US156243A - Improvement in reducing ores - Google Patents
Improvement in reducing ores Download PDFInfo
- Publication number
- US156243A US156243A US156243DA US156243A US 156243 A US156243 A US 156243A US 156243D A US156243D A US 156243DA US 156243 A US156243 A US 156243A
- Authority
- US
- United States
- Prior art keywords
- shaft
- air
- ore
- gases
- carbon
- Prior art date
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- Expired - Lifetime
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- 239000007789 gas Substances 0.000 description 56
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 40
- 229910052799 carbon Inorganic materials 0.000 description 32
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 238000002485 combustion reaction Methods 0.000 description 16
- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 14
- 229910052742 iron Inorganic materials 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000003245 coal Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000000630 rising Effects 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 230000001264 neutralization Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000001590 oxidative Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 206010022000 Influenza Diseases 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 235000009808 lpulo Nutrition 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
- C21B13/002—Reduction of iron ores by passing through a heated column of carbon
Definitions
- the ores suitable for treatment by this process are those oxides which are found in the form of sand, or those which have been crushed. to a like form, and are reducible by deoxidation.
- the height of that part of the shaft occupied by the ilame should be such that.each particle of ore will become greatly heated or fused during the time of vits fall the carbon gases should have such a height that such particle, of heated or fused ore will give up its oxygen to the carbon gas while it is falling through such gas to a crucible ⁇ or other proper receptacle placed at the bottom of the shaft.
- the carbon-gas colbe simply deoxidized or carbonized at will, so that, by regulating the height and richness of the carbon-gas column, neutral iron, steel, or carbonized iron may be obtained from oxide of iron at will.
- the desired gas-column may be produced and maintained in a reducingshaft, as above indicated, by connecting the base of the shaft by a iiuewith a Treveray furnace or generator (that is ⁇ to say, aiiapparatus in which a mixture of carbonio-oxide, hydrocarbon, and nitrogen gases is formed by the incomplete combustion of coal) in such a way that the reducing-shaft forms a chimney rlhe desired gas-coluinn may also be produced and maintained through a suitable attachment to a gas-well, such as are developed by artesian borings in Pennsylvania and other parts of the world.
- a Treveray furnace or generator that is ⁇ to say, aiiapparatus in which a mixture of carbonio-oxide, hydrocarbon, and nitrogen gases is formed by the incomplete combustion of coal
- desired gas-column may also be produced and maintained by eject-ing petroleum vapor by means of a steam-jet or otherwise, or be derived from retorts fitted for the distillation of gas from coal or other fuel.
- the desired llame-column may be produced and maintained by opening a series of airholes through the walls of the reducing-shaft,
- Hydrogen gas may be substituted for or mingled with the aforesaid carbon gaseswith good effect, on account of its affinity for oxygen and the great heat evolved by it when of refractory material, mounted upon support-s so disposed as to allow of the removal and re-V.
- D is a gas-generator or fireplace used for the generation of carbonio-oxide and hydrocarbon gases diluted with the nitrogen of the atmosphere by the incomplete combustion of coal or other fuel.
- the generator is connected to the shaft B by a flue in sucha way that the reducing-shaft B forms a chimney for the generator D and carries upward the gases generated by it.
- K K At the lower part of the shaft B is a series of air-holes, K K, a sufficient number of which should be left open for the indraft of air to burn enough of the carbon gases to establish and maintain the requisite heat, which,
- the reducing-shaft B is surmounted by a chimney, C, to carry the products of combustion above the heads of the workmen upon the platform E.
- the ore to be treated is to be elevated to the platform E and placed in the hopper F by workmen, from whence it will fall through the feed-holes M M down inside the shaft B in a shower, when the gates are open.
- the red ucin g-sh aft should be arranged as for the treatment of sulphurous ores, and such collectors attached to the chimney as are now used with roasting-kilns for the purpose of collecting the zinc-white.
- the first action upon the ore will be by the ⁇ oxidizing part of the flame, whereby the zinc will be burned to peroxide and carried into the collectors, and the subsequent. action upon the iron ore will be 'as hereinbefore described, so that the complete reduction and utilization of the metals may be accomplished by one heat and operation.
- the reducing-shaft should be increased in height
- gases and air may be introduced above the primary llame; or a mixture of air and pulverizedfuel may be forced into the reducing-shaft to supplcment and extend the effect of the primary flame.
- the gases and air may be heated by wellknown means previous to the entrance thereof into the reducing-shaft.
- the ore under treatment requires the use of fluxes they may be finely divided, mingled with the ore, and showered down the shaft with it, or placed directly in the crucible A, and be reduced to, and kept' in, a state of fusion by means .of a blast of air through the pipe H, directed downward upon whatever may be in the crucible through the intervening carbon gases, care being taken that the mixed air and gas be ignited.
- the finely-divided or comminuted ore may be heated before its .introduction into the hop'- per F, if desired.
