US1131859A - Electrolytic apparatus. - Google Patents
Electrolytic apparatus. Download PDFInfo
- Publication number
- US1131859A US1131859A US8616?314A US1131859DA US1131859A US 1131859 A US1131859 A US 1131859A US 1131859D A US1131859D A US 1131859DA US 1131859 A US1131859 A US 1131859A
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- United States
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- plates
- electrode
- bell
- casing
- conductor
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
Definitions
- T all w/iom 2'17 may concern Be it known that l, CLIFTON A. PARKS, a citizen ofthe United States of America, and a resident of Chicago, county of (look, and State of Illinois, have invented certain new and useful lrnprovements vin. Electrolytic Apparatus, of Which thefollowing is a specification.
- the main objects of this invention are to provide an improved form of electrolytic apparatus suitable for use in decomposing products by. electricity; to provide an improved apparatus of this kind particularly adapted for use in the commercial production. of hydrogen and oxygen by the decorposition of water; and to provide an improved construction and arrangementof the electrodes so as to facilitate the decomposition of the electrolyte and the collection of the products which are. liberated thereby.
- FIG. 1 is a perspective View of the improved electrolytic apparatus, a part thereof being broken away and shown in section so as to more clearly illustrate the construc tion thereof.
- Fig. 2 is an enlarged sectional detail of the terminal binding post.
- Fig, 3 is an enlarged transverse sectional detail of one of the conductor plates and baille plates attached.
- Fig. l is an enlarged end View of the electrode proper removed from the easing,
- Fig. 5 is a detail view in elevation of one of the supports, for the electrode plates.
- Fig. 6 is a plan View partly sectional of the complete electrode with the hell or top of the casing removed
- the apparatus comprises a casing or housing 1, within which are suspended the terminal posts 2, to which the conductor plates 3, of the electrode, are attached.
- the casing is made up of a bell l, having depending flanges 5 extending around the edges thereof, and end members 6 having inwardly disposed flanges 7 along the Vertical edges thereof and forming channel members.
- the end members 6 are secured together at their lower ends by bars 8 and have their upper ends received *ithin the flanges of the bell l.
- the casing parts are preferablyinetal stampings and their arrangement as shown in Fig. 1 provides open ,sides and bottom through which the electrdde proper is exposed.
- lnsulating battle 152 preterably made of hard rubber, are secured to the plates 3 so to extend beyond the sides and ends thereof, as shown in Figs. at and 6.
- the hafile plates 12 are secured to the respective conductor plates 3 at intervals along their length by means of screws 13, with spacing blocks 14; located between the plates so as to the, cnductor plates and the barlle plates apart and allow gases arising from ti e top of the plates 3 to be deflected in to the space
- the angularity and spacing of thef cs 3 are such that the screws 13 co. vc liently accessible for attaching or removing the .ha'ille plates 12-. Since the battle plates extend beyond the ends and sides or the conductor plates, they engage the end members 6 and support the electrode proper centrally in the casingout oil contact with all parts thereoi".
- the post 2 to which the source of elec trinity connected, has the stud 10 extendgular cross-section and have,
- A. bus bar or terminal member 20 is attached to the stud l0 and secured against dislodginent by means of a knurled nut 21.
- a pipe is provided for drawing oil the gases as they accumulate in the bell t and directing thorn 'i o a reservoir (not shown).
- a pipe or elbow 27 is supported on one of the end flanges 5 of the bell a (as shown in Fig. 1) and communicates with the interior of the bell.
- This pipe has its outlet a short distance above the lower edges of the flanges 5 -and in case the gas is liberated faster than it is taken away, the overflow will occur through the outlet of the pipe 27 instead of bubbling out around the edges of the flanges 5.
- a plurality of devices as shown in Fig. l are arranged closely together side by side with their open sides opposed, and immersed in a tank containing the electrolyte, such as di tilled water, rendered slightly acid or alnaline to increase its conductivity.
- Alternate electrodes are respectively connected to the positive and negative terminals of the source of electricity. When the electrodes are charged, the current passes through the electrolyte from the plates 3 on one electrode'to-the plates 3 on the adjacent electrode. As is well known, the electrolyte is thereby decomposed into its elements, hydrogen being liberated at the negative plates and oxygen at the positive plates.
