US11205A - Improvement in kerosene burning-fluids - Google Patents

Description

' UNITED STATES- PATE T OFFICE.

ABRAHAM GESNER, OF VVILLIAMSBIIBG, NEW YORK, ASSIGNOR TO THE ASPHALT MINING AND KEROSENE GAS COMPANY.

IMPROVEMENT IN KEROSENEBURNING-FLUIDS.

Specification forming part of Letters Patent No. 1|,205, dated June .27, 1854.

T 0 all whom it may concern:

Be it known that I, ABRAHAM GESNER, late of the city and county of New York, now of I Williamsburg, in the county of Kings and State of New York, have invented or discovered a new and useful manufacture or composition of matter, being a new liquid hyd roearbon, which I denominate Kerosene, and which may be. used for illuminating and other purposes, of which the following is a specification.

I obtain this productfrom petroleum, maltha, or soft mineral pitch, asphaltum, or bitumen, wherever found, by dry distillation and subsequent treatment with powerful reagents and redistillation.

This process, which will presently be described, yields kerosene of three different qualities or proofs, each of which, in my opinion, is a mixture in certain proportions of a spirituous',1ight, and highly volatile and intlam niable liquid, with an oily, heavy, and less volatile and inflammable liquid. 1 have not succeeded in completely separating these liquids in the manufacture, and I see no practically-useful object tobegained by doing so. Neither have I ascertained the exact proportions in which the two liquids are mixed; but I suppose the lightest fluid, which I denominate A kerosene, tobe composed of two parts, by measure or equivalent proportions, of the heavy and eight parts of the light fluid. Its specific gravity is .750, water being 1, and it boils at 150 Fahrenheit. It is not a solvent of such gums as I have tried to dissolve in it, among which Iinay mention india-rubber. Sixty-five parts, by measure, ofalcohol ofspeciflc gravity .844, at a temperature of 60 Fahrenheit, will dissolve thirty-five parts, by measure, of this liquid. By itself the A kerosone is highly volatile and inflammable, so much so that even in cold. winter weather a good light is produced.

by forcing a current of atmospheric air through it, circulating the same in it in jets like gas.

The second or medium-proof fluid Icall B kerosene, and suppose it to be composed of four parts or equivalentsot the heavy and six of the light fluid. Its specific gravity is pipes, and burning @no and its boiling-point 250 Fahrenheit. It is not a solvent of gums, but will soften them very slightly. Seventy-five parts of alcohol ot' specific gravity .844, ata temperature of 00 Fahrenheit, will dissolve twenty. five parts of this liquid. By itself the B kerosene is moderately "olatile and inflammable, but will not, likethe A,'" yield a good light by having a current of air passed through it and burned.

The third or low-proof fluidlcall' U kerosene, and suppose it to be composed of silt parts or equivalentsof the heavy and four of the light liquid. Unlike the A and B, the heavy liquid preponderates in and gives character to the O kerosene. Its specific gravity is .800 and its boiling-point is 3509 Fahrenheit. Unlike A and B, it is not soluble in alcohol, but it is a good solventof gums, as india-rubber dissolves in it readily.

It is not very volatile or inflammable; but in an Argand lamp, wit-ha button over the wick, it burns with a brilliant white light without smoke or the napthalous odor so offensive in many hydrocarbons having some resemblance to this, but possessing very different properties. As burning-fluids for the purposeot artificial illumination these are highly useful and economical, either separately, mixed together, or A and B mixed with alcohol. The O kerosene has also proved very good as a lubricant for machinery where it has been tried; but, being a new thing, the kerosene doubtless has very numerous uses besides its adaptation to illumination and lubrication that will soon bediscovered after it is manufactured on the large scale and put into market as an article of trade. Moreover, as the rocks whence the kerosene is most abundantly obtained are widely disseminated, and the deposits of them are of almost unlimited extent, an immense mass of hitherto useless matter will by meaghs of this invention be rendered available for the uses of mankind as a cheap and convenient substitute for illuminating purposes for the oils and fats which are yearly increasing in scarcity and value.

Theprocess and apparatus Iem ploy in prod uc ing the kerosene I will now proceed to describe, premising that I do not confine myself to any particular form or arrangement of apparatus,

but intend to use whatever may prove most convenient in any given case.

