UA112862C2 - COMPOSITION CONTAINING PESTICIDE, SURFACTANT AND ALCOXYLATE 2-PROPYLGETTYLAMINE - Google Patents

Abstract

Composition containing pesticide, surfactant and alkoxylate. In addition, the invention relates to a concentrate containing surfactant and alkoxylate; and to a method of manufacturing a composition by contacting a concentrate and a pesticide; or by contacting a pesticide, surfactant and alkoxylate; as well as the use of surfactant by adding to the mixture containing pesticide and alkoxylate. The invention also relates to a method of combating phytopathogenic fungi and / or unwanted vegetation and / or undesirable attack by insects or ticks and / or to regulate plant growth, where the compositions allow to act on the relevant harmful organisms, their environment or plants to be protected from the relevant harmful organism against soil and / or undesirable plants and / or cultivated plants and / or their environment. In addition, the invention relates to seeds containing the composition.

Description

The present invention relates to a composition containing a pesticide, a surfactant and an alkoxylate.

In addition, the invention relates to a concentrate containing a surfactant and an alkoxylate; as well as to the method of making the composition by bringing the concentrate and pesticide into contact; or by contacting a pesticide, a surfactant, and an alkoxylate; as well as to the use of a surfactant for addition to a mixture containing a pesticide and an oxylate. In addition, the invention relates to a method of combating phytopathogenic fungi and/or unwanted vegetation and/or unwanted insect or mite attack and/or for regulating plant growth, where the compositions act on relevant harmful organisms, their environment or on plants that subject to protection against the relevant harmful organism, on the soil and/or on undesirable plants and/or cultivated plants and/or their environment. In addition, the invention relates to seeds containing the composition.

The present invention contains combinations of preferred features with other preferred features.

Agrochemical preparative forms containing amine alkylates are mainly known:

MO 2009/004044 discloses a herbicide composition containing a herbicide based on phenoxy acid and an alkylated alkylamine as an auxiliary substance, while it is possible for the alkylamine, for example, to be 2-propylheptylmethylamine, which is alkylated with 3-20 ethylene oxide groups. 05 5,668,085 discloses a herbicidal composition containing an aqueous solution of glyphosate and a surfactant. The surfactant can be an alkoxylated alkylamine, an alkyl group containing 8-22 carbon atoms.

UMO 2011/086115 discloses 2-propylheptylamine alkoxylates, their production, as well as agrochemical preparations containing a pesticide and 2-propylheptylamine oxylates.

О520100317521 and 5 20110039703 disclose a preparation form containing glyphosate and, as a surfactant, a branched alkylamine alkoxylate.

Alkoxylated alkylamines, in particular the commercially available ethoxylated fatty acid amines (POEAs), have significant toxic characteristics (such as skin and eye irritation) and ecotoxic characteristics (such as high ecotoxicity to aquatic organisms such as algae and daphnia). So, for example, ROEA (Mo SAB5 61791-26-2), which is often present in Koipacr herbicides? as a wetting agent, it is considered to be toxic to aquatic organisms (T5ii ii Spi, Spetozrpege 2003, 52, 1189-1197).

For this reason, it was an object of the present invention to find an adjuvant which is well suited to pesticides, in particular to herbicides such as glyphosate, and at the same time is less toxic (especially having lower toxicity to aquatic organisms). In addition, the auxiliary substance enables the preparative form of pesticides to be stable during storage. Another task was to increase the biological activity of the agrochemical composition. ! finally, this excipient must prevent a phytotoxic side effect.

The task was solved with the help of a composition containing a pesticide, a surfactant, and an alkoxylate, where the oxylate is an amine (A) m deo-y-y

Ave o-Y-ve t (A), or quaternized derivative (AS)

In E

M fleet 7AAM A in ve-o-I-ve

And (AC) of the amine (A), where

BA", VU, and 2? independently of each other represent ethylene, propylene, butylene or a mixture of the specified,

BZ is H, -OH, -OB", -IV2-O|p-He, C1-Cv-alkyl or oxygen anion,

B" represents C:-Cv-alkyl, C0-Cv-alkenyl or C2-Cv-alkynyl,

ANYA is H, C:-Cv-alkyl, Cg2-Cv-alkenyl, C2-Cv-alkynyl, -5Oz3i82a, -RI)OVRONU, -

SNO", or -S(O) VU,

B" is Ce-Si4-alkyl,

Weights of VZ, independently of each other, represent H, inorganic or organic cations,

Ve and Ee independently of each other represent H, inorganic or organic cations, C1-Cv-alkyl, Co-Cv-alkenyl or C2-Cv-alkynyl,

Does not represent C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C8-C8-aryl or C7-C8-20-alkylaryl, n, t and p independently of each other have values from 1 to 30,

A is an agriculturally suitable anion, or if BZ is an oxygen anion, then A" is absent.

Preferably, the composition according to the invention contains a pesticide and an alkylate, where the alkylate is an amine (A) alkylate.

Preferably, n has a value from 1 to 20, especially preferably from 1 to 15. Preferably, t has a value from 1 to 20, especially preferably from 1 to 15. Preferably, p has a value from 1 to 30, especially preferably from 1 to 20 .The values of n, t, and o are normally the average values that mainly occur after alkylation using alkoxides. As a result, n, t, and o can be not only integers, but can also have all values in the interval of integers.

Preferably, in the case of the amine alkoxylate (A), the total number of p and t is 2-40 and in its quaternized derivative (AC)) the total number of n, t and p is 3-80. In the case of the amine alkoxylate (A), the total number of p and t is particularly preferably 3-30, particularly preferably 5-18, and especially 8-14.

In an additional, particularly preferred embodiment, the total number of pi and t is 6-9, in particular 6.5-8.5 and in particular 6.9-7.9. In an additional particularly preferred embodiment, the total number of p and t is 11-40, in particular 12-30 and in particular 13.5-25. In an additional particularly preferred embodiment, the sum of p and t is 8-13, in particular 9-11.

In the case of the quaternized derivative (AC) of the amine (A), the total number of n and p is particularly preferably 3-40 and especially 5-25. In one particularly preferred embodiment, the sum of p and t is 8-13, particularly 9-11.

B", B? and E? preferably independently of each other represent ethylene, ethylene and propylene, ethylene and butylene, or ethylene, propylene and butylene. In an additional preferred embodiment, KK", НВ? and BC? are propylene. In an additional preferred embodiment, KE", B? and EE? are butylene. Particularly preferably, K', B? and E? independently of each other are ethylene, or ethylene and propylene. Very particularly preferably, E"', B ? and B? are ethylene.

If EE", B? or EK? contain a butylene radical, the latter may be present as an n-butylene, isobutylene or 2,3-butylene group, where n-butylene and isobutylene are preferred and n-butylene is most preferred.

B', B2g and E" independently of each other can be a mixture of ethylene, propylene or butylene. In this context, for example, one or all of the radicals K", B: and KE? may contain a mixture of these groups in each alkoxylate chain. Such mixtures may be linked to each other in any desired order, for example, in a random order or cell-wise (eg, as one block of ethylene and one block of propylene). Also, it is possible that in each case one or more radicals EC, B, and E? formed a complete alkoxylate chain composed of various alkylene groups. For example, K' and 22 can consist of ethylene and EC? sawed off

BZ preferably represents H, -OH, C1-C-alkyl or an oxygen anion, and especially preferably represents H, methyl, butyl or an oxygen anion. In a particularly preferred embodiment, KZ is methyl. In an additional particularly preferred embodiment, the short circuit is an oxygen anion. In an additional, particularly preferred embodiment, the short circuit is H.

B" preferably represents C1-C8-alkyl, in particular methyl or butyl, especially butyl.

VU is preferably H or C:-Cv-alkyl, more preferably H or methyl, especially H.

B' can be a straight or branched, saturated or unsaturated C 1 -C 1 -alkyl radical, such as hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl or tetradecyl. KK" is preferably a C-Siz-alkyl radical. K/ is especially preferably a branched alkyl radical SeH':", a branched CizH?-alkyl radical, 2-propylheptyl or 2-ethylhexyl. In an additional particularly preferred form, K/ is especially preferably represents a branched alkyl radical CoH:io, 2-propylheptyl or 2-ethylhexyl. In particular, KK" represents 2-propylheptyl. In one embodiment, K/ is one of the radicals mentioned above, with the exception

In a preferred embodiment, K" is 2-ethylhexyl.

In an additional preferred embodiment, K/" is a branched alkyl radical CoeH;:o. Examples are, among others, 2-methyl-1-octanol, 2-ethyl-1-heptanol, 2-propyl-1-60 hexanol , 3-methyl-4-hydroxymethyl-heptane, 3-methyl-3-hydroxymethyl-heptane or 2-hydroxymethyl-

C-methyl-heptane. Preferably, the branched alkyl radical CoeH:io contains several different, branched alkyl radicals CeNio. The average degree of branching in this case is 1.01 - 2.5, preferably 1.05 - 1.8, especially preferably 1.1 - 1.5, very especially preferably 1.2 - 1.3. The term "degree of branching" is defined here as, in principle, known as the number of methyl groups in one molecule of alcohol minus 1. The average degree of branching is a statistical average of the degrees of branching of all molecules in the sample.

Production of these compounds is known, for example, from O5 61/314600.

In an additional preferred embodiment, B" represents a branched alkyl radical CizHg?. An example is an isotridecyl radical.

In a particularly preferred embodiment, K/ is 2-propylheptyl. In this case, the alkoxylate corresponds to the amine alkoxylate (AT) of

AALeu

TEveo-T-ve (AT) or quaternized derivative (AO1)

WITH

BUT

TM n -

Tag vl ve-o-I-v (AS).

Be and BZ independently of each other represent H, or inorganic or organic cations, which can be singly or multiply positively charged. Examples of inorganic cations are ammonium cations, Ma», KU», Mod, Sa», or 7p». Examples of organic cations are methylammonium, dimethylammonium, trimethylammonium, tetramethylammonium, (2-hydroxyethyl)ammonium, bis(2-hydroxyethyl)ammonium, tris(2-hydroxyethyl)ammonium, tetra(2-hydroxyethyl)ammonium. Preferably, Ka and Ko independently of each other are H or inorganic cations. If an inorganic or organic cation is present, then a bound anionic group is formed on Ke with the help of an appropriate functional group (for example, -50Oz3-, -P(0)O-O-, or -CH»CO»2-).

БЕ and Еге are mostly, independently of each other, H, inorganic or organic cations. Suitable inorganic or organic cations are those specified in accordance with

Va.

In another embodiment, in the quaternary derivative (AOS), the K2g, Be, Be, and KZ radicals can independently be organic cations, with a cationic group that itself is a quaternary nitrogen cation of AO. As a result, it is also possible for a zwitterion to form in AS on K AO, with an anionic group that is formed with the help of an appropriate functional group (for example, -50Oz3-, -P(Ф0)0-0О-, or -СН2бСО»2-) , and a cationic group with the help of quaternary nitrogen AS. In this zwitterionic form Ag, the presence of an agriculturally suitable anion A: is optional.

Be is preferably C1-C:12-alkyl, C1-C12-aryl, or C7-C:12-alkylaryl, more preferably

Ci-Cv-alkyl.

A is an agriculturally suitable anion, as is generally known in practice.

Preferably, A" is a halide (such as chloride or bromide), phosphate, sulfate or an anionic pesticide. Particularly preferably, A" is an anionic pesticide such as glyphosate anion or glufosinate anion. If the short circuit is an oxygen anion, then an amine oxide is present. In this case, an additional anion such as A" is absent.

In a preferred embodiment, KK! and K? independently of each other are ethylene, ethylene and propylene, ethylene and butylene, or ethylene, propylene and butylene, and the total number of p i t is 2-60, preferably 2-40, especially preferably 3-30 and in particular 5-25. In a particularly highly preferred embodiment, K' and Kg are ethylene, ethylene and propylene, ethylene and butylene, or ethylene, propylene and butylene and the total number of p and t is 5-18, in particular 8-12, and especially 9-11 .

In an additional preferred embodiment, B! and KE? independently of each other are ethylene and propylene, and the total number of p and t is 2-60, preferably 3-30, especially preferably 5-20 and in particular 8-14. Preferably, the alkylate contains 1.5 - 8 mol (preferably 2 - 6 mol) of propylene oxide and 5 - 20 mol (preferably 7 - 13 mol) of ethylene oxide.

In a particularly preferred embodiment, K' and BK are ethylene, and the total number of p and t is 2-60, preferably 2-40, especially preferably 3-30, especially preferably 5-18 and in particular 8-14.

Compounds (A) and (AC) can be present as a mixture of stereoisomers or as individual stereoisomers. Tautomers and betaines are similarly included using structures (A) and (AO).

In most cases, the composition according to the invention contains from 0.1 to 90 95 by weight of alkoxylate, preferably from 1 to 50 95 by weight and in particular from 3 to 30 95 by weight.