- finely-divided ore may be placed in the hopper F and showered down the shaft B, so as to fall first through a rising column of flame, and afterward through a rising column of carbon gases.
- carbon gases such as described, may be made to pass from the generator into the base of the shaft B, rise to a determinate height therein, and made to undergo combustion by admission of air through the air-holes L L, so that when the apparatus is properly worked the reducing-shaft B will l have its upper part filled with a body of flame, and its lower part lled with a body of carbon gases, thus furnishing the requisite'means for practicing the hereinbefore-described process.
- This process differs from those heretofore known for the roasting of ores by shower eX- posure to homogeneous hot gas, or to llame simply, and from those where the ore traversed through flues or ovens in a direction coinci dent with the current of gases, in that, to accomplish the object sought, the ore shower must fall, iirst, through a llame, and, second, through carbon gases, so as to be reduced during the time of its fall, and not simply roasted, desulphurized, or chlorinated.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
N. W. WHEELER.
. Reducing-UMS.
- Patented 0ct.27,1874.
/V ZZV/ A///.v K7/f hydrocarbon gases through the flame, and that part occupied by umn of a greater or less height, themetal may for the generator.
NQRMAN W. WHEELER,
IMPROVEMENT IN 0E NEW Yoan, N. Y.
REpucine oREs.
Specication forming part of Letters Patent No. 156,243, dated October 27, 1874; application filed February To all whom it may concern:
Beit known that I, NORMAN W. WHEELER, of New York city, in the State of New York, have invented an Improved Process for Beducing Iron or other Ores, and Apparatus for the Practice of the same, of which the following is a specification:
The ores suitable for treatment by this process are those oxides which are found in the form of sand, or those which have been crushed. to a like form, and are reducible by deoxidation.
Take of such ores and shower them down the inside of a vertical shaft, which is so constructed and worked or operated Ythat the upper partis filled with a rising column of oxidizing-lame or neutral flame, which I will, in this paper, term simply dame, and the lower part is filled with a rising column of carbon or for instance, such a mixture of gases as results from the partial coinbustion of coal. The height of that part of the shaft occupied by the ilame should be such that.each particle of ore will become greatly heated or fused during the time of vits fall the carbon gases should have such a height that such particle, of heated or fused ore will give up its oxygen to the carbon gas while it is falling through such gas to a crucible `or other proper receptacle placed at the bottom of the shaft. By making the carbon-gas colbe simply deoxidized or carbonized at will, so that, by regulating the height and richness of the carbon-gas column, neutral iron, steel, or carbonized iron may be obtained from oxide of iron at will. The desired gas-column may be produced and maintained in a reducingshaft, as above indicated, by connecting the base of the shaft by a iiuewith a Treveray furnace or generator (that is` to say, aiiapparatus in which a mixture of carbonio-oxide, hydrocarbon, and nitrogen gases is formed by the incomplete combustion of coal) in such a way that the reducing-shaft forms a chimney rlhe desired gas-coluinn may also be produced and maintained through a suitable attachment to a gas-well, such as are developed by artesian borings in Pennsylvania and other parts of the world. The
desired gas-column may also be produced and maintained by eject-ing petroleum vapor by means of a steam-jet or otherwise, or be derived from retorts fitted for the distillation of gas from coal or other fuel.
The desired llame-column may be produced and maintained by opening a series of airholes through the walls of the reducing-shaft,
at the proper height, so that the indraft of air through these holes will supply air for the complete coinbustionof the carbon gases as they rise to the level of the air-holes, and the ignition and complete combustion of the gases produce the desired column of iiame.
Hydrogen gas may be substituted for or mingled with the aforesaid carbon gaseswith good effect, on account of its affinity for oxygen and the great heat evolved by it when of refractory material, mounted upon support-s so disposed as to allow of the removal and re-V.
placement of the crucible. D is a gas-generator or fireplace used for the generation of carbonio-oxide and hydrocarbon gases diluted with the nitrogen of the atmosphere by the incomplete combustion of coal or other fuel. The generator is connected to the shaft B by a flue in sucha way that the reducing-shaft B forms a chimney for the generator D and carries upward the gases generated by it.' At the lower part of the shaft B is a series of air-holes, K K, a sufficient number of which should be left open for the indraft of air to burn enough of the carbon gases to establish and maintain the requisite heat, which,
however, will be partly produced by the coinbustion of the oxygen ofthe shower of ore `with a part of the carbon gases. At the'proper FICE.
series of air-holes, L L, for the admission of enough air to complete the combustion of the carbon gases as they rise to and above the level of the air-holes L L. At a proper height above the level of the complete-combustion air-holes L L, depending upon the length of flame attainable and the character of the ore under treatment, is a series of inclined f'eedholcs M M, opening into the reducing-shaft B and into the hopper F, and below the hopper F is a platform, E, for workmen. Grates-3 are fitted to each of the feed-holes wherewith to stop or regulate the supply of ore into the shaft. The reducing-shaft B is surmounted by a chimney, C, to carry the products of combustion above the heads of the workmen upon the platform E. The ore to be treated is to be elevated to the platform E and placed in the hopper F by workmen, from whence it will fall through the feed-holes M M down inside the shaft B in a shower, when the gates are open.
