US1705020A - Coke treatment and product - Google Patents
Coke treatment and product Download PDFInfo
- Publication number
- US1705020A US1705020A US58493A US5849325A US1705020A US 1705020 A US1705020 A US 1705020A US 58493 A US58493 A US 58493A US 5849325 A US5849325 A US 5849325A US 1705020 A US1705020 A US 1705020A
- Authority
- US
- United States
- Prior art keywords
- coke
- product
- substances
- coke treatment
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000571 coke Substances 0.000 title description 15
- 239000000126 substance Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- 229940046063 potassium chlorate Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000009781 Myrtillocactus geometrizans Nutrition 0.000 description 1
- 240000009125 Myrtillocactus geometrizans Species 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 244000171022 Peltophorum pterocarpum Species 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 101100409194 Rattus norvegicus Ppargc1b gene Proteins 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229940075397 calomel Drugs 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000006790 cellular biosynthetic process Effects 0.000 description 1
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
Definitions
- This invention relates ingeneral to treatment of cellular carbonaceous residues, such ascoke, and is of especial utility'in designating the origin of such material so that the domestic purchasers, even though not able to determine the difference in quality of the coke from the cellular formation and arrangement, may quickly and readily determine whether or not other kinds 'of' coke are mixed therewith. More particularl this inopen, as for instance in the open basket type of house heating grade. This type of fixture is often installed for heating rooms in dwelling houses and the like and while coke is recognized as the cleanest and best fuel, an objection which is fre uently raised t'o-the use of coke as a fuel in suc domestic opengrates. is that it produces a less pleasant flame from an aesthetic point of view than wood. The present invention provides means whereby such objections may be overcome.
- the invention further consists in such other new and seful improvements, and has for further objects such other operative advantages or results, as may be found to obtain in the processes and articles hereinafter described or claimed.
- the substances that may be used to produce flame coloration may be those commonly used in the pyrotechnic industry, and well known in that art. In pyrotechnic practice, such substances are generall mixed with potas sium chlorate or perc lorate before being added to the, combustible-material but this has been found not to be absolutely necessary in applying such substances to coke. A summa of the more common chemicals in the follows, but it is understood that the invention is not limited or confined in scope to the employment of any of these substances or any combination or combinations thereof.
- Red colors are commonly obtained by the use of the salts, such as the carbonate, nitrate and sulphate, of strontium and lithium.
- Blue flames result from the use of the carbonate, sulphide, and arsenite of copper ((11100 Cub,qand CuHAsOy, respectively), andalso coloration, and the oxalate and carbonate of sodium are used when a yellow flame is desired.
- Such salts are comonly used with po- (KClO or perchlorate tassium chlorate (KGIOQ, and finely divided magnesium is sometimes added to produce a'more brilliant efi'ect.
- the substances to be used are 7 dissolved or suspended in'water, and sprayed upon the coke to be marked, thelatter being preferably somewhat above ordinary temperatures.
- the substances may be introduced into the quen'chin' water at the place of manufacture of the co e.
- thecoke may be dipped into solutions or suspensions of the chemical or chemicals used. The preferred manner is to add the material at the final sorting at the coke-screening station of the coke plant.
- coke as hereinabove used is meant to' designate the cellular carbonaceous residue that is obtained from the distillation in the absence of air of bituminous materials such as coal, coal tar, itch, shale oil, petroleum, and the like, an is independent of the source or.
- method of carbonization employed such as ovens of the beehive or by-product type, retorts, and so on.
Description
Patented Mar. 12,- 1929.
UNITED STATES PATENT orrlca.
ALLISON A. KOHR OI MAPLEWOOD, NEW JERSEY, ASSIGNOR TO THE KOPIEBS COR-.- PANY, F PITTSBURGH, PENNSYLVANIA, A CORPORATION OF IBENNSYLVANLA.
COKE TREATMENT AN D PRODUCT.
l i No Drawing.
This invention relates ingeneral to treatment of cellular carbonaceous residues, such ascoke, and is of especial utility'in designating the origin of such material so that the domestic purchasers, even though not able to determine the difference in quality of the coke from the cellular formation and arrangement, may quickly and readily determine whether or not other kinds 'of' coke are mixed therewith. More particularl this inopen, as for instance in the open basket type of house heating grade. This type of fixture is often installed for heating rooms in dwelling houses and the like and while coke is recognized as the cleanest and best fuel, an objection which is fre uently raised t'o-the use of coke as a fuel in suc domestic opengrates. is that it produces a less pleasant flame from an aesthetic point of view than wood. The present invention provides means whereby such objections may be overcome.
