M435567 五、新型說明： 【新型所屬之技術領域】 本創1?係生態物理科技處理程序上之改變設 言1技ΐ!態燃料經燃燒後之廢氣源排放污 染，透=創=備之設計機制，而達到綠能環保 利用之使用目的者。 【先前技術】 在能源逐漸耗竭的今日’將廣棄物有效的回收再利用 並同時轉變為再生能源，不僅可替代部份化石能源，更可 減少節省廢棄，處理的費用。習用廢棄物能源利用多以直 接燃燒或焚祕，產生熱量’再經由熱回收設備產生蒸氣 或熱水，然，廢棄物組成複雜，若無適當的前處理程序， 燃燒時不易穩疋’其旎源回收效率亦無法與一般鋼爐相比 擬；此外，不穩定的燃燒也易產生二次污染物，造成曰後 空氣污染設備建置之負擔，因此，如何使廢棄物得到穩定 的燃燒，乃廢棄物能源是否可有效利用所必需面對的問 題。工研院自90年代起，引進並研究開發廢棄物衍生燃料， 此種技術是將廢棄物先經破碎或粉碎，再以筛選機、磁選 機及風力選別機等前處理設備將廢棄物分成不可燃及可燃 兩類，其中不可燃部份，先將有價物質（金屬、玻璃等） 資源回收，無價物質（土砂、石子、陶瓷等）則送至掩埋 場處置’而剩餘之有機可燃物則經過均化後製成RDF，藉以 做為再生燃料使用’因應環保規範之制定需求，RDF基本特 性要求包括：具較高熱源、利於儲存與運輸、低污染等功 能特質，其製程技術上，有其提升之必要性。 報廢機動車輛經回收利用機制所產生之破碎物 (ASR;Auto Shredder Residue)及含油脂污泥為處i里之重 3 M435567 點，其中固態RDF成份中可供燃燒再利用之物質主要以 綿、塑膠及橡膠類為主，再包含油脂污泥中可淬集供^ 燒之成伤物質為數可觀’其中如何藉由分離無用ϋ物t 之技術，經製成可供完全燃燒應用之衍生燃料，為重要 據來源。ASR組成因廢棄廠牌種類、來源不同並依回收 特性進行拆解、破碎及回收流程及設備差異，其最終物= 統一標準規格’於是乎ASR廢料中所掺雜之内容物士分^ 混掺有木材、玻璃、皮革、纖毛、砂石及特殊重金屬:暂 等’無俱燃燒效益之搭配物質，燃燒石油化學物所產生 廢氣’主要包含有高密度成份之含碳黑煙、有毒氣體⑶之 THC、NOx、SOx、PM灰臭氣等等，其中又以碳粒子之 : 物及劇毋對人類產生最大的生命威脅’並對於環境長期氟 吸附毒害更為可怕’有鑑於此，世界各國無不紛紛訂定^ 格之排污規定因此單從源頭ASR原料之蒐集分類，亦為^ 要解決之問題。 .、’、百 、由於ASR之組成成份複雜且多變，因此要完全達到符合經濟 效益、環境保護及資源回收的ASR處理方式仍不易，習知常用的 處理技藝方式有掩埋、焚化、熱裂解、固化/穩定化、高溫氣化、 電聚炫融及資源回收等，以下分別對這些處理方式加以說明： 掩埋處理：此為最常見的ASR處理方式，但由於asr 中，有重金屬、廢油/廢溶劑及不易腐化之廢塑膠等物質， 可能對土壤及地下水造成若干之影響，所以並不適合以直 接掩埋的方式來處理，其後續 掩埋土地取得逐漸困難，亦 疋原因所在。 焚化處理：ASR之组成物有40〜50 wt%為可燃性物質， ，值平岣約為5400 btu/lb，為煤碳所含熱值的一半，焚化 $ ASR之重量約可減少50 %，體積比則可減少約75 %，充 分達到減容、減重及減量的目的；目前並無專門用來處理 ASR的焚化設施與設備，而一般較常用於處理ASR的焚化系 4 M435567 統有兩種，分別為旋轉窯焚化系統（R〇tary Ki ln pr〇cess) 及流體化床焚化系統（Fluidized Bed Incineration)兩 種。 ，固化/穩定化處理：ASR可經固化/穩定化處理後，再以 =埋方式處理，ASR之固化/穩定化處理係指添加固化劑於 R中，使ASR變成不具流動性之固體，藉以有效降低 =動性、1解性及毒性，而減少廢棄ASR對環境造成之危 二。以目前技術而言，最常使用之固化劑有水泥、環氧樹M435567 V. New description: 【New technology field】 The innovation of the 1st eco-physical technology processing program is set to 1 technology! The fuel of the fuel is burned after being burned, and the design is transparent. Mechanism, and achieve the purpose of the use of green energy environmental protection. [Prior Art] In the gradual depletion of energy today, the effective recycling and reuse of waste materials and conversion to renewable energy will not only replace some fossil energy, but also reduce the cost of waste disposal and disposal. Conventional waste energy utilization is mostly direct combustion or incineration, generating heat' and then generating steam or hot water through heat recovery equipment. However, the waste composition is complicated, and if it is not properly pretreated, it is not easy to burn when it is burned. The source recovery efficiency can not be compared with that of ordinary steel furnaces; in addition, unstable combustion is also prone to secondary pollutants, which causes a burden on the construction of air pollution equipment after the flood. Therefore, how to make the wastes burn stably is discarded. Whether the energy of the energy can be effectively utilized. Since the 1990s, ITRI has introduced and researched and developed waste-derived fuels, which are used to break up or pulverize wastes, and then divide waste into pre-treatment equipment such as screening machines, magnetic separators and wind sorters. Non-combustible and flammable, in which the non-combustible part first recovers the valuable substances (metal, glass, etc.), and the invaluable substances (soil, stone, ceramics, etc.) are sent to the landfill for disposal' and the remaining organic combustibles After homogenization, RDF is used as a regenerative fuel. In response to the requirements of environmental protection regulations, the basic characteristics of RDF include: high heat source, good storage and transportation, low pollution and other functional characteristics. There is a need for improvement. The scrapped material (ASR; Auto Shredder Residue) and the grease-containing sludge generated by the recycling mechanism of the scrapped motor vehicle are 3 M435567 points, and the substances in the solid RDF component that can be used for combustion and reuse are mainly cotton. Plastics and rubbers are the main