TWM580039U - Composite structure of lamination - Google Patents

Abstract

The present invention relates to a laminated structure comprising: a silicone member; an elastic tensile layer followed by the silicone member; a soft layer which is a light transmissive layer and then on the elastic tensile layer, and As the outermost layer; and a decorative layer between the soft layer and the silicone article.

Description

Composite layered structure

The present invention relates to a laminated structure, in particular to a laminated structure in which a layer of soft tactile and textured layers, a decorative layer, and a layer of anti-stretch elastic layer are applied to a piece of silicone material.

With the vigorous development of mobile devices, wearable devices, 3C products, etc., and with the high pursuit of consumers' beauty and texture, the products must be powerful and complete, and the appearance and structure must be beautiful and unique. The conditions make surface decoration technology an important process technology, not only because it can change the appearance of the product, but also under the advancement of related technology, the outer structure formed on the surface of the product through surface decoration technology can also be a product. Bring more special features and added value.

Among the conventional techniques, the material most commonly used as the outer layer structure or the outer decorative layer of the product is two kinds of silicone rubber and thermoplastic polyurethane (TPU). The rubber is often referred to as tannin, which has micro-adsorption. Stable, thermal stability, chemical stability, high mechanical strength, insoluble in water and any solvent, high elasticity, good softness, ductility, light transmission, not easy to produce yellowing, etc., making it very suitable for production The outer layer structure, TPU is very wear-resistant and scratch-resistant, has tensile strength, transparency, light weight, and the surface has a slight viscosity, easy to adhere to the surface to be protected and its peripheral surface, so Widely used as a protective film for the outer layer of the product.

However, whether silicone or TPU still has its own shortcomings, for example, the problem of silicone rubber is that its mechanical properties such as tensile strength and tear strength are poor, and it is prone to heat deformation and tearing, which affects the service life, and it is not easy to use rubber. Coloring, easy to cause the appearance of the product is monotonous and boring, and the biggest problem of TPU is that its touch is not soft enough, and the material of TPU is quite easy to produce yellowing (yellowing) and other shortcomings.

Taking the strap as an example, the new strap on the market almost focuses on the performance of elasticity, toughness and comfort. Therefore, the material is mainly TPU and silicone, but whether it is TPU or silicone, It has its shortcomings and cannot fully meet the needs of consumers. For example, the commonly used TPU is easy to yellow, hydrolyze and break, and the surface feels too plastic, not fine enough. Silicone has poor mechanical properties such as tensile strength and tear strength. And it is not easy to be colored, and the surface of the silicone which is not treated with antifouling is easy to adsorb dust and the like.

Therefore, the creator of this case used a one-time integrated molding process to combine silicone and TPU into a composite film, and disclosed it in Taiwan's new patent No. M505400 "composite film", although such a composite film absorbs two materials. Advantages, and eliminate the disadvantages when used alone, but the composite film still has improvements, and is not limited to use as a film.

For the sake of his position, in view of the shortcomings of the conventional technology, the applicant has carefully tested and researched, and has a perseverance spirit to finally conceive the "composite laminated structure" of the case, which can overcome the shortcomings of the above-mentioned conventional technologies. The following is a brief description of the creation.

The composite laminated structure proposed by the present invention combines two materials with a soft and wear-resistant soft material and an elastic material with strong toughness but elasticity. The composite laminated structure provides a soft touch to the overall structure, and also provides strong tensile, tensile and tear resistance properties. The two layers can be easily added to the decorative layer. In addition to enhancing the structural characteristics of the structure, it also gives the structure a beautifully designed appearance.

A soft material arranged on the outermost layer, which has the characteristics of easy processing, can easily form a three-dimensional texture on the surface, creates a slight tactile change for the entire structure, and forms a texture, and is also allowed to be near the surface. The material is added with wear resistance, anti-slip, dustproof, sterilization and other functions to enhance the overall practicability and usability of the structure. The composite laminated structure of the present invention is not only low in manufacturing cost, but also easy to manufacture and has high production yield. .