The term pesticide refers to at least one active substance selected from the group of fungicides, insecticides, nematicides, herbicides, antidotes, molluscicides, rodenticides, and/or growth regulators. Preferred pesticides are fungicides, insecticides, herbicides and growth regulators. Particularly preferred pesticides are herbicides and growth regulators. Mixtures of pesticides from two or more of the classes mentioned above may also be used. Practitioners know such pesticides, which can be found, for example, in Rezbiyside

Mapiai, 15th edition. (2009). Pesticides may also contain salts, esters, optical isomers or tautomers. Suitable pesticides are (at the same time, groups A) - M) are fungicides):

A) Respiratory inhibitors - inhibitors of the Ш complex in the O region (for example, strobilurins): azoxystrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, phenaminostrobin, phenoxystrobin/fluphenoxystrobin, fluoxastrobin, kresoxim-methyl, methominostrobin, oryzastrobin, picoxystrobin, pyraclostrobin, pyramethostrobin, pyroxystrobin , trifloxystrobin, methyl 2-(2-(2,5-dimethylphenyloxymethyl)phenyl|-3-methoxyacrylate, 2-(2-(3-(2,6-dichlorophenyl)-1-methylallylideneaminooxymethyl)phenyl)-2-methoxyimino- M-methylacetamide, pyribencarb, triclopyricarb/chlorodincarb, famoxadone, fenamidon; - inhibitors of the I complex in the region O)/: ciazofamide, amisulbrom; - inhibitors of the I complex (for example, carboxamides): benodanil, bixafen, boscalid, carboxin, fenfuram, fluopiram, flutolanil, fluxapiroxad, furametpyr, isopyrazam, mepronil, oxycarboxin, penflufen, pentiopirad, sedaxan, tecloftalam, tifluzamide, M-(4-trifluoromethylthiobiphenyl) -2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide and N-(2-(1,3,3-trimethylbutyl)phenyl)-1,3-dimethyl-5-fluoro-1 N-pyrazole-4-carboxamide; - other respiratory inhibitors (for example, complex I, dissociative agents): diflumetorim; nitrophenyl derivatives: binapacryl, dinobuton, dinocap, fluazinam; ferimzone; organometallic compounds: fentin salts such as fentin chloride, fentin chloride or fentin hydroxide; amethotradine; and silthiofam;

C) Sterol biosynthesis inhibitors (ZVI fungicides) - C14-Demethylase inhibitors (OMI fungicides): - triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, diniconazole-M, epoxyconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, oxpoconazole, paclobutrazol, penconazole, propiconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, uniconazole; imidazoles: imazalil, pefurazoate, prochloraz, triflumizole; pyrimidines, pyridines and piperazines: fenarimol,

Nuarimol, pyrifenox, triforin; - delta14-reductase inhibitors: aldimorph, dodemorph, dodemorph acetate, fenpropimorph, tridemorph, fenpropidine, pvperalin, spiroxamine; - inhibitors of Z-ketoreductase: phenhexamide;

C) inhibitors of nucleic acid synthesis - phenylamides or acylamino acid-based fungicides: benalaxyl, benalaxyl-m, kiralaxyl, metalaxyl, metalaxyl-m (mefenoxam), ofuras, oxadixyl; - others: himexazole, octylinone, oxolinic acid, bupirimate; p) inhibitors of cell division and cellular skeleton - tubulin inhibitors, such as benzimidazoles, thiophanates: benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate-methyl; triazolopyrimidines: 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-(1,2,4Igriazolo|1,5-a|Ipyrimidine; - additional inhibitors of cell division : dietofencarb, etaboxam, pencicuron, fluopicolide, zoxamide, metrafenone, pyriofenone;

E) inhibitors of amino acid synthesis and protein synthesis - inhibitors of methionine (anilinopyrimidine) synthesis: cyprodinil, mepanipyrim, pyrimethanil;

- protein synthesis inhibitors: blasticidin-5, kazugamycin, kazugamycin hydrochloride hydrate, mildiomycin, streptomycin, oxytetracycline, polyoxin, validamycin A;

E) signal transmission inhibitors - MAP/histidine kinase inhibitors: fluorimid, iprodione, procymidone, vinclozolin, fenpiclonil, fludioxonil; - C-protein inhibitors: quinoxifene;

C) inhibitors of lipid and membrane synthesis - inhibitors of phospholipid biosynthesis: edifenfos, iprobenfos, pyrazofos, isoprothiolan; - lipid peroxidation: dicloran, quintozen, teknazen, tolclofos-methyl, biphenyl, chloroneb, etridiazole; - biosynthesis of phospholipids and attachment of cell walls: dimethomorph, flumorph, mandipropamide, pyrimorph, bentiavalicarb, iprovalicarb, valifenalate and 4-fluorophenyl M-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)/ucarbamate; - Compounds that affect cell membrane permeability and fatty acids: propamocarb, propamocarb hydrochloride

H) "Multisite" inhibitors - inorganic active substances: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur; - Thio- and dithiocarbamates: ferbam, mancozeb, maneb, metam, metiram, propineb, thiram, zineb, ziram; - organochlorine compounds (for example, phthalimides, sulfamides, chloronitriles): anilazine, chlorothalonil, captafol, captan, folpet, dichlofluanid, dichlorphen, flusulfamide, hexachlorobenzene, pentachlorophenol and its salts, phthalide, tolylfluanid, M-(4-chloro-2-nitrophenyl) )-M-ethyl-4-methylbenzenesulfonamide; - guanidines and others: guanidine, dodine, dodine in the form of a free base, guazatin, guazatin acetate, iminoctadine, iminoctadine triacetate, iminoctadine tris(albesylate), dithianone;

I) cell wall biosynthesis inhibitors - glucan synthesis inhibitors: validamycin, polyoxin B; inhibitors of melanin synthesis: pyroquilon, tricyclazole, carpropamide, diclomet, fenoxanil;

C) Inducers of resistance - acibenzolar-5-methyl, probenazole, isothianil, thiadinil, prohexadione-calcium; phosphonates: fosetyl, fosetyl aluminum, phosphoric acid and its salts;

K) Unknown mode of action - bronopol, quinomethionate, cyfluphenamide, cymoxanil, diazomet, debacarb, diclomesin, difenzoquat, difenzoquat-methyl sulfate, diphenylamine, fenpyrazamine, flumetover, flusulfamide, fluthianil, metasulfocarb, nitrapyrin, nitrothal-isopropyl, oxine-copper, proquinazid . 4-(4-chloro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-M-ethyl-M-methylformamidine, M'-(4-(4-fluoro-

3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-M-ethyl-M-methylformamidine, M'"(2-methyl-5-trifluoromethyl-4-(3-trimethylsilanylpropoxy)phenyl)-M-ethyl-M-methylformamidine, M'-(5-difluoromethyl-2-methyl-4-(3-trimethylsilanylpropoxy)phenyl)-M-ethyl-M-methylformamidine, M-methyl-(1,2,3,4-tetrahydronaphthalen-1-yl)- 2-11-(2-(5-methyl-3-trifluoromethylpyrazol-1-ylluacetyl|piperidine-4-ylluthiazole-4-carboxylate, M-methyl-(H)-1,2,3,4-tetrahydronaphthalene-1- yl 2-11- (2-(5-methyl-3-trifluoromethylpyrazol-1-ylluacetyl|piperidine-4-illuthiazole-4-carboxylate, 1-(4-(4-(5-(2,6-difluorophenyl)- 4,5-dihydro-3-isoxazolyl|-2-thiazolyl|-1-piperidinyl|-2-(5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl|ethanone, b-tert-butyl- 8-fluoro-2,3-dimethylquinolin-4-yl methoxyacetate, /N-methyl-2-11-(5-methyl-3-trifluoromethyl-1H-pyrazol-1-yl)uacetyl|piperidin-4-yl) А- MAK B)-1,2,3,4-tetrahydronaphthalene-1-yl|-4-thiazolecarboxamide, 3-(5-(4-methylphenyl)-2,3- dimethylisoxazolidin-3-yl|-pyridine, 3 -(5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl|-pyridine (pyrisoxazole), M-(6- methoxypyridin-3-yl) cyclopropanecarboxamide, 5-chloro-1-(4,6-dimethoxypyrimidin-2-yl)-2-methyl-1H-benzoimidazole, 2-(4-chlorophenyl)-IM-(4-(3 ,4-dimethoxyphenyl)isoxazol-5-yl|-2-prop-2-ynyloxyacetamide;

M Biological fungicides, plant-strengthening agents - AtreiIoptusez diizdchaii5 (for example, the product AO 102 from the company Ipigaspet Vio Stn 5. So.

KO, Germany), Azregoyii5 Piami5 (for example, the product AR'GASOAKO? from the company 5updepia,

Switzerland), Aegygeobavidisht riijshiap5 (for example, the product VOTESTOK? from the company bBio-Gegtt

Otrn, Germany), Vasiiii5 ritiishv (for example, strain MAK! Mo B-30087 in BOMATA? and VAG Are

Riy5 from the Adgadievti IPS company. USA), Vasiin5 z!IiBiib (for example, strain MEKKI Mo B-21661 in 60 VAVNARBOYU?E, 5EVEMAOE? MAH and ZEKEMAOE? OR from the company Adgadnevi Ips. USA), Vasiyi5

5, iBij5 mag. atuioiidchetasiepe 2824 (for example, the product TAESCO? from the company Momo7lgute

Vioiodisa!I5, Ips. USA), Sapaida oIeorpya I-82 (for example, the product ABRIKEZ? from the company Esodep

Ips. USA), Sapaida zayoapa (e.g. VIOSIONE products? (admixed with lysozyme) and

VIOSOATU from the company Misgo Rio Sotrapu, USA (the company VABE BE) and Aguzia), chitosan (for example, AKMOSHK-2EM from the company Voigilep CYA. New Zealand), SiIopoviaspuz gozea Her. sagapstsava, also known as Siiosiadiysht saiepiaysht (for example, U1446: REE5TOR-? from the company

Megdega, Finland), Sopiopugiit tipkapo5 (for example, the product SOMTAMZ5Z from the company Rhorpuia,

Germany), Sturpopesigia ragaziysa (for example, the product Epaoipia ragaziysa from the company SMISM,

France), Stguriosossi5 airidie (for example, the product MIEEEIO RIGOBU from the company Apspog Vio-

Tesppoiodieh, South Africa), ERizagisht ohuzrogyt (for example, products VIOBOH?U from the company 5.I.A.R.A. Italy, and ROBASIEAMU from the company Maishiga! Riapi Rgoiesiop, France),

Meivsppikoula yiisiisoia (for example, the product ZNEMEK? from the company Adgodgeep, Israel),

Misgodospisht detegit (for example, the AMTIVOTU product from the Adgaihipe company, France),

Rebiorzije didapiea (for example, the product KOT5BOR? from the company Megdega, Finland),

Rzepdoguta Posshoza (for example, the product BROBOOEH? from the company Riapi Rgodysiv So. GP.

Sapada), Ruipisht oiidapagyt 0М74 (for example, the product ROI UMEVZIM? from the company Retevzio

ZNO, Viorgeragaiu, Czech Republic), Keupotzigia zaspiipepvi5 (e.g. product VESAPIA? from Magtope Vioippomayop5, USA), Taiagotuse5 Shpamy5 M117B6 (e.g. product

RAOTIZU from the company Rhorpuia, Germany), Tgispodegta azregeisht 5KT-1 (for example, the product

ESO-NORES - from Kitiai Spetis company! Ipdyvigu So. ON. Japan), T. aigomigide I C52 (for example, the product ZEMTIMEI 9 from the Adgitt TesppoYodiech Tsa company, New Zealand), T. pagliapit T-22 (for example, the product RIH AMTZNIEGOE from the company Viom/ogk5 Ips. USA), T. paglapit TN 35 (for example, the product KOOT RKO? from the company Musopigo! 4. Israel), T. Ppaglapit T-39 (for example, the products TKISNOOEH? and T. migide (e.g., TKISNOREIG product from Adgitt Tespoiodieee CYA, New Zealand), T. paglapyt ISCO12 and T. migide ISCO8O (e.g., VEMEOSIEK? MUR product from Izadgo Risgsa, Italy), T. roiuzrogyt and T. pagliapite (for example, the product VIMAVU from the company VIMAV Vio-Ippomaiop AB, Sweden), T. zygotaiysit (for example, the product TEISOMAVZ from the company S.E.R.H.A.S. Brazil), T. migep5 SI -21 (for example, product BOI ZARO? from the company Sepiz 1 C, USA), T. miide (for example, products

TAIESOZ from the company Esozepvze I par. (Ipaia) Rm. Tsa., Ipaia and VIO-SOVE? E from the company T. Ziape5 e So. |a., India), T. migide TMI1 (for example, the product T. migide TM1 from the company Adgirioies gi, Italy),

Шиосиадиит очаетапвій НКОЗ (for example, the product VOTKU-2EM? from the company Voigu-2ep Tsa, Nova

Zealand;

