US1185058A - Separator. - Google Patents

Separator. Download PDF

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Publication number
US1185058A
US1185058A US84624414A US1914846244A US1185058A US 1185058 A US1185058 A US 1185058A US 84624414 A US84624414 A US 84624414A US 1914846244 A US1914846244 A US 1914846244A US 1185058 A US1185058 A US 1185058A
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United States
Prior art keywords
separator
ribs
wood
rubber
acid
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Expired - Lifetime
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US84624414A
Inventor
Rufus N Chamberlain
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GOULD STORAGE BATTERY Co
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GOULD STORAGE BATTERY CO
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Priority to US84624414A priority Critical patent/US1185058A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/429Natural polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • My invention relates to separators for storage batteries, and has for its object a wood separator so treated or constructed as to increase the life ofthe separator, and the efficiency of the battery in which it is used, and also the provision of a separator which will perform the function now performed by the usual wood separator and the a perforated rubber sheet combined.
  • My invention consists in taking the ordinary wood separator and preferably vulcanizing rubber on the outer portion of the ribs although the rubber may be placed thereon in other ways.
  • the rubber When the rubber is vulcanizedin place it probably penetrates wood which would otherwise come in direct contact with the positive is protected by the rubber or other suitable material placed upon the ribs, and at the same time the articlp is "produced at a considerably lower cos r it further distinct advantage secured by my invention is that the rubber placed upon the ribs strengthens them so that a mechanically stronger separator is secured, and it" also insures that the acid channels will be properly maintained throughout the life of the separator.
  • FIG. 1 shows a side elevation
  • Fig. 2 shows a section on the line 22 of Fig. 1.
  • the separator comprises a sheet '1 of wood, having ribs 2 preferably formed integrally therewith.
  • ribs 2 On the outer portion of each rib is a layer; of somewhat'relatively hard acid-resistant material 3, such as rubber. Thisrubber may be applied to the ribs in any suitable manner, preferably by vulcanizing, or it may be formed separately and otherwise secured in position.
  • the rubber or other material will insure that the channels for the electrolyte are inaintainedand a free circulation along the face of the plate thereby secured; At the same time the rubber will protect the ribs of the separator which has been treated preferably by the process set forth in my application, Serial No. 790,653, filed on the 19th day of September, 1914.
  • the separator Whentreated by that process, the separator has substantially all of its natural composition and structure, such as porosity, and contains all of its natural constituents, the fiber being "rcoateol throughout by'a suitable inert material .to
  • the rubber protects the surface of the ribs, whereby the length of life and usefulness of the separator are greatly increased.
  • a wood separatorfor storage batteries 3.
  • a separator for storage batteries com-' prising a sheet of wood with ribs thereon and having-a coating of rubber on the ribs 4.
  • a separator for storage batteries com- 7 prising a sheet of wood having its natural porosity and-constituents and its pores lined with an acid-resistant material and having ribs thereon with only their outer portions protected by a layer of rubber vulcanized in site ' plates having ribs thereon and having the I having thin porous portions of-natural struc- 1 resistant material.
  • A'porous separator for-storage battery plates having ribs thereon and having an acid-resistant material on the ribs only.
  • V A porous separator for storage battery resistant material.
  • a porous separator for storage battery plates having ribs thereon and having the face only of the ribs covered withan acid outer surface of the ribs covered with andthe pores of the ribs only filled with an acid- 8.
  • a porous separator for storage battery plates having ribs thereon and having the pores in the outer surface of the ribs only filled with an acid-resistant material. -9.
  • a separator for storage battery plates ture and thicker portions having theirouter having thin porous portions of natural structure and thicker portions adapted to bear against said plates, the surface of said.
  • a separator for storage battery plates having thin porous portions of natural structure and thicker portions adapted to bear against said plates, the surface of said thicker portions being rendered acid-resistant by filling the pores with an acid-resistant material;
  • a separator for storage battery plates having thin porous portions of natural structure and thicker portions adapted to Hear against said plates, the surface of said thicker ortions being rendered acid-resistant by llingathe pores of the thicker portions with rubber and vulcanizing it in situ.
  • a separator for storage battery plates having thin porous portions of natural structure and-thicker portions, said thicker portions having'only their faces protected by acid-resistant material.
  • a separator for storage battery plates having thin porous portions and thicker portions, said thicker portions only having a thin strip of acid-resistant material thereon.
  • A, separator for storage battery plates having only a portion of its surface adapted to contact w1th the positive plates, and an acid-resistant material between the contact surface and the positive plates only, the space between the other parts of the separator and the positive plates being effectively unobstructed.
  • a wood separator for storage batteries having its natural porosity and constituents, a portion only thereof being protected by an acid-resistant material.
  • a separator for storage battery plates 19 A wood separator for storage batteries having its natural porosity and constituents and having thereon strips of rubber covering only a portion of the surface of said sep-' arator.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cell Separators (AREA)