Accordingly, the present invention proposes a laminated structure comprising a silicone member; an elastic tensile layer which is subsequently applied to the silicone member; a soft layer which is a light transmissive layer and which is then applied to the elastic tensile layer and serves as the most An outer layer; and a decorative layer interposed between the soft layer and the silicone article.

Preferably, the laminated structure further includes a bottom layer interposed between the elastic tensile layer and the silicone member, and the underlayer comprises a material respectively corresponding to the elastic tensile layer and the The two functional groups of the material of the silicone material are used to promote the adhesion between the elastic tensile layer and the silicone member. When the silicone member is cured, the underlayer is converted into the silicone member and becomes a part of the silicone member.

Preferably, the material of the soft layer is selected from the group consisting of polyurethane, ruthenium-based rubber, polycarbonate, and a combination thereof, and the material of the elastic tensile layer is selected from the group consisting of thermoplastic polyurethane, thermoplastic polyolefin, polyolefin, and poly One of ethylene, and a combination thereof, the material of the silicone material is selected from the group consisting of sulfhydryl rubber, liquid silicone rubber, silicone resin, silicone rubber, silicone rubber, silicone resin, cerium oxide, fluorenone, and a combination thereof. .

Preferably, the soft layer comprises an outer surface comprising a plurality of three-dimensional microstructures. It can create a touch, texture, or light effect for the outer surface.

Preferably, the three-dimensional microstructures are selected from the group consisting of a convex structure, a concave structure, a three-dimensional pattern, a three-dimensional pattern, a texture structure, a three-dimensional pattern, and a combination thereof.

Preferably, the outer surface of the soft layer further provides hydrophobic function, hydrophilic function, anti-scratch function, wear resistance function, anti-skid function, dustproof function, antibacterial function, or sterilization function.

Preferably, the decorative layer is a first decorative layer and is interposed between the soft layer or the elastic layer, and the decorative layer is a second decorative layer interposed between the elastic layer or the silicone member.

Preferably, the decorative layer comprises a visual effect and a visual feature to be presented in the appearance of the laminated structure.

Preferably, the decorative layer and the soft layer together comprise the visual effect and the visual feature of the laminated structure to be presented in appearance.

Preferably, the soft layer, the decorative layer, the elastic tensile layer, and the underlayer are additionally attached to the silicone member as an outer layer structure.

Preferably, the silicone material is a silicone rubber strap, a silicone wristband, a silicone rubber strap, a silicone rubber protective shell, or an electronic device peripheral accessory.

Preferably, the laminated structure system is applied as a silicone rubber band, a silicone wristband, a silicone rubber band, a silicone rubber protective case, or an electronic device peripheral accessory.

Preferably, the soft layer, the decorative layer, the elastic tensile layer, the underlying layer, and the silicone article are combined by a hot press forming technique, an in-mold forming technique, or an injection molding technique.

10‧‧‧Composite laminated structure

100‧‧‧矽 glue pieces

200‧‧‧ outer structural assembly

210‧‧‧Soft layer

211‧‧‧ outer surface

212‧‧‧ inner surface

220‧‧‧elastic layer

221‧‧‧ first surface

222‧‧‧ second surface

231‧‧‧First decorative layer

232‧‧‧Second decorative layer

300‧‧‧ bottom layer

400‧‧‧Shaping components

500‧‧‧ Strap

510‧‧‧Band body

520‧‧‧Surface outer structural layer

D1‧‧‧ first direction

D2‧‧‧ second direction

1 is a schematic view showing the structure of the composite laminated structure of the present invention; FIG. 2 is a schematic view showing the structure of the outer layer structure of the present invention; and FIG. 3 is a first embodiment of the composite laminated structure of the present invention. A schematic diagram of a partial structure of an example.

The present invention will be fully understood by the following examples, so that those skilled in the art can do so, but the implementation of the present invention may not be restricted by the following implementation cases; the pattern of the creation is The size, size and scale of the creation are not included, and the size, size, shape and scale of the present practice are not limited by the schema of the creation.

