US1523742A - Webje hokn a - Google Patents
Webje hokn a Download PDFInfo
- Publication number
- US1523742A US1523742A US1523742DA US1523742A US 1523742 A US1523742 A US 1523742A US 1523742D A US1523742D A US 1523742DA US 1523742 A US1523742 A US 1523742A
- Authority
- US
- United States
- Prior art keywords
- fibre
- substantive
- sulpho
- yarn
- colors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 description 20
- 230000008569 process Effects 0.000 description 20
- 239000003086 colorant Substances 0.000 description 13
- 239000000835 fiber Substances 0.000 description 9
- 229920003043 Cellulose fiber Polymers 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 6
- 235000010980 cellulose Nutrition 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- -1 aromatic sulpho-chlorides Chemical class 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229950005499 carbon tetrachloride Drugs 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000009877 rendering Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 230000003113 alkalizing effect Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000008149 soap solution Substances 0.000 description 2
- 239000000984 vat dye Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002649 immunization Methods 0.000 description 1
- 230000003053 immunization Effects 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/265—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur containing halogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- Patented den. 26 i925.
- This invention relates to a process for rendering vegetable fibres indiderentto substantive colors or dyes, according to which vegetable fibres rendered alkaline in the well known manner, are treated with aromatic sulpho-chlorides, more particularly with para-toluol sulphochloride in suitable solvents and at suitable temperatures.v
- This process has the advantage that cheap materials may be used for carrying out the process and that the efiect is better than in the above stated known process.
- the alkalized cellulose fibre insoluble inalkali and water is converted according to this process into an ester compound which can no longer be dyed in a hot soap bath with substantive colors.
- the process may be as follows:
- lit also resists diluted acids much better and its indiderence to substantive colors remains unafi'ected even by the acid used for obtaining a transparent efi'ect and by the mercerizing lye provided that it is treated cold and for a short time and rinsed immediately afterwards, but it shows a not inconsiderable fixing property as regards basic colors.
- textile fabrics can be prepared with patterns in several colors of the most varied kinds.
- the treatment with alkali may also be carried out with potassium hydroxide, and instead of carbon tetra-chloride there may also be used a sulpho-chloride solvent or other chlorinated hydrocarbons of the fatty series, also hydrocarbons of the petroleum series and benzol and its homologues
- a sulpho-chloride solvent or other chlorinated hydrocarbons of the fatty series also hydrocarbons of the petroleum series and benzol and its homologues
- immune cellulose products with other sulpho-chlorides of the-non-substituted and substituted aromatic hydrocarbons, for instance with benzo-sulpho-chloride, ortho-toluol-sulpho-chloride, Xyloland naphtaline-sulphochlorides and With chlorine, bromine and nitro-derivates of all these compounds.
- Process for the manufacture of a cellulose fibre indifferent to substantive colors comprises subjecting the cellulose fibre to a treatment with an alcoholic solution of caustic soda, and treating the alkalized cellulose with aromatic sulphochlorides.
- Process for the manufacture of a cellulose fibre indifferent to substantive colors comprises subjecting the cel lulose fibre to an alkalizing treatment, and treating the alkalized cellulose with paratoluol-sulpho-chloride.
- Process for rendering vegetable fibres immune to substantive dyes which comprises treating fibre with alkali and then subjecting the fibre to the action of a solution of para-toluol-sulpho-chloride in carbon tetra-chloride.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
Patented den. 26), i925.
hairs s'rres arena ROBERT ZIMMERMANN, OF TUBACH, SWITZERLAND, ASSIGNOR T0 FKRM OF TEXTIL- VERK HORN A.-G., OF HORN AM BODENSEE, SWITZERLAND.
PROCESS FOR THE MANUFACTURE OF A CELLULOSE COMPOUND INDIFFERENT TG SUBSTANTIVE COLURS.
No Drawing.
To all whom it mag concern:
Be it known that 1, ROBERT ZIMMERMANN, a citizen of the ldepublic of Switzerland, residing at lubach, Canton St. Gall, Switzerland, have invented certain new and useful Improvements in Processes for the Manufacture of a Cellulose Compound Indifierent to Substantive Colors, of which the following is a specification.
It is known to produce effect-threads in cotton or other vegetable fibres by causing acid chlorides of the aromatic series to act in the presence of indiii'erent solvents on vegetable fibres previously treated with alkalis' This process has however the drawback of being relatively expensive owing to the acid chlorides utilized.
This invention relates to a process for rendering vegetable fibres indiderentto substantive colors or dyes, according to which vegetable fibres rendered alkaline in the well known manner, are treated with aromatic sulpho-chlorides, more particularly with para-toluol sulphochloride in suitable solvents and at suitable temperatures.v This process has the advantage that cheap materials may be used for carrying out the process and that the efiect is better than in the above stated known process.
