UA91016C2 - catalyst carrier, catalytic compound, processes of producing thereof and process of hydrocracking with use of catalytic compound - Google Patents
catalyst carrier, catalytic compound, processes of producing thereof and process of hydrocracking with use of catalytic compoundInfo
- Publication number
- UA91016C2 UA91016C2 UAA200610342A UAA200610342A UA91016C2 UA 91016 C2 UA91016 C2 UA 91016C2 UA A200610342 A UAA200610342 A UA A200610342A UA A200610342 A UAA200610342 A UA A200610342A UA 91016 C2 UA91016 C2 UA 91016C2
- Authority
- UA
- Ukraine
- Prior art keywords
- catalytic compound
- hydrocracking
- catalyst carrier
- processes
- producing
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000004517 catalytic hydrocracking Methods 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 2
- 150000001875 compounds Chemical class 0.000 title 2
- 238000000034 method Methods 0.000 title 2
- 239000011148 porous material Substances 0.000 abstract 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The invention provides a shaped catalyst carrier which is an inorganic refractory oxide having a monomodal mercury pore volume distribution wherein at least 50% of the total pore volume is present in pores having a pore diameter in the range of from 4 to 50 nm, a catalyst incorporating said carrier and having a high metals content. The catalyst finds use in hydrocracking refinery feedstocks.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04251241 | 2004-03-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
UA91016C2 true UA91016C2 (en) | 2010-06-25 |
Family
ID=34896131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA200610342A UA91016C2 (en) | 2004-03-03 | 2005-03-01 | catalyst carrier, catalytic compound, processes of producing thereof and process of hydrocracking with use of catalytic compound |
Country Status (11)
Country | Link |
---|---|
US (1) | US20050197249A1 (en) |
EP (1) | EP1735094A1 (en) |
JP (1) | JP2007526119A (en) |
KR (1) | KR20070004776A (en) |
CN (1) | CN100428995C (en) |
BR (1) | BRPI0508276A (en) |
CA (1) | CA2558172A1 (en) |
RU (1) | RU2366505C2 (en) |
UA (1) | UA91016C2 (en) |
WO (1) | WO2005084799A1 (en) |
ZA (1) | ZA200606951B (en) |
Families Citing this family (35)
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US7169291B1 (en) * | 2003-12-31 | 2007-01-30 | Uop Llc | Selective hydrocracking process using beta zeolite |
US6974788B2 (en) * | 2004-03-12 | 2005-12-13 | Chevron Oronite Company Llc. | Zeolite Y alkylation catalysts |
US7507844B2 (en) * | 2005-05-09 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides |
US7510645B2 (en) * | 2005-11-04 | 2009-03-31 | Uop Llc | Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha |
US7585405B2 (en) * | 2005-11-04 | 2009-09-08 | Uop Llc | Hydrocracking catalyst containing beta and Y zeolites, and process for its use to make jet fuel or distillate |
WO2007070394A2 (en) | 2005-12-14 | 2007-06-21 | Advanced Refining Technologies Llc | Method of making hydroprocessing catalyst |
RU2430778C2 (en) * | 2006-06-20 | 2011-10-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Sulphur-resistant, noble metal-containing catalyst for hydrogenating aromatic compounds and method of producing and using said catalyst |
US20080011647A1 (en) * | 2006-07-17 | 2008-01-17 | Li Wang | Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate |
US20080011649A1 (en) * | 2006-07-17 | 2008-01-17 | Li Wang | Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate |
US20080011648A1 (en) * | 2006-07-17 | 2008-01-17 | Li Wang | Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate |
CA2696607C (en) * | 2007-08-27 | 2017-01-17 | Shell Internationale Research Maatschappij B.V. | An aromatics hydrogenation catalyst and a method of making and using such catalyst |
WO2009105749A2 (en) * | 2008-02-21 | 2009-08-27 | Saudi Arabian Oil Company | Catalyst to attain low sulfur gasoline |
EP2424959B1 (en) | 2009-04-29 | 2020-04-08 | Shell International Research Maatschappij B.V. | Process of preparing a hydrocracking catalyst |
EP2424661B1 (en) | 2009-04-29 | 2020-12-16 | PQ Corporation | Zeolite y |
