US1836402A - Utilization of the heat of incandescent coke or the like material - Google Patents

Utilization of the heat of incandescent coke or the like material Download PDF

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US1836402A
US1836402A US230372A US23037227A US1836402A US 1836402 A US1836402 A US 1836402A US 230372 A US230372 A US 230372A US 23037227 A US23037227 A US 23037227A US 1836402 A US1836402 A US 1836402A
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coke
heat
grate
boiler
gases
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Schumacher Ernst
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FRANKFURTER GASGESELLSCHAFT
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FRANKFURTER GASGESELLSCHAFT
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/04Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being hot slag, hot residues, or heated blocks, e.g. iron blocks
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B39/00Cooling or quenching coke
    • C10B39/02Dry cooling outside the oven

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  • This invention concerns improvements in the utilization of the heat of incandescent coke coming from retorts coking chambers and coking ovens by conducting non-combustible gases over the coke and leading the said gases to a boiler plant.
  • the entiretemperature fall of the incandescent coke is not utilized at one time but the fall is split into two or more stages.
  • the first'stage which "embracesfsay, the temperatures from 1000 to 700 C. the heat of thecoke may be supplied to a high pressure boiler plant.
  • heat may be supplied to a Water preheater the water of which serves, if desired, asfeed water for the high pressure boiler.
  • the last coke with hot water or low pressure steam, the resulting steam then serving at the same time to furnish an air-seal and thus prevent the'coke burning in the air.
  • the utilization of this final heat sage isin general not in itself Worth while.
  • FIG. 1 shows one embodimentin which the incandescent coke is treated successively on a stepped grate and on a travelling grate
  • FIG. 2 a second embodiment 1n which a stepped grate only is used for the coke, and Fig. 3 shows an embodiment producing high and'low pressure steam.
  • a charging hopper 1 is provided fromthe'lower end of,
  • a stepped grate2 receives the incandescent coke.
  • the hopper 1 is closed in an air-tight manner by a flap or valve 3.
  • the heating tubes 4 of a high pressure boiler 5 are disposed above the stepped grate 2 and.
  • Fine gases from a firing plant may be passed into the'blowerin order that there shall always be a certain pressure, over and above that of the atmosphere, in the whole cooling system.
  • heating tubes may be located separately, as at 10, and heat ed by an auxiliary or additional burner arrangement 11, say by gas burners, when, as
  • a travelling grate 12 Adjacent the steppedgrate 2 is a travelling grate 12 which consists of a chain of bars with plates 13, or a similar construction, runningover chain wheels 14 and 15.
  • the coke next fallsjfrom the travelling grate 12 into a bunker 20 which is closed below by a pivoted flap or valve 21. Above thebunker is. an outlet pipe 22 in which two flaps 23 and 2d are located. The flap 23 is connected to the flap 21 by a linkage 25- in such a manner that when the one flap is closed the other is open and vice versa.
  • Varm water may be sprayed through the nozzle device 26 on to the incandescent coke in the bunker or low pressure steam may be blown by the nozzle 27 through the coke in order to cool it completely. The resulting steam then escapes partly through the outlet pipe 22 but also fills at a certain low pressure the entire space 28 above the bunker 20 and seals the same against the entry of air.
  • the flap 24 is connected by the linkage 29 with the flap 3', again in such a manner that when the one flap is open the other is closed and vice versa.
  • the modus operandi is as follows:
  • the incandescent coke from the retorts or the coking ovens falls, the flap 3 being open, into the hopper 1 and thus onto the stepped grate 2.
  • the fan 6 blows non-combustible gas through the grate and the coke and this sras flows around the heating tubes 4 of the high pressure boiler 5 and gives up its sensible heat to the latter. High pressure steam is thus generated.
  • the incandescent coke is cooled from about 1000 to 600 or 700 C.
  • the coke leaving the travelling grate still has a temperature of about 300 C. and falls at this temperature into the bunker 20. .After itscooling to about 100 C. the cokeisremoved from the bunker 20 by opening the flap 21. When the latter is opened the flap 23'is closed by the linkage 25 so that no air can enter from above.
