US1765320A - Method and apparatus for forming molds - Google Patents
Method and apparatus for forming molds Download PDFInfo
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- US1765320A US1765320A US144903A US14490326A US1765320A US 1765320 A US1765320 A US 1765320A US 144903 A US144903 A US 144903A US 14490326 A US14490326 A US 14490326A US 1765320 A US1765320 A US 1765320A
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- mold
- anode
- basket
- metal
- electrolyte
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/08—Electroplating with moving electrolyte e.g. jet electroplating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D1/00—Electroforming
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D1/00—Electroforming
- C25D1/10—Moulds; Masks; Masterforms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/605—Surface topography of the layers, e.g. rough, dendritic or nodular layers
Definitions
- the invention relates in general to an improved method for formin' articlesgby electrol ic deposition and to t e apparatus used in the production of articles by following the method herein featured.
- the present application constitutes a companion case with an application filed under even date entitled Method and ap aratus for forming molds and articles pro uced' thereby, Serial 'No.
- the invention in the form herein selected for specific treatment relates to a method of formlng working molds for use subsequently in forming flanged metallic parabolic reflec- 1 tors, but it is understood that this use is simply illustrative of the adaptability of the invention to the electroforming of any nonplanar article particularly those in which there are deep recesses. Difliculty has been experienced heretofore in providing a umform thickness of deposit across such recessed surfaces due presumably to the fact that the depositing current escapes by the shortest pathbefore it can reach the deep port ons of the recess. It is known that the deposit is of greater thickness adjacent the anodeand that the deposit thins out towards the lowest portion of the recessed parts of the surface of the mold under treatment.
- the primary object of the invention 1s to provide a mode of treatment and an assembliyl of the parts in the electrolytic bath 1n sue way as to insure a uniformity of deposition over surfaces which contain deeply recessed arts.
- the anode preferis positioned in close proxlmityto, but not touching the mold surface under treatment and in general the first method features the disposing of the anode so that the distance between the same and the opposite surface of the mold will be substantially uniform.
- the second method is to cause, the electrolyte to flow across the depressed surfaces and preferably to extend through the deepest por- 5 tion of the recessed surface.
- the primary object is to provide a simplified form of structural parts for locating the anode material in close proximity to the non-planar surface of the mold, and to provide in connection with the mold holder uid conducts which will insure the movement of the electrolyte past all of the mold surface under treatment and in such wa .as will tend to insure uniformity of electro ytic deposition.
- Another object of the invention is to provide an anode containing basket the underside or bottom of which will conform substantially to the configuration of the mold surface under treatment, which basket can be readily secured to-the mold sup ort, and with the anode material therein, will tend to provide the requisite location of the anode material and the insurance of a positive contact between the current carrying anode bar and the anode material in the basket.
- the figure is a view largely in side elevation and artly in radial section of a mold supporting frame, with an anode basket positioned thereon together constituting a preferred embodiment of the apparatus feature of the disclosure and illustrating a step in the method featureof the disclosure.
- a metal master mold 10-0n the outstanding flange 11 of which is positioned a celluloid-ring 12 designed subsequently to constitute a part of a finished article and which in the instant case is a working mold 13.
- the master mold and ring are contained in a celluloid clamping frame 14, all as is more particularly disclosed in the above identified copending ap lication.
- the present disclosure distinguls es from the companion application in that the cellu loid nipple 16 which acts to block off the deposition of metal forming on the metal connecting tip is provided centrally thereof with an opening 16 for ermltting the passage of the electrolyte t erethrough as will hereinafter be more fully described.
- a conducting strip 17 which may also be utilized for the purpose of sus ending the assemblage in an electrolytic bat and for this purpose is provided with an 15 eye 18 for engagement "with the buss bars usually positioned over the electrolytic tank.
- the resent disblosure features the use of an ano e basket 19, formed of insulating material, preferably celluloid.
- the bottom 20 20 of the basket is provided with perforations 21 and is designed so as to conform at least substantially to the configuration of the metal mold surface under treatment.
