TWM513882U - Nano ceramic coating micro particle structure having active tree-like support layer - Google Patents

Description

Nano ceramic coating particle structure with active dendritic support layer

The present invention discloses a nano ceramic coating particle structure having an active dendritic support layer, comprising a monooxane interpenetrating network core; a dendritic inlaid network layer; and an active dendritic support layer; The active dendritic support layer comprises an active dendritic structure, a plurality of active sites and an accommodating space, wherein the accommodating space supports the nano ceramic coating particle structure and functions as an environmental buffering function. Overcoming the prior art, special metal surfaces that meet various needs facilitate the purpose of upgrading, coloring, sealing and protecting.

In many applications such as building materials and home appliances, it is often necessary to modify the surface of the material to produce functional properties such as corrosion resistance or bonding of foreign materials. In the prior art, a phosphate treatment system is used to modify the surface of a metal material, and an acidic solution containing a phosphate ion is brought into contact with a steel sheet to cause a reaction, and a crystallized surface film containing a phosphate as a main component is formed on the surface of the plating layer. Such a treatment improves the adhesion to the coating film and has a stable undercoating property for various subsequent coatings. Therefore, the metal plate, in particular, the galvanized steel sheet is subjected to phosphate treatment, and is widely used as a coating application for building materials and home appliances. However, since phosphate treatment has insufficient corrosion resistance, it is usually subjected to a sealing treatment called "sealing treatment" after the phosphate treatment. In this sealing treatment, an aqueous solution containing hexavalent chromium is brought into contact with a steel sheet by spraying, dipping, or the like, and then dried without being washed with water, whereby the corrosion resistance is improved by the treatment. However, although the chromate treatment agent and the coating film have good reformability, the hexavalent chromium contained has been reported to be quite toxic to both the organism and the environment, and therefore, one can replace the chromate treatment agent. Low toxicity metal surface modifiers have their urgency. In addition, in the industrial process, there is often a tooth flow process, and often breakage or scratching, therefore, the need for metal surface roughness control and wear control is quite urgent. In order to solve these problems, a metal containing phosphorus, molybdenum or the like and a trivalent chromium ion, which are synthetic surface treatment agents containing no hexavalent chromium and fluoride, are disclosed in Japanese Laid-Open Patent Publication No. 2000-054157. Japanese Laid-Open Patent Publication No. Hei-3-39485 discloses a wax in which cerium oxide and a glass transition point (Tg point) are dispersed at 40 ° C or higher in an aqueous resin, and the dry mass is 0.3 g/m ² to 3.0 g. /m ² coating. U.S. Patent No. 5,292,549 discloses the use of a decane couplant for metal plate treatment to crosslink the organofunctional decane to form a fine siloxane film. In the case of a water-based acrylic resin and an aqueous amine-based resin, an epoxy resin and a phosphoric acid or a ring are disclosed in JP-A-61-83262, JP-A-4-41555, and JP-A-5-320568. A thermosetting composition in which an oxygen resin and a phosphate ester and a carboxylic acid reactant improve adhesion. An alcohol solution of an alkoxydecane oligomer having an average molecular weight of 1,000 to 10,000 is formed by hydrolysis and condensation using ethyl ortho-nonanoate as a precursor, as disclosed in Japanese Patent Publication No. 2004-047447 and No. 2004-073736. As a chromium-free water-soluble metal anti-rust coating. There are also many teams in Taiwan that want to solve the above problems, such as the Republic of China Patent Bulletin No. 555888, which proposes a magnesium-aluminum alloy surface treatment method characterized by acid treatment of the surface of the magnesium-aluminum alloy with an organic-inorganic acid mixed solution to achieve activated metal. The purpose of the organic-inorganic acid mixed solution is a mixed inorganic or organic acid or a mixed solution of the two, wherein the organic acid may be any one or more organic acids selected from the group consisting of acids, alkyds, diacids, and phosphonic acids; Any one or more may be selected from phosphoric acid, nitric acid, boric acid or hydrochloric acid. Republic of China Patent No. I406969, a method of coating a metal surface with an aqueous composition comprising decane/stanol/halothane/polyoxyalkylene, characterized in that the composition comprises at least one compound selected from the group consisting of a compound comprising titanium, cerium, zirconium, aluminum, and/or boron, at least one of which is a mis-fluoride, and at least one cation, and a metal cation and/or at least one corresponding compound, the composition further comprising at least one substance selected from the group consisting of: in each case having at least one amine group, urea group and/or imine group An antimony compound, an anion of a nitrite and/or a peroxide-based compound of a compound having at least one nitro group, and an anion of a phosphorus-containing compound, an anion of at least one phosphate, and/or at least one phosphonate. The Republic of China Patent Publication No. I339596 proposes a method for treating a nano ceramic solution on a metal surface, comprising a pretreatment step of first removing oil stains and impurities on a surface of a metal; and covering a nano ceramic solution step, The invention comprises covering a surface of the metal with a nano ceramic solution, and chemically bonding the nano ceramic solution to the surface of the metal to form a nano ceramic film, wherein the nano ceramic solution comprises at least two metal alkoxides, water and The metal alkoxide is catalyzed to further condense with water to form an acid of the nanoceramic solution. The Republic of China Patent Publication No. 201221683 proposes a method for preparing a low dielectric material film by inserting a substrate into a plasma generation reaction system; and introducing a carrier gas into the plasma generation reaction system, the carrier gas Carrying a fluorocarbon ceria precursor and forming the fluorocarbon-containing ceria precursor on the substrate; and converting the fluorocarbon-containing ceria precursor into a low dielectric material film and eliminating The stress of the low dielectric material film has a tighter structure; wherein the low dielectric material film has a carbon content of between 10% and 50% and a fluorine content of between 10% and 40%. However, these technologies cannot fully satisfy the problems of corrosion resistance, heat resistance, fingerprint resistance, conductivity, etc., especially halogen-containing or nano-additives have more environmental safety problems, and have no use and modulation convenience. Stability. In addition to the above problems, conventional techniques cannot achieve high-quality precision surface modification applications through normal temperature and quick-drying process operations. In addition, conventional nano ceramic coatings have the problem of shrinkage and brittle fracture. More specifically, for special metals such as lithium magnesium alloys (such as LZ91), magnesium alloys (such as AZ91, AZ31), because lithium has high activity, easy to react to produce rust, acid and alcohol, and difficult to adhere and corrosion Balanced performance, and from stamping, film passivation to coating, the perfect fit is required to achieve light weight, corrosion resistance, elongation strength, and stamping processing.

