UA72464C2 - Agent for combating plant pests - Google Patents

Abstract

The invention relates to agents for combating plant pests, containing the compound of formula (I) mixed with fungicidal active agents. (I).

Description

shk nyat

Shcharotyasniao University, Wo o "Von eta Yan

WIDELY NAZOM sh- - ah S AS ; pri viyu nH un Y KO kohana, who Be (FLUTEIAFOI sp

I yFr ote nn, Koch YASNUrONU. VZ ON, what a stump

FTEXACOVASE

SYA

Troy nn VO xx YASNSYA, VOZ SV, drink pShkLOVUTANKO these days

NK in Y x yProvizsyau y-e VYA ee (ONIBOvu, VO, pk

Zduesi

MPENCONAZOLI and tu nou seni

FEUOVivbnYA M-VO VZ I bonev, holy ssha SE,

STURCONAZOLI p

Tk nedo Menakhya

On the days of Nih osn pk presented (ETACONAZOLE and ak OSS Nenen a action sno nn, NNYA pe up ptegei

PROMUCHONAZOIA

KI i o i z NI SS V VE VN x M vi KI tu -Osn--

PNO V'a«v-o U-- BUT NO and type

What! roar and i y

Hsh- you are already tt and WE: "well Ku bu oktyae nn V emu ON given hi (FENPUKONAJMY si i

Shiva works at 0, YOU x SVYUSKUNE;, VZN lk baki

SPITRACONACT

(Mb) в1я с-45о "2 х -СН(ОНУС(СНИВ, ВЗ -Н, пе, (TRIADIMENOL) (нй7) в- с- о иВ2 ж -СО-С(СНИ)й, ВЗаН, пе, ( TRIADIMEFONE)

sht tu , oh oh in -

Wo zhih yin VE of SNOKUDONS Nam yah,

Masses ee

PETER TANOLI

FI

- «m Te me SYA x -u a zap i 3

CMV Vera ZVU KA x UNI M VZN pe,

M dylanny

NOT LEUTRAZIA)

She Z I dya yah y

PA May day penya, KY oh YASNU, you, hlyalny

SDYNIKONAILI

(M Alilkoye pravznoldityu forurya St.: y B t a | oh

Ben EnNinM OO

KA sn, KI pc more

COURT

In n prp Ukhilazol (and an azolone derivative of the formula

HA

And with her, g

SD ote ben nosa dyan N Mne mlyagt sn sheshe she that This is PROHLOBAH ro blyolua them 5 ihibast derivative formupy mya yah SY

Ob satyny y Z: tyu schy Z ne Kk kt i

KA ki oh, I chem

M; by (FLUKIINCONAZOLE

ХО 0 Heizodcycle of the formula х р й х г х Mmeonu Nanya Vi х и их КН зн 52 "ХК вк

OZ, let him wake up from his sleep

STVADEMORYII

UNI, hek Vo ee саДДИМОГХЮ pl

DO NOT HYPOPHNAVONUUUUUUU for sleep Med zol M. art

TWENPROTMMO of the Russian Federation) ---2 st

Noah m. tsa A TU

NI HesnyuVbanaonuk nya evche vd sia

IENPROPILVNI

Ttushlopuku formula an a chu po Z Z Ya shi a Shi

And what about! 120

Zk MN sich ku ShK o z 7 "m E!

GO) 2500 Foomula compound

Sat, Sun, Sun, Sun, Sun, Sun

Little is this ke oh pulyuopuka yakmugy,

EV dya t po ni a na ee es x SYA Oh and I Kk ves

M

He; yes

ASIA

PIVIFENOMO

1) Slanukz formula

Pi

Oh hey Oyaoh-

ACT

KE, rhymes I I

MK pieces, hey! I'm still 7 (them

ОVENARIMOMO j) The compound of the formula

SEZ zshzhzhkhy, rn shShnnu not Mena they

I: I hear them

CHRIFBLUMOYULI

PM slopuka foruuli s h

KM

From 34 x. - everything! them, (a

Z gr janv vk NMT tn snu a o bnesv.

PINKLEYULIN)

(In tsu di

Er, no

See ШЙ r я ху . about Sn

PROM MIDONI iXhReZ o x i actions

CO of the Ministry of Emergency Situations and

PLRODISVI p4u Compounds of the fovmula ozhzhnnnu en ki nn t h INN Z

In, and from Manny Kr

VE

KE dah ikhh skh Etese

PSHIRIMETANILI ikh) vl- Sas,

SMENANTSPEIM

PC about bpoluki formula

Dream ОЮМ-5 A ОШЕ

FOR

Oh, I'm here

VIZ and NANNY ate KN

ILYCHLORFLUANIA

ХУ в сSN,

POLILVYAUANI per bpoluka tormula about

I. ana r s a i o i s o dl (V

IDY TANOV pt o Compound formula

NS MN MN; SNSOON

MN ped (HU

ONE

08) Popukhazvermuli s x A syu

MO onya Y sho m ke

С хро "(CHLOROTALONIL)

pu Compound of the formula "t mo x ma tk 7 i; kA she i shesNoO 0 i U i

I'm eating

I h

Dreams r.

Hey Sn:

THEIR)

IIMETOMORPHI

20) Compound duormula

Here

WHO ARE WE?

Shchi x

Syu-O-snino SHNASOYUV zm

Ki N "t pays kosh ai h

B. also -- dick (METALAXKL) (21 Compound of the formula

NEO MNASO MAO OM SN syu sr

AHY) (CHU KSAVII i22" The compound of the formula sr pzh (Z 7 (also t-8-fy -ny yah A:

No. From san min. Goats are given in the SEZ of the village of Ru

OM set, (UHCSO

BELOUAINKAMI

Хр Споуха of the formula nos ше ЧК т я Я и бю, : и ! not y M im z E re ek ky Kk.

IOV

Her ployluy fovmuly ssh-5-12 ey Mi sce g ltAniYa y AH

ХУ о х я внавій" M N і

AAI, Fr

CAPTAIN

(XXVI century

Sa: I wa M ra a ul

IFOLNPETI

SK Compound fovrzhula

NNYA p

M-y plyants

BASKETS of laundry Z x 7 and i em it schi (хХху

TANILAZNY)

05 Compound dosmutri mile pi gu NYA

Sv h ii 5 / scho i YAM y U ro KE V: ( ---- M

Hi ch- in the 4th TKU

HOKSadDNKSIA 70 Compound of the formula

BOYU 0. and Poison : mouse ! M a - p scha prin

And XX

(FOCETYL ALUMINUM) (I Compound of the formula 2-СО-СНеСН-СН; 0 X Sn-sac i i OZ m I. or in

Ministry of Health

Mo ho

IDENTIFIER ro Compound of formula te

Fo r

In and KU

And I can bend and 3 you ze and in the thick;

Her ve

WITH

7 until and

Stud t S dya

AHA about the Spole of the formula "t v t yo: te, i i ' i 1 Os v l sake:

In NV nor udiy My hets became M Snu slehkA

XX

IN) block of the formula in oi

M---y can't with 8 and and! in

I ate another 8

M- and a

ХХХЦ

SPRAKON)

P2u The compound of the formula pe i

K-; And - to her?

