五、新型說明： 【新型所屬之技術領域】 本創作係棚於-輕倾淨倾置，制是賴於—種處理惡 臭物質（如含硫化合物質）之揮發性有機廢氣的淨化裝置。 【先前技術】 台灣發明專利證書號1314472揭露—種高效能冷凝吸收與高級氧 化觸媒技術處理有機廢氣之淨化裝置與方法包括：至少一冷凝除霧 單兀及同級氧化處理單元。有機廢氣經由淨化裝置中之冷凝除霧單 凡處理後’有機廢礼令大部分揮發性有機化合物⑽S)已被冷凝吸 收’再以下游端高級氧化處理單元氧化有機廢氣中剩餘之有機物，藉 此可將有機魏中大部分之舶冷凝回收及氧化分解，同時去除有機 廢亂之惡臭。另件台灣發明專利證書號196286揭露一種高沸點有機廢 礼處理$統，主要在改變系統風管的設計，增加熱流量，使脫附區之 ’皿度刀佈㈣’以增加脫附效率。使吸附、預熱、脫附、冷卻等形成 ，續操作之高效轉輪式吸_理线。然而，所述兩件習知專利技 β或而要冷凝處理’或需要吸、脫附處理；然而對於惡臭物質(如含 化合物貝）之揮發性有機物氣體，由於該氣體具有不易吸附亦不易冷 疑W故月j述兩件習知專利技藝，均無法達到良好之處理效果。 ::創作人有鑑於上述習知技術之缺失，乃產思創作改良而改 ^上=重Γ料性有機廢氣之淨化裝置及其淨化方法，除了能夠解 決上述缺失以外，尚可將嫩中的硫化合物進—步處理，而生成新的 M404059 硫化合物來加以回收再利用。 【新型内容】 本創作的目的係提供一種淨化裝置，除了能夠將揮發性有機物之 氣體（VOCs)處理成淨化氣體以外，尚可將V0Cs中的硫化合物進一步 處理，而生成新的硫化合物來加以回收再利用。 為了達成本創作上述目的，本創作提供一種處理揮發性有機廢氣 之淨化裝置，包括：-焚化單^，連接—廢氣管與—淨氣管，其中該 廢氣管制於導人-帶有臭味轉雜錢物(如含硫化合物)之氣體 至。亥夂化單元進行焚化處理，以形成一初階淨化氣體，其中該初階淨 化氣體排人於該淨氣管；—洗滌單元，連接該淨氣管，以及係利用水 或疋水碰之活關，m賊纽自該淨氣管輸人之馳階淨化氣 杜，使知該初階淨化氣體中的含硫物質自該初階淨化氣體析出。 本創作以下列實施例進—步制，惟該實關不應限制本創作之 病’獅此項胁者於不背離本創作之範，及精神下進行合理的變 化。 【實施方式】 第1圖顯不本創作處理揮發性有機廢氣之淨化裝置的架構圖。本 創作處理揮發性有機廢氣之淨化裝置1G乃包括：—焚化單元11以及 單7L 13鉍刀別s兒明如后内文。焚化單元u乃連接廢氣管15 ’、淨礼官17,其巾廢氣管15是时導人含硫化合物的揮雜有機物之 4 M404059 氣體（VOCs)’將VOCs輸送至焚化單元11進行焚化處理，而形成初階 淨化氣體’紐馳階淨化⑽再排丨於焚化單元u，纽排入於淨 氣管171化單it 11可採用㈣f熱式焚化爐、習用f熱式觸媒焚化 爐、I用直燃式焚化爐'習用觸媒焚化爐、或是其它種類的習用焚化 爐。若採用習用雙槽式蓄熱摘媒焚碱、彡槽式蓄熱式觸媒焚化爐 或習用觸媒焚化爐時，觸媒例如可採用鉑Q5t)、鈀(pd)、或五氧化二 饥(Vi2〇5)等金屬氧化物組合。 所述揮發性有機物之氣體中的硫化合物，乃例如是硫化氫 (Hydrogen sulfide, HzS)、二甲基硫(dimethyl sulfide, DMS)、二曱 基二硫(dimethyl disulfide，DMDS)的其中一種、多種、或是其組合， 甚或是其相關衍生物、或氧化物之組合。 所述VOCs中的硫化合物’茲舉以硫化合物為例說明，⑽占 硫化合物在焚化單元11進行燃燒反應，其反應式如下： 焚化爐 C2H6S + 〇2 —> co2 + h20 + S〇2 所述GHgS硫化合物在焚化單元u進行燃燒反應後，除生成s〇2 以外，尚可能生成SO或S〇3等硫氧化合物。 所述GHeS即為惡臭物質（如含硫化合物質）的v〇Cs之範例。上述 反應式所生成的C〇2、丨丨2〇、以及s〇2等即為所述初階淨化氣體的範例。 洗蘇單元13乃連接淨氣管17 ’洗蘇單元13的功能是將初階淨化 氣體中的含硫物質，自初階淨化氣體析出。洗滌單元13利用水或是水 溶性之活性劑，來洗條及處理自淨氣管17輸入的初階淨化氣體。所述 5 水溶性之活㈣可制過氧化氫（祕）、氫氧化_aGH)、或是其它 活性劑。 茲舉以稀釋之H2〇2做為活性劑，以及含s〇2硫化合物的初階淨化氣 體為例說明’在洗務單元13進行化學紐反應，其反應式如下： on H20 S〇2 + h2o2 ----> H2S04 洗蘇早7G 13的第一入口 131是用來輸入所述水或水溶性之活性 I第一人口 133 S連接淨氣管17，導人自焚化單元u所排出的初階 …氣λϊ帛itj α 135用來輸出自淨化氣體所析出的含硫物質及水， 例如上述的硫酸(Η孤)與洗蘇處理後的水；第二出口 137是用於輸出 自初階序化氣體析出含硫物質後的無惡臭淨化氣體。自第二出口 所排出的無惡臭淨化氣體乃進—步通過職管19，而輸送至煙⑽， 排出於外界》 所述so或sa亦#在洗務單元13中，進行相對應的化學洗蘇反 j，然後，自初階淨化氣體所析出相對應的含硫物f，同樣地，會自 第一出口 135排出。 。。本創作#化裝置1〇更包括風機23，其可設置於焚化單元I〗與洗 右早π 13 4中之上办端或下游端，例如設置於廢氣管巧的一端或 排放管19的一端，或是样作,, t '〇 、 兀11 /、洗滌單元13之間，風機23可 採行單一設置或並聯設置或串 置甚或亚、串聯組合設置於淨化 裝置10中。V. New description: [New technical field] The creation system is shed--light dumping, and the system relies on a kind of purification device for volatile organic waste gas which treats odorous substances (such as sulfur compounds). [Prior Art] Taiwan Invention Patent No. 1314472 discloses a high-performance condensing absorption and advanced oxidizing catalyst technology for treating organic waste gas purification apparatus and method including: at least one condensing defogging unit and a similar oxidation treatment unit. The organic waste gas is condensed and defogged in the purification device. After the treatment, the organic volatiles (the majority of the volatile organic compounds (10) S) have been condensed and absorbed, and the organic acid remaining in the organic waste gas is oxidized by the downstream advanced oxidation treatment unit. Most of the organic Wei can be condensed and recovered and oxidized and decomposed, while removing the stench of organic waste. Another Taiwan invention patent number 196286 discloses a high-boiling organic waste treatment system, which is mainly to change the design of the system duct, increase the heat flow, and