In view of this, the creators of this creation have carefully studied and proposed a nano-ceramic coating particle structure with an active dendritic support layer. In addition to solving the above requirements, the creative design product can be further adjusted according to the customization requirements. It is a kind of nano ceramic coating particle structure with active dendritic support layer with high maneuverability. Such a nano ceramic coating particle structure design with an active dendritic support layer solves the prior art using only the coating performance limitations of various types of mixtures, and the surface modifying agent of the present invention has the advantages of stable quality and stability. In particular, it can be dried at a constant temperature to achieve surface modification, and is not limited to the surface of a metal material.

The present invention discloses a nano ceramic coating particle structure having an active dendritic support layer. In order to achieve high maneuverability, an active multi-dentic core (Active Multi-Dentric Core) is specially designed for a normal temperature and quick drying coating. AMD Core) and its surface layer of helium oxide interpenetrating network structure layer, wherein the active dendritic core body has a receiving space which can serve as a surface microenvironment buffering function and an active dendritic structure supporting the receiving space, as The characteristic structure of the nano ceramic coating particle structure. The nano ceramic coating particle structure can overcome the prior art, and the surface for various needs is convenient for dry temperature modification, sealing, coloring and sufficient protection, and is particularly suitable for special metals such as lithium alloy, lithium magnesium alloy and aluminum. The protection of alloys, but not limited to the surface of special metal alloys and metal materials, is also applicable to the surface of other inorganic or organic systems.

