M353933 八、新型說明： 【新型所屬之技術領域】 本新型是有關於一種二氧化氯溶液製備裝置及其反應 器’特別是指一種能將穩定化二氧化氣溶液活化，以產製 出活化二氧化氣溶液供使用的二氧化氯溶液舉備裝置及其 反應器。 【先前技術】M353933 VIII. New description: [New technical field] The new type is related to a chlorine dioxide solution preparation device and its reactor 'in particular, it can activate a stabilized dioxide gas solution to produce a second activation The oxidizing gas solution is used for the chlorine dioxide solution holding device and the reactor thereof. [Prior Art]
近年來，有關二氧化氯（Cl〇2 )之研究與應用在國際 上疋廣受重視與推崇，尤其，二氧化氣不僅被視為是氯氣 的最佳替代者，更被公認為是最高效、環保、衛生、安全 的綠色殺菌消毒劑。 主要疋，二氧化氯是一種具有氯氣相似之刺激性氣味 的黃綠色氣體，相較具有水溶性是氣氣的5倍、氧化能力 是氯氣的2.63冑、用量少且作用快、殺菌能力較不受酸鹼 景/曰殺菌效果持續時間長、不會生成致癌物（如三氯甲 烧四氯化石反、氣驗…）、高溫下殺菌效果增強 '能有效滅 示、、菌/ ¥類/孢子/病毒...等特點。故目前，二氧化氣以被用 作為水處理劑、食品保鮮劑、漂白劑、防腐劑與除臭劑， 並廣泛應用在工業廢水處理、給水處理、食品業、造紙業 $療領域（如器械/患部之消毒、沖洗，病房空氣消毒， 病毒殺滅）、衛生防疫方面、畜牧養殖業..等。 不過’二氧化氯於水溶液中是相當不穩定的，且且有 易揮發、易爆料特性，難以儲存、運輸，故通常必須是 立即配製、立即使用。因此，市面上二氧化氯的產品主要 5 M353933 有穩定型二氧化氯溶液，與雙試劑型固體製劑等兩種；以 穩定型二氧化氣溶液來說，是指將二氧化氣氣體穩定吸收 於碳酸鈉（NasCCh)、硼酸鈉（Na2B4〇7.10H2O)、過氧化氫 (Η"2)或氫氧化鈉（Na〇H)等溶液中，以讓二氧化氯以 亞氣酸鹽（C102 )型態存在者，所以，穩定型二氧化氯溶- 液於使用前必須經由活化/酸化，才能呈現出二氧化氣的高 效氧化能力；另外，以雙試劑型固體製劑來說，同樣是一- 為含有亞氯酸鹽者，另一是有機酸或無機酸者，將兩種試. 劑投加入適當水溶液中，便能製得活化二氧化氯溶液供使鲁 用0 有鑑於此，本案申請人乃研發出一種自動化操作設備 ，主要是將穩定化二氧化氯溶液予以加酸活化，以能自動 化地連續產f出面濃度且高效能之活化二氧化氯溶液供使 用’且能兼具極高的操作安全性。 【新型内容】 因此本新型之目的，即在提供一種能自動化地連續 產製出高濃度、高效能之活化二氧化氣溶液供使用的二氧籲 化氯合液裝備裝置，及用以使穩定化二氧化氯溶液酸化而 生成-氧化氯氣體之該二氧化氯溶液製備裝置的反應器。 於疋，本新型之二氧化氯溶液製備裝置，是能將一原-料液與-活化液混合，以反應生成一活化二氧化氯溶液供-使用該一氧化氯洛液製傷裝置包含一用以儲存並供應該 原料液的原料液桶、一用以儲存並供應該活化液的活化液 桶、—反應器’以及-連接該反應器的吸收器。該反應器 6 M353933 包括-連接該原料液桶與該活化液桶且供該原料液與該活 化液混合以反應生成一二氧化氯氣體輸出的玻璃器體，以 及多數容置在該玻璃器體中的攪拌珠。該吸收器是用以讓 來自該反應器之二氧化氯氣體充分溶解於水中而形成該活 化二氧化氣溶液。 本新型之功效在於，利用該原料液桶、該活化液桶、 該反應器與該吸收器等結構配置設計，整體能產生將穩定 化二氧化氯溶液活化，以自動化地連續產製出高濃度、高 效月b之活化一氧化氯溶液供使用的功效。 【實施方式】 有關本新型之前述及其他技術内容、特點與功效，在 以下配合參考圖式之一個較佳實施例的詳細說明中，將可 清楚的呈現。 如圖1〜圖3所示，本新型之二氧化氣製備裝置的該較 佳實施例，是能將一原料液與一活化液混合以反應生成一 一氧化氣氣體（Cl〇2(g))，再使二氧化氣氣體溶解、吸收於 水中，便能製成一活化（actived)二氧化氯溶液以供使用 °本實施例中，該原料液是重量百分濃度為80%以上的穩 定化（Stabilized )二氧化氯溶液，指的是將二氧化氣氣體 穩定吸收於碳酸鈉（Na2C〇3 )溶液中（或是硼酸鈉（ Na2B4(V1〇H2〇)、過氧化氫（h2〇2)、氫氧化鈉（Na〇H) 等溶液）’讓二氧化氣以亞氣酸鹽（Cl〇r，如NaC102)型 態存在者；另外’該活化液是鹽酸（HC1 )，也可以是檸檬 酸（C6H8〇7)、硫酸（H2s〇4) _.·等。 M353933 _二氧化氯溶液製備裝置是包含一用以儲存並定時定 量地提供該原料液的原料液桶1、一用以儲存並定時定量地 提供該活化液的活化液桶2、一連接該原料液桶1與該活化 液桶2的反應器3、一連接該反應器3的吸收器4、一連接 該吸收器4的儲備桶5、一監測單元6，以及一加壓單元7 該反應器3包括一連接該原料液桶1、該活化液桶2與 該吸收器4的玻璃器體31、二上下相間隔地設置在該玻璃 體31中之多孔性的支樓隔板32，以及多數疊置在該玻璃 器體31中且充填在該二支撐隔板32之間的授拌珠33。本 實施例中，支撐隔板32的數量是二個，當然也可以只有下 方之支樓隔板32者即可，便足以支樓檀拌珠33而使其疊 置於其上。 該二支撐隔板32使該玻璃器體31内部由上往下地依 序具有一連通該原料液桶1、該活化液桶2與該吸收器4的 上層空間34、一供該多數攪拌珠33充填其中的中層空間 35,以及一下層空間36,所以，上方的支撐隔板32是位在 該上、中層空間34、35之間’而下方的支撐隔板32是位 在該中、下層空間35、36之間。本實施例中，攪拌珠33 是玻璃材質製成，當然也可以是陶瓷材質製成，主要具有 不參與化學反應的特性。 