The invention further consists in such other new and seful improvements, and has for further objects such other operative advantages or results, as may be found to obtain in the processes and articles hereinafter described or claimed.
' The substances that may be used to produce flame coloration may be those commonly used in the pyrotechnic industry, and well known in that art. In pyrotechnic practice, such substances are generall mixed with potas sium chlorate or perc lorate before being added to the, combustible-material but this has been found not to be absolutely necessary in applying such substances to coke. A summa of the more common chemicals in the follows, but it is understood that the invention is not limited or confined in scope to the employment of any of these substances or any combination or combinations thereof. The
invention mav be practiced successfullv with Application filed September 25, 1925; Serial No. 58,493.
the useof any other substances which are found to give the color or combination of colors, desired upon combustion of coke that has been suitably treated. 4
Red colors are commonly obtained by the use of the salts, such as the carbonate, nitrate and sulphate, of strontium and lithium. Blue flames result from the use of the carbonate, sulphide, and arsenite of copper ((11100 Cub,qand CuHAsOy, respectively), andalso coloration, and the oxalate and carbonate of sodium are used when a yellow flame is desired. Such salts are comonly used with po- (KClO or perchlorate tassium chlorate (KGIOQ, and finely divided magnesium is sometimes added to produce a'more brilliant efi'ect. Various colors may also be'obtained, without the use of potassium chlorate, .b the e5 'calomel (HgCl). The nitrate, chlorate and carbonate of barium are used to effect a green use of the following materials, or com ina-.'
tions thereof: black oxide of antimony, sulphate of copper, and borax, andnumerous other. substances some of which are not deemed suitable for use for the purpose described, by reason of the offensive or poisonous character of the products of volatilization.
.Prefer ably, the substances to be used are 7 dissolved or suspended in'water, and sprayed upon the coke to be marked, thelatter being preferably somewhat above ordinary temperatures. For instance, the substances may be introduced into the quen'chin' water at the place of manufacture of the co e. i As an alternate method, thecoke may be dipped into solutions or suspensions of the chemical or chemicals used. The preferred manner is to add the material at the final sorting at the coke-screening station of the coke plant.
The term coke, as hereinabove used is meant to' designate the cellular carbonaceous residue that is obtained from the distillation in the absence of air of bituminous materials such as coal, coal tar, itch, shale oil, petroleum, and the like, an is independent of the source or. method of carbonization employed, such as ovens of the beehive or by-product type, retorts, and so on. (p
The broad idea of renderi'n coke distinc tive is described and claimed in the co nding application of F. W. Sperr, Jr., rial No. 58,492 filed of even date'herewith forv coke treatment and product.
The invention as hereinabove set forth 55a with quenching water containing and depositing upon the coke a flame-coloring substance or substances that will impart a characteristic color to the flame of combustion ofthe coke so quenched.
In testimony whereof I have hereunto set my hand.
' ALLISON A, KOHB.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58493A US1705020A (en) | 1925-09-25 | 1925-09-25 | Coke treatment and product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58493A US1705020A (en) | 1925-09-25 | 1925-09-25 | Coke treatment and product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1705020A true US1705020A (en) | 1929-03-12 |
Family
ID=22017145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US58493A Expired - Lifetime US1705020A (en) | 1925-09-25 | 1925-09-25 | Coke treatment and product |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1705020A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370932A (en) * | 1963-11-27 | 1968-02-27 | Johnson Coal Cubing Co | Flame coloring product and method of manufacturing same |
| US4062655A (en) * | 1969-06-20 | 1977-12-13 | Business Controls, Inc. | Artificial fire place logs which burn with colored flame and process for making same |
| US4309189A (en) * | 1980-07-31 | 1982-01-05 | Oberhardt Bruce J | Method and means for producing sustained colored flames |
-
1925
- 1925-09-25 US US58493A patent/US1705020A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370932A (en) * | 1963-11-27 | 1968-02-27 | Johnson Coal Cubing Co | Flame coloring product and method of manufacturing same |
| US4062655A (en) * | 1969-06-20 | 1977-12-13 | Business Controls, Inc. | Artificial fire place logs which burn with colored flame and process for making same |
| US4309189A (en) * | 1980-07-31 | 1982-01-05 | Oberhardt Bruce J | Method and means for producing sustained colored flames |
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