types, and the amount of wounds that can be quenched and collected in the oil sludge is considerable. How can it be made into a derivative fuel for complete combustion applications by separating the use of unwanted wastes? As an important source. The composition of ASR is different due to the type and source of the abandoned brand, and the disassembly, crushing and recycling process and equipment are different according to the recycling characteristics. The final product = uniform standard specification 'The content of the ASR waste is mixed with the material. There are wood, glass, leather, cilia, sandstone and special heavy metals: temporary, 'combustible materials with no combustion efficiency, the waste gas produced by burning petroleum chemicals' mainly contains high-density carbon black smoke and toxic gases (3) THC, NOx, SOx, PM ash and so on, among which carbon particles: Things and dramas have the greatest life threat to humans' and are more terrible for environmental long-term fluorine adsorption and poisoning. In view of this, there are no countries in the world. It is not necessary to set the classification rules for the pollution of the grid. Therefore, the collection of the raw materials from the source ASR is also a problem to be solved. ., ', Bai, because the composition of ASR is complex and variable, it is still not easy to fully achieve the ASR treatment method that meets economic benefits, environmental protection and resource recovery. The commonly used processing techniques are buried, incineration, thermal cracking. , curing / stabilization, high temperature gasification, electropolymerization and resource recovery, etc., these are described separately below: Buried treatment: This is the most common ASR treatment, but due to asr, there are heavy metals, waste oil / Waste solvents and non-corrosive waste plastics, etc., may have some impact on soil and groundwater, so it is not suitable for direct burial. The subsequent land burial has become increasingly difficult. Incineration: The composition of ASR is 40~50 wt% as flammable substance, and the value is about 5400 btu/lb, which is half of the calorific value of coal, and the weight of incineration $ ASR can be reduced by about 50%. The volume ratio can be reduced by about 75%, which fully achieves the purpose of volume reduction, weight reduction and reduction; there is currently no incineration facility and equipment specially used to treat ASR, and the incineration system 4 M435567, which is generally used to treat ASR, has two The species are Rotary Ki ln pr〇cess and Fluidized Bed Incineration. , curing / stabilization treatment: ASR can be cured / stabilized, and then treated in the = buried mode, ASR curing / stabilization treatment refers to the addition of curing agent in R, so that ASR becomes a non-liquid solids, so Effectively reduce = motility, 1 solution and toxicity, and reduce the environmental risk caused by abandoned ASR. In the current technology, the most commonly used curing agents are cement and epoxy trees.
，、石灰以及瀝青等’固化/穩定化處理方式可有效降低ASR 中=含重金屬及多氣聯本之流動性，以減低ASR所含物質 對環境可能造成的危害及避免造成二次污染。但此處理方 式仍有其以下缺失： 1. 處理所需之成本較高。 2. ASR數量龐大，且所含物質有膨鬆現象。 3· ASR經固化/穩定化處理後，仍須要最終處理及處置。 4. ASR所含之有機物質會產生分解現象.，破壞固化及穩 定性’造成裂縫的產生，進而增加其滲透性，而降 低了固化/穩定化所需的強度。 熱裂解處理：熱裂解（pyrolysis)為厭氧或無氧狀態 下’將長鏈狀有機化合物加熱，使其分子鍵斷裂，最後分 解成較小分子結構之副產物（如燃料油品等）及水，經熱 裂解後’可得固態 '液態及氣油（tar )，氣態為可燃性氣 體。熱裂解技術為能源開發的一項重要科技，其應用於有 害廢棄物處理及廢棄物資源化之領域，由於ASR的組成中， 以有機物佔大多數，因此適合採用熱裂解方式予以處理。 ASR資源回收：一般來說’要利用廢棄物所蘊藏的能量， 必須藉燃燒將其中的熱能釋放，再經熱回收設備將其轉變 M435567 較易於利用的能源形式後，才得以有效的利用，將廢棄物 製成RDF，其RDF其具有高熱值、性質均勻穩定、燃燒時 易於控制等特性，十分便於利用，因此將ASR轉製成ASRDF 衍生燃料，如此不但可妥善處理ASR，同時亦能充份發輝 ASR高熱值之特性，兼具廢棄物處理及能源化之功效，使成 為一兼具環保及經濟效益之燃料。 處理廢棄物過程中隱含許多毒害之物質產生，特別是有 害之氣體或化合物殘液，窺見於先前技術中，參考日本國 專利公告2-10341號所揭示之淨化方法為，在廢棄物破綷、 擠斷、混凝過程中受靜壓力及摩擦效應之影響，於封閉氣 室内攪置過程中，以添加入氯氣除用劑（如熟石灰），用 來中和戴奥辛（dioxin)氣體之溢漫濃度。 現今處理RDF回收之方法，已有由批次式運轉之中小 型設備轉換至自動化運轉之大型設備之趨勢，藉由法規曰 趨嚴苛，迫使營運中小型處理設備之團體或中介廢棄物回 收處理商，被迫必須投入更高額之設備改善費用，因處理 過程中，連續性排放放有毒之重金屬廢水及氣體，以往於 排氣流送往最終過程之袋濾器中，雖施以冷卻、沉浸處理， 其毒性殘渣仍依舊保存，是以必須又頭疼其處理之煩腦。 