- An electrode comprising a support, a plurality of conductor plates attached to said support one above another and inclined upwardly, and battle plates of insulating material attached to said conductor plates and extending beyond the edges there-oi.
- An electrode comprising a support, a
- Electrode comprising a support, a plurality of conductor plates attached to said support one above another and inclined upwardly, batlle plates of insulating material attached to said conductor plates and extending beyond the edges thereof, channel members embracing the ends of said conductor plates and being spaced away from the ends and sides thereof by said baftle plates, and a gas collecting bell located over the top of said plates and resting on said channel members.
- An electrode comprising a pair of vertically disposed supports, a plurality of conductor plates extending from one to the other oi said supports and attached thereto on opposite sides thereof, said plates being inclined inwardly and upwardly and providing a space between their inner edges, channel members embracing the ends of said plates, insulating means attached to said conductor plates and engaging said channel members so as to space said conductor plates away thereirou'i, a gas collecting bell located above said plates and resting on said channel members. and means connecting said supports to said bell.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Description
O. A. PARKS. ELECTROLYTIC APPARATUS.
' APPLICATION FILED SEPT. 14. 1914. 11,1 31 859 Patented Mar. 16, 1915.
2 SHEETSSHEET l.
I 1 5111 15125. U2 RE I [120622 to 0. A. PARKS. ELECTROLYTIC APPARATUS.
APPLICATION FILED SEPT. 14. 1914.
Patented Mar. 16, 1915.
2 SHEETS-SHIU1IJ 2.
r b p t v v m r F l I I. I F l I b wz'ineaqea;
Specification of Letters .Qatent.
insists.
Application filed September '34, 331.4%.
T all w/iom 2'17 may concern Be it known that l, CLIFTON A. PARKS, a citizen ofthe United States of America, and a resident of Chicago, county of (look, and State of Illinois, have invented certain new and useful lrnprovements vin. Electrolytic Apparatus, of Which thefollowing is a specification.
The main objects of this invention are to provide an improved form of electrolytic apparatus suitable for use in decomposing products by. electricity; to provide an improved apparatus of this kind particularly adapted for use in the commercial production. of hydrogen and oxygen by the decorposition of water; and to provide an improved construction and arrangementof the electrodes so as to facilitate the decomposition of the electrolyte and the collection of the products which are. liberated thereby.
An illustrative embodiment of this invention is shown in the accompanying drawing in which Figure 1 is a perspective View of the improved electrolytic apparatus, a part thereof being broken away and shown in section so as to more clearly illustrate the construc tion thereof. Fig. 2 is an enlarged sectional detail of the terminal binding post. Fig, 3 is an enlarged transverse sectional detail of one of the conductor plates and baille plates attached. Fig. l: is an enlarged end View of the electrode proper removed from the easing, Fig. 5 is a detail view in elevation of one of the supports, for the electrode plates. Fig. 6 is a plan View partly sectional of the complete electrode with the hell or top of the casing removed In the construction shown in the drawings, the apparatus comprises a casing or housing 1, within which are suspended the terminal posts 2, to which the conductor plates 3, of the electrode, are attached.
The casing is made up of a bell l, having depending flanges 5 extending around the edges thereof, and end members 6 having inwardly disposed flanges 7 along the Vertical edges thereof and forming channel members. The end members 6 are secured together at their lower ends by bars 8 and have their upper ends received *ithin the flanges of the bell l. The casing parts are preferablyinetal stampings and their arrangement as shown in Fig. 1 provides open ,sides and bottom through which the electrdde proper is exposed.
