US1361811A - Dye-soap and mordant - Google Patents
Dye-soap and mordant Download PDFInfo
- Publication number
- US1361811A US1361811A US1361811DA US1361811A US 1361811 A US1361811 A US 1361811A US 1361811D A US1361811D A US 1361811DA US 1361811 A US1361811 A US 1361811A
- Authority
- US
- United States
- Prior art keywords
- dye
- mordant
- soap
- flake
- illinois
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000344 soap Substances 0.000 title description 32
- 239000000975 dye Substances 0.000 description 46
- 239000000463 material Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 6
- 210000002268 Wool Anatomy 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- MCTQNEBFZMBRSQ-UHFFFAOYSA-N (3-amino-4-phenyldiazenylphenyl)azanium;chloride Chemical compound Cl.NC1=CC(N)=CC=C1N=NC1=CC=CC=C1 MCTQNEBFZMBRSQ-UHFFFAOYSA-N 0.000 description 2
- WBTCZEPSIIFINA-UHFFFAOYSA-J Antimony potassium tartrate Chemical compound O.O.O.[K+].[K+].O1C(=O)C2O[Sb-]1(OC1=O)OC1C(C(=O)O1)O[Sb-]31OC(=O)C2O3 WBTCZEPSIIFINA-UHFFFAOYSA-J 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 240000000491 Corchorus aestuans Species 0.000 description 2
- 235000011777 Corchorus aestuans Nutrition 0.000 description 2
- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- FDZZZRQASAIRJF-UHFFFAOYSA-M Malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 2
- 229940107698 Malachite green Drugs 0.000 description 2
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 description 2
- LZTRCELOJRDYMQ-UHFFFAOYSA-N Triphenylmethanol Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C1=CC=CC=C1 LZTRCELOJRDYMQ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 235000020127 ayran Nutrition 0.000 description 2
- 235000012970 cakes Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- SUXCALIDMIIJCK-UHFFFAOYSA-L disodium;4-amino-3-[[4-[4-[(1-amino-4-sulfonatonaphthalen-2-yl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=C4C=CC=CC4=C(C=3)S([O-])(=O)=O)N)C)=CC(S([O-])(=O)=O)=C21 SUXCALIDMIIJCK-UHFFFAOYSA-L 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- HOPRIFATEWRIEO-XGZFOCIOSA-J tetrasodium;(3E)-5-amino-3-[[4-[4-[(2Z)-2-(8-amino-1-oxo-3,6-disulfonatonaphthalen-2-ylidene)hydrazinyl]phenyl]phenyl]hydrazinylidene]-4-oxonaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].O=C\1C2=C(N)C=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C/1=N/NC(C=C1)=CC=C1C(C=C1)=CC=C1N\N=C1/C(S([O-])(=O)=O)=CC(C=C(C=C2N)S([O-])(=O)=O)=C2C1=O HOPRIFATEWRIEO-XGZFOCIOSA-J 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
Definitions
- My invention relates to dye soaps and partlcularly to a novel combination of a dye soap and mordant.
- ' ne of the principal objects of the invention is to provide a composition in which a greater range of dye may be employed in order to securee ually satisfactory results.
- the present invention contemplates the addition of the mordant to the material and to mechanically mix the same therewith.- This is not generally practical where the dye soap is marketed in cake form for the reason that the mordant is likely to cause precipitation of the dye or oxidization or alteration of the dye stuff. I have found, however, that by flaking or otherwise finely dividing the product the mordant added thereto will not injuriously aflect the substance and dyestuffs may be employed which were not heretofore considered practical for use in dyesoaps.
- mordant refers to any substance which may be used in connection with coloring matter, either as a preliminary treatment of the fabric prior to the application of the dye, or color; or any after treatment intended to improve, or 0th erwise alter, the tone, shade, tint, evenness or uniformity of the dyeing; its fastness to light, heat, washing, topping, perspiration, or chemical action; or tending to "affect the solubility, or the equalizing properties of the dye.
- the material may be prepared in the usual manner by suitabl mixing a vegetable oil or other saponifiab e substance with the necessary quantity of sodium hydroxid or other saponifying agent, to this may be added the dye stuff in solution. If
- the mordant is to be actually combined with the soap mass it will be added thereto in the crutcher, after which the material is immed ately flaked or otherwise finely divided in order to assure solubility
- the reason why the mordant does not affect the dye stuff when the material is in the form of flakes is not entirely understood but it is belleved to be for the reason that the flaking ofthe material results in the dissipation of substantially all the uncombined water and of yellow, tan, and brown by adding to soap flakes containing as a dye, the sodium salt of diphenyldiazobi-salicylic acid (chrysamin (Jr) a mordant flake containing about 20% Glaubers salt, and 1% soda ash.
- chlorrysamin (Jr) a mordant flake containing about 20% Glaubers salt
- ditolyldiazo-dinaphthionic acid benzopurpurin 4 B
- tannin and tartar emetic to the zinc double chlorid of tetramethyl di paraamido triphenyl-carbinol (malachite green) to render the dye universally applicable to silk, wool, jute, leather and-cotton.