That is, the present disclosure discloses a nano ceramic coating particle structure having an active dendritic support layer, wherein the nano ceramic coating particle structure comprises a phthalic oxide interpenetrating network core; a dendritic embedded structure layer; And an active dendritic support layer; wherein the oxane interpenetrating network core comprises a plurality of siloxane oxide molecular chain structures, and the oxane oligo molecular chain structure is interconnected to form the oxime An alkane interpenetrating network core; the active dendritic support layer comprises an active dendritic structure, a plurality of active sites and an accommodating space, wherein the active dendritic structure comprises a plurality of dendritic structures and a plurality of dendrites a structural terminal, wherein the dendritic structures are connected to each other to form the active dendritic structure, and at the same time form the accommodation Space, and supporting the nano ceramic coating particle structure; and the dendritic intercalation layer is disposed between the xenon oxide interpenetrating core body and the active dendritic support layer for The outer contour of the alkane interpenetrating network core supports a network structure in which the active dendrimer is fitted.

Preferably, the accommodating space functions as a buffer for the microenvironment structure.

Preferably, the accommodating space can be used to accommodate a pH adjusting particle to adjust the pH value.

Preferably, the helium oxide interpenetrating layer has a weight ratio of aluminum to lanthanum between 1:20 and 1:100, including (OR) _x MOM(OR) _x , (R) _y (OR) _xy MOM(OR) _xy (R) _y , M(OR) _x , M(OR) _xy (R) _y or (OR) _x MOM(OR) _x and combinations thereof; R is selected from alkyl a group consisting of an alkenyl group, an aryl group, an alkylhalide group, a hydrogen group, and combinations thereof; the M system may be selected from the group consisting of aluminum, strontium, and combinations thereof. Group; x>y, and x is 2, 3, 4 or 5, and y is 1, 2, 3 or 4.

Preferably, the molecular structure of the siloxane oxide oligomer is selected from the group consisting of ethylene trimethoxy decanoate, methyl trimethoxy decanoate, tetraethoxy decyl halide, dimethyl diethoxy decyl halide. Phenyltriethoxydecane, γ-methylpropoxypropyl-trimethoxydecane, γ-chloropropyltrimethyloxydecane, decyltrimethoxydecane, isobutyltrimethyl Oxaloxane, tertiary-butyldimethylchloromethane, vinyltrichloromethane, 3-aminopropyltrimethoxydecane, diphenyldichlorodecanoate, hexamethyldidecane, Vinyl tridecane, citrate derivative, bis(3-triethoxydecylpropyl)amine, bis(3-trimethoxydecylpropane)amine, 3-aminopropanylmethyldiethoxylate Decane, 3-aminopropane-triethoxyoxane, 3-aminopropanyl-methyldiethoxyoxane, polyamine decane, polyamine oxirane, 3-aminopropane-trimethoxy decane , triamine functional propane trimethaneoxydecane, 2-aminoethyl-3-aminopropyl Methyl-dimethoxydecane, 2-aminoethyl-3-aminopropyl-trimethoxydecane, epoxy oxane, and combinations thereof are formed.

Through the creation of nano ceramic coating particle structure can be used but not limited to metal surface, especially for the modification of the surface characteristics of zinc, aluminum, stainless steel and titanium alloy products, to achieve surface adhesion adjustment, surface tension adjustment, surface roughness Adjustment, surface biocompatibility adjustment, surface dielectric constant adjustment, surface thermal expansion coefficient adjustment, surface isolation film thickness adjustment, surface color adjustment, surface oxidation degree adjustment, etc. More specifically, it is more suitable for special metals such as lithium-magnesium alloys (such as LZ91), magnesium alloys (such as AZ91, AZ31), and aluminum alloys (such as 5052-H32) to solve the problem that special metals are easily reacted to produce rust, acid and alcohol. It is difficult to balance the adhesion and corrosion resistance, and from the stamping, film passivation to coating, the need for perfect fit, to achieve the purpose of product lightweight, corrosion resistance, extension strength, and stamping.