M) growth regulators abscisic acid, amidochlor, ancymidol, b-benzylaminopurine, brassinolide, butralin, chlormequat (chlormequat chloride), choline chloride, cyclanilide, daminoside, dikegulak, dimetipine, 2,6b-dimethylpuridine, ethephon, flumetraline, flurprimidol, fluthiacet, forchlorfenuron, gibberellic acid, inabenfid, indole-3-acetic acid, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), metconazole, naphthaleneacetic acid, M-6b-benzyladenine, paclobutrazol, prohexadione (prohexadione-calcium), prohydrojasmone, thidiazuron, triapentenol , tributyl phosphorotrithioate, 2,3,5-triiodobenzoic acid, trinexapak-ethyl and uniconazole;

M) herbicides - acetamide: acetochlor, alachlor, butachlor, dimetachlor, dimethenamid, flufenacet, mefenacet, metolachlor, metazachlor, napropamide, naproanilid, pentaxamide, pretilachlor, propachlor, tenilchlor; - amino acid analogs: bilanaphos, glyphosate, glufosinate, sulfosate; - aryloxyphenoxypropionates: clodinafop, cigalofop-butyl, fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefuryl; - bipyridyls: diquat, paraquat; - carbamates and thiocarbamates: azulam, butylate, carbetamide, desmedipham, dimepiperate, eptam (ERTS), esprocarb, molinate, orbencarb, phenmedipham, prosulfocarb, pyributycarb, thiobencarb, trialate; - cyclohexanediones: butroxidim, clethodim, cycloxidim, profoxidim, sethoxidim, tepraloxidim, tralkoxidim; - dinitroanilines: benfluralin, etalfluralin, oryzalin, pendimethalin, prodiamine, trifluralin; - simple diphenyl ethers: acifluorfen, aclonifen, bifenox, diclofop, ethoxyfen, fomezafen, lactofen, oiifluorfen; 60 - hydroxybenzonitriles: bromoxynil, dichlobenil, yoxynil;

- imidazolinones: imazametabenz, imazamox, imazapic, imazapir, imazaquin, imazetapir;

- phenoxyacetic acids: clomeprop, 2,4-dichlorophenoxyacetic acid (2,4-O0), 2,4-OB, dichloroprop, MSRA, MSRA-thioethyl, MSRV, mecoprop;

- pyrazines: chloridazone, flufenpyr-ethyl, flutiacet, norflurazon, pyridate;

- pyridines: aminopyralid, clopyralid, diflufenican, dithiopyr, fluridone, fluroxypyr, picloram, picolinafen, thiazopyr;

- sulfonylureas: amidosulfuron, azimsulfuron, bensulfuron, chlorimuron-ethyl, chlorsulfuron, cynosulfuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupirsulfuron, foramsulfuron, halosulfuron, imazosulfuron,

iodosulfuron, mesosulfuron, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, 1-((2-chloro-b-propylimidazo|1, 2-b|Ipyridazin-3-yl)usulfonyl)-3-(4,6-dimethoxypyrimidin-2-yl)urea;

- triazines: ametrin, atrazine, cyanazine, dimetamethrin, ethiosin, hexazinone, metamitron, metribuzin, promethrin, simazine, terbuthylazine, terbutrin, triaziflam;

- ureas: chlortoluron, daiimuron, diuron, fluometuron, isoproturon, linuron, metabenzthiazuron, tebuthiuron;

- other aceloctate synthase inhibitors: bispiribac-sodium, cloransulam-methyl, diclosulam,

florazulam, flucarbazone, flumetsulam, methosulam, orthosulfamuron, penoxsulam, propoxycarbazone, pyribambenz-propyl, pyribenzoxime, pyriphthalide, pyriminobac-methyl, pirimisulfan, pyrithiobac, pyroxasulfone, piroxsulam;

- others: amicarbazone, aminotriazole, anilofos, beflubutamide, benazolin, bencarbazone, benflurezat, benzofenap, bentazone, benzobicyclone, bromacil, bromobutide, butafenacil,

butamiphos, cafenestrol, cafentrazone, cinidone-ethyl, chlorthal, cinmethylin, clomazone, cumiluron, cyprosulfamide, dicamba, difenzoquat, diflufenzopyr, ХОгеспб5иега топосега5, endothal, etofumesate, etobenzanid, fentrazamide, flumiclorac-pentyl, flumioxazin, flupoxam, fluorochloridone, indano flurtamone , isoxaben, isoxaflutol, lenacil, propanil, propizamide, quinclorac, quinmerac, mesotrione, methylarsenic acid, naptalam, oxadiargyl, oxadiazon,

oxacyclomefon, pentoxazone, pinoxaden, pyraclonil, pyraflufen-ethyl, pyrasulfotol, pyrazoxifene, pyrazolinate, quinoclamine, safluphenacil, sulcotrione, sulfentrazone, terbacil, tefuryltrione, tembotrione, thiencarbazone, topramesone, 4-hydroxy-3-(2-(2-methoxyethoxymethyl) -6- trifluoromethylpyridine-3-carbonyl|bicyclo|3.2.1|oct-3-en-2-one, ethyl (3-(2-chloro-4-fluoro-5-(3- methyl-2,6-dioxo -4--rifluoromethyl-3,6b-dihydro-2H-pyrimidin-1-yl)uphenoxy|pyridin-2-

yloxy)acetate, methyl b-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylate, b-chloro-3-(2-cyclopropyl-b-methylphenoxy)-pyridazin-4-ol, 4-amino-3-chloro -6-(4-chlorophenyl)-5-fluoropyridine-2-carboxylic acid, methyl 4-amino-33-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylate and methyl 4 -amino-3-chloro-6-(4-chloro-3-dimethylamino-2-fluorophenyl)pyridine-2-carboxylate;

to O) insecticides

- organo(thio)phosphates: acephate, azamethifos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidophos, methidathion, methyl parathion , mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phentoate, phosalon, phosmet,

phosphamidon, phorate, foxim, pirimiphos-methyl, profenofos, prothiophos, sulprofos, tetrachlorvinphos, terbuphos, triazophos, trichlorfon;

- carbamates: alanicarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, phenoxycarb, furatiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, triazamate;

- pyrethroids: allethrin, bifenthrin, cyfluthrin, cygalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, pralethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralometrin, transfluthrin, profluthrin, dimefluthrin,

- insect growth inhibitors: a) chitin synthesis inhibitors: benzoylureas: chlorfluazuron, cyramazine, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron; buprofezin, diofenolan, hexythiazox, etoxazole, clofentrazine; B) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide, azadirachtin; c) juvenoids: pyriproxyfen, methoprene, fenoxycarb; 4) biosynthesis inhibitors

60 lipids: spirodiclofen, spiromesifen, spirotetramate;

- agonists/antagonists of nicotinic receptors: clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, thiacloprid, 1-(2-chlorothiazol-5-ylmethyl)-2-nitrimino-3,5-dimethyl-|1,3,5| griazinan; - GABA antagonists: endosulfan, iprol, fipronil, vaniliprol, pyrafluprol, pyriprol, M-

B-amino-1-(2,6-dichloro-4-methylphenyl)-4-sulfinamoyl-1H-pyrazole-33-thiocarboxamide; - macrocyclic lactones: abamectin, emamectin, milbemectin, lipemectin, spinosad, spinetoram; - acaricides (METI) and electrons related to transfer inhibitors of the mitochondrial chain: phenazaquin, pyridaben, tebufenpirad, tolfenpirad, flufenerim; - METI II and I substances: acequinocil, fluaciprim, hydramethylnon; - disconnecting agents: chlorfenapyr; - inhibitors of oxidative phosphorylation: cihexatin, diafenthiuron, fenbutatin oxide, propargite; - insect molting inhibitors: cryomasin; - "mixed function oxidase" inhibitors: piperonyl butoxide; - blockers of sodium channels: indoxacarb, metaflumizone; - others: benclotiaz, bifenazate, kartap, flonikamid, pyridalyl, pymetrozin, sulfur, thiocyclam, flubendiamide, chlorantraniliprole, ciazipyr (NOMUUVb); cyenopyrafen, flupyrazofos, cyflumethofen, amidoflumet, imiciafos, bistrifluron and pyrifluquinazone.

Examples of antidotes are benoxacor, clohintocet, cyometrinil, cyprosulfamide, dichloramide, dicyclonone, dietolate, fenchlorazole, fenclorim, furazole, fluxofenim, ffurilazole, isoxadifen, mefenpyr, mefenate, naphthoic anhydride, oxabetrinil, 4-(dichloroacetyl)-1-oxa- 4- azaspiroI(4.5|decane (CA5 71526-07-3) and 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (CA5 52836-31-4).

Preferred pesticides contain at least one pesticide with at least one H-acid group (such as a carboxylic acid group, a phosphonic acid group, a phosphinic acid group) or their anionic salts (eg, single, double, or triple salts).

Said anionic salts of H-acid group pesticides are also suitable as Group A anionic pesticides." Preferred H-acid group pesticides are H-acid group herbicides. Examples of H-acid group herbicides are amino acid analogs (such as glyphosate or glufosinate) or imidazolinones (such as imazametabenz, imazamox, imazapic, imazapyr, imazaquin, imazetapyr).

Particularly preferred pesticides with the H-acid group are glyphosate and glufosinate. In another preferred embodiment, pesticides with an H-acid group are imidazolinones.

Particularly preferably, the pesticide contains a pesticide with an H-acid group and one additional pesticide. In another embodiment, the pesticide contains a mixture of at least two pesticides with a 3 H-acidic group, and optionally additional pesticides (such as at least one fungicide, herbicide, insecticide, and/or antidote, with fungicides and/or herbicides being preferred) .

In a further preferred embodiment, the pesticide comprises glyphosate (e.g., as the free acid, sodium salt, sesquisodium salt, potassium salt, dipotassium salt, ammonium salt, diammonium salt, dimethylammonium salt, trimesium salt, or isopropylamine salt) or glufosinate (e.g. , as an ammonium salt). Particularly preferably, the pesticide contains glyphosate (for example, as a potassium salt, an ammonium salt or an isopropylamine salt). With particular advantage, the pesticide contains glyphosate or glufosinate and, in addition, an additional herbicide. In another preferred embodiment, the pesticide comprises glyphosate or glufosinate and, in addition, an additional pesticide (such as at least one fungicide, herbicide, insecticide and/or antidote, with fungicides and/or herbicides being preferred).

Most preferably, the pesticide contains glyphosate and at least one additional herbicide selected from the following list: acetochlor, acifluorfen, aclonifen, acrolein, alachlor, ametryn, amidosulfuron, amitrole, anilophos, azulam, atrazine, azafenidin, azimsulfuron, benazolin, benfluralin, benfurezate, bensulfuron -methyl, benzulide, bentazone, benzofenap, bialafos, bifenox, bromacil, bromobutide, bromophenoxime, bromoxynil, butachlor, butamiphos, butralin, butroxidim, butylate, cafenstrol, carbetamide, cafentrazone-ethyl, clomethoxifen, chloroamben, chlorobromuron, chloroidazone, chloroimuron-ethyl ) ,

2,4-0, 2,4-OB, daiimuron, dalapon, desmedipham, desmethrin, dicamba, dichlobenil, dichlorprop, diclofop-methyl, difenzoquat, diflufenican, dimefuron, dimepiperate, dimetachlor, dimethamethrin, dimethenamid, dinitramine, dinoterb, difenamide, diquat, dithiopyr, diuron, endotal, ERTS, esprocarb, etalfluralin, ethametsulfuron-methyl, etofumesate, ethoxysulfuron, ethobenzanid, fenac, fenoxaprop, fenoxaprop-ethyl, fenuron, flamprop, flamprop-methyl, flazasulfuron, fluazifop-butyl, fluchloralin, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazin, fluometuron, fluorochloridone, fluoroglycofen, fluoroglycofen-ethyl, flupoxam, flupropanate, flurenol, fluridone, Ffluroxypyr-1-methylheptyl, flurtamone, fluthiacet-methyl, fomezafen, fosamine, glufosinate, halosulfuron, haloxifop-methyl, hexazinone, imazamet, imazametabenz, imazamox, imazapic, imazapyr, imazaquin, imazetapyr, imazosulfuron, indanophan, yoxinil, isoproturon, isouron, isoxaben, isoxaflutol, isoxapyrifop, lactofen, lenacil, linuron, MSRA, MSRV, mekop rop, mefenacet, mesotrione, metamitron, metazachlor, metabenzthiazuron, methylarsinic acid, methyldimron, metobenzuron, metobromuron, metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, molinate, monolinuron, naproanilide, napropamide, naptalum, neburon, nicosulfuron, nonanoic acid, norflurazon, orbencarb, oryzalin, oxadiargil, oxadiazon, oxasulfuron, oxyfluorfen, paraquat, pebulate, pendimethalin, pentanochlor, pentoxazone, phenmedipham, picloram, piperofos, pretilachlor, primisulfuron, prodiamine, prometon, promethrin, propachlor, propanil, propaquizafop, propazine, propham, propisochlor, propizamide, prosulfocarb, prosulfuron, pyraflufen-ethyl, pyrazolinate, pyrazosulfuron-ethyl, pyrazoxifene, pyributycarb, pyridate, pyriminobac-methyl, quinclorac, quinmerac, quizalofop-ethyl, rimsulfuron, sethoxydim, siduron, simazine, symetryn, sulcotrione, sulfamic acid, sulfentrazone , sulfometuron, sulfosulfuron, TSA, tebutam, tebuthiuron, terbacil, terbumeton, terbutilazine, terbutrin, t enilchlor, thiazopyr, thifensulfuron, thiobencarb, thiocarbazyl, tralkoxide, trialate, triasulfuron, tribenuron, 2,3,6- trichlorobenzoic acid, triclopyr, trietazin, trifluralin, triflusulfuron, vernolate.

