TWI837178B - Method for manufacturing electronic device - Google Patents
Method for manufacturing electronic device Download PDFInfo
- Publication number
- TWI837178B TWI837178B TW108133490A TW108133490A TWI837178B TW I837178 B TWI837178 B TW I837178B TW 108133490 A TW108133490 A TW 108133490A TW 108133490 A TW108133490 A TW 108133490A TW I837178 B TWI837178 B TW I837178B
- Authority
- TW
- Taiwan
- Prior art keywords
- electronic component
- laminate film
- adhesive
- resin layer
- adhesive laminate
- Prior art date
Links
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 71
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Images
Abstract
Description
本發明是有關於一種電子裝置的製造方法。 The present invention relates to a method for manufacturing an electronic device.
電子裝置的製造步驟中,為了對電子零件賦予電磁波屏蔽性,有時進行如下步驟,即於利用保護膜等保護電子零件的電路形成面的狀態下於電子零件的表面形成電磁波屏蔽層。藉此,可對電子零件賦予電磁波屏蔽性,可阻斷自電子零件產生的電磁波雜訊。藉此,可抑制電子零件對周邊的其他電子零件造成不良影響。 In the manufacturing process of electronic devices, in order to provide electromagnetic wave shielding properties to electronic components, the following step is sometimes performed, that is, an electromagnetic wave shielding layer is formed on the surface of the electronic component while the circuit forming surface of the electronic component is protected by a protective film or the like. In this way, electromagnetic wave shielding properties can be provided to the electronic component, and electromagnetic wave noise generated by the electronic component can be blocked. In this way, the electronic component can be prevented from causing adverse effects on other surrounding electronic components.
與所述電子零件的電磁波屏蔽性相關的技術例如可列舉專利文獻1(國際公開第2010/029819號手冊)中記載者。 Technologies related to the electromagnetic wave shielding properties of the electronic components can be cited, for example, as described in Patent Document 1 (International Publication No. 2010/029819).
[現有技術文獻] [Prior art literature]
[專利文獻] [Patent Literature]
專利文獻1:國際公開第2010/029819號手冊 Patent document 1: International Publication No. 2010/029819
根據本發明者等人的研究,關於具有電磁波屏蔽性的電子裝 置的製造方法,發現了如下課題。 According to the research conducted by the inventors of the present invention, the following issues have been discovered regarding the manufacturing method of electronic devices with electromagnetic wave shielding properties.
首先,本發明者等人發現,於先前的電子裝置的製造方法中,如圖3所示,於利用電路形成面保護用膠帶130保護電子零件100的電路形成面100A的狀態下在電子零件100的表面形成電磁波屏蔽層140的情況下,有時於電子零件100的側面的下端部150不會形成電磁波屏蔽層140。該情況下,電子零件100的電磁波屏蔽性差。
First, the inventors and others found that in the previous method of manufacturing electronic devices, as shown in FIG. 3, when the electromagnetic
本發明者等人基於所述見解進一步進行研究,結果發現如圖3所示,於將貼附於切割膠帶120上的電子零件100再排列於電路形成面保護用膠帶130時,有時電路形成面保護用膠帶130的與電子零件100的側面的下端部150相接的部分(黏著性層)凸起而覆蓋電子零件100的側面的下端部150。即,根據本發明者等人的研究,明確了電子零件100的側面的下端部150由構成電路形成面保護用膠帶130的黏著性層的黏著劑160覆蓋,因此於電子零件100的側面的下端部150不會形成電磁波屏蔽層140。
The inventors of the present invention have conducted further research based on the above-mentioned viewpoints, and found that as shown in FIG3, when the
另外,關於具有電磁波屏蔽性的電子裝置的製造方法,如圖3所示,將電子零件100貼附於背面研磨膠帶110上而進行背面研磨步驟,繼而將電子零件100自背面研磨膠帶110剝落後貼附於切割膠帶120上而進行切割步驟,繼而將電子零件100自切割膠帶120剝落後再排列於電路形成面保護用膠帶130上而進行電磁波屏蔽層形成步驟。因此,先前的電子裝置的製造方法中,使用3種用以暫時固定電子零件100的膠帶,且包括將電子零件
100貼附於各膠帶上的步驟或將電子零件100自各膠帶剝落的步驟等,步驟數非常多。
In addition, regarding the manufacturing method of an electronic device with electromagnetic wave shielding properties, as shown in Figure 3, the
即,本發明者等人發現,於具有電磁波屏蔽性的電子裝置的製造方法中,就於電子零件上良好地形成電磁波屏蔽層且縮短電子裝置的製造步驟的觀點而言,存在改善的餘地。 That is, the inventors and others have found that in the manufacturing method of electronic devices with electromagnetic wave shielding properties, there is room for improvement from the perspective of forming an electromagnetic wave shielding layer on electronic parts well and shortening the manufacturing steps of the electronic device.
本發明是鑒於所述情況而形成,提供一種電子裝置的製造方法,其可於電子零件上良好地形成電磁波屏蔽層且可縮短電子裝置的製造步驟。 The present invention is formed in view of the above situation and provides a method for manufacturing an electronic device, which can form an electromagnetic wave shielding layer on the electronic parts well and shorten the manufacturing steps of the electronic device.
本發明者等人為了達成所述課題而反覆進行銳意研究。結果發現藉由於準備具備進行了半切割的電子零件的結構體的步驟、背面研磨步驟、全切割步驟及電磁波屏蔽層形成步驟中使用相同的黏著性積層膜作為保護電子零件的電路形成面的膜,可省略將電子零件貼附於各膠帶上的步驟或將電子零件自各膠帶剝落的步驟等的一部分,進而可抑制電子零件的側面的下端部中的電磁波屏蔽層的形成不良,從而完成了本發明。 The inventors of the present invention have repeatedly conducted intensive research to achieve the above-mentioned topic. As a result, they found that by using the same adhesive multilayer film as a film for protecting the circuit forming surface of the electronic component in the steps of preparing a structure with half-cut electronic components, the back grinding step, the full cutting step, and the electromagnetic wave shielding layer forming step, a part of the step of attaching the electronic component to each tape or the step of peeling the electronic component from each tape can be omitted, thereby suppressing the poor formation of the electromagnetic wave shielding layer at the lower end of the side of the electronic component, thereby completing the present invention.
根據本發明,提供以下所示的電子裝置的製造方法。 According to the present invention, a method for manufacturing an electronic device as shown below is provided.