  • the space 28 is kept filled with steam arising from the hot coke due to the spraying with water or steam, air thus being excluded. A further air seal results from the pressure maintained by drawing in additional gas.
  • this 'flap' 2 1 may also be connected by a separate linkage with the flaps 23 and '21 so that whenever one flap is opened the two others are always kept closed.
  • travelling grate is replaced by a similar stepped grate 31 through which inert gas is again blown by means of the blower 16 and conduit 17, flows over the tubes of the preheater 18 and re-enters the blower 16 at 19.
  • this stepped grate 31 is a large drum 32 which rotates slowly in the direction of the arrow, gradually removing the coke from the bottom of the grate and passing it to the bunker 20 the arrangement of which is again the same as inthe embodiment according to Fig. 1.
  • the drum 32' may, if necessary, be furnished with grippers 32 at its periphery in order to convey the coke better.
  • the sub-division may be carried even further by the interposition of a further stage for the generation of low pressure-steam between the two above described stages.
  • Thesame method and the same device may also be employed for utilizing the sensible heat of hot or incandescent materials, other than coke. discharged from any sort of burning ovens or the like.
  • the incandescent. coke may, if desired, also be fed over the grates by a separate conveyor device.
  • the cooling of the coke according to this system gives a very good coke because the wetquenching thereof is only performed at a temperature of about 300 and then with hot water or steam so that the water or the steam cannotexercise any destructive action on the coke.
  • the quenching in stages may also be subdivided into high pressure steam generation, low pressure steam generation and wet quenchingthatis without any hot water production; in this case coke at about 400 is wet-quenched and the feed water for the high pressure boiler is taken from the low pressure boiler.
  • the low pressure boiler may then be coupled directly to a Ruth feeder, possibly to an existing one.
  • Fig. 3 I have shown such a construction, wherein 1 is the feed hopper provided with a valve or closure 3 connectedby rod 29 to valve in the chimneyor stack.
  • the apparatus is provided withthree chambers or hoppers a, 6 and 0 for .recelvmg breeze that is dlscharged through valves 30, and a coke receiving hopper cl that is discharged through valve 21 connected by rod 25 to a second valve 23.
  • On the stem of the valve 23 is a disc 10 having a convex portion 4t()' and a concave portion 40 This disc cooperates with a disc 41 on the stem of valve 24: and has a similar convex portion 41 and a concave portion 41".
  • the arrangement is such that when closure 3 for the hop per 1 is opened valve 2 1- is closed and convex portion ll enters the concave portion 40 of disc 10 and prevents valve, 23 from closing and valve 21 connected to it from being opened. 1
  • the stationary grate 2 discharges onto the travelling grate 13 guided on rotating guides 12 and 14.
  • the grate 13 discharges onto grate 15 and is guided on rotating guides 12 and 15, the end of grate 13 discharging over the guides 15 into the coke hopper or chamber (Z.
  • the tubes 4 of the drums 5 of a heat or;- changer, or a high pressure steam boiler, are located above the stationary grate 2, and noncombustible gases are drawn into the appara tus by blower 6 through pipe 35 controlled by a damper 35 and connected by rods 3% to a damper 34 on the circulating sideof the blow-,
  • the blower circulates gases through pipe 7, through the high temperature colre to be cooled, through port 9 in the boiler, pipe 33, back through pipe 7.
  • a burner 11 supplies a gas flame to tubes 10 of the steam generator for forced steam generation, as in Figs. 1 and 2.
  • a second heat exchanger Over the travelling grates 13 and hopper b is mounted a second heat exchanger, a low pressure vertical tube boiler 36, provided with a circulating blower 16 and connected to the low pressure boiler at 19, and circulating the cooling gases through the partly cooled coke on grate 13 through pipe 17.
  • a pump 38 feeds water from boiler 36 to a high-pressure boiler drum 5.
  • the low pressure steam boiler is provided with a Ruth feeder 39.
  • Over discharge grate 13 and hopper c is a third heat exchanger, a feed water heater 18, its circulating blower and circulating pipe being designated 16 and 17 respectively.
