TWM587596U - Light-storage type light-emitting thermoplastic composite laminate - Google Patents
Light-storage type light-emitting thermoplastic composite laminate Download PDFInfo
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Abstract
一種蓄光型發光熱塑性複合層狀物,其係設有至少一層體,該至少一層體設有一本體及一與該本體相結合的補強件,該本體為一高分子基材所製成的條狀體或片狀體,該高分子基材包含有一熱塑性樹脂及一蓄光件,該蓄光件設於該熱塑性樹脂內且包含有複數個分佈於該熱塑性樹脂內部的顆粒,該補強件經過加壓及加熱與該本體相結合而分佈於該熱塑性樹脂內,且與該蓄光件相接觸而形成該蓄光型發光熱塑性複合層狀物,藉以提供一能提高生產效率、重複使用以及改善結構韌性的蓄光型發光熱塑性複合層狀物。A light-storing light-emitting thermoplastic composite layer is provided with at least one layer. The at least one layer is provided with a body and a reinforcing member combined with the body. The body is a strip made of a polymer base material. Body or sheet-like body, the polymer base material includes a thermoplastic resin and a light storage member, the light storage member is provided in the thermoplastic resin and contains a plurality of particles distributed inside the thermoplastic resin, and the reinforcement member is pressurized and The heating is combined with the body to be distributed in the thermoplastic resin, and is in contact with the light storage member to form the light storage type light emitting thermoplastic composite layer, so as to provide a light storage type which can improve production efficiency, reuse and improve structural toughness. Luminous thermoplastic composite layer.
Description
本創作涉及一種蓄光型發光熱塑性複合層狀物,尤指一種能提高生產效率、重複使用以及改善結構韌性的蓄光型發光熱塑性複合層狀物。This creation relates to a light-storing light-emitting thermoplastic composite layer, especially a light-storing light-emitting thermoplastic composite layer which can improve production efficiency, reuse and improve structural toughness.
按,現有蓄光型發光熱固性複合層狀物主要包含有一蓄光熱固性樹脂及一人造纖維,其中該蓄光熱固性樹脂是由一熱固性樹脂及一蓄光材料所組成,該熱固性樹脂經過加熱加壓後,分子鏈間會產生一交聯反應,進而形成網狀結構使高分子固化,現有常見的熱固性樹脂包含環氧樹脂、酚醛樹脂以及聚酯樹脂等,而該蓄光材料能將波長介於200~700奈米(nanometer;nm)之間的激發光源進行吸收及儲存,當該激發光源停止提供光能後,該蓄光材料能將儲存的能量以光的形式逐漸釋放,其釋放光的過程能持續數個小時,進而讓該蓄光材料具有暫時發光的效果,現有常見的蓄光材料包含有硫化物、鋁酸鹽及矽酸鹽等,該人造纖維係用以作為現有蓄光型發光熱固性複合層狀物的補強材料,藉以增加現有蓄光型發光熱固性複合層狀物的結構強度。According to the existing light-storing light-emitting thermosetting composite layer, the light-storing thermosetting resin mainly includes a light-storing thermosetting resin and an artificial fiber, wherein the light-storing thermosetting resin is composed of a thermosetting resin and a light-storing material. After the thermosetting resin is heated and pressurized, the molecular chain There will be a cross-linking reaction between them, and then a network structure will be formed to polymer solidify. The existing common thermosetting resins include epoxy resin, phenolic resin and polyester resin, etc., and this light-storing material can have a wavelength between 200 and 700 nanometers. (nanometer; nm) between the excitation light source for absorption and storage, when the excitation light source stops providing light energy, the light storage material can gradually release the stored energy in the form of light, and the process of releasing light can last for several hours Furthermore, the light-storage material has the effect of temporarily emitting light. The existing common light-storage materials include sulfide, aluminate, silicate, etc. The artificial fiber is used as a reinforcing material for the existing light-storage light-emitting thermosetting composite layer. To increase the structural strength of the existing light-storing light-emitting thermosetting composite layer.
