US10392493B2 - Dispersion solution, organic/inorganic hybrid material and preparation method thereof - Google Patents
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1046—Polyimides containing oxygen in the form of ether bonds in the main chain
- C08G73/105—Polyimides containing oxygen in the form of ether bonds in the main chain with oxygen only in the diamino moiety
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1075—Partially aromatic polyimides
- C08G73/1078—Partially aromatic polyimides wholly aromatic in the diamino moiety
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- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/14—Polyamide-imides
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- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/11—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids from solid polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Definitions
- the present disclosure relates to dispersion solutions, and in particular relates to an organic/inorganic hybrid dispersion solution and the material fabricated therefrom.
- Organic polymeric materials are characterized by being flexible and transparent, but having very high coefficients of thermal expansion (CTE).
- Inorganic materials provide the advantages of good rigidity and low cost, but they have a problem of fragility.
- an organic/inorganic composite material having flexibility, transparency and thermostability is desired. Further, the most efficient way to fabricate the material is to hybridize an organic polymeric material and an inorganic material.
- the current hybridizing method for obtaining the organic/inorganic composite material is to combine the organic polymer and the inorganic material at a specific ratio (such as, the amount of the inorganic material added is far lower than the amount of the organic polymer added), after modifying one or both of them.
- organic ammonium salts are common modifiers for modifying inorganic clay by intercalation, and disperse the modified inorganic clay into an organic polymer.
- the modified inorganic clay made by the approach is able to be hybridized with organic polymer, the added amount of about 20 wt % almost approaches the upper limit of the added amount of inorganic clay.
- the organic/inorganic composite material obtained after hybridization loses its transparency and has high haze. The thermostability also worsens, due to the addition of the modifier.
- the present disclosure provides a dispersion solution, including: a first solvent; a second solvent miscible with the first solvent, wherein the boiling points of the first solvent and the second solvent are different; an inorganic nano sheet material dispersed in the first solvent; and a polymer dissolved in the second solvent.
- the present disclosure further provides an organic/inorganic hybrid material, including: a polymer; and an inorganic nano sheet material dispersed in the polymer in a content of at least 20%, based on a total weight of the organic/inorganic hybrid material, wherein the organic/inorganic hybrid material analyzed at 2 ⁇ angle with X-ray diffraction (XRD) has a diffraction peak in a range of from 3° to 8°.
- XRD X-ray diffraction
- the present disclosure further provides a method for preparing an organic/inorganic hybrid material, including: providing the aforementioned dispersion solution; applying the dispersion solution on a substrate; heating the dispersion solution on the substrate at a first temperature between the boiling points of the first solvent and the second solvent; and heating the dispersion solution on the substrate at a second temperature higher than the boiling points of the first solvent and the second solvent to obtain the organic/inorganic hybrid material formed on the substrate.
- the method for preparing an organic/inorganic hybrid material of the present disclosure is to obtain a hybridized polymeric and inorganic nano sheet material with a relatively lower CTE, in the absence of a modifier, by leveraging the difference in the boiling points of the two solvents and stepwise heating.
- FIG. 1 is an X-ray diffraction spectrum of control example 1 and examples 1 to 4;
- FIG. 2 is an X-ray diffraction spectrum of control example 2 and examples 5 to 7;
- FIG. 3 is an X-ray diffraction spectrum of control example 1 and comparative examples 6 to 8;
- FIG. 4 is a UV-vis spectrum of control example 2 and examples 5 to 7;
- FIG. 5 shows the observation field of the hybrid material in comparative example 4 under Transmission Electron Microscope (TEM) with a magnification of 20,000 ⁇ ;
- TEM Transmission Electron Microscope
- FIG. 6 shows the observation field of the hybrid material in example 3 under TEM with a magnification of 20,000 ⁇
- FIG. 7 shows the observation field of the hybrid material in example 7 under TEM with a magnification of 20,000 ⁇
- FIG. 8 shows the observation field of the hybrid material in example 4 under TEM with a magnification of 20,000 ⁇
- FIG. 9 is a UV-vis spectrum of the dispersion solutions used in control example 1, preparatory example 1 and examples 1 to 4, and 8.