I M n a h 8 sh- zh: B yakh eh

ХХАХПХ

Their chychy goal «cineb) ХХХ your meme

IMANEBI

ХХХНИЛ MoeMyrua Mankozeb;

so bpoluka foosmula

From 5

Fu 0 Kmech 5-8 IHHAI

STIRAMY ate, Compound of the formula s p o i KO h reni 3 stele

Гты и пдв / M вл fe, Where I'm Sleeping

M XXX

PIMIEENCONAZOT : (ik compound of the formula

I peEsvmnonosnemnov va YAMI: : SVO MNSNESNeMNSV-V.) in Shk - and - XX uM

IMETNKAHMO id; o Specuk of the formula ra y sf ny y y st ; x her hmm

HERE The compound of the formula about cSnst i

Ffnuronoyone-MmnA-sn-Yaya ASV, and SH

PR o Compounds of the formula posa shii. tt h ii -' ki v cha S Powers 1: ki J

With many Sh

IZHAHIKH in which

VZ Her ВЭ independently of each other mean hydrogen atoms, halogen, methyl or phenyl group and

B!" means a hydrogen atom or a methyl group, (39) b-tert-butyl-2-(M-ethyl-M-n-propylamino)-methyl-1,4-dioxa-spiro|4,5|decane of the formula " Our Saint Sean nn shvsh- ОИ sSveneom; then them

Ben 0 kensny-s-СсНОВОуСМ, --Щ СНАХВОСНІ

NK bpoluka formula o 1 s d. DL tiy te her measures of battles and inc

(2) The compound of formula y

Mo

Oh

Go

MN

I9; i x fludiuksoniy si NI zer

SI where t! Fanpiklonium m D she shi i dya | AND

We would take SE, (13) The compound of the formula izv i

You- 0 9-сСНy-СНесNUM

Mann shk (443 Benzimidazole formula ve

And I,

Sn" kh

KE I DOUBTED; Vykh -MNOSOOMe Benomyl

Kt horse on Pabendvzol

Ne vn n Ve- MYSOOME Karbendaziy (45y Compound of the Putty Formula

And!

Kosyk

Мне СВ МНеООМе 46) The compound of the formula y qi SHHI

NMA Onodemn SM i- -4 (7 Compound of the formula s s x Kk ha x b-..335-kMo x y sany i s ny (48) Compound of the formula

Sleeping vases in

What is it?

It's an ear

D Ira son of d zey

Her and Mr. IN! " 4 These poison We -

1495 Formula compound

WITH

H

TC,

It has legs

ХМ that in My (50) The compound of the formula ох M г TS с р -

E oto M nie ro» ha same bud (51) Compound of the formula

AND

-

What will I throw, what and VS about 1372) Spepuka of the formula ;0 t-

Her same 87 "bai OT 5333 The compound of the formula is morn

І M sto Tobvnina rsotg "531) 0 FShlopyuyu shremuda breath, і

Because wow oh. melon saetmpovnzyZa mm ohm

TO blrluka of the formula

KU Evnokhfen o u hlogvkhm she shk KchShkYa i y Y me SHY:

The active compound of formula (I) is known from the European patent application Me 0375907. Fungicidal compounds are also known. For example, the following further publications describe: (1) Compounds of formula (II) Patent application FRG Me 2201063 Patent application FRG Me 2324010 Patent application FRG Mo 2737489 Patent application FRG Mo 3018866 Patent application FRG Me 2551560 European patent Mo 47594 German patent Mo 2735872 (2) Compounds of formula (II) European patent Mo 68813 US patent Me4496551 (3) Compound of formula (IM) German patent application Mo 2429523 German patent application Mo 2856974 Patent

USA Mo4108411 (6) Compounds of formula (MI) GDR patent Mo 140041 (7) Compound of formula (MI!) European patent Mo 382375 (8) Compound of formula (IX) European patent Mo 515901 (9) Compound of formula (X) European patent Mo 314422 (10) Compound of formula (XI) European patent Mo 49854 (11) Compound of formula (XII) German patent application Me 1770288 US patent Mo 3869456 (13) Compounds of formula (XIM) German patent Me 2207576 US patent Mo 3903090 US patent Me 3755350

US Patent Mo 3823240 (14) Compounds of Formula (XM) European Patent Me 270111 (19) Compound of Formula (XX) European Patent Me 219756 (34) Compound of Formula (XXU) US Patent Me 4512989 (38) Compounds of Formula (XXXIX) European Patent Me 398692 (48) Compound from international patent Mo

(49y Compound from international patent Me 96/16048; this compound can be represented by two tautomeric formulas (A) and (B)

SI SI sneb-R sneo- E

Sn sn same" 9ZN same" uh she

N

Compounds from groups (15), (16), (17), (18), (23), (34), (25), (28), (31), (32), (33) and from (38 ) by (47) are described, for example, in the book by K. N. Vyspei, "RMPapgepespii: pa Zspadiipdzrekatriipd", p. 121-153, ed. Georg Thieme, Stuttgart, 1977. The compound of group (39) is known from the European patent application Me281842. The compound from group (50) is known from the international patent application Me97/06171.

The compound from group (51) is known from German patent Me 2433410.

Compounds of groups from (52) to (54) are known from MU. Rashiv, "Mistobrisidez g She Rgoiesiyop oi Maiegia!v", Chapman 8. Hall 1993.

The compound of group (55) is known from the European patent Mo 0512349.

According to the invention, combinations of active substances contain, along with the active substance of formula (1), at least one fungicidal active substance selected, for example, from compounds in groups from (1) to (55). In addition, they may contain other active substances and usual auxiliary and additional components, as well as solvents.

Predominant active substances with fungicidal properties in the means according to the invention should be named: cresoxymethyl, tebuconazole, metalaxyl, azoxystrobin, triadimenol, bitertanol, fenpiclonil, cyproconazole, propiconazole, fludioxonil and triazoxides.

If the active substances in the combinations of active substances corresponding to the invention are in certain mass ratios, a pronounced synergistic effect of the mixtures is revealed. However, the ratio of the mass of active substances in such combinations of active substances varies in a relatively wide range. In general, from 0.1 to 10 parts by mass, preferably from 0.3 to 3 parts by mass, of at least one fungicidal active substance, for example from groups (1) to (55), is added to 1 part by mass of the active substance of formula (I).

The combinations of active substances according to the invention have very good fungicidal properties. they can be used primarily to combat phytopathogenic fungi, such as Riazthodiorpogotuseiyev,

Ootuseievz, Spuipidiotuseiyev, 7udotuseievz, Azsotuseiez, Vazidiotuseiez, Oeshegotusei!ez and others.

The combinations of active substances according to the invention are particularly suitable for combating diseases of cereal crops, such as Eguzirpe, Sospiyorois5, Zeriopa, Rugepornoga and I eryusrpayegia, as well as against fungal diseases of grapes, vegetables and fruit and berry crops, for example, against Mepissia or Rhodozrpayeg on apples, Osiptsia on the vine or Z5rnaegoiesa on cucumbers.

Such combinations of active substances are very well suited for combating pests that represent the animal world, mainly for combating arthropods, especially mainly insects that cause damage to agriculture and forestry; they can also be used for the protection of stocks and materials, as well as in the field of hygiene. They show activity against common sensitive and resistant species, as well as against all or individual phases of development. The above-mentioned pests include:

From the series of Izorod, for example, Opibzsiv azeshv, Appaaiiasht myYidage, RogseiPo 5sabeg.

From the Pirioroda series, for example, Viapishiv dikyiai!v.

From the Spiyuroda series, for example, seorpyi5 sagrorpadiv, bsciidega zres.

From the series 5utrpPuia, for example, bsciidegegeiiia ittasiiaia.

From the Tpuzapyga series, for example, I erizta sassnaip.

From the SoPetboia series, for example, Opuspiigi5 appaiiv.

From the Opporiega series, for example, Viatsa ogiepiaiii5, Regpiriapeiga ategisapa, I eisorpaya tadegaye, ViayeiYia deptapisa, Asneia dotevzviisiv, SguPoiaira 5rr., I osivia tidgayuga tidgayugioide5, Meiaporiiz ainegepiaiiv, Zspiviosegsa dgedaga.