因此，當供自於該原料液桶i之原料液（即NaCi〇2) 與供自於該活化液桶2之活化液（即HC1) 一併注進入該域 璃器體31之上層空間34中後，會迅速地繼續往下流進aIn recent years, the research and application of chlorine dioxide (Cl〇2) has been widely recognized and respected in the world. In particular, dioxide gas is not only regarded as the best substitute for chlorine, but also recognized as the most efficient. Environmentally friendly, hygienic and safe green disinfectant. Mainly, chlorine dioxide is a yellow-green gas with a similar pungent odor of chlorine. It is 5 times more water-soluble than gas, and its oxidation capacity is 2.63 氯 of chlorine. It is used in a small amount and has a fast effect and bactericidal ability. It is not affected by the acid-base effect and long-lasting bactericidal effect, and does not produce carcinogens (such as trichloromethane, tetrachloride, anti-gas test, etc.), and the sterilization effect is enhanced at high temperature, which can effectively extinguish the display, bacteria / ¥ / spore / virus ... and other characteristics. Therefore, at present, dioxide is used as a water treatment agent, food preservative, bleach, preservative and deodorant, and is widely used in industrial wastewater treatment, water treatment, food industry, paper industry, such as equipment. / disinfection, washing of the affected part, air disinfection of the ward, virus killing), health and epidemic prevention, animal husbandry, etc. However, 'chlorine dioxide is quite unstable in aqueous solution, and it has volatile and explosive properties, and it is difficult to store and transport. Therefore, it must be prepared immediately and used immediately. Therefore, the products of chlorine dioxide on the market mainly 5 M353933 have stable chlorine dioxide solution, and two kinds of solid preparations, etc.; in the case of stable dioxide gas solution, it means stable absorption of sulfur dioxide gas. Sodium carbonate (NasCCh), sodium borate (Na2B4〇7.10H2O), hydrogen peroxide (Η2) or sodium hydroxide (Na〇H) in a solution such that the chlorine dioxide is a gas sulfite (C102) type. The state exists, therefore, the stable chlorine dioxide solution must be activated/acidified before use to exhibit the high oxidation capacity of the dioxide gas; in addition, in the case of the two-agent solid preparation, the same is For those who have chlorite and another organic or inorganic acid, the two reagents can be added to a suitable aqueous solution to prepare an activated chlorine dioxide solution for use. Therefore, the applicant of this case It has developed an automatic operation equipment, which mainly activates the stabilized chlorine dioxide solution with acid to automatically produce the continuous concentration of the surface and the high-efficiency activated chlorine dioxide solution for use' and can be extremely high. Operational safety . [New content] Therefore, the object of the present invention is to provide a device for automatically producing a high-concentration, high-efficiency activated dioxide gas solution for use in an automated manner, and for stabilizing The chlorine dioxide solution is acidified to form a reactor of the chlorine dioxide gas-producing chlorine dioxide solution preparation device. Yu Yu, the novel chlorine dioxide solution preparation device is capable of mixing a raw material liquid and an activation liquid to react to form an activated chlorine dioxide solution for use - the use of the chlorine monoxide