現有蓄光型發光熱固性複合層狀物於製造時,係先將一熱固性樹脂、一蓄光材料、一助劑、一固化劑及一促進劑均勻混合形成一膠體,將該膠體均勻塗抹於一人造纖維上,同時配合溫度及壓力,使該膠體能滲入該人造纖維的空隙中,並經過冷卻、切邊、包覆離型紙以及收卷等加工流程後,形成一預浸材(半成品),最後依據產品形狀需求、高分子種類以及纖維種類等,對於該預浸材進行熱壓成型加工,其所需的時間介於10~60分鐘、加工溫度介於120~180℃之間。When the existing light-storing light-emitting thermosetting composite layer is manufactured, a thermosetting resin, a light-storing material, an auxiliary agent, a curing agent and an accelerator are evenly mixed to form a colloid, and the colloid is evenly coated on an artificial fiber. At the same time, with temperature and pressure, the colloid can infiltrate into the void of the artificial fiber, and after cooling, trimming, covering release paper, and winding and other processing processes, a prepreg (semi-finished product) is formed, and finally according to the product For shape requirements, polymer types, and fiber types, the hot stamping process for this prepreg requires 10 to 60 minutes and the processing temperature ranges from 120 to 180 ° C.
然而,現有蓄光型發光熱固性複合層狀物,雖然具有蓄光及發光的效果,但在製造過程中為了避免樹脂及預浸材(半成品)等原料,在加工前產生固化的情形,通常將原料以低溫(<-15℃)進行保存,保存的條件相當嚴苛且會增加生產所需之成本;進一步,由於該預浸材具有黏性,而為了避免與週遭物件相沾黏,必須以離型紙進行包裝,相對會增加生產所需之時間及成本,缺乏經濟效益;再進一步,因熱固性的材料特性,使得現有蓄光型發光熱固性複合層狀物在加熱固化後,無法重複加工使用,相對缺乏再利用的價值;另外,經由熱壓加工後的現有蓄光型發光熱固性複合層狀物,其結構韌度值不足(0.1~1 kJ/m 2),有鑒於上述的問題及不足,現有蓄光型發光熱固性複合層狀物誠有其需加以改進之處。 However, although the existing light-storing light-emitting thermosetting composite layer has the effects of light storage and light emission, in order to avoid curing of raw materials such as resins and prepregs (semi-finished products) during the manufacturing process, the raw materials are usually Store at low temperature (<-15 ° C), the storage conditions are quite strict and will increase the cost required for production; further, because the prepreg is sticky, in order to avoid sticking with surrounding objects, a release paper must be used. Packing will relatively increase the time and cost required for production, and lack economic benefits. Furthermore, due to the properties of thermosetting materials, the existing light-storing light-emitting thermosetting composite layers cannot be repeatedly processed and used after being cured by heating. The value of utilization; In addition, the existing light-storing type light-emitting thermosetting composite layer after hot pressing has a structural toughness value of insufficient (0.1-1 kJ / m 2 ). In view of the above problems and shortcomings, the existing light-storing type light-emitting type The thermosetting composite layer has its needs for improvement.
因此,本創作有鑑於現有蓄光型發光熱固性複合層狀物於實際使用時,不易保存、需以離型紙進行包裝、無法重複使用以及結構韌度不足的缺失及問題,特經過不斷的試驗與研究,終於發展出一種能改進現有缺失之本創作,本創作的蓄光型發光熱塑性複合層狀物,主要係以熱塑性樹脂作為材料使用,於生產時原料不需以低溫進行保存,且不需使用離型紙進行包覆,並且加工為成品後可再重複使用,進一步,熱塑性樹脂的韌性高於熱固性樹脂的韌性,藉以提供一能提高生產效率、重複使用以及改善結構韌性的蓄光型發光熱塑性複合層狀物之目的。Therefore, this creation takes into account the lack and problems of the existing light-storing light-emitting thermosetting composite layers in actual use, which are difficult to save, need to be packaged with release paper, cannot be reused, and have insufficient structural toughness. Finally, a kind of light-emitting light-emitting thermoplastic composite layer that can improve the existing missing work has been developed. This work mainly uses thermoplastic resin as the material. During production, the raw materials do not need to be stored at low temperature and do not need to be used. The paper is coated and can be reused after being processed into a finished product. Further, the toughness of the thermoplastic resin is higher than that of the thermosetting resin, so as to provide a light-emitting light-emitting thermoplastic composite layer that can improve production efficiency, reuse and improve structural toughness. The purpose of things.