In an additional, particularly preferred embodiment, the pesticide contains imazamox and at least one additional herbicide selected from the following classes B1) - 615):

B1) inhibitors of lipid biosynthesis: chloroazifop, clodinafop, clofop, cigalofop, diclofop, fenoxaprop, fenoxapropep, fentiaprop, fluazifop, fluazifop-P, haloxyfop, haloxyfop-P, isoxapyrifop, metamifop, propaquizafop, quizalofop, quizalofop-P, trifop, aloxidim, butroxidim, clethodim, cloproxidim, cycloxidim, profoxidim, sethoxidim, tepraloxidim, tralcoxidim, butylate, cycloate, dialate, dimepiperate, ERTS, esprocarb, etiolate, isopolinate, methiobencarb, molinate, orbencarb, pebulate, prosulfocarb, sulfate, thiobencarb, thiocarbazyl, trialate, vernolate, benfuresate, etofumesate, bensulide and pinoxaden; B2) inhibitors

AI 5: amidosulfuron, azimsulfuron, bensulfuron, chloroiimuron, chlorosulfuron, cynosulfuron, cyclosulfamuron, ethametsulfuron, ethoxysulfuron, flasasulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, mesosulfuron, metsulfuron, nicosulfuron, oxasulfuron, pyrosulfuron, dorasulfuron, primiuron sulfometuron, sulfosulfuron, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, imazametabenz, imazapic, imazapyr, imazaquin, imazetapyr, cloransulam, diclosulam, florazulam, flumetsulam, metosulam, penoxsulam, bispiribac, pyriminobac, propoxicarbazone, pyridoxazone pyrithiobac, flucetosulfuron, orthosulfamuron, pirimisulfan; 63) photosynthesis inhibitors: atraton, atrazine, ametrine, aziprothrin, cyanazine, cyanathrine, chloroazine, cyprazine, desmethrin, dimetamethrin, dipropethrin, eglinazine, ipazine, mesoprazine, methometon, methoprothrin, procyazine, progliansin, prometon, promethrin, propazine, sebutilazine, secbumeton , simazine, simeton, simethrin, terbumeton, terbuthylazine, terbutrin, triethazine, ametridione, ambuzin, hexazinone, isomethiosin, metamitron, metribuzin, bromacil, isocil, lenacil, terbacil, brompyrazone, chloridazone, dimidazone, desmedipham, phenizofam, phenmedipham, phenmedipham-ethyl , benzthiazuron, buthiuron, ethidimuron, isouron, metabenzthiazuron, monizuron, tebuthiuron, thiazafluron, anizuron, buturon, chlorbromuron, chlorturon, chlorotoluron, chloroxuron, difenoxuron, dimefuron, diuron, fenuron, fluometuron, fluotiuron, isoproturon, linuron, metiuron, methobromuron , methoxuron, monolinuron, monuron, neburon, parafluron, phenobenzuron, siduron, tetrafluron, thidiazuron, cyperquat, dieetamquat, difenzoquat, diquat, m orfamquat, paraquat, bromobonil, bromoxynil, chloroxynil, iodobonil, yoxinil, amicarbazone, bromophenoxime, flumezin, metazol, bentazone, propanil, pentanochlor, pyridate and pyridafol; 54) protoporphyrinogen-YH oxidase inhibitors: acifluorfen, bifenox, clomethoxifene, 60 chloronitrophen, ethoxyfen, fluorodifen, fluoroglycofen, fluoronitrophen, fomezafen,

furyloxifen, halozafen, lactofen, nitrofen, nitroftorfen, oxyfluorfen, fluazolate, pyraflufen, cinidon-ethyl, flumiclorac, flumioxazin, flumipropin, fluthiacet, thidiazimin, oxadiazon, oxadiargyl, azafenidine, cafentrazone, sulfentrazone, pentoxazone, benzphendizone, butafenacil, pyraclonil, profluazole, flufenpyr, flupropacil, nipiraclofen, etnipromide, safluphenacil and bencarbazone; 065) decolorizing herbicides: metfluazone, norflurazon, flufenican, diflufenican, picolinafen, beflubutamide, fluridone, flurochloridone, flurtamone, mesotrione, sulcotrione, isoxachlortol, isoxaflutol, benzofenap, pyrazolinate, pyrazoxifene, benzobicyclone, amitrole, clomazone, aclonifen, 4-(z- trifluoromethyl-phenoxy)-2-(4-trifluoromethylphenyl)pyrimidine, disclosed in EP 723960, topramesone, 4-hydroxy-3-CH2-methyl-b-(trifluoromethyl)-3-pyridinylcarbonyl)bicycloY3.2.1|oct-3-ene -2-one, disclosed in UMO 00/15615, 4-hydroxy-3-C2-(2-methoxyethoxy)methyl-6-(trifluoromethyl)-3-pyridinylcarbonyl)bicyclo|/3.2.1|oct-Z-en- 2-one, disclosed in UMO 01 /94339, 4-hydroxy-3-|4- (methylsulfonyl)-2-nitrobenzoyl|bicyclo|3.2.1|-oct-3-en-2-one, disclosed in ER 338992, 2-(2-chloro-4-(methylsulfonyl)-3-(2,2,2-trifluoroethoxy)methyl-3-hydroxy-3-cyclohexen-1-one (disclosed in OE 19846792) and pyrasulfotol; Bb) ERBR inhibitors synthases: oglyphosate; 57) glutamine synthase inhibitors: glufosinate and bilanafos; B8) ONR synthase inhibitors: azulam; 09) mitosis inhibitors: benfluralin, butralin, dinitramine, etalfluralin, fluchloralin, isopropalin, metalpropalin, nitralin, oryzalin, pendimethalin, prodiamine, profluralin, trifluralin, amiprofos-methyl, butamiphos, dithiopyr, thiazopyr, propizamide, tebutam, chlorthal, carbetamide, chlorbupham , chlorpropham and profam; 10) MISEA inhibitors (inhibitors of the synthesis of very long-chain fatty acids): acetochlor, alachlor, butachlor, butenachlor, delachlor, diethyl, dimetachlor, dimethenamid, dimethenamid-P, metazachlor, metolachlor, 5-metolachlor, pretilachlor, propachlor, propisochlor, prinachlor, terbuchlor , tenylchlor, xylachlor, alidochlor,

COEA, epronaz, difenamide, napropamide, naproanilide, petxamide, flufenacet, mefenacet, fentrazamide, anilophos, piperophos, cafenstrol, indanophan and tridiphan; bB11) cellulose biosynthesis inhibitors: dichlobenil, chlorthiamide, isoxaben and flupoxam; 012) disconnecting herbicides: dinofenate, dinoprop, dinosam, dinoseb, dinoterb, OMOS, etinofen and medinoterb; 013) auxin herbicides: clomeprop, 2,4-0, 2,4,5-TH, MCPA, MCPA thioethyl, dichlorprop, dichlorprop-

P, mecoprop, mecoprop-P, 2,4-08, MOSRV, chloramben, dicamba, 2,3,6-TVA, tricamba, quinclorac, quinmerac, clopyralid, fluroxypyr, picloram, triclopyr, benazolin and aminopyralid; 014) auxin transport inhibitors: naptalam, diflufenzopyr; 615) benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldimron, ethobenzanide, fosamine, metham, pyributycarb, oxacyclomefon, diazomet, triaziflam, methyl bromide.

Suitable surfactants include, but are not limited to, anionic, cationic, nonionic and amphoteric surfactants, block polymers and polyelectrolytes. Preferred surfactants are anionic surfactants and nonionic surfactants. In a particularly preferred embodiment, the surfactants are anionic surfactants. In an additional particularly preferred embodiment, the surfactants are nonionic surfactants.

Suitable anionic surfactants are surfactants containing an anionic group, such as sulfonates, sulfates, phosphates or carboxylates. Anionic surfactants can be used in the form of alkali metals, alkaline earth metals or ammonium salts, or additionally in the form of a free acid. Preferred anionic surfactants are sulfonates and phosphates. In one embodiment, phosphonates are particularly preferred. In a further embodiment, phosphates are particularly preferred.

Examples of sulfonates are alkylaryl sulfonates, diphenyl sulfonates, alpha-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Preferred sulfonates are alkylarylsulfonates, particularly preferred is C-alkylbenzenesulfonate. Such alkylaryl sulfonates can be prepared by sulfonating alkylbenzene with sulfur trioxide. Alkylarylsulfonates are commercially available as C0-3-alkylbenzenesulfonate, the free acid, or C0-13-alkylbenzenesulfonate, an alkanolamine salt. Alkylarylsulfonates are preferably present as a free acid or as an alkanolamine salt (for example, triethanolamine).

Examples of sulfates are sulfates of fats and oils, ethoxylated alkylphenols, C2-alcohols, ethoxylated alcohols, or fatty acid esters. Preferred sulfates are sulfates of C12-2-alcohols and ethoxylated C12-2-alcohols.

Examples of phosphates are phosphate esters. Preferred phosphates are complex phosphate esters of alkoxylates, such as complex phosphate esters of alkanolalkoxylates. 60 Preferred phosphates are complex phosphate esters of Svgg2-alkanolalkoxylates

(in particular St-14-alkanol oxylates). Alkoxylate chain is usually composed of ethylene oxide and/or propylene oxide. In most cases, it has an average number of aluoxide units in the range from b to 30, preferably from 12 to 18. Phosphates are preferably presented in the form of a free acid or as an alkanolamine salt (for example, triethanolamine). Complex phosphate esters can be present as complex phosphate monoesters or complex phosphate diesters, or as a mixture of these.

Examples of carboxylates are alkyl carboxylates and carboxylated alcohol ethoxylates or alkylphenol ethoxylates. Preferred carboxylates are alkyl carboxylates, such as alkyl carboxylates having 8-32 carbon atoms, in particular 10-22 carbon atoms. Examples are fatty acids, which can also be present in technical mixtures of chains with a length that is, for example, from 10 to 22 carbon atoms.

Suitable nonionic surfactants are alkylates, M-alkylated fatty acid amides, amine oxides, esters or sugar-based surfactants. Preferred nonionic surfactants are alkylates and sugar-based surfactants. In one embodiment, alkylates are particularly preferred. In a further embodiment, sugar-based surfactants are particularly preferred.

Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkylated. Ethylene oxide and/or propylene oxide can be used for alkylation, preferably ethylene oxide.

Preferred alkoxylates are alkanol alkoxylates, preferably straight and branched, saturated or unsaturated C422-alkanol alkoxylates, while the oxylate is composed of ethylene oxide and/or propylene oxide. The alkanol alkoxylate usually contains an average number of alkoxide units in the range from 2 to 50, preferably from 2.2 to 20, particularly preferably from 2.8 to 12 and in particular from 2.8 to 8. Alkanol alkoxylates are commercially available from VABE

ZE as Etshciape species, Ringagas species or I Shepzois species.

Examples of M-alkylated fatty acid amides are fatty acid glucamides or fatty acid alkanolamides.

Examples of esters are fatty acid esters, glycerol esters or monoglycerides.

Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose esters, and glucose esters or alkylpolyglucosides. The preferred sugar-based surfactants are C-alkylpolyglucosides, for example, from S.P. (degree of polymerization) from 1.2 to 1.9.

Suitable cationic surfactants are quaternary surfactants, for example, quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.

Suitable amphoteric surfactants are alkyl betaines and imidazolines.

Suitable block polymers are block polymers of the A-B or A-B-A type, while it is possible for the A and B blocks to be polyethylene oxide, polypropylene oxide or polybutylene oxide.

Preferred examples are A-B block polymers composed of polyethylene oxide and polypropylene oxide, or polyethylene oxide and polybutylene oxide; as well as A-B-A block polymers composed of polyethylene oxide and polypropylene oxide, or polyethylene oxide and polybutylene oxide (in particular, polyethylene oxide/polypropylene oxide/polyethylene oxide). In addition, other block polymers that are also suitable are block polymers of type A-B-C containing polyethylene oxide, polypropylene oxide and polybutylene oxide.

Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali metal salts of polyacrylic acid. Examples of polybases are polyvinylamines or polyethyleneamines.

