CN107629649A - A kind of inorganic composite film material of the high grade of transparency - Google Patents
A kind of inorganic composite film material of the high grade of transparency Download PDFInfo
- Publication number
- CN107629649A CN107629649A CN201711015681.9A CN201711015681A CN107629649A CN 107629649 A CN107629649 A CN 107629649A CN 201711015681 A CN201711015681 A CN 201711015681A CN 107629649 A CN107629649 A CN 107629649A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- film material
- transparency
- high grade
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Laminated Bodies (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to the component that a kind of inorganic composite film material of the high grade of transparency includes following parts by weight：50 350 titanate esters, 10 50 titanate coupling agent, 20 70 esters of silicon acis, 10 50 water, 3 10 p-hydroxybenzenyl sulfonate, 10 20 dimethyl acetamide, 20 50 makrolon, 5 15 phenolsulfonic acid.The inorganic composite film material of the high grade of transparency provided by the invention has high index of refraction, the high grade of transparency and high-wear resistance; its surface smoothness is high; synthesized film material may be used as the protective layer of automobile lamp, the surface of CD and breathing mask, it may also be used for resin lens, transparent optical device, the surface antireflective wear-resistant coating of display device and solar cell.
Description
Technical field
The invention belongs to solar energy and environmental protection and energy saving technical field, more particularly to a kind of inorganic composite film of the high grade of transparency
Material.
Background technology
Currently, high index of refraction optical coating is broadly divided into two major classes：Polymer optical coating and inorganic optical coating.Polymerization
Thing optical coating has the advantages that light, shock resistance, easy processing shaping, but polymer surfaces hardness is low, poor heat resistance, refraction
Narrower (the n of excursion of ratedBetween 1.35~1.7).Although for example poly- thiophene phenol of some special polymer has higher refraction
Rate (n=2.12), but it has strong optical absorption coupling in visible region, which limits it in high index of refraction (nd＞
1.7) application on optical component.Inorganic material typically has higher refractive index (nd=2.0~5.0), larger Abbe
Number, but its density is big, material is more crisp.Especially as antireflection coatings in use, the value of its refractive index is unable to continuously adjustabe, and
Requirement to processing technology is higher.And Inorganic-Organic Hybrid Material can then have the advantages of both the above material concurrently, therefore in recent years
Inorganic nano-particle is introduced into optical coating and answered to prepare the nanometer of high index of refraction by the method that people begin through collosol and gel
Hybrid material is closed, this material can solidify through ultraviolet light or be heating and curing to obtain transparent film layer material compound on nanoscale
Material.The surface that this material can be used for glass or resin lens, breathing mask, automobile lamp and CD applies as wear Protection
Layer, also has broad application prospects in terms of the antireflective coating of solar cell, material of infrared window and optical component.
The universal all relatively low (n of the refractive index for the wear-resisting optical coating of hybrid inorganic-organic applied at presentd＜ 1.60), still
The design requirement of the antireflection coatings of high index of refraction optical material surface is not well positioned to meet.Therefore by the inorganic of high index of refraction
Thing be incorporated into hybrid coating prepare refractive index more than 1.65, and optical clear wear-resisting hybridization compounding coating be to be currently needed for
Solve the problems, such as.
The content of the invention
In view of the problems of prior art, the present invention provides a kind of inorganic composite film material of the high grade of transparency, tool
There is the advantages of high high index of refraction, transparency, wear-resisting damage resistant.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of inorganic composite film material of the high grade of transparency,
Include the component of following parts by weight：50-350 titanate esters, 10-50 titanate coupling agent, 20-70 esters of silicon acis, 10-50's
Water, 3-10 p-hydroxybenzenyl sulfonate, 10-20 dimethyl acetamide, 20-50 makrolon, 5-15 phenolsulfonic acid.
Further, the titanate esters are 50 parts by weight, and the titanate coupling agent is 10 parts by weight, and the esters of silicon acis is
20 parts by weight, the water are 10 parts by weight, and the p-hydroxybenzenyl sulfonate is 3 parts by weight, and the dimethyl acetamide is 10 weight
Part, the makrolon is 20, and the phenolsulfonic acid is 5 parts by weight.