From the Oeptaiioriega series, for example, Eopistsa atsygisshagia.

From the Izoriega series, for example, NeiiscShegptev yr.

From the Aporishga series, for example, Redisshiv pitapiz sogrogi5, Nayetaioripiz zrr., And ipodpayiv zrr.

From the MaIPornada series, for example, Tispodesies 5yr., bataiyipea grr.

From the Tpuzaporiega range, for example, NegsipoiPgirv Tetogaiiv, TNgirv gabasi.

From a number of Neyegoryeg, for example, Eshgudavzieg zrr., Ouzayegsiv ipiepptediyz, Riezta diaadgayga, Sitekh Iesyshapyv,

Apoapiiz rgoiikhiv, Tiayuta district.

From the Notoriega series, for example, AIeygodez Bgazvisae, Vetisia garasi, TpiaIeygode5 marogapyogit, Arpiz dozvuria,

Vhemisogupe Bbgazzisaye, Sturiyutuvzyvz gri, Bohaiyiv Tabae,

Bogaii roti, Epozota Iapidegit, Nuaiyur (egiv apipaipih, Masgovirnit amepaeye, Mugiz 5rr., Rpogodop pytiti,

Aporaiosirpyt radii, RNnuiPohega maviayih, Retrpidiv v5rr., Etroavzsa zrr., Eivseiiv riobraishve, Merpoientsikh sipsiiserv, I esapisht soti, Zaizetsia oieae, I aodeiIrnach vigpiatePiv, Miaragmaia Ishdepv, Aopidieia ashygapiiy, Azriaioshe

Pedegaye, Rzeidosossiz zrr., RzuyiYa 5yr.

З ряду І ерідорієга, наприклад, Ресііпорнога доззурієїа, Вирашве ріпіагіив, Спеітайбіа бгитаїйа, І посоПеїв ріапсагаєїа, Нуропотеша радеїІа, РішейнНа тасиїїреппіх5, Маіасозота пеивіпйа, Еиргосіїв спгузопнеєа, І утапініа врр., Виссшайіх ШигрегпеїйПа, РНуїоспівіїз сігейПМПа, Адгоїїз 5рр., Еихоа 5рр. , BeSha 5 years.

Sagrosarza rotopeia, Riegiz srr., Spo grr., Rugatsyvia pibiiaiii5, Erpezia Kienpieyiia, SaPepa teiPopepPa, Tipeoia

BrizzeyePa, Tipea reiopeia, Noitappornpiya rzecydozrgeiiieIia, Sasoesia rodapa, Sarca heisshapa, Spogpiziopecga titigegapa, Siuvia atridoeMya, Notopa tadpapita, Togpich miidapa. З ряду СоіІєорієга, наприклад, Апорійт рипсіашт, АПізорепна аотіпіса, Вгисніаіїв обіесіи5, Асапіпозсеїїдез обіесіив5, Нуіоїгирез Ба|шив, Адеїавіїса аіпі, І ерііпоїаїза десетіїпеаїа, Рпаєдоп сосНієатпає, Оіаргоїса з5рр., РевуПодез спгузосернаїа, Еріїаснпа магмевіїв, АЮютагіа 5рр., Огулаерпйив 5игппатепвів, Apipopotiv vrr., Zyuorpishv vrr., Obogpupspyv zitsyisaiv,

Sovtoroiyez zogaidiv5, Sespotpupspyv avvzitiiyy5, Nurega roziisa, Oeppeviyez srr., Tgododegta 5yr., Apipgepyv 5yr., Ayadepiz v5yr., I usiiv vrr., MeiyideIpev ayepetsv, Riyipiz 5rr., Mirshve Ppoioieysivy, Sirbisht reguiPoidev 5, Tepiroyi Topiroi. Adgioie5 zrr., Sopodegiz 5rr., MeIiopipa teiIiopina, AtrPitayop zoiviyaiiv, SoviePuna 7eaiapaisa.

From the Nuteporiega series, for example, Oirgiop 5yr., Noriosagpra grr., I aziye yr., Mopotoigyit rpagaopiv, Mezra yr.

From the Oiriega series, for example, Aedez g5yr., AporpeiIyez gzrr., Ssheh vrr., Ogozorpiia teiIapodavieg, Myvzsa gzrr.,

Rappia gr., Saiyirpoga eguipgoserpaiia, Hisiia srr., Spguzotuia 5yr., Sshciegerga 5yr., Savzigorpiiv 5yr.,

Nurrorozsa sr., 5iotokhuv sr., Oeevigiz 5r., Nurodepta sr., Tarapiz sr., Tappia 5r., Virbio popshapyv,

Ozsipeia her, Rpoibia srr., Redotuia Nuozsuati, Segashiv sarigaa, Yuasiz oIeae, Tirsha raindosa. Plants tolerate combinations of active substances in concentrations necessary for combating plant diseases, and this allows processing of both aerial parts of plants and seed material, as well as soil processing.

The combinations of active substances according to the invention can be translated into conventional preparative forms, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, finely dispersed encapsulated forms in polymeric substances, preparations for ultra-small-volume spraying, they can also be administered to the composition of polymer coatings for seeds.

These preparative forms are made by known methods, for example, by mixing active substances with solvents, that is, with liquid solvents, with liquefied gases under pressure, and/or with solid substances - carriers, in appropriate cases with the use of such surface-active substances as emulsifying agents and/or dispersing agents and/or foaming agents. When using water as a solvent, you can use, for example, organic solvents as auxiliary solvents. The liquid solvents can mainly be aromatic compounds such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic compounds or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins such as distillation products petroleum, as well as alcohols, for example, butanol or glycol, and their simple and complex esters, such as ketone, acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, solvents with high polarity, for example, dimethylformamide and dimethyl sulfoxide, as well as water. Liquefied gaseous solvents or carrier substances are defined as liquids that are in a gaseous state at normal temperature and pressure, for example propellants for aerosol preparations, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide. As solid substances - carriers can be used, for example, ground rock, such as kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite, or infused earth, as well as ground synthetic minerals, such as finely dispersed silicic acid, oxide aluminum and silicates. For example, crushed and fractionated natural minerals, such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granules based on inorganic and organic ground materials and granules from organic materials, can act as solid substances - carriers for granular preparations , such as wood flour, coconut shells, corncobs and tobacco stalks. As emulsifying and/or foaming agents can act, for example, nonionic and anionic emulsifiers, such as polyethylene oxide ester of fatty acids, polyethylene oxide ether of fatty alcohols, for example , oxyethylated alkylphenols, alkyl sulfonates, alkyl sulfates, aryl sulfonates, as well as protein hydrolysates. Dispersants can be, for example, lignin sulfite alkalis and methyl cellulose.

To improve the adhesion of preparation forms, you can use, for example, carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids. Mineral and vegetable oils can act as other additives.

Application can find such coloring substances as inorganic pigments, for example, iron oxide, titanium oxide, blue ferrocyanides, and organic dyes, such as alizarin and metallophthalocyanine dyes, azo dyes, and trace elements, for example, salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

The content of active substances in preparative forms in general can be from 0.1 to 95 wt. to, preferably from 0.5 to 90,905.

According to the invention, combinations of active substances can also be present in preparative forms in a mixture with other known active substances, such as fungicides, insecticides, acaricides, herbicides, as well as in mixtures with fertilizers and plant growth regulators.

Combinations of active substances can be used as such, in the form of their preparative forms or in the form of ready-to-use preparations prepared from them, which are solutions, emulsifiable concentrates, emulsions, suspensions, duets, wettable powders, and granules.