Particularly preferred is at least one surfactant selected from sulfonates, phosphates, alkoxylates, and sugar-based surfactants (eg, in compositions containing an alkoxylate, where KE" is a branched alkyl radical of SeNi, 2-propylheptyl, or 2-ethylhexyl). Very particularly preferred is at least one surfactant selected from among alkylarylsulfonates, complex phosphate ester of alkoxylates, alkanolalkoxylates and alkylpolyglucosides (for example, in compositions containing an alkoxylate, where K/ is a branched alkyl radical SeH'", 2-propylheptyl or 2-ethylhexyl).

A number of surfactants are preferably suitable for the composition according to the invention: a) In a preferred embodiment, the surfactant is a C16-18-alkanol alkoxylate, where the alkanol is composed of ethylene oxide and/or propylene oxide, and the alkanol alkoxylate has an average number of alkoxide units in the range from 12 to 35 , mostly from 17 to 26.

B) In an additional preferred embodiment, the surfactant is a C10-alkanol alkoxylate based on Herby alcohol, where the alkoxylate is composed of ethylene oxide, and the alkanol alkoxylate has an average number of alkoxide units in the range from 2 to 8, preferably from 2.5 to 6. c) In in an additional preferred embodiment, the surfactant is an iso-C13-alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide, and the alkanol alkoxylate has an average number of alkoxide units in the range from 3 to 10, preferably from 4.5 to 8. 4) In an additional preferred embodiment, the surfactant is a C4-8 alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide, and the alkanol alkoxylate has an average number of alkoxide units in the range from 2 to 9, preferably from 3.5 to 7. f) In a preferred embodiment, the surfactant is a C8-10 -alkyl polyglucoside from

S.P. from 1.4 to 1.9, preferably from 1.6 to 1.8. 7 In an additional preferred embodiment, the surfactant is C8-14-alkylbenzenesulfonate. 9) In an additional preferred embodiment, the surfactant is a complex phosphate ester of C8-14-alkanol oxylates.

Among the series mentioned above, surfactants B), c), g) and U) are more preferably suitable.

In another embodiment, the surfactant is selected from the groups B1) - 55): 01) nonionic surfactant of the formula B""Xp and its polyalkylated derivatives, where B" is selected from aliphatic or aromatic residues having at least eight carbon atoms; X is selected from hydroxy , -O-(C1-Cv-alkyl), -O-(C3-Cv-alkenyl), amine, amide, or ester; and n represents 1, 2, 3, 4, 5 or 6; 02) anionic a surfactant of the formula K'Mp, where K" is selected from aliphatic or aromatic residues having at least eight carbon atoms; M is selected from carboxylate, sulfonate, sulfate, phosphate, or phosphonate; and n is 1, 2, 3, 4, 5 or 6; rZ) cationic surfactant; p4) zwitterionic surfactant; or 05) polymeric surfactant.

In particular, the surfactant can be selected from 01) nonionic surfactants of the formula K'Xp and their polyalkylated derivatives (as defined below), where KK" is selected from aliphatic or aromatic residues having at least eight carbon atoms; X is selected from hydroxy, -

O-(C1-Cv-alkyl), -O-(C3-Cv-alkenyl), amine, amide, or ester; and n is 1, 2, 3, 4, 5, or 6. For example, glyceryl can be propyl (YAK), which includes three hydroxy groups (X). In the case where X is hydroxy, preferably at least one of the hydroxy groups is polyaluoxylated. The surfactant is preferably selected (from the polyalkylated derivatives of the formula K'"Xp. Preferred amides are mono- or di-

C:-C 1 -alkyl amides and mono- or di-C 1 -C 1 -acyl amides, where alkyl amides are particularly preferred.

A" is preferably selected from aliphatic or aromatic residues having up to at least 10, more preferably at least 12 carbon atoms. Aromatic residues may include aliphatic and/or aromatic substituents. In another form, KE" is selected from aliphatic or aromatic residues having from 8 to 30, preferably from 10 to 22 and in particular from 12 to 18 carbon atoms. K" is preferably selected from aliphatic residues having at least 10, more preferably at least 12 carbon atoms. Aliphatic residues can be straight or branched, saturated or unsaturated. Examples of K" are: 2,4,6-triisopropylphenyl, polystyrenephenyl, n-octyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-hexadecyl, n-octadecyl, 2-ethylhexyl .

Surfactant 61 is preferably selected from nonionic surfactants polyaluoxylated derivatives of formula B''Xp'', where CC'' is selected from aliphatic or aromatic residues having at least eight carbon atoms; and X is selected from hydroxy, amine or amide.

Polyalkylated derivatives of the formula K'"Xp include a polyaloxylate residue, which may include 5-50 (preferably 6-25 and in particular 6-20) equivalents of C 0 -C 8 -alkylene oxide. Of course,

A"Xp includes one or two polyalukoxylate residues for each X residue, depending on the free valences of X. In the case where X is hydroxy, said hydroxy group may include one polyalukoxylate residue for each hydroxy group. In the case when X is an amine, then the specified amino group may include one or two, preferably two, polyalkyloxylate residues for each amino group. Preferably, the alkylene oxide is selected from 60 ethylene oxide, propylene oxide, butylene oxide, as well as mixtures thereof. In a preferred form,

polyalkylated derivatives of the formula K'"Xp include polyethylene oxide residues, which may include 6-15 equivalents of ethylene oxide. Preferred are poly(C2-Ce alkoxylate) residues, such as polyethylene oxide, polypropylene oxide. Alkylene oxide units can be arranged in an arbitrary or block sequence (as, for example , EO-PO-EO). The alkylene oxide units may be further substituted with other functional groups, such as alkyl, acyl, or polyethylene glycol groups. The polyalkyloxylate residue may be hydrogen-terminated or any organic group such as C:-C 1 alkyl.

In an additional embodiment, X may be selected from ethoxylated amide derivatives, which may include 1-20 equivalents of ethylene oxide.

In an additional embodiment, X can be selected from alkylated derivatives of complex esters, where the polyaluoxylate residue includes 1-50 (preferably 2-25 and in particular 5-25) equivalents of Co-C"-alkylene oxide.

Particularly preferred surfactants 01) of the formula K'""Xp are - ethoxylated isotridecyl alcohols, which include 5, 6, 8, 15, or 20 equivalents of ethylene oxide, and optionally end with a methyl group, - alkoxylated 2-propylheptyl alcohols, which include 10 equivalents of ethylene oxide, and optionally 2 or 5 equivalents of propylene oxide, - alkylated straight, saturated fatty alcohols, such as alkylated straight, saturated C16-18 fatty alcohols, which include 2-80 equivalents of ethylene oxide, - alkylated 2-propylheptylamines, for example, which include 7-15 equivalents of ethylene oxide, - Alkoxylated tallow amine, for example, which includes 10-20 equivalents of ethylene oxide, - Alkoxylated isodecanol, for example, which includes 5-15 equivalents of ethylene oxide, - Alkoxylated Herbie C10 alcohols, for example, which include 5-15 equivalents ethylene oxide, - alkylated C13/15-oxoalcohols, for example, which include 5-30 equivalents of ethylene oxide, - aluoxylated straight, saturated fatty alcohols, which include at least one equivalent of ethylene oxide and at least one equivalent of C3-6 alkylene oxide, - ethoxylated n-dodecanol (8 EC), - an ethoxylated fatty acid (saturated or unsaturated) which includes 5-20 equivalents of ethylene oxide, optionally ending with an acyl (e.g. , which is a fatty acid derivative), - ethoxylated fatty acid monoamide (saturated or unsaturated), which includes 5-20 equivalents of ethylene oxide, - ethoxylated fatty acid diamide (saturated or unsaturated), which includes 10-40 equivalents of ethylene oxide, - ethoxylated glycerol, which includes a total of 10-45 equivalents of ethylene oxide and up to 15 in each polyethoxylate chain, and optionally ends with C8-C22-alkyl.

Surfactant 52) can be selected from 52) anionic surfactants of the formula K"Up, where B" is selected from aliphatic or aromatic residues having at least eight carbon atoms; U is selected from carboxylate, sulfonate, sulfate, phosphate, or phosphonate; and Y represents 1, 2, 3, 4, 5 or 6. The residue B" is determined as described above for V'Xp.

The anionic surfactant may be present as alkaline, alkaline earth, ammonium salts, or aliphatic amine salts (eg, hydroxyethylammonium, trihydroxyethylammonium, tetrahydroxyethylammonium, trihydroxypropylammonium).

Particularly preferred surfactants 52) of the formula K"Up are - aliphatic monocarboxylates, such as fatty acids or sarcosinates, - aliphatic oligocarboxylates, such as malonate or succinate derivatives, - sulfonamidocarboxylates, - aliphatic or aromatic sulfates, - polyether sulfates, - amidopolyether sulfates, - sulfated carboxylates, glycerides of carbonic acid, or esters of carbonic acid, - aliphatic or aromatic sulfonates, - sulfonated esters of carboxylic acids or amides of carboxylic acids, - esters of sulfosuccinic acid, - polyethersulfonates, - polyether phosphates, such as tristyryl polyether phosphate or polyalkylated fatty alcohol phosphate ester , 60 - polyether sulfate, such as fatty alcohol polyether sulfate,

- polyaloxylated derivatives of the formula K11Xp, where the polyalkyloxylate residue ends with a U residue.

Surfactant 63) can be selected from 53) cationic surfactants B''7n, which usually contain a lipophilic moiety such as KE" as disclosed above; cationic group 7; where n is 1, 2, 3, 4, 5 or 6 Suitable cationic groups 7 are ammonium; mono-, di-, tri-, or tetrasubstituted ammonium, where the substituents may be selected from C-C:o alkyl (e.g., methyl, ethyl, propyl, allyl), benzyl, C- C-simple alkyl ether or polyethylene glycol residue; di-C1-C12-alkylsulfonium; or nitrogen, which includes aromatic groups, such as M-substituted derivatives of pyrrole, pyridine, quinoline or isoquinoline, imidazole, oxazole, thiazole.

The cationic surfactant may be present as a salt, for example, an acetate, formate, propionate, sulfonate, sulfate, methyl sulfate, methyl sulfonate, phosphate, or halide (eg, chloride, bromide, or iodide) salt.

Particularly preferred surfactants 653), selected from cationic surfactants, are salts of - trimethyl-Ci-Coalkylammonium - C1-Coalkylammonium, - di-C--Coalkylammonium, - tri-Ci-Coalkylammonium, - benzyltri-Ci-Coalkylammonium, - M- substituted pyridinium, - derivatives of M, M'-C1-C12-dialkylimidazolium, - derivatives of M-C1-C12-oxazolium, - derivatives of M-C1-C12-thiazolium, - C3-C0-alkyl-dimethylsulfonium, - C1-C0 esters 2-hydroxyethyl-trimethylammonium carboxylic acid, - C1-C2 esters of ethoxylated (1-15 EC) 2-hydroxyethyl carboxylic acid - trimethylammonium, - tri-C1-C2-alkyl-C1-C2-alkylammonium.

Surfactant 54) can be selected from 654) zwitterionic surfactants, which usually contain a lipophilic moiety such as K" as disclosed above, an anionic group such as U as disclosed above, and a cationic group 2 as disclosed above.

Particularly preferred surfactants 64), chosen from zwitterionic surfactants, are - tri-Ci-C-Co-alkylamine M-oxide, - betaines, such as M, M, M-tri-Ci-Cco-alkylglycine, - aminocarboxylic acids, - dimethylammonium, which ends with an ethoxylated C1-C5-alkylphosphonate, - derivatives of "-sulfated C3-C5-carbonic acid 2-(trimethylammonium) - complex ethyl ether, - Ф-(tri-C1-C5-alkylammonium)-C2-C5-alkylsulfonic acid, - (Z-Dodecanoylamino-propyl)-dimethyl-ammonium|-acetic acid.

Surfactant 55) can be selected from B5) polymeric surfactants, which usually have a molecular weight of at least 2000 g/mol, preferably at least 5000 g/mol. The polymeric surfactant can be composed of monomers, such as derivatives of M-vinylamines, C2-C4 alkylene oxide, (meth)acrylates, (meth)acrylic acid, M-vinylformamides, M-vinyliridines, AMP5. Monomers can be arranged in a random or block sequence. Suitable block polymers are block polymers of type A-B or A-B-A blocks containing polyethylene oxide and polypropylene oxide, or of type A-B-C containing alkanol, polyethylene oxide and polypropylene oxide. Block polymers can end with hydrogen or C1-C4 alkyl groups.

The most preferred surfactants from groups B1) - 55) are selected from: - polyester phosphates, in particular complex phosphate ester of polyalkylated fatty alcohol; - Alkoxylated 2-propylheptylamines, in particular ethoxylated 2-propylheptylamines, which include 7-15 equivalents of ethylene oxide, - Alkoxylated tallow amine, in particular ethoxylated tallow amine, which includes 10-20 equivalents of ethylene oxide, - Polyether sulfate, in particular lauryl alcohol polyether sulfate, - Ethoxylated isotridecyl alcohols, in particular those that include at least 5 equivalents of ethylene oxide,

- Alkoxylated straight, saturated fatty alcohols, in particular, Alkoxylated straight, saturated C:v fatty alcohols, which include 10-80 equivalents of ethylene oxide, - Alkoxylated isodecanols, in particular those that include 4-15 equivalents of Ethylene oxide, - Alkoxylated Gerbi Hundred alcohols , in particular those that include 5-15 equivalents of ethylene oxide, - alkylated Sisl5-oxo alcohols, in particular those that include 5-30 equivalents of ethylene oxide, - block polymers of type A-B-A, containing blocks A of polyethylene oxide and blocks B of polypropylene oxide, which can have a molecular weight from 800 to 8000 Da, - alkylated straight, saturated fatty alcohols, which include at least one equivalent of ethylene oxide and at least one equivalent of C3.e alkylene oxide.