make the desorption area 'the knife cloth (4)' to increase the desorption efficiency. The adsorption, preheating, desorption, cooling, etc. are formed, and the high-efficiency rotary suction type _ line is continuously operated. However, the two conventional patents are either condensed or require condensation or desorption treatment; however, for volatile organic gases of malodorous substances (such as compound shells), the gas is not easily adsorbed and is not cold. Suspected that the two months of the patents of the two patents, can not achieve a good processing effect. :: In view of the lack of the above-mentioned prior art, the creator has improved the production and improved the purification equipment of the organic waste gas and the purification method thereof, in addition to being able to solve the above-mentioned defects, it is still possible to The sulfur compound is further processed to form a new M404059 sulfur compound for recycling. [New content] The purpose of this creation is to provide a purification device. In addition to being able to treat volatile organic compounds (VOCs) into purified gases, the sulfur compounds in V0Cs can be further processed to form new sulfur compounds. Recycling. In order to achieve the above object of the present creation, the present invention provides a purification apparatus for treating volatile organic waste gas, comprising: - incineration unit, connection - exhaust pipe and - net gas pipe, wherein the exhaust gas is controlled by a person - with an odor The gas of money (such as sulfur compounds) to. The blackening unit is incinerated to form a primary purification gas, wherein the primary purification gas is discharged into the clean air tube; the washing unit is connected to the clean air tube, and the water or the water is touched. The m thief New Zealand has purified the gas from the clean gas of the net gas pipe, so that the sulfur-containing substance in the preliminary gas is precipitated from the preliminary gas. This creation is based on the following examples, but the actual practice should not limit the disease of the creation. The lion's threatening party will make a reasonable change without departing from the scope of this creation. [Embodiment] FIG. 1 is a schematic view showing the structure of a purification apparatus for treating volatile organic waste gas. The purification apparatus 1G for processing volatile organic waste gas includes: - the incineration unit 11 and the single 7L 13 knives are as follows. The incineration unit u is connected to the exhaust pipe 15', the net ritual 17, and the towel exhaust pipe 15 is the 4 M404059 gas (VOCs) that conducts the volatile organic compounds of the sulfur compound to transport the VOCs to the incineration unit 11 for incineration. The formation of the initial purification gas 'New Chi Chi purification (10) and then drained in the incineration unit u, New Zealand into the net gas pipe 171 chemical single it 11 can be used (four) f thermal incinerator, conventional f thermal catalyst incinerator, I use Direct-fired incinerators' conventional catalytic incinerators, or other types of conventional incinerators. If a conventional double-tank regenerative extraction caustic soda, a gutter type regenerative catalytic incinerator or a conventional catalyst incinerator is used, the catalyst may be, for example, platinum Q5t), palladium (pd), or pentoxide ( Vi2〇5) and other metal oxide