本創作之目的即為解決此現實問題，利用對其產製RDF過 程中施以化學上安定之離子結合方法，成型為水性造膜性 無機化合物(liquid membrane of inorganic compound; LC) 膠質，再經蒐集有害重金屬之濾除，藉以達到淨化之目的。 綜上所陳述之習知裝置或方法中，本案創作人針對因 應科技化、環保節能之應用原則下，從自然法則中推導出 另一創新改良構思，以此觀點所衍生設計出一套結合上述 各種處理程序優益功能之設備，使其經濟量化，藉此更普 及一般大眾民生應用之接受，藉此初衷用心良苦。 M435567 【新型内容】 ，創，之主要目的在於提出—種智慧型 —Derived Fuel)職結構 物再製能源，經再 ，使得廢棄 標準排放範圍目標下之使^後之排放^源，能有效控制在安全 其主要特徵其係於峨廢氣排出口處抱設一自動加熱哪筒， =動加難置係利用廢氣體導人勤管的同時將油料空油管另 端之燃，由藉由引用屢力差將燃油私出弓丨入時透過空氣霧化混 合再接觸熱感應火星塞而碰觸點火，再與_所排放之未完全辦 燒之廢氣射職絲能，即域㈣雜質之減，透過再次愿 縮令便能點火’而魏自動域裝置的魏將排煙淨化器滤芯所 補捉在排煙淨化器環面上之碳粒子很快加熱再次燃燒，也能提昇 淨化器的除煙除臭除毒之魏達到膽⑽貴金屬㈣之轉化溫 又必須達聊GC再生溫度375。(：，而峨之排煙溫度僅在2〇『c左 右）本創作能使得引擎排出之有害氣體化學物質經加熱淨化器效 應可降低至女全檢核量及達到環保與使用安全之維護空污改 目的。 為，成前揭目的，本_所提出之設備輯，其主 嗜翁=自動ΐ熱哪筒，該自動加熱卿筒細柱筒-端插設-，於其表面密佈附設複數似上如針狀之喷氣孔， 之進氣口接^自—高壓儲氣哪筒内之高ί氣體 5=3輸油管經由嗔氣柱導入於該自動= 上 ㈣壓力室内，經混合輪油管噴入之燃油及來自鍋以燒 7 M435567 點火器模組，該點火器模組主要’一 又該點火器模組主要能源係透;電 哪筒細柱筒壓力室環置之熱感應火星塞達到^=動加熱 引燃壓力室中之可燃混合氣氣體. ^燃，轎以 未完全含^1之，廢氣成為可燃之混合氣氣體； 引燃壓力室中之可燃混合氣氣姐， 、 一過濾唧筒模組，該過濾；筒模組主要由一 ^膜性無機化合物）稀釋槽室及一沉澱槽 LC (水性 $體：Ϊ氣端係接收導入來自該自動加熱42；^筒,, lime and asphalt, etc. The curing/stabilizing treatment method can effectively reduce the fluidity of heavy metals and multi-gas in ASR, so as to reduce the environmental damage caused by ASR and avoid secondary pollution. However, this treatment still has the following shortcomings: 1. The cost of processing is high. 2. The number of ASRs is large and the materials contained are bulky. 3. After the ASR is cured/stabilized, it still needs final treatment and disposal. 4. The organic substances contained in ASR will decompose. Destruction of solidification and stability will cause cracks to occur, thereby increasing their permeability and reducing the strength required for curing/stabilization. Pyrolysis treatment: pyrolysis is the heating of long-chain organic compounds under anaerobic or anaerobic conditions, causing their molecular bonds to break, and finally decomposing into by-products of smaller molecular structures (such as fuel oils, etc.) Water, after thermal cracking, 'available solid' liquid and gas oil (tar), the gaseous state is flammable gas. Thermal cracking technology is an important technology for energy development. It is used in the field of hazardous waste treatment and waste recycling. Because of the majority of organic components in the composition of ASR, it is suitable for thermal cracking. ASR resource recovery: Generally speaking, 'the energy contained in the waste must be released by burning the heat energy, and then converted into M435567, which is easier to use, by the heat recovery equipment, and then it can be effectively utilized. RDF is made of RDF. Its RDF has high calorific value, uniform and stable properties, easy to control during combustion, and is very easy to use. Therefore, ASR is converted into ASRDF derivative fuel, so that it can not only properly handle ASR, but also fully The characteristics of the high heat value of ASR, combined with the effects of waste treatment and energy, make it a fuel that is both environmentally friendly and economical. In the process of treating waste, a lot of poisonous substances are produced, especially harmful gases or compound residual liquids. In the prior art, the purification method disclosed in Japanese Patent Publication No. 2-10341 is used in the destruction of waste. During the process of crushing and coagulation, it is affected by static pressure and friction effect. In the process of mixing in the closed gas chamber, chlorine gas de-inger (such as slaked lime) is added to neutralize the dioxin gas. concentration. Nowadays, the method of handling RDF recycling has a tendency to switch from small and medium-sized equipment in batch operation to large-scale equipment that is operated automatically. With strict regulations, it is forced to recycle small or medium-sized processing equipment. Business, forced to invest in higher equipment to improve costs, due to the continuous discharge of toxic heavy metal waste water and gas, in the