Further, the titanate esters are 350 parts by weight, and the titanate coupling agent is 50 parts by weight, the esters of silicon acis
For 70 parts by weight, the water is 50 parts by weight, and the p-hydroxybenzenyl sulfonate is 10 parts by weight, and the dimethyl acetamide is 20 weights
Part is measured, the makrolon is 50, and the phenolsulfonic acid is 15 parts by weight
Further, the titanate esters are 150 parts by weight, and the titanate coupling agent is 25 parts by weight, the esters of silicon acis
For 30 parts by weight, the water is 25 parts by weight, and the p-hydroxybenzenyl sulfonate is 5 parts by weight, and the dimethyl acetamide is 14 weights
Part is measured, the makrolon is 30, and the phenolsulfonic acid is 10 parts by weight.
Further, the inorganic composite film material of the high grade of transparency also includes the polyamic acid of 10-20 parts by weight.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit
Determine the scope of the present invention.
A kind of inorganic composite film material of the high grade of transparency, include the component of following parts by weight：50-350 titanate esters,
10-50 titanate coupling agent, 20-70 esters of silicon acis, 10-50 water, 3-10 p-hydroxybenzenyl sulfonate, 10-20 dimethyl
Acetamide, 20-50 makrolon, 5-15 phenolsulfonic acid.
Inventor has carried out the screening experiment of substantial amounts of component and dosage early stage, is found surprisingly that, technology of the invention
Scheme is by reasonably matching and the combination of each component, the thin-film material of manufacture have high index of refraction, the high grade of transparency and height
Anti-wear performance, its surface smoothness is high, and synthesized film material may be used as the surface and gas defence face of automobile lamp, CD
The protective layer of tool, it may also be used for resin lens, transparent optical device, the surface antireflective of display device and solar cell are wear-resisting
Coating.
It is introduced below by specific embodiment.
Embodiment 1
The inorganic composite film material for the high grade of transparency that the present embodiment provides includes the component of following parts by weight：The metatitanic acid
Ester is 50 parts by weight, and the titanate coupling agent is 10 parts by weight, and the esters of silicon acis is 20 parts by weight, and the water is 10 weight
Part, the p-hydroxybenzenyl sulfonate is 3 parts by weight, and the dimethyl acetamide is 10 parts by weight, and the makrolon is 20, described
Phenolsulfonic acid is 5 parts by weight.
Embodiment 2
The inorganic composite film material for the high grade of transparency that the present embodiment provides includes the component of following parts by weight：The metatitanic acid
Ester is 100 parts by weight, and the isobutyl triethoxy silane is 30 parts by weight, and the esters of silicon acis is 5 parts by weight, and the water is 20
Parts by weight, the hydroxy benzene sulfonic acid are 1 parts by weight, and the dimethyl acetamide is 5 parts by weight, and the benzidine is 1 weight
Part.
Embodiment 3
The inorganic composite film material for the high grade of transparency that the present embodiment provides includes the component of following parts by weight：The metatitanic acid
Ester is 350 parts by weight, and the titanate coupling agent is 50 parts by weight, and the esters of silicon acis is 70 parts by weight, and the water is 50 weight
Part, the p-hydroxybenzenyl sulfonate is 10 parts by weight, and the dimethyl acetamide is 20 parts by weight, and the makrolon is 50, institute
It is 15 parts by weight to state phenolsulfonic acid
Embodiment 4
The inorganic composite film material for the high grade of transparency that the present embodiment provides includes the component of following parts by weight：The metatitanic acid
Ester is 50 parts by weight, and the titanate coupling agent is 10 parts by weight, and the esters of silicon acis is 20 parts by weight, and the water is 10 weight
Part, the p-hydroxybenzenyl sulfonate is 3 parts by weight, and the dimethyl acetamide is 10 parts by weight, and the makrolon is 20, described
The polyamic acid that phenolsulfonic acid is 5 parts by weight and the benzidine is 10 parts by weight and 15 parts by weight.