liquid damage device comprises a a raw material tank for storing and supplying the raw material liquid, an activated liquid tank for storing and supplying the activated liquid, a reactor, and an absorber connected to the reactor. The reactor 6 M353933 includes a glass body connecting the raw material liquid tank and the activation liquid tank and mixing the raw material liquid and the activation liquid to react to generate a chlorine dioxide gas output, and most of the glass body is accommodated in the glass body Stirring beads in. The absorber is for forming the activated dioxide gas solution by allowing the chlorine dioxide gas from the reactor to be sufficiently dissolved in water. The utility model has the advantages that the raw material liquid barrel, the activation liquid barrel, the reactor and the absorber and the like have the structural arrangement design, and the whole can generate the stabilized chlorine dioxide solution to automatically produce the high concentration continuously. Efficient monthly b activation of chlorine dioxide solution for use. The above and other technical contents, features and effects of the present invention will be apparent from the following detailed description of the preferred embodiments. As shown in FIG. 1 to FIG. 3, in the preferred embodiment of the present invention, a raw material liquid can be mixed with an activation liquid to react to form a mono-oxidation gas (Cl〇2(g). ), the gas is dissolved and absorbed in water, and an active chlorine dioxide solution can be prepared for use. In the present embodiment, the raw material liquid is stable at a concentration of 80% by weight or more. Stabilized chlorine dioxide solution refers to the stable absorption of sulfur dioxide gas in sodium carbonate (Na2C〇3) solution (or sodium borate (Na2B4 (V1〇H2〇), hydrogen peroxide (h2〇2) ), sodium hydroxide (Na〇H) and other solutions) 'Let the dioxide gas exist in the form of sulfite (Cl〇r, such as NaC102); otherwise 'the activation liquid is hydrochloric acid (HC1), it can also be Citric acid (C6H8〇7), sulfuric acid (H2s〇4) _.·, etc. M353933 _ chlorine dioxide solution preparation device is a raw material liquid tank 1 for storing and periodically providing the raw material liquid, An activation liquid tank 2 for storing and periodically providing the activation liquid, and a raw material liquid tank 1 and the activation liquid a reactor 3 of 2, an absorber 4 connected to the reactor 3, a reserve tank 5 connected to the absorber 4, a monitoring unit 6, and a pressurizing unit 7. The reactor 3 includes a tank for connecting the raw material 1. The activation liquid tank 2 is disposed in the glass body 31 of the absorber 4, and the porous branch partition 32 disposed in the glass body 31 at a distance from the upper and lower sides, and a plurality of stacked in the glass body 31 And the mixing beads 33 are filled between the two supporting partitions 32. In this embodiment, the number of the supporting partitions 32 is two, and of