Specific, non-limiting examples of preferred surfactants from groups 01) - 55) are the following surfactants:

T1 is ethoxylated isotridecyl alcohol, which includes 8 equivalents of ethylene oxide.

T2 is an ethoxylated tallow amine that includes 15 equivalents of ethylene oxide.

ТZ ethoxylated 2-propylheptylamines, which include 10 equivalents of ethylene oxide.

T4 is a complex phosphate ester of a polyalkylated fatty alcohol, commercially available as Kieagas? DA-270 from VABE 5E company.

T5 are alkylated straight, saturated Stv-v fatty alcohols that include 2-20 equivalents of ethylene oxide and 2-20 equivalents of propylene oxide.

T6 polyester sulfate of lauryl alcohol, which includes 10 equivalents of ethylene oxide, sodium salt.

T7 is ethoxylated isotridecyl alcohol, which includes 5 equivalents of ethylene oxide.

T8 is ethoxylated isotridecyl alcohol, which includes 4 equivalents of ethylene oxide.

T9 is ethoxylated isotridecyl alcohol, which includes 3 equivalents of ethylene oxide.

T10 is ethoxylated pentanol, which includes 4 equivalents of ethylene oxide.

T11 Polyoxyethylene(20)-sorbitan monolaurate.

The composition may contain at least one surfactant, for example, one, two or three surfactants.

In one embodiment, the composition contains at least two different surfactants.

Preferably, the composition contains one nonionic and one anionic surfactant, two different anionic surfactants, or two different nonionic surfactants.

Suitable examples of two nonionic surfactants are two alkoxylates, preferably two different alkanol alkoxylates.

Suitable examples of two anionic surfactants are one sulfonate and one phosphate, preferably one alkylarylsulfonate and one complex phosphate ester of alkoxylates, in particular one oSlv-alkylbenzylsulfonate and one complex phosphate /- ether of alkanolalkoxylates.

Suitable examples of one nonionic and one anionic surfactant are, in the first embodiment, one alkoxylate and one sulfonate, preferably one alkanol alkoxylate and one alkylaryl sulfonate; in the second variant of implementation, one alkylpolyglucoside and one sulfonate, preferably one S-iv-alkyloliglucoside with S.P. from 1.2 to 1.9 and one S-iv- alkylbenzylsulfonate.

The mass ratio of the surfactant to the alkoxylate is generally in the range of 1:99 to 70:30, preferably in the range of 5:95 to 50:50, particularly preferably in the range of 25:75 to 40:60.

In most cases, the composition contains from 1 to 80 95 by weight (preferably from 3 to 50, especially preferably from 5 to 30, and in particular from 8 to 2095 by weight) of the total amount of surfactant and alkoxylate.

Compositions according to the invention may, in addition, also contain auxiliary substances that are traditionally used for agrochemical preparations, the choice of auxiliary substances depends on the specific type of application, type of preparation form or active substance. Examples of suitable excipients are solvents, solid fillers, surfactants (such as surfactants, solubilizers, protective colloids, wetting agents and tackifiers), organic and inorganic thickeners, bactericides, antifreeze agents, antifoam agents, necessarily dyes, and adhesives (for example, for seed treatment) or traditional auxiliary substances for preparative forms in the form of baits (for example, attractants, nutrients, bitter substances).

Suitable solvents are water or organic solvents such as medium to high boiling mineral oil fractions such as kerosene and diesel oil, in addition coal oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e.g. , paraffins, tetrahydronaphthalene, alkylated naphthalenes and their derivatives, alkylated benzenes and their derivatives, alcohols such as methanol, ethanol, propanol, butanol and cyclohexanol, glycols, ketones such as cyclohexanone, gamma-butyrolactone, fatty acid dimethylamides, fatty acids and fatty acid esters as well as highly polar solvents such as amines such as M-methylpyrrolidone. In principle, it is also possible to use mixtures of solvents and mixtures of the above-mentioned solvents and water.

Solid fillers are natural minerals such as silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, lime clay, loess, clay, dolomite, diatomite, calcium and magnesium sulfate, magnesium oxide, crushed synthetic materials, fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as grain flour, tree bark flour, tree flour and nut shell flour, cellulose powders or other solid fillers.

Suitable thickeners are compounds that impart modified flow properties to the formulation, i.e. high viscosity at rest and low viscosity when agitated. Examples are polysaccharides, proteins (such as casein or gelatins), synthetic polymers, or inorganic layered minerals. Such thickeners are commercially available, for example, Hapitap sit (Keygap?, SR Keiiso company, USA), EPpodoroiI223 (KPpoyaia company,

France) or Meedit?e (K.T. Mapaegbiy company, USA) or ANasiau? (Company EpdeiNaga Sogr.

Moscow State University, USA). The content of the thickener in the preparative form depends on the effectiveness of the thickener. The practitioner will choose such a content, at which the desired viscosity of the preparation form will be achieved. In most cases, the content varies from 0.01 to 10 95 by mass.

Bactericides may be added to stabilize the formulation. Examples of bactericides are those based on dichlorphen and benzyl alcohol hemiformal, as well as isothiazolinone derivatives, such as alkylisothiazolinones and benzoisothiazolinones (Aciyside? MV5 from Tpog Spetier). Examples of suitable antifreezes are ethylene glycol, propylene glycol, urea and glycerin. Examples of antifoam agents are silicone emulsions (such as, for example, 5ykCope 5EE, Umaskeg Company,

Germany or KPodogziie, KEPodia company, France), long-chain alcohols, fatty acids, salts of fatty acids, organofluorine compounds and mixtures of the above.

The composition according to the invention can preferably be presented in the form of an agrochemical preparation form, while water-soluble concentrates are preferred.

Examples of preparative forms and their manufacture are: i) Water-soluble concentrates (51, I 5): 10 parts by weight of active substances are dissolved using 90 parts by weight of water or a water-soluble solvent. Alternatively, wetting agents or other excipients are added. After dilution in water, the active substance dissolves. This gives a composition with an active substance content of 10 95 by weight. i) Dispersion concentrates (0C): 20 parts by mass of active substances are dissolved in 70 parts by mass of cyclohexanone with the addition of 10 parts by mass of a dispersant, for example, polyvinylpyrrolidone. After dilution in water, a dispersion is obtained. The content of the active substance is 20 95 by weight) Emulsion concentrates (EC): 15 parts by weight of active substances are dissolved in 75 parts by weight of xylene with the addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). After dilution in water, an emulsion is obtained. The composition has an active substance content of 15 95 by weight. im) Emulsions (EMU, EO, E5): 25 parts by mass of active substances are dissolved in 35 parts by mass of xylene with the addition of calcium dodecylbenzene sulfonate and castor oil ethoxylate (in each case 5 parts by mass). By applying an emulsifying agent (eg

MOPga-Tiggah), the specified mixture is added to 30 parts by weight of water and turned into a homogeneous emulsion. After dilution in water, an emulsion is obtained. The composition has an active substance content of 25-95% by weight. m) Suspensions (ZS, 00, E5): 20 parts by mass of active substances are ground with the addition of 10 parts by mass of dispersing substances and wetting substances and 70 parts by mass of water or an organic solvent in a ball mill with a stirring mechanism, which gives a highly dispersed suspension of active substances After dilution in water, a stable suspension of the active substance is obtained. The content of the active substance in the composition is 20 95 by mass.

mi) Water-dispersible granules and water-soluble granules (MUS, 56): 50 parts by weight of active substances are finely ground with the addition of 50 parts by weight of dispersing substances and wetting substances and are made up as water-dispersible granules, or water-soluble granules using technical means (for example, extrusion, irrigation column, fluidized bed). After dilution in water, a stable dispersion or solution of the active substance is obtained. The composition has an active substance content of 50-95% by weight. water-dispersible powders and water-soluble powders (MUR, ZR, 55, UMU5): 75 parts by mass of active substances are ground in a rotor-stator mill with the addition of 25 parts by mass of dispersing substances and wetting substances, as well as silica gel After dilution in water, a stable dispersion or solution of the active substance is obtained. The content of the active substance of the composition is 75-95% by weight. gels (CE): 20 parts by mass of active substances, 10 parts by mass of dispersing substance, 1 part by mass of gelling substance and 70 parts by mass of water or organic solvent are ground in a ball mill, which gives a finely dispersed suspension. After dilution with water, a stable suspension with an active substance content of 9% by mass is obtained. them) Dust-like substances (OR, 05): 5 parts by mass of active substances are finely ground and thoroughly mixed with 95 parts by mass of highly dispersed kaolin. This gives a dust-like substance with an active substance content of 5.95% by weight. x) Granules (OK, BO, b, Mo): 0.5 parts by mass of active substances are finely ground and combined with 99.5 parts by mass of fillers. Traditional methods for this purpose are extrusion, spray drying or fluidized bed. This gives granules for direct use with an active substance content of 0.5 95 by weight. xi) Ultra-low volume solutions (UL): 10 parts by weight of active substances are dissolved in 90 parts by weight of an organic solvent, for example, xylene. This gives a composition to be used directly with an active substance content of 10 95 by weight.

Basically, the compositions contain from 0.01 to 95 95 by weight, preferably from 0.1 to 90 95 by weight of pesticides.

A user typically applies a composition according to the invention to be used in a pre-applying equipment, in a knapsack sprayer, in a spray can, or in a spray aircraft. Here, the formulation is brought to the desired concentration for use using a liquid, usually water and/or a buffer solution, optionally with the addition of additional excipients, resulting in a ready-to-use spray mixture (known as tank mix).

Of course, 50-500 liters of ready-to-use spraying mixture is used per hectare of useful agricultural area, preferably from 100 to 400 liters. In certain areas, the amount may also be higher (e.g. fruit growing) or lower (e.g. aircraft application) than the specified amount. In certain cases, such as, for example, application by aircraft, it is also possible to use an organic solvent instead of water to make up the spray mixture.

The concentration of the active substance in ready-to-use preparations can vary within significant ranges. Basically, they are in the range between 0.0001 and 10 95, preferably in the range between 0.01 and 1 Fo.

The concentration of the total amount of surfactant and alkoxylate in the ready-to-use preparation is in most cases in the range from 0.01 to 50 g/l, preferably 0.08 - 10 g/l and in particular 0.5 - 8 g/l.

Oils of various kinds, wetting agents, transfer reducers, tackifiers, fillers, auxiliaries, fertilizers, plant enhancers, trace elements, herbicides, bactericides, fungicides and/or pesticides may be added to the active substances or preparations , containing them, optionally also to the tank mixture, immediately before use. The specified products can be added to the compositions according to the invention in a mass ratio of 1:100-100:1, preferably 1:10-10:11. Depending on the nature of the desired effect, the rates of application of the active substance when used for plant protection are between 0.001 and 2.0 kg of active substance per hectare, preferably between 0.005 and 2 kg per hectare, especially preferably between 0, 0510.9 kg per hectare, in particular between 0.1 and 0.75 kg per hectare.

The rate of application of the total amount of surfactant and alkoxylate in most cases is in the range from 10 to 3000 g/ha, preferably from 10 to 1000 g/ha, especially preferably from 60 to 80 to 750 g/ha and especially from 200 to 400 g/ha.

In addition, the present invention relates to a concentrate containing a surfactant and an amine alkoxylate (A), or a quaternized derivative (AC) of an amine alkoxylate (A). This concentrate is particularly suitable for use as an additive to the tank mix. Suitable and preferred embodiments of the surfactant, the amine alkoxylate (A) and the quaternized derivative (AC) of the amine alkoxylate (A) are as mentioned above. The mass ratio of the surfactant to the alkoxylate is in the range from 1:99 to 70:30, preferably in the range from 5:95 to 50:50, especially preferably in the range from 25:75 to 40:60. The concentrate may optionally contain solvents such as water or organic solvents. The concentrate may optionally contain excipients such as the excipients mentioned above.

In addition, the present invention relates to the method of manufacturing the composition according to the invention by means of a) bringing the concentrate according to the invention into contact with the pesticide; or p) by contacting a pesticide, a surfactant and an amine (A), or a quaternized derivative (AC) of an amine (A) alkoxylate.