Application is by conventional methods, such as watering, spraying, sprinkling, dusting, brushing, dry, semi-dry and wet etching, application of the etchant in the form of a suspension or in an encrusting composition.

When processing plant parts, concentrations of active substances in ready-to-use forms can vary widely. In general, they range from 1 to 0.0001 wt. 956, mostly from 0.5 to 0.001 95.

In general, amounts of active substances from 0.001 to 50 g per kilogram of seed, preferably from 0.01 to 10 g, are required for seed treatment.

When treating the soil, the concentration of active substances at the site of action should be from 0.00001 to 0.1 mass. 95, preferably from 0.0001 to 0.02 wt. 90.

In addition, it turned out that the combinations of active substances corresponding to the invention demonstrate high insecticidal activity against insects that damage technical materials.

As predominant examples, without limiting the scope of legal protection, such insects can be named.

These are bugs like

Nuioipyrez Ba|shiv, Spiogorpogiv rhyosis, Apobisht rypsiait, Heviobisht hyomyositis, Riyipiv resiisotiv,

Oepagobisht repipeh, Etobiiz toiiyiv, Robit sagripi, Husiiv rgippeiv, And usiiv apisapiv, Husiiz riapisoiiv, Gustiv

Ipeagiz, everything ryrezsep5, Todohuyup aeditsaiye, Mipipevz hydisoiyiv, Huierogiz zres, Puriodepagop res, Araiye topaspyv, Voziguspyv sarisipv5, Negegoroviguspyv bhyppetsv, bZipohuiop 5res, Oipodegiv tipyshv.

Such lepidoptera as

Zigekhiiimepsiv, Ogosegiz dida5, Ogosegiv didaz (aidpy5, Ogosegiv aiydig.

Such termites as

Kaioiegptez Pamisoiyiv, Sturioieptev Bhemiv, Neiegoieptev ipaisoia, NeysySheptevz Pamirev5, VeiiscShegtev zapiopepzi5, Veisciyeptev sycdiv5, Mavzioieptez dagmipiviepviz, 2ooieeptorvziz pemadepzi5, Soriyuyetgtev tyugptozapiv. Such bristletails as I erieta zasspagiipa.

In connection with the above, technical materials should be understood as inanimate materials, for example, primarily plastics, adhesives and glues, paper and cardboard, leather, wood and wood processing products, as well as coatings for them.

As for insect damage, it is necessary to protect mainly such materials as wood and wood processing products from them.

Wood and wood processing products, which can be protected by means of the invention and, accordingly, mixtures containing them, include, for example, wooden building materials, wooden beams, railway sleepers, bridge parts, moorings for ships, wooden vehicles, boxes, pallets, containers, telegraph poles, wood paneling, wood window frames and doors, glulam, veneer, carpentry or wood products generally used in building or carpentry .

Combinations of active substances can be used as such, in the form of concentrates or in the form of such conventional preparation forms as powders, granules, solutions, suspensions, emulsions or pastes.

The above-mentioned preparation forms can be obtained by the usual methods used for this, for example, as a result of mixing active substances with at least one solvent or, respectively, a diluent, emulsifier, dispersant and/or binding agent or with a fixing agent, with a water-repellent composition; if necessary, they may include desiccants and agents for increasing resistance to UV radiation, dyes and pigments may be added, as well as other processing aids.

Insecticides or concentrates used to protect wood and wood materials contain the active substance corresponding to the invention in a concentration of 0.0001 to 95 wt. 95, preferably from 0.001 to 60 wt. 95.

The amount of the agent or, accordingly, the concentrate used depends on the appearance and habitat of the insects, as well as on the environment. The optimal amount required for processing can be determined in each specific case in a series of experiments. In the general case, however, it is sufficient to use from 0.0001 to 20 wt. 905, preferably from 0.001 to 10 wt. 95, active substance based on the material to be protected.

The solvent and/or thinner is a chemical organic solvent or a mixture of solvents, or an oily or oily chemical organic solvent or a mixture of solvents with low vapor pressure, and/or a polar chemical organic solvent or a mixture of polar solvents, and/or water with the possible addition of an emulsifier and/or wetting agent.

Oily or oil-like solvents with an evaporation number greater than 35 and a flash point greater than 30"С, preferably greater than 45"С are preferably used as a chemical organic solvent. As such low-volatile and water-insoluble oily or oily solvents, suitable mineral oils or their aromatic fractions, or mixtures of solvents containing mineral oils, preferably white spirit, kerosene and/or alkylbenzene, are used.

It is preferable to use mineral oils with a boiling point in the range from 170 to 220"C, white spirit with a boiling point in the range from 170 to 220"C, spindle oil with a boiling point in the range from 250 to 350"C, kerosene and aromatic compounds with boiling point in the range from 160 to 280"C, turpentine and similar solvents.

In the preferred embodiment of the invention, liquid aliphatic hydrocarbons with a boiling point in the range from 180 to 210"C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling point in the range from 180 to 220"C and/or spindle oil and/or monochloronaphthalene are used, preferably a-monochloronaphthalene. Organic high-boiling oily or oil-like solvents with an evaporation number higher than 35 and a flash point higher than 30"C, preferably higher than 45"C, can be partially replaced by chemical organic solvents with high or medium volatility, provided that such a mixture of solvents also is characterized by an evaporation number of more than 35 and a flash point of more than 30"C, preferably more than 45"C, and that the insecticide-fungicide mixture is soluble or can form an emulsion in this mixture of solvents.

According to the preferred embodiment of the invention, part of the organic chemical solvent or mixture of solvents is replaced by an aliphatic polar organic chemical solvent or mixture of solvents. Preferably, aliphatic organic chemical solvents containing hydroxyl groups and/or ester groups and/or ether functional groups are used for this purpose, for example, it is a simple ether based on glycol, a complex ether or similar solvents.

As organic chemical binders within the scope of this invention, known ones are used that are diluted with water and/or soluble or dispersible or, accordingly, emulsified in organic chemical solvents, and artificial resins and/or binders based on drying oils are used, preferably adhesives consisting of an acrylate resin, a vinyl resin such as polyvinyl acetate, a polyester resin, a polycondensation or polyaddition resin, a polyurethane resin, an alkyd resin or a suitably modified alkyd resin, a phenolic resin, a hydrocarbon resin such as an indencumarone resin, a silicone resins, drying vegetable oils and/or drying oils, mAbo physically drying binders based on natural or artificial resin, as well as binders containing these resins.

The artificial resin used as a binder can be introduced into the composition in the form of an emulsion, dispersion or solution. Bitumen or bitumen products can also be used as binders in the amount of up to 10 wt. 90. In addition to this, known dyes, pigments, water repellents, aromatic perfumes and inhibitors, such as corrosion protection agents, etc., can be used.

The agent or concentrate according to the invention should contain at least one alkyd resin or a suitably modified alkyd resin and/or drying vegetable oil as the preferred organic chemical binder. According to the invention, preference is given to alkyd resins with an oil content of more than 45 wt. 95, preferably from 50 to 68 wt. 905.

The above binder can be completely or partially replaced by a fixing agent (mixture) or a plasticizer (mixture). These additives should prevent the evaporation of active substances, as well as their crystallization or, accordingly, their precipitation. Preferably, when they replace from 0.01 to 30 90 of the binder (based on 100 95 of the binder used).

Plasticizers are such chemical classes as phthalic acid ester, for example dibutyl-, dioctyl- or benzylbutyl phthalate, phosphoric acid ester, for example tributyl phosphate, adipic acid ester, for example di-(2-ethyl-hexyl) dipinate, stearates. for example butyl stearate or amyl stearate, oleates, for example butyl oleate, glycerol ether or high molecular weight glycol ether, glycerol ester, as well as esters of l-toluenesulfonic acid.