Landscapes
- Coloring (AREA)
- Detergent Compositions (AREA)
Description
UNITED STATES PATENT-OFFICE.
DAVID JULIAN BLOCK, OF CHICAGO, ILLINOIS, ASSIGNOR T0 SUNIBEAM CHEMICAL COMPANY, OF CHICAGO, ILLINOIS, A CORPORATION OF ILLINOIS, AND-CHARLE C. HUFFMAN, OF CHICAGO, ILLINOIS.
DYE-SOAP AND MORDANT.
80 Drawing.
To all whom it may concern Be it known that I, DAVID JULIAN Bnoox, a citizen of the UnitedStates, and resident of Chicago, in the county of Cook and State of Illinois, have discovered a certain new and useful Dye-Soap and Mor(' at, of which the following is a specification.
My invention relates to dye soaps and partlcularly to a novel combination of a dye soap and mordant.
' ne of the principal objects of the invention is to provide a composition in which a greater range of dye may be employed in order to securee ually satisfactory results.
In the making 0 a dye soap it has been found that in order to produce a universal dye soap only a certain limited number of dyes may be used. The difiiculty has been in causing the dyes-of other than a certain limited number to adhere to the fabrics without the use of a mordant.
The present invention contemplates the addition of the mordant to the material and to mechanically mix the same therewith.- This is not generally practical where the dye soap is marketed in cake form for the reason that the mordant is likely to cause precipitation of the dye or oxidization or alteration of the dye stuff. I have found, however, that by flaking or otherwise finely dividing the product the mordant added thereto will not injuriously aflect the substance and dyestuffs may be employed which were not heretofore considered practical for use in dyesoaps.
By the word mordant as used herein I refer to any substance which may be used in connection with coloring matter, either as a preliminary treatment of the fabric prior to the application of the dye, or color; or any after treatment intended to improve, or 0th erwise alter, the tone, shade, tint, evenness or uniformity of the dyeing; its fastness to light, heat, washing, topping, perspiration, or chemical action; or tending to "affect the solubility, or the equalizing properties of the dye.
In making a dye soap in accordance with my invention the material may be prepared in the usual manner by suitabl mixing a vegetable oil or other saponifiab e substance with the necessary quantity of sodium hydroxid or other saponifying agent, to this may be added the dye stuff in solution. If
Specification of Letters Patent.
Application filed April 21,
Patented Dec. 14, 1920. 1919. Serial No. 291,115.
the mordant is to be actually combined with the soap mass it will be added thereto in the crutcher, after which the material is immed ately flaked or otherwise finely divided in order to assure solubility The reason why the mordant does not affect the dye stuff when the material is in the form of flakes is not entirely understood but it is belleved to be for the reason that the flaking ofthe material results in the dissipation of substantially all the uncombined water and of yellow, tan, and brown by adding to soap flakes containing as a dye, the sodium salt of diphenyldiazobi-salicylic acid (chrysamin (Jr) a mordant flake containing about 20% Glaubers salt, and 1% soda ash. These may be directly combined with the soap flake during the process of saponification, or may be'added after the soap is formed by crutching or mechanically working the salts into the soap; The foregoing proportions are productive of light shades; for darker colors I double the quantity of mordant material added; this treatment is roductive of brilliant yellows. For tans use the same dye flake and mordant flake, but add to this mixture a flake containing in mechanical admixture, a wei ht of copper sulfate equivalent to the weig t of dye used.
' As a practical example of after treatment I add to dye flakes containing the sodium salt of dimethoxy-diphenyldiazo-naphtholdisulfo'nic-azo-di metatoluenediamin (direct blue black) as a dye, a soap flake carrying in benzene-azo-meta-phenylene-diamin (chrysoidin) which makes the dye alike applicable to silk, WOOl, or cotton. I add soda ash to the mordant flake for use with the soda salt of ditolyldiazo-dinaphthionic acid (benzopurpurin 4 B) to secure fast reds on cotton; tannin and tartar emetic to the zinc double chlorid of tetramethyl di paraamido triphenyl-carbinol (malachite green) to render the dye universally applicable to silk, wool, jute, leather and-cotton.
It will be understood that the product herein claimed may be produced by the use of materials other than those herein s ecified and may be marketed in a condition other than the particular condition specified. Many mordants other than those specified and many (1 es different from those mentionedmay e'employed with satisfactory results and I do not wish to be limited other than as indicated in the appended claims.
I claim:
1. A dye soap in the form of-flakes and a mordant mixed with the flakes, substantially as described. I d
2. A dye soap in the form of particles and a mordant in substantially -the same form combined and mechanically mixed therewith, substantially as described.
' Signed-at. Chicago, Illinois, this 14th day of April, 1919. I
7 DAVID JULIAN BLOCK. Witness T. D. BUTLER.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1361811A true US1361811A (en) | 1920-12-14 |
Family
ID=3397128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US1361811D Expired - Lifetime US1361811A (en) | Dye-soap and mordant |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1361811A (en) |
-
0
- US US1361811D patent/US1361811A/en not_active Expired - Lifetime
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