基於上述目的,本創作係在於提供一蓄光型發光熱塑性複合層狀物,其係設有至少一層體,該至少一層體設有一本體及一與該本體相結合的補強件,該本體為一高分子基材所製成的條狀體或片狀體,該高分子基材包含有一熱塑性樹脂及一蓄光件,該蓄光件設於該熱塑性樹脂內且包含有複數個分佈於該熱塑性樹脂內部的顆粒,該補強件經過加壓及加熱與該本體相結合而分佈於該熱塑性樹脂內,且與該蓄光件相接觸而形成該蓄光型發光熱塑性複合層狀物。Based on the above purpose, the present invention is to provide a light-storing light-emitting thermoplastic composite layer, which is provided with at least one layer, the at least one layer is provided with a body and a reinforcing member combined with the body, and the body is a high A stripe or sheet made of a molecular substrate. The polymer substrate includes a thermoplastic resin and a light-storage member. The light-storage member is disposed in the thermoplastic resin and includes a plurality of distributed in the thermoplastic resin. Granules, the reinforcing member is combined with the body to be distributed in the thermoplastic resin after being pressurized and heated, and is in contact with the light storage member to form the light storage type light emitting thermoplastic composite layer.
進一步,如前所述之蓄光型發光熱塑性複合層狀物,其中該熱塑性樹脂包含有結晶型、半結晶型及非結晶型聚合物。Further, the light-storing light-emitting thermoplastic composite layer as described above, wherein the thermoplastic resin includes crystalline, semi-crystalline, and amorphous polymers.
再進一步,如前所述之蓄光型發光熱塑性複合層狀物,其中該蓄光件包含有硫化物、稀土類鋁酸鹽、稀土類矽酸鹽及稀土類硫氧化物所製成的複數個顆粒。Still further, the light-storage type light-emitting thermoplastic composite layer as described above, wherein the light-storage member includes a plurality of particles made of a sulfide, a rare earth aluminate, a rare earth silicate, and a rare earth sulfur oxide. .
較佳的是,如前所述之蓄光型發光熱塑性複合層狀物,其中該補強件包含有複數個分佈於該熱塑性數之內部的人造纖維,該人造纖維包含有碳纖維、玻璃纖維、礦物纖維及高分子纖維等,其型態可為短纖維、長纖維、連續纖維、編織纖維或粉狀纖維等。Preferably, the light-storing light-emitting thermoplastic composite layer as described above, wherein the reinforcing member includes a plurality of artificial fibers distributed inside the thermoplastic number, and the artificial fibers include carbon fibers, glass fibers, and mineral fibers. And high-molecular fibers, the types of which can be short fibers, long fibers, continuous fibers, woven fibers, or powdery fibers.
較佳的是,如前所述之蓄光型發光熱塑性複合層狀物,其中該蓄光型發光熱塑性複合層狀物設有複數個層體,該些層體呈上、下堆疊設置。Preferably, the light-storage type light-emitting thermoplastic composite layer as described above, wherein the light-storage type light-emitting thermoplastic composite layer is provided with a plurality of layers, and the layers are arranged on top and bottom.