- the dispersion solution of the present disclosure includes a first solvent; a second solvent miscible with the first solvent, wherein the boiling points of the first solvent and the second solvent are different; an inorganic nano sheet material dispersed in the first solvent; and polymer dissolved in the second solvent.
- the boiling points of the first solvent and the second solvent are different.
- the solvent with a lower boiling point evaporates first, gradually decreasing the volume and the degree of dispersion and dissolution of the solvent system.
- the inorganic nano sheet material is arranged and dispersed orderly and/or sequentially in the polymer.
- the boiling points of the first solvent and the second solvent are different.
- the difference in the boiling points between the first solvent and the second solvent is 10° C. or higher.
- the boiling point of the first solvent is lower than that of the second solvent.
- the solvent type used in the present disclosure is not limited.
- the first solvent not only can disperse the inorganic nano sheet material therein, but also can make the polymer soluble or insoluble.
- the second solvent is regularly selected from the ones in which the inorganic nano sheet material which cannot be dispersed.
- the first solvent is water, alcohol, or alcohol ether.
- the alcohol is methanol, ethanol, and isopropanol.
- the alcohol ether is propylene glycol methyl ether (PGME).
- the second solvent is at least one selected from the group consisting of methylpyrrolidone (NMP), dimethylacetamide (DMAc), dimethylformamide (DMF), dimethyl sulfoxide (DMSO), ⁇ -butyrolactone (GBL), m-cresol, toluene, xylene, 1,2-propanediol, ethyl 2-hydroxypropanoate, propylene glycol monomethyl ether acetate (PGMEA), cyclohexanone, and tetrahydrofuran (THF).
- other organic solvents may be selected.
- the first solvent is water;
- the second solvent is selected from organic solvents, such as dimethylacetamide (DMAc) and ⁇ -butyrolactone (GBL).
- DMAc dimethylacetamide
- GBL ⁇ -butyrolactone
- the solid content of the inorganic nano sheet material is from 20 to 80%, such as 20 to 50% or 50 to 80%. In the aforementioned embodiment, the solid content of the inorganic nano sheet material is from 20 to 80%.
- the inorganic nano sheet material is natural or artificially synthesized clay.
- the natural or artificially synthesized inorganic nano sheet material is an un-modified inorganic sheet material, for example, the inorganic material is at least one selected from the group consisting of montmorillonite, volkonskoite, saponite, hectorite, vermiculite, wyoming bentonite, halloysite, mica, and laponite.
- the polymer type is not limited. The following simply provides examples of some of the polymers.
- the polymer is at least one selected from the group consisting of polyimide (PI), polyamic acid (PAA), polyamideimides (PAI), polyurethanes (PU), polycarbonate (PC), polyarylance (PAR), polyether sulfones (PES), and cyclo-olefin copolymer (COC).
- PI polyimide
- PAA polyamic acid
- PAI polyamideimides
- PU polyurethanes
- PC polycarbonate
- PAR polyarylance
- PES polyether sulfones
- COC cyclo-olefin copolymer
- the content of the polymer is from 20 to 80%, such as 20 to 50% or 50 to 80%. In an embodiment, the content of the polymer is from 20 to 80%.
- the dispersion solution used for preparing the organic/inorganic hybrid material of the present disclosure is a suspended emulsion, which has an absorbance peak in the wavelength range of from 350 to 650 nm.
- the suspended emulsion has an absorbance peaks in the wavelength range of from 350 to 450 nm.
- the suspended emulsion has an absorbance peak in the wavelength range of from 550 to 650 nm. The phenomenon indicates that the even mixing of the inorganic nano sheet material solution and the polymer solution indeed form a dispersion solution.
- the inorganic nano sheet material dispersed in the first solvent is present in the form of a plurality of the first micelles.
- the polymer dissolved in the second solvent is present in the form of plurality of the second micelles.
- the first solvent and the second solvent are miscible to be a solvent system.
- the solvent system has a plurality of the first micelles and the second micelles.
- the present disclosure further provides a method for preparing an organic/inorganic hybrid material.