past, the exhaust stream is sent to the bag filter of the final process, although cooling, immersion treatment The toxic residue is still preserved, so it is an annoyance that must be dealt with by headaches. The purpose of this creation is to solve this practical problem, and to form a liquid membrane of inorganic compound (LC) colloid by applying a chemically stable ionic bonding method in the process of producing RDF. Collecting harmful heavy metals for purification purposes. In summary, in the conventional device or method as stated, the creator of the present case deduced a new innovative and improved concept from the natural law in response to the application principle of technology, environmental protection and energy conservation. A variety of equipment for processing the benefits of the function, so that it is economically quantified, thereby making it more popular for the general public's livelihood application, so that the original intention is good. M435567 [New content], the main purpose of the creation is to propose a kind of intelligent-derived fuel, and then to make the energy source, and then make the emission source under the target of the waste standard discharge range effective. The main feature of safety is that it is equipped with an automatic heating cylinder at the exhaust gas discharge outlet. When the fuel is privately smashed into the bow, it is atomized by air and then contacted with the heat-sensing spark plug to touch the contact fire. Then, the exhaust gas that has not been completely burned is discharged, and the field (4) impurity is reduced. Once again, I hope that the contraction will be able to ignite. The Wei will automatically remove the carbon particles from the exhaust gas purifier on the surface of the exhaust gas purifier, which will quickly heat up and burn again. The deodorizing detoxification of the Wei to reach the gallbladder (10) precious metal (four) conversion temperature must also reach the GC regeneration temperature of 375. (:, and the exhaust gas temperature is only about 2〇C) This creation can make the harmful gas chemicals discharged from the engine can be reduced to the female full inspection volume and the maintenance of environmental protection and safety by the heating purifier effect. The purpose of the pollution. For the purpose of the pre-existing, the equipment series proposed by this _, the main sorcerer = which is the hot tube, the automatic heating cylinder, the end of the cylinder - the end of the cartridge - the surface of the densely attached as a needle The shape of the jet hole, the inlet port of the high-pressure gas storage tank, the high pressure gas 5=3 oil pipeline is introduced into the automatic = upper (four) pressure chamber via the helium column, and the fuel injected through the mixing wheel tubing From the pot to burn 7 M435567 igniter module, the igniter module is mainly 'one and the igniter module main energy system through; electric tube fine cylinder pressure chamber ring placed heat induction spark plug to reach ^ = dynamic heating The combustible mixture gas in the ignition pressure chamber is burned, the car is not completely contained, and the exhaust gas becomes a combustible mixture gas; the combustible gas mixture in the ignition pressure chamber, a filter cartridge module, The filter; the cartridge module is mainly composed of a membrane inorganic compound) dilution tank chamber and a sedimentation tank LC (aqueous body: body: helium end system receives the introduction from the automatic heating 42;
