CN106476368A - A kind of restraint zone manufacture method and watchband - Google Patents

A kind of restraint zone manufacture method and watchband Download PDF

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Publication number
CN106476368A
CN106476368A CN201610825146.9A CN201610825146A CN106476368A CN 106476368 A CN106476368 A CN 106476368A CN 201610825146 A CN201610825146 A CN 201610825146A CN 106476368 A CN106476368 A CN 106476368A
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CN
China
Prior art keywords
film layer
restraint zone
manufacture method
zone manufacture
rubber
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201610825146.9A
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Chinese (zh)
Inventor
范开贤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Modern Precision Plastic Mould (shenzhen) Co Ltd
Original Assignee
Modern Precision Plastic Mould (shenzhen) Co Ltd
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Priority to CN201610825146.9A priority Critical patent/CN106476368A/en
Publication of CN106476368A publication Critical patent/CN106476368A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/08Animal fibres, e.g. hair, wool, silk

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  • Laminated Bodies (AREA)
  • Materials For Medical Uses (AREA)

Abstract

The invention discloses a kind of restraint zone manufacture method and watchband, methods described comprises the steps:A film layer is provided, the film layer material is transparent rubber;Ink layer, adhesive phase is set gradually in the film layer and is dry;The film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in described adhesive layer side, form fastening band body in described adhesive layer side after cooling.The present invention is frequently bent during solving restraint zone Long-Time Service, is distorted by the elastomer film layer using specific tensile strength, causes substrate layer with fastening band body local detachment, the problem of local delamination.