- the method involves mixing the inorganic nano sheet material, the polymer, the first solvent for dispersing the inorganic nano sheet material therein, and the second solvent for dissolving the polymer, so as to obtain a dispersion solution, wherein the first solvent and the second solvent are miscible, and the boiling points of the first solvent and the second solvent are different; applying the dispersion solution on a substrate; heating the dispersion solution on the substrate under the first temperature that is between the boiling points of the first solvent and the second solvent; and heating the dispersion solution on the substrate at the second temperature that is higher than the boiling points of the first solvent and the second solvent, so as to obtain the organic/inorganic hybrid material formed on the substrate.
- the carrier can be removed optionally.
- the obtained organic/inorganic hybrid material is a film.
- the step for heating the dispersion solution needs at least two heating temperatures.
- the step of mixing the inorganic nano sheet material, polymer, the first solvent, and the second solvent involves dispersing the inorganic nano sheet material in the first solvent to form the first solution, dissolving the polymer in the second solvent to form the second solution, and then mixing the first solution and the second solution to form a homogeneously suspended emulsion.
- the substrate can be glass, ceramics, stones, or metals.
- the aforesaid approach for applying the dispersion solution on a substrate can be scraper coating, spin-coating, spray coating, or roller coating.
- step of stepwisely increasing the temperature from an initial temperature that is lower than the boiling points of the first solvent and the second solvent can be further included.
- the substrate with the applied dispersion solution is directly placed in an environment with an initial temperature of from 50° C. to 80° C. for 120 minutes, and then the temperature is stepwisely increased to the first temperature, and maintained for 30 minutes, wherein the first temperature is in the range of from 140 to 170° C.
- the second temperature is in the range of from 210 to 250° C.
- the present disclosure provides an organic/inorganic hybrid material, including: a polymer; and an inorganic nano sheet material dispersed in the polymer in a content of at least 20%, based on the total weight of the organic/inorganic hybrid material.
- the organic/inorganic hybrid material is analyzed at 2 ⁇ angle with an X-Ray Diffraction, and is found to have a diffraction peak in the range of from 3° to 8°.
- the CTE of the organic/inorganic hybrid material is from 5 to 60 ppm/° C.
- the transparency of the organic/inorganic hybrid material can approach 80% or higher, and more preferably 88% or higher.
- the inorganic nano sheet material is natural or artificially synthesized clay.
- the natural or artificially synthesized inorganic nano sheet material is an un-modified inorganic sheet material.
- the material is at least one selected from the group consisting of montmorillonite, volkonskoite, saponite, hectorite, vermiculite, wyoming bentonite, halloysite, mica, and laponite.
- the polymer type is not limited. The following simply provides example of some of the polymers.
- the polymer is at least one selected from the group consisting of PI, PAA, PAI, PU, PC, PAR, PES, and COC.
- BAPPm 2,2-bis[4-(4-aminophenoxy)phenyl]propane
- the polyimide was dissolved in dimethylacetamide (DMAc), and was formulated to make polyimide solutions (containing polyimide with solid contents of 2.0 wt % and 18.9 wt %) of preparatory example 2. The solutions were kept for further mixing.
- DMAc dimethylacetamide
- the polyimide was dissolved in dimethylacetamide (DMAc), and was formulated to make a polyimide solution (containing polyimide with a solid content of 2.0 wt %) of preparatory example 3. The solutions were kept for further mixing.
- DMAc dimethylacetamide
- the 2.0 wt % polymer solution (BB) of preparatory example 2 was coated on a glass to form a film with an 800 ⁇ m scraper.
- the film was baked in an oven at 50° C. for 2 hours, baked for 10 minutes after ramping up to 150° C., and then baked in the oven at 210° C. for 1 hour.
- the film of control example 1 could be peeled off from the glass.
- the polymer solution (EB) of preparatory example 3 was coated as film on a glass with the 800 ⁇ m scraper.
- the film was baked in the oven at 50° C. for 2 hours, baked for 10 minutes after ramping up to 150° C., and then baked in the oven at 210° C. for 1 hour.
- the film of control example 2 was peeled off from the glass.
- the suspended emulsion was coated on a glass to form a film with 800 ⁇ m scraper.
- the film was baked in the oven at 50° C. for 2 hours, baked for 10 minutes after ramping up to 150° C., and then baked in the oven at 210° C. for 1 hour.
- the organic/inorganic hybrid material of the present disclosure formed on the glass was obtained.