[1] [1]
一種電子裝置的製造方法,其依次包括:步驟(A),準備具備電子零件與黏著性積層膜的結構體,所述電子零件具有電路形成面且進行了半切割,所述黏著性積層膜具有基材層及黏著性樹脂層,且以保護所述電路形成面的方式將 所述黏著性樹脂層側貼附於所述電子零件的所述電路形成面;步驟(B),於貼附於所述黏著性積層膜的狀態下,對與所述電子零件的所述電路形成面為相反側的面進行背面研磨;步驟(C),於貼附於所述黏著性積層膜的狀態下,對所述電子零件進行全切割;以及步驟(D),於貼附於所述黏著性積層膜的狀態下,於經單片化的所述電子零件上形成電磁波屏蔽層,於所述步驟(A)、所述步驟(B)、所述步驟(C)及所述步驟(D)中,使用同一黏著性積層膜作為所述黏著性積層膜。 A method for manufacturing an electronic device, comprising: step (A), preparing a structure having an electronic component and an adhesive laminate film, wherein the electronic component has a circuit forming surface and is half-cut, the adhesive laminate film has a base layer and an adhesive resin layer, and the adhesive resin layer is attached to the circuit forming surface of the electronic component in a manner to protect the circuit forming surface; step (B), in a state of being attached to the adhesive laminate film, The circuit forming surface of the electronic component is back-grinded on the surface opposite to the circuit forming surface; step (C), fully cutting the electronic component while being attached to the adhesive laminate film; and step (D), forming an electromagnetic wave shielding layer on the singulated electronic component while being attached to the adhesive laminate film. In the steps (A), (B), (C) and (D), the same adhesive laminate film is used as the adhesive laminate film.
[2] [2]
如所述[1]所述的電子裝置的製造方法,其中所述步驟(A)包括:步驟(A1),對具有電路形成面的電子零件進行半切割,繼而於進行了半切割的所述電子零件的所述電路形成面上貼附所述黏著性積層膜;或者步驟(A2),於具有電路形成面的電子零件的所述電路形成面上貼附所述黏著性積層膜,繼而對貼附於所述黏著性積層膜上的所述電子零件進行半切割。 The method for manufacturing an electronic device as described in [1], wherein the step (A) comprises: step (A1), half-cutting the electronic component having a circuit forming surface, and then attaching the adhesive laminate film to the circuit forming surface of the half-cut electronic component; or step (A2), attaching the adhesive laminate film to the circuit forming surface of the electronic component having a circuit forming surface, and then half-cutting the electronic component attached to the adhesive laminate film.
[3] [3]
如所述[1]或[2]所述的電子裝置的製造方法,其中所述黏著性積層膜於所述基材層與所述黏著性樹脂層之間進一步具有凹凸吸收性樹脂層。 The method for manufacturing an electronic device as described in [1] or [2], wherein the adhesive laminate film further has a concave-convex absorptive resin layer between the substrate layer and the adhesive resin layer.
[4] [4]
如所述[3]所述的電子裝置的製造方法,其中於所述步驟(A)與所述步驟(D)之間進一步包括步驟(E),所述步驟(E)是藉由使所述凹凸吸收性樹脂層交聯而提高所述凹凸吸收性樹脂層的耐熱性。 The method for manufacturing an electronic device as described in [3] further includes a step (E) between the step (A) and the step (D), wherein the step (E) is to improve the heat resistance of the concave-convex absorbent resin layer by cross-linking the concave-convex absorbent resin layer.
[5] [5]
如所述[3]或[4]所述的電子裝置的製造方法,其中所述凹凸吸收性樹脂層包含交聯性樹脂。 A method for manufacturing an electronic device as described in [3] or [4], wherein the concavoconvex absorptive resin layer comprises a cross-linking resin.
[6] [6]
如所述[3]至[5]中任一項所述的電子裝置的製造方法,其中所述凹凸吸收性樹脂層的厚度為10μm以上且1000μm以下。 A method for manufacturing an electronic device as described in any one of [3] to [5], wherein the thickness of the concavoconvex absorptive resin layer is greater than 10 μm and less than 1000 μm.
[7] [7]
如所述[1]至[6]中任一項所述的電子裝置的製造方法,其中於所述步驟(D)後進一步包括步驟(F),所述步驟(F)是將所述電子零件與所述黏著性積層膜剝離。 The method for manufacturing an electronic device as described in any one of [1] to [6], further comprising a step (F) after the step (D), wherein the step (F) is to peel the electronic component from the adhesive laminate film.
[8] [8]
如所述[7]所述的電子裝置的製造方法,其中於所述步驟(F)中,於使所述黏著性積層膜中的貼附有所述電子零件的區域於膜的面內方向上擴張,使鄰接的所述電子零件間的間隔擴大的狀態下,自所述黏著性積層膜剝離所述電子零件。 The method for manufacturing an electronic device as described in [7], wherein in the step (F), the electronic component is peeled off from the adhesive laminate film while the area of the adhesive laminate film to which the electronic component is attached is expanded in the in-plane direction of the film to expand the interval between adjacent electronic components.
[9] [9]
如所述[1]至[8]中任一項所述的電子裝置的製造方法,其中 所述電子零件的所述電路形成面包含凸塊電極。 A method for manufacturing an electronic device as described in any one of [1] to [8], wherein the circuit forming surface of the electronic component includes a bump electrode.
[10] [10]
如所述[9]所述的電子裝置的製造方法,其中於將所述凸塊電極的高度設為H[μm]且將所述凹凸吸收性樹脂層的厚度設為d[μm]時,H/d為0.01以上且1以下。 The method for manufacturing an electronic device as described in [9], wherein when the height of the bump electrode is set to H [μm] and the thickness of the uneven absorptive resin layer is set to d [μm], H/d is greater than 0.01 and less than 1.
[11] [11]
如所述[1]至[10]中任一項所述的電子裝置的製造方法,其中所述步驟(D)中,使用選自濺鍍法、蒸鍍法、噴塗法、電鍍法及非電鍍法中的至少一種方法而於所述電子零件上形成所述電磁波屏蔽層。 The method for manufacturing an electronic device as described in any one of [1] to [10], wherein in the step (D), the electromagnetic wave shielding layer is formed on the electronic component using at least one method selected from sputtering, evaporation, spraying, electroplating and non-electroplating.
[12] [12]
如所述[1]至[11]中任一項所述的電子裝置的製造方法,其中所述步驟(D)中,至少於所述電子零件中的與所述電路形成面對向的對向面以及連接所述電路形成面與所述對向面的側面形成所述電磁波屏蔽層。 A method for manufacturing an electronic device as described in any one of [1] to [11], wherein in step (D), the electromagnetic wave shielding layer is formed on at least the opposing surface of the electronic component that is opposite to the circuit forming surface and the side surface connecting the circuit forming surface and the opposing surface.
[13] [13]
如所述[1]至[12]中任一項所述的電子裝置的製造方法,其中構成所述基材層的樹脂包含選自由聚酯系彈性體、聚醯胺系彈性體、聚醯亞胺系彈性體、聚對苯二甲酸丁二酯、聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯及聚醯亞胺所組成的群組中的一種或兩種以上。 A method for manufacturing an electronic device as described in any one of [1] to [12], wherein the resin constituting the substrate layer comprises one or more selected from the group consisting of polyester elastomers, polyamide elastomers, polyimide elastomers, polybutylene terephthalate, polyethylene terephthalate, polyethylene naphthalate and polyimide.
[14] [14]
如所述[1]至[13]中任一項所述的電子裝置的製造方法,其中構成所述黏著性樹脂層的黏著劑包含選自(甲基)丙烯酸系黏著劑、矽酮系黏著劑、胺基甲酸酯系黏著劑、烯烴系黏著劑及苯乙烯系黏著劑中的一種或兩種以上。 A method for manufacturing an electronic device as described in any one of [1] to [13], wherein the adhesive constituting the adhesive resin layer comprises one or more selected from (meth)acrylic adhesives, silicone adhesives, urethane adhesives, olefin adhesives and styrene adhesives.