Optionally, the nano ceramic coating particle structure further comprises a pH adjusting agent for adjusting the pH value according to the application of the normal temperature dry coating. Optionally, the nano ceramic coating particle structure may further be selected from the group consisting of a polyurea resin, a polyacrylate resin, a polyamide resin, a polyepoxy resin, a polytetrafluoroethylene, a polyoxyalkylene resin, A functional resin of a polycarbonate resin, a polyacetylene resin, a polyethylene glycol resin, a polyvinylpyrrolidone, a polyolefin resin, and a combination thereof forms a custom functional coating. Selectively achieve metal surface adhesion adjustment, surface tension adjustment, surface roughness adjustment, surface biocompatibility adjustment, surface dielectric constant adjustment, surface thermal expansion coefficient adjustment, surface isolation film thickness adjustment, surface oxidation degree adjustment The metal surface is colored and adjusted to function.

1‧‧‧Nano ceramic coating particle structure with active dendritic support layer

10‧‧‧Active tree core subject

11‧‧‧dendritic structure

12‧‧‧dendritic terminal

13‧‧‧Active dendritic structure

15‧‧‧Active points

17‧‧‧ accommodating space

20‧‧‧Hane oxide interpenetrating network core

25‧‧‧Oxygenane oligomer molecular chain structure

30‧‧‧Tree-like inlaid mesh structure

35‧‧‧ mesh structure

Fig. 1, a schematic diagram of a nano-ceramic coating particle structure with an active dendritic support layer Figure.

The present invention discloses a nano ceramic coating particle structure having an active dendritic support layer, comprising a monooxane interpenetrating network core; a dendritic inlaid network layer; and an active dendritic support layer; The oxane interpenetrating network core comprises a plurality of siloxane oxide molecular chain structures, and the siloxane oxide oligo molecular chain structure is interconnected to form the oxirane interpenetrating network core; the active tree The support layer comprises an active dendritic structure, a plurality of active sites and an accommodating space, wherein the active dendritic structure comprises a plurality of dendritic structures and a plurality of dendritic structures, and the dendritic structures are interconnected Supporting to form the active dendritic structure, and simultaneously forming the accommodating space, and supporting the nano ceramic coating particle structure; and the dendritic intercalation structure layer, disposed on the siloxane base interpenetrating core body and the Between the active dendritic support layers, for forming a network structure capable of fitting the active dendrites to the outer contour of the oxime interpenetrating network core, wherein the nano ceramic coating particle structure Aluminum Weight ratio is between 2 and 20, and includes -Si-O-Si- bond -Si-O-Al- and bond the IPN structure. The nano ceramic coating particle structure can overcome the prior art, and achieve the purpose of convenient modification, coloring, sealing and protection of the metal surface of various requirements. In order to make the objects, features, and advantages of the present invention more comprehensible, the preferred embodiments are described in detail below.

First Embodiment - Preparation of Nano Ceramic Coating Particle Structure for Surface Protection of Lithium-Oxide Alloy