Description

A kind of restraint zone manufacture method and watchband
Technical field
The invention belongs to restraint zone field, more particularly to a kind of watchband, bracelet, Worn type locator phone, Worn type are fixed The restraint zone manufacture method of position device and watchband.
Background technology
In recent years, the mobile Wrist belt-type product such as intelligent watch, Intelligent bracelet, Worn type children's telephone was fast-developing, these Modish Worn type product is most of to have watch function, and is fixed in wrist by restraint zone.Synthetic resin is rich because having Rich can be ornamental, has almost become the first-selection of fashion type Worn type product restraint zone (as watchband).
Getting up early naval stores is decorated, and pattern is printed or coats surface by the mode for mainly using spraying or printing, is in Existing various patterns or color.However, this manufacture method is more numerous and diverse first, it is unfavorable for industrial mass production.In addition, this Pattern is located at the most appearance of product, has the defect being easily worn.In order to solve this problem, industry is have developed in a kind of mould The forming technique of decoration, wherein main flow are with protective layer structure, the film with decorative pattern by one, are placed in and are penetrated Go out in the mould of shaping.Thermoplastic resin is projected in the pattern side of form film using the mode of ejection formation, make hot melt tree Fat is combined with each other with the film and is integrated, and pattern is closedly fixed between resin and film, can obtain film protection, prolonged not Easy to wear.Through the effort of technical staff, this technology on the rigid plastics watchband of part, such as intelligent watch, intelligent hand In the watchband of the mobile Wrist belt-type product such as ring, Worn type children's telephone.
Although rigid plastics watchband has itself some unique advantage, but Wrist belt-type product be a kind of directly and human body skin The product of directly contact, consumer define, to material texture development, the rubber watchband being intended to skin-friendly, submissive resilience. Rubber watchband has the excellent body-sensing advantage of sense of touch, but which decorates poor performance, can be carried out using technology such as top layer printing, coatings Appearance is beautified, but its wear-resisting prolonged property is poor;And when adopting decoration technique inside mold beautify product, using PET (poly terephthalic acid second Diol ester, i.e. Polyethylene terephthalate) material, film with decorative pattern because self-strength high, hard Degree is big, by long-term use after easily produce local delamination with material for the watchband main body of rubber, even separate or peel off.
Content of the invention
It is an object of the invention to overcoming above-mentioned of the prior art with because being rubber easily with material after by long-term use The defect that watchband main body produces local delamination, even separates or peel off, there is provided a kind of restraint zone manufacture method, this method system Film in the restraint zone that makes can be firm with fastening band body attachment, still closely connects by long-term use.
The technical scheme is that:There is provided a kind of restraint zone manufacture method, comprise the steps:
A film layer is provided, the film layer is transparent rubber, its tensile strength is horizontal 222kg/cm2~272kg/ cm2, longitudinal direction 284kg/cm2~348kg/cm2
Ink layer, adhesive phase is set gradually in the film layer and is dry;
The film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in described adhesive layer side, after cooling Fastening band body is formed in described adhesive layer side.
Wherein, tensile strength testing standard is ASTM-D412- rubber tensile property assay method.
Further, the tensile strength of film layer is preferably horizontal 235kg/cm2~259kg/cm2, longitudinal direction 300kg/cm2 ~332kg/cm2, pliability, elasticity are more preferable within this range, can bear repeatedly larger distortion and bending, and not tired disconnected Folding.Most preferably horizontal 242kg/cm2~252kg/cm2, longitudinal direction 309kg/cm2~323kg/cm2, within this range, flexible Property, elasticity with sense of touch reach optimum balance, larger distortion and bending can be born repeatedly, optimal feel can be kept again.
Further, the shore hardness of film layer is 90A~98A;Preferably 92A~97A;Most preferably 94A~96A.
Further, described fastening band body material be thermoplastic elastomer (TPE) (thermoplastic elastomer, TPE), also known as artificial rubber or synthetic rubber, such as TPUE rubber (TPU), dynamic perduren (TPV).Its product had both possessed the high resiliency of traditional cross-linking vulcanized rubber, the every excellent properties of ageing-resistant, oil resistivity, while have again The standby feature that common plasticses are easy to process, processing mode is wide.As fastening band body selection, preferred thermoplastic polyurethane elastomer Rubber.
Further, the material of film layer is thermoplastic elastomer (TPE), preferably TPU and PVC blending.TPU and PVC Hydrolysis after blending, with good printing and anti-scratch performance.
Further, the fusing point of film layer is 160 DEG C~280 DEG C;When fusing point is 180 DEG C~210 DEG C, film layer during injection More preferable with restraint zone ontology fusion effect.
Further, the thickness of film layer is 0.1mm~0.7mm.When the thickness of film layer is 0.14mm~0.45mm, The degrees of fusion in injection is higher with fastening band body for substrate layer, and the later stage is using less local detachment, local delamination, it is most important that During Long-Time Service, substrate layer is not allowed to be easily cracked.
When the fusion face of restraint zone and film layer is curved surface, film layer is being placed before a mold, is also being included film Layer is hot-forming, the step of cut into predetermined shape.
Present invention also offers a kind of watchband, which is fabricated by using restraint zone manufacture method described above.
The present invention solves restraint zone Long-Time Service process intermediate frequency by the elastomer film layer using specific tensile strength Numerous be bent, distort, cause substrate layer with fastening band body local detachment, the problem of local delamination.
The method that the present invention is provided is applied to watchband, bracelet, the manufacture of Intelligent bracelet.Alleged restraint zone refers to wrist-watch, hand The fastener of ring, Intelligent bracelet and wrist strap phone etc..
Description of the drawings
For the technical scheme being illustrated more clearly that in the embodiment of the present invention, below by to be used needed for embodiment Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for ability For the those of ordinary skill of domain, on the premise of not paying creative work, can also be obtained according to these accompanying drawings other attached Figure.
