US1713530A - Fuel - Google Patents

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Publication number
US1713530A
US1713530A US94965A US9496526A US1713530A US 1713530 A US1713530 A US 1713530A US 94965 A US94965 A US 94965A US 9496526 A US9496526 A US 9496526A US 1713530 A US1713530 A US 1713530A
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US
United States
Prior art keywords
fuel
parts
alcohol
mixture
gasoline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US94965A
Inventor
Hammond Grant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUEL DEV CORP
FUEL DEVELOPMENT Corp
Original Assignee
FUEL DEV CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUEL DEV CORP filed Critical FUEL DEV CORP
Priority to US94965A priority Critical patent/US1713530A/en
Application granted granted Critical
Publication of US1713530A publication Critical patent/US1713530A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition

Definitions

  • My invention relates to liquid hydrocarbon fuels for use in internal combustion englues, such as automobile engines and similar engines for other power purposes.
  • My invention relates particularly to improvements in saturated hydrocarbon fuels of the homologous series, such as kerosene and gasoline, but also includes the benzene series.
  • the object of my invention is to add to these or similar fluids, a substance which will enable internal combustion engines to be operated at much higher temperatures and pressures than heretofore without det- 15 onation or What is known as knocking,
  • a further object of my invention is to produce a fuel which will prevent the for- 2 mation of carbon deposits on the cylinder walls and other parts of the engine without producing any deleterious effect on the surfaces in which the fuel comes in contact.
  • a further object of my invention is to produce a fuel which will be free from poisonous or toxic gases other than the usual products of combustion and one which would not be poisonous or injurious to health in its manufacture.
  • a further object-of my invention is to produce a fuel which may be easily and economically manufactured without greatly increasing the cost of the fuel over those ordinarily used at the present time in internal combustion engines and one that will give greatly increased mileage per gallon used;
  • Ethyl alcohol of 180-190 proof contains, as well known, 10 or cent per cent of water. Ordinarily t e water thus contained in the alcohol prevents the alcohol from becoming dissolved in or thoroughly mixed with the hydrocarbon fuel and precludes the making of a water-white liquid fuel.
  • glycerine As an equivalent of either or both glycerine and alcohol I may also use ethylene-glycol, of which the chemical formula is 0 11,. (OH) This latter material partakes both of the nature of alcohol as well as of glycerine but is not volatile as is alcohol. As another equivalent ingredient I may also use methyl alcohol, propinol or other glycols.
  • Other hydrocarbon fuels may also be used.
  • the proportions of the mixture of alcohol and butanol, with or without gl'ycer'ine are not critical and more water may be used than is contained in commercial alcohol when found to be efficacious, particularly when saturated hydrocarbons of lower boiling points than gasoline are used.
  • the amount of butanol introduced need be suflicient only to produce complete miscibility of the alcohol and water with the hydrocarbon employed as a. fuel.
  • a fuel comprising a light saturated liquid hydrocarbon fuel, commercial alcohol containing from to per cent of Water, butanol to cause miscibility thereof with said hydrocarbon, and a small quantity of glycerine.
  • a fuel comprising a light saturated liquid hydrocarbon fuel having added thereto from 1% to 10% of a mixture of commercial alcohol about 70 parts, butanol about parts, and glycerine about 5 parts.
  • a fuel comprising a light saturated
  • a liquid hydrocarbon fuel having added thereto from 1% to 10% of a mixture of commercial ethyl alcohol about 70 parts, butanol about 20 parts and glycerine about 5 parts.
  • a fuel comprising gasoline having added thereto a mixture of alcoholto parts, water 3 to 10 parts, butanol about 20 parts and glycer'ine about 5 parts.
  • a fuel comprising gasoline having added thereto from 1% to 10% of a mixture of commercial alcohol of from 180 to 190 proof about parts, and butanol about 20 parts.
  • a fuel comprising gasoline having added thereto from 1 to 10% of a mixture of commercial alcohol of from to proof about 70 parts. butanol about 20 parts and glycerine about 5 parts.
  • a fuel comprising gasoline having added thereto from 1% to 10% of a mixture of commercial ethyl alcohol about 70 parts, butanol about 20 parts, and glycerine about 5 parts.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Description

