US11697768B2 - Foaming additive with low ecotoxicological impact for soil conditioning in the presence of mechanised excavation - Google Patents
Foaming additive with low ecotoxicological impact for soil conditioning in the presence of mechanised excavation Download PDFInfo
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- US11697768B2 US11697768B2 US17/262,389 US201917262389A US11697768B2 US 11697768 B2 US11697768 B2 US 11697768B2 US 201917262389 A US201917262389 A US 201917262389A US 11697768 B2 US11697768 B2 US 11697768B2
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- foam
- glutamate
- weight
- soil conditioning
- soil
- Prior art date
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- 239000000654 additive Substances 0.000 title claims abstract description 48
- 239000002689 soil Substances 0.000 title claims abstract description 23
- 238000005187 foaming Methods 0.000 title claims abstract description 20
- 230000000996 additive effect Effects 0.000 title claims description 28
- 230000003750 conditioning effect Effects 0.000 title claims description 18
- 238000009412 basement excavation Methods 0.000 title claims description 14
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 239000006072 paste Substances 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 239000006260 foam Substances 0.000 claims description 32
- -1 alkyl ether sulphate Chemical class 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000007046 ethoxylation reaction Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
- 229940082509 xanthan gum Drugs 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229940071085 lauroyl glutamate Drugs 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- VTQCNEDHHKIARX-QMMMGPOBSA-N (4S)-4-amino-5-hexanoyloxy-5-oxopentanoic acid Chemical compound CCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O VTQCNEDHHKIARX-QMMMGPOBSA-N 0.000 claims description 2
- MKLBZEFCSOAOQB-JTQLQIEISA-N (4S)-4-amino-5-octanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O MKLBZEFCSOAOQB-JTQLQIEISA-N 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229940071124 cocoyl glutamate Drugs 0.000 claims description 2
- 239000004872 foam stabilizing agent Substances 0.000 claims description 2
- 229930195712 glutamate Natural products 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 229940070800 myristoyl glutamate Drugs 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 1
- 241000251468 Actinopterygii Species 0.000 description 27
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 22
- 230000007059 acute toxicity Effects 0.000 description 21
- 231100000403 acute toxicity Toxicity 0.000 description 21
- 239000000203 mixture Substances 0.000 description 19
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000001988 toxicity Effects 0.000 description 12
- 231100000419 toxicity Toxicity 0.000 description 12
- 229910052938 sodium sulfate Inorganic materials 0.000 description 11
- 235000011152 sodium sulphate Nutrition 0.000 description 11
- 239000000047 product Substances 0.000 description 8
- 231100000636 lethal dose Toxicity 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000011435 rock Substances 0.000 description 6
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000002360 explosive Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229920001222 biopolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- 241000238578 Daphnia Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000011150 reinforced concrete Substances 0.000 description 2
- 239000011378 shotcrete Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000006592 excitoxicity Effects 0.000 description 1
- RRDQTXGFURAKDI-UHFFFAOYSA-N formaldehyde;naphthalene-2-sulfonic acid Chemical compound O=C.C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 RRDQTXGFURAKDI-UHFFFAOYSA-N 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
- 229940048848 lauryl glucoside Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/16—Soil-conditioning materials or soil-stabilising materials containing organic compounds only applied in a physical form other than a solution or a grout, e.g. as platelets or granules
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
- C09K17/32—Prepolymers; Macromolecular compounds of natural origin, e.g. cellulosic materials
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D9/00—Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
- E21D9/001—Improving soil or rock, e.g. by freezing; Injections
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D9/00—Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
- E21D9/06—Making by using a driving shield, i.e. advanced by pushing means bearing against the already placed lining
- E21D9/0642—Making by using a driving shield, i.e. advanced by pushing means bearing against the already placed lining the shield having means for additional processing at the front end
- E21D9/0678—Adding additives, e.g. chemical compositions, to the slurry or the cuttings
- E21D9/0685—Foaming agents
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D9/00—Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
- E21D9/10—Making by using boring or cutting machines
Definitions
- the present invention relates to the use of foaming additives in liquid, paste or powder form to condition soil excavated with a tunnel boring machine.
- Said additives can be classified as readily biodegradable and are characterised by a lower ecotoxicological impact than commercial products.