The present invention relates to a nano ceramic coating particle structure for protecting a surface of a lithium magnesium alloy having a buffer layer of a siloxane active dendrite, which can be prepared by the following steps. Taking a first functional oxirane 1 Mohr and a second functional oxirane 2 Mohr corresponding to the addition or condensation reaction of the first functional group, dissolved in 20 g of isopropyl alcohol solvent to form a mixed oxime The oxyalkylate isopropanol solution, that is, the first functional group energy of the corresponding reaction and the reactant number of the second functional group are controlled, mixed and stirred at room temperature at 25° to form a siloxane activity. Dendrimer solution. Further, taking aluminum sec-butoxide 0.01 molg dissolved in 10 g of isopropyl alcohol solvent to form an aluminum oxide isopropanol solution, the oxirane compound 0.2 mol, dissolved in 20 g different The propanol solvent forms a mixed aluminum oxide/nonoxyalkylated isopropanol solution, and is stirred and mixed and subjected to an interpenetrating reaction at room temperature of 25° to obtain a molecular chain structure containing a plurality of siloxane oxide oligomers. The oxane interpenetrates the core body solution and adds a oxoxane active dendrimer solution to form an in-core network structure forming reaction for 10 minutes. Optionally, additives such as a reaction accelerator, a pH adjuster, or a co-catalyst may be added to control the molecular weight of the reaction product and the interpenetrating network density in accordance with the requirements of customization. For example, 0.1 g of nitric acid is added and stirred for 10 minutes, 20 g of water is added, and the mixture is stirred for 2 hours to make the reaction more fully interpenetrating. Of course, titanium oxide and chromium oxide can also replace aluminum oxide in specific applications. For example, titanium oxide is mainly transmitted through a titanium oxide propoxide (titanium (IV) propoxide), titanium isopropoxide (titanium). (IV) isopropoxide), titanium (IV) butoxide, titanium (IV) sec-butoxide, titanium tertiary butane (titanium (IV) Teit-butoxide) and its combination group of titanyl alkoxides. In the embodiment, the nano ceramic coating particle structure having the active dendritic support layer is designed, wherein the helium oxide interpenetrating core body has an aluminum crucible weight ratio of between 20 and 100. The infrared ceramic spectroscopic analysis of the nano ceramic coating particle structure revealed an absorption peak at 1000 to 1100 cm ^-1 , which is evidence that the active siloxane sub ^- network multi-core structure has Si-O-Si bonding. The core body of the aluminum-niobium oxide composite interpenetrating network oligomer has a particle diameter of between 0.01 micrometers and 0.1 micrometers as determined by particle size analysis. The first oxime oxyalkylate and the second oxo oxyalkylate used in this embodiment are selected from the group consisting of ethylene trimethoxy decanoate, methyl trimethoxy decane, tetraethoxy decyl, dimethyl diethoxy Base hydride, phenyltriethoxy decane, γ-methyl propyloxypropyl-trimethoxy decane, γ-chloropropyltrimethyloxydecane, decyltrimethoxydecane, different Butyl trimethoxy decanoate, tertiary butyl dimethyl chloroformate, vinyl trichloromethane, 3-aminopropyl trimethoxy decane, diphenyl dichloromethane, hexamethyl Decane, vinyl tridecanoate, decanoate derivative, bis(3-triethoxydecylpropyl)amine, bis(3-trimethoxydecylpropane)amine, 3-aminopropanylmethyl Diethoxyoxane, 3-aminopropanyl-triethoxyoxane, 3-aminopropanyl-methyldiethoxyoxane, polyaminodecane, polyamine oxirane, 3-aminopropanyl- Trimethoxane, triamine functional propane trimethaneoxydecane, 2-aminoethyl-3-aminopropylmethyl-dimethoxydecane, 2- An alkoxyalkylate of aminoethyl-3-aminopropyl-trimethoxydecane, an epoxy oxane, and combinations thereof. Therefore, the present constant temperature and quick-drying surface modifier mainly comprises an interpenetrating network structure and the structure comprises (OR) _x MOM(OR) _x , (R) _y (OR) _xy MOM(OR) _xy (R) _y , M(OR) _x , M(OR) _xy (R) _y or (OR) _x MOM(OR) _x and combinations thereof; R is selected from an alkyl group, an alkenyl group, a group consisting of an aryl group, an alkylhalide group, an amino group, a hydrogen group, and a combination thereof; the M system may be selected from the group consisting of aluminum, cerium, and combinations thereof; x>y, and x is 2, 3, 4 or 5, y is 1, 2, 3 or 4; and the weight ratio of aluminum to bismuth is between 1:20 and 1:100; the particle size is between 0.1 micron Up to 100 microns. The paints that can be applied in this creation may be a combination of a group consisting of a sol, a gel, a sol-gel, a particle suspension, a homogeneous liquid, and an emulsion. Therefore, it can be immersed, sprayed, roller coated, and generally coated as needed. The combined process performs the modification of the surface of the target material. The surface of the modified material can be directly air-dried, and further strengthened by high-temperature drying or ultraviolet light irradiation according to requirements. In a specific application, the surface of the target material can be firstly filtered through plasma, ozone, acid and alkali to increase the activity of the surface of the target metal, to achieve surface adhesion adjustment, surface tension adjustment, surface roughness adjustment, surface bio-phase Capacitive adjustment, surface dielectric constant adjustment, surface thermal expansion coefficient adjustment, surface isolation film thickness adjustment, surface oxidation degree adjustment, etc.