combinations. The sulfur compound in the gas of the volatile organic substance is, for example, one of hydrogen sulfide (HzS), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS). A variety, or a combination thereof, or even a combination of related derivatives, or oxides. The sulfur compound in the VOCs is exemplified by a sulfur compound, and (10) the sulfur compound is subjected to a combustion reaction in the incineration unit 11, and the reaction formula is as follows: Incinerator C2H6S + 〇2 -> co2 + h20 + S〇2 After the combustion reaction of the GHgS sulfur compound in the incineration unit u, in addition to the formation of s〇2, a sulfur oxide such as SO or S〇3 may be formed. The GHES is an example of v〇Cs of a malodorous substance such as a sulfur-containing compound. C 〇 2, 丨丨 2 〇, and s 〇 2 generated by the above reaction formula are examples of the preliminary purification gas. The washing unit 13 is connected to the clean air tube 17'. The function of the washing unit 13 is to precipitate the sulfur-containing substance in the preliminary purification gas from the preliminary purification gas. The washing unit 13 uses water or a water-soluble active agent to wash and treat the primary purification gas input from the clean gas pipe 17. The water-soluble activity (4) can produce hydrogen peroxide (secret), hydrogen peroxide (aGH), or other active agents. Taking the diluted H2〇2 as the active agent and the primary purification gas containing the s〇2 sulfur compound as an example, the chemical reaction in the washing unit 13 is carried out, and the reaction formula is as follows: on H20 S〇2 + H2o2 ----> H2S04 The first inlet 131 of the 7G 13 is used to input the water or the water-soluble active I first population 133 S connecting the net air pipe 17, which is discharged by the self-incineration unit u The first step...gas λϊ帛itj α 135 is used to output the sulfur-containing substance and water precipitated from the purified gas, such as the above-mentioned sulfuric acid (Η孤) and the water after the washing treatment; the second outlet 137 is used for output from the beginning. The odor-free purge gas after the stepwise gas is released from the sulfur-containing substance. The malodor-free purge gas discharged from the second outlet is passed through the service pipe 19, and is sent to the smoke (10), and discharged to the outside. The so or sa is also in the washing unit 13, and the corresponding chemical washing is performed. Su said, the corresponding sulfur-containing substance f is precipitated from the preliminary purification gas, and is similarly discharged from the first outlet 135. . . The creation device 1 further includes a fan 23, which can be disposed at the upper end or the downstream end of the incineration unit I and the washing right early π 13 4 , for example, at one end of the exhaust pipe or one end of the discharge pipe 19 For example, between the t'〇, 兀11/, and the washing unit 13, the fan 23 may be disposed in the cleaning device 10 in a single setting or in parallel or in series or even in a sub-series.