根據本發明,可於電子零件上良好地形成電磁波屏蔽層且可縮短電子裝置的製造步驟。 According to the present invention, an electromagnetic wave shielding layer can be well formed on electronic parts and the manufacturing steps of electronic devices can be shortened.
10、100:電子零件 10, 100: Electronic parts
10A、100A:電路形成面 10A, 100A: Circuit formation surface
10B:電極 10B: Electrode
20:基材層 20: Base material layer
30:凹凸吸收性樹脂層 30: Concavoconvex absorbent resin layer
40:黏著性樹脂層 40: Adhesive resin layer
50:黏著性積層膜 50: Adhesive laminate film
60:結構體 60:Structure
70、140:電磁波屏蔽層 70, 140: Electromagnetic wave shielding layer
110:背面研磨膠帶 110: Back grinding tape
120:切割膠帶 120: Cutting tape
130:電路形成面保護用膠帶 130: Tape for protecting circuit forming surface
150:下端部 150: Lower end
160:黏著劑 160: Adhesive
A~D:步驟 A~D: Steps
圖1是表示本發明的電子裝置的製造方法的一例的流程圖。 FIG1 is a flow chart showing an example of a method for manufacturing an electronic device of the present invention.
圖2(A)~圖2(D)是示意性表示本發明的實施形態的電子裝置的製造方法的一例的剖面圖。 Figures 2(A) to 2(D) are cross-sectional views schematically showing an example of a method for manufacturing an electronic device according to an embodiment of the present invention.
圖3是示意性表示先前的電子裝置的製造方法的一例的剖面圖。 FIG3 is a cross-sectional view schematically showing an example of a conventional method for manufacturing an electronic device.
以下,對於本發明的實施形態,使用圖式進行說明。再者,於所有圖式中,對同樣的構成要素標註共通的符號,且適當地省略說明。另外,圖為概略圖,與實際的尺寸比率不一致。另外,數值範圍的「A~B」若無特別說明,則表示A以上且B以下。另外,本實施形態中,所謂「(甲基)丙烯酸」是指丙烯酸、甲基丙烯酸或者丙烯酸及甲基丙烯酸的兩者。 Hereinafter, the embodiments of the present invention will be described using drawings. Furthermore, in all drawings, common symbols are used for the same components, and the description is omitted appropriately. In addition, the drawings are schematic diagrams and are not consistent with the actual dimensional ratios. In addition, the numerical range "A~B" means above A and below B unless otherwise specified. In addition, in this embodiment, the so-called "(meth)acrylic acid" refers to acrylic acid, methacrylic acid, or both acrylic acid and methacrylic acid.
圖1是表示本發明的電子裝置的製造方法的一例的流程 圖。圖2(A)~圖2(D)是示意性表示本發明的實施形態的電子裝置的製造方法的一例的剖面圖。 FIG. 1 is a flow chart showing an example of a method for manufacturing an electronic device of the present invention. FIG. 2(A) to FIG. 2(D) are cross-sectional views schematically showing an example of a method for manufacturing an electronic device of an embodiment of the present invention.
本實施形態的電子裝置的製造方法至少依次包括以下的步驟(A)、步驟(B)、步驟(C)及步驟(D),於步驟(A)、步驟(B)、步驟(C)及步驟(D)中,使用同一黏著性積層膜作為黏著性積層膜50。
The manufacturing method of the electronic device of this embodiment at least includes the following steps (A), (B), (C) and (D) in sequence. In steps (A), (B), (C) and (D), the same adhesive laminate film is used as the
(A)準備具備電子零件10與黏著性積層膜50的結構體60的步驟,所述電子零件10具有電路形成面10A且進行了半切割,所述黏著性積層膜50具有基材層20及黏著性樹脂層40,且以保護電路形成面10A的方式將黏著性樹脂層40側貼附於電子零件10的電路形成面10A
(A) A step of preparing a
(B)於貼附於黏著性積層膜50的狀態下,對與電子零件10的電路形成面10A為相反側的面進行背面研磨的步驟
(B) A step of back grinding the surface opposite to the
(C)於貼附於黏著性積層膜50的狀態下,對電子零件10進行全切割的步驟
(C) The step of fully cutting the
(D)於貼附於黏著性積層膜50的狀態下,於經單片化的電子零件10上形成電磁波屏蔽層70的步驟
(D) A step of forming an electromagnetic
如上所述,根據本發明者等人的研究,發現了於先前的電子裝置的製造方法中,如圖3所示,於利用電路形成面保護用膠帶130保護電子零件100的電路形成面100A的狀態下在電子零件100的表面形成電磁波屏蔽層140的情況下,有時於電子零件100的側面的下端部150不會形成電磁波屏蔽層140。該情況下,
電子零件100的電磁波屏蔽性差。
As described above, according to the research of the inventors and others, it was found that in the previous method of manufacturing electronic devices, as shown in FIG3, when the electromagnetic
本發明者等人基於所述見解進一步進行研究,結果發現如圖3所示,於將貼附於切割膠帶120上的電子零件100再排列於電路形成面保護用膠帶130時,有時電路形成面保護用膠帶130的與電子零件100的側面的下端部150相接的部分(黏著性層)凸起而覆蓋電子零件100的側面的下端部150。即,根據本發明者等人的研究,明確了電子零件100的側面的下端部150由構成電路形成面保護用膠帶130的黏著性層的黏著劑160覆蓋,因此於電子零件100的側面的下端部150不會形成電磁波屏蔽層140。
The inventors of the present invention have conducted further research based on the above-mentioned viewpoints, and found that as shown in FIG3, when the
另外,關於具有電磁波屏蔽性的電子裝置的製造方法,如圖3所示,將電子零件100貼附於背面研磨膠帶110上而進行背面研磨步驟,繼而將電子零件100自背面研磨膠帶110剝落後貼附於切割膠帶120上而進行切割步驟,繼而將電子零件100自切割膠帶120剝落後再排列於電路形成面保護用膠帶130上而進行電磁波屏蔽層形成步驟。因此,先前的電子裝置的製造方法中,使用3種用以暫時固定電子零件100的膠帶,且包括將電子零件100貼附於各膠帶上的步驟或將電子零件100自各膠帶剝落的步驟等,步驟數非常多。
In addition, regarding the manufacturing method of an electronic device with electromagnetic wave shielding properties, as shown in Figure 3, the
即,本發明者等人發現,於具有電磁波屏蔽性的電子裝置的製造方法中,就於電子零件上良好地形成電磁波屏蔽層且縮短電子裝置的製造步驟的觀點而言,存在改善的餘地。 That is, the inventors and others have found that in the manufacturing method of electronic devices with electromagnetic wave shielding properties, there is room for improvement from the perspective of forming an electromagnetic wave shielding layer on electronic parts well and shortening the manufacturing steps of the electronic device.