- the first method involves cyclical application of the operations described below:
- Said method is based on eliminating the right portion of rock so as to redistribute forces around the excavation, resulting in the “arch effect”, which partly supports the consolidating action of the reinforcing rods and shotcrete.
- the second construction technique can be divided into two main categories: the partial-face system and the full-face system (which involves excavating the entire tunnel diameter at the same time).
- the first case operations proceed as already described for the conventional method with roadheaders and rock breakers (instead of explosive), gradually forming the shape of the tunnel which will subsequently be lined with reinforced concrete.
- the advance is effected with a complex machine called a Tunnel Boring Machine (TBM), also known as a “mole” which, as well as performing the excavation, supports and prevents collapses of the face, carries away muck (by means of a screw and a conveyor belt), and places the final tunnel lining, consisting of prefabricated reinforced concrete segments.
- TBM Tunnel Boring Machine
- This type of machine can excavate nearly all types of geological material, including compact rock (hard-rock TBM), fractured rock (double-shield TBM), loose soil and under aquifers (EPB—Earth Pressure Balance machine).
- a TBM consists of:
- the cutterhead is fitted with tools called cutters, namely steel discs, which are designed to demolish the soil.
- Scrapers convey the soil to the conveyor belt that carries it out of the tunnel.
- the advance must take place with the excavation chamber constantly and completely full of suitably conditioned excavated material, in order to guarantee homogenous, uniform distribution of soil pressure on the tunnel face and prevent pressure drops between one push and the next.
- Said machines operate well when the layers through which the tunnel is driven are relatively hard and rigid, but do not perform so well when soft, friable soils are excavated.
- One technique used to overcome this problem is to apply a conditioning agent to the soil through the cutterhead. This stabilises the soil and facilitates excavation and soil extraction.
- a standard foaming agent formulation comprises a foaming agent and a stabilising agent.
- the foam is directly injected into the cutterhead at the excavation interface.
- the excavated soil is thus characterised by an organic content, deriving from the use of said additives, which interferes with the ecosystem.
- the foaming products generally used contain anionic surfactants.
- Said anionic surfactants are usually C12-16 alcohol ethoxylate (1-4 ethoxylation groups) sulphates. They are salified organic compounds, generally as sodium salts.
- foaming additives available on the market are:
- Polyfoamer ECO 100 comprising 10 to 20% by weight of a mixture of linear alcohols with a C12-C14 alkyl ethoxylate chain, sulphonated and salified with sodium.
- EP 1027528 illustrates a boring method wherein the composition of the aqueous material injected into the tunnel face consists of a polyethylene oxide with a molecular weight ranging between 2 and 8 million and an anionic surfactant containing sulphate.
- U.S. Pat. No. 6,172,010 discloses an aqueous foaming additive consisting of a surfactant and a polymer characterised by opposite charges, to obtain a stable foam.
- U.S. Pat. No. 6,802,673 discloses an aqueous foaming additive consisting of an anionic surfactant and a ⁇ -naphthalene sulphonate formaldehyde condensate.
- U.S. Pat. No. 4,442,018 discloses the composition of an additive for the production of a stable foam in aqueous phase consisting of an acrylic acid polymer, a C12-C14 and C16 alcohol, a C4 and C5 alcohol, sodium lauryl sulfate or alpha-olefin sulphonate, and water.
- the present invention relates to the use as conditioning foaming additive of a salified alkyl ether sulphate having a straight or branched C7-C11 alkyl chain and a degree of ethoxylation ranging between 4 and 9 as conditioning agent able to generate foam during mechanised soil excavation with a TBM.
- the additive in liquid, paste or powder form, generates foam when added in percentages of 0.1-4% by weight to an aqueous solution used on the tunnel face to soften the soil and allow faster extraction, and in the conditioning chamber to maintain the stability of the tunnel face.
- the use of a salified alkyl ether sulphate having a branched C7-C11 alkyl chain and a degree of ethoxylation of 7-9 is preferred.
- the alkyl ether sulphate is preferably a sodium or potassium salt.
- the salified alkyl ether sulphate can be used in addition to an aqueous solution in a percentage by weight of 0.1-4.0%.
