US107490A - Improvement in the preparation of composition for pavements - Google Patents
Improvement in the preparation of composition for pavements Download PDFInfo
- Publication number
- US107490A US107490A US107490DA US107490A US 107490 A US107490 A US 107490A US 107490D A US107490D A US 107490DA US 107490 A US107490 A US 107490A
- Authority
- US
- United States
- Prior art keywords
- bitumen
- tar
- asphalt
- coal
- calcareous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 14
- 239000010426 asphalt Substances 0.000 description 86
- 229940108066 Coal Tar Drugs 0.000 description 26
- 239000011280 coal tar Substances 0.000 description 26
- 229910052500 inorganic mineral Inorganic materials 0.000 description 18
- 239000011707 mineral Substances 0.000 description 18
- 239000011269 tar Substances 0.000 description 18
- 238000004821 distillation Methods 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000004576 sand Substances 0.000 description 10
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- 241001465754 Metazoa Species 0.000 description 6
- 235000015450 Tilia cordata Nutrition 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 230000000717 retained Effects 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 206010022114 Injury Diseases 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000010438 granite Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-N nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000011505 plaster Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- 229960002126 Creosote Drugs 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- 235000006173 Larrea tridentata Nutrition 0.000 description 2
- 240000007588 Larrea tridentata Species 0.000 description 2
- 229940068124 Pine tar Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002802 bituminous coal Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003818 cinder Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000011286 gas tar Substances 0.000 description 2
- -1 gravel Substances 0.000 description 2
- 239000011396 hydraulic cement Substances 0.000 description 2
- 230000000266 injurious Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000005445 natural product Substances 0.000 description 2
- 239000011297 pine tar Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000011276 wood tar Substances 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C1/00—Working-up tar
- C10C1/04—Working-up tar by distillation
Definitions
- Bitumen combined with earthy matter not calcareous makes an impure asphalt; in fact, the bitumen or pitch remains as such, because no chemical combination takes place other than with calcareous substances.
- This condition is found in the pitch lake on the island of Trinidad, improperly called by some persons Trinidad asphalt, but where bitumen is found combined with a calcareous earth we find the true asphalt, which, in the language of Professor Ure, forms a compact semi-elastic solid which is not liable to injury by the greatest alternation of frost and thaw, which often disintegrate in a few years the hardest stone, nor can it be ground to dust and worn away by the attrition of the feet of men and animals, as sandstones, flags, and even granite, are.
- coal-tar is a very complex compound, containing a dozen or more organic-elements, the products of vegetable decay, which being distilled off by gradual elevations of heat, there is left behind a solid pitchy or bituminous substance identical with the bitumen in mineral asphalt.
- the protean elements in coal-tar for mechanical and other purposes is an accomplished fact inoperative chemistry; but in doing so the valuable residuum or bitumen is injured to the extent as to make it wholly unserviceable for the durable purpose required for pavements.
- this bitumen in a pure state, and uninjured by the processes used to distill off the many compounds in coal-tar, and which are not essential, but absolutely injurious for paving purposes if retained, is the object of my invention.
- the vessel or retort in which is placed the coal-tar to be distilled off is wholly surrounded and embedded in a sand-bath, in order that no injury may occur by charring (through the direct contact of fire and heat) to the bitumen composing the solid part of the tar.
- the heat of dis tillation is then run up to a few degrees short of the point when the carbolic acid or creosote of coal-tar is eliminated-say 375 Fahrenheitand no higher degree of heat applied, in order that the carbolic acid and other fixed elements in the tar may be retained in the bitumen.
- Bitumen only requires a calcareous earth to unite chemically with it to render it durable and solid for paving purposes, and the addition of sand, gravel, ashes, cinders, stones, hydraulic cement, lime, uncombined, or any other substances, only tends to destroy the integrity and tenacity of the compound, while the materials themselves are convertible into impalpable powders, to annoy all who travel upon them.
- the bitumen prepared as I have described is mixed, when melted and hot, with the calcareous sand or earth previously warmed over a gentle fire. In localities where calcareous earth is inaccessible, it may be artificially made by adding lime or plaster to very fine sand, in the proportion of one part of plaster or lime to ten parts of the finest earth-sand that can be procured.
- bitumen or pitch from wood or pine tar is so unlike in chemical nature with the bitumens of the mineral asphalts and coal-tar, and withal so brittle and made up of so many volatile and pungently odorous particles, that I deem the use of this kind of tar impracticable.