顯示本創作處理揮發性有機 廢氣之淨化處理的流程圖。本 M404059 創作處理揮發性有機航之淨域理30 75包括：提供焚化單元u的 步称301以及提供洗務單元13的步驟303，茲分別說明如后内文。步 驟301乃疋提供焚化單元u，而焚化單元u連接於廢氣管κ與淨氣 e 17以及其廢氣官15係用於導入一帶有臭味的揮發性有機物(如含 硫化合物)之氣體至焚化單元n進行焚化處理，以__淨化氣體， 接著，初階淨化氣體排入於淨氣管17。轉3〇3乃是提供_單元13, 而洗滌單元13連接淨氣管17’以及糊水或是水溶性之活性劑，來洗 條及處理自淨Μ 17輸人的該初階淨化氣體，使得該初階淨化氣體中 的含硫物質自該初階淨化氣體析出。在洗蘇單元13中，初階淨化氣體 中的含疏物質稍水或水雜之活性舰行化學反應，而生成新的硫 化合物（例如：亞硫酸、稀硫酸等溶液）。 在淨化處理30中的焚化單元U與洗蘇單元13，#皆已於上述淨 化t置10詳述’因此不另再重費。再者，本創作淨化處理3〇的較佳 實施例，乃可藉由所述的淨化裝置10而獲得支持。 本創作淨轉置10與淨化處理30除了能触揮發财機物之氣 體（VOCs)處理成淨化氣體以外，尚可將齡中的硫化合物進一步處 理’而生成新的硫化合物（例如：亞硫酸、稀硫酸等溶液）來加以回收 再利用’此即為本創作重要貢獻所在。 雖然本創作已以較佳實施例揭露如上，然其並非用以限定本創 作，任何熟習此項技藝者，在不脫離本創作之精神和範圍内，當可作 更動與_，耻本鑛之賴範㈣視_之_請專概騎界定 者為準。 7 M404059 【圖式簡單說明】 第1圖顯示本創作處理揮發性有機廢氣之淨化裝置的架構圖。 第2圖顯示本創作處理揮發性有機廢氣之淨化處理的流程圖。 【主要元件符號說明】 10 淨化裝置 11 焚化單元 13 洗滌單元 15 廢氣管 17 淨氣管 19 排放管 21 煙囪 23 風機 30 淨化處理 131第一入口 133第二入口 135第一出口 137第二出口 301 ' 303 步驟 8A flow chart showing the purification treatment of volatile organic waste gas by this creation is shown. The M404059 creation processing volatile organic route 30 75 includes: providing a step 301 of the incineration unit u and a step 303 of providing the washing unit 13, respectively, as explained later. Step 301 is to provide an incineration unit u, and the incineration unit u is connected to the exhaust pipe κ and the clean gas e 17 and its exhaust gas 15 is used to introduce a gas with a volatile organic substance (such as a sulfur-containing compound) to incineration. The unit n is incinerated to purge the gas with __, and then the preliminary purge gas is discharged into the clean gas pipe 17. Turning 3〇3 is to provide the _ unit 13, and the washing unit 13 is connected to the clean air tube 17' and the paste water or the water-soluble active agent to wash the strip and treat the initial purification gas of the self-cleaning 输 17 input, so that The sulfur-containing substance in the preliminary purification gas is precipitated from the preliminary purification gas. In the sacrificial unit 13, the active ship in the preliminary purification gas containing a little water or water is chemically reacted to form a new sulfur compound (for example, a solution such as sulfurous acid or dilute sulfuric acid). The incineration unit U and the sacrificial unit 13, # in the purification treatment 30 have been described above in detail in the above-described purification t. Therefore, no additional weight is required. Further, the preferred embodiment of the present purification treatment can be supported by the purification apparatus 10 as described. The net transposition 10 and the purification treatment 30 of the present invention can treat the sulfur compounds in the middle of the sulfur compounds in addition to the gases (VOCs) which can be used to treat the volatile substances, thereby generating new sulfur compounds (for example, sulfurous acid). , dilute sulfuric acid and other solutions to recycle and reuse 'this is the important contribution of this creation. Although the present invention has been disclosed in the above preferred embodiments, it is not intended to limit the present invention, and anyone skilled in the art can make a change and _, the shame of the mine without departing from the spirit and scope of the present creation. Lai Fan (4) _ _ _ please refer to the definition of the rider. 7 M404059 [Simple description of the diagram] Figure 1 shows the architecture of the purification device for the treatment of volatile organic waste gas. Figure 2 shows a flow chart of the purification process for the treatment of volatile organic waste gas. [Description of main components] 10 Purification device 11 Incineration unit 13 Washing unit 15 Exhaust pipe 17 Net air pipe 19 Discharge pipe 21 Chimney 23 Fan 30 Purification process 131 First inlet 133 Second inlet 135 First outlet 137 Second outlet 301 ' 303 Step 8