US17040A - Improvement in coating metals with silveir - Google Patents
Improvement in coating metals with silveir Download PDFInfo
- Publication number
- US17040A US17040A US17040DA US17040A US 17040 A US17040 A US 17040A US 17040D A US17040D A US 17040DA US 17040 A US17040 A US 17040A
- Authority
- US
- United States
- Prior art keywords
- silver
- improvement
- silveir
- coating metals
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 4
- 239000002184 metal Substances 0.000 title description 4
- 239000011248 coating agent Substances 0.000 title description 3
- 238000000576 coating method Methods 0.000 title description 3
- 150000002739 metals Chemical class 0.000 title description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- 229910052709 silver Inorganic materials 0.000 description 8
- 239000004332 silver Substances 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 235000004263 Ocotea pretiosa Nutrition 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 244000227633 Ocotea pretiosa Species 0.000 description 2
- 241000497192 Phyllocoptruta oleivora Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000010956 nickel silver Substances 0.000 description 2
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 240000003936 Plumbago auriculata Species 0.000 description 1
- 244000009660 Sassafras variifolium Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- -1 britannia Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- OVMJVEMNBCGDGM-UHFFFAOYSA-N iron silver Chemical compound [Fe].[Ag] OVMJVEMNBCGDGM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
- C23C18/44—Coating with noble metals using reducing agents
Definitions
- my invention consists in giving to a metallic surface, especially brass, copper, German silver, britannia, iron, and steel, a surface of pure silver of any desired thickness, without the use of an amalgam or a galvanic battery, but by the simple act of rubbing the surface of the metal to be coated with a solution of silver prepared in the manner hereinafter described.
- I first dissolve a given'quantity of silver in nitric acid and dilute the solution with several parts of water, or I dissolveagiven quantity of nitrate ofsilverin Wat er, and stirinto eithersolution a sufficiency of chloride of sodium.
- the resulting 1 recipitate-chloride of silver-I wash several times with water, or until there is left no trace of salt or acid, and I then add, portionwise, a sufficiency of a strong solution of cyanide of potassium to exactly dissolve the chloride of silver. I then add an excess, preferring one-third, of the said solution of cyanide of potassium and agitate the mixture.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preparation Of Fruits And Vegetables (AREA)
- Detergent Compositions (AREA)
Description
- UNITED STATES PATENT OFFICE.
LEVI L. BILL, OF HUDSON, NEW YORK.
IMPROVEMENT lN COATING METALS WITH SlLVElR.
Specification forming part of Letters Patent No. 17,040, dated April 14, 1857.
.19 all whom it may concern:
Be it known that I, LEVI L. HILL, of the city of Hudson, county of Columbia, and State of New York, have invented a new and Improved Mode of Coating Metals with Silver; and I do hereby declare that the following is a full and exact description of the same.
The nature of my invention consists in giving to a metallic surface, especially brass, copper, German silver, britannia, iron, and steel, a surface of pure silver of any desired thickness, without the use of an amalgam or a galvanic battery, but by the simple act of rubbing the surface of the metal to be coated with a solution of silver prepared in the manner hereinafter described.
To enable others skilled in the art to use my invention, I will proceed to describe it.
I first dissolve a given'quantity of silver in nitric acid and dilute the solution with several parts of water, or I dissolveagiven quantity of nitrate ofsilverin Wat er, and stirinto eithersolution a sufficiency of chloride of sodium. The resulting 1: recipitate-chloride of silver-I wash several times with water, or until there is left no trace of salt or acid, and I then add, portionwise, a sufficiency of a strong solution of cyanide of potassium to exactly dissolve the chloride of silver. I then add an excess, preferring one-third, of the said solution of cyanide of potassium and agitate the mixture. I next add a certain quantity (preferring one-fourth, by weight, of the silver employed) of grapesugar previously mingled with an alcoholic solution of oil of sassafras. The essence of Sassafras I prepare by adding to strong alcohol In bottling for use I add about one-third the A bulk of the fluid of a mixture in nearly equal proportions of clay and paris-white.
For silvering brass, copper, German silver, and britannia, I simply rub the pasty liquid on the article with a brush, a piece of buckskin, or, better still, a piece of buckskin previously Well rubbed with plumbago. To silver iron or steel, I cleanse and brighten the article and coat it with copper by means of rubbing upon it an acid solution of sulphate of copper. I then rinse it in water and proceed with the silvering as above. The finish should be given by thorough rinsing with water and rubbing or polishing by any of the usual methods. 1
I do not claim the use of cyanide of silver, for this has been used in the electrot-ype art, nor the use of the grape-sugar or paris-white, separately considered; but
I do claim- The combination of cyanide of silver, grapesugar, essence of sassafras, clay, and pariswhite, or any of their equivalents respectively, substantially in the manner and for the ,purpose herein described.
LEVI I1. HILL.-
Witnesses ALVIN BUSHNELL, GEORGE J. COLEMAN.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US17040A true US17040A (en) | 1857-04-14 |
Family
ID=2079178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US17040D Expired - Lifetime US17040A (en) | Improvement in coating metals with silveir |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US17040A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100389137B1 (en) * | 2000-04-01 | 2003-06-25 | 주식회사 아레오커뮤니케이션즈 | E-mail system issuing accounts dynamically and e-mail sending/receiving method |
-
0
- US US17040D patent/US17040A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100389137B1 (en) * | 2000-04-01 | 2003-06-25 | 주식회사 아레오커뮤니케이션즈 | E-mail system issuing accounts dynamically and e-mail sending/receiving method |
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