. .r a W M "n e i w i tell haul-l" no, striatnciial. Mo. 8 1,683.
are prefand have suitable plates 3 wrought iron and are secured to the ders 9 on the posts preferably by w the plates on, each side being arranged. in substantially parallel relation and spaced apart the thickness supports Bf so u to provide a. vertically disposed. open soace ll 6) between the liner edges of plates. lnsulating battle 152 preterably made of hard rubber, are secured to the plates 3 so to extend beyond the sides and ends thereof, as shown in Figs. at and 6. The hafile plates 12 are secured to the respective conductor plates 3 at intervals along their length by means of screws 13, with spacing blocks 14; located between the plates so as to the, cnductor plates and the barlle plates apart and allow gases arising from ti e top of the plates 3 to be deflected in to the space The angularity and spacing of thef cs 3 are such that the screws 13 co. vc liently accessible for attaching or removing the .ha'ille plates 12-. Since the battle plates extend beyond the ends and sides or the conductor plates, they engage the end members 6 and support the electrode proper centrally in the casingout oil contact with all parts thereoi".
The post 2, to which the source of elec trinity connected, has the stud 10 extendgular cross-section and have,
iids 10 which extend supporting mg a considerable distance above the top.
of hell i, as shown in Fig. 2, and is electrically insulated "from the hell by means of a gasket or insulating washer 15 and an insulating tube 16, embracing the stud and incased n thin a tube or shell. 17 welded on the top 41;. A. nut 18 hearing on an insulating washer 19, firmly secures the post 2 in place. A. bus bar or terminal member 20 is attached to the stud l0 and secured against dislodginent by means of a knurled nut 21. A pipe is provided for drawing oil the gases as they accumulate in the bell t and directing thorn 'i o a reservoir (not shown). ided with suitable trap cylinder 22 secured to the bell 4: and having a pipe 23 extending up from below the bell into the interior of the cylinder above the water level. A bell 24, suspended from the top of the'cylinder 22, extends below the water level in the cylinder so as to provide a water seal. The support for the bell 2a is the pipe 26, which is closed at its lower end and provided with apertures 25, through which the gases enter the pipe 26 after pass ing through the liquid in the trap.
A pipe or elbow 27 is supported on one of the end flanges 5 of the bell a (as shown in Fig. 1) and communicates with the interior of the bell. This pipe has its outlet a short distance above the lower edges of the flanges 5 -and in case the gas is liberated faster than it is taken away, the overflow will occur through the outlet of the pipe 27 instead of bubbling out around the edges of the flanges 5.
When the apparatus herein shown is used, a plurality of devices as shown in Fig. l are arranged closely together side by side with their open sides opposed, and immersed in a tank containing the electrolyte, such as di tilled water, rendered slightly acid or alnaline to increase its conductivity. Alternate electrodes are respectively connected to the positive and negative terminals of the source of electricity. When the electrodes are charged, the current passes through the electrolyte from the plates 3 on one electrode'to-the plates 3 on the adjacent electrode. As is well known, the electrolyte is thereby decomposed into its elements, hydrogen being liberated at the negative plates and oxygen at the positive plates. As the bubbles of gases are liberated, they travel up the inclined parts of the plates 3 and 12 into the open space 11 and rise to the top of the casing l and into the pipes 23 from which they are conveyed to the storage reservoir. This arrangement of the conductor plates of the electrode also promotes the circulation of electrolyte, since the-latter is carried along by the gases rising between plates of electrodes, and thus maintains uniformity of density of electrolyte'and prevents the deposit on the plates of acid or alkaline salts present in the electrolyte.
Although but one specific embodiment of this invention has been herein shown and described, it will be understood that numerous details of the construction shown may be altered or omitted without departing from the spirit of this invention asdefined by the following claims 1. An electrode. comprising a support, a plurality of conductor plates attached to said support one above another and inclined upwardly, and battle plates of insulating material attached to said conductor plates and extending beyond the edges there-oi.
An electrode, comprising a support, a
plurality of conductor plates attached to said support one above another and inclined terial attached to said conductor plates and extending beyond the edges thereof, said baille plates overlapping said conductor plates and being spaced, away therefrom.
a. An electrode-comprising a support, a
plurality of plates attached to said support one above another and inclined upwardly, channel members embracing the ends of said plates, and a gas collecting bell located over the top of said plates and resting on said channel members.
5.-An electrode comprising a support, a plurality of conductor plates attached to said support one above another and inclined upwardly, batlle plates of insulating material attached to said conductor plates and extending beyond the edges thereof, channel members embracing the ends of said conductor plates and being spaced away from the ends and sides thereof by said baftle plates, and a gas collecting bell located over the top of said plates and resting on said channel members.