Si内，再噴入含矽烷醇鹽之鹼金屬稀釋：稀 湾本體沉澱槽室之過筛發泡程序，最後將氣體排匕 透過利用改善鍋爐排污氣之改良結構，或右 f化器因溫度無法達到再生者’透過本創作可凌 D，俾以達到將該廢氣中殘留之CO、THC、NOx、%7疋王改 未燃燒之臟行再次完全之燃燒，並同時Ui y化态之過濾以排出於大氣中，使得排出之有 :降低至安全檢核量，藉以達到環保及淨化4維= 的，此乃本案創作人所欲解決之技術特徵目的者〔°之 【實施方式】 點;δίϋ責審4委貞方便簡捷瞭解本創狀其他特_容與優 圖i5建成之功效能夠更為顯現，茲將本創作配合參閱第一 圃、第二圖及其附圖一〜四’詳細說明如下： 尸一種智慧型固態衍生燃料（RDF; Residue Derived Fuel)濾 氧結構裝置，其至少包含： ^ 一自動加熱唧筒10，該自動加熱唧筒10其係呈一\— (上下對稱），於該自動加熱唧筒10細柱筒設有一壓力 M435567 室103，於壓力室103環側設至少一個以上之喷油孔100及熱 感應火星塞，又於該自動加熱唧筒10出口端套設一排煙淨 化器20，且於排煙淨化器20之芯蕊設有一溫度感知桿200 ，該自動加熱唧筒10細柱筒一端插設一喷氣柱，又喷氣柱 呈一中空柱桿狀，於其表面密佈附設複數個以上如針狀之 喷氣孔1020，且喷氣柱之進氣口接設來自一高壓儲氣唧筒 内之高壓氣體，藉由驅動空壓機辅助高壓泵洩壓控制閥管 控該南壓氣體經由該輸油管經由0M"氣柱導入於該自動加熱 唧筒10細柱筒壓力室103内，經混合輸油管喷入之燃油及來 自鍋爐燃燒未完全含ASR之廢氣成為可燃之混合氣氣體； 一點火器模組，該點火器模組主要包括一電子控制電 路及調節器，又該點火器模組主要能源係透過自動加熱唧 筒裝置周圍所設置之電瓶（一般汽車電瓶），利用其電瓶電 壓將該自動加熱唧筒10細柱筒壓力室103環置之熱感應火 星塞達到可點燃，藉以引燃壓力室103中之可燃混合氣氣體 ，又電子控制電路與排煙淨化器20上之溫度感知桿200成信 號感測，主要透過其觸發信號觸發熱感應火星塞點火；溫 度感知桿200，其溫度感知桿200其係感應來自該自動加熱 唧筒10細柱筒廢氣之溫度，俾當鍋爐排氣口周圍溫度過低 時，令電子控制電路觸發熱感應火星塞之點火，藉以降低 鍋爐之排廢氣受外界溫度影響，無法充份燃燒因而產生重金屬 污染； 一過濾唧筒模組，該過濾唧筒模組主要由一LC (水性 造膜性無機化合物）稀釋槽室7 0 0及一沉澱槽室7 01所組成 ，唧筒本體一進氣端係接收導入來自該自動加熱唧筒10細 柱筒之氣體，氣體經吹入唧筒本體LC (水性造膜性無機化 合物）稀釋槽室700内，再喷入含矽烷醇鹽之鹼金屬稀釋液 ，待經過唧筒本體沉澱槽室701之過篩發泡程序，最後將氣 體排出大氣中。 以下就一應用實施例提出說明： M435567 从掺混有不同比例ASR油泥所製成之RDF， 燒°c ’於分？:ϊ時間時為使廢棄物 ，二過剩空氣比設γ=4,第一段燃燒爐主要 丨 理論空氣量： :，、t爐J 2行熱解反應’:斤二在曰第一段爐内不供給空氣量 弟一 #又爐内供給4倍過剩空氣里。依 V'dr (Nm3/Kg): 1 32 24.4 02Ϊ x(2.67C -hSH —0 - 0.23CI +S) 實際空氣量： L(Nm3/Kg)= κν χ (1 + γ 燃燒每公斤廢棄物之理誨空氣量 燃燒每公斤廢棄物之實際空氣量 廢棄物中碳、氫、氧、氣、硫元素重量百分比 γ:表示過剩空氣比（Excess Air) 經鍋爐燃燒後，排送至廢氣口之ASR燃氣内含值，分別 依所提供給鍋爐之空氣比例高低而同時形成未充分燃燒 之RDF廢氣含ASR燃氣比例成等量反比，意思即：當鍋爐 内空氣值含量低於所欲燃燒RDF比值時熱效率最高，相對 的所排出含ASR廢氣之濃度亦高（不完全燃燒），如經由鍋 爐直接排出，重金屬污染性更大，因此有勢必要再經過排 放處理之步驟。於各種鍋爐燃燒條件下之C0排放濃度可 知當摻混ASR油泥比例愈高時，C0排放濃度皆超過煙道氣 體分析儀偵測極限（10000 ppm)，經複燃燒時C0排放濃 度變化趨勢。實驗結果顯示，各種燃燒條件下，CO濃度隨 悶燒時間增加而減少，CO濃度則降至35. 2 ppm以下。CO 是燃燒系統中碳氫化合物與氧反應成C〇2過程之中間產 物，當燃燒完全時，碳分子會直接與氧反應生成C〇2 : c+o2—co2 10 M435567 如果燃燒不完全時，碳分子則會與氧反應生成c〇，去 充足時再與氧反應成C〇2 : ^ 當RDF物料未在第一段燃燒爐停留而直接燃燒時，由 物料之熱解及氣化速率過快，造成燃燒不完全而產生大量的 C0。隨重複燃燒時間增加可使RDF物料在第一次燃燒爐内進 行較元全之熱解反應，讓RDF物料之可燃性成份完全揮發出 來，當與二次空氣混合後，愈能達到較完全之氧化效率， 致C0濃度下降。 ^ NOx (氣氧化物）冬生成乃取決於中間產物是被〇H、H、 〇等氧化為NO或是由NHi、N0等還原為N2，NOx濃度隨掺混 油泥比例增加而有減少趨勢，是因為Ν〇χ的產生可能是廢棄 斗勿所含氮成份所引起的，ASR之氮元素含量約為3. 14 %，且 當ASR直接燃燒時，NOx無法有足夠的時間還原成N2，而導 致NOx濃度較高，所以ASR之氮元素含量會隨著摻混油泥比 例增加而減少，相對的NOx濃度亦隨著摻混油泥比例增加而 減少。 焚化所產生之SOx主要是廢棄物中之s元素與氧分子反 應而形成，廢氣中的S02是由硫原子與氧分子反應生成，ς〇2 則主要由一氧化硫與氧分子反應生成，ASR之硫元素含量約 為0.43°/。，燃燒過程中，HC1主要是由廢棄物中C1元素經 焚化反應而形成，ASR(自動車油泥衍生廢棄物）之氣元素含 量約為3 %以下，主要來自塑膠、橡膠等含氣物質，當廢棄 物中氣含量較大時’氣化氫濃度隨溫度升高而逐尜減少，义 原因是氯氣及HC1之平衡常數隨溫度之增加而減少，此時平 11 M435567 衡常數與氧氣濃度相乘之值隨溫度升高而降低’即氣氣和 HC1比值減少，使得HC1減少，相對氯氣減少幅度更大。結 果顯示，隨著鍋爐内燃燒時間增加’可使含油泥之RDF而降 低CO、NOx、SOx及HC1的濃度。C0濃度會隨油泥摻混比例 增加而提高，NOx及HC1濃度會因油泥摻混比例增加而有減 少趨勢，SOx濃度則不受油泥摻混比例影響。燃燒溫度增加 可降低CO、SOx及HC1濃度’對SOx則無影響。整體而言， 各種燃燒條件下，CO、NOx ' SOx及HC1的濃度皆會隨著燃 燒時間、油泥摻混比例及燃燒溫度增加而有減少之趨勢，僅 有C0濃度會隨油泥摻混比例增加而增加’主要是因為含高 油泥RDF，含碳量高，易進行氧化反應，但當燃燒不完全時’ C0濃度相對增高。 鍋爐燃燒為取得最高及持續性效率’重複燃燒RDF之程 序將造成鍋爐效能輸出之等量下滑，有鑑於此’訂一次性於 鍋爐中燃燒效率最佳之燃燒環境（空燃比、燃燒溫度），將 其燃燒後所排放之廢燃氣逕導入本創作自動加熱裝置中重 新處理，藉以實現有效抑制含重金屬廢氣之排放’而達到環 保潔淨之生態控制。 上述詳細說明係針對本創作之一可行實施例之具體說 明，惟該實施例並非用以限制本創作之專利範圍，凡未脫 離本創作技藝精神所為之等效實施或變更，均應包含於本 案之專利範圍中。 為使本創作更加顯現其進步性與實用性，茲與習用作 一比較分析如下： 習用缺失 1. 僅能提供小批量處理，其後處理過濾設備過於昂責。 2. 處理設備易故障，維修成本高。 3. 無法有效解決重金屬污染源之產生。 本創作優點 12 M435567 本創作之整體結構設備，盘目前習 益，其主要用益利用部份:、歹_^$ 其異曲同功之效 卜有效提昇鎮爐效率，避免降低輪出效能。 2、 搭配性便利，適合多種環境處理。 3、 建置成本低雄修簡單。 欲辦在突破先前之技術結構下，確實已達到所 ί亲曰ϊ=ί 也非熟悉該項技藝者所易於思及，再者，本創 作申。月刖未a么開，其所具之進步性、實用性， if ί請要件，纽读提出申請，懇請貴局核i荆击專 申請案，以勵創作，至感德便。 件新型專利 【圖式簡單說明】 第一圖，本創作自動加熱唧管立體線構圖示专。 附圖一係本創作自動加熱唧管實體剖面示专^。 第二圖巧本創作LC稀釋槽室立體線構圖示^。。 附圖士，本創作LC稀釋槽室實體剖面示意^。 附圖二係本創作LC稀釋槽室+沉殿槽室實體剖_ 附圖四係本創作整體構件分解示意圖。 不思圖。 1020喷氣孔 200溫度感知桿 701沉澱槽室 【主要元件符號說明】 10自動加熱哪筒 100噴油孔 103壓力室 20排煙淨化器 700 LC稀釋槽室 13In Si, the alkali metal dilution containing decyl alkoxide is sprayed: the sifting foaming process of the thin tank body sedimentation tank chamber, and finally the gas enthalpy is passed through the improved structure for improving the boiler blowdown gas, or the right finizer is temperature-dependent. Can not reach the regenerator's through this creation can be D, in order to achieve the residual CO, THC, NOx, %7 疋 王 unburned dirty line again completely burned, and at the same time Ui y state of the filter In order to be discharged into the atmosphere, the discharge is reduced to a safe check quantity, thereby achieving environmental protection and purification of 4 dimensions =, which is the technical feature of the creator of the case ([Embodiment] point; Δίϋ Responsible for reviewing 4 committees, convenient and