- a street-pavement laid with this kind of tar either in its crude condition or after the lighter particles have been extracted by distillation, cannot, from the nature of the material, be durable.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Working-Up Tar And Pitch (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Description
UNITED STATES PATENT OFFICE.
JOSHUA R. HAYES, OF NEW YORK, N. Y.
IMPROVEMENT IN THE PREPARATION OF COMPOSITION FOR PAVEMENTS.
Specification forming part of Letters Patent No. 107,490, dated September 20, 1870.
To all whom it may concern:
Be it known that I, JOSHUA R. HAYES, M. D., of New York, in the county of New York and State of New York, have invented certain new and useful Improvements in Making Asphalt Pavements; and do hereby declare that the following is a full, clear, and exact description thereof.
In making my improved asphaltic compound for paving streets, sidewalks, &c., I keep in view the chemical affinity that exists between bitumen and calcareous matter-a combination found in nature and known under the name of mineral asphalt. This natural substance is not found in sufficient quantities over the surface of the earth to make it a practicable thing for paving purposes in all localities, when brought into competition, as to cost, with stone and wood. Hence, asphalt pavements are used only in France, Switzerland, and a few other countries contiguous to the natural deposits of mineral asphalt. Chemically, this native mineral asphalt is bitumen or pitch in combination with earthy material. Of the latter material, calcareous earth, by reason of its natural affinity for bitumen, if not in excess, gives to the asphalt mineral its valuable and durable characteristics for paving purposes. For this reason the Val de Travers asphalt, found near Paris, in France, is superior to that found elsewhere, as in Trinidad, &c. v
Bitumen combined with earthy matter not calcareous makes an impure asphalt; in fact, the bitumen or pitch remains as such, because no chemical combination takes place other than with calcareous substances. This condition is found in the pitch lake on the island of Trinidad, improperly called by some persons Trinidad asphalt, but where bitumen is found combined with a calcareous earth we find the true asphalt, which, in the language of Professor Ure, forms a compact semi-elastic solid which is not liable to injury by the greatest alternation of frost and thaw, which often disintegrate in a few years the hardest stone, nor can it be ground to dust and worn away by the attrition of the feet of men and animals, as sandstones, flags, and even granite, are.
The received opinion among geologists is,that the bitumen or pitch (forming the true asphalt when in combination witha calcareous earth) is the product of vegetable matter in decay, which, under other circumstances, would have been changed into bituminous coal. The conceded knowledge of this fact forms the basis of my invention, as relates to the formation of an improved asphaltic compound for paving and other purposes.
In distilling coal for its gases for illuminating purposes, a thick, viscid, and tenacious residuum, termed gas or coal far, is found. This coal-tar is a very complex compound, containing a dozen or more organic-elements, the products of vegetable decay, which being distilled off by gradual elevations of heat, there is left behind a solid pitchy or bituminous substance identical with the bitumen in mineral asphalt. -To eliminate successfully, under various degrees of heat, the protean elements in coal-tar for mechanical and other purposes is an accomplished fact inoperative chemistry; but in doing so the valuable residuum or bitumen is injured to the extent as to make it wholly unserviceable for the durable purpose required for pavements. To obtain from coal-tar this bitumen in a pure state, and uninjured by the processes used to distill off the many compounds in coal-tar, and which are not essential, but absolutely injurious for paving purposes if retained, is the object of my invention.
The vessel or retort in which is placed the coal-tar to be distilled off is wholly surrounded and embedded in a sand-bath, in order that no injury may occur by charring (through the direct contact of fire and heat) to the bitumen composing the solid part of the tar.
When a moderate degree of heatsay about 225 Fahrenheit-is applied so that the naphthas and other light volatile products are about passing over in distillation, I add to every fifty gallons of tar one-half gallon fuming nitrous acid previously heated to the boiling-point. This acid violently attacks the naphthas and all the lighter volatile elements in the tar, and, by decomposing and consuming them, facilitates the distillation, and at the same time tends to render inodorous (by thus destroying and decomposing the volatile elements) the remaining bitumen or pitch. The heat of dis tillation is then run up to a few degrees short of the point when the carbolic acid or creosote of coal-tar is eliminated-say 375 Fahrenheitand no higher degree of heat applied, in order that the carbolic acid and other fixed elements in the tar may be retained in the bitumen.