- the bottom of the basket is of similar parabolic formation and 1s outllned by flanged portion 22 which overlaps the flanged portion 11 of the mold.
- the basket 1s provided with an outstanding attaching flange 3o 23, demountably secure in position y clampin screws 24.
- the basket is provided within t e line of clamping screws with an upstanding wall 25 so as to insure suflicient capacit to contain the requisite amount of anode orm'mg material 26 'eontained in the basket.
- the material 26 is granularcopper, and in any case the anode material is of sufiicient fineness of particles to insure a configuration of the underside of the anode which will correspond, at least roughly, to the configuration of the mold surface under treatment.
- the loose anode material is arched out of the basket towards the center so as to insure an extensive electric contact with the positive current carrying anode bar 31.
- the anode bar is preferably a metal cylinder to which electric current is led thr ough the flexible connector 27 leading to the bindin screw 28 engaging bar 31.
- a celluloid tubmg 29 extends through the bar 31 and has its lower discharge end intruded into the anode material adjacent the bottom thereof and in axial alignment with the opening 16 in the outlet nipple 16'.
- the electrolyte is forced under pressure or is permitted to flow through the tubing 29, through the anode material which causes the liquid to spread across the entire bottom of the basket, with some of the electrode discharging through the lowermost portion of the recess in the mold and out through the aperture 16.
- the method which consists in positioning the depositing metal in solid form within the recess, adjacent to but not in contact with the surface of the recess r to be plated, and in fixed relation thereto, and subjecting the same to the action of an electrolytic bath while causing the electrolyte to flow through the solid metal and into depositing contact with the recessed surface.
- the method which consists in disposing anode forming material in juxtaposition to the negative mold surface to be coated, arranging such material so that the distances between the same and the opposing surface of the mold shall be substantially uniform, subjecting the mold and anode material so disposed to the action of an electrolytic bath while causing the electro-. lytiidto flow across the deepest part of the mo surfaces, the method which consists in subjecting the concaved surface to the action of an electrolyte bath while causing the electrolyte to flow through the deepest portion of the concaved surface.
- the method which consists in disposing an anode of metallic particles of the electroplating material in juxtaposition tothe surface to be plated and spaced substantially equidistantly therefrom, and subjecting the surface together with the anode particles to the action of a circulating electrolytic bath.
- the method which consists in disposing an anode of metallic particles of the electroplating material in juxtaposition to the surface to be plated and spaced substantially equidistantly therefrom, and subjecting the surface together with the anode par- 3.
- the method of electroplating concaved no ticles to the action of an electrolytic bath while causing a stream of the electrolyte to move past the anode particles and into depositing engagement with the irregular surface being plated.
- a mefsipaced substantially a relative thereto, and means particles in tallic master form including a parabolic central portionv ro'vided with an outstanding flange, said ange having a ring locating groove in one face, a ring located by said groove, a ring shaped clamp for securing the ring temporarily to the mold, an anode basket carried by the frame and having a perforated bottom conforming'somewhat to and equidistant from the n'ge and parabolic portion of the master mold, said basket adapted tocontain particles of metal forming an anode positioned by said basket substantially equidistant from the mold surface to be plated.
- metallic master form the combination of a including a parabolic central portion provided with an outstanding flange, said flange having a ring locating groove in one face, a ring located by said groove, a ring shaped clamp for securing the ring temporarily to the mold, an anode basket carried by the frame and having a perforated bottom conforming somewhat to and spaced substantially equidistant from the flange and parabolic portion of the master mold, said basket adapted to contain particles of metal forming an anode positioned by said basket substantially equidistant from the mold surface to be plated, and a hollow anodetube adapted, to be intruded into the particles in the basket and adapted to convey electrolyte to the basket.
- a metal faced mold having a depression in the face to be i electroplated, means for positionin a body of metal anode particles substantial y equidistantly spaced from the surface of said depression, and fixed for conveying a stream of electrolyte through the depression surface.