The chemical basis of fixing agents is a polyvinyl alkyl ether, for example polyvinyl methyl ether, or a ketone, for example benzophenone, ethylbenzophenone.

As a solvent or thinner, the main role belongs to water, which can be included in the composition in a mixture with one or more of the above-mentioned organic chemical solvents or, respectively, thinners, emulsifiers and dispersants.

Particularly effective protection of wood is achieved by industrial methods of impregnation, for example, in the processes of vacuum, double vacuum treatment or pressure treatment.

Ready-to-use mixtures may, if necessary, contain other insecticides.

As additional components of mixtures, it is preferable to use insecticides described in the international patent application Mo 94/29268. The compounds listed in this document represent the main constituent part of this invention.

As particularly preferred additional components of the mixture, such insecticides as chlorpyrifos, foxime, silafluofin, alphamethrin, cyfluthrin, cypermethrin, deltamethrin, permethrin, imidacloprid, M1-25, flufenoxuron, hexaflumuron and triflumuron should be mentioned.

The high pesticidal activity of the combinations of active substances according to the invention is demonstrated by further examples. While individual active substances or known combinations of active substances show insufficiently high pesticidal activity, the tables of further examples clearly show that the revealed effectiveness of the combinations of active substances according to the invention exceeds the total effectiveness of individual active substances, and also exceeds the effectiveness of known combinations of active substances.

In the following examples, the active substance of the formula (I) is used in mice and mice.

M. "MO

Other fungicidal active substances used together with it are indicated in the examples.

Example A

Experiment on larvae of Rpaedop

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 mass part of alkylaryl polyglycol ether

To obtain the appropriate form of the ready-to-use active preparation, mix 1 part of the mass of the active substance or combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

Cabbage leaves (Vgavvzysa oIeegasea) are treated by dipping them in a preparation with the desired concentration of the active substance, and the larvae of the rape leaf-eater (Rpaedop sospieapaye) are transferred to the still wet leaves.

After the end of the control time, the percentage of death of larvae is determined. At the same time, 100 95 means that all beetle larvae have died; 0 95 means that none of the beetle larvae died.

According to the results of this study, for example, the following combinations of active substances according to the invention demonstrate a synergistic increase in efficiency compared to the active substances used separately.

Table A (Insects - pests of plants) Experiment on larvae of Rpaedop and substances: VechoBinsumaci diTIVNYH; : : rechomyk I ZU yvtvy tones he, oh, dooo3u | a b : According to the formula (| ! | : now what !!! ! And Dreams. ry iOSN : and she TO" !

Example B

An experiment on RisheyPa

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 mass part of alkylaryl polyglycol ether

To obtain the appropriate form of the ready-to-use active preparation, mix 1 part of the mass of the active substance or combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

Cabbage leaves (Vgavvzisa oIeegasea) are treated by dipping in a preparation with the desired concentration of the active substance and the caterpillars of the cabbage moth (Richeia huiozie Pa) are transferred to the still wet leaves.

After the end of the control time, the percentage of death of caterpillars is determined. At the same time, 100 95 means that all caterpillars have died; 0 95 means that none of the caterpillars died.

According to the results of this study, for example, the following combinations of active substances corresponding to the invention demonstrate a synergistic increase in efficiency compared to the active substances used separately.

Table B 1/2 (Insects - pests of plants) Experiment on RicheiPa

GT obucektyuovysimumii vkpyanty: 00 Kene ootsiya dtyaenih 1 oanyny in ! Rvosvyk N substance sad vytnakUh: I! : Let's go! and with where and : ! and syu For M and chn: : x and I! at

In Corresponding to dizhmuva () : :

OT about suv:

E and M : : ! : Teyusonazod : : I and 7 Ж sevosn, : : !

Y yaz : and and Throwing : ! IS

And ppfuzhea killed Vada

GoOyuadnyu Mena 000000 LIVES

Example B

An experiment on Neiot migesepz

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 mass part of alkylaryl polyglycol ether

To obtain the appropriate form of the ready-to-use active preparation, mix 1 part of the mass of the active substance or combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

Shoots of soybeans (Siusipe tah) are treated by immersion in a preparation with the desired concentration of the active substance and the caterpillars of Neioin migezsepv are transferred to still wet leaves.

After the end of the control time, the percentage of death of caterpillars is determined. At the same time, 100 95 means that all caterpillars have died; 0 95 means that none of the caterpillars died.

According to the results of this study, for example, the following combinations of active substances corresponding to the invention demonstrate a synergistic increase in efficiency compared to the active substances used separately.

Table B (Insects - pests of plants) Experiment on RicheiPa

GOBEvkIresovnisme which: 1 Kovi yaktnykh 100 aAVEy

E rechevsnn : rechovUtsisumishyamanykh ! and ! ! reslyak 6 I ! g shi shi nn: inshsh i sy shi nen : ! b

According to the formula of : : ! listen! | : ' in EK and ysNh : 5 ! | :

I gave mlrok: : ! ! 7 Fershmula y) oseayutrovn 000000 OVO sh

Example G

Experiment on Merpoietsy

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 mass part of alkylaryl polyglycol ether

To obtain the appropriate form of the ready-to-use active preparation, mix 1 part of the mass of the active substance or combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

The sprouts of rice (Ogula zaina) are treated by immersion in a preparation with the desired concentration of the active substance, and the green rice cycads (Merpogiei cypsiiserv) are transferred to the still wet leaves.

After the control time, the percentage of death is determined. At the same time, 100 9o means that all cicadas have died; 0 95 means that none of the cicadas died.

According to the results of this study, for example, the following combinations of active substances corresponding to the invention demonstrate a synergistic increase in efficiency compared to the active substances used separately.

Table G 1/2 (Insects - pests of plants) Experiment on Merpoietsy: rechoken t orezshenmoumina: actovyh : H : ! substances in! shi pon or; : : ! : what : ! and Nidpovdcho to the forms: ! ! : bot we swarm; : I

POV ovtsisn : ! ! MetnihksiiY N Ya: g Shoreula Ve MEtanay 7 evaya d

Example

Threshold concentration test/Soil insects

Experimental insect: 5rodoriega hydiregda

Solvent: 4 parts by mass of acetone

Emulsifier: 1 mass part of alkylaryl polyglycol ether

To obtain the appropriate form of the ready-to-use active preparation, mix 1 part of the mass of the active substance or combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

The ready-to-use form is thoroughly mixed with soil. At the same time, the concentration of the active substance in the preparative form plays almost no role, only the content of the active substance or, accordingly, the mixture of active substances per unit volume of the soil, which is indicated in parts per million (mg/l), is of decisive importance.

The soil is placed in pots with a volume of 0.5 l and left at a temperature of 20"C. Immediately after filling, three germinated corn grains are placed in each pot. After the corn grains have germinated, perforated sleeves are installed on the pots. 9 days after the start of the experiment, test insects are planted on corn. After another 5 days, the percentage of death is determined. At the same time, 100 95 means that all test insects died; 0 95 means that the number of live insects is the same as in the untreated group.

In this study, for example, the following combinations of active substances according to the invention demonstrate a synergistic increase in effectiveness compared to the active substances used separately.

Table D 1/3

An experiment on brodoriega Igidiregaa and yumapoaynyanumny active 0 Komcentoaya ZylvinHx 1000 VVA! substances about rneshaiKisuuyui ZKTIkNiH S u : ! : Pechovyn BM, : N

The purpose of N Z and C! Yo! ' ГЙ Km я U : t : zi Nevkovn ' i 5 Or, esti Y va i

N M.: N! Oh: : and Podlovidno to folmulkh Y : : ! mouths: N and her stump ': it

N sh-k : : ! : Oh : and :

N : ' and tyukukhkonamt! : and sOsnUh : yes : and And ! N -: N i: z i: i i a. drinking : : ! ' WITH M I N : ' ! Shy : : :

N Tredduavno : : N and Y N : : A : and mouth : :

N ! eh!