本發明者等人為了達成所述課題而反覆進行銳意研
究。結果發現藉由於準備具備進行了半切割的電子零件的結構體的步驟、背面研磨步驟、全切割步驟及電磁波屏蔽層形成步驟中使用相同的黏著性積層膜50作為保護電子零件10的電路形成面10A的膜,可省略將電子零件10貼附於各膠帶上的步驟或將電子零件10自各膠帶剝落的步驟等的一部分,進而可抑制電子零件10的側面的下端部中的電磁波屏蔽層的形成不良。
The inventors of the present invention have repeatedly conducted intensive research to achieve the above-mentioned subject. As a result, it was found that by using the same
若於準備具備進行了半切割的電子零件的結構體的步驟、背面研磨步驟、全切割步驟及電磁波屏蔽層形成步驟中使用相同的黏著性積層膜50作為保護電子零件10的電路形成面10A的膜,可省略將如圖3所示的貼附於切割膠帶120上的電子零件100再排列於電路形成面保護用膠帶130上的步驟。因此,不會發生電子零件10的側面的下端部由構成黏著性樹脂層40的黏著劑覆蓋的現象。因此,於本實施形態的電子裝置的製造方法中,可至電子零件10的側面的下端部良好地形成電磁波屏蔽層70。
If the same adhesive
另外,於本實施形態的電子裝置的製造方法中,藉由於準備具備進行了半切割的電子零件的結構體的步驟、背面研磨步驟、全切割步驟及電磁波屏蔽層形成步驟中使用相同的黏著性積層膜50作為保護電子零件10的電路形成面10A的膜,可省略將電子零件10貼附於各膠帶上的步驟或將電子零件10自各膠帶剝落的步驟等的一部分。
In addition, in the manufacturing method of the electronic device of the present embodiment, by using the same
如上所述,根據本實施形態的電子裝置的製造方法,可於電子零件上良好地形成電磁波屏蔽層且可縮短電子裝置的製造步 驟。 As described above, according to the manufacturing method of the electronic device of this embodiment, an electromagnetic wave shielding layer can be well formed on the electronic parts and the manufacturing steps of the electronic device can be shortened.
1.黏著性積層膜 1. Adhesive laminate film
以下,對本實施形態的電子裝置的製造方法中使用的黏著性積層膜50進行說明。
The following describes the
<基材層> <Base layer>
基材層20是出於使黏著性積層膜50的操作性或機械特性、耐熱性等特性更良好的目的而設置的層。
The
基材層20並無特別限定,例如可列舉樹脂膜。
The
作為構成基材層20的樹脂,可使用公知的熱塑性樹脂。例如可列舉選自以下化合物中的一種或兩種以上:聚乙烯、聚丙烯、聚(4-甲基-1-戊烯)、聚(1-丁烯)等聚烯烴;聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚萘二甲酸乙二酯等聚酯;尼龍-6、尼龍-66、聚己二醯間苯二甲胺等聚醯胺;聚丙烯酸酯;聚甲基丙烯酸酯;聚氯乙烯;聚醯亞胺;聚醚醯亞胺;聚醯胺醯亞胺;乙烯.乙酸乙烯酯共聚物;聚丙烯腈;聚碳酸酯;聚苯乙烯;離子聚合物;聚碸;聚醚碸;聚醚醚酮;聚苯硫醚;聚苯醚;聚酯系彈性體、聚醯胺系彈性體、聚醯亞胺系彈性體等彈性體等。
As the resin constituting the
該些中,就使透明性良好的觀點而言,較佳為選自聚丙烯、聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯、聚醯胺、聚醯亞胺、乙烯.乙酸乙烯酯共聚物、聚酯系彈性體、聚醯胺系彈性體、聚醯亞胺系彈性體及聚對苯二甲酸丁二酯中的一種或兩種以上,更佳為選自聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯、聚酯系彈性體、 聚醯胺系彈性體、聚醯亞胺系彈性體、聚對苯二甲酸丁二酯及聚醯亞胺中的一種或兩種以上。 Among these, from the viewpoint of achieving good transparency, preferably one or more selected from polypropylene, polyethylene terephthalate, polyethylene naphthalate, polyamide, polyimide, ethylene-vinyl acetate copolymer, polyester elastomer, polyamide elastomer, polyimide elastomer and polybutylene terephthalate are used, and more preferably one or more selected from polyethylene terephthalate, polyethylene naphthalate, polyester elastomer, polyamide elastomer, polyimide elastomer, polybutylene terephthalate and polyimide are used.
另外,就使黏著性積層膜50的柔軟性或伸縮性等特性與耐熱性的平衡提高的觀點而言,作為構成基材層20的樹脂,進而佳為選自聚酯系彈性體、聚醯胺系彈性體、聚醯亞胺系彈性體及聚對苯二甲酸丁二酯等中的一種或兩種以上。藉此,黏著性積層膜50的伸縮性或柔軟性提高,於在步驟(D)後剝離電子零件10與黏著性積層膜50時使黏著性積層膜50於面內方向上擴張的情況進一步變得更容易,容易自黏著性積層膜50剝離電子零件10。
In addition, from the perspective of improving the balance between the properties such as flexibility or stretchability of the
基材層20的熔點較佳為100℃以上。熔點上限並無特別限定,只要鑒於加工性等進行選擇即可。
The melting point of the
若使用所述基材層20,則於步驟(D)中即便將黏著性積層膜50暴露於高溫下,亦可更進一步抑制黏著性積層膜50的變形或熔融。
If the
基材層20可為單層,亦可為兩種以上的層。
The
另外,為了形成基材層20而使用的樹脂膜的形態可為延伸膜,亦可為於單軸方向或雙軸方向上延伸的膜。
In addition, the resin film used to form the
就獲得良好的膜特性的觀點而言,基材層20的厚度較佳為10μm以上且500μm以下,更佳為20μm以上且300μm以下,進而佳為25μm以上且250μm以下。
From the perspective of obtaining good film properties, the thickness of the
基材層20為了改良與其他層的黏接性,亦可進行表面處理。具體而言,亦可進行電暈處理、電漿處理、下塗(under coat)處
理、底塗(primer coat)處理等。
The
<凹凸吸收性樹脂層> <Concave-convex absorbent resin layer>
本實施形態的黏著性積層膜50較佳為於基材層20與黏著性樹脂層40之間進一步具有凹凸吸收性樹脂層30。
The
凹凸吸收性樹脂層30是出於使黏著性積層膜50的對於電路形成面10A的追隨性良好,且使電路形成面10A與黏著性積層膜50的密接性良好的目的而設置的層。
The unevenness
此處,根據本發明者等人的研究,發現了如下課題:於在利用保護膜保護電子零件的電路形成面的狀態下於電子零件的表面形成電磁波屏蔽層時,用以形成電磁波屏蔽層的導電性成分進入至電子零件的電路形成面並附著於電路,結果有時電路發生電氣短路。另外,電路形成面的凹凸越大,構成電路形成面的電路越容易發生電氣短路。尤其,於使用在電子零件的電路形成面上形成有凸塊電極的電子零件的情況下,存在構成電路形成面的電路容易發生電氣短路的傾向。 Here, according to the research of the inventors and others, the following topic was discovered: When an electromagnetic wave shielding layer is formed on the surface of an electronic component while the circuit forming surface of the electronic component is protected by a protective film, the conductive component used to form the electromagnetic wave shielding layer enters the circuit forming surface of the electronic component and adheres to the circuit, resulting in an electrical short circuit in the circuit. In addition, the larger the unevenness of the circuit forming surface, the more likely the circuit constituting the circuit forming surface is to have an electrical short circuit. In particular, when using an electronic component with a bump electrode formed on the circuit forming surface of the electronic component, there is a tendency for the circuit constituting the circuit forming surface to have an electrical short circuit.