較佳的是,如前所述之蓄光型發光熱塑性複合層狀物,其中蓄光型發光熱塑性複合層狀物設有複數個層體,該些層體呈上、下堆疊,且兩上、下相鄰的層體之間具有一夾角。Preferably, the light-storing type light-emitting thermoplastic composite layer as described above, wherein the light-storing type light-emitting thermoplastic composite layer is provided with a plurality of layers, the layers are stacked on top and bottom, and two tops and bottoms There is an included angle between adjacent layer bodies.
較佳的是,如前所述之蓄光型發光熱塑性複合層狀物,其中各層體具有相同或不同的厚度。Preferably, the light-storing light-emitting thermoplastic composite layer is as described above, wherein each layer has the same or different thickness.
藉由上述的技術手段,本創作蓄光型發光熱塑性複合層狀物係具有至少以下之優點及功效:
一、提高生產效率:本創作的蓄光型發光熱塑性複合層狀物,係以熱塑性樹脂作為高分子基材的原料之一,使得本創作於製造時不需再提供低溫設備,而可以室溫下對於該熱塑性樹脂及預浸材進行保存;進一步,經由該熱塑性樹脂所製成的預浸材的表面乾燥,不會產生沾黏現象,因此於生產過程中不需使用離型紙進行包覆,不僅能縮短生產時間且能減少成本的支出;並且進行熱壓成形所需的時間(小於5分鐘)也相較現有熱固性樹脂(10~60分鐘)來得短,能有效提高生產效率。
二、重複使用:因熱塑性樹脂的材料特性,使得本創作蓄光型發光熱塑性複合層狀物在固化後,能透過再次加熱而能重複加工使用,具有再利用的價值且符合環保趨勢。
三、改善結構韌性:透過該熱塑性樹脂所製成的蓄光型發光熱塑性複合層狀物,其韌度值為1~10 kJ/m
2,高於現有蓄光型發光熱固性複合層狀物的韌度值,因此,本創作能有效地改善該蓄光型發光熱塑性複合層狀物的結構韌性,進而增加其應用範圍及廣度。
With the above-mentioned technical means, the light-storing light-emitting thermoplastic composite layer system of the present invention has at least the following advantages and effects:
I. Improve production efficiency: The light-storing light-emitting thermoplastic composite layer of this creation uses thermoplastic resin as one of the raw materials of the polymer base material, so that this creation does not need to provide low-temperature equipment during manufacture, but can be used at room temperature. The thermoplastic resin and the prepreg are stored; further, the surface of the prepreg made by the thermoplastic resin is dried without sticking, so it is not necessary to use a release paper for coating during the production process, not only It can shorten production time and reduce costs; and the time required for hot pressing (less than 5 minutes) is shorter than the existing thermosetting resin (10 ~ 60 minutes), which can effectively improve production efficiency.
2. Reuse: Due to the material properties of the thermoplastic resin, the light-storing light-emitting thermoplastic composite layer can be reprocessed and reused after curing after curing. It has the value of reuse and conforms to the trend of environmental protection.
3. Improving structural toughness: The light storage type light emitting thermoplastic composite layer made through the thermoplastic resin has a toughness value of 1-10 kJ / m 2 , which is higher than the existing light storage type light emitting thermosetting composite layer. Therefore, the present invention can effectively improve the structural toughness of the light-storing light-emitting thermoplastic composite layer, thereby increasing its application range and breadth.