simple to understand the other features of the creation of the special _ 容 and excellent map i5 can be more effective, I will refer to this creation with reference to the first 第二, the second figure and its drawings 1-4 The description is as follows: The corpse is a smart solid-state derivatized fuel (RDF) oxygen-filtering structure device, which comprises at least: ^ an automatic heating cylinder 10, which is in the form of a vertical-symmetric The automatic heating 10 is arranged with a pressure M435567 chamber 103, at least one injection hole 100 and a heat-sensing spark plug are arranged on the ring side of the pressure chamber 103, and a row of smoke purifiers 20 is arranged at the outlet end of the automatic heating cylinder 10, And a temperature sensing rod 200 is disposed on the core of the exhaust gas purifier 20, and a jet column is inserted into one end of the thin cylindrical tube of the automatic heating cylinder 10, and the jet column is in the form of a hollow column, and a plurality of surfaces are densely attached on the surface thereof. The needle-shaped air hole 1020, and the air inlet of the jet column is connected to the high-pressure gas from a high-pressure gas storage cylinder, and the high-pressure pump pressure-relief control valve is driven by the driving air compressor to control the south-pressure gas via the oil pipeline. 0M" gas column is introduced into the fine cylinder pressure chamber 103 of the automatic heating cylinder 10, the fuel injected through the mixed oil pipeline and the exhaust gas from the boiler burning not completely containing ASR become a combustible mixed gas; an igniter module, the ignition The module mainly includes an electronic control circuit and a regulator, and the main energy system of the igniter module is used to automatically heat the battery (general car battery) disposed around the cylinder device, and utilize the same The voltage of the battery is ignited by the heat-sensing spark plug of the automatic heating cylinder 10, which is surrounded by the fine cylinder pressure chamber 103, thereby igniting the combustible mixture gas in the pressure chamber 103, and the electronic control circuit and the exhaust gas purifier 20 The temperature sensing rod 200 is signal sensed, mainly triggering the heat-sensing spark plug ignition through its trigger signal; the temperature sensing rod 200, the temperature sensing rod 200 thereof senses the temperature from the fine-column exhaust gas of the automatic heating cylinder 10, and the boiler When the temperature around the exhaust port is too low, the electronic control circuit triggers the ignition of the heat-sensing spark plug, thereby reducing the exhaust gas of the boiler from being affected by the external temperature, and being unable to fully burn and causing heavy metal pollution; a filter cartridge module, the filter cartridge The module is mainly composed of an LC (aqueous film-forming inorganic compound) dilution tank chamber 700 and a sedimentation tank chamber 71, and the inlet body of the cylinder body receives the gas introduced from the fine cylinder of the automatic heating cylinder 10. The gas is blown into the dilution tank chamber 700 of the cylinder body LC (aqueous film-forming inorganic compound), and then sprayed into the alkali metal dilution liquid containing decyl alkoxide, and waited After passing through the sifting foaming process of the cylinder body sedimentation tank chamber 701, the gas is finally discharged into the atmosphere. The following is an explanation of an application example: M435567 RDF made by blending different proportions of ASR sludge, burning °c' in minutes? : When the time is 使, the second excess air ratio is γ=4, the first stage combustion furnace is mainly 丨theoretical air volume: :,, t furnace J 2 row pyrolysis reaction': Jin 2 in the first stage furnace The inside does not supply air volume to the younger one and the furnace supplies 4 times excess air. According