US1660597A - Process for treating brass condenser tubes - Google Patents

Process for treating brass condenser tubes Download PDF

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Publication number
US1660597A
US1660597A US37591A US3759125A US1660597A US 1660597 A US1660597 A US 1660597A US 37591 A US37591 A US 37591A US 3759125 A US3759125 A US 3759125A US 1660597 A US1660597 A US 1660597A
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Prior art keywords
tube
alloy
condenser tubes
brass condenser
treating brass
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US37591A
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Ralph H Conkle
Clay William Frank
Harmon L Weston
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C6/00Coating by casting molten material on the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D13/00Centrifugal casting; Casting by using centrifugal force
    • B22D13/02Centrifugal casting; Casting by using centrifugal force of elongated solid or hollow bodies, e.g. pipes, in moulds rotating around their longitudinal axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S118/00Coating apparatus
    • Y10S118/10Pipe and tube inside

Definitions

  • This invention relates to a novel process for treating brass condenser tubes to prevent corrosion and deterioration thereof.
  • a tube may be provided with a permanent lining of an alloy which will resist the corrosive action of the saline and other im- 16 purities presentinsea water, and by which process such tubes may be quickly and economically treated so as to be proof against corrosion and deterioration.
  • Another object of the invention is to pro- 20 vide a lining for brass condenser tubes in the nature of an alloy which will possess the properties of cohering to the wall of the tube when applied by the process of the invention, and in a manner such that there will be no likelihood of the lining or coating peeling from the wall of thetube or becoming cracked, the alloy possessing such a degree of malleability as to insure against such deterioration and yet being sufficiently hard to resist the abrasive action of sand and other solid particles which might be present in the condensing apparatus.
  • the invention contemplates, generally speaking, providing the inner surface of a brass condenser tube with a lining of an alloy which will possess the properties recited above, and this alloy consists of equal parts, by weight, of tin, lead, and zinc, the alloy being, of course, repared in the usual manner .by reducing t e stated proportions of these metals to a molten state.
  • the tube to be treated is first swabbed interiorly with muriatic acid which has been cut with a suitable quantity of zinc, and the purpose Application filed June 16, 1925. Serial N0. 37,591.
  • gaseous fuel burner which is positioned to direct its flame against the tube throughout the entire length of the tube, and while the burner is in operation and the flames are directed against the tube, the tube is rotated at approximately one hundred revolutions per minute and this step is continued until the tube has reached a temperature of 212 Fahrenheit, or a slightly higher temperature. At this point, a suitable quantity of the alloy ina molten state is poured slowly into one end of the tube and the speed of rotat on of the tube is increased to approximately twelve hundred revolutions per minute. so that the molten alloy is spread, by centrifugal force, evenly over the'inner surface of the wall of the tube.
  • the coating of the alloy will be more in the nature of av cohering surface film than in the nature of a lining.
  • the lead in the alloy resists corrosion asit is not affected by the saline and other impurities in sea water, and the zinc of the alloy renders the coating Sufliciently hard to resist the abrasive action of sand and other forei solid particles.
  • the method of providing a condenser. tube with an interior coating to prevent corrosion which comprises the steps of simultaneously slowly rotating the tube and heating the same, and, when the tube has become heated, increasing the speed of rotation of the tube, introducing therein a quantity of molten metal capable of resisting corrosion, continuing the rotation of the tube 0 tube with an interior coating to prevent eor-.
  • rosion which comprises the steps ofv rotating the tube at approximately one hundred revo- .lutio'ns per minute about its axis and simultaneously applying heat to the exterior of the tube, increasing the speed of rotation of the tube to approximately twelve hundred revolutions per minute and simultaneously pouring into the tube a quantity of molten metal capable. of resisting corrosion, continuing the rotation of the tube until the introduced metal has coated the Wall thereof through centrifugal force, and, While the 20 tube is still rotating, discontinuing the heating of the tube and reciprocating a Wiper thercthrough to effect even distribution of the molten metal.

