US1826718A - Manufacture of threads, ribbons, films, and the like from solutions of cellulose esters and cellulode ethers - Google Patents
Manufacture of threads, ribbons, films, and the like from solutions of cellulose esters and cellulode ethers Download PDFInfo
- Publication number
- US1826718A US1826718A US209163A US20916327A US1826718A US 1826718 A US1826718 A US 1826718A US 209163 A US209163 A US 209163A US 20916327 A US20916327 A US 20916327A US 1826718 A US1826718 A US 1826718A
- Authority
- US
- United States
- Prior art keywords
- films
- ribbons
- threads
- solutions
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002678 cellulose Polymers 0.000 title description 18
- 238000004519 manufacturing process Methods 0.000 title description 15
- 150000002170 ethers Chemical class 0.000 title 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 24
- 239000000243 solution Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 9
- 230000001112 coagulating effect Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000001376 precipitating effect Effects 0.000 description 8
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- FVFJGQJXAWCHIE-UHFFFAOYSA-N [4-(bromomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CBr)C=C1 FVFJGQJXAWCHIE-UHFFFAOYSA-N 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 239000010697 neat foot oil Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- CJAJEZSCULAKCB-UHFFFAOYSA-N 2-sulfohexadecanoic acid Chemical class CCCCCCCCCCCCCCC(C(O)=O)S(O)(=O)=O CJAJEZSCULAKCB-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- 229920000875 Dissolving pulp Polymers 0.000 description 1
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 1
- 229940093471 ethyl oleate Drugs 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- -1 polyprenes Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930004725 sesquiterpene Natural products 0.000 description 1
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Definitions
- Said liquid may consist of an aqueous solution; of ammonium oleate, potassium oleate or sodium oleate, and these substances may be used either separately or mixed together; or it may consist, in general,lof anyaqueous solution which contains an ammonium or alkali salt of one or more'fatty acids (which may even'be sulfonated), for instance, am-
- Hydrocarbons such as'decane, tridecane, hexadecane,toluene, the three xylenes, tetralin, decalin, terpenes, sesquiterpenes, polyprenes, mineral oils and so on.
- the present invention presents a. great advantage over known processes, inasmuch as turpentine .or in animal or vegetable I
- turpentine .or in animal or vegetable I When mineral or vegetable oils are added, the Y rior emulsification of the fatty substances in a very simple manner by merely washing in lukewarm water, as a result ofthe known cleansing action of alkaline soaps, the sulfo-L leatessulfopalmitates and the like.
- the threads are thoroughlylubricated by the coagulant vsolution itself, since the latter acts in the same manner as a true lubricating oil owing to .the simultaneous presence of a fatty oil wlth a sulforicmoleate or an alkaline soap.
- the apparatus in which-the precipitation is effected may be so designed that .thesolvent for the cellulose, esters can be continuously recovered by simple distillation, so that the drained and cooled bath may be used over and over again for precipitating fresh quantities of films or threads, on issuing from the dephlegmator.
- Example 48 parts of a 50% solution of ammonium oleate are mixed with parts of neats-foot oil and 12 parts of mineral oil.
- a 19.8%. solution of cellulose acetate in acetone is threads, films, ribbons and the like, which consists in forcing a solution of cellulose acetate in acetone into an aqueous emulsion containing a solution of ammonium oleate mixed with neats-foot oil and mineral oil.
- a process of manufacturing artificial threads, films, ribbons and the like which consists in forcing an approximately 19.8% solution ofcellulose acetate in acetone into an aqueous emulsion containing about l-8-parts of a solution of ammonium oleate, 40 parts neats-foot oil and 12 parts of mineral oil.
- a process of. manufacturing artificial threads, films, ribbons-and thelike which consists in introducing acetone solutions'of cellulose esters into an emulsified aqueous bath containing a slightly soluble organic liquid and an emulsifying agent.
- a process of manufac'uring artificial threads, films, ribbons and the like which consists in introducing a solution of cellulose acetate in acetone into aqueous bat-h comprising an oil emulsified in an aqueous solution of ammonium oleate.
- a process of manufacturing artificial threads, films, ribbons and the like which consists in introducing acetone solutions of cellulose esters into a mixture of an emulsifying agent in waterand an emulsified compound dispersed in the mixture.