to V'dr (Nm3/Kg): 1 32 24.4 02Ϊ x(2.67C -hSH —0 - 0.23CI +S) Actual air volume: L(Nm3/Kg)= κν χ (1 + γ burning per kg of waste The actual amount of air per kilogram of waste burned by the amount of air, the weight percentage of carbon, hydrogen, oxygen, gas and sulfur in the waste γ: indicates that the excess air ratio (Excess Air) is burned by the boiler and discharged to the exhaust port. The internal value of ASR gas is inversely proportional to the ratio of the air supplied to the boiler and the proportion of the insufficiently fired RDF exhaust gas containing ASR gas, meaning that the air content in the boiler is lower than desired. The RDF ratio has the highest thermal efficiency, and the relative concentration of the discharged ASR-containing exhaust gas is also high (incomplete combustion). If it is directly discharged through the boiler, the heavy metal is more polluted, so it is necessary to go through the discharge treatment step. Under the condition of C0 emission concentration, it can be seen that when the proportion of blended ASR sludge is higher, the C0 emission concentration exceeds the detection limit of the flue gas analyzer (10000 ppm), and the C0 emission concentration changes during recombustion. The experimental results show that various Burning strip Under the condition, the CO concentration decreases with the increase of the smoldering time, and the CO concentration falls below 35.2 ppm. CO is an intermediate product of the reaction between hydrocarbons and oxygen in the combustion system to form C〇2, when the combustion is complete, carbon The molecule reacts directly with oxygen to form C〇2: c+o2—co2 10 M435567 If the combustion is incomplete, the carbon molecule will react with oxygen to form c〇, and when it is sufficient, it will react with oxygen to form C〇2: ^ When RDF When the material does not stay in the first stage of the combustion furnace and directly burns, the pyrolysis and gasification rate of the material is too fast, resulting in incomplete combustion and a large amount of C0. The RDF material can be burned for the first time as the repeated combustion time increases. The pyrolysis reaction in the furnace is carried out to completely evaporate the flammable components of the RDF material. When mixed with the secondary air, the more complete oxidation efficiency can be achieved, and the C0 concentration is lowered. ^ NOx (gas oxide) The winter production depends on whether the intermediate product is oxidized to NO by H, H, 〇 or the like, or reduced to N2 by NHi, N0, etc., and the NOx concentration decreases with the increase of the proportion of the mixed sludge. Produced may be the nitrogen content of the waste The nitrogen content of ASR is about 3.4%, and when ASR is directly burned, NOx can not have enough time to reduce to N2, which leads to higher NOx concentration, so the nitrogen content of ASR will be mixed. The proportion of mixed sludge decreases and the relative NOx concentration decreases as the proportion of mixed sludge increases. The SOx produced by incineration is mainly formed by the reaction of s elements in the waste with oxygen molecules, and the S02 in the exhaust gas is composed of sulfur atoms. It is formed by the reaction with oxygen molecules, and ς〇2 is mainly formed by the reaction of sulfur monoxide with oxygen molecules. The sulfur content of ASR is about 0.43 ° /. During the combustion process, HC1 is mainly formed by the incineration reaction of C1 element in waste. The content of gas element of ASR (automatic vehicle sludge-derived waste) is about 3% or less, mainly from gas-containing substances such as plastic and rubber. When the gas content is large, the concentration of vaporized hydrogen decreases with increasing temperature. The reason is that the equilibrium constant of chlorine and HC1 decreases with increasing temperature. At this time, the equilibrium constant of the 11 M435567 is multiplied by the oxygen concentration. The value