- the salified alkyl ether sulphate can also be used in admixture with one or more surfactants selected from acyl glutamates and alkyl polyglucosides, in particular in admixture with an acyl glutamate selected from cocoyl glutamate, lauroyl glutamate, myristoyl glutamate, capryloyl glutamate, caproyl glutamate and the sodium salts thereof or in admixture with an alkyl polyglucoside selected from decyl glucoside, capryl glucoside, lauryl glucoside and cocoyl glucoside. Lauroyl glutamate, in particular in the form of sodium salt, and capryl glucoside, are particularly preferred.
- the percentages by weight of the total surfactant(s) present in the conditioning additive can range from 30 to 100% for alkyl ether sulphate, 0 to 50%, preferably 5 to 50%, for acyl glutamates, and 0 to 50%, preferably 10 to 50%, for alkyl polyglucoside, obviously on the proviso that the total is 100.
- the surfactants according to the invention are classifiable as readily biodegradable according to the OECD 301 guidelines.
- the additives can also contain foam stabilisers able to increase the half-lives of the foams generated.
- the stabilisers can be biopolymers.
- biopolymers refers to polymers degradable due to the effect of micro-organisms such as bacteria, fungi or seaweed. They are mainly water-soluble polysaccharides able to increase the viscosity of an aqueous system in a pH range between 4 and 12.
- the preferred biopolymers are xanthan gum and guar gum.
- the additives are characterised by a lower ecotoxicological impact than the products commercially available and used in mechanised excavations.
- the foaming additive can also contain other compounds useful to deal with specific problems such as clogging due to clayey soils, to prevent high consumption of the cutters fitted in the cutterhead, or to reduce the quantity of soluble salts in the water present in the excavation soil.
- Column A shows the composition by weight expressed as a percentage of the formulation
- column B shows the weight percentage of the single compound as a percentage of the active content.
- the stability of the foam generated by an aqueous solution prepared by adding 2% by weight of foaming additive to 5000 g of water is evaluated.
- the stability is expressed as the half-life, which indicates the time required for the weight of the foam to halve.
- the test is conducted by evaluating the time in which water amounting to half the weight/volume of the foam is released in a 250 ml cylinder.
- the foam is formed by a generator that conveys the flow of liquid at a constant airflow into a glass ball mixer.
- Example 2 Conditioning Capacity of the Additives of Example 1
- the conditioning capacity of the additives of Example 1 was evaluated with a stabilised soil called “Vitali” (particle size 0.075-25 mm).
- the foam used to condition the matrix is generated from an aqueous solution prepared by adding 2% by weight of foaming additive to 5000 g of water.
- the foam is formed by a generator that conveys the flow of liquid at a constant airflow into a glass ball mixer.
- the evaluation involves adding the foams generated with the additives to three 11 kg samples of aggregate, and homogenising the mixture in an IMER 5140 cement mixer (drum capacity 138 lt) for 5 minutes.
- the matrix conditioning is scored as a slump class.
- Table 3 The results are set out in Table 3:
- Example 3 Composition of Alcohol-Free Additive Having a Lower Degree of Ethoxylation (Present in Commercial Additives)
- Sample no. 4 was formulated without straight Cl 2-C14 alcohol ethoxylate (2-3 moles of ethylene oxide) and sodium sulphate.
- the stability of the foam generated by an aqueous solution prepared by adding 2% by weight of foaming additive to 5000 g of water is evaluated.
- the stability is expressed as the half-life, which indicates the time required for the weight of the foam to halve.
- the test is conducted by evaluating the time in which water amounting to half the weight/volume of the foam is released in a 250 ml cylinder.
- the foam is formed by a generator using a constant airflow.
- the data demonstrate an increase in the stability of the foam.
- the foaming additives have the following compositions:
- Sample no. 7 was formulated without straight C12-C14 alcohol ethoxylate (2-3 moles of ethylene oxide) and sodium sulphate, which is always present as foam generator in commercial products.
- the stability of the foam generated by an aqueous solution prepared by adding 2% by weight of foaming additive to 5000 g of water is evaluated.
- the stability is expressed as the half-life, which indicates the time required for the weight of the foam to halve.
- the test is conducted by evaluating the time in which water amounting to half the weight/volume of the foam is released in a 250 ml cylinder.
- the foam is formed by a generator using a constant airflow.
- Example 6 Aquatic Toxicity of an Additive of Example 1 by Comparison with a Commercial Additive
- Example 7 Aquatic Toxicity of the Additives of Example 1 by Comparison with a Commercial Additive
- Example 8 Acute Toxicity in Fish of the Additive of Example 3
- Example 9 Acute Toxicity in Fish of the Additive of Example 4
- the foaming additives called “Polyfoamer ECO 100” and “sample 7” were evaluated to establish their acute toxicity in fish (OECD 203).