Fig. 1 is the perspective view of watchband provided in an embodiment of the present invention;
Fig. 2 is the sectional view of tight watchband provided in an embodiment of the present invention.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with drawings and Examples, right The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only in order to explain the present invention, and It is not used in the restriction present invention.
Embodiments provide a kind of restraint zone manufacture method, the restraint zone refer to wrist-watch, bracelet, Intelligent bracelet with And the fastener of wrist strap phone etc..The restraint zone manufacture method of the present invention is described with specific embodiment below.
Embodiment 1
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber P.The film layer by TPU with PVC blending is formed, and its shore hardness is 90A, and its tensile strength is horizontal 222kg/cm2, longitudinal direction 284kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 160 DEG C, and the thickness of film layer is 0.1mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 25%, simulation fatigue test averagely stand 20000 bendings, distortion start local delamination occur.
Embodiment 2
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber.The film layer by TPU with PVC blending is formed, and its shore hardness is 98A, and its tensile strength is horizontal 272kg/cm2, longitudinal direction 348kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 280 DEG C, and the thickness of film layer is 0.7mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 28%, simulation fatigue test averagely stand 2.3 ten thousand bendings, distortion start local delamination occur.
Embodiment 3
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPV, i.e. dynamic perduren.The film layer is by TPU and PVC blending Become, its shore hardness is 95A, its tensile strength is horizontal 247kg/cm2, longitudinal direction 316kg/cm2, the tensile strength testing standard Determine for ASTM-D412- rubber tensile property;In addition, being added with yellowing-resistant interpolation in TUP in the manufacture process of film layer Agent.
The fusing point of the film layer is 200 DEG C, and the thickness of film layer is 0.28mm~0.32mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 45%, simulation fatigue test averagely stand 4.28 ten thousand bendings, distortion start local delamination occur.
Embodiment 4
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber.The film layer by TPU with PVC blending is formed, and its shore hardness is 92A, and its tensile strength is horizontal 235kg/cm2, longitudinal direction 300kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 180 DEG C, and the thickness of film layer is 0.14mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 50%, simulation fatigue test averagely stand 5.3 ten thousand bendings, distortion start local delamination occur.
Embodiment 5
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber.The film layer by TPU with PVC blending is formed, and its shore hardness is 97A, and its tensile strength is horizontal 259kg/cm2, longitudinal direction 332kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 210 DEG C, and the thickness of film layer is 0.45mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 52%, simulation fatigue test averagely stand 5.5 ten thousand bendings, distortion start local delamination occur.
Embodiment 6
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber.The film layer by TPU with PVC blending is formed, and its shore hardness is 94A, and its tensile strength is horizontal 242kg/cm2, longitudinal direction 309kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 200 DEG C, and the thickness of film layer is 0.3mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 80%, simulation fatigue test averagely stand 70000 bendings, distortion start local delamination occur.
Embodiment 7
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber.The film layer by TPU with PVC blending is formed, and its shore hardness is 96A, and its tensile strength is horizontal 252kg/cm2, longitudinal direction 323kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 200 DEG C, and the thickness of film layer is 0.3mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 82%, simulation fatigue test averagely stand 7.1 ten thousand bendings, distortion start local delamination occur.
Embodiment 8
A kind of restraint zone manufacture method is present embodiments provided, is comprised the steps:
One transparent thin film layer is provided;
Ink layer, adhesive phase is set gradually in film layer and is dry;
Film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in adhesive phase side, in adhesive after cooling Layer side forms fastening band body.
The material of the fastening band body is TPU, i.e. TPUE rubber.The film layer by TPU with PVC blending is formed, and its shore hardness is 95A, and its tensile strength is horizontal 247kg/cm2, longitudinal direction 316kg/cm2, the tensile strength Testing standard is determined for ASTM-D412- rubber tensile property;In addition, being added with TUP in the manufacture process of film layer anti-yellowing Become additive.
The fusing point of the film layer is 200 DEG C, and the thickness of film layer is 0.28mm~0.32mm.
Carry out outward appearance detection to watchband, and with acetone soln soak 48 hours inspection composite beds of watchband that injection completes with The adhesion property of body, analog machine simulation fatigue wear test.Overall product qualification rate 95.8%, the average warp of simulation fatigue test Started local delamination occur by 8.3 ten thousand bendings, distortion.
As depicted in figs. 1 and 2, the embodiment of the present invention additionally provides a kind of watchband, and which includes film layer 2, is successively set on Ink layer 3, adhesive phase 4 in film layer 2, and it is arranged on fastening band body of the adhesive phase 4 away from the side of film layer 2 1, the tensile strength of the film layer 2 is horizontal 222kg/cm2~272kg/cm2, longitudinal direction 284kg/cm2~348kg/cm2.Its In, adhesive phase 4 is with bonding effect and ink defencive function.The embodiment of the present invention is by the elasticity using specific tensile strength Thin-film layers 2, are frequently bent during solving restraint zone Long-Time Service, distort, and cause substrate layer with fastening band body office Part is from the problem of, local delamination.
Presently preferred embodiments of the present invention is the foregoing is only, not in order to limit the present invention, all essences in the present invention Any modification, equivalent or improvement that is made within god and principle etc., should be included within the scope of the present invention.