Patented May 21, 1929.
UNITED STATES PATENT OFFICE.
GRANT HAMMOND, OF WHITNEYVILLE, CONNECTICUT, ASSIGNOR TO FUEL DEVELOP- MENT CORPORATION, A CORPORATION OF DELAWARE.
FUEL.
No Drawing.
My invention relates to liquid hydrocarbon fuels for use in internal combustion englues, such as automobile engines and similar engines for other power purposes.
i. My invention relates particularly to improvements in saturated hydrocarbon fuels of the homologous series, such as kerosene and gasoline, but also includes the benzene series.
The object of my invention is to add to these or similar fluids, a substance which will enable internal combustion engines to be operated at much higher temperatures and pressures than heretofore without det- 15 onation or What is known as knocking,
under various atmospheric conditions and at high altitudes as in aeroplane engines.
A further object of my invention is to produce a fuel which will prevent the for- 2 mation of carbon deposits on the cylinder walls and other parts of the engine without producing any deleterious effect on the surfaces in which the fuel comes in contact.
A further object of my invention is to produce a fuel which will be free from poisonous or toxic gases other than the usual products of combustion and one which would not be poisonous or injurious to health in its manufacture.
A further object-of my invention is to produce a fuel which may be easily and economically manufactured without greatly increasing the cost of the fuel over those ordinarily used at the present time in internal combustion engines and one that will give greatly increased mileage per gallon used;
I have found that if commercial ethyl alcohol (180190 proof) be introduced into gasoline and become thoroughly mixed therewith, greatly improved results will be obtained over the use of gasoline and other hydrocarbon fuels without such additions. Ethyl alcohol of 180-190 proof contains, as well known, 10 or cent per cent of water. Ordinarily t e water thus contained in the alcohol prevents the alcohol from becoming dissolved in or thoroughly mixed with the hydrocarbon fuel and precludes the making of a water-white liquid fuel.
As stated in my prior Patent No. 1,570,- 060, issued January 19, 1926, I find that butyl alcohol when introduced to the extent of a small percentage into a mixture of Application filed March 15, 1926. Serial No. 94,965.
gasoline and similar hydrocarbons with alcohol causes the alcohol to immediately become miscible with the gasoline. I prefer, however, to use in addition to these ingredients, a small percentage of glycerine or its equivalent. As an equivalent of either or both glycerine and alcohol I may also use ethylene-glycol, of which the chemical formula is 0 11,. (OH) This latter material partakes both of the nature of alcohol as well as of glycerine but is not volatile as is alcohol. As another equivalent ingredient I may also use methyl alcohol, propinol or other glycols.
As an example of one mixture above mentioned, I take 67 parts of commercial ethyl alcohol, 18 parts of butanol and 5 parts of glycerine. These are mixed together by agitation or any other suitable manner and then introduced into the gasoline to the extent of l or more per cent thereof without resulting in a milky or turbid mixture. Other hydrocarbon fuels ma also be used.
I find that by addition 0 the glycerine, the tendency of the mixture to detonate or knock is still further reduced so that compression in a gasoline engine may be carried as high as 110 to 120 pounds per square inch without detonation and consequently the temperatures existing during compression may be carried correspondingly high.
'As another example of a mixture above referred to I mix 72 parts of ethylene glycol with 18 parts of butanol and a small quantity about 4% or 5% of water. This, when introduced into gasoline to the extent of 3 or more per cent also produces similar advantageous results to those above described As above indicated the addition of 1 to 3% of a mixture of alcohol, glycerine and butanol to the fuel is siifiicient to eliminate detonation or knocking in automobile and similar engines having the usual compressions of the present time but the addition of greater percentages of the mixture up to 10 per cent or more, according to the degree of temperature or amount of compression employed, will eliminate detonation with compressions as high as 110 to 120 pounds per square inch.
The proportions of the mixture of alcohol and butanol, with or without gl'ycer'ine are not critical and more water may be used than is contained in commercial alcohol when found to be efficacious, particularly when saturated hydrocarbons of lower boiling points than gasoline are used. The amount of butanol introduced need be suflicient only to produce complete miscibility of the alcohol and water with the hydrocarbon employed as a. fuel.
What I claim and desire to protect by Letters Patent is:
1. A fuel comprising a light saturated liquid hydrocarbon fuel, commercial alcohol containing from to per cent of Water, butanol to cause miscibility thereof with said hydrocarbon, and a small quantity of glycerine.
2. A fuel comprising a light saturated liquid hydrocarbon fuel having added thereto from 1% to 10% of a mixture of commercial alcohol about 70 parts, butanol about parts, and glycerine about 5 parts.
3. A fuel comprising a light saturated A liquid hydrocarbon fuel having added thereto from 1% to 10% of a mixture of commercial ethyl alcohol about 70 parts, butanol about 20 parts and glycerine about 5 parts.
4. A fuel comprising gasoline having added thereto a mixture of alcoholto parts, water 3 to 10 parts, butanol about 20 parts and glycer'ine about 5 parts.
5. A fuel comprising gasoline having added thereto from 1% to 10% of a mixture of commercial alcohol of from 180 to 190 proof about parts, and butanol about 20 parts.
(3. A fuel comprising gasoline having added thereto from 1 to 10% of a mixture of commercial alcohol of from to proof about 70 parts. butanol about 20 parts and glycerine about 5 parts.
7 A fuel comprising gasoline having added thereto from 1% to 10% of a mixture of commercial ethyl alcohol about 70 parts, butanol about 20 parts, and glycerine about 5 parts.
GRANT HAMMOND.
US94965A 1926-03-15 1926-03-15 Fuel Expired - Lifetime US1713530A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2671104A (en) * 1950-03-22 1954-03-02 Texas Co Process for producing motor fuel from synthesis product
EP0146907A2 (en) * 1983-12-16 1985-07-03 Uni-Commerz Handelsgesellschaft mbH Solvent for carburetter fuel
US4527995A (en) * 1984-05-14 1985-07-09 Kabushiki Kaisha Komatsu Seisakusho Fuel blended with alcohol for diesel engine
EP0162122A1 (en) * 1982-12-09 1985-11-27 Union Carbide Corporation Fuel compositions
US20060162243A1 (en) * 2005-01-25 2006-07-27 Wolf Leslie R Reduced RVP oxygenated gasoline composition and method
US20090107031A1 (en) * 2007-10-31 2009-04-30 Daniel Stedman Connor Fuel System for Improved Fuel Efficiency Utilizing Glycols in a Spark Ignition Engine
US20090199464A1 (en) * 2008-02-12 2009-08-13 Bp Corporation North America Inc. Reduced RVP Oxygenated Gasoline Composition And Method
AU2011226816B2 (en) * 2005-01-25 2012-08-30 Bp Corporation North America Inc. Reduced RVP oxygenated gasoline composition and method
US9873845B2 (en) 2010-06-16 2018-01-23 Butamax Advanced Biofuels Llc Oxygenated butanol gasoline composition having good driveability performance
US10301563B2 (en) 2010-06-16 2019-05-28 Butamax Advanced Biofuels Llc Oxygenated butanol gasoline composition having good driveability performance