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Excavating Of Shafts Or Tunnels (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT102018000007438A IT201800007438A1 (it) | 2018-07-23 | 2018-07-23 | Additivo schiumogeno a basso impatto ecotossicologico per il condizionamento del terreno in presenza di scavo meccanizzato |
IT102018000007438 | 2018-07-23 | ||
PCT/IB2019/056273 WO2020021445A1 (fr) | 2018-07-23 | 2019-07-23 | Additif moussant à faible impact écotoxicologique pour le conditionnement du sol en présence d'une excavation mécanisée |
Publications (2)
Publication Number | Publication Date |
---|---|
US20210269718A1 US20210269718A1 (en) | 2021-09-02 |
US11697768B2 true US11697768B2 (en) | 2023-07-11 |
Family
ID=63896519
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US17/262,389 Active 2040-01-08 US11697768B2 (en) | 2018-07-23 | 2019-07-23 | Foaming additive with low ecotoxicological impact for soil conditioning in the presence of mechanised excavation |
Country Status (11)
Country | Link |
---|---|
US (1) | US11697768B2 (fr) |
EP (1) | EP3827066B1 (fr) |
AU (1) | AU2019308812A1 (fr) |
CA (1) | CA3107241A1 (fr) |
DK (1) | DK3827066T3 (fr) |
ES (1) | ES2977190T3 (fr) |
IT (1) | IT201800007438A1 (fr) |
PL (1) | PL3827066T3 (fr) |
PT (1) | PT3827066T (fr) |
SG (1) | SG11202100497YA (fr) |
WO (1) | WO2020021445A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114320327A (zh) * | 2022-01-18 | 2022-04-12 | 中国铁建重工集团股份有限公司 | 一种多地质隧道掘进装备及其施工方法 |
Citations (7)
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WO1994014918A1 (fr) * | 1992-12-28 | 1994-07-07 | Henkel Kommanditgesellschaft Auf Aktien | Preparations aqueuses coulantes pouvant etre pompees, dirigees de maniere rheologique pour servir par exemple de boues de forage a base d'eau |
US20160022557A1 (en) * | 2012-06-15 | 2016-01-28 | Lubrizol Advanced Materials, Inc. | Alkyl Glycoside-Based Micellar Thickeners For Surfactant Systems |
CN106433679A (zh) | 2016-10-10 | 2017-02-22 | 中昊(大连)化工研究设计院有限公司 | 耐酸性盾构泡沫剂 |
WO2017108382A1 (fr) | 2015-12-21 | 2017-06-29 | Mapei S.P.A. | Additif porogène pour conditionner le sol en présence d'une excavation mécanisée pour la construction d'un tunnel |
CN108138087A (zh) * | 2015-10-28 | 2018-06-08 | 艺康美国股份有限公司 | 使用去污聚合物的方法 |
US20190144794A1 (en) * | 2017-11-13 | 2019-05-16 | The Procter & Gamble Company | Method of cleaning a surface having soil comprising fatty acid and consumer product composition therefor |
US20210171365A1 (en) * | 2017-12-08 | 2021-06-10 | Eminus, Llc | Enchanced system and method for treatment of soil and groundwater contaminated with pfas |
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WO2001023703A1 (fr) * | 1999-09-24 | 2001-04-05 | Akzo Nobel N.V. | Procede d'amelioration de la permeabilite d'une formation souterraine renfermant du petrole |
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Also Published As
Publication number | Publication date |
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PT3827066T (pt) | 2024-04-11 |
CA3107241A1 (fr) | 2020-01-30 |
EP3827066A1 (fr) | 2021-06-02 |
DK3827066T3 (da) | 2024-03-04 |
PL3827066T3 (pl) | 2024-05-27 |
US20210269718A1 (en) | 2021-09-02 |
SG11202100497YA (en) | 2021-02-25 |
IT201800007438A1 (it) | 2020-01-23 |
WO2020021445A1 (fr) | 2020-01-30 |
ES2977190T3 (es) | 2024-08-20 |
EP3827066B1 (fr) | 2024-02-07 |
AU2019308812A1 (en) | 2021-03-18 |
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