N . EE : : and ! S and Me and : ! ! ИЧ ш : и : ан чи : : и бывртякий Н : Н

Table D 2/3 (Continuation)

An experiment on brodoriega pydiregaa

GOBELzhn recholynitumei zitsheiiy 10 Kanpechsrvshyaktyavnyh 1000 allele ! rivulets: pechleinayuya active oi yah and ! : substances Kk : : i o Iii H 2 : ШЧI '

And. "ih Y : H "Tit y H '

N HY y y y ! ! i No N NU N : ! nak chai : : I t NYA x 1. t z

Y Gu N: N

I U, KU: N

I'm here ::

N penekloyuya : : : no NN na NA NO nn ! and :

НН х и : и Н : : ! : but I taye and : 2, Щ Х that : : about NGO p. CMU ::

N z a Me N! her: i

N them; N : Avpesistya : : i

РОбюрицы: ! !

N o t SHE : i : we Y eh - : i ! Well, why? B: ! . with : : : N y she : N ! : : !

H. Metalaxy : : :

Olya St. chne : ! ! Ba i "zhen ' N i : U ! me Y : i

More :

N Tsenrokonyaaoi : : a o

Table D 3/3 (Continued)

An experiment on brodoriega Ppidiregda

GOfyut ren umn ayannih 0 Zhomosntrasya verse 000 data

N yam» iorysyamitumnii ktivnyakh al N ! ! emokom m A : I : t Ka sh i ' ! me shi she! Пропихана : ! ! ! "p ferushna I Tobukanyazoy T pe NN nn SNY ! ; : plo uv | Za ! : podo e vod : Zo ! puvimuna y; Triydymenosi : ieszrniknu : z !

I : pato : Zo i : : lot oo : vo N v ne pi V sh: M is S i i svo moi : v : : zap voi : to ! ! N plo ego: shcha N seams NN WITH HIM NOT

N: zva Ya ho! : and ze ' a

Her and zdo o: Zo and ! : ode to the sheep : 2 !

Table D 4/3 (Continuation)

An experiment on brodoriega Ppidiregda

Formula (1) k

Cyproconazole 1.25-20.00 100 0.60 - 20.00 50 0.30 - 20.00 (9)

Formula (1) k

Propiconazole 1.25 - 20.00 100 0.60 - 20.00 90 0.30 - 20.00 70

Example E

Experiment to determine the threshold concentration/Systemic effect through the roots Test insect: Larvae

Solvent: 4 parts by mass of acetone

Emulsifier: 1 part by mass of alkylaryl polyglycol ether. To obtain the appropriate form of the ready-to-use active drug, mix 1 part by mass of the active substance or, accordingly, the combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

The ready-to-use form is thoroughly mixed with soil. At the same time, the concentration of the active substance in the preparative form plays almost no role, only the content of the active substance or, accordingly, the mixture of active substances in a unit volume of soil, which is indicated in parts per million (mg/l), is of decisive importance.

The soil is placed in pots with a volume of 250 ml and cabbage (Vgazvisa oiegasea) is planted in them. An active substance or, accordingly, a combination of active substances can thus come from the soil and be transported into the leaves.

After 7 days, the above-mentioned experimental insects are planted on the leaves. After three days, the percentage of death is determined. At the same time, 100 95 means that all test insects died; 0 9o means that there are as many live insects as in the untreated group.

In this study, for example, the following combinations of active substances according to the invention demonstrate a synergistic increase in effectiveness compared to the active substances used separately.

Table E 1/2

Experiment on Rpaedop sospiyeagiea shi V VE V ! rekheimh : reopeinysumii eager and

I I things I A : ! hu her still : ze : children tons of sleep : what : s Ya

Kk y y sha: mm i cho N i N she ia zn! "WE ! g sen ! and m-k7 : : : (more

M : : : : Teyukokayut : : Y nn | ! E: A: I

I n Ying I! 1st : : ! Triddimenol : : And we still, ! :: shi vn! ! ! o ai ki: And! Biterujanoya ::

Table E 2/2 (Continuation)

Research on Rpaedop sospiagiea.

GOAtzhni peodnkenkyuayaisninonoh 00 Confbntranya deeniakh 00 Zaoleya ! active substances and substances. ! : ! ! peayuyn ku : I : 1 V : : N : NOV shk : : !

I vu WHOSE : : : pli : mm A and I and Ffenpikovnyi I : ! certain breath! IS

I sm BUT a, ih : : : azkystrosiv : : ! and r A I ! must ::

Who are you, : :

She MY :: Miznpaksii :: and shk Ge. | | : those

Heli : - what : : : More : : and ! At N: !

Table D 3/2 (Continuation)

Research on Rpaedop sospiagivea

Concentration

Active active substances/mixture of substances/mixtures Death of active substances active substances in 95 1.25 - 20.00 100

Formula (1) k

Tebuconazole 0.60 I 20.00 80 0 ZO I 20.00 80 1 25 20.00 100

Formula (1) is 0.60 20.00 100

Triadimenol " " riad 0.30 - 20.00 100

Formula (1) with 1.25-0.00 100

Bitertanol 0.60 - 20.00 100 0.30 - 20.00 70

Formula (1) 125-2000 100

Fenpiclonil o 60 5 20.00 100 0.30 - 20.00 70

Formula (1) from 1.25 - 20.00 100

Azoxystrobin 0.60 20.00 Zo 0.30 - 20.00 50

Formula()» 06012000 100

Metalaxyl 0.30 - 20.00 BO

Formula (1) from 1.25 - 20.00 100

Propiconazole 0.60 20.00 100 0.30 - 20.00 90

The experiment of J

Formula for calculating the measure of effectiveness of a combination of two active substances The expected effectiveness of a specific combination of two active substances can be calculated as follows (5.A. SoiBu, "SaIscaipo

Zupegadiviis apa Apiadopiviis Nezropzez oi NegrisiZde Sotbripayopv", UUeadz 15, pp. 20-22, 1967): if

X means the measure of efficiency, which is expressed as 95% of the untreated control, when using the active substance A at the consumption rate of t g/ha,

U means the measure of efficiency, expressed as 95% of the untreated control, when using the active substance B at the consumption rate of n g/ha and

E means a measure of efficiency, expressed as 95% of the untreated control, when using active substances A and B at consumption rates t and n g/ha, then

E-HU KU 100

If the experimentally established fungicidal activity exceeds the calculated one, then the activity of the combination is superadditive and this means that we are dealing with a synergistic effect. In this case, the measure of efficiency observed in the experiment should be higher than the value of the expected measure of efficiency (E) calculated by the above formula.

Test on contact activity in relation to Rpuiorpyroga on tomatoes.

Solvent: 47 parts by mass of acetone

Emulsifier: From part of the mass of alkylaryl polyglycol ether

To obtain an appropriate ready-to-use form of the active substance, one part of the mass of the active substance or, accordingly, a combination of active substances is mixed with the indicated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration, or the preparative form of the active substance that is available for sale is diluted with water to the desired concentration , or combinations of active substances.

To study the contact activity, young plants are sprayed with the preparative form of the active substance, which is available for sale, with the specified rate of consumption. After drying the applied preparation, the plants are inoculated with an aqueous suspension of spores of РНуюрпиога ипевиап5. After that, the plants are placed in an incubation cabin with a temperature of approximately 20"C and a relative humidity of 100,905.