- inorganic clay (Laponite RD) was dispersed in 1000 g of DI water, and the mixture was shaken vigorously for even mixing, and sonicated for about 20 minutes. A transparent clear suspension was obtained.
- the inorganic clay dispersion solution was deionized by using a mixture of anionic exchange resins (Dowex Marathon A OH ⁇ form) and cationic exchange resins (Dowex Marathon MSC H + form). The resins were filtered, and the suspension was eluted from an aqueous phase to an organic phase (i.e., isopropanol (IPA)) and then eluted from the IPA phase into dimethylacetamide (DMAc) with a calculated solid content of 6.0 wt %.
- the modified inorganic clay suspension containing clay with a solid content of 6.05 wt % was obtained. The suspension was kept for further mixing.
- inorganic clay (Laponite RD) was dispersed in 1000 g of DI water, and the mixture was shaken vigorously for even mixing, and sonicated for about 20 minutes. A transparent clear suspension was obtained.
- the inorganic clay dispersion solution was deionized by using a mixture of anionic exchange resins (Dowex Marathon A OH ⁇ form) and cationic exchange resins (Dowex Marathon MSC H + form). The resins were filtered, and the suspension was eluted from an aqueous phase to an organic phase (i.e., IPA) and then eluted from the IPA phase into ⁇ -butyrolactone (GBL) with a calculated solid content of 5.0 wt %.
- the modified inorganic clay suspension containing clay with a solid content of 4.88 wt % was obtained. The suspension was kept for further mixing.
- the mixed suspension was coated on a glass to form a film with the 600 ⁇ m scraper.
- the film was baked in the oven at 50° C. for 30 minutes, baked for 20 minutes after ramping up to 150° C., and baked in the oven at 210° C. for 1 hour.
- the film formed on the glass was obtained.
- the polymer solution (BB) of comparative preparatory example 3 was coated on a glass to form a film with a 300 ⁇ m scraper.
- the film was baked in the oven at 50° C. for 1 hour, baked for 20 minutes after stepwisely increasing the temperature to 150° C., and baked in the oven at 210° C. for 1 hour.
- the film of comparative example 5 could be peeled off from the glass.
- the mixed suspension was coated on a glass to form a film with a 300 ⁇ m scraper.
- the film was baked in the oven at 50° C. for 1 hour, baked for 20 minutes after ramping up to 150° C., and baked in the oven at 210° C. for 1 hour.
- the film formed on the glass was obtained.
- the brand model of the instrument for measuring CTE was TMA Q400, which was used to apply 0.05N on the materials of control examples 1 and 2, comparative examples 1 to 8 and examples 1 to 8, and scanned at scan rate of 10° C./min from room temperature to 350° C. The results are recorded in Table 1.
- the brand of the instrument for assessing X-Ray Diffraction spectrum was PANalytical (Model: Empyrean), which fixed the film sample on a holder for direct instrumental measurement under the condition of a scan range of 2 to 10° and a scan step size of 0.01° at 2 ⁇ angle.
- the brand model of the instrument for observation of Transmission Electron Microscope is JEOL JEM-2100F Field-Emission Transmission Electron Microscope, which was operated for observation under the condition of a voltage of 200 kV and a magnification of 20,000 ⁇ .
- examples 1 to 4 in the present disclosure showed lower CTEs. Further, compared to control example 2, examples 5 to 7 in the present disclosure also showed lower CTEs.
- FIG. 1 shows an XRD spectrum of control example 1 and examples 1 to 4 in the present disclosure.
- examples 1 to 4 in the present disclosure had diffraction peaks in the range of 3° to 8° at 2 ⁇ angle in the XRD spectrum.
- FIGS. 5, 6, 7 and 8 show observation fields of the organic/inorganic hybrid materials of comparative example 4, example 3, example 7 and example 4 under TEM at a magnification of 200 ⁇ , respectively.
- comparative example 4 i.e., having 40% of modified inorganic clay ( FIG. 5 )
- comparative example 3 and 4 of the present disclosure i.e., having 40% and 50% of inorganic clay ( FIGS. 6 and 8 )
- the inorganic clay and polymer were evenly dispersed and had orderly arrangements.
