US10648661B2 - Coal nozzle assembly comprising two flow channels - Google Patents
Coal nozzle assembly comprising two flow channels Download PDFInfo
- Publication number
- US10648661B2 US10648661B2 US16/051,433 US201816051433A US10648661B2 US 10648661 B2 US10648661 B2 US 10648661B2 US 201816051433 A US201816051433 A US 201816051433A US 10648661 B2 US10648661 B2 US 10648661B2
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- US
- United States
- Prior art keywords
- nozzle
- coal
- assembly according
- nozzle assembly
- tips
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B31/00—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements or dispositions of combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
- F23C13/06—Apparatus in which combustion takes place in the presence of catalytic material in which non-catalytic combustion takes place in addition to catalytic combustion, e.g. downstream of a catalytic element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
- F23C13/08—Apparatus in which combustion takes place in the presence of catalytic material characterised by the catalytic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/02—Structural details of mounting
- F23C5/06—Provision for adjustment of burner position during operation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
- F23D2201/10—Nozzle tips
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
- F23D2201/10—Nozzle tips
- F23D2201/101—Nozzle tips tiltable
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2201/00—Burners adapted for particulate solid or pulverulent fuels
- F23D2201/20—Fuel flow guiding devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/00001—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas local catalytic coatings applied to burner surfaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/00003—Fuel or fuel-air mixtures flow distribution devices upstream of the outlet
Definitions
- This disclosure relates to a nozzle assembly for a steam generation apparatus for directing the flow of solid particles entrained in primary air into a combustor or furnace. It further relates to a steam generating system which comprises a furnace and at least one coal nozzle assembly.
- a solid fueled firing system burns powdered solid fuel, typically cowl, blown into a furnace in a stream of air.
- This furnace is typically a boiler that creates steam for various uses, such as creating electricity.
- the nozzle and the guide vanes are integrally formed for example by casting.
- the guide vanes are more or less parallel to each other resulting in a sub-optimal mixture of the partially aggregated coal particles and the primary air before exiting the nozzle and entering the furnace.
- the coal nozzle assembly comprises an elongated nozzle body having a nozzle tip at one end thereof; said nozzle tip comprising two channels each channel having a curved or buckled flow paths, the nozzle tip further comprising parting means separating the channels from each other, wherein the directions of the flow paths of the channels at their ends distal from the nozzle body enclose an angle greater than 0° and equal to or less than 90°.
- the coal nozzle assembly comprises an elongated nozzle body and an inner shell having two nozzle tips at one end thereof; the nozzle assembly further comprising parting means being located in the inner shell upstream of said two nozzle tips and splitting the flow from said nozzle body into the two nozzle tips, the directions of the flow paths of the two nozzle tips of the second embodiment enclosing an angle ⁇ greater than 0° and equal to or less than 90°.
- Both embodiments of the invention make use of a two-step approach.
- the first step takes place as the non-homogeneous stream of coal particles and primer), air exits the nozzle body and enters the nozzle tip.
- This stream is split into two partial streams inside the tip by parting means.
- two partial streams are redirected such that they will intersect and shear against one another upon exit, which is the second step.
- the exit faces through which the partial streams exit the nozzle tip encloses an angle greater than 90° and less than 180°. This shearing causes an external mixing of the two partial streams, helping to break up the coal stream resulting in a very efficient combustion and low emissions.
- the coal nozzle assemblies according to the invention generate a well-mixed and rather homogenous stream of coal and primary air by mixing the coal particles and the primary air in the furnace immediately before the combustion takes place, rather than solely relying on mixing inside the tip.
- the nozzle tips are being mounted for pivotal movement about an axis being orthogonal with respect to the longitudinal axis of the elongate body. In most cases this axis is horizontal.
- the nozzle body partially overlaps the nozzle tips.
- the plane walls and the bent walls of the claimed nozzle tip limit a rectangular cross section of the nozzle tip.
- the nozzle body may have rectangular or truncated pyramid longitudinal section, thus speeding up the velocity of the primary air and the coal particles before entering the nozzle tip.
- one or two shear bars may be fixed at each nozzle tip near the exit face.
- a perimeter of secondary air may surround the coal nozzle tip.
- each nozzle tip comprises a splitter plate extending between the two plane walls to direct the flow of air and coal particles.