Three days after inoculation, the condition of the plants is assessed. At the same time, 095 corresponds to the measure of effectiveness on untreated control plants, while the measure of effectiveness of 10095 means that infection of plants is not observed.

The following table unequivocally demonstrates that the effectiveness of the observed combinations of active substances according to the invention exceeds that calculated by the above formula, thus confirming the synergistic effect.

Table F/.

Research on contact activity in relation to Rpuiorpinoga on tomatoes

N tkhtism rЭЦСВСНатумнц ВКТИВНЫ pdkokne pechionnellyuy My etsmekiivioNm With : substances : ACTIVE rezivnyh i di calculated anaiyedene: i U i, I : N sho v ananeei ! ше : : ' Ekanovidko to Shormute : I ! and also she : : and writes not | | :

І Prodljoesaop I:

Goru woyak 7 EE Zaka E

Table F/2.

Research on contact activity in relation to Rpuiorpinoga on tomatoes

Gpzhryvna resoliniyauin yaknizhnyh S Active roar: VKA UdeIaNoe

I prepare 1 active pecsons I: what! ! : sta : opirEKOVanhlecideno : : seti they ste : ! ;

With ! ! According to pyrmuma : : du t tt : і :

Y and N Her. : : N shi o an : -yi : ! : Tovadymeetsa : : !

Table F/Z.

Test on contact activity in relation to Rpuiorpinoga on tomatoes! rezhonen : active remyuvim V and : Bo

N : calculated and found out the number of points, : : ! b : ! : didpovidep to the form | I: bony chor, :On it: ; ! ! t ' Metopaksyuh : :

Example C

An experiment on contact activity in relation to brpayegoines on cucumbers. Solvent: 47 parts by mass of acetone

Emulsifier: From a part of the mass of alkylaryl polyglycol ether To obtain an appropriate ready-to-use form of the active substance, mix one part of the mass of the active substance or, accordingly, a combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration or dilute the preparative form of the active substance with water to the desired concentration , which goes on sale, or combinations of active substances.

To study the contact activity, young plants are sprayed with the preparative form of active substances, which is available for sale, with the specified rate of consumption. After drying the applied preparation, the plants are inoculated with an aqueous suspension of spores of Brpaegoiis Shiidipea. After that, the plants are installed in the incubation cabin at a temperature of approximately 20"C and a relative humidity of 100 95.

Ten days after inoculation, the condition of the plants is assessed. At the same time, 0 95 corresponds to the measure of effectiveness on untreated control plants, and the measure of effectiveness 100 95 means that infection of plants is not observed.

The following table unequivocally demonstrates that the observed effectiveness of the combinations of active substances according to the invention exceeds that calculated by the above formula, thus confirming the synergistic effect.

Table 3/1.

An experiment on contact activity in relation to Zrpayegoines on cucumbers.

Glen race bathes Kana VEINS SOAP pH

H is not alive. of active lawsuits Va to N! ' calculated zhkidenoi ! pyt dexni dn | ! !

I ? mouth : i

N. Mo. : : N

N Mo : : i

According to sbormulnii : : : SKode Sh i t ! then! and Ve a se : !

M

! and : ! and Tsypookrova and N!

GL lvarmio from Tsroai Prava tu fri mon What

Table 3/2.

An experiment on contact activity in relation to Zrpayegoines on cucumbers.

If active wounds are used: Measure: rum and cooked foods: 7:

N і грпзражаваноетхидеиги ! seam of St., : ! and according to pormale : : ! WE : : ! b zhk : i : : VM : ! I ! SENIOR : : !

Example

An experiment on contact activity in relation to Vogguia5 on beans. Solvent: 47 parts by mass of acetone

Emulsifier: From a part of the mass of alkylaryl polyglycol ether To obtain an appropriate ready-to-use form of the active substance, mix one part of the mass of the active substance or, accordingly, a combination of active substances with the indicated amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration or dilute with water to the desired concentration the commercially available preparative the form of an active substance or a combination of active substances.

To study the contact activity, young plants are sprayed with a preparative form of active substances with the specified consumption rate. After the applied drug has dried, two small pieces of agar sprouted from Voiguiis sipegea are placed on each sheet. Inoculated plants are installed in a darkened chamber at a temperature of about 207C and a relative humidity of 100 95.

Two days after inoculation, the size of the affected areas on the leaf is evaluated. At the same time, 0 95 corresponds to the measure of effectiveness on untreated control plants, and the measure of effectiveness 100 95 means that infection of plants is not observed.

The following table unequivocally demonstrates that the effectiveness of the observed combinations of active substances according to the invention exceeds that calculated by the above formula, thus confirming the synergistic effect.

Table 1/1.

An experiment on contact activity in relation to Vogguia5 on beans.

STAGES OF THE OWL M Vykh AKIOYA roar I Min sennya: real. : vyutivnyh rezpemnoe sia! p : i : pikharohovansyaiyayn chic shchi | ! ! Kk : ! ) ! Q. : : ! Shishlovidno where she slept (V ! and !

Pl, seh NN skh VYN and "NN

Table 1/2.

Test for contact activity in relation to Vogguia5 on beans.

Idy rstoeksiaumke Zenyk Aktovna pelvinyaniki Mira fyutnosetya

N yomovyn I ZVytivnykh reovkhm i tia: Z. i i : iuhorakhtaih kuzmaidyanu tyni i nn yn eh pit un ! U I N : ! : Corresponds to the form U | ! !

FLOW of education! and it zones : : and

Sya! c) and : N : Tebukonaaoh : N

NS NIK IN SN,

Example K

Experiment with pickling of wheat seeds for protection against Ryzagpt sy!togyt. The use of active substances is carried out in the form of preparations for dry pickling. These drugs are prepared by diluting the corresponding active substances with ground rock to form a finely dispersed mixture that ensures uniform distribution on the surface of the seed material.

For pickling, the infected seed material is shaken for three minutes with a pickling agent in a closed glass bottle.

Wheat is sown with 2 X 100 seeds at a depth of 1 cm in standard soil and grown in a greenhouse at a temperature of about 18" with a relative humidity of about 95 95 in seedling boxes, which are exposed to light for 15 hours every day.

Approximately three weeks after sowing, the plants are evaluated for signs of damage. At the same time, 0 905 corresponds to the measure of effectiveness on untreated control plants, and the measure of effectiveness 100 95 means that infection of plants is not observed.

Table K.

Experiment with pickling of wheat seeds for protection against Gyzaite sytogyt. 1 bdtikev rezpennomuuei active about Aetrknh pezpolkoduyut pMukh cross of ZM!

N pecha i o vktekeh daotseek oyu V S rourozhyuonnoiznandemoi se" you teny it ! : ! MO: and! Related to dhamaha (I) | : : : Flow | :

The TT fee is to be paid in full: ! : M-th : : ! : Trizdimenoya : : : : Formula 1" vludUotya N ZKTh Z : he hasn't drunk yet

Application

Contaian activity test in relation to Rissipia on wheat. Solvent: 25 parts by mass of M,M-dimethylacetamide Emulsifier: 0.6 parts by mass of alkylaryl polyglycol ether To obtain an appropriate ready-to-use form of the active substance, mix one part by mass of the active substance or a combination of active substances with the specified amounts of solvent and emulsifier and dilute the concentrate with water to of the desired concentration or dilute with water to the desired concentration the preparative form of the active substance or combination of active substances available for sale.

To study the contact activity, young plants are sprayed with a preparative form of active substances with the specified consumption rate. After drying the applied drug, the plants are sprinkled with a suspension of Rissipia hesopaia conidia. The plants are left in the incubation cabin for 48 hours at a temperature of 20"C and a relative humidity of 100,905.