- the particles to basket of insulating material with its bottom perforated and conforming somewhat to the configuration of said surface, closely positioned to but spaced therefrom and adapted to contain an anode material and to position the same close to the concaved surface to be plated, and an anode substantially centered in said basket, and a tube for conducting electrolyte to the particles in the basket.
- ananode basket of insulating material with its bottom perforated and conforming somewhat to the configuration of said surface, closely positioned to but spaced therefrom tain'an anode material and to position the same close to the concaved surface to be plated, and an anode substantially centered in said basket.
- an anode basket of insulating material with its bottom perforated and conforming somewhat to the configuration of said surface, closely positioned to but spaced therefrom and adapted to contain within the basket and above the bottom thereof an anode material and to position the same close to and above the concaved surface to be plated.
- a mold provided with a concaved portion, and having an opening located at the lowest part of said concaved portion to provide an electrolyte opening to permit the passage of electrolyte through the concaved part of the mold when installed in an electrolytic bath.
- a device of the class described the combination of a mold provided with a concaved portion, and having an opening located at the lowest part of said concaved portion to provide an electrolyte opening to permit the passage of electrolyte through the concaved part of the mold when installed in an electrolytic bath, and a tln'mble of insulating I material outlining said opening.
- a metal mold provided with an opening extending therethrough, a metal connector inserted in said opening and providmg means for ma g electric connection with the metal mold. 17.
- a metal mold ing extending therethrough, a metal connector inserted in said opening and providing provided with an openand adapted to conmeans for making electric connection with means for metal conthe metal mold, and insulatin stopping off the deposition on said nector.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Description
June 17, 1930. BARTw 1,765,320
METHOD AND APPARATUS FOR FORMING MOLDS Filed Oct. 28. 1926 INVENTOR MM June 11, 1930 UNITED sures PATENT OFFICE" BLASIUS m'r, OF EAST ORANGE, NEW JERSEY, ASSIGNOR TO BART REILEOTOE (30., ING, OI NEWARK, NEW JERSEY, A CORPORATION OF NEW JERSEY KEI'HOD AND APPARATUS FOR FORMING HOLDS Application filed October-28, 1923. Serial No. 144,808.
The invention relates in general to an improved method for formin' articlesgby electrol ic deposition and to t e apparatus used in the production of articles by following the method herein featured. The present application constitutes a companion case with an application filed under even date entitled Method and ap aratus for forming molds and articles pro uced' thereby, Serial 'No.
The invention in the form herein selected for specific treatment relates to a method of formlng working molds for use subsequently in forming flanged metallic parabolic reflec- 1 tors, but it is understood that this use is simply illustrative of the adaptability of the invention to the electroforming of any nonplanar article particularly those in which there are deep recesses. Difliculty has been experienced heretofore in providing a umform thickness of deposit across such recessed surfaces due presumably to the fact that the depositing current escapes by the shortest pathbefore it can reach the deep port ons of the recess. It is known that the deposit is of greater thickness adjacent the anodeand that the deposit thins out towards the lowest portion of the recessed parts of the surface of the mold under treatment.
The primary object of the invention 1s to provide a mode of treatment and an assembliyl of the parts in the electrolytic bath 1n sue way as to insure a uniformity of deposition over surfaces which contain deeply recessed arts.
P This phase of the invention is attained in two ways and which are preferably used conjointly to obtain themost satisfactory results. By the first method, the anode, preferis positioned in close proxlmityto, but not touching the mold surface under treatment and in general the first method features the disposing of the anode so that the distance between the same and the opposite surface of the mold will be substantially uniform.
The second method is to cause, the electrolyte to flow across the depressed surfaces and preferably to extend through the deepest por- 5 tion of the recessed surface.
ably in-the form of fine nuggets or particles,
.. With reference to the apparatus feature of the disclosure. the primary object is to provide a simplified form of structural parts for locating the anode material in close proximity to the non-planar surface of the mold, and to provide in connection with the mold holder uid conducts which will insure the movement of the electrolyte past all of the mold surface under treatment and in such wa .as will tend to insure uniformity of electro ytic deposition.