DE102009026585A1 (en) * | 2009-05-29 | 2010-12-02 | Evonik Oxeno Gmbh | Preparation of 3-methylbut-1-ene by dehydration of 3-methylbutan-1-ol |
US9187702B2 (en) | 2009-07-01 | 2015-11-17 | Chevron U.S.A. Inc. | Hydroprocessing catalyst and method of making the same |
JP5547923B2 (en) | 2009-08-03 | 2014-07-16 | 出光興産株式会社 | Heavy oil hydrocracking catalyst and method for hydrotreating heavy oil using the same |
WO2013060666A1 (en) | 2011-10-24 | 2013-05-02 | Total Raffinage Marketing | Process for preparing a hydroconversion catalyst, catalyst thus obtained and use thereof in a hydroconversion process |
WO2013092808A1 (en) * | 2011-12-23 | 2013-06-27 | Shell Internationale Research Maatschappij B.V. | Process for preparing hydrocracking catalyst compositions |
CA2847233A1 (en) | 2012-02-28 | 2013-09-06 | Sekisui Chemical Co., Ltd. | Catalyst for c2 oxygenate synthesis, device for manufacturing c2 oxygenate, and method for manufacturing c2 oxygenate |
KR101885247B1 (en) * | 2012-07-26 | 2018-08-03 | 삼성전자주식회사 | Co2 reforming catalyst, method preparing the same and method reforming co2 |
RU2640804C2 (en) * | 2012-09-17 | 2018-01-18 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Method for producing hydrocracking catalyst |
MX349965B (en) * | 2012-11-14 | 2017-08-04 | Univ Mexico Nac Autonoma | Catalysts supported for the production of ultra-light sulfur fuels. |
US20150159095A1 (en) * | 2013-12-09 | 2015-06-11 | Bi-Zeng Zhan | Method for making a middle distillate |
US10138428B2 (en) * | 2014-05-08 | 2018-11-27 | Reliance Industries Limited | Catalyst assisted conversion of biomass to bio-oil |
US20160121313A1 (en) * | 2014-10-31 | 2016-05-05 | Chevron U.S.A. Inc. | Middle distillate hydrocracking catalyst containing highly a stabilized y zeolite with enhanced acid site distribution |
US20160121312A1 (en) * | 2014-10-31 | 2016-05-05 | Chevron U.S.A. Inc. | Middle distillate hydrocracking catalyst containing highly nanoporous stabilized y zeolite |
US10183282B2 (en) * | 2015-01-22 | 2019-01-22 | Chevron U.S.A. Inc. | Noble metal zeolite catalyst for second-stage hydrocracking |
US10183286B2 (en) * | 2015-08-11 | 2019-01-22 | Chevron U.S.A. Inc. | Noble metal zeolite catalyst for second-stage hydrocracking to make middle distillate |
CN107344107B (en) * | 2016-05-05 | 2019-10-15 | 中国石油化工股份有限公司 | A kind of catalyst for hydro-upgrading and preparation method thereof |
RU2633965C1 (en) * | 2016-10-19 | 2017-10-20 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Method of producing catalyst of hydrocarbon raw material hydrocraking |
CN107469870A (en) * | 2017-08-29 | 2017-12-15 | 淄博齐茂催化剂有限公司 | A kind of preparation method for the catalyst for adjusting pore structure |
US20190126227A1 (en) * | 2017-10-30 | 2019-05-02 | Saudi Arabian Oil Company | Catalyst loading method to disperse heat in hydroconversion reactor |
SG11202106285TA (en) | 2018-12-13 | 2021-07-29 | China Petroleum & Chem Corp | Hydrocracking catalyst, preparation method therefor and application thereof |
FR3130640B1 (en) | 2021-12-21 | 2024-09-13 | Ifp Energies Now | Catalyst comprising a support based on a silico-aluminum matrix and zeolite, its preparation and process for hydrocracking hydrocarbon feedstocks |
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US4003851A (en) * | 1973-10-31 | 1977-01-18 | American Cyanamid Company | Stable alumina catalyst support, process therefor, and promoted support |
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US4085069A (en) * | 1976-08-27 | 1978-04-18 | Filtrol Corporation | Hydrothermally stable catalysts containing ammonium faujasite zeolites |
US4419271A (en) * | 1979-10-15 | 1983-12-06 | Union Oil Company Of California | Hydrocarbon conversion catalyst |
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US4572778A (en) * | 1984-01-19 | 1986-02-25 | Union Oil Company Of California | Hydroprocessing with a large pore catalyst |
JPS6115739A (en) * | 1984-04-25 | 1986-01-23 | Toa Nenryo Kogyo Kk | Hydrogenating-treatment catalyst |
FR2582665B1 (en) * | 1985-06-04 | 1988-08-05 | Inst Francais Du Petrole | CATALYTIC CRACKING PROCESS |
JPS62199687A (en) * | 1986-04-28 | 1987-09-03 | ユニオン・オイル・コンパニ−・オブ・カリフオルニア | Hydrogenation using catalyst having large pores |