6. An electrode comprising a pair of vertically disposed supports, a plurality of conductor plates extending from one to the other oi said supports and attached thereto on opposite sides thereof, said plates being inclined inwardly and upwardly and providing a space between their inner edges, channel members embracing the ends of said plates, insulating means attached to said conductor plates and engaging said channel members so as to space said conductor plates away thereirou'i, a gas collecting bell located above said plates and resting on said channel members. and means connecting said supports to said bell.
7. in an electrolytic apparatus, the com bination of a casing; open at two sides, a terminal post suspended within'said casing, conductor plates extendinglongitudinally of said casing and secured to said post at opposite sides thereofisaid plates being arranged one above another and inclined inwardly and upwardly and providing a space between their inner edges.
8. in an electrolytic apparatus, the combination of a casing open at two sides, a terminal. post suspended "within said casing, conductor plates extending longitudinally of said casing and secured to said post at opposite sides thereof, said plates being arranged one above another and inclined inupwardly, and baille plates of insulating magetfllweelli their mngr edges, an? insulating tember 1914. v
a e p ates secure to said con iictor plates and extending beyond the edges and ends CLIFTON PARKS 5 thereof and engaging said casing so as to Witnesses: i
support said conductor-plates out of contact EUGENE A. RUMMLER, therewith. M. IRENE HU'rcHINGs.
wardly and upwardly and providing aspace Signed at Chicago this 12th day of Sep-
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3855104A (en) * | 1972-03-21 | 1974-12-17 | Oronzio De Nora Impianti | PROCESS AND APPARATUS FOR THE ELECTROLYSIS OF HCl CONTAINING SOLUTIONS WITH GRAPHITE ELECTRODES WHICH KEEP THE CHLORINE AND HYDROGEN GASES SEPARATE |
US3945908A (en) * | 1974-06-20 | 1976-03-23 | Hooker Chemicals & Plastics Corporation | Liquid seal for chlorine headers |
US8671985B2 (en) | 2011-10-27 | 2014-03-18 | Pentair Residential Filtration, Llc | Control valve assembly |
US8961770B2 (en) | 2011-10-27 | 2015-02-24 | Pentair Residential Filtration, Llc | Controller and method of operation of a capacitive deionization system |
US9010361B2 (en) | 2011-10-27 | 2015-04-21 | Pentair Residential Filtration, Llc | Control valve assembly |
US9637397B2 (en) | 2011-10-27 | 2017-05-02 | Pentair Residential Filtration, Llc | Ion removal using a capacitive deionization system |
US9695070B2 (en) | 2011-10-27 | 2017-07-04 | Pentair Residential Filtration, Llc | Regeneration of a capacitive deionization system |
-
0
- US US8616?314A patent/US1131859A/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3855104A (en) * | 1972-03-21 | 1974-12-17 | Oronzio De Nora Impianti | PROCESS AND APPARATUS FOR THE ELECTROLYSIS OF HCl CONTAINING SOLUTIONS WITH GRAPHITE ELECTRODES WHICH KEEP THE CHLORINE AND HYDROGEN GASES SEPARATE |
US3945908A (en) * | 1974-06-20 | 1976-03-23 | Hooker Chemicals & Plastics Corporation | Liquid seal for chlorine headers |
US8671985B2 (en) | 2011-10-27 | 2014-03-18 | Pentair Residential Filtration, Llc | Control valve assembly |
US8961770B2 (en) | 2011-10-27 | 2015-02-24 | Pentair Residential Filtration, Llc | Controller and method of operation of a capacitive deionization system |
US9010361B2 (en) | 2011-10-27 | 2015-04-21 | Pentair Residential Filtration, Llc | Control valve assembly |
US9637397B2 (en) | 2011-10-27 | 2017-05-02 | Pentair Residential Filtration, Llc | Ion removal using a capacitive deionization system |
US9695070B2 (en) | 2011-10-27 | 2017-07-04 | Pentair Residential Filtration, Llc | Regeneration of a capacitive deionization system |
US9903485B2 (en) | 2011-10-27 | 2018-02-27 | Pentair Residential Filtration, Llc | Control valve assembly |
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