The term "preferred" as used herein is non-exclusive and should be understood as "preferably, but not limited to", and any steps described or recited in any specification or claim can be performed in any order, and are not limited to the claim The order of the present invention should be determined only by the accompanying claims and its equal schemes, and should not be determined by the examples of the embodiments; the term "comprising" and its variations appear in the specification and claims. An open-ended term that does not have a limiting meaning and does not exclude other features or steps.

Fig. 1 is a schematic view showing the structure of the composite laminated structure of the present invention; Fig. 2 is a schematic view showing the structure of the outer structural assembly of the present invention; the composite laminated structure 10 of the present invention comprises a silicone rubber article. 100, an outer structure assembly 200, and a primer layer 300 and the like, the outer layer structure 200 includes a soft layer 210, an elastic layer (bomb a tensile layer 220, a selective first decorative layer (decorative layer) 231, and an optional second decorative layer (decorative layer) 232, etc., the elastic layer 220 comprising a first surface 221 facing the first direction D1 And a second surface 222 facing the second direction D2, the first direction D1 means a direction substantially facing the outside, the outside, or the upper direction, and the second direction D2 means a direction substantially facing the inside, the inside, or the lower side, the soft layer 210 In the composition of the composite laminated structure 10, a layer arranged on the outermost side or the outermost layer, and including an outer surface 211 facing the first direction D1 and an inner surface 212 facing the second direction D2, the silicone article 100 A layer of underlying layer 300 is included between the outer structure assembly 200.

The soft layer 210 is preferably a light transmissive layer made of, for example, polyurethane (PU, Polyurethane), polycarbonate (PC, Polycarbonate), or silicone. The soft layer 210 is characterized in that the structure itself has a relatively high hardness. However, it still retains certain elastic, abrasion resistance, and tensile properties, since the outer surface 211 of the soft layer 210 is ultimately the outermost surface of the composite laminated structure 10, so when the soft layer 210 is When the outer surface 211 has a second surface direction D2, it can provide a soft and elastic touch, while still providing an outer surface 211 which retains a certain strength and wear resistance.

Further, in the forming or film forming process of the soft layer 210, it is preferable to use the forming member 400, for example, a release film with a three-dimensional pattern or a mold with a three-dimensional pattern, A multi-dimensional microstructure such as a three-dimensional pattern, a three-dimensional pattern, a convex structure, a concave structure, a special texture, or a three-dimensional pattern is formed on the surface 211, and the outer surface 211 of the soft layer 210 is provided with a feeling of touch, texture, or light and shadow. Preferably, the outer surface 211 can be further subjected to a series of functional surface treatments by spraying, printing or the like, so that the outer surface 211 can simultaneously have, for example, hydrophobic, hydrophilic, scratch resistant, abrasion resistant, non-slip, dustproof, and antibacterial. , sterilizing and the like, so when the soft layer 210 is the outermost layer of the composite laminated structure 10, and When the surface 211 is the outermost surface, the multi-functional effect of the visual decorative effect, the elastic touch, the abrasion resistance, the special material feeling, and the functional surface can be brought to the entirety of the composite laminated structure 10, in an embodiment. The inner surface 212 of the soft layer 210 may also provide a first decorative layer 231 formed thereon.

The elastic layer 220 is preferably made of, for example, thermoplastic polyurethane (TPU, Thermoplastic Polyurethane), polyolefin (PO, Polyolefins), thermoplastic polyolefin (TPO, Thermoplastic Polyolefins), or polyethylene (PE, Poly). Is a high molecular polymer layer having a thickness of between 0.01 mm and 0.1 mm and having properties of softness, toughness, tensile strength, tear resistance, thermoplasticity, etc., which can be made into a light transmitting layer, or The opaque layer is characterized in that the elastic layer 220 is characterized in that it can provide tensile and tear resistance in the long axis direction (longitudinal direction) as a whole of the composite laminated structure 10, and is a composite laminated structure 10 The overall mechanical strength and structural toughness are improved, and the first surface 221 and the second surface 222 are provided for the first decorative layer 231 or the second decorative layer 232 to be formed thereon, respectively.