- a process of manufacturing artificial threads, films, ribbons and the like which consists in precipitating or forcing acetone solutions of cellulose esters into an aqueous coagulating bath composed of an emulsifying agent in water and an emulsified compound dispersed in the mixture, said compound being a solvent of the solvent employed for the preparation of the cellulose acetate solution.
- a process of manufacturing artificial threads, films, ribbons and the like which consists in precipitating or forcing acetone solutions of cellulose esters into an emulsified mixture of water and compounds which are not solvents of esters of cellulose, and which compounds added to Water will diminish its surface tension.
- a process of manufacturing artificial threads, films, ribbons and the like which consists in precipitating or forcing acetone solutions of cellulose esters into an aqueous mixture containing oil and an emulsifying g t 9.
- a process of manufacturing artificial threads, films, ribbons and the like which consists in coagulating cellulosic ester solutions in a mixture of water and a material giving an emulsion with water.
- a process of manufacturing artificial threads, films, ribbons and the like consisting in coagulating solutions of cellulose esters in an aqueous mixture composed of water, and an organic compound insoluble in water and a chemical compound which emulsifies the organic compound in the water.
- A' process of manufacturing artificial threads, films, ribbons and the like consisting in coagulating solutions of cellulose esters in a mixture of water, a material having the property of lowering the surface tension of water and of emulsifying fatty substances, and an organic solvent of the cellulose ester to be spun.
- Aprocess of manufacturing artificial threads, films, ribbons and the like which consists in precipitating an acetone solution ofa cellulose ester in an emulsified aqueous liquid mass containing acetone.
- a process of manufacturing artificial threads films, ribbons and the like which consists in, precipitating acetone solutions of cellulose esters in an emulsion of water and iquids which are not solvents of the cellulose ester used.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR505222X | 1926-12-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1826718A true US1826718A (en) | 1931-10-13 |
Family
ID=8908347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US209163A Expired - Lifetime US1826718A (en) | 1926-12-28 | 1927-07-28 | Manufacture of threads, ribbons, films, and the like from solutions of cellulose esters and cellulode ethers |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US1826718A (en)) |
| BE (1) | BE347293A (en)) |
| DE (1) | DE505222C (en)) |
| FR (1) | FR638899A (en)) |
| GB (1) | GB282790A (en)) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2492451A (en) * | 1945-01-03 | 1949-12-27 | American Viscose Corp | Spinneret for the production of viscose filaments |
| US3267189A (en) * | 1959-11-03 | 1966-08-16 | Celanese Corp | Wet spinning of cellulose triesters |
| US3342921A (en) * | 1966-03-16 | 1967-09-19 | West Virginia Pulp & Paper Co | Process for producing fibrous filler having high wet end retention |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE903261C (de) * | 1951-10-18 | 1954-02-04 | Basf Ag | Verfahren zur Herstellung von kuenstlichen Gebilden aus Loesungen von organischen, fadenbildenden Stoffen in wasserloeslichen, organischen Loesungsmitteln |
-
0
- BE BE347293D patent/BE347293A/xx unknown
-
1926
- 1926-12-28 FR FR638899D patent/FR638899A/fr not_active Expired
-
1927
- 1927-03-13 DE DER70544D patent/DE505222C/de not_active Expired
- 1927-07-28 US US209163A patent/US1826718A/en not_active Expired - Lifetime
- 1927-12-28 GB GB35062/27A patent/GB282790A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2492451A (en) * | 1945-01-03 | 1949-12-27 | American Viscose Corp | Spinneret for the production of viscose filaments |
| US3267189A (en) * | 1959-11-03 | 1966-08-16 | Celanese Corp | Wet spinning of cellulose triesters |
| US3342921A (en) * | 1966-03-16 | 1967-09-19 | West Virginia Pulp & Paper Co | Process for producing fibrous filler having high wet end retention |
Also Published As
| Publication number | Publication date |
|---|---|
| BE347293A (en)) | |
| DE505222C (de) | 1930-08-15 |
| FR638899A (fr) | 1928-06-05 |
| GB282790A (en) | 1929-06-28 |
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