, Another object of the invention is to provide an anode containing basket the underside or bottom of which will conform substantially to the configuration of the mold surface under treatment, which basket can be readily secured to-the mold sup ort, and with the anode material therein, will tend to provide the requisite location of the anode material and the insurance of a positive contact between the current carrying anode bar and the anode material in the basket.
Various other objects and advantages of the invention will be obvious from a consideration ofthe preferred method of racticing the invention hereinafter describe and from an inspection of the accompanying drawings and in part will be more fully set forth in the following particular description of one method and of one form of apparatus for practicing the method and the invention also consists in certain new and novel operations and features of construction and combination of parts hereinafter set forth and claimed.
In the accompanying drawing, the figure is a view largely in side elevation and artly in radial section of a mold supporting frame, with an anode basket positioned thereon together constituting a preferred embodiment of the apparatus feature of the disclosure and illustrating a step in the method featureof the disclosure.
In the drawing, there is shown a metal master mold 10-0n the outstanding flange 11 of which is positioned a celluloid-ring 12 designed subsequently to constitute a part of a finished article and which in the instant case is a working mold 13. The master mold and ring are contained in a celluloid clamping frame 14, all as is more particularly disclosed in the above identified copending ap lication. The present disclosure distinguls es from the companion application in that the cellu loid nipple 16 which acts to block off the deposition of metal forming on the metal connecting tip is provided centrally thereof with an opening 16 for ermltting the passage of the electrolyte t erethrough as will hereinafter be more fully described. In this case negative electric connection is made to the metal mold through a conducting strip 17 which mayalso be utilized for the purpose of sus ending the assemblage in an electrolytic bat and for this purpose is provided with an 15 eye 18 for engagement "with the buss bars usually positioned over the electrolytic tank. The resent disblosure features the use of an ano e basket 19, formed of insulating material, preferably celluloid. The bottom 20 20 of the basket is provided with perforations 21 and is designed so as to conform at least substantially to the configuration of the metal mold surface under treatment. In the case 6f the arabolic form of metal surface herein disc osed, the bottom of the basket is of similar parabolic formation and 1s outllned by flanged portion 22 which overlaps the flanged portion 11 of the mold. The basket 1s provided with an outstanding attaching flange 3o 23, demountably secure in position y clampin screws 24. The basket is provided within t e line of clamping screws with an upstanding wall 25 so as to insure suflicient capacit to contain the requisite amount of anode orm'mg material 26 'eontained in the basket. For instance, if it is intended to elect-roplate the mold with copper the material 26 is granularcopper, and in any case the anode material is of sufiicient fineness of particles to insure a configuration of the underside of the anode which will correspond, at least roughly, to the configuration of the mold surface under treatment. 'Preferably, the loose anode material is arched out of the basket towards the center so as to insure an extensive electric contact with the positive current carrying anode bar 31. The anode bar is preferably a metal cylinder to which electric current is led thr ough the flexible connector 27 leading to the bindin screw 28 engaging bar 31. A celluloid tubmg 29 extends through the bar 31 and has its lower discharge end intruded into the anode material adjacent the bottom thereof and in axial alignment with the opening 16 in the outlet nipple 16'.
In operation, the electrolyte is forced under pressure or is permitted to flow through the tubing 29, through the anode material which causes the liquid to spread across the entire bottom of the basket, with some of the electrode discharging through the lowermost portion of the recess in the mold and out through the aperture 16.
It is, of course, within the scope of the disclosure to position the entire device illustrated withln and beneath the surface of an electrolytic bath either with or without the current forming tubing 29 and outlet 16.
B means of the device illustrated and following the method herein suggested it is possible to form the coatings or layers on the mold of substantially uniform thickness, and there is thereby avoided the possibility of abnormal formation of trees and other growths which usually take place adjacent the celluloid ring.
' While I have shown and described, and have pointed out in the annexed claims, certain novel features of my invention, it will be understood that various omissions, substitutions and changes in the form and details of the device illustrated and in its operation may I be made by those skilled in the art without departing from the spirit of the invention.