Description

Patented Feb. 28, 1928 UNITED STATES 1,660,597 PATENT OFFICE.
RALPH H. CONK LE, WILLIAM FRANK CLA Y, AND BIARMON L. WESTON, OF LONG BEACH, CALIFORNIA.
PROCESS FOR TREATING BRASS CONDENSER TUBES.
No Drawing.
This invention relates to a novel process for treating brass condenser tubes to prevent corrosion and deterioration thereof.
It is well known that sea water rapidly corrodes the brass tubes of condensers and that the life of a brass condenser tube is usually from sixty to ninety days, after which tlme it will be found to have deteriorated to such 'an .extent as to require replacement. The
present invention, therefore, has as one of its objects to evolve a novel process whereby such a tube may be provided with a permanent lining of an alloy which will resist the corrosive action of the saline and other im- 16 purities presentinsea water, and by which process such tubes may be quickly and economically treated so as to be proof against corrosion and deterioration.
Another object of the invention is to pro- 20 vide a lining for brass condenser tubes in the nature of an alloy which will possess the properties of cohering to the wall of the tube when applied by the process of the invention, and in a manner such that there will be no likelihood of the lining or coating peeling from the wall of thetube or becoming cracked, the alloy possessing such a degree of malleability as to insure against such deterioration and yet being sufficiently hard to resist the abrasive action of sand and other solid particles which might be present in the condensing apparatus.
The invention contemplates, generally speaking, providing the inner surface of a brass condenser tube with a lining of an alloy which will possess the properties recited above, and this alloy consists of equal parts, by weight, of tin, lead, and zinc, the alloy being, of course, repared in the usual manner .by reducing t e stated proportions of these metals to a molten state.
In carrying out the process, the tube to be treated is first swabbed interiorly with muriatic acid which has been cut with a suitable quantity of zinc, and the purpose Application filed June 16, 1925. Serial N0. 37,591.
gaseous fuel burner which is positioned to direct its flame against the tube throughout the entire length of the tube, and while the burner is in operation and the flames are directed against the tube, the tube is rotated at approximately one hundred revolutions per minute and this step is continued until the tube has reached a temperature of 212 Fahrenheit, or a slightly higher temperature. At this point, a suitable quantity of the alloy ina molten state is poured slowly into one end of the tube and the speed of rotat on of the tube is increased to approximately twelve hundred revolutions per minute. so that the molten alloy is spread, by centrifugal force, evenly over the'inner surface of the wall of the tube. While the tube is still rotating, asuitable wiper saturatedwith oil, is inserted into the tube and moved from end to end thereof, and at this time 7 the burner is cut out of operation and the swabbing step performed b the reciprocation of the wiper is repeate approximately five times and the wiper withdrawn. In this swabbing step, the molten alloy is evenly distributed over the inner surface of the wall of the tube, the oil upon the swab employed in this step serving to prevent sticking of the swab to the wall of the tube. The tube thus acted upon will, when cooled, be foundto be coated with a smooth and bright film-like layer of the alloy, and the tube is then ready for installation in the condenser.
Inasmuch as the tin in the alloy has an aflinity for the copper in the brass, the coating of the alloy will be more in the nature of av cohering surface film than in the nature of a lining. The lead in the alloy resists corrosion asit is not affected by the saline and other impurities in sea water, and the zinc of the alloy renders the coating Sufliciently hard to resist the abrasive action of sand and other forei solid particles.
Having thus described the invention, what we claim is:
1. The method of providing a condenser. tube with an interior coating to prevent corrosion, which comprises the steps of simultaneously slowly rotating the tube and heating the same, and, when the tube has become heated, increasing the speed of rotation of the tube, introducing therein a quantity of molten metal capable of resisting corrosion, continuing the rotation of the tube 0 tube with an interior coating to prevent eor-.
rosion which comprises the steps ofv rotating the tube at approximately one hundred revo- .lutio'ns per minute about its axis and simultaneously applying heat to the exterior of the tube, increasing the speed of rotation of the tube to approximately twelve hundred revolutions per minute and simultaneously pouring into the tube a quantity of molten metal capable. of resisting corrosion, continuing the rotation of the tube until the introduced metal has coated the Wall thereof through centrifugal force, and, While the 20 tube is still rotating, discontinuing the heating of the tube and reciprocating a Wiper thercthrough to effect even distribution of the molten metal.
In testimony whereof we afiix our signa- 25 tures.
RALPH H. CONKLE. [n.s] WILLIAM FRANK CLAY.
[L.s.] HARMON L. WESTON.
US37591A 1925-06-16 1925-06-16 Process for treating brass condenser tubes Expired - Lifetime US1660597A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2470689A (en) * 1943-02-16 1949-05-17 Chase Brass & Copper Co Process for tin-coating the interiors of copper tubes
US2734832A (en) * 1956-02-14 lewis
US2880109A (en) * 1955-09-22 1959-03-31 United States Steel Corp Method of coating the interior of cylinders
DE3823309A1 (en) * 1987-07-11 1989-01-19 Usui Kokusai Sangyo Kk METHOD FOR PRODUCING METAL TUBES COATED WITH TIN OR TIN-BASED ALLOYS

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2734832A (en) * 1956-02-14 lewis
US2470689A (en) * 1943-02-16 1949-05-17 Chase Brass & Copper Co Process for tin-coating the interiors of copper tubes
US2880109A (en) * 1955-09-22 1959-03-31 United States Steel Corp Method of coating the interior of cylinders
DE3823309A1 (en) * 1987-07-11 1989-01-19 Usui Kokusai Sangyo Kk METHOD FOR PRODUCING METAL TUBES COATED WITH TIN OR TIN-BASED ALLOYS

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