After that, the plants are placed in a greenhouse at a temperature of about 202 and at a relative humidity of 80 95 to stimulate the development of stem rust.

Ten days after inoculation, the condition of the plants is assessed. At the same time, 0 95 corresponds to the measure of effectiveness on untreated control plants, and the measure of effectiveness 100 95 means that infection of plants is not observed.

Table L.

Research on contact activity in relation to Rissipia on wheat.

And kemocha reetsyn utyannykh Z V insya rele Mido ten Ki! resovyn : active rechovmny Zika "calculated regretfully! kish not and : It's surprising that firms : :

I ik t : y i shi aa she

N, | | : : i : U, nn : Н N : и a M !

N sh-i : : and Trizakhmenoy : N ! she NN I ee MINE More

Example M

An experiment on contact activity in relation to Roogepornog (egesis on barley.

Solvent: 25 parts by weight of M,M-dimethylacetamide

Emulsifier: 0.6 parts by weight of alkylaryl polyglycol ether

To obtain an appropriate ready-to-use form of the active substance, one part of the mass of the active substance or a combination of active substances is mixed with the specified amounts of a solvent and an emulsifier and the concentrate is diluted with water to the desired concentration, or the commercially available preparative form of the active substance or combination with water is diluted with water to the desired concentration active substances.

To study the contact activity, young plants are sprayed with a preparative form of active substances with the specified consumption rate. After drying the applied drug, plants are sprinkled with a suspension of conidia of the Rugepornoga iege5. The plants are left in the incubation cabin for 48 hours at a temperature of 20"C and a relative humidity of 100,905.

After that, the plants are placed in a greenhouse at a temperature of about 20"C and at a relative humidity of about 80,905.

Seven days after inoculation, the condition of the plants is assessed. At the same time, 095 corresponds to the measure of effectiveness on untreated control plants, and the measure of effectiveness 100,905 means that infection of plants is not observed.

Table M.

An experiment on contact activity in relation to Roogepornog (egesis on barley.

Ro Active substance of umo aktiknyh slktkanya substanceachsum kra efficiency in Ya. Ya and dezovykh ktvyany substances who - Bezrahovainpuvnadavny! ! their yah! yours: ab! ! Geo v v : " : !! y NI ne : ! byu : ! i -E : : i According to the formula | ! shi i ' shi i. : : ! ! o : : !! : : : 5 : ' ! dashhoyudtretsim : ! : kn NI NN KK Kt: NYM NN she ! Bolotova ee PI M ts stv PM IN

Example N

An experiment on contact activity in relation to Eguzirpe on barley.

Solvent: 25 parts by weight of M,M-dimethylacetamide

Emulsifier: 0.6 parts by weight of alkylaryl polyglycol ether

To obtain an appropriate ready-to-use form of the active substance, one part of the mass of the active substance or a combination of active substances is mixed with the specified amounts of a solvent and an emulsifier and the concentrate is diluted with water to the desired concentration, or the commercially available preparative form of the active substance or combination with water is diluted with water to the desired concentration active substances.

To study the contact activity, young plants are sprayed with a preparative form of active substances with the specified consumption rate.

After drying the applied drug, the plants are sprinkled with spores of Eguzirpe dgatipiv g. zr. anus

Plants are installed in a greenhouse at a temperature of approximately 20"C with a relative humidity of approximately 80-95 to stimulate the development of powdery mildew.

Seven days after inoculation, the condition of the plants is assessed. At the same time, 0905 corresponds to the measure of effectiveness on untreated control plants, and the measure of effectiveness 10095 means that infection of plants is not observed.

Table N.

Test on contact activity in relation to Eguzirne on barley.

What are the udders of the umbilical cords of the udders of the umbilical cords, etc.? ! nt they and sn, : : and ! M: : : ! pdpyuvidno to byduhyia n) : Ya Ya re obr Uh | :still a whistle : o: : : : : krazvkusymustiya : ! :

EOpBERyuva In: KreansnmEya PEV same

Example O

Threshold concentration test/Systemic effect through roots Test insect: Borodoriega ytidiregada Solvent: 4 parts by weight of acetone

Emulsifier: 1 part by mass of alkylaryl polyglycol ether. To obtain the appropriate form of the ready-to-use active drug, mix 1 part by mass of the active substance with the indicated amount of solvent, add the indicated amount of emulsifier and dilute the concentrate with water to the desired concentration.

The ready-to-use form of the active substance is thoroughly mixed with the soil. At the same time, the concentration of the active substance in the preparative form plays almost no role, only the content of the active substance per unit volume of soil, which is indicated in parts per million (mg/l), is of decisive importance.

The soil is placed in pots with a volume of 250 ml and left at a temperature of 2076.

Immediately after the start of the experiment, a grain of corn is placed in each pot. 14 days after the start of the experiment, test insects are placed in an insect clip and attached to the plant. 4 days after infection, the measure of the effectiveness of the active substance is determined by calculating the number of dead and alive insects in 9o. At the same time, 100 95 means that all test insects died; 0 9o means that there are as many live insects as in the untreated control group.

Table O

An experiment on brodoriega Igidiregaa

G butan renovnieumko active OO OPloenizanefetv pen cocoon WHAT

N substances of the language of speech and language of children and adults: ha miliyon mo) and ! i i r i same:

I am omniscient of the formula: and ОН aby

And Uh: and Romain N

Masses E and ! Ppopukm from the corpse (43) and I Spoluuh from the corpse (48) : kb ek I

Example P

Experiment to determine the threshold concentration/Soil insects

Experimental insect: Oiabgoiisa baieaga - larvae in the soil

Solvent: 4 parts by mass of acetone

Emulsifier: 1 mass part of alkylaryl polyglycol ether

To obtain the appropriate form of the ready-to-use active drug, mix 1 part of the mass of the active substance with the indicated amounts of solvent, add the indicated amount of emulsifier, and dilute the concentrate with water to the desired concentration. At the same time, the concentration of the active substance in the preparative form plays almost no role, only the content of the active substance per unit volume of soil, which is indicated in parts per million (mg/l), is of decisive importance. The soil is placed in pots with a volume of 0.5 l and left at a temperature of 2076.

Immediately after refueling, 5 grains of corn are placed in each pot. After three days, experimental insects are planted in the treated soil. After another 7 days, the measure of effectiveness is determined. The measure of efficiency is determined by the number of sprouted corn plants. Active substances, consumption rates and results are shown in the following table.

Table P

Soil insecticides Oiabgoiis Braieia - larvae in the soil! Active deesviny fudsev! The percentage of gray matter in homocentrations of active:

And I am a SON! rati tone, ! oh : : Fermuga V : ! мя а | OM moz TO b

RO otaki! ! and Bo. me : !

Mu sn | : and Inappropriately de porzhumh (B: I I on en pi op no t Na ! Z Sloluka bormula (BI : EOM moh LULyu :

Table P

Soil insecticides

Oiangoiisa Brai(eaia - larvae in the soil

N bktivn: roehne moneupuetsiya) :Percent mmlibeli priya hoocenti tih OkhTianyh! : и речевое в здетяхх комиющен им хо : : мех НУ ц по мч 0 : и т и и ' : Ух х и, : Н

Tory meti NM: H rode di tons yn : : there is sh " i and : I N !

N Gh UK: 1 and MO! : Form 0, : N and : MPC mo N

Yi woo: Ya

And at home: ! roles : I : Sat : : Or : ! : n N i : " N sqm : :

N Khudizhya MO: and and tests: and

N ne Z i CHYN N i iy M I el y y roya V : : uk od N : Vipponinny go" foryuuai (avu : '

N Snapuki fopmuny pah, N

And I piopuye frormulyutiv, : EOM Y