Havipg thus described my invention, I claim:
-1. In the art of electroplating the recessed portion of a surface, the method which consists in positioning the depositing metal in solid form within the recess, adjacent to but not in contact with the surface of the recess r to be plated, and in fixed relation thereto, and subjecting the same to the action of an electrolytic bath while causing the electrolyte to flow through the solid metal and into depositing contact with the recessed surface.
t 2. In the art of electroforming articles having irregular surfaces, the method which consists in disposing anode forming material in juxtaposition to the negative mold surface to be coated, arranging such material so that the distances between the same and the opposing surface of the mold shall be substantially uniform, subjecting the mold and anode material so disposed to the action of an electrolytic bath while causing the electro-. lytiidto flow across the deepest part of the mo surfaces, the method which consists in subjecting the concaved surface to the action of an electrolyte bath while causing the electrolyte to flow through the deepest portion of the concaved surface.
4. In the art of electroplating irregular surfaces, the method which consists in disposing an anode of metallic particles of the electroplating material in juxtaposition tothe surface to be plated and spaced substantially equidistantly therefrom, and subjecting the surface together with the anode particles to the action of a circulating electrolytic bath.
5. In the art of electroplating irregular surfaces, the method which consists in disposing an anode of metallic particles of the electroplating material in juxtaposition to the surface to be plated and spaced substantially equidistantly therefrom, and subjecting the surface together with the anode par- 3. In the art of electroplating concaved no ticles to the action of an electrolytic bath while causing a stream of the electrolyte to move past the anode particles and into depositing engagement with the irregular surface being plated.
. 6. In a device for use informing working molds for subsequent use in forming flanged parabolic reflectors, the combination of a mefsipaced substantially a relative thereto, and means particles in tallic master form including a parabolic central portionv ro'vided with an outstanding flange, said ange having a ring locating groove in one face, a ring located by said groove, a ring shaped clamp for securing the ring temporarily to the mold, an anode basket carried by the frame and having a perforated bottom conforming'somewhat to and equidistant from the n'ge and parabolic portion of the master mold, said basket adapted tocontain particles of metal forming an anode positioned by said basket substantially equidistant from the mold surface to be plated.
In a device for use in forming working molds for subsequent parabolic reflectors, metallic master form the combination of a including a parabolic central portion provided with an outstanding flange, said flange having a ring locating groove in one face, a ring located by said groove, a ring shaped clamp for securing the ring temporarily to the mold, an anode basket carried by the frame and having a perforated bottom conforming somewhat to and spaced substantially equidistant from the flange and parabolic portion of the master mold, said basket adapted to contain particles of metal forming an anode positioned by said basket substantially equidistant from the mold surface to be plated, and a hollow anodetube adapted, to be intruded into the particles in the basket and adapted to convey electrolyte to the basket. I
8. In a device of the classdescribed, the combination of a metal faced mold having a depression in the face to be i electroplated, means for positionin a body of metal anode particles substantial y equidistantly spaced from the surface of said depression, and fixed for conveying a stream of electrolyte through the depression surface.
9 Ina device of the class described, the combination of a metal faced mold having a depression in the face to be electroplated, means for positioning a body of metal anode fixed relation substantiallyeqmdistantly spaced from the surface of said de pression and a conduit for directing a flow of electrolyte through said particles.
10. In a device for electroplatirfg irregular surfaces including a form having the irregular configuration of the desired surface, anv
use'in forming flanged,
the particles to basket of insulating material with its bottom perforated and conforming somewhat to the configuration of said surface, closely positioned to but spaced therefrom and adapted to contain an anode material and to position the same close to the concaved surface to be plated, and an anode substantially centered in said basket, and a tube for conducting electrolyte to the particles in the basket.