  • a pump 37 supplies water from the heater to the low pressure boiler 36, and the heater 18 is itseli supplied by a pump 37.
  • A. warm water spray pipe 26 and low pressure steam pipes 27 are arranged 1n the coke hopper cl, as in Figs. 1 and 2, for quenching.
  • cokesupporting means over which the coke passes through the, chambers, heat interchanging devices associated with the chambers,a separate blower associated-with each device to circulate gases through diiferent portions of the coke and device, and means to -supply inert gases to the chambers and means for wet cooling the, coke and simultaneously creating a seal of steam against externalcatmospheric air and against the inert gases in the drying portions.
  • a coke cooling apparatus a plurality of serially connected chambers, a grate for each chamber cooperating to discharge one to the other, a heat interchange device for .each chamber, means to supply inert gases to chambersin open communication in series,
  • a charging hopper at one end of the series and a closure therefor, a coke chamber at the other end of the series into which said means delivers, means to supply aqueous quenching medium to the coke in the coke chamber thereby forming a steam seal and cooling the coke, a discharge valve for the last chamber, a stack for the coke chamber, two valves in the stack one connected to the discharge valve for alter nate operation and oneconnected to the hopper closure for alternate operation whereby one of the stack valves will be closed When either the stack valve or hopper closure is opened.
  • a high pressure steam boiler in the first chamber of the series arranged to receive heat from said coke, a gas burner to additionally heat the boiler for overload, a heat interchanger in the second chamber of the series,
  • a coke cooling apparatus a plurality of serially communicating chambers through which coke is continually passed, a heat exchangingdevice associated with each chamber, means for supplying a separate circulation of inert gas through the coke as it passes adjacent each chamber and to the corresponding heat exchange device, whereby a definite temperature gradient in each chamber is attained, the coke being delivered into the last of the serially communicating chambers, and means to supply aqueous quenching fluid in said last chamber to form a protecting seal of steam therein against the entrance of the atmosphere.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Physics & Mathematics (AREA)
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  • Coke Industry (AREA)

Description

Dec. 15, 1931.
E. SCHUMACHER UTILIZATION OF THE HEAT OF INCANDESCENT COKE OR THE LIKE MATERiAL 2 Sheets-Sheet 1 w 9 l V. O N d 8 l 1 F Dec. 15, 1931. E. scHuMAcHER UTILIZATION OF THE HEAT 0F INCANDESCENT COKE OR THE LIKE MATERIAL 2 Sheets-Sheet 2 Filed Nov. 1. 1927 Patented Dec. 15, 1931 uNiraosrArEs P T-ENT- orr es ERNST senor/manna, on FnAnxnoRT-on-Tnn-MAm, GERMANY, ASSIGNOR T FRANK- FURTER GASGESELLSGHAET, OF FRANKFURT-ON-THE-MAIN, GERMANY, A. CORPORA- TION ' UTILIZATION or 'rnn HEAT or moannnsonnr come on THE LIKE MATERIAL Application filed November 1, 182?,Sria1 1101230372, and. in Germany November 11, 1926.
This invention concerns improvements in the utilization of the heat of incandescent coke coming from retorts coking chambers and coking ovens by conducting non-combustible gases over the coke and leading the said gases to a boiler plant. I
Since'in arrangements of this nature proposed hitherto the entire temperature drop of the coke from 1000 C. to about 200 C.
is utilizedextraordinarily large quantities of non-combustible gases are necessary for the heat transferand also very large boiler plants. The high cost of the plant thus arising in great'part outbalances, inmost cases, the advantages gained by recovering the heat; 1
According to the present invention the entiretemperature fall of the incandescent coke is not utilized at one time but the fall is split into two or more stages. In the first'stage which "embracesfsay, the temperatures from 1000 to 700 C. the heat of thecoke may be supplied to a high pressure boiler plant. In
t a second stage of about 700 to 300 C. the
heat may be supplied to a Water preheater the water of which serves, if desired, asfeed water for the high pressure boiler. The last coke with hot water or low pressure steam, the resulting steam then serving at the same time to furnish an air-seal and thus prevent the'coke burning in the air. The utilization of this final heat sage isin general not in itself Worth while.