The original temperature-drying coatings are used for common metal surfaces in order to protect or change the surface function of materials, especially special metals, but not limited to metals, which can be used for the modification of the surface properties of zinc, aluminum, stainless steel and titanium alloy products or glass or矽 wafers, especially for lithium-magnesium alloys (such as LZ91), magnesium alloys (such as AZ91, AZ31), aluminum alloys (such as 5052-H32), to achieve product weight, corrosion resistance, ductility, and stamping processing purposes. More suitably, when the surface protection of the lithium-magnesium alloy is applied, the protective effect can be further enhanced by the film treatment or the anodizing treatment or the micro-arc oxidation treatment.

Can be used to achieve surface adhesion adjustment, surface tension adjustment, surface roughness adjustment, surface biocompatibility adjustment, surface dielectric constant adjustment, surface thermal expansion coefficient adjustment, surface isolation film thickness adjustment, surface oxidation degree adjustment, etc. purpose.

Second Embodiment - Nano Ceramic Coating Particle Structure with Active Dendritic Support Layer

In this embodiment, a nano ceramic coating particle structure (1) having an active dendritic support layer is designed as shown in FIG. 1 , wherein the nano ceramic coating particle structure having the active dendritic support layer The body (1) comprises a monooxane interpenetrating network core (20); a dendritic network structure layer (30); and an active dendritic support layer (10); wherein the xenon oxide interpenetrating network core The main body (20) comprises a plurality of siloxane oxide oligomer molecular chain structures (25), and the siloxane oxide oligomer molecular chain structure (25) is interconnected to form the oxirane interpenetrating network core (20) The active dendritic support layer (10) comprises a plurality of active dendritic structures (13), a plurality of active sites (15) and an accommodating space (17), wherein the active dendritic structure (13) comprises a plurality of dendritic structures (11) and a plurality of dendritic structures (12), wherein the dendritic structures (11) are interconnected to form the active dendritic structure (13), and simultaneously form the accommodating space (17) And supporting the nano ceramic coating particle structure (1) having an active dendritic support layer; and the dendritic intercalation structure layer (30) disposed on the xenon oxide interpenetrating network core (20) Between the active dendritic support layer (10), a net for supporting the active dendrimer structure (13) is formed on the outer contour of the xenon oxide interpenetrating core body (20). Structure (35)Wherein the xenon oxide interpenetrating network core (20) has a particle size of between 0.01 micrometers and 0.1 micrometer; and the nano ceramic coating particle structure (1) having an active dendritic support layer has a Particle size between 0.5 microns. The accommodating space (17) mainly plays the role of structural buffering in the structure. In a specific application, the nano ceramic coating particle structure (1) having an active dendritic support layer is highly compatible with most functional resins, and may be combined with a plurality of selected from polyurea resins. Polyacrylate resin, polyamide resin, polyepoxy resin, polytetrafluoroethylene, polyoxyalkylene resin, polycarbonate resin, polyacetylene resin, polyethylene glycol resin, polyvinylpyrrolidone, polyolefin resin and The functional resin of the combined group is used to fully characterize the highly compatible nature of the creation, and can further form a product that conforms to the customized function.

The present invention relates to a nano ceramic coating particle structure design with an active dendritic support layer. The prior art utilizes only the coating performance limitations of various types of mixtures, such as solvent compatibility. Environmental friendliness, coating stability, coating thickness, coating and metal adhesion, corrosion of coatings to special metals. Moreover, due to the design of the nano-ceramic coating particle structure with active dendritic support layer as the main feature of the normal temperature and quick-drying coating, the creation of the normal temperature and quick-drying coating in addition to the performance improvement, but also because of the active tree core body, With core features such as structural stability of the key products and fast drying at room temperature, the terminal products are more stable in quality control and operation applications. Further, it is more convenient to modulate various functional coatings due to customized requirements. A room temperature quick-drying coating with the advantages of progressiveness, innovation, convenience of industrial utilization and improvement of related industries. More suitably, when the surface protection of the lithium-magnesium alloy is applied, the protective effect can be further enhanced by the film treatment or the anodizing treatment or the micro-arc oxidation treatment.