- FIG. 1 A side view of a first embodiment of a nozzle body and a nozzle tip according to the invention (exploded view),
- FIG. 2 A side view of the outer housing surrounding the nozzle tip
- FIG. 3 A side view of the nozzle body, mounted nozzle tip end outer housing according to FIGS. 1 and 2 ,
- FIG. 4 A schematic cross section through a second embodiment of the claimed coal nozzle assembly
- FIG. 5 illustrating the flow of the coal and the primary air through the second embodiment according to FIG. 4 and
- FIG. 6 A perspective view of the second embodiment.
- FIG. 1 shows an exploded side view of a nozzle body 3 and a nozzle tip 5 according to the invention.
- the nozzle tip 5 has an axis symmetry 31 .
- the nozzle tip 5 of this embodiment is comprised of two parallel plane walls 7 , only one of them being visible in FIG. 1 .
- the nozzle tip 5 of this embodiment further comprises two curved or buckled walls 9 . These two pairs of walls 7 , 9 are the outer boundary or housing of the nozzle tip 5 . Inside this housing parting means 11 are located. The parting means 11 extend from one (plane) wall 7 to the other (plane) wall 7 . The parting means 11 are shaped so that a leading edge 12 splits the flow from the nozzle body 3 into two partial streams.
- the cross section of the channels 14 of this embodiment is rectangular (not visible in FIG. 1 ).
- flow path in conjunction with this invention has to be understood such that the main direction or the transport direction of the primary air and the coal is meant.
- local and/or temporary deviations of the flow of the primary air from the flow path may occur, for example due to turbulent flow of the primary air. These deviations do not have an influence on the direction of the flow path.
- the longitudinal axes 33 . 1 , 33 . 2 of the channels 14 . 1 , 14 . 2 are curved or buckled, too.
- the channels 14 . 1 , 14 . 2 are arranged symmetrically with regard to the axis of symmetry 31 of the nozzle tip 5 .
- the primary air and the coal particles flow through the nozzle body 3 and the channels 14 . 1 and 14 . 2 as illustrated by arrows.
- the air and coal particles exit the channels 14 . 1 , 14 . 2 via exit faces 13 . 1 and 13 . 2 .
- the cross section of the exit faces 13 . 1 , 13 . 2 of this embodiment is rectangular (not visible in FIG. 1 ).
- the longitudinal axes 33 . 1 , 33 . 2 at an end of the channels 14 . 1 , 14 . 2 distal from nozzle body 3 (and near the exit faces 13 . 1 and 13 . 2 ) enclose an angle ⁇ being greater than 0° and equal or less than 90°. In this particular embodiment the angle ⁇ is about 60°.
- the flow direction of the primary air when exiting the nozzle tip via the exit faces is perpendicular to the exit faces.
- the curved or buckled channels 14 . 1 , 14 . 2 direct the partial flows of the air and the coal particles such that they intersect and shear after having left the nozzle tip 5 just before they are combusted. This results in a more homogenous mixture of primary air and coal particles before and during combustion. Due to that the efficiency of the flame is improved and emissions are reduced.
- splitter plates may be arranged in the channels 14 . 1 , 14 . 2 near the exit faces 13 . 1 , 13 . 2 .
- FIG. 2 shows a side view of an outer housing or air housing 18 .
- the air housing 18 surrounds the nozzle body 3 and the nozzle tip 5 and is spaced from them. Combustion or secondary air is admitted to the region defined between the nozzle body 3 and the nozzle tip 5 on one side and the air housing 18 on the other side. In other words: a perimeter of secondary air surrounds the coal nozzle tip 5 .
- FIG. 3 shows an assembled first embodiment of the claimed nozzle tip. For reasons of clarity not all reference numerals are drawn.
- the nozzle tip 5 is pivotally connected to the air housing 18 by a pair of pivot members 16 , 20 .
- a pivot pin 16 is visible.
- the air housing 18 comprises a bearing 20 for the pivot pin 16 (c. f. FIG. 2 ).
- the pivot members 16 , 20 allow the nozzle tip 5 to be rotated or to be tilted about an axis (in most cases a horizontal axis) so that the fuel and combustion air can be directed upwardly or downwardly with respect to a vertical axis of the furnace.