' The economy of this method is materially enhanced by such subdivision into stages of the whole heat drop; 7
Twoembodimentsof the invention are illustrated by way of example in the accompany 7 ing drawings lIl whlch r Fig. 1 shows one embodimentin which the incandescent coke is treated successively on a stepped grate and on a travelling grate,
Flg. 2 a second embodiment 1n which a stepped grate only is used for the coke, and Fig. 3 shows an embodiment producing high and'low pressure steam.
Referring'first to the example illustrated in Fig. 1 it will be seen that a charging hopper 1is provided fromthe'lower end of,
which a stepped grate2 receives the incandescent coke. The hopper 1 is closed in an air-tight manner by a flap or valve 3. The heating tubes 4 of a high pressure boiler 5 are disposed above the stepped grate 2 and.
at 9 by way of. the return conduit 8. Fine gases from a firing plant may be passed into the'blowerin order that there shall always be a certain pressure, over and above that of the atmosphere, in the whole cooling system.
. If necessary also a part of the heating tubes may be located separately, as at 10, and heat ed by an auxiliary or additional burner arrangement 11, say by gas burners, when, as
occasion demands, forced operation of the high' pressure boiler is necessary.
Adjacent the steppedgrate 2 is a travelling grate 12 which consists of a chain of bars with plates 13, or a similar construction, runningover chain wheels 14 and 15. The
second temperature stage is utilized in this temperature drop is efi'ected by quenching the I "a blower 16 through a conduit 17 and the grate 12on which the incandescent coke layer grate,-again by inert gases being blown by is disposed; said gases then flow around a water preheating device 18 and re-enter the blower 16 at 19. Flue gases from a firing plant may also be introduced into the blower :device may be employed to supply the high pressure boiler with feed water.
The coke next fallsjfrom the travelling grate 12 into a bunker 20 which is closed below by a pivoted flap or valve 21. Above thebunker is. an outlet pipe 22 in which two flaps 23 and 2d are located. The flap 23 is connected to the flap 21 by a linkage 25- insuch a manner that when the one flap is closed the other is open and vice versa.
Varm water may be sprayed through the nozzle device 26 on to the incandescent coke in the bunker or low pressure steam may be blown by the nozzle 27 through the coke in order to cool it completely. The resulting steam then escapes partly through the outlet pipe 22 but also fills at a certain low pressure the entire space 28 above the bunker 20 and seals the same against the entry of air.
The flap 24 is connected by the linkage 29 with the flap 3', again in such a manner that when the one flap is open the other is closed and vice versa.
The modus operandi is as follows:
The incandescent coke from the retorts or the coking ovens falls, the flap 3 being open, into the hopper 1 and thus onto the stepped grate 2. The fan 6 blows non-combustible gas through the grate and the coke and this sras flows around the heating tubes 4 of the high pressure boiler 5 and gives up its sensible heat to the latter. High pressure steam is thus generated.
-On this grate 2 the incandescent coke is cooled from about 1000 to 600 or 700 C.
It then falls on to the travelling grate 12,
carried on which it is subjected. as before to non-combustible gases blown through it by the blower 16, possibly with the addition of flue gases; the gases flow around the preheater tubes and give up their heat thereto. The coke gradually falls from the travelling grate over the chain wheel 15 down into the bunker 20 where it is cooled either by warm water from the nozzles 26 or by low pressure steam from the nozzle 27.
The coke leaving the travelling grate still has a temperature of about 300 C. and falls at this temperature into the bunker 20. .After itscooling to about 100 C. the cokeisremoved from the bunker 20 by opening the flap 21. When the latter is opened the flap 23'is closed by the linkage 25 so that no air can enter from above. The space 28 is kept filled with steam arising from the hot coke due to the spraying with water or steam, air thus being excluded. A further air seal results from the pressure maintained by drawing in additional gas.
