US1807554A - Wilhelm rohn - Google Patents
Wilhelm rohn Download PDFInfo
- Publication number
- US1807554A US1807554A US1807554DA US1807554A US 1807554 A US1807554 A US 1807554A US 1807554D A US1807554D A US 1807554DA US 1807554 A US1807554 A US 1807554A
- Authority
- US
- United States
- Prior art keywords
- alloys
- carbon
- rohn
- wilhelm
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000956 alloy Substances 0.000 description 13
- 229910045601 alloy Inorganic materials 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000000788 chromium alloy Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/052—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 40%
Definitions
- such alloys contained 40% to 80% nickel, 12%25%. chromium and -30% iron. Besides the main ingredients, in certain cases-there was also 16,. used an addition of 2%5% molybdenum or tungsten. It has also been proposed to replace part of the nickel bycobalt.
- chromium nickel alloys free from 45 carbon are completely non-sensitive in heat treatment, so that for instance when soldering on the bands which extend around the ,m'outg' ends of. the turbine blades, and binding wiresfiheredsno need'xto pay any particular attention to the cooling conditions or toefiect a subsequent annealing with definite conditions of cooling.
- the toughness at the region of'the notch does not change at all, whether they be slowly cooled from the annealing temperature, or cooled suddenly.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Description
Patented May 26, 1931.
UNlTE DhS TATES PATENT OFFICE WILHELM ROHN, OF HANAU, GERMANY ALLOY non TURBINE BLADES AND momma PARTS nxrosn n 'ro smmaza oon'nrrrons No Drawing. Application filed December 16, 1936, Serial No. 155,345, and in Germany December 28, 1985.
It has been proposed by various persons to ilse chromium nickel alloys for the manu- "facture of gas and steam turbine blades and of machine parts exposed to similar 'me- 5 chanical, thermic and chemical conditions.
According to the proposals, such alloys contained 40% to 80% nickel, 12%25%. chromium and -30% iron. Besides the main ingredients, in certain cases-there was also 16,. used an addition of 2%5% molybdenum or tungsten. It has also been proposed to replace part of the nickel bycobalt.
The reason for not adopting in practice such alloys for the above-mentioned purposes,
15 is probably that these alloys produced by the processes of manufacture hitherto employed, and with the composition hitherto usual, failed to comply with all the conditions which have to be fulfilled by gas and steam turbine blades and by machine parts exposed to similar mechanical, thermic and chemical conditions.
, It has been found that the chief-reason for the non-adoption was that, according to the Z usual processes of manufacture, the alloys contained 0.2% and more per cent. of carbon, and that the alloys become much more 7 suitable for the purposes mentioned if they are made completely free from carbon. .The
39 absence of carbon reduces in the first place the brittleness of such alloys, so that their toughness or tenacity in the regio of the notch is considerably increased at t e temperatures to'be considered. In the second 5 place,'the resistance to corrosion of;al1oys free from carbon is very much greater than that oi carbon-containing alloys. For instance an. alloy consisting of 62% nickel, %-chromium,'22% iron and 1% manganese,
has four times smaller resistance-to corrosion by dilute sulphuric acid, and 400 times smaller resistance to corrosion by diluted nitric acid,
' thanlwhen it contains 0.9% carbon. In the 1 third place, chromium nickel alloys free from 45 carbon, are completely non-sensitive in heat treatment, so that for instance when soldering on the bands which extend around the ,m'outg' ends of. the turbine blades, and binding wiresfiheredsno need'xto pay any particular attention to the cooling conditions or toefiect a subsequent annealing with definite conditions of cooling. The toughness at the region of'the notch does not change at all, whether they be slowly cooled from the annealing temperature, or cooled suddenly. high yield- In order to ensure a sufliciently 'ing point, to the alloys maybe added up to 15% tungsten, up to 12% molybdenum or up to cobalt. It has been found that the same result maybe obtained by an addition of up to.6% aluminum.
The manufacture of such alloys free from carbon could be efiected by the so-called vacuum smelting process.
Having now particularly described and ascertained the nature of my said invention and in what manner the same is to be performed, I declare that what I claim is A turbine blade which is non-corrodible and non-sensitive by heat treatment to the. thermal, mechanical and physical conditions of use, consisting of an alloy com risin 10 to 40% of chromium, 40 to 85% o a nic ellikemetal, 10 to 40%ofiron, and u to 15% of a toughening metal having the c aracteristics of tungsten, the alloy being substantially free from carbon.
y In testimony whereof signature. g
' WILHELM ROHN.
I have aflixed my
Publications (1)
Publication Number | Publication Date |
---|---|
US1807554A true US1807554A (en) | 1931-05-26 |
Family
ID=3422120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US1807554D Expired - Lifetime US1807554A (en) | Wilhelm rohn |
Country Status (1)
Country | Link |
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US (1) | US1807554A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2763920A (en) * | 1951-03-06 | 1956-09-25 | Thompson Prod Inc | Corrosion and impact-resistant article |
US3170789A (en) * | 1961-11-16 | 1965-02-23 | Owens Corning Fiberglass Corp | Nickel-base alloy |
US3177074A (en) * | 1962-04-23 | 1965-04-06 | Duriron Co | Cobalt base alloys |
US3188204A (en) * | 1963-04-08 | 1965-06-08 | Union Carbide Corp | Nickel-alloy |
-
0
- US US1807554D patent/US1807554A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2763920A (en) * | 1951-03-06 | 1956-09-25 | Thompson Prod Inc | Corrosion and impact-resistant article |
US3170789A (en) * | 1961-11-16 | 1965-02-23 | Owens Corning Fiberglass Corp | Nickel-base alloy |
US3177074A (en) * | 1962-04-23 | 1965-04-06 | Duriron Co | Cobalt base alloys |
US3188204A (en) * | 1963-04-08 | 1965-06-08 | Union Carbide Corp | Nickel-alloy |
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