Claims (17)

1. a kind of restraint zone manufacture method, it is characterised in that comprise the steps:
A film layer is provided, the film layer material is transparent rubber;
Ink layer, adhesive phase is set gradually in the film layer and is dry;
The film layer is placed in mould, and thermoplastic elastomer (TPE) is injected in described adhesive layer side, in institute after cooling State adhesive phase side and form fastening band body.
2. restraint zone manufacture method as claimed in claim 1, it is characterised in that the tensile strength of the film layer material is horizontal stroke To 222kg/cm2~272kg/cm2, longitudinal direction 284kg/cm2~348kg/cm2.
3. restraint zone manufacture method as claimed in claim 2, it is characterised in that the tensile strength of the film layer is horizontal 235kg/cm2~259kg/cm2, longitudinal direction 300kg/cm2~332kg/cm2.
4. restraint zone manufacture method as claimed in claim 3, it is characterised in that the tensile strength of the film layer is horizontal 242kg/cm2~252kg/cm2, longitudinal direction 309kg/cm2~323kg/cm2.
5. the restraint zone manufacture method as described in claim 2~4 any one, it is characterised in that tensile strength testing standard For ASTM-D412- rubber tensile property assay method.
6. restraint zone manufacture method as claimed in claim 1, it is characterised in that the shore hardness of the film layer be 90A~ 98A.
7. restraint zone manufacture method as claimed in claim 6, it is characterised in that the shore hardness of the film layer be 92A~ 97A.
8. restraint zone manufacture method as claimed in claim 7, it is characterised in that the shore hardness of the film layer be 94A~ 96A.
9. restraint zone manufacture method as claimed in claim 1, it is characterised in that the material of the fastening band body is thermoplasticity Elastomer rubber.
10. restraint zone manufacture method as claimed in claim 1, it is characterised in that the material of the fastening band body is thermoplastic Property elastic polyurethane body rubber.
11. restraint zone manufacture methods as claimed in claim 1, it is characterised in that the material of the film layer is thermoplastic elastomehc Gonosome rubber.
12. restraint zone manufacture methods as claimed in claim 11, it is characterised in that the material of the film layer be by TPU with The thermoplastic elastomer rubbers of PVC blending.
The 13. restraint zone manufacture methods as described in Claims 1 to 4 any one, it is characterised in that the fusing point of the film layer For 160 DEG C~280 DEG C.
14. restraint zone manufacture methods as claimed in claim 13, it is characterised in that the fusing point of the film layer be 180 DEG C~ 210℃.
The 15. restraint zone manufacture methods as described in Claims 1 to 4 any one, it is characterised in that the thickness of the film layer For 0.1mm~0.7mm.
16. restraint zone manufacture methods as claimed in claim 15, it is characterised in that the thickness of the film layer be 0.14mm~ 0.45mm.
The watchband of the restraint zone method manufacture described in a kind of 17. employing claim 1~16 any one.
CN201610825146.9A 2016-09-14 2016-09-14 A kind of restraint zone manufacture method and watchband Pending CN106476368A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publication number Priority date Publication date Assignee Title
CN107399042A (en) * 2017-07-17 2017-11-28 福建省石狮市通达电器有限公司 A kind of IMF watchbands moulding process and its IMF watchbands
CN109124583A (en) * 2018-08-08 2019-01-04 加动健康科技(芜湖)有限公司 Comfort type bandage for individual energy consumption measuring device
CN109157193A (en) * 2018-08-08 2019-01-08 加动健康科技(芜湖)有限公司 Individual energy consumption measuring device

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107399042A (en) * 2017-07-17 2017-11-28 福建省石狮市通达电器有限公司 A kind of IMF watchbands moulding process and its IMF watchbands
CN107399042B (en) * 2017-07-17 2023-05-23 福建省石狮市通达电器有限公司 IMF watchband forming process
CN109124583A (en) * 2018-08-08 2019-01-04 加动健康科技(芜湖)有限公司 Comfort type bandage for individual energy consumption measuring device
CN109157193A (en) * 2018-08-08 2019-01-08 加动健康科技(芜湖)有限公司 Individual energy consumption measuring device

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Application publication date: 20170308