On opening the flap 3 the flap 24 closes and prevents air being drawn in through the opening 22. Similarly this 'flap' 2 1 may also be connected by a separate linkage with the flaps 23 and '21 so that whenever one flap is opened the two others are always kept closed.
Below the travelling grate 12 there is moreover a further flap 30 whereby resulting coke dust may be withdrawn.
In the embodiment of the invention illustrated in Fig. 2'the arrangement of the first part ofthe plant is the same; in thelatter part of the cooling system, however, the
travelling grate is replaced by a similar stepped grate 31 through which inert gas is again blown by means of the blower 16 and conduit 17, flows over the tubes of the preheater 18 and re-enters the blower 16 at 19.
,At the end of this stepped grate 31 is a large drum 32 which rotates slowly in the direction of the arrow, gradually removing the coke from the bottom of the grate and passing it to the bunker 20 the arrangement of which is again the same as inthe embodiment according to Fig. 1. The drum 32'may, if necessary, be furnished with grippers 32 at its periphery in order to convey the coke better. r
In both cases the incandescent coke charged .in travels slowly over the two grates and gives up its heat in stages to the high pressure boiler and water pre-heating device.
Ifoccasion demand the sub-divisionmay be carried even further by the interposition of a further stage for the generation of low pressure-steam between the two above described stages.
It is possible by the stepwise utilization of the heat to produce the heat receiving apparatus in a materially simpler and materially cheaper form than hitherto. Since moreover the cooling of the coke by inert gases is preferably only carried down to about 300 400 0., the blower output is considerably less so that the economical efiiciency of the whole plant is substantially higher than is the case when the heat is utilized in one single stage.
Thesame method and the same device may also be employed for utilizing the sensible heat of hot or incandescent materials, other than coke. discharged from any sort of burning ovens or the like.
The incandescent. coke may, if desired, also be fed over the grates by a separate conveyor device.
The cooling of the coke according to this system givesa very good coke because the wetquenching thereof is only performed at a temperature of about 300 and then with hot water or steam so that the water or the steam cannotexercise any destructive action on the coke.
The quenching in stages may also be subdivided into high pressure steam generation, low pressure steam generation and wet quenchingthatis without any hot water production; in this case coke at about 400 is wet-quenched and the feed water for the high pressure boiler is taken from the low pressure boiler. The low pressure boiler may then be coupled directly to a Ruth feeder, possibly to an existing one.
In Fig. 3 I have shown such a construction, wherein 1 is the feed hopper provided with a valve or closure 3 connectedby rod 29 to valve in the chimneyor stack. The apparatus is provided withthree chambers or hoppers a, 6 and 0 for .recelvmg breeze that is dlscharged through valves 30, and a coke receiving hopper cl that is discharged through valve 21 connected by rod 25 to a second valve 23. On the stem of the valve 23 is a disc 10 having a convex portion 4t()' and a concave portion 40 This disc cooperates with a disc 41 on the stem of valve 24: and has a similar convex portion 41 and a concave portion 41". The arrangement is such that when closure 3 for the hop per 1 is opened valve 2 1- is closed and convex portion ll enters the concave portion 40 of disc 10 and prevents valve, 23 from closing and valve 21 connected to it from being opened. 1
The stationary grate 2 discharges onto the travelling grate 13 guided on rotating guides 12 and 14. The grate 13 discharges onto grate 15 and is guided on rotating guides 12 and 15, the end of grate 13 discharging over the guides 15 into the coke hopper or chamber (Z.
The tubes 4 of the drums 5 of a heat or;- changer, or a high pressure steam boiler, are located above the stationary grate 2, and noncombustible gases are drawn into the appara tus by blower 6 through pipe 35 controlled by a damper 35 and connected by rods 3% to a damper 34 on the circulating sideof the blow-,
er. The blower circulates gases through pipe 7, through the high temperature colre to be cooled, through port 9 in the boiler, pipe 33, back through pipe 7. A burner 11 supplies a gas flame to tubes 10 of the steam generator for forced steam generation, as in Figs. 1 and 2.