decreases with increasing temperature', ie, the ratio of gas to HC1 decreases, resulting in a decrease in HC1 and a greater reduction in chlorine. The results show that as the combustion time in the boiler increases, the RDF of the sludge can be lowered to lower the concentrations of CO, NOx, SOx and HC1. The concentration of C0 will increase with the increase of the proportion of sludge blending. The concentration of NOx and HC1 will decrease due to the increase of the proportion of sludge blending, and the concentration of SOx will not be affected by the proportion of sludge blending. An increase in combustion temperature reduces the concentration of CO, SOx, and HC1, which has no effect on SOx. Overall, under various combustion conditions, the concentrations of CO, NOx ' SOx and HC1 will decrease with the increase of burning time, sludge blending ratio and combustion temperature. Only C0 concentration will increase with the proportion of sludge blending. The increase is mainly due to the high oil sludge RDF, high carbon content, easy to carry out oxidation reaction, but when the combustion is not complete, the C0 concentration is relatively high. Boiler combustion is the highest and lasting efficiency. The process of repeated combustion RDF will result in an equivalent decline in boiler performance output, in view of the fact that this is the best combustion environment (air-fuel ratio, combustion temperature) in the boiler. The waste gas path discharged after combustion is introduced into the automatic heating device of the present invention for reprocessing, thereby realizing effective suppression of the discharge of heavy metal-containing exhaust gas, and achieving ecological control of environmental protection and cleanliness. The detailed description of the present invention is intended to be illustrative of the preferred embodiments of the present invention, and is not intended to limit the scope of the present invention. In the scope of patents. In order to make this creation more progressive and practical, a comparative analysis is used as follows: Deficiency of use 1. It can only provide small batch processing, and then the processing equipment is too high. 2. The processing equipment is prone to failure and the maintenance cost is high. 3. It is impossible to effectively solve the problem of heavy metal pollution sources. Advantages of this creation 12 M435567 The overall structure and equipment of this creation, the current benefits of the disk, its main benefits and utilization parts: 歹 _ ^ $ The same effect of the same effect effectively improve the efficiency of the furnace, to avoid reducing the round-out efficiency. 2, the convenience of matching, suitable for a variety of environmental processing. 3, the construction cost is low and the repair is simple. In order to break through the previous technical structure, it has indeed reached the relatives = ί is not familiar with the skill of the art is easy to think, and again, this creation. The moon is not open, its progress and practicality, if ί please, and the new reading application, I ask you to apply for the nuclear attack, to encourage creation, to the sense of virtue. A new type of patent [Simple description of the figure] The first picture, this creation automatically heats the three-dimensional line structure of the manifold. Figure 1 shows the creation of an automatic heating manifold profile. The second picture is a schematic diagram of the three-dimensional line structure of the LC dilution tank. . Figure, the physical section of the LC dilution tank of this creation is shown as ^. Figure 2 is a schematic diagram of the physical dilution of the LC dilution chamber + the sink chamber. Do not think about it. 1020 jet hole 200 temperature sensing rod 701 sedimentation tank chamber [Main component symbol description] 10 automatic heating barrel 100 fuel injection hole 103 pressure chamber 20 exhaust smoke purifier 700 LC dilution tank chamber 13