Comparative example 1
Makrolon and phenolsulfonic acid are not put in this comparative example.Other components and proportioning and the technical side in example IV
Case is identical.
Comparative example 2
Polyamic acid is not put in this comparative example, other are identical with the technical scheme that embodiment is a kind of.
Measure of merit
The performance of the inorganic composite film material of the high grade of transparency of above-described embodiment and comparative example preparation is determined respectively.
Test result is as shown in table 1.
Table 1
| Refractive index | Transmitance (%) | |
| Embodiment 1 | 1.76 | 85.8 |
| Embodiment 2 | 1.82 | 86.2 |
| Embodiment 3 | 1.75 | 87.1 |
| Embodiment 4 | 1.78 | 86.4 |
| Comparative example 1 | 1.63 | 56.3 |
| Comparative example 2 | 1.59 | 56.8 |
Data in table 1 can be seen that the inorganic composite film of the high grade of transparency of technical scheme offer
Material to be put into refractive index and percent of pass very high, its surface smoothness is high, and synthesized film material may be used as Automobile
The protective layer of lamp, the surface of CD and breathing mask, it may also be used for resin lens, transparent optical device, display device and too
The surface antireflective wear-resistant coating of positive energy battery.Wherein from the contrast of embodiment and comparative example in table 1, of the invention real
Apply and polyamic acid, p-hydroxybenzenyl sulfonate, dimethylacetamide and amine benzidine are with the addition of in example, therefore can increase substantially thin
The transparency of membrane material.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (5)
1. a kind of inorganic composite film material of the high grade of transparency, it is characterised in that include the component of following parts by weight：50-350's
Titanate esters, 10-50 titanate coupling agent, 20-70 esters of silicon acis, 10-50 water, 3-10 p-hydroxybenzenyl sulfonate, 10-20's
Dimethyl acetamide, 20-50 makrolon, 5-15 phenolsulfonic acid.
2. the inorganic composite film material of the high grade of transparency according to claim 1, it is characterised in that：The titanate esters are 50
Parts by weight, the titanate coupling agent are 10 parts by weight, and the esters of silicon acis is 20 parts by weight, and the water is 10 parts by weight, described
P-hydroxybenzenyl sulfonate is 3 parts by weight, and the dimethyl acetamide is 10 parts by weight, and the makrolon is 20, the phenol sulphur
Acid is 5 parts by weight.
3. the inorganic composite film material of the high grade of transparency according to claim 1, it is characterised in that：The titanate esters are
350 parts by weight, the titanate coupling agent are 50 parts by weight, and the esters of silicon acis is 70 parts by weight, and the water is 50 parts by weight, institute
It is 10 parts by weight to state p-hydroxybenzenyl sulfonate, and the dimethyl acetamide is 20 parts by weight, and the makrolon is 50, the phenol
Sulfonic acid is 15 parts by weight.
4. the inorganic composite film material of the high grade of transparency according to claim 1, it is characterised in that：The titanate esters are
150 parts by weight, the titanate coupling agent are 25 parts by weight, and the esters of silicon acis is 30 parts by weight, and the water is 25 parts by weight, institute
It is 5 parts by weight to state p-hydroxybenzenyl sulfonate, and the dimethyl acetamide is 14 parts by weight, and the makrolon is 30, the phenol
Sulfonic acid is 10 parts by weight.