本發明者等人為了達成所述課題而反覆進行銳意研究。結果發現於電子零件與保護膜之間的密接性不充分的情況下,用以形成電磁波屏蔽層的導電性成分容易進入至電子零件的電路形成面,容易引起電路的導通不良。 The inventors of the present invention have repeatedly conducted intensive research to achieve the above-mentioned topic. As a result, it was found that when the adhesion between the electronic components and the protective film is insufficient, the conductive components used to form the electromagnetic wave shielding layer can easily enter the circuit forming surface of the electronic components, which can easily cause poor conduction of the circuit.
尤其,於使用在電路形成面形成有凸塊電極等較大凹凸的電子零件的情況下,保護膜對於電子零件的電路形成面的凹凸的追隨性容易變得不充分,因此電子零件與保護膜之間的密接性容易 變得不充分。結果發現用以形成電磁波屏蔽層的導電性成分容易浸入至電子零件的電路形成面,容易引起構成電路形成面的電路的導通不良。 In particular, when using electronic components with relatively large bumps and depressions such as bump electrodes formed on the circuit forming surface, the protective film is likely to be insufficient in following the bumps and depressions of the circuit forming surface of the electronic component, and thus the adhesion between the electronic component and the protective film is likely to be insufficient. As a result, it was found that the conductive component used to form the electromagnetic wave shielding layer is likely to penetrate into the circuit forming surface of the electronic component, which is likely to cause poor conduction of the circuit constituting the circuit forming surface.
本發明者等人基於所述見解進一步反覆進行研究。結果發現藉由使用依次具有基材層20、凹凸吸收性樹脂層30及黏著性樹脂層40的黏著性積層膜50作為保護電子零件10的電路形成面10A的膜,可抑制電路形成面10A的電氣短路,可穩定地獲得具有電磁波屏蔽性的電子裝置。
The inventors of the present invention and others have further repeatedly conducted research based on the above-mentioned insights. As a result, it was found that by using an
即,藉由黏著性積層膜50進一步具有凹凸吸收性樹脂層30,黏著性積層膜50容易追隨電子零件10的電路形成面10A,可使黏著性積層膜50與電子零件10的電路形成面10A之間的密接性提高。藉此,容易追隨電子零件10的電路形成面10A的凹凸,可進一步減小黏著性積層膜50與電子零件10的電路形成面10A之間的空隙。結果於在電子零件10的表面形成電磁波屏蔽層70時,可抑制用以形成電磁波屏蔽層70的導電性成分進入至電子零件10的電路形成面10A,可抑制構成電路形成面10A的電路的電氣短路。
That is, since the
構成凹凸吸收性樹脂層30的樹脂只要為顯示凹凸吸收性者,則並無特別限定,例如可列舉選自由聚烯烴系樹脂、聚苯乙烯系樹脂及(甲基)丙烯酸系樹脂所組成的群組中的一種或兩種以上。
The resin constituting the unevenness
另外,凹凸吸收性樹脂層30較佳為包含交聯性樹脂。
藉由凹凸吸收性樹脂層30包含交聯性樹脂,可於步驟(D)前對凹凸吸收性樹脂層30進行交聯而使耐熱性提高,結果於步驟(D)中即便將黏著性積層膜50暴露於高溫下,亦可更進一步抑制黏著性積層膜50的變形或熔融。
In addition, the uneven
作為本實施形態的交聯性樹脂,只要為可形成凹凸吸收性樹脂層30且藉由熱或光等的外部刺激進行交聯而耐熱性提高的樹脂,則並無特別限定,例如可使用選自以下化合物中的一種或兩種以上:包含乙烯及碳數3~20的α-烯烴的乙烯.α-烯烴共聚物、高密度乙烯系樹脂、低密度乙烯系樹脂、中密度乙烯系樹脂、超低密度乙烯系樹脂、直鏈狀低密度聚乙烯(線型低密度聚乙烯(Linear Low Density Polyethylene,LLDPE))系樹脂、丙烯(共)聚合物、1-丁烯(共)聚合物、4-甲基戊烯-1(共)聚合物、乙烯.環狀烯烴共聚物、乙烯.α-烯烴.環狀烯烴共聚物、乙烯.α-烯烴.非共軛聚烯共聚物、乙烯.α-烯烴.共軛聚烯共聚物、乙烯.芳香族乙烯基共聚物、乙烯.α-烯烴.芳香族乙烯基共聚物等烯烴系樹脂;乙烯.不飽和羧酸酐共聚物、乙烯.α-烯烴.不飽和羧酸酐共聚物等乙烯.羧酸酐系共聚物;乙烯.含環氧基的不飽和化合物共聚物、乙烯.α-烯烴.含環氧基的不飽和化合物共聚物等乙烯.環氧系共聚物;乙烯.(甲基)丙烯酸乙酯共聚物、乙烯.(甲基)丙烯酸甲酯共聚物、乙烯.(甲基)丙烯酸丙酯共聚物、乙烯.(甲基)丙烯酸丁酯共聚物、乙烯.(甲基)丙烯酸己酯共聚物、乙烯.(甲基)丙烯酸-2-羥基乙酯共聚物、乙烯.(甲基)丙烯酸-2-羥基丙酯共聚物、乙烯.(甲基)丙烯酸縮
水甘油酯共聚物等乙烯.(甲基)丙烯酸酯共聚物;乙烯.(甲基)丙烯酸共聚物、乙烯.順丁烯二酸共聚物、乙烯.反丁烯二酸共聚物、乙烯.丁烯酸共聚物等乙烯.乙烯性不飽和酸共聚物;乙烯.乙酸乙烯酯共聚物、乙烯.丙酸乙烯酯共聚物、乙烯.丁酸乙烯酯共聚物、乙烯.硬脂酸乙烯酯共聚物等乙烯.乙烯酯共聚物;乙烯.苯乙烯共聚物等;(甲基)丙烯酸酯(共)聚合物等不飽和羧酸酯(共)聚合物;乙烯.丙烯酸金屬鹽共聚物、乙烯.甲基丙烯酸金屬鹽共聚物等離子聚合物樹脂;胺基甲酸酯系樹脂;矽酮系樹脂;丙烯酸系樹脂;甲基丙烯酸系樹脂;環狀烯烴(共)聚合物;α-烯烴.芳香族乙烯酯化合物.芳香族聚烯共聚物;乙烯.α-烯烴.芳香族乙烯酯化合物;芳香族聚烯共聚物;乙烯.芳香族乙烯酯化合物.芳香族聚烯共聚物;苯乙烯系樹脂;丙烯腈.丁二烯.苯乙烯共聚物;苯乙烯.共軛二烯共聚物;丙烯腈.苯乙烯共聚物;丙烯腈.乙烯.α-烯烴.非共軛聚烯.苯乙烯共聚物;丙烯腈.乙烯.α-烯烴.共軛聚烯.苯乙烯共聚物;甲基丙烯酸.苯乙烯共聚物;對苯二甲酸乙二酯樹脂;氟樹脂;聚酯碳酸酯;聚氯乙烯;聚偏二氯乙烯;聚烯烴系熱塑性彈性體;聚苯乙烯系熱塑性彈性體;聚胺基甲酸酯系熱塑性彈性體;1,2-聚丁二烯系熱塑性彈性體;反式聚異戊二烯系熱塑性彈性體;氯化聚乙烯系熱塑性彈性體;液晶性聚酯;聚乳酸等。
The crosslinking resin of the present embodiment is not particularly limited as long as it can form the concave-convex
