steam through it, and enables them to lift out and carry away from the mass of ore all the vaporized matters as fast as they are liberated from the ore. This operation goeson until the combustion ceases of itself by the exhaustion of the combustible matters, when the operation is finished, and the retort is ready to be discharged and-filled again. The time of treatment varies with the nature of the ore, say from five to eight hours.
Although I have especially designated pitchpine sawdust as the kind of carbonaceous and hydrogenous material to be mixed with the i ore to be treated, yet other similar materials may be used insteadsuch as other kinds of? sawdust, or chips, leaves, peat, &c. The use of steam mixed with the hot air in this process enables the heat in the mass of ore to be so graduated as to prevent the slagging of the ore by the excessive combustion of the sulphur, which would interrupt the operation.
This use of a current of hot' air and steam which is driven mechanically through the mass of ore made pervious to that current, enables the volatile products of the operation to be immediately removed and carried away with great facility, and also conveys the heat into all parts of the mass of ore at the same time, and carries on the work of desulphurization or volatilization within the mass itself, which enables the operation to be performed in a comparatively short time, and at a comparatively low temperature.
Although I have described the apparatus and the process of desulphurizing ores fully,
and. wish to claim it broadly as such, yet there are substantial and material subordinate parts of the invention which I deem to be new, and which may be usefully employed in connection with other operations than those specifically described-as, for instance, the admixture of sawdust, or its equivalent, with the ore, whereby a combustible material, which serves as a portion of the fuel, is intimately incorporated with it, and imparts a porosity to the mass under treatment, which enables a diffused current of air and steam to be driven through it mechanically, to support' the combustion of it and carry 011' the volatile matters produced, is an operation that may be used in metallurgy in other connections than that specifically mentioned, and be of great utility, and I therefore desire to claim it separately as a feature of my invention. And so of the use of the mixture of steam with the current of air which supports the combustion of the combustible matters within the mass of ore, to prevent slagging the sulphuret by reason of the intense combustion of the combustible matters. I deem this to be new, and desire to claim it separately as a part of my invention.
I do not confine myself to the particular construction of the apparatus herein repreretort, whereby the bottom of the retort is shielded from the direct furnace-flame, substantially as described.
2. The herein-described process of desulphurizing ores, which consists in moistening a mixture of the pulverized ore and sawdust with salt-water, and then subjecting the mass to the action of a heated current of air and steam, the current being disseminated throughout the material, and its flow continued until desulphurization is completed, all substantially as herein shown and described.
3. The method herein described of preparing pulverized sulphuret ore or other mineral for treatment, by intimately incorporating therewith a suitable proportion of sawdust, or other similar combustible substance, and moistenin g the whole with salt-water, substantially as described.
4. The process of treating a mass of pulverized sulphuret ore, which consists in intimately incorporating with it sawdust, or similar carbonaceous matter, then passing through this mass a current of air and steam, the quantity of steam being regulated by the operator, whereby combustion is maintained within the retort, and by the presence of the steam the slagging of the sulphuret is prevented, substantially as described.
Z. A. WILLARD.
Witnesses:
J. ROBBINS, WM. 0. HIIBBARD.
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US20050063355A1 (en) * | 2003-09-09 | 2005-03-24 | Sony Corporation | System and method for multi-link communication in home network |
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US20050063355A1 (en) * | 2003-09-09 | 2005-03-24 | Sony Corporation | System and method for multi-link communication in home network |
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