US1179176A - Paint for protecting metals from rusting. - Google Patents
Paint for protecting metals from rusting. Download PDFInfo
- Publication number
- US1179176A US1179176A US85506314A US1914855063A US1179176A US 1179176 A US1179176 A US 1179176A US 85506314 A US85506314 A US 85506314A US 1914855063 A US1914855063 A US 1914855063A US 1179176 A US1179176 A US 1179176A
- Authority
- US
- United States
- Prior art keywords
- rusting
- paint
- sulfur
- protecting metals
- metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002184 metal Substances 0.000 title description 11
- 229910052751 metal Inorganic materials 0.000 title description 11
- 150000002739 metals Chemical class 0.000 title description 7
- 239000003973 paint Substances 0.000 title description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000010426 asphalt Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- GFVUWETXLKDTIO-UHFFFAOYSA-J [C+4].[SH-].[SH-].[SH-].[SH-] Chemical compound [C+4].[SH-].[SH-].[SH-].[SH-] GFVUWETXLKDTIO-UHFFFAOYSA-J 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Definitions
- the present invention relates to the art of rust proofing metals and consists in the preparation of an improved rust proofing composition.
- oils such as linseed oil, rape-seed oil, etc.
- suitable temperatures with sulfur yield certain roducts of condensation
- hlorid of sulfur serves equally as well as sulfur and the term sulfur is used hereinafter and in the claims in a sense broad enough to include such a compound.
- other oils, vegetable as well as animal ones yield on treatment with sulfur or chlorid of sulfur at suitable temperatures, similar products of condensation. Depending upon the proportions of the reagents entering into the mixture and upon the temperature at which the reaction is carried out, products are obtained which vary all the way from syrupy consistency to brittle masses.
- Products of a tough, rubber-like character may be obtained, if an oil such as linseed oil, or a mixture of the same with resin, is heated to a temperature from 170 C. to 200 C. and while at this temperature sulfur is added little by little until the mixture is of such consistency that it can be drawn out into threads that do not readily break. On cooling, this product discloses physical properties closely approaching those of rubber.
- One hundred (100) parts by Weight of linseed oil is mixed with one hundred parts (100) by weight of American resin, during agitation and in the presence of heat.
- the temperature of the mixture has reached from 170 C. to 200 (3., small portions of sulfur are added gradually until'a sample taken from the mass, draws out to a thread.
- this condition has been attained,-the temperature being such that it may serve to melt the added ingredients,one hundred (100) parts tar 011 are added or some other solvent such as a low boiling fraction of raw petroleum, carbon tetrachlorid, carbon bisulfid, benzol, etc.
- a paint for protecting metals from rusting comprising a solution of the condensation products of oil, resin and sulfur, which condensation products are capable, at a suitable temperature, of being drawn out to threads, such solution being intimately intermixed with a tarry liquid.
- a paint for protecting metals from rusting comprising a solution of the condensation products of oil, resin and sulfur,
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
UNITED STATES PATENT OFFICE.
HEINRICH GRNNWALD, 0E GBIESBOBN, NEAR BOUS-ON-THE-SAAR, GERMANY.
PAINT FOR PROTECTING METALS FROM RUSTING.
No Drawing.
To all whom it may concern Be it known that I, HEINRICH GRiiNWALD, a subject of the King of Bavaria, residing at No. 218 Griesborn, near Bous-on-the-Saar, Germany, have invented a certain new and useful Paint for Protecting Metals from Rusting; and I do hereby declare the following to be a full, clear, and exact description of the invention.
The present invention relates to the art of rust proofing metals and consists in the preparation of an improved rust proofing composition.
The fact that oils, such as linseed oil, rape-seed oil, etc., when combined at suitable temperatures with sulfur, yield certain roducts of condensation, is well known.
hlorid of sulfur serves equally as well as sulfur and the term sulfur is used hereinafter and in the claims in a sense broad enough to include such a compound. Also other oils, vegetable as well as animal ones yield on treatment with sulfur or chlorid of sulfur at suitable temperatures, similar products of condensation. Depending upon the proportions of the reagents entering into the mixture and upon the temperature at which the reaction is carried out, products are obtained which vary all the way from syrupy consistency to brittle masses.
Products of a tough, rubber-like character may be obtained, if an oil such as linseed oil, or a mixture of the same with resin, is heated to a temperature from 170 C. to 200 C. and while at this temperature sulfur is added little by little until the mixture is of such consistency that it can be drawn out into threads that do not readily break. On cooling, this product discloses physical properties closely approaching those of rubber.
Through extended researches which have resulted in the present discovery, it has been found that these masses or mixtures of the same with asphalt, pitch tar or other substances which are useful for rust proofing metals, when applied in suitable manner to metal surfaces, adhere extremely firmly thereto, stretch with the same without cracking when the metal expands or contracts by Specification of Letters Patent.
Patented Apr. 11, 1916.
reason of temperature change, protect the metal against moisture, insulate it against the action of electric currents and forms an eflicient protection against erosion and like mechanical Wear upon the surface.
The following example serves to illustrate the invention: One hundred (100) parts by Weight of linseed oil is mixed with one hundred parts (100) by weight of American resin, during agitation and in the presence of heat. When the temperature of the mixture has reached from 170 C. to 200 (3., small portions of sulfur are added gradually until'a sample taken from the mass, draws out to a thread. When this condition has been attained,-the temperature being such that it may serve to melt the added ingredients,one hundred (100) parts tar 011 are added or some other solvent such as a low boiling fraction of raw petroleum, carbon tetrachlorid, carbon bisulfid, benzol, etc. To this are added five hundred (500) parts of coke oven tar (free from water) and the metalobjects, such as iron pipes, then dipped therein. Upon cooling, the objects are found to be covered with an extremely adherent protective coating possessing the characteristics above mentioned. It is pos-.
sible furthermore to dissolve the above described sulfur-oil-resin mixture after it has cooled to 100 C., in varnish or in one of the other abovementioned thin fluid solvents and add thereto a solution of one hundred (100) parts asphalt in one hundred (100) parts varnish. This preparation may be applied cold to the metal, and upon the evaporation of the solvent leaves a protec-' tive covering having the same characteristics as that first described.
I claim:
1. A paint for protecting metals from rusting, comprising a solution of the condensation products of oil, resin and sulfur, which condensation products are capable, at a suitable temperature, of being drawn out to threads, such solution being intimately intermixed with a tarry liquid.
2. A paint for protecting metals from rusting, comprising a solution of the condensation products of oil, resin and sulfur,
to threads, such solution being intimately I intermixed with a tarry liquid consisting of 5 a solution of asphalt in an equal part of varnish.
In testimony whereof I have signed my which condensation products are capable, at name to this specification in the presence of a suitable temperature, of being drawn out two subscribing w tnesses.
HEINRICH GRI'INWALD.
Witnesses:
FRITZ MOLIBQR, CARL DRAPPER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85506314A US1179176A (en) | 1914-08-04 | 1914-08-04 | Paint for protecting metals from rusting. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85506314A US1179176A (en) | 1914-08-04 | 1914-08-04 | Paint for protecting metals from rusting. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1179176A true US1179176A (en) | 1916-04-11 |
Family
ID=3247162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US85506314A Expired - Lifetime US1179176A (en) | 1914-08-04 | 1914-08-04 | Paint for protecting metals from rusting. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1179176A (en) |
-
1914
- 1914-08-04 US US85506314A patent/US1179176A/en not_active Expired - Lifetime
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