該些中,就利用有機過氧化物等交聯劑的交聯容易的方面而言,較佳為使用選自以下化合物中的一種或兩種以上:包含乙烯及碳數3~20的α-烯烴的乙烯.α-烯烴共聚物、低密度乙烯系 樹脂、中密度乙烯系樹脂、超低密度乙烯系樹脂、直鏈狀低密度聚乙烯(LLDPE)系樹脂、乙烯.環狀烯烴共聚物、乙烯.α-烯烴.環狀烯烴共聚物、乙烯.α-烯烴.非共軛聚烯共聚物、乙烯.α-烯烴.共軛聚烯共聚物、乙烯.芳香族乙烯基共聚物、乙烯.α-烯烴.芳香族乙烯基共聚物等烯烴系樹脂、乙烯.不飽和羧酸酐共聚物、乙烯.α-烯烴.不飽和羧酸酐共聚物、乙烯.含環氧基的不飽和化合物共聚物、乙烯.α-烯烴.含環氧基的不飽和化合物共聚物、乙烯.乙酸乙烯酯共聚物、乙烯.丙烯酸共聚物、乙烯.甲基丙烯酸共聚物等乙烯.不飽和羧酸共聚物、1,2-聚丁二烯系熱塑性彈性體。 Among these, in terms of the ease of crosslinking using a crosslinking agent such as an organic peroxide, it is preferred to use one or more selected from the following compounds: ethylene-α-olefin copolymers containing ethylene and α-olefins having 3 to 20 carbon atoms, low-density ethylene resins, medium-density ethylene resins, ultra-low-density ethylene resins, linear low-density polyethylene (LLDPE) resins, ethylene-cyclic olefin copolymers, ethylene-α-olefin-cyclic olefin copolymers, ethylene-α-olefin-non-conjugated polyolefin copolymers, ethylene-α-olefin-conjugated polyolefin copolymers, ethylene-aromatic vinyl copolymers, ethylene-α-olefin-aromatic vinyl copolymers and other olefin resins, ethylene-unsaturated carboxylic acid anhydride copolymers, ethylene-α-olefin- Unsaturated carboxylic acid anhydride copolymers, ethylene. epoxy-containing unsaturated compound copolymers, ethylene. α-olefin. epoxy-containing unsaturated compound copolymers, ethylene. vinyl acetate copolymers, ethylene. acrylic acid copolymers, ethylene. methacrylic acid copolymers, etc. ethylene. unsaturated carboxylic acid copolymers, 1,2-polybutadiene-based thermoplastic elastomers.
更佳為使用選自以下化合物中的一種或兩種以上:包含乙烯及碳數3~20的α-烯烴的乙烯.α-烯烴共聚物、低密度乙烯系樹脂、超低密度乙烯系樹脂、直鏈狀低密度聚乙烯(LLDPE)系樹脂、乙烯.α-烯烴.非共軛聚烯共聚物、乙烯.α-烯烴.共軛聚烯共聚物、乙烯.不飽和羧酸酐共聚物、乙烯.α-烯烴.不飽和羧酸酐共聚物、乙烯.含環氧基的不飽和化合物共聚物、乙烯.α-烯烴.含環氧基的不飽和化合物共聚物、乙烯.乙酸乙烯酯共聚物、乙烯.丙烯酸共聚物、乙烯.甲基丙烯酸共聚物等乙烯.不飽和羧酸共聚物。 It is more preferable to use one or more of the following compounds: ethylene-α-olefin copolymers containing ethylene and α-olefins with 3 to 20 carbon atoms, low-density ethylene resins, ultra-low-density ethylene resins, linear low-density polyethylene (LLDPE) resins, ethylene-α-olefin-non-conjugated polyolefin copolymers, ethylene-α-olefin-conjugated polyolefin copolymers, ethylene-unsaturated carboxylic acid anhydride copolymers, ethylene-α-olefin-unsaturated carboxylic acid anhydride copolymers, ethylene-epoxy-containing unsaturated compound copolymers, ethylene-α-olefin-epoxy-containing unsaturated compound copolymers, ethylene-vinyl acetate copolymers, ethylene-acrylic acid copolymers, ethylene-methacrylic acid copolymers and other ethylene-unsaturated carboxylic acid copolymers.
進而佳為使用選自以下化合物中的一種或兩種以上:包含乙烯及碳數3~20的α-烯烴的乙烯.α-烯烴共聚物、低密度乙烯系樹脂、超低密度乙烯系樹脂、直鏈狀低密度聚乙烯(LLDPE)系樹脂、乙烯.α-烯烴.非共軛聚烯共聚物、乙烯.α-烯烴.共軛聚烯共聚物、乙烯.乙酸乙烯酯共聚物、乙烯.丙烯酸共聚物、乙烯.甲基丙 烯酸共聚物等乙烯.不飽和羧酸共聚物。 It is further preferred to use one or more of the following compounds: ethylene-α-olefin copolymers containing ethylene and α-olefins with 3 to 20 carbon atoms, low-density ethylene resins, ultra-low-density ethylene resins, linear low-density polyethylene (LLDPE) resins, ethylene-α-olefin-non-conjugated polyolefin copolymers, ethylene-α-olefin-conjugated polyolefin copolymers, ethylene-vinyl acetate copolymers, ethylene-acrylic acid copolymers, ethylene-methacrylic acid copolymers, and other ethylene-unsaturated carboxylic acid copolymers.
該些中,可尤佳地使用選自乙烯.α-烯烴共聚物及乙烯.乙酸乙烯酯共聚物中的至少一種。再者,本實施形態中所述樹脂可單獨使用,亦可混合使用。 Among these, at least one selected from ethylene-α-olefin copolymers and ethylene-vinyl acetate copolymers can be preferably used. Furthermore, the resins described in this embodiment can be used alone or in combination.