The alkalized cellulose fibre insoluble inalkali and water is converted according to this process into an ester compound which can no longer be dyed in a hot soap bath with substantive colors.
In the case of the transformation (immunization) of yarn, the process may be as follows:
By heating industrial alcohol containing water, for instance 95% alcohol, with pieces of soda in excess, there is prepared in a Well known manner first as strong an alcoholic solution of soda as possible, for instance of 14%, which on being cooled forms a brownish liquid. If carefully bleached cotton, as free from fat as possible, either loose or in the form of yarn or fabric is immersed in the said solution and left for several hours, the'said cotton will be converted in the well known manner into its soda compound, that is to say alkalized. The cotton is thereupon withdrawn and the lye adhering to it, removed by pressure or centrifugal action.
Application filed March 28, 1923. Serial No. 628,323.
1 kg. of the alkalized and centrifuged yarn is immersed in 15 litres of a tetra" chloride of carbon of 1520'using a clay or enamelled vessel-which contains 200 gr.-para-toluol-sulphochloride per litre. After a short time a reaction takes place with a rise of temperature which however does not reach the boiling point of the liquid. Care must be taken that the yarn always remains under the surface of the liquid. The whole is then allowed to cool for several hours, and heated again by supplying heat by external means until the boiling point is nearly reached. The yarn is then withdrawn and pressed out, and afterwards all sulpho-chloride and solvent are removed from it by passing it several tifnes through a soap solution of C. and rinsing until it is quite odorless. A yellowish-white end product thereupon is obtained by means of a hot soda washing and by the usual chlorine bleaching with to a considerable extent which may amount to 20% and more. lVhen dyeing with substantive colors in hot soda-soap solution, the said yarn proves to be indifferent. Unlike the ordinary yarn, its strength is unaffected by the usual bleaching chlorine solution, even if exposed to its action cold for several days. lit also resists diluted acids much better and its indiderence to substantive colors remains unafi'ected even by the acid used for obtaining a transparent efi'ect and by the mercerizing lye provided that it is treated cold and for a short time and rinsed immediately afterwards, but it shows a not inconsiderable fixing property as regards basic colors.
By weaving it together with raw or bleached cotton yarn, it may be used advantageously for the manufacture of colored pattern fabrics and transparent fabrics.
Yarn previously treated with vat dyes, for instance with indanthrene blue, can in the same way be rendered immune to substantive colors. By weaving such immune colored yarn with the ordinary yarn and subsequently dyeing with substantive colors,
textile fabrics can be prepared with patterns in several colors of the most varied kinds.
In the process of preparation, the treatment with alkali may also be carried out with potassium hydroxide, and instead of carbon tetra-chloride there may also be used a sulpho-chloride solvent or other chlorinated hydrocarbons of the fatty series, also hydrocarbons of the petroleum series and benzol and its homologues It is also possible to prepare immune cellulose products with other sulpho-chlorides of the-non-substituted and substituted aromatic hydrocarbons, for instance with benzo-sulpho-chloride, ortho-toluol-sulpho-chloride, Xyloland naphtaline-sulphochlorides and With chlorine, bromine and nitro-derivates of all these compounds.
I claim: 7
1. Process for converting alkalized cellulose fibres into a fibre which can no longer be dyed with substantive colors which process comprises treating the alkalized cellulose with aromatic sulpho-clilorides.
2. Process for the manufacture of a cellulose fibre indifferent to substantive colors which process comprises subjecting the cellulose fibre to a treatment with an alcoholic solution of caustic soda, and treating the alkalized cellulose with aromatic sulphochlorides.
3. Process for the manufacture of a cellulose fibre indifferent to substantive colors which process comprises subjecting the cel lulose fibre to an alkalizing treatment, and treating the alkalized cellulose with paratoluol-sulpho-chloride.
4. Process for rendering vegetable fibres immune to substantive dyes, which comprises treating the fibre with alkali and then subjecting the fibre to the action of a solution of aromatic sulpho-cliloride in carbon tetra-chloride .and washing the fibre.
5. Process for rendering vegetable fibres immune to substantive dyes, which comprises treating fibre with alkali and then subjecting the fibre to the action of a solution of para-toluol-sulpho-chloride in carbon tetra-chloride.
6. Process for the manufacture of a cellulose fibre indifferent to substantive colors,
which process comprises treating the. fibre with vat-dyes, subjecting this fibre to an alkalizing treatment and treating the alkalized fibre with aromatic sulpho-chlorides.-
In testimony whereof I atfix my signature.
ROBERT ZIMMERMANN.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1523742A true US1523742A (en) | 1925-01-20 |
Family
ID=3407966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US1523742D Expired - Lifetime US1523742A (en) | Webje hokn a |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1523742A (en) |
-
0
- US US1523742D patent/US1523742A/en not_active Expired - Lifetime
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