The above description is only a preferred embodiment of the present invention. When it is not possible to limit the scope of the creation of the present invention, the equivalent changes and modifications made by the applicant in accordance with the scope of the patent application and the contents of the new manual should remain This creative patent covers the scope. Looking at the above, the structural features of this creation do have practical value and progressiveness. In terms of its overall structure, Cheng has already complied with the statutory requirements of the Patent Law and has filed a new type of patent application according to law.

1‧‧‧Nano ceramic coating particle structure with active dendritic support layer

10‧‧‧Active tree core subject

11‧‧‧dendritic structure

12‧‧‧dendritic terminal

13‧‧‧Active dendritic structure

15‧‧‧Active points

17‧‧‧ accommodating space

20‧‧‧Hane oxide interpenetrating network core

25‧‧‧Oxygenane oligomer molecular chain structure

30‧‧‧Tree-like inlaid mesh structure

35‧‧‧ mesh structure

Claims (5)

A nano ceramic coating particle structure having an active dendritic support layer, wherein the nano ceramic coating particle structure comprises a fluorene oxide interpenetrating network core; a dendritic network layer; and an active tree a bulk support layer; wherein the oxane interpenetrating network core comprises a plurality of siloxane oxide molecular chain structures, and the siloxane oxide oligomer molecular chain structure is interconnected to form the oxirane interpenetrating network core The active dendritic support layer comprises an active dendritic structure, a plurality of active sites and an accommodating space, wherein the active dendritic structure comprises a plurality of dendritic structures and a plurality of dendritic structures, and the The dendritic structures are interconnected to form the active dendritic structure, and at the same time form the accommodating space and support the nano ceramic coating particle structure; and the dendritic intercalated structure layer is disposed on the decane intercalation Between the core body and the active dendritic support layer, a mesh structure capable of fitting the active dendrites is formed in a supportive manner on the outer contour of the xenon oxide interpenetrating core body. The nano ceramic coating particle structure according to claim 1, wherein the helium oxide interpenetrating core body has a weight ratio of aluminum to tantalum of between 1:20 and 1:100, including (OR) _x MOM(OR) _x , (R) _y (OR) _xy MOM(OR) _xy (R) _y , M(OR) _x , M(OR) _xy (R) _y or (OR) _x MOM( OR) a bond of _x and a combination thereof; R is selected from the group consisting of an alkyl group, an alkenyl group, an aryl group, an alkylhalide group, an amino group, a hydrogen group, and a group consisting of a combination; the M system may be selected from the group consisting of aluminum, strontium, and combinations thereof; x>y, and x is 2, 3, 4, or 5, and y is 1, 2, 3, or 4 . The nano ceramic coating particle structure according to claim 1, wherein the molecular structure of the siloxane oxide oligomer is selected from the group consisting of ethylene trimethoxy decyl halide and methyl trimethoxy decyl halide. , tetraethoxy decyl hydride, dimethyl diethoxy decyl hydride, phenyl triethoxy decyl hydride, γ-methyl propyloxypropyl-trimethoxy decane, γ-chloropropyl trimethyl Oxaloxane, decyltrimethoxydecane, isobutyltrimethoxydecane, tert-butyldimethylchloromethane, vinyltrichloromethane, 3-aminopropyltrimethoxydecane , diphenyldichloromethane, hexamethyldidecyl, vinyl tridecanoate, decanoate derivative, bis(3-triethoxydecylpropyl)amine, bis(3-trimethoxydecane) Alkyl)amine, 3-aminopropanylmethyldiethoxydecane, 3-aminopropanyl-triethoxyoxane, 3-aminopropanyl-methyldiethoxydecane, polyaminodecane, Polyamine-based oxane, 3-aminopropylpropane-trimethoxy decane, triamine functional propane-trimethyloxy decane 2-Aminoethyl-3-aminopropylmethyl-dimethoxydecane, 2-aminoethyl-3-aminopropyl-trimethoxydecane, epoxy oxoxane, and combinations thereof The formation of ethnic groups. The nano ceramic coating particle structure according to claim 1, wherein the accommodating space functions as a buffer for the microenvironment structure. The nano ceramic coating particle structure according to claim 1, wherein the accommodating space can be used to accommodate a pH adjusting particle to adjust the pH value.