關於可作為本實施形態中的交聯性樹脂而使用的包含乙烯及碳數3~20的α-烯烴的乙烯.α-烯烴共聚物的α-烯烴,通常可將碳數3~20的α-烯烴單獨使用一種或者組合使用兩種以上。其中較佳的是碳數為10以下的α-烯烴,尤佳的是碳數3~8的α-烯烴。作為所述α-烯烴,例如可列舉:丙烯、1-丁烯、1-戊烯、1-己烯、3-甲基-1-丁烯、3,3-二甲基-1-丁烯、4-甲基-1-戊烯、1-辛烯、1-癸烯、1-十二烯等。該些中,就獲取的容易性而言,較佳為丙烯、1-丁烯、1-戊烯、1-己烯、4-甲基-1-戊烯及1-辛烯。再者,乙烯.α-烯烴共聚物可為無規共聚物,亦可為嵌段共聚物,但就柔軟性的觀點而言,較佳為無規共聚物。 Regarding the α-olefin of the ethylene-α-olefin copolymer containing ethylene and an α-olefin having 3 to 20 carbon atoms that can be used as the crosslinking resin in the present embodiment, generally, one α-olefin having 3 to 20 carbon atoms can be used alone or in combination of two or more α-olefins having 3 to 20 carbon atoms. Among them, α-olefins having 10 or less carbon atoms are preferred, and α-olefins having 3 to 8 carbon atoms are particularly preferred. Examples of the α-olefin include propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 3,3-dimethyl-1-butene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, and the like. Among these, propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene and 1-octene are preferred in terms of ease of acquisition. Furthermore, the ethylene-α-olefin copolymer may be a random copolymer or a block copolymer, but from the perspective of softness, a random copolymer is preferred.
凹凸吸收性樹脂層30的厚度若為可將電子零件10的電路形成面10A的凹凸埋入的厚度,則並無特別限制,例如較佳為10μm以上且1000μm以下,更佳為20μm以上且900μm以下,進而佳為30μm以上且800μm以下,尤佳為50μm以上且700μm以下。
The thickness of the unevenness absorbing
此處,於電子零件的電路形成面包含凸塊電極的情況下,於在電子零件的表面形成電磁波屏蔽層時,存在構成電路形成面的電路容易發生電氣短路的傾向。但是,藉由使用進一步具
有凹凸吸收性樹脂層30的黏著性積層膜50,對於在電路形成面10A上包含凸塊電極的電子零件10,亦可抑制電氣短路。
Here, when the circuit forming surface of the electronic component includes a bump electrode, when an electromagnetic wave shielding layer is formed on the surface of the electronic component, there is a tendency for the circuit constituting the circuit forming surface to be easily short-circuited. However, by using an adhesive
另外,於將電子零件10的電路形成面10A上存在的凸塊電極的高度設為H[μm]且將凹凸吸收性樹脂層30的厚度設為d[μm]時,H/d較佳為1以下,更佳為0.85以下,進而佳為0.7以下。若H/d為所述上限值以下,則可使黏著性積層膜50的厚度更薄,且使凹凸吸收性更良好。
In addition, when the height of the bump electrode on the
H/d的下限並無特別限定,例如為0.01以上。凸塊電極的高度通常為2μm以上且600μm以下。 The lower limit of H/d is not particularly limited, and is, for example, greater than 0.01. The height of the bump electrode is usually greater than 2μm and less than 600μm.
此處,根據本發明者等人的研究而明確了電路形成面的凹凸越大,構成電路形成面的電路越容易發生電氣短路。因此,於凸塊電極的高度較佳為10μm以上、更佳為30μm以上、進而佳為50μm以上、進而更佳為80μm以上、尤佳為100μm以上時,可進一步更有效地獲得本實施形態的電子裝置的製造方法的效果。 Here, according to the research of the inventors and others, it is clear that the larger the unevenness of the circuit forming surface, the easier it is for the circuit constituting the circuit forming surface to have an electrical short circuit. Therefore, when the height of the bump electrode is preferably 10μm or more, more preferably 30μm or more, further preferably 50μm or more, further preferably 80μm or more, and particularly preferably 100μm or more, the effect of the manufacturing method of the electronic device of this embodiment can be further and more effectively obtained.
<黏著性樹脂層> <Adhesive resin layer>
黏著性樹脂層40為設置於基材層20或凹凸吸收性樹脂層30的一面側的層,是於將黏著性積層膜50貼附於電子零件10的電路形成面10A時,與電子零件10的電路形成面10A接觸而黏著的層。
The
構成黏著性樹脂層40的黏著劑可列舉:(甲基)丙烯酸系黏著劑、矽酮系黏著劑、胺基甲酸酯系黏著劑、烯烴系黏著劑、苯乙烯系黏著劑等。該些中,就可容易調整黏接力的方面等而言,
較佳為將(甲基)丙烯酸系聚合物作為基礎聚合物的(甲基)丙烯酸系黏著劑。
The adhesive constituting the
另外,作為構成黏著性樹脂層40的黏著劑,亦可使用藉由放射線而使黏著力下降的放射線交聯型黏著劑。由放射線交聯型黏著劑所構成的黏著性樹脂層40藉由放射線的照射而交聯,黏著力顯著減少,因此於將後述的電子零件10與黏著性積層膜50剝離的步驟(F)中,容易自黏著性樹脂層40剝離電子零件10。放射線可列舉紫外線、電子束、紅外線等。
In addition, as the adhesive constituting the
放射線交聯型黏著劑較佳為紫外線交聯型黏著劑。 The radiation cross-linking adhesive is preferably an ultraviolet cross-linking adhesive.
(甲基)丙烯酸系黏著劑中所含的(甲基)丙烯酸系聚合物例如可列舉:(甲基)丙烯酸酯化合物的均聚物、(甲基)丙烯酸酯化合物與共聚單體的共聚物等。(甲基)丙烯酸酯化合物例如可列舉:(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丁酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸羥基乙酯、(甲基)丙烯酸羥基丙酯、(甲基)丙烯酸二甲基胺基乙酯、(甲基)丙烯酸縮水甘油酯等。該些(甲基)丙烯酸酯化合物可單獨使用一種,亦可併用兩種以上。 Examples of (meth)acrylic polymers contained in (meth)acrylic adhesives include homopolymers of (meth)acrylic acid ester compounds, copolymers of (meth)acrylic acid ester compounds and comonomers, etc. Examples of (meth)acrylic acid ester compounds include methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, dimethylaminoethyl (meth)acrylate, glycidyl (meth)acrylate, etc. These (meth)acrylate compounds may be used alone or in combination of two or more.
另外,構成(甲基)丙烯酸系共聚物的共聚單體例如可列舉:乙酸乙烯酯、(甲基)丙烯腈、苯乙烯、(甲基)丙烯酸、衣康酸、(甲基)丙烯醯胺、羥甲基(甲基)丙烯醯胺、順丁烯二酸酐等。該些共聚單體可單獨使用一種,亦可併用兩種以上。 In addition, the copolymers constituting the (meth)acrylic copolymers include, for example: vinyl acetate, (meth)acrylonitrile, styrene, (meth)acrylic acid, itaconic acid, (meth)acrylamide, hydroxymethyl (meth)acrylamide, maleic anhydride, etc. These copolymers may be used alone or in combination of two or more.
放射線交聯型黏著劑例如包含:所述(甲基)丙烯酸系聚合物、交聯性化合物(具有碳-碳雙鍵的成分)、以及光聚合起始 劑或熱聚合起始劑。 The radiation cross-linking adhesive includes, for example: the (meth) acrylic polymer, a cross-linking compound (a component having a carbon-carbon double bond), and a photopolymerization initiator or a thermal polymerization initiator.