- the pivotal connection of the nozzle tip 5 allows a redirection of the air within a range of approximately ⁇ 30°. In a simplified embodiment of the nozzle tip 5 is not pivotably mounted.
- shearing bars 29 swirl and direct the air and coal particles exiting the exit faces 13 . 1 and 13 . 2 such that the ignition point of the flame comes closer to the nozzle tip 5 and provides improved flame stability.
- the shear bars 29 are optional.
- FIG. 3 a channel 22 limited by the air housing 18 on one side and by the nozzle body 3 and the nozzle tip 5 on the other side can be seen.
- a perimeter of secondary air flows into the furnace.
- secondary air cools the nozzle tip 5 and additionally mixes the coal particles and the air before being combusted. It is further advantageous to reduce the height of the channel 22 to a minimum near the exit faces 13 . 1 , 13 . 2 to accelerate the secondary air.
- FIGS. 4 and 5 illustrate a second embodiment of the claimed invention. Similar parts have the same reference numerals as the first embodiment ( FIGS. 1 to 3 ).
- the nozzle body 3 is attached to an inner shell 3 . 1 of the nozzle assembly 1 . It further comprises two nozzle tips 15 . 1 and 15 . 2 , each being pivotably mounted to the inner shell 3 . 1 by means of pivot pins 16 and the respective bearings 20 .
- parting means 21 are installed in the inner shell 3 . 1 splitting the flow through the nozzle body 3 into two partial flows and forming together with the inner shell 3 . 1 two channels 14 . 1 , 14 . 2 .
- Each channel 14 . 1 , 14 . 2 supplies approximately a half of the flow through the nozzle body 3 to each of the nozzle tips 15 . 1 and 15 . 2 .
- the directions of the flow paths and the longitudinal axes 33 . 1 and 33 . 2 of the nozzle tips 15 . 1 and 15 . 2 enclose an angle ⁇ between 90° and 0° (illustrated is an angle of approximately 40°). This promotes intersecting and shearing the two partial streams outside the nozzle assembly 1 with the above-mentioned positive results.
- both nozzle tips 15 . 1 and 15 . 2 may be tilted independently, it is possible to adjust the angle ⁇ between the directions of the flow paths and/or the longitudinal axes 33 . 1 and 33 . 2 of the nozzle tips 15 . 1 and 15 . 2 such that an optimal combustion is achieved. Further, it is possible, to adjust the ignition point of the flame.
- the outer housing 18 and the inner shell 3 . 1 and the nozzle tips 15 . 1 , 15 . 2 limit a channel 22 through which the a.m. a perimeter of secondary air for cooling the nozzle tips 15 . 1 and 15 . 2 flows.
- outer housing 18 and the inner shell 3 . 1 are pivotally mounted by means of means of pivot pins 37 , 39 such that they can be tilted about an angle of approximately +/ ⁇ 30°.
- each nozzle tip 15 . 1 , 15 . 2 and 15 may comprise a splitter plate 25 disposed near the exit faces 13 . 1 , 13 . 1 , 23 . 1 , and 23 . 3 to direct the flow of air and coal particles.
- FIG. 5 illustrates the flow, of the primary air through the nozzle assembly 1 and further illustrates the intersection and shearing of the two partial streams after having left the nozzle tips 15 . 1 , 15 . 2 .
- FIG. 6 illustrates a perspective view of the second embodiment. From this perspective view it can be seen that between the outer housing 18 and the nozzle body 3 . 1 a channel 22 for cooling the nozzle tips 15 . 1 and 15 . 2 exists.
- a plurality of ribs 24 is disposed between the air housing 18 and the inner shell 3 . 1 . They are welded to the inner surface of the air housing 18 and to the outer surface of the elongated nozzle body 3 . 1 forming the structural framework of the nozzle tip 1 .
- the ribs 24 may further serve as 22 guiding means for the secondary air.
- the exit faces 23 . 1 and 23 . 2 may enclose an angle of 180° (this means that the flow paths are parallel). In some cases this may be the optimal direction for the flow of primary air and coal particles exiting the nozzle 15 . 1 and 15 . 2 .