In a preferred embodiment, the method is a method of producing a tank mixture containing the composition by bringing the surfactant into contact with a mixture containing a pesticide and an amine oxylate. In most cases, the mixture is an aqueous mixture (such as tank mix) which may contain a conventional composition of excipients. Here, the surfactant can be added in pure form or even diluted in water or organic solvents. Similarly, additional conventional excipients may be added in addition to the surfactant. Additional pesticides may also be added to the tank mix, such as at least one herbicide (eg, glyphosate) and at least one insecticide and/or one fungicide (eg, pyraclostrobin).

In addition, the present invention relates to the use of a surfactant in addition to a mixture (such as a tank mixture) containing a pesticide and an amine oxylate. Surfactant is mainly added in order to increase the biological activity of the pesticide.

In addition, the present invention relates to a method of combating phytopathogenic fungi and/or unwanted vegetation and/or an unwanted attack by insects or mites and/or for regulating plant growth, where the compositions according to the invention act on the relevant harmful organisms, their environment, or on plants to be protected against the relevant harmful organism, on soil and/or on undesirable plants and/or on cultivated plants and/or their environment.

Examples of suitable crops are cereal crops such as wheat, rye, barley, triticale, oats or rice; beet, for example, sugar or fodder beet; pome fruits, stone fruits and bush fruits or berry crops, such as apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, currants or gooseberries; legumes, such as beans, lentils, peas, alfalfa or soybeans; oil crops, for example, oilseed rape, mustard, olives, sunflower, coconuts, cocoa, castor, oil palm, peanut or soybean; cucurbit crops, such as pumpkin/zucchini, cucumber or melon; fiber crops, for example, cotton, flax, hemp or jute; citrus crops, for example, oranges, lemons, grapefruits or tangerines; vegetable plants and greens, such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, squash/zucchini or peppers; plants of the laurel family, for example, avocado, cinnamon tree or camphor tree; energy crops and industrial commodity crops, such as corn, soybeans, wheat, rapeseed, sugar cane or palm oil; corn; tobacco; nuts; coffee; tea; bananas; grapevine (dessert grapes and grapes for winemaking); hop; herbaceous plants, for example, turf; sweet grass (5iemia heratsdapia); rubber plants and forest plants, such as flowers, shrubs, deciduous trees and conifers, as well as plant propagation material, such as seeds, and the harvested products of said plants.

The term cultivated plants also includes such plants that have been modified by breeding, mutagenesis or recombinant methods, including biotechnological agricultural products that are on the market or are in the process of development.

Genetically modified plants are plants whose genetic material has been modified in a way that does not occur under natural conditions by crossing, mutation or natural recombination (ie recombination of genetic material). Here, one or more genes, as a rule, have been integrated into the genetic material of the plant in order to improve the characteristics of the plant. Such recombinant modifications also include post-translational modifications of proteins, oligo- or polypeptides, for example, by means of glycosylation or linking polymers, such as, for example, prenylated, acetylated 60 or farnesylated residues or PEG residues.

Examples that can be mentioned are plants that, as a result of plant breeding and recombinant means, have acquired tolerance to certain classes of herbicides, such as hydroxyphenylpyruvate dioxygenase inhibitors (HPPs), aceloctate synthase (AI5) inhibitors, such as, for example, sulfonylureas ( EP-A 257 993, 5 5,013,659) or imidazolinones (for example 5 6,222,100,

MO 01/82685, MO 00/26390, MO 97/41218, MO 98/02526, MO 98/02527, MO 04/106529, MO 05/20673, UO 03/14357, UMO 03/13225, UMO 03/14356, UO 04/16073), enolpyruvylshikimate Z-phosphate synthase (ERBR5) inhibitors, such as, for example, glyphosate (see, for example, UMO 92/00377), glutamine synthase (5) inhibitors, such as, for example, glufosinate (see, for example, EP-A 242 236, EP-A 242 246) or oxynil herbicides (see, for example, 05 5,559,024). For example, did selection and mutagenesis lead to the oilseed rape Seagull? (WABE 5E company, Germany), which has tolerance to imidazolinones, for example, to imazamox. Using recombinant methods, crops such as soybeans, cotton, corn, beets, and canola have been created that are resistant to glyphosate or glufosinate, and these plants are commercially available under the trade names

Warriorhead? (resistant to glyphosate, Mopzapio company, USA) and Girepu pc? (resistant to glufosinate, Waweg Storzsiepse, Germany).

Also covered are plants that, using recombinant methods, produce one or more toxins, for example, toxins from the Wasiya5 strain of bacteria. Toxins produced by such genetically modified plants contain, for example, insecticidal proteins

Vasiyi5 5yrs. in particular, B. IPyhipdiepvi5, such as endotoxins StutAbr, StutAs, Stui1E, StuiRa?g,

StgugAB, StuzA, StuzBЬ1, Studs, StuZz4АБИ or Stuz5БАБИ1; or plant insecticidal proteins (MIRs), for example, MIR1, MIR2, MIRZ, or MIRZA; insecticidal proteins of bacteria that colonize nematodes, for example, Rioiogpabdiv 5yr. or Hepotavaiz 5 years; toxins from animal organisms, for example, wasp, spider or scorpion toxins; mushroom toxins, for example, Zygeriotusegiev; plant lectins, for example, pea or barley lectins; agglutinins; proteinase inhibitors, for example, trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome-inactivating proteins (RIP proteins), such as ricin, maize RIP, abrin, lufin, saporin, or briodin; enzymes of steroid metabolism, for example, 3-hydroxysteroid oxidase, ecdysteroid-

IOR-glycosyltransferase, cholesterol oxidase, inhibitors of ecdysone or NMO CoA-reductase; blockers of ion channels, for example, inhibitors of sodium or calcium channels; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stilbene synthase, bibenzyl synthase, chitinases and glucanases. These toxins can also be produced in plants in the form of pretoxins, hybrid proteins, processed or otherwise modified proteins. Hybrid proteins are distinguished by a new combination of different protein domains (see, for example, MO 2002/015701). Additional examples of such toxins or genetically modified plants that produce said toxins are disclosed in EP-A 374 753,

MO 93/07278, MO 95/34656, ER-A 427 529, ER-A 451 878, UMO 03/18810 and UMO 03/52073. Methods of creating these genetically modified plants are known in practice and are explained, for example, in the above-mentioned publications. A large number of the toxins mentioned above give the plants that produce them tolerance to harmful organisms from all taxonomic classes of arthropods, in particular to beetles (SoepIegoria), Diptera (Oiriega) and Lepidoptera (I eridoriega) and to nematodes (Metaiioda). Genetically modified plants that produce one or more genes that encode insecticidal toxins are described, for example, in the above-mentioned publications, and in some cases are commercially available, for example, such as MmiwiiasSaga? (varieties of corn that produce StutAbB toxin), mMividysSaga? Rye (corn varieties that produce SguTAb toxins and

StuzVvr1), stageip0k? (varieties of corn that produce Sgubs toxin), Negosheh? UM (maize varieties that produce toxins StuZz4АБИ1, StuzBABII and also the enzyme phosphinothricin M- acetyltransferase |IRATI); MyiSOTMe Z33B (cotton varieties that produce the SgutAs toxin),

Vojdauga? | (cotton varieties that produce the SgutAs toxin), Voidaga? Iii (cotton varieties that produce StutAs and Stu2Ar2 toxins); MIRSOT?U (cotton varieties that produce the MIR toxin);

Mel eai? (potato varieties that produce SguzZA toxin); VI-Hna?, MaishgesSagaye, Kposkoipy,

VieeSagagye, Rgoivsia", ВІ1 (for example, Adgyzyge? SV) and ВІ76 from the company Zupdepia beeydz5 5AB5,

France, (maize varieties that produce the SgutAb toxin and the RAT enzyme), MICbO4 from the company

Zupdepia beeazh ZA5, France (maize varieties that produce a modified version of the toxin

StuzA, in this context see M/O 03/018810), IOM 863 from the company Mopzapio Eigore 5.A.,

Belgium (maize varieties that produce the StuZVT toxin), IRS 531 from the company Mopzapio Eigore 5.A., Belgium (cotton varieties that produce a modified version of the StuTAs toxin) and 1507 from the company Riopeeg Omegzea5 Sogrogaiyop, Belgium (maize varieties that produce the toxin SguiE and the enzyme PAT).

Also covered are plants that, with the help of recombinant methods, produce one or more proteins that cause increased resistance, or the ability to resist bacterial, viral or fungal pathogens, such as, for example, so-called pathogen-associated proteins (RK proteins, see EP-A 0 392 225), resistance proteins (e.g., potato cultivars that produce two resistance genes to Riuorpiyoga iptebiap5 from the Mexican wild potato Zoiapyt rioyrosaeiapyt), or lysozyme T4 (e.g., potato cultivars that, as a result of the production of said protein, is resistant to bacteria such as Egmipia atu/yomoga).

Also covered are plants whose performance has been improved through the use of recombinant techniques, for example by increasing potential yield (eg, biomass, grain yield, starch content, oil content or protein content), resistance to drought, soil salinity or other limiting environmental factors, or resistance to harmful organisms and to fungal, bacterial and viral pathogens.

Also covered are plants whose composition, in particular to improve human or animal nutrition, has been modified by recombinant methods, for example, using oil plants that produce health-promoting long-chain omega-3 fatty acids or monounsaturated omega-9 fatty acids (for example, Mehega oil rape?, Adgo rum company zsiepse5, Canada).

The present invention also relates to seeds (for example, to seeds or other plant propagation materials) containing a composition according to the invention. Plant propagation materials can be treated, as a preventive measure, with a composition according to the invention during or even before sowing, or during or even before planting seedlings.

For seed treatment, as a rule, water-soluble concentrates (I 5), suspensions (E5), dust-like substances (05), water-dispersible powders, and water-soluble powders (UU5,

ZB), emulsions (E5), emulsion concentrates (EC) and gels (CE). The specified compositions can be applied to plant propagation material, in particular to seeds, in an undiluted form or, preferably, in a diluted form. Here, the specified composition can be diluted 2- to 10-fold, so that in the compositions used for pickling seeds, the active substance is present in a concentration from 0.01 to 6095 by weight, preferably from 0.1 to 40 95 by weight.

Application can be made before or during sowing. The treatment of plant propagation material, in particular the treatment of seeds, is a known practice and is carried out by dusting, coating, drizzling, dipping or soaking the plant propagation material, the treatment being preferably carried out by dusting, coating and dusting or by furrow treatment, thus , to, for example, prevent untimely early seed germination. It is preferable to use suspensions for seed treatment. Of course, such compositions contain from 1 to 800 g/l of active substance, from 1 to 200 g/l of surfactants, from 0 to 200 g/l of antifreeze substances, from 0 to 400 g/l of binding substances, from 0 to 200 g/l of dyes and solvent, mostly water. to The advantages of the invention are high stability of the preparative form and mixture for spraying, small drift caused by wind, in the case of application by spraying, good adhesion of the preparative form to the surface of treated plants, increased solubility of pesticides in the preparative form, increased penetration of pesticides into the plant and, as the result is faster and stronger action. An important advantage is the low toxicity of alkoxylates, in particular low toxicity for aquatic organisms. Another advantage is a low harmful effect on cultivated plants, that is, a low phytotoxic effect. An additional advantage is the simple processing of these alkoxides, because, for example, gel formation does not occur after their inclusion in preparative forms. Another advantage is that there is no phase separation and no salt precipitation in high salt compositions such as, for example, more than 400 g/L glyphosate; however, alkylates are fully compatible with surfactants, especially anionic surfactants.

Another important advantage is that the invention provides a stable preparative form of anionic, H-acid pesticides in the presence of cationic surfactants. This was particularly surprising because usually precipitation of salts can occur in formulations that contain anionic and cationic compounds, for example during storage, in a spray mixture or in another diluted form.

The examples that follow illustrate the invention without imposing any limitations.

Examples

Surfactant A: C:io-z-alkylbenzenesulfonate, free acid.

Surfactant B: Complex phosphate ester of C:o-2-alkanol alkyloxylate, while the alkoxylate is composed of ethylene oxide and/or propylene oxide, and has an average number of aluoxide units in the range from 12 to 18.

Surfactant C: Si-v-Alkanol Alkoxylate, where the Alkoxylate is composed of ethylene oxide and propylene oxide, and has an average number of alkoxide units in the range of 17 to 26.

Surfactant 0: iso-C1is-alkanol alkoxylate, while the alkoxylate is composed of ethylene oxide and has an average number of alkoxide units in the range from 4.5 to 8.

Surfactant E: thio-alkanol alkoxylate on the basis of Herbie alcohol, while the alkoxylate is composed of ethylene oxide and has an average number of alkoxide units in the range from 2.5 to 6.

Surfactant E: C1-alkanol alkoxylate, while the alkoxylate is composed of ethylene oxide and has an average number of alkoxide units in the range from 3.5 to 7.

Surfactant C: A mixture of fatty acids containing 50-60 96 dodecanoic acid and 20-30 95

C:i4-alkanoic acid, and additionally Sto-v-alkanoic acid, while the acid number is 250-260.

Surfactant H: Sv-io-alkylpolyglucoside, S.P. 1.7.

