US131680A - Improvement in annealing and tinning wire - Google Patents
Improvement in annealing and tinning wire Download PDFInfo
- Publication number
- US131680A US131680A US131680DA US131680A US 131680 A US131680 A US 131680A US 131680D A US131680D A US 131680DA US 131680 A US131680 A US 131680A
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- US
- United States
- Prior art keywords
- wire
- annealing
- bath
- tinning
- improvement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000000137 annealing Methods 0.000 title description 22
- 238000000034 method Methods 0.000 description 28
- 229910052718 tin Inorganic materials 0.000 description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
Definitions
- Fig. 2 represents ⁇ a transverse vertical section of the annealing apparatus;
- Fig. 3 represents y a transverse vertical section of the tinning apparatus5 and
- Fig. 4 represents a-longitudinal section of an addition-al bath or modification of the apparatus, which may sometimes be desired.
- This invention relates to certain improvements in the manufacture of tinned wire.
- the part marked A representsthe wire, which is first drawn from a suitable supporting-reel (notshown) through a vat ⁇ of melted lead, B, which is kept at a eonl stant ⁇ degree of temperature by a fire in the is then drawn through a vat of diluted muriatie acid,
- the acid cleans the surfaceof the wire, which, after ⁇ leaving the acid-bath, is drawn n throu ghavat of melted tin, E, arranged over a furnace, F, so as to be kept at a proper degree of temperature, and covered by a hood,
- a friction-roll is arranged at K, around which the wire passes, ⁇ and suitable mechanism connected therewith for retardin g its motion, so ,that the wire will be wound upon the cylinder J with the proper degree of tension.
- Operating mechanism is to be combined with the spindle L of the cylinder J for revolving I said cylinder and drawing forward the wire through the various. baths.
- the wire is, in the present instance, held beneath .the surface of the various baths by means of pressers M, which have grooves in their lower ends to guidethewire, and which are pivoted to supporting-bars m in such a manner that they can be swung ⁇ up, (as shown at N in dotted lines,) and the wire raised from the baths.
- a bath,P of muriate of zine
- a wiper may be used, as at R, for removing the water from the surface of the wire as it leaves the bath I.
- This 'wiper may be composed of v cotton-waste or similar material, fixed in a suitable frame, andV clamped down upon the wire with the re-
- the furnaces, vats, and other mechanism may be constructed as described in my application for Letters Patent for improved apparatus for annealing and tinning wire, of even date herewith, or their form may be somewhat varied, provided the process is substantially the same, the essential features of said process being, flrst annealing the wire by passing it through a bath of melted lead, then through diluted muriatic acid or muriate of zinc, or both, and then through a bath of melted tin, after which it is cooled and coiled in a -suitablemanner, the entire process being performed in one continuous and combined operation.
- the Wire is left with a smooth and even surface, and in a much softer and more pliable condition than Wire produced by the ordinary method, which method is to place the Wire in close annealing-pots and subject it to heat Within a furnace for about twenty-four hours; then, after removing it from the furnace and allowing it to cool gradually, the Wire is taken from the pot and dipped in boiling diluted sulphuric acid, to clean or scale its surface; it is then placed in a liquor composed of rye-meal and water to prevent it from rusting, and afterward drawn through suitable dies to produce the required size, it being passed through from one to four dies, according to the size to which it is required to reduce the Wire.
- the soft and pliable Wire is preferable, as it hugs closer and winds more uniformly upon the central Wire, While the strings formed of softwire produce a clearer and more perfect tone than do those Wound with a stiff wire, which is liable to spring away from the central Wire and produce a jarring tone When the string is vibrated.
- This clearness of tone is important; and copperwire has heretofore been much used for the purpose of Winding the strings, owing to its extreme pliability; but it has been foundupon trial that tinned iron wire, made by my improved process, above described, is a superior article for the purpose, and large quantities are at present being used therefor.