- a catalyst 35 is applied to the surfaces of the nozzle tip(s) that are exposed to the primary air and the coal particles. Catalytic combustion of the volatile matter in the injected fuel is achieved at temperatures favorable for the reduction of NOx species originating from the volatile matter or partial combustion of solid fuels. Catalytic combustion inside the nozzle tip also improves the quality of the flame downstream and corresponding reduced NOX emission within the furnace.
- Catalytic combustion of the volatile matter in the injected fuel is achieved at temperatures favorable for the reduction of NOx species originating from the volatile matter or partial combustion of solid fuels. Catalytic combustion near the exit face(s) of the nozzle tip(s) also improves the quality of the flame and corresponding reduced NOX emission within the furnace.
- the catalyst is of the perovskite-type with catalytic activity in the preferred temperature range, but not limited to, of 500° C. to 900° C.
- the catalyst is Lanthanum, Strontium and/or Titanate doped with metals. Such metals are, but are not limited to, Fe, Mn, and Co.
- the claimed invention is also directed to a method to operate a steam generating system which comprises a furnace and at least one coal nozzle assembly according to one of the foregoing claims by initially adjusting the angle ⁇ of the nozzle tips 5 , 15 . 1 , 15 . 2 during commissioning such that optimal combustion is achieved.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
Abstract
Description
Claims (15)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17184062 | 2017-07-31 | ||
| EP17184062.2A EP3438529B1 (en) | 2017-07-31 | 2017-07-31 | Coal nozzle assembly comprising two flow channels |
| EP17184062.2 | 2017-07-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20190032914A1 US20190032914A1 (en) | 2019-01-31 |
| US10648661B2 true US10648661B2 (en) | 2020-05-12 |
Family
ID=59501347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US16/051,433 Active 2038-10-26 US10648661B2 (en) | 2017-07-31 | 2018-07-31 | Coal nozzle assembly comprising two flow channels |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10648661B2 (en) |
| EP (1) | EP3438529B1 (en) |
| JP (1) | JP7202097B2 (en) |
| KR (1) | KR102575340B1 (en) |
| CN (1) | CN109323250B (en) |
| PL (1) | PL3438529T3 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111750347B (en) * | 2020-08-06 | 2024-12-10 | 扬州新建水泥技术装备有限公司 | A line-driven burner with nozzle angle adjustment |
| CN113357628B (en) * | 2021-05-25 | 2024-03-19 | 江苏大学 | Baffling type automatic ignition miniature catalytic combustor |
| CN113864783B (en) * | 2021-09-06 | 2022-08-05 | 清华大学 | Ammonia fuel fast pyrolysis grading injection gun |
| CN114963168B (en) * | 2022-06-27 | 2022-11-29 | 杭州富丽达热电有限公司 | Clean coal high-efficient burner |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1721879A (en) * | 1928-11-20 | 1929-07-23 | Hazlehurst Henry Edward | Pulverized fuel burner |
| US4252069A (en) * | 1979-04-13 | 1981-02-24 | Combustion Engineering, Inc. | Low load coal bucket |
| US5464344A (en) * | 1993-07-08 | 1995-11-07 | Rolls-Royce Power Engineering Plc | Low NOx air and fuel/air nozzle assembly |
| DE19729607A1 (en) | 1997-07-10 | 1999-01-14 | Andreas P Rosteuscher | Device for heating heat carrier e.g. at vessel wall |
| WO2009114331A2 (en) | 2008-03-07 | 2009-09-17 | Alstom Technology Ltd | LOW NOx NOZZLE TIP FOR A PULVERIZED SOLID FUEL FURNACE |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4356975A (en) | 1980-03-07 | 1982-11-02 | Combustion Engineering, Inc. | Nozzle tip for pulverized coal burner |