The first decorative layer 231 or the second decorative layer 232 is an optional layer, that is, the outer structure assembly 200 may include the first decorative layer 231 and the second decorative layer 232, but may also include only one of the layers, the first decoration Layer 231, if any, may optionally be formed and attached to inner surface 212 of soft layer 210, or first surface 221 of elastic layer 220, and second decorative layer 232, if any, may be formed and attached to second surface 222 of elastic layer 220. Preferably, the first decorative layer 231 or the second decorative layer 232 is formed by, for example, digital printing, ink jet printing, digital printing, screen printing, letterpress printing, gravure printing, or spraying. And attached to the selected surface.

The first decorative layer 231 or the second decorative layer 232 includes an appearance, an artwork, or a visual design that the designer desires the composite laminated structure 10 to exhibit in the first direction D1, and the first decorative layer 231, Or the second decorative layer 232 includes: an ink material, or Metal texture material to visually present 2D flat decoration, 3D stereo decoration, or material simulation effects, such as: text, trademark, stamp, symbol, pattern, texture, pattern, color block, gradient color, leather pattern a visual design effect of a printed pattern, a broken pattern, a three-dimensional pattern, a three-dimensional pattern, a metallic color, a metallic texture, a special material, or a special texture, the first decorative layer 231 or the second decorative layer 232 is matched with the outer surface 211, Together, the composite laminated structure 10 exhibits the appearance decorative effect expected by the designer, and provides a soft and elastic, touch with a special material feel, and at the same time has anti-wear and multi-functionality.

The composition of the underlying layer 300 preferably comprises: a material similar to the material of the material of the elastic layer 220, and a material similar to the material of the material of the silicone material 100, and further comprises a polycarbonate (PC) material, a thermoplastic polymer material, a hot melt adhesive material, a catalyst curing material, a heat curing material, or a UV light curing material, etc., if the elastic layer 220 is regarded as an adhesive for the soft layer 210 and the silicone material 100, The two functional groups provided in the underlying layer 300 can create cross-linking between the elastic layer 220 and the silicone article 100, promote the adhesion between the elastic layer 220 and the silicone article 100, or can be regarded as elastic. The layer 220 produces a cohesive effect. Through the use of the elastic layer 220 and the underlying layer 300, the soft layer 210 and the silicone material 100 can be tightly combined, and the elastic layer 220 also provides structural toughness to the composite laminated structure 10. .

In one embodiment, the first decorative layer 231 or the second decorative layer 232 is preferably formed and attached to the first surface 221 of the elastic layer 220 or the elastic layer by, for example, printing, printing, or spraying. On the second surface 222 of the 220, in a certain embodiment, the soft layer 210, the elastic layer 220, and the first decorative layer 231 or the second decorative layer 232 may be directly printed, printed, sprayed, etc. To stack and bond, or through molding The manner of forming is directly integrated, and then the underlying layer 300 is coated on the elastic layer 220.

In an embodiment, in order to include the outer layer structure 200 including the soft layer 210, the elastic layer 220, and the first decorative layer 231 or the second decorative layer 232 on the elastic layer 220, the adhesive member is firmly attached to the silicone member. 100, which becomes the outer layer structure of the silicone article 100, and achieves the effect of decorating or protecting the silicone article 100. The outer layer structure 200 and the silicone article 100 further comprise a primer layer 300 as an adhesion promoter, and the primer layer 300 is provided. In the present embodiment, the second surface 222 of the elastic layer 220 or the second decorative layer 231 (if any) is formed by coating.

In an embodiment, after the soft layer 210, the elastic layer 220, the underlying layer 300, and the silicone article 100 are sequentially arranged, they are preferably joined together by using, for example, thermal forming. The composite laminated structure 10, the relatively high temperature and high pressure environment in the process, enables the underlying layer 300 to exert an adhesion promoting effect on the elastic layer 220, so that the soft layer 210 is tightly bonded to the silicone member 100, and the process is higher than after the process is completed. 99% of the bottom layer 300 component is converted into a silicone component into a part of the silicone article 100. If the base layer 300 content is detected after the curing or curing of the silicone article 100, the underlying layer 300 component is inspected in the silicone article 100. The content is less than 1%, or in most cases the composition of the underlying layer 300 is detected near zero in the silicone article 100.