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2671104A (en) * 1950-03-22 1954-03-02 Texas Co Process for producing motor fuel from synthesis product
EP0162122A1 (en) * 1982-12-09 1985-11-27 Union Carbide Corporation Fuel compositions
EP0146907A2 (en) * 1983-12-16 1985-07-03 Uni-Commerz Handelsgesellschaft mbH Solvent for carburetter fuel
EP0146907A3 (en) * 1983-12-16 1987-04-29 Uni-Commerz Handelsgesellschaft mbH Solvent for carburetter fuel
US4527995A (en) * 1984-05-14 1985-07-09 Kabushiki Kaisha Komatsu Seisakusho Fuel blended with alcohol for diesel engine
WO2006081089A1 (en) * 2005-01-25 2006-08-03 Bp Corporation North America Inc. Reduced rvp oxygenated gasoline composition and method
US20060162243A1 (en) * 2005-01-25 2006-07-27 Wolf Leslie R Reduced RVP oxygenated gasoline composition and method
JP2008528758A (en) * 2005-01-25 2008-07-31 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド Reduced RVP oxygenated gasoline composition and method
AU2011226816B2 (en) * 2005-01-25 2012-08-30 Bp Corporation North America Inc. Reduced RVP oxygenated gasoline composition and method
US20090107031A1 (en) * 2007-10-31 2009-04-30 Daniel Stedman Connor Fuel System for Improved Fuel Efficiency Utilizing Glycols in a Spark Ignition Engine
US20090199464A1 (en) * 2008-02-12 2009-08-13 Bp Corporation North America Inc. Reduced RVP Oxygenated Gasoline Composition And Method
US9873845B2 (en) 2010-06-16 2018-01-23 Butamax Advanced Biofuels Llc Oxygenated butanol gasoline composition having good driveability performance
US10301563B2 (en) 2010-06-16 2019-05-28 Butamax Advanced Biofuels Llc Oxygenated butanol gasoline composition having good driveability performance

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