Description

R. N. CHAMBERLAIN SEPARATOR.
APPLICATION FILED JUNE 20.1914.
"U 1 9 1 0 3 W M d Le w m P llllllIll "time causes a comparativel EFUFUS I l. CHELMBERLAIN, OF CHICAGO, ILLINOIS, ASSIGNUR T0 GSULD'STOW GE BATTERY COMPANY, A CORPORATION OF NEW YORK.
Specification of Letters Patent.
Patented May 3ft, iiltlllS.
Application filed .l'une 20, 191%. serial No. siesta.
To all whom it may concern Be it known that l, RUFUS N. GHAMBER-- LAIN, a citizen of the United States, and a resident of the city of Chicago, county of Cook, and State of lfllinois, have invented certain new and useful Improvements in Separators, of which the following is a specification. I
My invention relates to separators for storage batteries, and has for its object a wood separator so treated or constructed as to increase the life ofthe separator, and the efficiency of the battery in which it is used, and also the provision of a separator which will perform the function now performed by the usual wood separator and the a perforated rubber sheet combined.
hat the life of wood increase in the cost of the battery. The rea- I son why the rubber sheet increases the life of the separator is probably because when the wood is placed in direct contact with the positive plate, the oxygen liberated from the plate attacks the wood while in nascent condition, and being more active at that rapid disintegration of the wood; while when the rubber sheet is used the wood is a sufiicient distance away from the surface of the positive to escape the action of the oxygen while in nascent condition.
My invention consists in taking the ordinary wood separator and preferably vulcanizing rubber on the outer portion of the ribs although the rubber may be placed thereon in other ways. When the rubber is vulcanizedin place it probably penetrates wood which would otherwise come in direct contact with the positive is protected by the rubber or other suitable material placed upon the ribs, and at the same time the articlp is "produced at a considerably lower cos r it further distinct advantage secured by my invention is that the rubber placed upon the ribs strengthens them so that a mechanically stronger separator is secured, and it" also insures that the acid channels will be properly maintained throughout the life of the separator.
A separator embodying my invention is shown in the accompanying drawings, forming a part of this specification, in which Figure 1 shows a side elevation; and Fig. 2 shows a section on the line 22 of Fig. 1.
By reference to the drawings, it will be seen that the separator comprises a sheet '1 of wood, having ribs 2 preferably formed integrally therewith. On the outer portion of each rib is a layer; of somewhat'relatively hard acid-resistant material 3, such as rubber. Thisrubber may be applied to the ribs in any suitable manner, preferably by vulcanizing, or it may be formed separately and otherwise secured in position.
Front the foregoing it will. be seen that the rubber or other material will insure that the channels for the electrolyte are inaintainedand a free circulation along the face of the plate thereby secured; At the same time the rubber will protect the ribs of the separator which has been treated preferably by the process set forth in my application, Serial No. 790,653, filed on the 19th day of September, 1914. Whentreated by that process, the separator has substantially all of its natural composition and structure, such as porosity, and contains all of its natural constituents, the fiber being "rcoateol throughout by'a suitable inert material .to
retard the action of the electrolyte upon the constituents of the wood, and when treated as set forth herein, the rubber protects the surface of the ribs, whereby the length of life and usefulness of the separator are greatly increased.
While I have specifically mentioned rubber as the material for protecting the surface of the ribs, it is understood that any material, which is relatively harder than I having ribs at intervals on one surface there of, only said ribs having their outer por-' 7 only.