In one embodiment, the first decorative layer 231 or the second decorative layer 232 is preferably formed and attached to the inner surface 212 of the soft layer 210 or the elastic layer, for example, by printing, printing, or spraying. On the second surface 222 of the 220, after the soft layer 210, the elastic layer 220, and the underlying layer 300 are sequentially arranged, it is preferable to inject the silicone into the mold by using, for example, injection molding or molding. In the high temperature and high pressure environment, the composite layer structure 10 is formed together with the soft layer 210, the elastic layer 220, and the underlying layer 300. If the process is completed, the tantalum article 100 in the composite layered structure 10 is bottomed. Layer 300 content detection, underlying layer 300 composition The content detected in the silicone article 100 is less than 1%, or in most cases the composition of the primer layer 300 is detected near zero in the silicone article 100.

FIG. 3 is a partial structural view showing the first embodiment of the present composite laminated structure; in the present embodiment, the composite laminated structure 10 of the present invention is finally formed into, for example, a watchband 500, a third The figure discloses a partial structure of the watch band 500, which comprises a silicone article 100 as the watch body 510, and an outer structure assembly 200 as a watchband outer decorative layer 520, which comprises a soft layer 210, an elastic layer 220, And the first decorative layer 231 is included between the soft layer 210 and the elastic layer 220. The watchband 500 of the embodiment does not include the second decorative layer 232, and the bottom layer 300 is finally converted into the rubber-changing material 100 after the manufacturing is completed. In part, the watchband 500 of the present embodiment therefore does not include the underlying layer 300.

The watch band 500 has the soft layer 210 and its outer surface 211 as the outermost layer and the outer surface, so that the watch band 500 has a soft and elastic surface touch as a whole, and has a visually distinctive texture, and has both antibacterial and hydrophobic properties. The composite function 231 provides visual design decoration for the appearance of the watch band 500, and even simulates the texture of the special material, for example, the metal texture, and the elastic layer 220 is a composite layer. The structural body 10, as well as the outer structural assembly 200, provides structural strength such that the outer structural assembly 200 forms a visual decorative pattern that resists stretching during use and is less prone to breakage, and the underlying layer 300 provides the outer structural assembly 200. The various layers included form a strong bond with the silicone article 100 of the watch body 510, and are not easily detached from the silicone article 100 of the watch body 510 even under various extreme conditions of use.

In summary, the composite layered structure of this creation has the following advantages:

(1) Because it is a composite structure, it is stronger and more comfortable than the structure of pure TPU or pure silicone. It can also have the toughness of TPU at the same time. The comfort and softness of the glue.

(2) The soft material is used on the contact surface, for example, PU material, so the touch is very good. Unlike the pure TPU, the touch is harder and more plastic.

(3) The decorative layer in the laminated structure is covered and protected by the soft layer or the elastic layer, so that the wear resistance and protection of the decorative layer can be effectively increased, and since the decorative layer can be formed independently, it is easier to The decorative layer is made of complex, exquisite and colorful patterns, giving the composite laminated structure a more design look.

(4) When applying a soft layer, it is possible to transfer the texture of the upper release protective film or the texture on the mold to cause a change in the tactile sensation on the outer surface of the soft layer, to form a texture, and to improve the composite lamination. The overall feel and appearance of the structure.

(5) The composite laminated structure of the present invention is not only low in manufacturing cost, but also easy to manufacture and has high production yield.

(6) The outer surface of the soft layer can be easily passed through the surface treatment to increase the wear resistance, anti-slip, dustproof and sterilization functions, and increase the overall practicability and usability of the composite laminated structure.