The first part of the'process consists in submitting the raw material to dry distillation at the lowest temperature at which the kerosene will volatilize, care being taken not to raise the temperature so long as tolerably-rapid evaporation continues, and the heat must not in any case be raised above 800 Fahrenheit, as the heat, if raised to the slightest perceptible red in daylight, would be so high as to defeat the whole object of the process, for a greatly-increased production of gas would take place and the liquid product would be-naptha instead of kerosene. Whatever gas may be generated I employ for illuminating purposes in the ordinary manner, and also as fuel for heating the still. For this dry distillation I have used large cast-iron retorts, set in suitable furnaces for the evaporation and metal pipes or chambers surrounded by water for the condensation of the vapor. The liquid products of this-distillation are heavy tar and water or ammoniacal liquor, which lie-at the bottom of the receiver, and alighter liquid, which floats above them. The heavyliquids and the light are separated by drawing 01f one or the other into another vessel by means of a cock, siphon, or otherwise. The heavy liquids may be utili zed or disposed of advantageously; but they have no further connection with this process,

andtherefore I shall not here describe the modem which I propose to utilize them. The light liquid is then submitted to rcdistillation at the lowest possible heat in a common still and condenser. The product of this redistillation is a light volatile liquid, which accumulates in the receiver, and aheavy tarry residuum left in the still, and which may be added to the heavy liquid impurities of the first distillate." The light liquid is transferred from the receiver to a suitable vessel or vat, and mixed thoroughly with from five to ten percent. of strong sulphuric, nitric, or muriatic acid, accordingtothequantit-yof tarpresent. Seven per cent. is about the average quantity required; but any quantity is useful. I have enumerated three acids; but I give the preference to sulphuric, although either of the others'will answer very well. I also mix with the liquid from one to three per cent. of peroxide of manganese, according to the turbidness of the liquid, about two per cent. being the average quantity required. It has the effect of facilitating greatly the precipitation of certain of the impurities which the liquid contains; but although useful 'I do not deem it essential. After these substances have been thoroughly mixed with' the liquid by agitation it is al-' lowed to stand from twelve ,to twcnty four' hdurswithout being disturbed, in order that The clear super-' the impurities may subside. natant liquid is now separated from the impurities, both solid and liquid, that have settled to the bottom of the tank, by drawing oft either the one or the other into a separate vessel. I next mix the distillate with about two per cent., by weight, of powdered and freshly-calcined lime. The latter by its powerful affinity for water will absorb it thoroughly from the liquid hydrocarbon, which always at this stage of the process contains water in a greater or less quantity. Lime by its alkaline properties will also neutralize any acid in the liquid. After the lime has been thoroughly mixed with the liquid by stirring, the mixture is again distilled, care being taken to raise the heat gradually and slowly to about 160 Fahrenheit, where it is kept by regulating the damper until all the vaporhas passed over the receiver that the liquid will yield at this temperature. This product or distillate is the A kerosene, and is drawn off from the receiver into an appropriate vessel. The heat is now raised by again drawing the damper to about 260 Fahrenheit, when vapors will again rise and be condensed'in the receiver. As soon as the distillate'ceases to flow at this temperature it is drawn off from the receiver into a separate vessel, and itconstitntes, the B kerosene. The heat of the still is now raised to about 360 Fahrenheit, when vapors will again rise and condense in the receiver. As soon as the distillate ceases to run at this temperature the processis cor'rr' pleteL This last product is the O 'kerosene.

The quantity of lime I have mentioned is the quantity I have found sufficient in all cases; but any quantity less than tenper cent. would be useful. The lime as an alkali appears to exert a specific influence or effect which is indispensable to the good quality of the product. Neither soda nor potash can produce this effect in any form in whichI have tried them, and I have made numerous and special efforts to replace the lime with these alkalies.

To deprive the liquid of water by freshlycalcined lime is important, because, as I have discovered, water is highly injurious to the process and product, even in very small quantities, as it causes carholic acid to pass over siblc effect upon the quality or character of the product, as no evaporation takes place-at a temperature below that at which the-first distillation'begins, or between the first and second, or second and third distillations, and

a thermometer is not used for the purpose of regulating the temperature, as the observatheliquidhydrocarbon herein described,which tion and judgment of a skillful workman are I I denominate B kerosene.

sufficient. 4 In testimony whereof I have hereunto sub- Having claimed under separate specificascribed myname. V tions the A and O kerosenesg in this I ABRAHAM GESNER. c1aim Witnesses:

As a new manufacture or composition of F. G. DE FONTAINE, matter for illuminating and other purposes, HORATIO EAGLE.