wood, and has the necessary acid-resistant qualities, will be. equally satisfactory for the purpose specifie Having described my invention, what I clann as new .and desire to secure by Letters-Patent is 5- i 1. A wood separatorfor storage batteries 3. A separator for storage batteries com-' prising a sheet of wood with ribs thereon and having-a coating of rubber on the ribs 4. A separator for storage batteries com- 7 prising a sheet of wood having its natural porosity and-constituents and its pores lined with an acid-resistant material and having ribs thereon with only their outer portions protected by a layer of rubber vulcanized in site ' plates having ribs thereon and having the I having thin porous portions of-natural struc- 1 resistant material. I v
5. A'porous separator for-storage battery plates having ribs thereon and having an acid-resistant material on the ribs only.
6. A porous separator for storage battery resistant material. V
7. A porous separator for storage battery plates having ribs thereon and having the face only of the ribs covered withan acid outer surface of the ribs covered with andthe pores of the ribs only filled with an acid- 8. A porous separator for storage battery plates having ribs thereon and having the pores in the outer surface of the ribs only filled with an acid-resistant material. -9. A separator for storage battery plates ture and thicker portions having theirouter having thin porous portions of natural structure and thicker portions adapted to bear against said plates, the surface of said.
surface rendered acid-resistant. Y
10. .A separator for storage battery plate thicker portions being-rendered acid-resistant.
11. A separator for storage battery plates having thin porous portions of natural structure and thicker portions adapted to bear against said plates, the surface of said thicker portions being rendered acid-resistant by filling the pores with an acid-resistant material;
having thin porous portions of natural struc- 'ture and thicker portions adapted to bear against said plates, the surface of said thicker ortions being rendered acid-resistant by lling the pores thereof with rubber and vulcanizing it.
13. A separator for storage battery plates having thin porous portions of natural structure and thicker portions adapted to Hear against said plates, the surface of said thicker ortions being rendered acid-resistant by llingathe pores of the thicker portions with rubber and vulcanizing it in situ.
14. A separator for storage battery plates having thin porous portions of natural structure and-thicker portions, said thicker portions having'only their faces protected by acid-resistant material.
'15. A separator for storage battery plates having thin porous portions and thicker portions, said thicker portions only having a thin strip of acid-resistant material thereon.
16. A, separator for storage battery plates having only a portion of its surface adapted to contact w1th the positive plates, and an acid-resistant material between the contact surface and the positive plates only, the space between the other parts of the separator and the positive plates being effectively unobstructed.
17 A wood separator for storage batteries having its natural porosity and constituents, a portion only thereof being protected by an acid-resistant material. 1
12. A separator for storage battery plates 19. A wood separator for storage batteries having its natural porosity and constituents and having thereon strips of rubber covering only a portion of the surface of said sep-' arator.
In testimony whereof, I have signed my name to this specification, in the presence of two subscribing witnesses.
- RUFUS N. CHAMBERLAIN.
WVitnesses:
' NEWTON A. BURGESS,
EDWIN Seem.
US84624414A 1914-06-20 1914-06-20 Separator. Expired - Lifetime US1185058A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2569361A (en) * 1947-06-27 1951-09-25 Nat Battery Co Electrochemical cell diaphragm
US2687445A (en) * 1950-04-11 1954-08-24 Dewey And Almy Chem Comp Battery separator
WO2002028955A2 (en) * 2000-10-03 2002-04-11 Daramic, Inc. Lignins used in ultrahigh molecular weight thermoplastic battery separators

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2569361A (en) * 1947-06-27 1951-09-25 Nat Battery Co Electrochemical cell diaphragm
US2687445A (en) * 1950-04-11 1954-08-24 Dewey And Almy Chem Comp Battery separator
WO2002028955A2 (en) * 2000-10-03 2002-04-11 Daramic, Inc. Lignins used in ultrahigh molecular weight thermoplastic battery separators
WO2002028955A3 (en) * 2000-10-03 2002-06-13 Daramic Inc Lignins used in ultrahigh molecular weight thermoplastic battery separators

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