Further provide more of this creative implementation such as:

Embodiment 1: A laminated structure comprising a silicone member; an elastic tensile layer attached to the silicone member; a soft layer which is a light transmissive layer and then on the elastic tensile layer and serves as an outermost layer And a decorative layer between the soft layer and the silicone article.

Embodiment 2: The laminated structure according to Embodiment 1, further comprising a primer layer interposed between the elastic tensile layer and the silicone member.

Embodiment 3: The laminated structure according to Embodiment 2, wherein the underlayer comprises two functional groups respectively approximating the material of the elastic tensile layer and the material of the silicone material to promote Adjacent to the elastic tensile layer and the silicone article, the underlayer is converted into the silicone article and becomes part of the silicone article when the silicone article is cured.

Embodiment 4: The laminated structure according to Embodiment 1, wherein the soft layer is made of a material selected from the group consisting of polyurethane, sulfhydryl rubber, polycarbonate, and a combination thereof.

Embodiment 5: The laminated structure according to Embodiment 1, wherein the material of the elastic tensile layer is selected from the group consisting of thermoplastic polyurethane, thermoplastic polyolefin, polyolefin, polyethylene, and a combination thereof.

Embodiment 6: The laminated structure according to Embodiment 1, wherein the material of the silicone material is selected from the group consisting of ruthenium-based rubber, liquid silicone rubber, silicone resin, silicone rubber, silicone rubber, silicone resin, cerium oxide, anthrone And one of its combinations.

Embodiment 7: The laminated structure according to Embodiment 1, wherein the soft layer comprises an outer surface comprising a plurality of three-dimensional microstructures, which can create a tactile, texture, or light-shadowing effect on the outer surface.

Embodiment 8: The laminated structure according to Embodiment 7, wherein the three-dimensional microstructure is selected from the group consisting of a convex structure, a concave structure, a three-dimensional pattern, a three-dimensional pattern, a texture structure, a three-dimensional pattern, and a combination thereof.

Embodiment 9: The laminated structure according to Embodiment 1, wherein the soft layer comprises an outer surface further providing hydrophobic function, hydrophilic function, anti-scratch function, wear resistance function, anti-skid function, dustproof function, antibacterial function, One of the sterilization functions, and a combination thereof.

Embodiment 10: The laminated structure according to Embodiment 1, wherein the decorative layer is a first decorative layer and is interposed between the soft layer or the elastic layer.

Embodiment 11: The laminated structure according to Embodiment 1, wherein the decorative layer is a second decorative layer interposed between the elastic layer or the silicone article.

Embodiment 12: The laminated structure according to Embodiment 1, wherein the decorative layer comprises a visual effect and a visual feature to be presented in appearance of the laminated structure.

Embodiment 13: The laminated structure according to Embodiment 12, wherein the decorative layer and the soft layer together comprise the visual effect and the visual feature of the laminated structure to be presented in appearance.

Embodiment 14: The laminated structure according to Embodiment 12, wherein the visual effect comprises one of a 2D planar decorative effect, a 3D three-dimensional decorative effect, a material simulation effect, and a combination thereof, the visual feature comprising a text, a trademark, a standard Chapters, symbols, patterns, lines, patterns, color blocks, gradient colors, texture patterns, leather patterns, printed patterns, broken patterns, three-dimensional patterns, three-dimensional patterns, metallic colors, metallic textures, special materials, special textures, and Combine one of them.

Embodiment 15: The laminated structure according to Embodiment 2, wherein the soft layer, the decorative layer, the elastic tensile layer, and the underlayer are additionally attached to the silicone member as an outer layer structure.

Embodiment 16: The laminated structure according to Embodiment 1, wherein the silicone member is a silicone tape, a silicone wristband, a silicone tape, a silicone protective cover, or an electronic device peripheral accessory.

Embodiment 17: The laminated structure according to Embodiment 1, wherein the laminated structural system is applied as a silicone tape, a silicone wristband, a silicone tape, a silicone protective cover, or an electronic device peripheral accessory.

Embodiment 18: The laminated structure according to Embodiment 2, wherein the soft layer, the decorative layer, the elastic tensile layer, the underlying layer, and the silicone member are passed through a hot press forming technique and an in-mold forming method. Technology, or injection molding technology combined.