| JPS61223411A (en) * | 1985-03-27 | 1986-10-04 | Hitachi Ltd | Pulverized coal catalytic combustion method |
| JPH0483535A (en) * | 1990-07-26 | 1992-03-17 | Univ Beijing | Perovskite-type rare earth composite oxide combustion catalyst |
| JP2995013B2 (en) * | 1997-03-31 | 1999-12-27 | 三菱重工業株式会社 | Pulverized fuel combustion burner |
| JP3686250B2 (en) * | 1998-03-26 | 2005-08-24 | 三菱重工業株式会社 | Pulverized coal burner |
| JP2002336744A (en) * | 1999-11-25 | 2002-11-26 | Asahi:Kk | High-speed thermal spray apparatus for forming a substance and a method for forming a coating or a bulk substance by the spray apparatus |
| JP3790489B2 (en) * | 2002-03-25 | 2006-06-28 | 三菱重工業株式会社 | Fine solid fuel combustion equipment |
| JP3950428B2 (en) * | 2003-03-13 | 2007-08-01 | 三菱重工業株式会社 | Fine fuel combustion burner and fine fuel combustion system |
| JP4896143B2 (en) * | 2006-09-27 | 2012-03-14 | バブコック日立株式会社 | Burner, combustion apparatus equipped with burner, and boiler |
| JP5535522B2 (en) | 2009-05-22 | 2014-07-02 | 三菱重工業株式会社 | Coal fired boiler |
| US8955776B2 (en) | 2010-02-26 | 2015-02-17 | Alstom Technology Ltd | Method of constructing a stationary coal nozzle |
| CN101886807A (en) * | 2010-07-09 | 2010-11-17 | 王同 | Coal-fired cyclone impact combustor |
| CN202835334U (en) * | 2012-04-02 | 2013-03-27 | 国际壳牌研究有限公司 | Burner used for gasified solid fuel |
| JP5797238B2 (en) * | 2013-08-05 | 2015-10-21 | 三菱日立パワーシステムズ株式会社 | Fuel burner and swirl combustion boiler |
| CN103615717B (en) * | 2013-10-24 | 2016-01-13 | 中国计量学院 | A kind of novel oxygen-enriched tiny-oil ignition and steady burning burner in ultra low load |
| CN104132330B (en) * | 2014-07-18 | 2017-02-15 | 中节环(北京)环境科技股份有限公司 | Method for maintaining wind speed by adjusting cross-sectional area of nozzle |
| CN204141575U (en) * | 2014-09-25 | 2015-02-04 | 武汉理工大学 | Be applicable to the coal burner nozzle being with minor air cell's cement decomposing furnace fuel-staged combustion |
-
2017
- 2017-07-31 EP EP17184062.2A patent/EP3438529B1/en active Active
- 2017-07-31 PL PL17184062T patent/PL3438529T3/en unknown
-
2018
- 2018-07-27 CN CN201810843573.9A patent/CN109323250B/en not_active Expired - Fee Related
- 2018-07-30 KR KR1020180088415A patent/KR102575340B1/en active Active
- 2018-07-31 US US16/051,433 patent/US10648661B2/en active Active
- 2018-07-31 JP JP2018143045A patent/JP7202097B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1721879A (en) * | 1928-11-20 | 1929-07-23 | Hazlehurst Henry Edward | Pulverized fuel burner |
| US4252069A (en) * | 1979-04-13 | 1981-02-24 | Combustion Engineering, Inc. | Low load coal bucket |
| CA1136924A (en) | 1979-04-13 | 1982-12-07 | Michael S. Mccartney | Low load coal bucket |
| US5464344A (en) * | 1993-07-08 | 1995-11-07 | Rolls-Royce Power Engineering Plc | Low NOx air and fuel/air nozzle assembly |
| DE19729607A1 (en) | 1997-07-10 | 1999-01-14 | Andreas P Rosteuscher | Device for heating heat carrier e.g. at vessel wall |
| WO2009114331A2 (en) | 2008-03-07 | 2009-09-17 | Alstom Technology Ltd | LOW NOx NOZZLE TIP FOR A PULVERIZED SOLID FUEL FURNACE |
Non-Patent Citations (1)
| Title |
|---|
| Search Report and Examination from corresponding EP Application No. 17184062.2 dated Feb. 5, 2018. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109323250A (en) | 2019-02-12 |
| CN109323250B (en) | 2022-09-27 |
| JP2019052838A (en) | 2019-04-04 |
| EP3438529A1 (en) | 2019-02-06 |
| PL3438529T3 (en) | 2020-10-19 |
| KR102575340B1 (en) | 2023-09-05 |
| EP3438529B1 (en) | 2020-04-22 |
| KR20190013638A (en) | 2019-02-11 |
| JP7202097B2 (en) | 2023-01-11 |
| US20190032914A1 (en) | 2019-01-31 |
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