Over the travelling grates 13 and hopper b is mounted a second heat exchanger, a low pressure vertical tube boiler 36, provided with a circulating blower 16 and connected to the low pressure boiler at 19, and circulating the cooling gases through the partly cooled coke on grate 13 through pipe 17.
V A pump 38 feeds water from boiler 36 to a high-pressure boiler drum 5. I
The low pressure steam boiler is provided with a Ruth feeder 39.
Over discharge grate 13 and hopper c is a third heat exchanger, a feed water heater 18, its circulating blower and circulating pipe being designated 16 and 17 respectively.
A pump 37 supplies water from the heater to the low pressure boiler 36, and the heater 18 is itseli supplied by a pump 37.
A. warm water spray pipe 26 and low pressure steam pipes 27 are arranged 1n the coke hopper cl, as in Figs. 1 and 2, for quenching.
It will thus be seen that there are four chambers in open communication in series, in which the inert'cooling gases are maintained above atmospheric pressure by waste flue gases supplied through pipe 35 to blower 6. The first three chambers or hoppers a, b and 0 are each supplied with a heat interchanger operating at different progressively lower temperatures in accordance with the abstraction Oi heat f1 om the moving coke by the cooling gases and the transference of heat to the respective heat interchanging devices by repeated separate circulation,
Having nowparticularly described and as certained the nature of my said invention and in what manner the same is to be performed I declare that'what I claim is.- v
1. In a coke cooling apparatus, a plurality of chambers in open communication in series,
cokesupporting means over which the coke passes through the, chambers, heat interchanging devices associated with the chambers,a separate blower associated-with each device to circulate gases through diiferent portions of the coke and device, and means to -supply inert gases to the chambers and means for wet cooling the, coke and simultaneously creating a seal of steam against externalcatmospheric air and against the inert gases in the drying portions.
2. In a coke cooling apparatus, a plurality of serially connected chambers, a grate for each chamber cooperating to discharge one to the other, a heat interchange device for .each chamber, means to supply inert gases to chambersin open communication in series,
coke supporting means over which the coke travels past'the chambers, a heat interchanging device associated with each chamber,
means to continuously circulate gases through each device and the coke as it travels past the individual devices through the respective chambers, a charging hopper at one end of the series and a closure therefor, a coke chamber at the other end of the series into which said means delivers, means to supply aqueous quenching medium to the coke in the coke chamber thereby forming a steam seal and cooling the coke, a discharge valve for the last chamber, a stack for the coke chamber, two valves in the stack one connected to the discharge valve for alter nate operation and oneconnected to the hopper closure for alternate operation whereby one of the stack valves will be closed When either the stack valve or hopper closure is opened.
4;. In a coke cooling plant, a plurality of chambers in open communication in series,
means to move hotcoke through the series,
a high pressure steam boiler in the first chamber of the series arranged to receive heat from said coke, a gas burner to additionally heat the boiler for overload, a heat interchanger in the second chamber of the series,
means to supply the'boiler from the interchanger, a blower associated with the boiler to repeatedly circulate gases through the hot coke and boiler, a blower associated with the interchanger to circulate gases therethrough and through the coke that has passed the boiler and first chamber and means for wet cooling the coke after passage through the dry cooling chambers.
5. In a coke cooling apparatus, a plurality of serially communicating chambers through which coke is continually passed, a heat exchangingdevice associated with each chamber, means for supplying a separate circulation of inert gas through the coke as it passes adjacent each chamber and to the corresponding heat exchange device, whereby a definite temperature gradient in each chamber is attained, the coke being delivered into the last of the serially communicating chambers, and means to supply aqueous quenching fluid in said last chamber to form a protecting seal of steam therein against the entrance of the atmosphere.
In testimony that I claim the foregoing as my invention, I have signed my name this 13th day'of October, 1927.
' ERNST SCHUMACHER.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4443955A (en) * 1980-05-30 1984-04-24 Waagner-Biro A.G. Method and installation for cooling hot bulk material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4443955A (en) * 1980-05-30 1984-04-24 Waagner-Biro A.G. Method and installation for cooling hot bulk material

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