為能詳細瞭解本創作的技術特徵及實用功效並可依照說明書的內容來實現,玆進一步以如圖式所示的較佳實施例,詳細說明如後:In order to understand the technical features and practical effects of this creation in detail and can be realized in accordance with the contents of the description, the preferred embodiment shown in the figure is further described in detail as follows:
本創作係提供一蓄光型發光熱塑性複合層狀物,請配合參看如圖1至圖3所示,該蓄光型發光熱塑性複合層狀物設有至少一層體10,該至少一層體10設有一本體及一與該本體相結合的補強件40,其中該本體為一高分子基材所製成的條狀體或片狀體,該高分子基材包含有一熱塑性樹脂20及一蓄光件30,該熱塑性樹脂20包含有結晶型、半結晶型及非結晶型聚合物,該蓄光件30係設於該熱塑性樹脂20內且包含有複數個顆粒,該複數個顆粒分佈於該熱塑性樹脂20內部,進一步,該蓄光件30包含有硫化物、稀土類鋁酸鹽、稀土類矽酸鹽及稀土類硫氧化物所製成的複數個顆粒,再進一步,該蓄光件30為稀土類鋁酸鹽所製成的複數個顆粒,該複數個顆粒的平均粒徑介於10~80微米(μm)。This creation provides a light-storing light-emitting thermoplastic composite layer. Please refer to FIG. 1 to FIG. 3. The light-storing light-emitting thermoplastic composite layer is provided with at least one layer 10, and the at least one layer 10 is provided with a body. And a reinforcing member 40 combined with the body, wherein the body is a strip or sheet made of a polymer base material, the polymer base material includes a thermoplastic resin 20 and a light storage member 30, the The thermoplastic resin 20 includes crystalline, semi-crystalline, and non-crystalline polymers. The light storage member 30 is disposed in the thermoplastic resin 20 and includes a plurality of particles. The plurality of particles are distributed inside the thermoplastic resin 20, and further The light storage member 30 includes a plurality of particles made of sulfide, rare earth aluminate, rare earth silicate, and rare earth sulfur oxide. Furthermore, the light storage member 30 is made of rare earth aluminate. The plurality of particles are formed, and the average particle diameter of the plurality of particles is between 10 and 80 micrometers (μm).
較佳的是,該高分子基材另設有一增塑件及一助劑,其中該增塑件作為該熱塑性樹脂20及該蓄光件30的載體,使該熱塑性樹脂20與該蓄光件30的複數個顆粒,能與該補強件40相結合,而該助劑為一抗氧化劑(增加高分子基材的抗氧化能力)、一分散劑(使蓄光件30均勻分散在高分子基材中)或一偶合劑,其中該偶合劑能增加高分子基材與補強件40的結合性,如圖4所示將該熱塑性樹脂、蓄光件、增塑件以及助劑均勻混合後,使該本體形成一蓄光熱塑性樹脂,即為製造該蓄光型發光熱塑性複合層狀物的第一個操作步驟:配膠;進一步,該熱塑性樹脂、蓄光件、增塑件以及助劑係分別以50~95%、5~50%、0~60%以及0~10%的重量百分比進行混合。Preferably, the polymer substrate is further provided with a plasticizing member and an auxiliary agent, wherein the plasticizing member serves as a carrier of the thermoplastic resin 20 and the light storage member 30, so that the thermoplastic resin 20 and the light storage member 30 are plural Particles, which can be combined with the reinforcing member 40, and the auxiliary agent is an antioxidant (increasing the anti-oxidation ability of the polymer substrate), a dispersant (the light storage member 30 is uniformly dispersed in the polymer substrate) or A coupling agent, wherein the coupling agent can increase the bonding between the polymer substrate and the reinforcing member 40. As shown in FIG. 4, the thermoplastic resin, the light-storing member, the plasticizing member, and the auxiliary agent are evenly mixed to form the body into a The light-storing thermoplastic resin is the first operation step of manufacturing the light-storing light-emitting thermoplastic composite layer: compounding; further, the thermoplastic resin, the light-storing member, the plasticizing member, and the auxiliary agent are 50-95%, 5 ~ 50%, 0 ~ 60% and 0 ~ 10% by weight.