- the organic/inorganic hybrid material is obtained by hybridizing the organic polymer and the inorganic material, in absence of a modifier.
- FIG. 2 shows an XRD spectrum of control example 2 and examples 5 to 7 of the present disclosure.
- examples 5 to 7 of the present disclosure showed diffraction peaks in the range of from 4° to 5° at 2 ⁇ angle in the XRD spectrum
- example 7 i.e., organic/inorganic hybrid material with 40% inorganic clay
- FIG. 7 shows an observation field under TEM with a magnification of 20,000 ⁇ .
- the inorganic clay and the polymer were evenly dispersed and orderly arranged.
- FIG. 3 shows an XRD spectrum of control example 1 and comparative examples 6 to 8 of the present disclosure which showed no peaks in the range of from 2° to 10° at 2 ⁇ angle. Apparently, even if the organic/inorganic hybrid materials were made by modifying inorganic clay in comparative examples 6 to 8, the inorganic clay still failed to effectively arrange in the theoretical order.
- inorganic clay in examples 5 to 7 of the present disclosure were all higher than 20%. However, under light penetration at 550 nm, transmittances in examples 5 to 7 were still higher than 88%. The transmittances in the examples and control example 2 (i.e., without inorganic clay) were not any different.
- the suspended emulsions of examples 1 to 4 and 8 of the present disclosure showed absorbance peaks in the range of wavelength of from 350 to 450 nm or 550 to 650 nm in the UV-vis spectrum, which indicated an evenly mixed suspension was formed.
- CTE of the organic/inorganic hybrid material of the present disclosure can be reduced by adding a high content of the inorganic material to the hybrid material.
- the inherent good transmittance of the polymer can be retained.
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Abstract
Description
TABLE 1 | ||||
Composition | ||||
Content of | Decrease in CTE | |||
inorganic clay | CTE (ppm/° C.) | (ppm/° C.) | ||
Control | BB | 57.05 | — |
example 1 | |||
Example 1 | clay-W/BB | 33.51 | 41.3% |
20% | |||
Example 2 | 30% | 23.28 | 59.2% |
Example 3 | 40% | 14.72 | 74.2% |
Example 4 | 50% | 7.791 | 86.3% |
Control | EB | 250.0 | — |
example 2 | |||
Example 5 | clay-W/EB | 101.9 | 59.2% |
20 | |||
Example e6 | |||
30% | 67.02 | 73.2% | |
Example 7 | 40% | 33.23 | 86.7% |
Comparative | BB | 57.05 | — |
example 1 | |||
Comparative | clay-D | 40.3 | 29.4% |
example 2 | 20% | ||
Comparative | 30% | 34.8 | 39.0% |
example 3 | |||
|
40% | 27.6 | 51.6% |
example 4 | |||
Comparative | BB | 57.05 | — |
example 5 | |||
Comparative | clay-γ | 42.86 | 24.9% |
example 6 | 20% | ||
Comparative | 30% | 34.45 | 39.6% |
example 7 | |||
|
40% | 27.69 | 51.5% |
example 8 | |||
Claims (18)
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Application Number | Priority Date | Filing Date | Title |
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TW104143766A TWI551628B (en) | 2015-12-25 | 2015-12-25 | Dispersion and preparation method thereof and organic/inorganic hybrid material |
TW104143766 | 2015-12-25 | ||
TW104143766A | 2015-12-25 |
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US20170183476A1 US20170183476A1 (en) | 2017-06-29 |
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CN107629649A (en) * | 2017-10-26 | 2018-01-26 | 桂林加宏汽车修理有限公司 | A kind of inorganic composite film material of the high grade of transparency |
TWI655097B (en) | 2017-12-27 | 2019-04-01 | 財團法人工業技術研究院 | Optical waveguide element and method of manufacturing same |
CN111592862B (en) * | 2020-05-15 | 2022-03-11 | 武汉理工大学 | Montmorillonite nanosheet/water nanofluid and preparation method thereof |
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CN106916322B (en) | 2019-04-26 |
TW201723035A (en) | 2017-07-01 |
TWI551628B (en) | 2016-10-01 |
CN106916322A (en) | 2017-07-04 |
US20170183476A1 (en) | 2017-06-29 |
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