When constructing such apparatus I provide air-holes at various heights, and furnish means of closing such as are not required for use, so that varying qualities of ore may be treated in the same apparatus, and different kinds of fuel be used.
When sulphurous ores are to be treated it will be well to open larger areas of air-holes than willbe necessary for complete combustion simply, so that the ilame may be rich in oxygen, and capable of burning away the sulphur or other oxidizable impurity before the ore shall have fallen into the carbon gases. An additional series of air-holes near the top of the reducing-shaft B will be of use in such cases, to furnish the required amount of oxygen without cooling the whole body of llame by over admission of air.
Vhen it is desirable to reduce ferrugiuous zinc ores the red ucin g-sh aft should be arranged as for the treatment of sulphurous ores, and such collectors attached to the chimney as are now used with roasting-kilns for the purpose of collecting the zinc-white. The first action upon the ore will be by the` oxidizing part of the flame, whereby the zinc will be burned to peroxide and carried into the collectors, and the subsequent. action upon the iron ore will be 'as hereinbefore described, so that the complete reduction and utilization of the metals may be accomplished by one heat and operation.
Should refractory ores require a greater height of flame-column than is readily attainable by the means hereinbefore described, thereducing-shaft should be increased in height,
and additional supplies of carbon gases and air may be introduced above the primary llame; or a mixture of air and pulverizedfuel may be forced into the reducing-shaft to supplcment and extend the effect of the primary flame. The gases and air may be heated by wellknown means previous to the entrance thereof into the reducing-shaft.
If the ore under treatment requires the use of fluxes they may be finely divided, mingled with the ore, and showered down the shaft with it, or placed directly in the crucible A, and be reduced to, and kept' in, a state of fusion by means .of a blast of air through the pipe H, directed downward upon whatever may be in the crucible through the intervening carbon gases, care being taken that the mixed air and gas be ignited.
If a steam-jet, through the pipe I, be used to induce the air-blast, it is thought that the hydrogen resulting from the decomposition of the steam will be of benefit, the oxygen combinin g with carbon and leaving the hydrogen free to combine with the oxygen of the ore at a lower temperature, which will obtain above the blast-jet.
The finely-divided or comminuted ore may be heated before its .introduction into the hop'- per F, if desired.
It will now be understood that finely-divided ore may be placed in the hopper F and showered down the shaft B, so as to fall first through a rising column of flame, and afterward through a rising column of carbon gases.
It is also obvious that carbon gases, such as described, may be made to pass from the generator into the base of the shaft B, rise to a determinate height therein, and made to undergo combustion by admission of air through the air-holes L L, so that when the apparatus is properly worked the reducing-shaft B will l have its upper part filled with a body of flame, and its lower part lled with a body of carbon gases, thus furnishing the requisite'means for practicing the hereinbefore-described process.
This process differs from those heretofore known for the roasting of ores by shower eX- posure to homogeneous hot gas, or to llame simply, and from those where the ore traversed through flues or ovens in a direction coinci dent with the current of gases, in that, to accomplish the object sought, the ore shower must fall, iirst, through a llame, and, second, through carbon gases, so as to be reduced during the time of its fall, and not simply roasted, desulphurized, or chlorinated.
The process herein described for obtaining metals from the ores thereof, namely, the showering of 'granulated ore downward through a double atmosphere, consisting of a column of heating, or heating and oxidizing, llame of adequate height for the preheating of the ore, over a column of reducing-gas of adequate height for the reduction of the greater part thereof, substantially in the manner and for the purposes set forth.
In testimony whereof I have hereunto set my hand this 24th day of February, 1874, in the presence of two subscribing witnesses.
NORMAN W. WHEELER.
Witnesses:
-ARNOLD HORMANN,
WILLIAM C. DEY.
Publications (1)
Publication Number | Publication Date |
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US156243A true US156243A (en) | 1874-10-27 |
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Family Applications (1)
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US156243D Expired - Lifetime US156243A (en) | Improvement in reducing ores |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2784077A (en) * | 1955-04-21 | 1957-03-05 | William E Greenawalt | Processes of smelting finely divided metallic ore |
US3298825A (en) * | 1958-04-24 | 1967-01-17 | Mansfeld Kombinat W Pieck Veb | Process and furnace for separating volatile from non-volatile material |
-
0
- US US156243D patent/US156243A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2784077A (en) * | 1955-04-21 | 1957-03-05 | William E Greenawalt | Processes of smelting finely divided metallic ore |
US3298825A (en) * | 1958-04-24 | 1967-01-17 | Mansfeld Kombinat W Pieck Veb | Process and furnace for separating volatile from non-volatile material |
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