該補強件40與該本體相結合而分佈於該熱塑性樹脂20內,且與該蓄光件30相接觸,其中該補強件40包含有複數個人造纖維;較佳的是,該人造纖維包含有碳纖維、玻璃纖維、礦物纖維及高分子纖維等,其型態可為短纖維、長纖維、連續纖維、編織纖維或粉狀纖維等,於製造時將該蓄光熱塑性樹脂均勻塗抹於該複數個人造纖維上,並透過一滾輪施加壓力使該蓄光熱塑性樹脂滲入該複數個人造纖維的空隙中,同時加溫使該蓄光熱塑性樹脂融化而與該補強件的複數個人造纖均勻複合,其中熱塑性樹脂經過加熱加壓後,分子鏈間相互滑動,使高分子呈熔融流動態,待冷卻後進行收卷即形成該蓄光型發光熱塑性複合層狀物的一預浸材,前述的操作即為圖4所示製造流程中的第二個步驟:含浸,接著依據產品形狀需求、高分子種類以及纖維種類等,對於該預浸材進行熱壓成型的操作步驟,其所需的時間小於5分鐘、加工溫度介於140~300℃之間,熱壓成形後形成本創作的蓄光型發光熱塑性複合層狀物。The reinforcing member 40 is combined with the body to be distributed in the thermoplastic resin 20 and is in contact with the light storage member 30. The reinforcing member 40 includes a plurality of artificial fibers; preferably, the artificial fiber includes carbon fibers , Glass fiber, mineral fiber, polymer fiber, etc., the type can be short fiber, long fiber, continuous fiber, woven fiber or powdery fiber, etc. When manufacturing, the light-storing thermoplastic resin is evenly applied to the plurality of artificial fibers. And applying pressure through a roller to infiltrate the light-storing thermoplastic resin into the voids of the plurality of artificial fibers, and at the same time heating to melt the light-storing thermoplastic resin and uniformly compound with the plurality of personal fibers of the reinforcement, wherein the thermoplastic resin is heated After being pressurized, the molecular chains slide against each other, so that the polymer exhibits a melt flow dynamics. After cooling, it is rolled up to form a prepreg material of the light-storing light-emitting thermoplastic composite layer. The foregoing operation is shown in FIG. 4 The second step in the manufacturing process: impregnation, and then according to the product shape requirements, polymer types and fiber types, etc. Procedure hot press forming, which is the time required is less than 5 minutes, the processing temperature is between 140 ~ 300 ℃, formed thermoplastic composite layer type light emitting light storing substance after hot press forming according to the present writing.
進一步,如圖1及2所示該蓄光型發光熱塑性複合層狀物設有三個層體10,該些層體10呈上、下堆疊設置,再進一步,請配合參看如圖3所示,該蓄光型發光熱塑性複合層狀物設有複數個層體10,該些層體10呈上、下堆疊,且兩上、下相鄰的層體10之間具有一夾角;較佳的是,該些層體10的厚度可為相同或者不同。Further, as shown in FIGS. 1 and 2, the light-storing light-emitting thermoplastic composite layer is provided with three layers 10, and the layers 10 are stacked on top and bottom. Further, please refer to FIG. 3 for cooperation. The light-storing type light-emitting thermoplastic composite layer is provided with a plurality of layers 10, the layers 10 are stacked on top of each other, and an angle is included between two upper and lower adjacent layers 10; preferably, the The thicknesses of the layers 10 may be the same or different.