US5160033A (en) * | 1988-03-30 | 1992-11-03 | Uop | Octane gasoline catalyst and process using same in a hydrocracking process |
US5223240A (en) * | 1989-08-16 | 1993-06-29 | Degussa Aktiengesellschaft | Method of preparing zeolite Y |
JP2547115B2 (en) * | 1990-03-30 | 1996-10-23 | 財団法人石油産業活性化センター | Hydrotreating catalyst composition for hydrocarbon oil and hydrotreating method using the same |
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JPH06154610A (en) * | 1992-11-27 | 1994-06-03 | Chevron Res & Technol Co | Catalyst for residual oil having high metal content, method for its production and process for its use |
US5435987A (en) * | 1993-07-22 | 1995-07-25 | Pq Corporation | Process for preparing ammonium zeolites of low alkali metal content |
EP0817676A1 (en) * | 1995-03-03 | 1998-01-14 | Shell Internationale Researchmaatschappij B.V. | Catalyst compositions and their use in hydrocarbon conversion processes |
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FR2780308B1 (en) * | 1998-06-25 | 2000-08-11 | Inst Francais Du Petrole | CATALYST CONSISTING OF A CLAY AND A VB GROUP ELEMENT, AND ITS USE IN HYDROCRACKING OF HYDROCARBON OIL FEEDS |
US6136291A (en) * | 1998-10-08 | 2000-10-24 | Mobile Oil Corporation | Faujasite zeolitic materials |
CN1096296C (en) * | 1998-11-13 | 2002-12-18 | 中国石油化工集团公司 | Hydrocracking catalyst for producing middle distillate and its preparation method |
JP3553429B2 (en) * | 1999-03-29 | 2004-08-11 | 株式会社コスモ総合研究所 | Gas oil hydrotreating catalyst and gas oil hydrotreating method |
JP4643805B2 (en) * | 2000-07-28 | 2011-03-02 | 日本ケッチェン株式会社 | Heavy hydrocarbon oil hydrotreating catalyst and hydrotreating method |
CN1108356C (en) * | 2000-10-26 | 2003-05-14 | 中国石油化工股份有限公司 | High-activity high-or medium-oilness hydrocracking catalyst and its preparing process |
FR2819430B1 (en) * | 2001-01-15 | 2003-02-28 | Inst Francais Du Petrole | CATALYST COMPRISING SILICA-ALUMINA AND ITS USE IN HYDROCRACKING OF HYDROCARBON CHARGES |
JP4156859B2 (en) * | 2001-06-20 | 2008-09-24 | コスモ石油株式会社 | Gas oil hydrotreating catalyst, method for producing the same, and gas oil hydrotreating method |
US20040064008A1 (en) * | 2002-09-30 | 2004-04-01 | Torsten Maurer | Molecular sieve catalyst composition |
WO2004050548A2 (en) * | 2002-11-27 | 2004-06-17 | Pq Holding, Inc. | High surface area zeolites and methods for preparation and use thereof |
US7192900B2 (en) * | 2002-11-27 | 2007-03-20 | Shell Oil Company | Hydrocracking catalyst |
FR2863913B1 (en) * | 2003-12-23 | 2006-12-29 | Inst Francais Du Petrole | ZEOLITHIC CATALYST, SILICO-ALUMINUM MATRIX AND ZEOLITE BASE, AND METHOD FOR HYDROCRACKING HYDROCARBON LOADS |
JP3990673B2 (en) * | 2004-02-09 | 2007-10-17 | 触媒化成工業株式会社 | Hydrodesulfurization method of light oil |
-
2005
- 2005-03-01 BR BRPI0508276-5A patent/BRPI0508276A/en not_active IP Right Cessation
- 2005-03-01 CN CNB2005800099444A patent/CN100428995C/en active Active
- 2005-03-01 US US11/069,425 patent/US20050197249A1/en not_active Abandoned
- 2005-03-01 KR KR1020067019894A patent/KR20070004776A/en not_active Application Discontinuation
- 2005-03-01 EP EP05716843A patent/EP1735094A1/en not_active Withdrawn
- 2005-03-01 UA UAA200610342A patent/UA91016C2/en unknown
- 2005-03-01 CA CA002558172A patent/CA2558172A1/en not_active Abandoned
- 2005-03-01 RU RU2006134729/04A patent/RU2366505C2/en active
- 2005-03-01 WO PCT/EP2005/050866 patent/WO2005084799A1/en active Application Filing
- 2005-03-01 JP JP2007501276A patent/JP2007526119A/en active Pending
-
2006
- 2006-08-18 ZA ZA2006/06951A patent/ZA200606951B/en unknown
Also Published As
Publication number | Publication date |
---|---|
US20050197249A1 (en) | 2005-09-08 |
CA2558172A1 (en) | 2005-09-15 |
EP1735094A1 (en) | 2006-12-27 |
WO2005084799A1 (en) | 2005-09-15 |
JP2007526119A (en) | 2007-09-13 |
CN1938088A (en) | 2007-03-28 |
RU2366505C2 (en) | 2009-09-10 |
BRPI0508276A (en) | 2007-08-07 |
KR20070004776A (en) | 2007-01-09 |
ZA200606951B (en) | 2008-04-30 |
CN100428995C (en) | 2008-10-29 |
RU2006134729A (en) | 2008-04-10 |
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