- Wire can, with equal facility, be coated with zinc by means of this process, the only change necessary being to substitute zinc in place of tin in the bath E.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Description
ATE
EDW'IIT` Il. HILLL, OF WORCESTER, MASSACHUSETTS, ASSIGNOR TO WASH- V AND-MOENMANUFAOTURING` COMPANY, OF SAME PLAGE.
` i liviPuovEMENT INANNEALING AND TINNING WIRE.
- Specification forming part of Letters Patent No. 131,680, dated September 24,1872.
p CASE A.
tain new and useful Improvements in the Pro-4 cess of Annealing and Tinning Wire and I do hereby declare that the following is a full,
clear, and exact description of the same, reference being had to the accompanying drawingwhichfforms apart of this specification, and inwhichy Figurel represents a central longitudinal section of apparatus for annealing and tinning wire 1n accordance with my improved process;
Fig. 2 represents `a transverse vertical section of the annealing apparatus; Fig. 3 represents y a transverse vertical section of the tinning apparatus5 and Fig. 4represents a-longitudinal section of an addition-al bath or modification of the apparatus, which may sometimes be desired. i
This invention relates to certain improvements in the manufacture of tinned wire; and
consists in a process of annealing `and. tinning, as hereinafter described, by one continuous'and combined operation.
In the drawing, the part marked A representsthe wire, which is first drawn from a suitable supporting-reel (notshown) through a vat `of melted lead, B, which is kept at a eonl stant` degree of temperature by a fire in the is then drawn through a vat of diluted muriatie acid,
which is arranged in close proximity to and in linewith the annealing-bath B. The acid cleans the surfaceof the wire, which, after `leaving the acid-bath, is drawn n throu ghavat of melted tin, E, arranged over a furnace, F, so as to be kept at a proper degree of temperature, and covered by a hood,
` G, having a flue`,`H, to convey the acid-fumes away to the chimney. The wire leaves the tinning-bath E with its surface coated with `quired pressure.
tin, and it is then drawn through a bath of clear water, I, by means of which the wire is cooled, after which it is wound in `a finished condition upon the cylinder J, and from the cylinder it is removed in suitable-sized coils,
which are properly tied and packed for shipment. A friction-roll is arranged at K, around which the wire passes,` and suitable mechanism connected therewith for retardin g its motion, so ,that the wire will be wound upon the cylinder J with the proper degree of tension. Operating mechanism is to be combined with the spindle L of the cylinder J for revolving I said cylinder and drawing forward the wire through the various. baths. The wire is, in the present instance, held beneath .the surface of the various baths by means of pressers M, which have grooves in their lower ends to guidethewire, and which are pivoted to supporting-bars m in such a manner that they can be swung` up, (as shown at N in dotted lines,) and the wire raised from the baths. If preferred, other mechanism'lmay be used for holding the wires beneath the surface of the baths. If desired, a bath,P, of muriate of zine, may be arranged between the acid-bath D and the tinbath E, as illustrated in Fig. 4. A wiper may be used, as at R, for removing the water from the surface of the wire as it leaves the bath I. This 'wiper may be composed of v cotton-waste or similar material, fixed in a suitable frame, andV clamped down upon the wire with the re- The furnaces, vats, and other mechanism may be constructed as described in my application for Letters Patent for improved apparatus for annealing and tinning wire, of even date herewith, or their form may be somewhat varied, provided the process is substantially the same, the essential features of said process being, flrst annealing the wire by passing it through a bath of melted lead, then through diluted muriatic acid or muriate of zinc, or both, and then through a bath of melted tin, after which it is cooled and coiled in a -suitablemanner, the entire process being performed in one continuous and combined operation.