course, only the lower branch partition 32 can be used, which is enough to support The two supporting baffles 33 are stacked thereon. The two supporting partitions 32 sequentially connect the interior of the glass body 31 from top to bottom with a communication liquid tank 1, the activation liquid tank 2 and the absorption. The upper space 34 of the device 4, the middle space 35 in which the plurality of stirring beads 33 are filled, and the lower space 36, so that the upper supporting partition 32 is located between the upper and middle spaces 34, 35' The lower support partition 32 is located between the middle and lower spaces 35, 36. In this embodiment, the stirring beads 33 Made of glass material, of course, can also be made of ceramic material, mainly having the characteristics of not participating in chemical reaction. Therefore, when the raw material liquid (ie, NaCi〇2) supplied from the raw material liquid tank i is supplied from the activation liquid After the activation liquid of the barrel 2 (i.e., HC1) is injected into the upper space 34 of the field body 31, it will continue to flow down a quickly.
M353933 該中層空間35内，並在存有攪拌珠33而提供足夠接觸面 積與停留時間的系統環境中充分混合以進行化學反應，生 成大量—氧化氯氣體，其中所涉反應機制如下列方程式所 示： 5NaCl〇2+4HCl— 4C102+5NaCl+2H20 而所生成二氧化氯氣體會迅速向上竄升入並積存在該上層 二間34中，隨後再被抽送入該吸收器4。當然，上述反應 過程中所產生的其他終端產物，會定期地被從該下層空間 36中清除出。 該吸收4是連接該反應器3之上層空間34，本實施 例中，該吸收器4是-吸入器（1咖叫，有關吸入器的結構 與原理乃該技_域巾具㈣常知識者所熟知，不再詳述 。簡單來說，利用該吸收器4之進、出口處的水流壓力差 所生真工吸力’將該反應器3所生成的二氧化氯氣體抽吸 該吸收器4中’加上一氧化氯氣體易溶於水且不水解的 特性’能讓二氧化氯氣體與在該吸收器4内流動的吸收水 體充分混合並溶解、吸收於水中，以形成活化二氧化氯溶 液，隨後再予輸送㈣儲_ 5中暫細定時定量地供應 使用。 該監測單元6是包括三分別用以偵測該原料液桶！、該 活化液桶2與該儲備桶5之液位變化的液位計 61、一用以 偵測該儲備桶5中之活化 氧化還原電位計62、一連接該儲備桶 位計62控制啟閉的稀釋水供應件63 ； 二氧化氯溶液之氧化還原電位的 5且受該氧化還原電 以及一用以將該儲備 M353933 :二中之t化二氧化氯溶液迴流入該吸收器4中且受該氧 J'、電位计62控制啟閉的循環吸收系64。主要是，利用 Π"還原電位計62偵測該儲備桶5中之活化二氧化氯溶 、、化還原電位值（〇RP值），能藉此得知所製得活化二氧 化乳溶液中所含二氧化氯濃度及其氧化能力是否符合使用 需求：當該氧化還原電位計62測知該活化二氧化氯溶液之 值k低時，便會控制該循環吸收粟Μ啟動（此時該稀 釋水供應件63是呈關蘭彳，胺# ^ # 疋呈關閉）將該館備桶5中的活化二氧化氯 溶液抽出並迴流至該吸收器4中，以能再溶解、吸收足量 的二氧化氯氣體；而當該氧化還原電位計62測知該活化二 氧化氯溶液之〇RP值過高時’料控制該稀釋水供應件Μ 啟動(此時該循環吸收泉64 {呈關閉)，將適當純水量補充 入該儲備桶5 t，以稀釋其中的活化二氧化氯溶液；藉以 ，能確保自該儲備_ 5輸出以供使用之該活化二氧化氣溶 液的瓣值（代表其氧化能力），是符合使用需求且安全益 虞。 該加壓單元7包括一用以將該原料液桶i中之原料液 定時定量地抽送至該反應器3之上層空間34中的原料液果 71、-用以將該活化液桶2中之活化液定時定量地抽送至 該反應器3之上層空間34中的活化液i 72，以及—用以將 該儲備桶5中之活化二氧化氯溶液定時定量地抽送出以供 立即使用的供應泵73。 因此’利賴原料液桶丨、該活化液桶2、該反應器3 、該吸收器4、該儲備桶5與該加壓單元7等能將原料液與 10 M353933 活化液混合、反應，以連續產製出活化二氧化氯溶液，配 合該監測單元6能確保整個反應系統之穩定、安全，以及 所產製活化二氧化氣溶液之品質效能，讓整體能產生自動 化連續產製出高濃度、高效能之活化二氧化氯溶液以供使 用且知作安全性佳等功效。 歸納上述’本新型之二氧化氯製備裝置，整體能產生 自動化連續產製出兩濃度、高效能之活化二氧化氯溶液以 • 供使用的效果，故確實能達到本新型的功效。 * 惟以上所述者，僅為本新型之較佳實施例而已，當不 能以此限定本新型實施之範圍，即大凡依本新型申請專利 範圍及新型說明内容所作之簡單的等效變化與修飾，皆仍 屬本新型專利涵蓋之範圍内。 【圖式簡單說明】 圖1是一結構配置示意圖，說明本新型之二氧化氯溶 液製備裝置的一較佳實施例； 圖2疋一剖視示意圖，說明該較佳實施例之一反應器 ® 的結構；以及 圖3是該較佳實施例的一反應流程圖。 11 M353933 【主要元件符號說明】 1 .... .原料液桶 6 ... .監測單元 2 ···, .活化液桶 61 . .液位計 3 .反應器 62 . .氧化還原電位計 31.· .玻璃器體 63 . .稀釋水供應件 32.. .支撐隔板 64 . .循環吸收泵 33·· .攪拌珠 7 ... .加壓單元 34·· .上層空間 71 . .原料液果 35…中層空間 72 . .活化液泵 3 6...下層空間 73 · .供應泵 4 ... .吸收器 5 .