5. the inorganic composite film material of the high grade of transparency according to claim 1, it is characterised in that：Also include 10-20 weights
Measure the polyamic acid of part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711015681.9A CN107629649A (en) | 2017-10-26 | 2017-10-26 | A kind of inorganic composite film material of the high grade of transparency |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711015681.9A CN107629649A (en) | 2017-10-26 | 2017-10-26 | A kind of inorganic composite film material of the high grade of transparency |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107629649A true CN107629649A (en) | 2018-01-26 |
Family
ID=61106546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711015681.9A Pending CN107629649A (en) | 2017-10-26 | 2017-10-26 | A kind of inorganic composite film material of the high grade of transparency |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107629649A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699488A (en) * | 2005-05-27 | 2005-11-23 | 吉林大学 | High strength organic / inorganic nano composite transparent film layer materials and method for preparing same |
| CN101328023A (en) * | 2008-07-31 | 2008-12-24 | 哈尔滨工业大学 | Organic-inorganic mixed film and method for preparing the same |
| CN102248736A (en) * | 2010-05-21 | 2011-11-23 | 中国科学院化学研究所 | Method for preparing regular composite membrane and semi-spherical inorganic substance micro-nano particles |
| CN104877290A (en) * | 2015-06-08 | 2015-09-02 | 西安钧盛新材料科技有限公司 | Preparation method for anti-glare material and anti-glare glass product |
| CN106916322A (en) * | 2015-12-25 | 2017-07-04 | 财团法人工业技术研究院 | Dispersion liquid, process for producing the same, and organic/inorganic hybrid material |
-
2017
- 2017-10-26 CN CN201711015681.9A patent/CN107629649A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699488A (en) * | 2005-05-27 | 2005-11-23 | 吉林大学 | High strength organic / inorganic nano composite transparent film layer materials and method for preparing same |
| CN101328023A (en) * | 2008-07-31 | 2008-12-24 | 哈尔滨工业大学 | Organic-inorganic mixed film and method for preparing the same |
| CN102248736A (en) * | 2010-05-21 | 2011-11-23 | 中国科学院化学研究所 | Method for preparing regular composite membrane and semi-spherical inorganic substance micro-nano particles |
| CN104877290A (en) * | 2015-06-08 | 2015-09-02 | 西安钧盛新材料科技有限公司 | Preparation method for anti-glare material and anti-glare glass product |
| CN106916322A (en) * | 2015-12-25 | 2017-07-04 | 财团法人工业技术研究院 | Dispersion liquid, process for producing the same, and organic/inorganic hybrid material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102985499B (en) | Antireflection film and method for manufacturing same | |
| CN102268184B (en) | Light-diffusing dimethyl organic silicone rubber composition and LED light-diffusing molding body | |
| US20060251884A1 (en) | Plastic lens and method of manufacturing a plastic lens | |
| US20090029153A1 (en) | Plastic lens and method for producing plastic lens | |
| CN104007491B (en) | A kind of antireflecting coating based on cage-type silsesquioxane structure and preparation method thereof and application | |
| CN109810555A (en) | The hardened layer coating fluid and a kind of cured film of a kind of high rigidity, anti-dazzle | |
| CN109880507A (en) | The hardened layer coating fluid and a kind of cured film of a kind of high abrasion, high tenacity | |
| CN107245299A (en) | A kind of aqueous light diffusion coating and its production and use | |
| EP2374849A3 (en) | Opacifying particles and compositions formed therefrom | |
| JP2008046264A (en) | Optical article | |
| US20200096674A1 (en) | Optical Article Comprising an Abrasion- and/or Scratch-Resistant Coating Having a Low Sensitivity to Cracks | |
| CN107629649A (en) | A kind of inorganic composite film material of the high grade of transparency | |
| CN206892367U (en) | A kind of UV hardens SRF films | |
| CN107739533A (en) | A kind of inorganic composite film material of high index of refraction | |
| CN111440517A (en) | High-definition antifogging coating | |
| US20140036223A1 (en) | Self-healing transparent coatings containing mineral conductive colloids | |
| JP7248429B2 (en) | Photocurable composition, laminate and method for producing same, light guide plate for display | |
| JP2004168945A (en) | Transparent composite composition | |
| CN106084403A (en) | A kind of anticorrosion plastic wood sheet | |
| CN112521851B (en) | Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof | |
| CN205951421U (en) | Polyvinyl chloride static membrane | |
| CN105062328A (en) | High performance antiglare film | |
| CN211471280U (en) | Anti PET ya keli protection film of scraping | |
| CN112680103A (en) | Ultrahigh-strength hydrophobic antifogging coating composition and application thereof | |
| TWM532572U (en) | Spectacle lens with hard coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180126 |
|
| RJ01 | Rejection of invention patent application after publication |