Example 1 - Production of amine A alkoxylate

First, 2-propylheptylamine was prepared using 2-propylheptanol and ammonia as starting materials, as described in Example 1 of PCT/EP2011/050369.

Then 1280 g (8.15 mol) of 2-propylheptylamine with 40 g of water was added. Then, after purging with nitrogen (2 bar, 16 h), at a temperature of 100 "C, 717 g (16.3 mol) of ethylene oxide was measured.

After that, at a temperature of 90 "C, the remaining traces of ethylene oxide were removed under reduced pressure. This led to a quantitative yield with an amine number of 229 mg KOH/g. In the next step, 821.5 g (3.35 mol) of the specified previous product was added to 8.0 g of 50% KOH concentration and water was removed at a temperature of 90 "C under reduced pressure. After purging with nitrogen (1.5 bar, 12 h), at a temperature of 120 "C, 1179 g (- 26.8 mol) of ethylene oxide was measured. This led to the quantitative yield of a yellowish liquid amine alkoxylate A, with a low viscosity.

Example 2 - Alkoxylate of amine and - surfactant A

For research in the vegetation house, winter wheat (variety Siri5) and soybean (variety Ohio) were sown or planted in pots in clayey sandy soil to a depth of 1-2 cm. When the plants reached a growth height of 10-25 cm (i.e., approximately 10-21 days after sowing), the plants were sprayed with a mixture for spraying in a spraying booth.

A concentrated formulation containing glyphosate-isopropylammonium in an aqueous solution containing surfactants was established and the amine A oxylate from Example 1 was diluted with deionized water and applied at a water application rate of 375 l/ha (140 g or 280 g glyphosate/ha ). Temperatures during the experiment were between 18-35 "C. During this time, the experimental plants received optimal watering, using nutrients that were added to the water used for irrigation.

Herbicidal activity was assessed by scoring treated plants before (each time) compared to untreated control plants. The rating scale varied from O 9o to 100 95 actions. The action, which is 100 95, means the complete destruction of at least those parts of the plant that are above the ground. In contrast, an activity of 0.95 means that there was no difference between treated and untreated plants.

The results in Tables 1 demonstrate the increased activity of the active substance as a result of the addition of the amine admixture with the surfactant.

Table 1A

Effectiveness after 21 days at 140 g/ha of glyphosate is. Efficiency on y y . Quantity and - Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat ooleeyunyanyuyuenny | MOui" | Kmdni Heterrit

Bezai///////711111111111111111111-11Y111117153111111111111o (Alkoxylatamine A and surfactantA | 2555445 | 86 | 85 a) not according to the invention

Table 18:

Effectiveness after 21 days at 280 g/ha of glyphosate 2. Effectiveness on y y . Quantity and - Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat o

Ig/ha) o/; (yeah

Bezai//////77771111111111111111111-111Ї11171716811111111111lo

AlkoxylatamineA?) 77777711 300 | 77771786 1111111178

Surfactant A 2) 800 Its 90 shShsh | 7

Alkoxylate amine A x surfactant A 255-45 a) not according to the invention

Table 1cS:

Effectiveness after 21 days at 140 g/ha of glyphosate 2. Effectiveness on y y . Quantity and - Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat o

Ig/ha) o/; (yeah

Alkoxylate of amine A x surfactant A z5o-50 | (86 Yud Zh Z"MV | 7 a) not in accordance with the invention

Table 10:

Effectiveness after 21 days at 280 g/ha of glyphosate 2. Effectiveness on y y . Quantity and - Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat o

Ig/ha) o, (be

AlkoxylatamineA) ////77777777111111111400 HER 77771783 17777717117169 2

Alkoxylate amine A x surfactant A 350-50 a) not according to the invention

Example C - Alkoxylate amine t surfactant A t surfactant B

Experiments were carried out as in Example 2, and the results are summarized in Table 2.

Table 2A:

Effectiveness after 21 days at 140 g/ha of glyphosate is. Efficiency on and . . Quantity and : Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/gaY o, Io

Surfactant B 2)

Alkoxylate of amine A « a) is not according to the invention

Table 28B:

Effectiveness after 21 days at 280 g/ha of glyphosate is. Efficiency on and . . Quantity and : Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/gaY o, Io

AlkoxylatamineA?) /////1777777711400777777177771111178311111Ї1111117169 1

Surfactant B 2)

Alkoxylate of amine A nya a) not according to the invention

Example 4 - Alkoxylate amine t surfactant A and surfactant C

Experiments were carried out as in Example 2, and the results are summarized in Table 3.

Table FOR:

Effectiveness after 21 days at 140 g/ha of glyphosate is. Efficiency on and . . Quantity and : Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/gaY o, Io

Surfactant C 2)

Alkoxylate of amine A « a) is not according to the invention

Table ZV:

Effectiveness after 21 days at 280 g/ha of glyphosate is. Efficiency on and . . Quantity and : Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat o

І/гаІ о/; (yeah

AlkoxylatamineA?) | 777777/7400777771777777171178311117111111111169 1

Surfactant C 2) 1100 Ї1777771171768 77 Ї177111139 2

Alkoxylate of amine A « a) is not according to the invention

Example 5 - Alkoxylate amine t surfactant A and surfactant O

Experiments were carried out as in Example 2, and the results are summarized in Table 4.

Table 4A:

Effectiveness after 21 days at 140 g/ha of glyphosate 2. Effectiveness on and . . Number of seeds and efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/ha) about, (for

Surfactant b d) 2800 Y771111180117111111151c1

Alkoxylate of amine A and a) not according to the invention

Table 48:

Effectiveness after 21 days at 280 g/ha of glyphosate 2. Effectiveness on and . . Quantity and : Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/ha) about, (for

AlkoxylatamineAe) | 7777/7300 1777771717861111Ї11111111781

Surfactant b d)

Alkoxylate of amine A and a) not according to the invention

Example 6 - Alkoxylate amine t surfactant A t surfactant E

Experiments were carried out as in Example 2, and the results are summarized in Table 5.

Table 5A:

Effectiveness after 21 days at 140 g/ha of glyphosate is. Efficiency on and . . Quantity and : Efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/gaY o, Io

SurfactantE 2)

Alkoxylate of amine A « a) is not according to the invention

Table 58B:

Effectiveness after 21 days at 280 g/ha of glyphosate 2. Effectiveness on and . . Number of seeds and efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/ha) about, (for

AlkoxylatamineA?) | 7777777/7300 Y7777771717867771117 11111178

SurfactantE 2

Alkoxylate of amine A SHII a) not according to the invention

Example 7 - Alkoxylate amine t surfactant E t surfactant E

Experiments were carried out as in Example 2, and the results are summarized in Table 6.

Table bA:

Effectiveness after 21 days at 140 g/ha of glyphosate 2. Effectiveness on and . . Number of seeds and efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat

Ig/ha) about, (for

SurfactantE 2)

Surfactant E 2)

Alkoxylate of amine A nya a) not according to the invention

Table 68B:

Effectiveness after 21 days at 280 g/ha of glyphosate 2. Effectiveness on and . . Number of seeds and efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat o

Ig/ha| at/; (for

AlkoxylatamineA 77777771 3007 Y77777717117861111117 11111178

SurfactantE 2

SurfactantEE 2) shi t i p: z i PO: t po

Alkoxylate of amine A SHII a) not according to the invention

Example 8 - Alkoxylate amine t surfactant A "t surfactant C

Experiments were carried out as in Example 2, and the results are summarized in Table 7.

Table 7A:

Effectiveness after 21 days at 140 g/ha of glyphosate

Quantity Effectiveness on Effectiveness on soybeans

Alkoxylate amine/surfactant of winter wheat o

Ig/ha| at/; (for

Alkoxylate of amine A SHII a) not according to the invention

Table 7B:

Effectiveness after 21 days at 280 g/ha of glyphosate 2. Effectiveness on and . . Number of seeds and efficiency on soybeans

Alkoxylate amine/surfactant of winter wheat o

Ig/ha| at/; (for

AlkoxylatamineA | 777777/7400 | 77777837 1771717117169 2

Alkoxylate of amine A SHII a) not according to the invention

Example 9 - Stability test

Aqueous solution composed of 480 g/l isopropylamine glyphosate salt, 225 g/l amine oxylate

A and 75 g/l of surfactant H were stored for four weeks either at a temperature of -5 °C or at a temperature of 455 °C. Phase separation did not occur.

By way of comparison, an aqueous solution composed of 480 g/l isopropylamine glyphosate salt and 300 g/l sepatype? T 150 (Stylamine ethoxylate, having 15 EO units, commercially available from the company Ciagiap)) was stored accordingly. Was there a clear phase separation in the lower aqueous phase with glyphosate salt and the upper phase with sepatype? T150.

As a further comparison, an aqueous solution composed of 480 g/l isopropylamine glyphosate salt, 150 g/l Sepatype? T 150 and 150 g/l of surfactant H were kept respectively. Similarly, was there clear phase separation in the aqueous lower phase with glyphosate salt and the upper phase with bepatipe? T150.

Claims (17)

FORMULA OF THE INVENTION 1. A composition containing a pesticide, a surfactant, and an alkylate, where the alkylate is an alkylate of amine (A) Dv--o-y-v 1 M p y Bag o-Y-v y (A), or a quaternized derivative (AOS) dz and | Bi---. tA M n A and Bag o 1 in " (AO) of the amine alkoxylate (A), where B and K2 independently of each other are ethylene, ethylene and propylene, ethylene and butylene, or ethylene, propylene and butylene, BZ is H, -OH, Ci-Cv-alkyl or oxygen anion, VU represents H or C.|-Cv-alkyl, B' represents 2-propylheptyl, n, t and p independently of each other have values from 1 to 30 , A is an agricultural anion, or, if KZ is an oxygen anion, A" is absent, and wherein the surfactant is an anionic surfactant containing an anionic group that is sulfonate, sulfate, phosphate, or carboxylate; and/or a nonionic surfactant, which is a sugar-based surfactant or an alkanol alkoxylate. 2. The composition according to claim 1, where the ratio of the mass of the surfactant to the alkoxylate is in the range from 1:99 to 70:30. 3. The composition according to claim 1 or 2, where the composition contains from 1 to 80 95 by weight of the total amount of surfactant and alkoxylate. 4. The composition according to any one of claims 1-3, where the composition contains at least two different surfactants. 5. The composition according to any one of claims 1-4, where at least one surfactant is selected from among the following surfactants: a) Civv-alkanolalkoxylate, where the alkylate is composed of ethylene oxide and/or propylene oxide, and the alkanolalkoxylate has an average number of alkoxide units in the range from 12 to 35; p) Gerbe alcohol-based sio-alkanol oxylate, where the alkoxylate is composed of ethylene oxide, and the alkanol alkoxylate has an average number of alkoxide units in the range from 2 to 8; c) iso-Cys-alkanolalkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanolalkoxylate has an average number of alkoxide units in the range from 3 to 10; 4) sl-alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has an average number of alkoxide units in the range from 2 to 9; f) St-o-alkylpolyglucoside, from p. p. from 1.4 to 1.9; C) C-14a-alkylbenzenesulfonate; and 9d) complex phosphate ester of Св-л4-alkanolalkoxylates. 6. The composition according to any one of claims 1-4, where at least one surfactant is an S-v-alkylpolyglucoside. 7. The composition according to any of claims 1-4, where the surfactant is a linear or branched, saturated or unsaturated Сl22-alkanol alkoxylate, and the alkoxylate is composed (of ethylene oxide and/or propylene oxide. 8. The composition according to any one of claims 1-7, where the pesticide is a pesticide with at least one H-acid group or an anionic salt of a pesticide with at least one H-acid group. 9. The composition according to any of claims 1-8, where, in the amine alkoxylate (A), the total number of p and t is from 2 to 40, and in its quaternized derivative (AC), the total number of p, and p is from C to 80 10. Composition according to any of claims 1-9, where EZ is H. 11. Composition according to any of claims 1-10, where RU is H. 12. The composition according to any one of claims 1-11, wherein the pesticide contains a pesticide with at least one H-acid group. 13. A concentrate containing a surfactant according to any of claims 1-12 and an amine alkylate (A) or a quaternized derivative (AC) of an amine alkoxylate (A) according to any of claims 1-12. 14. The method of manufacturing the composition according to any of claims 1-12, by bringing the concentrate according to claim 13 and the pesticide into contact; or by contacting a pesticide, a surfactant, and an amine oxylate (A) or a quaternized derivative (AS) of an amine oxylate (AND). 15. Use of a surfactant according to any of claims 1-12 in addition to a mixture containing a pesticide according to any of claims 1-12 and an amine oxylate according to any of claims 1- 12. 16. A method of combating phytopathogenic fungi and/or unwanted vegetation, and/or an unwanted attack by insects or mites, and/or for regulating plant growth, where the compositions according to any of claims 1-12 allow to act on the relevant harmful organisms, their environment the environment or on plants to be protected against the relevant harmful organism, on soil and/or on undesirable plants, and/or cultivated plants, and/or on their environment. 17. Seeds containing the composition according to any one of claims 1-12.