儲備桶 12M353933 is in the intermediate space 35 and is thoroughly mixed in a system environment where the stirring beads 33 are provided to provide sufficient contact area and residence time to carry out a chemical reaction to generate a large amount of chlorine oxide gas, wherein the reaction mechanism is as shown in the following equation : 5NaCl〇2+4HCl-4C102+5NaCl+2H20 The generated chlorine dioxide gas is rapidly ascended upward and accumulated in the upper two compartments 34, and then pumped into the absorber 4. Of course, other end products produced during the above reaction are periodically removed from the lower space 36. The absorption 4 is connected to the upper space 34 of the reactor 3. In the present embodiment, the absorber 4 is an inhaler (1 coffee bar, the structure and principle of the inhaler is the skill of the domain) As is well known, it will not be described in detail. Briefly, the chlorine dioxide gas generated by the reactor 3 is sucked into the absorber 4 by the difference in water flow pressure at the inlet and outlet of the absorber 4. The 'addition of chlorine monoxide gas is easily soluble in water and does not hydrolyze characteristics' enables the chlorine dioxide gas to be thoroughly mixed with the absorption water flowing in the absorber 4, dissolved and absorbed in water to form activated chlorine dioxide. The solution is then re-delivered (4) in the storage _ 5 for temporary fine-time quantitative supply. The monitoring unit 6 includes three for detecting the raw material liquid tank, the liquid level of the activation liquid tank 2 and the storage tank 5 a varying level gauge 61, a activated redox potentiometer 62 for detecting the reserve tank 5, a dilution water supply member 63 connected to the reserve barrel gauge 62 for controlling opening and closing; and a redox reaction of the chlorine dioxide solution 5 of the potential and subject to the redox electricity The reserve M353933: the second-staged chlorine dioxide solution is refluxed into the absorber 4, and is controlled by the oxygen J' and the potentiometer 62 to open and close the circulating absorption system 64. Mainly, the Π" reduction potentiometer 62 is utilized. Detecting the activated chlorine dioxide dissolved and the reduction potential value (〇RP value) in the storage tank 5, can thereby know whether the concentration of chlorine dioxide contained in the activated oxidized milk solution and its oxidizing ability are In accordance with the use requirement: when the redox potentiometer 62 detects that the value of the activated chlorine dioxide solution is low, it will control the cycle to absorb the miller start (at this time, the dilution water supply member 63 is Guanlan, amine) # ^ # 疋 关闭 closed) The activated chlorine dioxide solution in the library 5 is withdrawn and returned to the absorber 4 to re-dissolve and absorb a sufficient amount of chlorine dioxide gas; and when the redox potential When it is determined that the 〇 RP value of the activated chlorine dioxide solution is too high, the material controls the dilution water