The embodiments of the present invention can be arbitrarily combined or replaced with each other, thereby deriving more implementations, but the scope of the protection of the present invention is not limited by the scope of the creative protection. The record is subject to change.

Claims (18)

A laminated structure comprising: a silicone member; an elastic tensile layer followed by the silicone member; a soft layer which is a light transmissive layer and then on the elastic tensile layer and serves as the outermost layer And a decorative layer between the soft layer and the silicone article. The laminated structure according to claim 1, further comprising: a primer layer interposed between the elastic tensile layer and the silicone member. The laminated structure according to claim 2, wherein the underlayer comprises two functional groups respectively approximating the material of the elastic tensile layer and the material of the silicone material to promote the elastic tensile layer and Next to the silicone article, the underlayer is converted to the silicone article and becomes part of the silicone article when the silicone article is cured. The laminated structure according to claim 1, wherein the material of the soft layer is selected from the group consisting of a polyurethane, a fluorene rubber, a polycarbonate, and a combination thereof. The laminated structure according to claim 1, wherein the elastic tensile layer is selected from the group consisting of a thermoplastic polyurethane, a thermoplastic polyolefin, a polyolefin, a polyethylene, and a combination thereof. The laminated structure according to claim 1, wherein the material of the silicone material is selected from the group consisting of a base rubber, a liquid silicone rubber, an epoxy resin, a silicone rubber, a rubber, a silicone resin, and a silicone resin. One of cerium oxide, monoterpene ketone, and a combination thereof. The laminated structure according to claim 1, wherein the outer layer of the soft layer comprises a plurality of three-dimensional microstructures, which can create a tactile, texture, or light-shadow effect on the outer surface. The laminated structure according to claim 7, wherein the three-dimensional microstructure is selected from the group consisting of a convex structure, a concave structure, a three-dimensional pattern, a three-dimensional pattern, a texture structure, a three-dimensional pattern, and Combine one of them. The laminated structure according to claim 1, wherein the outer layer of the soft layer further provides a hydrophobic function, a hydrophilic function, a scratch resistance function, an abrasion resistance function, a non-slip function, and a One of dustproof function, one antibacterial function, one sterilization function, and a combination thereof. The laminated structure according to claim 1, wherein the decorative layer is a first decorative layer and is interposed between the soft layer and one of the elastic layers. The laminated structure according to claim 1, wherein the decorative layer is a second decorative layer interposed between the elastic layer and one of the silicone members. The laminated structure according to claim 1, wherein the decorative layer comprises a visual effect and a visual feature in the appearance of the laminated structure. The laminated structure according to claim 12, wherein the decorative layer and the soft layer together comprise the visual effect and the visual feature of the laminated structure to be presented in appearance. The layered structure according to claim 12, wherein the visual effect comprises a 2D planar decorative effect, a 3D solid decorative effect, a material simulation effect, and a combination thereof, the visual feature comprising a text, a Trademark, a label, a symbol, a pattern, a texture, a pattern, a color block, a gradient color, a texture pattern, a leather pattern, a printed pattern, a broken pattern, a three-dimensional pattern, a three-dimensional pattern One of a metallic color, a metallic texture, a special material, a special texture, and a combination thereof. The laminated structure according to claim 2, wherein the soft layer, the decorative layer, the elastic tensile layer, and the underlayer are additionally attached to the silicone member as an outer layer structure. The laminated structure according to claim 1, wherein the silicone article is a silicone tape, a silicone wristband, a silicone tape, a silicone protective cover, or an electronic device peripheral accessory. The laminated structure according to claim 1, wherein the laminated structural system is applied as a rubberized strap, a silicone wristband, a silicone adhesive tape, a silicone protective cover, or an electronic device peripheral accessory. The laminated structure according to claim 2, wherein the soft layer, the decorative layer, the elastic tensile layer, the underlying layer, and the silicone member are passed through a thermoforming technique, a film Molding technology, or a combination of injection molding technology.