藉由上述的技術特徵,本創作的蓄光型發光熱塑性複合層狀物,係以熱塑性樹脂20作為高分子基材的原料之一,使得本創作於製造時不需再提供低溫設備,而可以室溫下對於該熱塑性樹脂20及預浸材進行保存;進一步,經由該熱塑性樹脂20所製成的預浸材的表面乾燥,不會產生沾黏現象,因此於生產過程中不需使用離型紙進行包覆,不僅能縮短生產時間且能減少成本的支出;進一步,因熱塑性樹脂20的材料特性,使得本創作蓄光型發光熱塑性複合層狀物在固化後,能透過再次加熱而能重複加工使用,具有再利用的價值且符合環保趨勢,並且進行熱壓成形所需的時間(小於5分鐘)也相較現有熱固性樹脂(10~60分鐘)來得短,能有效提高生產效率;另外,透過該熱塑性樹脂所製成的蓄光型發光熱塑性複合層狀物,其韌度值為1~10 J/m 2,高於現有蓄光型發光熱固性複合層狀物的韌度值,其拉伸強度大於300MPa,拉伸模數大於17GPa,且持續發光時間大於12小時,因此,本創作能有效地改善該蓄光型發光熱塑性複合層狀物的結構韌性,進而增加其應用範圍及廣度,藉以提供一能提高生產效率、重複使用以及改善結構韌性的蓄光型發光熱塑性複合層狀物。 Based on the above technical features, the light-storing light-emitting thermoplastic composite layer of this creation uses thermoplastic resin 20 as one of the raw materials of the polymer base material, so that this creation does not need to provide low-temperature equipment and can The thermoplastic resin 20 and the prepreg are stored at a temperature; further, the surface of the prepreg made through the thermoplastic resin 20 is dried without sticking, so no release paper is needed in the production process. Coating can not only shorten production time and reduce costs; further, due to the material properties of the thermoplastic resin 20, the light-storing light-emitting thermoplastic composite layer of this invention can be repeatedly processed and used again after curing, after curing, It has the value of recycling and conforms to the environmental protection trend, and the time required for hot pressing (less than 5 minutes) is shorter than the existing thermosetting resin (10 ~ 60 minutes), which can effectively improve the production efficiency. In addition, through the thermoplastic Photoluminescent emission thermoplastic resin composite layer was formed, the toughness is 1 ~ 10 J / m 2, higher than the conventional light emitting thermosetting STORING The toughness value of the composite layer has a tensile strength of more than 300 MPa, a tensile modulus of more than 17 GPa, and a continuous light emission time of more than 12 hours. Therefore, the present invention can effectively improve the structure of the light-storing light-emitting thermoplastic composite layer. Toughness, and further increase its application range and breadth, so as to provide a light-emitting light-emitting thermoplastic composite layer that can improve production efficiency, reuse and improve structural toughness.
以上所述,僅是本創作的較佳實施例,並非對本創作做任何形式上的限制,任何所屬技術領域中具有通常知識者,若在不脫離本創作所提技術方案的範圍內,利用本創作所揭示技術內容所作出局部更動或修飾的等效實施例,並且未脫離本創作的技術方案內容,均仍屬於本創作技術方案的範圍內。The above is only a preferred embodiment of the creation, and does not limit the creation in any form. Any person with ordinary knowledge in the technical field to which this invention belongs will use the present invention without departing from the scope of the technical solution proposed in the creation. Equivalent embodiments of partial changes or modifications made to the technical content disclosed in the creation without departing from the technical solution content of the creation are still within the scope of the technical solution of the creation.
10‧‧‧層體10‧‧‧layer
20‧‧‧熱塑性樹脂 20‧‧‧ thermoplastic resin
30‧‧‧蓄光件 30‧‧‧Light storage
40‧‧‧補強件 40‧‧‧ Reinforcement
圖1是本創作蓄光型發光熱塑性複合層狀物的剖面側視示意圖。
圖2是本創作蓄光型發光熱塑性複合層狀物的局部放大剖面側視示意圖。
圖3是本創作蓄光型發光熱塑性複合層狀物的俯視示意圖。
圖4是本創作蓄光型發光熱塑性複合層狀物的製造流程方塊圖。
FIG. 1 is a schematic cross-sectional side view of the light-storing light-emitting thermoplastic composite layer of the present invention.
FIG. 2 is a schematic partial cross-sectional side view of the light-emitting thermoplastic composite layer of the present invention.
FIG. 3 is a schematic top view of the light-storing light-emitting thermoplastic composite layer of the present invention.
FIG. 4 is a block diagram of a manufacturing process of the light-storing light-emitting thermoplastic composite layer of the present invention.
Claims (12)
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