supply member Μ to start (at this time, the circulation absorption spring 64 is closed), and the appropriate pure water amount is added to the storage tank 5 t to dilute the activated chlorine dioxide solution therein; thereby, It is ensured that the valve value (representing its oxidizing ability) of the activated dioxide gas solution for output from the reserve _ 5 is in accordance with the use requirement and is safe. The pressurizing unit 7 includes a barrel for the raw material. The raw material liquid in i is quantitatively pumped to the raw liquid fruit 71 in the upper space 34 of the reactor 3, for quantitatively pumping the activation liquid in the activated liquid tank 2 to the upper space of the reactor 3 The activation liquid i 72 in 34, and the supply pump 73 for periodically and quantitatively pumping the activated chlorine dioxide solution in the reserve tank 5 for immediate use. Therefore, the 'lire raw material liquid barrel 丨, the activation liquid The barrel 2, the reactor 3, the absorber 4, the reserve tank 5, the pressurizing unit 7 and the like can mix and react the raw material liquid with the 10 M353933 activating liquid to continuously produce an activated chlorine dioxide solution, and the same The monitoring unit 6 ensures the stability and safety of the entire reaction system and the quality performance of the activated dioxide gas solution, so that the whole can automatically produce a high concentration and high efficiency activated chlorine dioxide solution for use. know Good security and other effects. In summary, the above-mentioned chlorine dioxide preparation device of the present invention can automatically produce a two-concentration, high-performance activated chlorine dioxide solution for use in an overall manner, so that the efficacy of the present invention can be achieved. * The above is only the preferred embodiment of the present invention, and the scope of the present invention cannot be limited thereto, that is, the simple equivalent change and modification made by the novel patent application scope and the new description content. , are still within the scope of this new patent. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic structural view showing a preferred embodiment of a chlorine dioxide solution preparation apparatus of the present invention; FIG. 2 is a cross-sectional view showing a reactor of the preferred embodiment. Structure; and Figure 3 is a reaction flow diagram of the preferred embodiment. 11 M353933 [Explanation of main component symbols] 1 ..... Raw material liquid tank 6 ... . Monitoring unit 2 ···, . Activation liquid tank 61 . Level gauge 3 .Reactor 62 . . Oxidation reduction potentiometer 31.·. Glass body 63. Dilution water supply member 32.. Support spacer 64. Circulating absorption pump 33··. Stirring bead 7 .... Pressurizing unit 34·· . Upper space 71 . Raw liquid fruit 35... middle space 72. Activated liquid pump 3 6... lower space 73 · Supply pump 4 ... . Absorber 5 . Reserve barrel 12