In a device for electroplating concaved surfaces, the combination of ananode basket of insulating material with its bottom perforated and conforming somewhat to the configuration of said surface, closely positioned to but spaced therefrom tain'an anode material and to position the same close to the concaved surface to be plated, and an anode substantially centered in said basket. 1
13. In a device for electroplating concaved surfaces, the combination of an anode basket of insulating material with its bottom perforated and conforming somewhat to the configuration of said surface, closely positioned to but spaced therefrom and adapted to contain within the basket and above the bottom thereof an anode material and to position the same close to and above the concaved surface to be plated.
14; In a device of the class described, a mold provided with a concaved portion, and having an opening located at the lowest part of said concaved portion to provide an electrolyte opening to permit the passage of electrolyte through the concaved part of the mold when installed in an electrolytic bath.
- 15. In a device of the class described, the combination of a mold provided with a concaved portion, and having an opening located at the lowest part of said concaved portion to provide an electrolyte opening to permit the passage of electrolyte through the concaved part of the mold when installed in an electrolytic bath, anda tln'mble of insulating I material outlining said opening.
16. A metal mold provided with an opening extending therethrough, a metal connector inserted in said opening and providmg means for ma g electric connection with the metal mold. 17. A metal mold ing extending therethrough, a metal connector inserted in said opening and providing provided with an openand adapted to conmeans for making electric connection with means for metal conthe metal mold, and insulatin stopping off the deposition on said nector.
18'. In a device of the class described, the combination of a mold, a ring detachably located on the mold, means'for clamping the ring to the mold and means for locating an anode in substantially equidistantly s aeexi relation to the portion of the mold out eci by the ring. i I
19. In a device of the class described, the combination of a mold having an irregular surface and an anode holder having its bottom perforated and disposed for locating solid anode particles in substantially equidistantly spaced relation above said surface of the mold. Signed at New York, in the county of New York and State of New York, this 20th day of October, A. D. 1926.
v BLASIUS BART.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US144903A US1765320A (en) | 1926-10-28 | 1926-10-28 | Method and apparatus for forming molds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US144903A US1765320A (en) | 1926-10-28 | 1926-10-28 | Method and apparatus for forming molds |
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US1765320A true US1765320A (en) | 1930-06-17 |
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US144903A Expired - Lifetime US1765320A (en) | 1926-10-28 | 1926-10-28 | Method and apparatus for forming molds |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2500205A (en) * | 1945-04-12 | 1950-03-14 | Cleveland Graphite Bronze Co | Method of plating |
US2540805A (en) * | 1946-04-30 | 1951-02-06 | John C Schwartz | Electrolytic apparatus for making radiator cores |
US2559926A (en) * | 1947-02-04 | 1951-07-10 | John C Schwartz | Anode basket |
US2563903A (en) * | 1949-12-07 | 1951-08-14 | Zadra John Benjamin | Electrolytic cell for the deposition of gold and/or silver from solutions |
US3356598A (en) * | 1964-02-13 | 1967-12-05 | Hispano Suiza Sa | Process for the fabrication of specially contoured electrodes |
FR2663045A1 (en) * | 1990-06-07 | 1991-12-13 | Traitements Surface Mecanique | Device for metal deposition on uneven surfaces |
-
1926
- 1926-10-28 US US144903A patent/US1765320A/en not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2500205A (en) * | 1945-04-12 | 1950-03-14 | Cleveland Graphite Bronze Co | Method of plating |
US2540805A (en) * | 1946-04-30 | 1951-02-06 | John C Schwartz | Electrolytic apparatus for making radiator cores |
US2559926A (en) * | 1947-02-04 | 1951-07-10 | John C Schwartz | Anode basket |
US2563903A (en) * | 1949-12-07 | 1951-08-14 | Zadra John Benjamin | Electrolytic cell for the deposition of gold and/or silver from solutions |
US3356598A (en) * | 1964-02-13 | 1967-12-05 | Hispano Suiza Sa | Process for the fabrication of specially contoured electrodes |
FR2663045A1 (en) * | 1990-06-07 | 1991-12-13 | Traitements Surface Mecanique | Device for metal deposition on uneven surfaces |
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