The advantages derived from my improved process `of annealing and tinning, are, first,
great economy of time and labor over the ordinary method; and, second, the Wire is left with a smooth and even surface, and in a much softer and more pliable condition than Wire produced by the ordinary method, which method is to place the Wire in close annealing-pots and subject it to heat Within a furnace for about twenty-four hours; then, after removing it from the furnace and allowing it to cool gradually, the Wire is taken from the pot and dipped in boiling diluted sulphuric acid, to clean or scale its surface; it is then placed in a liquor composed of rye-meal and water to prevent it from rusting, and afterward drawn through suitable dies to produce the required size, it being passed through from one to four dies, according to the size to which it is required to reduce the Wire. After drawing, it is passed through a bath of muriate of zinc, and then through a bath of melted tin. This old process is long and laborious, and the Wlre, owing to its being drawn through the dies after it has been annealed, and before it is tinned, is rendered stiff and hard, which is an objection that it is desirable to obvia-te, and which objection is obviated by my improved process of annealing and tinning; and the Wire produced thereby is soft and pliable, as above stated, thereby rendering it more desirable for the manufacture of Wire-cloth, in the construction of Which large quantities are annually used With a constantly-increasing demand. Also, for covering the bass-strings of pianos and similar instruments the soft and pliable Wire is preferable, as it hugs closer and winds more uniformly upon the central Wire, While the strings formed of softwire produce a clearer and more perfect tone than do those Wound with a stiff wire, which is liable to spring away from the central Wire and produce a jarring tone When the string is vibrated. This clearness of tone is important; and copperwire has heretofore been much used for the purpose of Winding the strings, owing to its extreme pliability; but it has been foundupon trial that tinned iron wire, made by my improved process, above described, is a superior article for the purpose, and large quantities are at present being used therefor.
It will' be understood that Wire can, with equal facility, be coated with zinc by means of this process, the only change necessary being to substitute zinc in place of tin in the bath E.
I am aware that it is not newto draw Wire in a heated state from the annealing-oven directly into the cleaning-bath, and thence, when the galvanizing is to be done, directly into the bath of molten metal, such process'havingbeen described and claimed in the patent of G. Bedson, No. 37,669, of February 17 1863; and this, therefore, I do not claim; but
Having described my improved process of annealingand tinnin g Wire, whatI claim there- -in as new and of my invention, and desire to secure by Letters Patent, is-
1. The process of annealing and tinnin g Wire by one continuous and combined operation, substantially as above described.
2. The process of annealing Wire With a combined lead and charcoal bath, substantially as set forth. l
EDWIN H. HILL.
Witnesses:
Tnos. H. DODGE, GHAs. H. BURLEIGH,
Publications (1)
Publication Number | Publication Date |
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US131680A true US131680A (en) | 1872-09-24 |
Family
ID=2201097
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US131680D Expired - Lifetime US131680A (en) | Improvement in annealing and tinning wire |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2587605A (en) * | 1947-12-09 | 1952-03-04 | United States Steel Corp | Manufacture of tin plate |
US3024492A (en) * | 1958-06-30 | 1962-03-13 | Okonite Co | Method of and apparatus for curing thermosetting materials |
US3993803A (en) * | 1971-10-20 | 1976-11-23 | Giuseppe Camardella | Method of tinning coil terminals |
US4101695A (en) * | 1975-12-05 | 1978-07-18 | Johns-Manville Corporation | Method of coating strand material |
US4177326A (en) * | 1976-12-17 | 1979-12-04 | Vallourec Usines A Tubes De Lorraine-Escaut Et Vallourec Reunies | Process for coating stainless steel with a lead-based alloy and article |
-
0
- US US131680D patent/US131680A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2587605A (en) * | 1947-12-09 | 1952-03-04 | United States Steel Corp | Manufacture of tin plate |
US3024492A (en) * | 1958-06-30 | 1962-03-13 | Okonite Co | Method of and apparatus for curing thermosetting materials |
US3993803A (en) * | 1971-10-20 | 1976-11-23 | Giuseppe Camardella | Method of tinning coil terminals |
US4101695A (en) * | 1975-12-05 | 1978-07-18 | Johns-Manville Corporation | Method of coating strand material |
US4177326A (en) * | 1976-12-17 | 1979-12-04 | Vallourec Usines A Tubes De Lorraine-Escaut Et Vallourec Reunies | Process for coating stainless steel with a lead-based alloy and article |
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