About sixty per cent. of all gas-tar is made up of this bitumen or pitch, the remaining forty per cent. composing the ammoniacal waters, naphthas, and other volatile and odorous agents that are not necessary to be kept in for paving purposes. If they are retained, or a pavement made with crude coal-tar is laid down, however hard it may become in the shade, it will, when under the influence of the rays of the sun, become spongy and viscous, and too soft and elastic for a durable pavement.
Having thus extracted the bitumen from coal-tar, which I conceive to be about the same chemically as the bitumen in the mineral asphalt, I combine it with calcareous earth in the proportion of eighty parts of the latter to twenty parts of the prepared bitumen, this being the proportion that exists in the combination composing the native mineral asphalt, and therefore make an artificial asphalt which, for durability, tenacity, elasticity, and solidity, equals the native mineral itself, and when laid down, even upon crowded thoroughfares, will not sufi'er abrasiona fact exemplified in Paris and elsewhere. Any calcareous earth or calcareous sand may be used for the union with the bitumen, care being taken to keep keep the percentage of each as above given.
The simplicity of this combination of only two substancesviz., the solid part or bitumen of coal-tar and any calcareous earthto form a durable pavement (in short, the production of an artificial asphalt by this union) cannot be overlooked or its value overestimated, in view of the fact that in making pavements in which tar enters in a crude or prepared state, sometimes as many as a dozen or more in gredients are added to absorb the tar and harden the compoun d for a time, and to be ground into an impalpable powder by attrition from the feet of men and animals after being laid down as a composite pavement. Bitumen only requires a calcareous earth to unite chemically with it to render it durable and solid for paving purposes, and the addition of sand, gravel, ashes, cinders, stones, hydraulic cement, lime, uncombined, or any other substances, only tends to destroy the integrity and tenacity of the compound, while the materials themselves are convertible into impalpable powders, to annoy all who travel upon them.
The bitumen prepared as I have described is mixed, when melted and hot, with the calcareous sand or earth previously warmed over a gentle fire. In localities where calcareous earth is inaccessible, it may be artificially made by adding lime or plaster to very fine sand, in the proportion of one part of plaster or lime to ten parts of the finest earth-sand that can be procured.
The bitumen or pitch from wood or pine tar is so unlike in chemical nature with the bitumens of the mineral asphalts and coal-tar, and withal so brittle and made up of so many volatile and pungently odorous particles, that I deem the use of this kind of tar impracticable. Besides, a street-pavement laid with this kind of tar, either in its crude condition or after the lighter particles have been extracted by distillation, cannot, from the nature of the material, be durable. Ooal-tars, however, manipu' lated in the manner I have described, so as to obtain only the solid or bituminous parts thereof, give us a material that is durable and so closely allied to the asphalt bitumens that it can be used in lieu thereof, and when combined with a substance having a natural affinity therefor-via, a calcareous earth-an art-iticial asphalt is the result, which, in the language of Professor Ure, is a compact semielastic solid, which will not disintegrate by the greatest alternation of frost and thaw, nor can it be ground to dust and worn away by the attrition of the feet of men and animals, as sandstones, flags, and even granite, are.
Having thus described my invention, what I claim as new, and desire to secure by Letters Patent, is
1. The application of a sand-bath to a retort containing coal-tar in distillation, so as to obtain therefrom, uninjured by extreme heat, the bitumen or pitch for paving purposes, the heat in distillation for this purpose not exceeding, as the highest point, 325 Fahrenheit, in the manner substantially as set forth.
2. The treatment, by means of the fuming nitrous acid of commerce, to decompose and consumethe volatile and odorous elements in the coal-tar during the process of distillation, in the manner and for the purpose substantially as set forth.
3. The product made by uniting chemically the bitumen or pitch thus prepared from coaltar with any calcareous earth, so as to form an artificial asphalt for paving purposes, in the manner substantially as set forth.
J. R. HAYES, M. D.
Witnesses:
Y D. H. STONE,
WM. W. BADGER.
J any;
Publications (1)
Publication Number | Publication Date |
---|---|
US107490A true US107490A (en) | 1870-09-20 |
Family
ID=2176964
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US107490D Expired - Lifetime US107490A (en) | Improvement in the preparation of composition for pavements |
Country Status (1)
Country | Link |
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US (1) | US107490A (en) |
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0
- US US107490D patent/US107490A/en not_active Expired - Lifetime
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