交聯性化合物例如可列舉:分子中具有碳-碳雙鍵,可藉由自由基聚合而交聯的單體、寡聚物或聚合物等。所述交聯性化合物例如可列舉:三羥甲基丙烷三(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、四乙二醇二(甲基)丙烯酸酯、1,6-己二醇二(甲基)丙烯酸酯、新戊二醇二(甲基)丙烯酸酯、二季戊四醇六(甲基)丙烯酸酯等(甲基)丙烯酸與多元醇的酯;酯(甲基)丙烯酸酯寡聚物;2-丙烯基二-3-丁烯基三聚氰酸酯、2-羥基乙基雙(2-(甲基)丙烯醯氧基乙基)異三聚氰酸酯、三(2-甲基丙烯醯氧基乙基)異三聚氰酸酯等異三聚氰酸酯或者異三聚氰酸酯化合物等。 Examples of crosslinking compounds include: monomers, oligomers or polymers that have carbon-carbon double bonds in the molecule and can be crosslinked by free radical polymerization. Examples of the crosslinking compounds include: esters of (meth)acrylic acid and polyols such as trihydroxymethylpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, tetraethylene glycol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, and dipentaerythritol hexa(meth)acrylate; ester (meth)acrylate oligomers; isocyanurates or isocyanurate compounds such as 2-propylene di-3-butenyl cyanurate, 2-hydroxyethyl bis(2-(meth)acryloyloxyethyl) isocyanurate, and tris(2-methacryloyloxyethyl) isocyanurate.
再者,於(甲基)丙烯酸系聚合物為於聚合物的側鏈上具有碳-碳雙鍵的放射線交聯型聚合物的情況下,亦可不添加交聯性化合物。 Furthermore, when the (meth)acrylic acid polymer is a radiation cross-linked polymer having a carbon-carbon double bond on the side chain of the polymer, the cross-linking compound may not be added.
相對於(甲基)丙烯酸系聚合物100質量份,交聯性化合物的含量較佳為5質量份~900質量份,更佳為5質量份~100質量份,進而佳為10質量份~50質量份。藉由交聯性化合物的含量為所述範圍,與少於所述範圍的情況相比,黏著力的調整變得容易,且與多於所述範圍的情況相比,難以產生由於對熱或光的感度過高而引起的保存穩定性的下降。 The content of the crosslinking compound is preferably 5 to 900 parts by mass, more preferably 5 to 100 parts by mass, and further preferably 10 to 50 parts by mass relative to 100 parts by mass of the (meth)acrylic polymer. When the content of the crosslinking compound is within the above range, the adjustment of the adhesive force becomes easier than when the content is less than the above range, and the storage stability is less likely to decrease due to excessive sensitivity to heat or light than when the content is more than the above range.
光聚合起始劑只要為藉由照射放射線而開裂生成自由基的化合物即可,例如可列舉:安息香甲醚、安息香異丙醚、安息香異丁醚等安息香烷基醚類;苄基、安息香、二苯甲酮、α-羥 基環己基苯基酮等芳香族酮類;苄基二甲基縮酮等芳香族縮酮類;聚乙烯基二苯甲酮;氯硫雜蒽酮、十二烷基硫雜蒽酮、二甲基硫雜蒽酮、二乙基硫雜蒽酮等硫雜蒽酮類等。 The photopolymerization initiator can be any compound that generates free radicals by cleavage upon exposure to radiation, for example: benzoin alkyl ethers such as benzoin methyl ether, benzoin isopropyl ether, and benzoin isobutyl ether; aromatic ketones such as benzyl, benzoin, benzophenone, and α-hydroxycyclohexyl phenyl ketone; aromatic ketones such as benzyl dimethyl ketal; polyvinyl benzophenone; thioxanthrone such as chlorothioxanthrone, dodecylthioxanthrone, dimethylthioxanthrone, and diethylthioxanthrone, etc.
熱聚合起始劑例如可列舉有機過氧化物衍生物或偶氮系聚合起始劑等。就加熱時不會產生氮的方面而言,較佳為有機過氧化物衍生物。熱聚合起始劑例如可列舉:酮過氧化物、過氧化縮酮、氫過氧化物、二烷基過氧化物、二醯基過氧化物、過氧化酯及過氧化二碳酸酯等。 Examples of thermal polymerization initiators include organic peroxide derivatives or azo-based polymerization initiators. Organic peroxide derivatives are preferred because they do not generate nitrogen when heated. Examples of thermal polymerization initiators include ketone peroxides, peroxyketal, hydroperoxides, dialkyl peroxides, diacyl peroxides, peroxyesters, and peroxydicarbonates.
黏著劑中亦可添加交聯劑。交聯劑例如可列舉:山梨糖醇聚縮水甘油醚、聚丙三醇聚縮水甘油醚、季戊四醇聚縮水甘油醚、二丙三醇聚縮水甘油醚等環氧系化合物;四羥甲基甲烷-三-β-氮丙啶基丙酸酯、三羥甲基丙烷-三-β-氮丙啶基丙酸酯、N,N'-二苯基甲烷-4,4'-雙(1-氮丙啶羧基醯胺)、N,N'-六亞甲基-1,6-雙(1-氮丙啶羧基醯胺)等氮丙啶系化合物;四亞甲基二異氰酸酯、六亞甲基二異氰酸酯、聚異氰酸酯等異氰酸酯系化合物等。 Crosslinking agents can also be added to the adhesive. Examples of crosslinking agents include: epoxy compounds such as sorbitol polyglycidyl ether, polyglycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, and diglycerol polyglycidyl ether; aziridine compounds such as tetrahydroxymethylmethane-tri-β-aziridine propionate, trihydroxymethylpropane-tri-β-aziridine propionate, N,N'-diphenylmethane-4,4'-bis(1-aziridine carboxylamide), and N,N'-hexamethylene-1,6-bis(1-aziridine carboxylamide); isocyanate compounds such as tetramethylene diisocyanate, hexamethylene diisocyanate, and polyisocyanate.
就提高黏著性樹脂層40的耐熱性或與密合力的平衡的觀點而言,相對於(甲基)丙烯酸系聚合物100質量份,交聯劑的含量較佳為0.1質量份以上且10質量份以下。
From the perspective of improving the heat resistance of the
黏著性樹脂層40的厚度並無特別限制,例如較佳為1μm以上且100μm以下,更佳為3μm以上且50μm以下。
The thickness of the
黏著性樹脂層40例如可藉由在基材層20或凹凸吸收性樹脂層30上塗佈黏著劑塗佈液而形成。
The
塗佈黏著劑塗佈液的方法可採用現有公知的塗佈方法,例如:輥塗佈機法、反向輥塗佈機法、凹版輥法、棒塗法、缺角輪塗佈機法、模塗佈機法等。對所塗佈的黏著劑的乾燥條件並無特別限制,一般而言較佳為於80℃~200℃的溫度範圍內乾燥10秒~10分鐘。進而佳為於80℃~170℃下乾燥15秒~5分鐘。為了充分促進交聯劑與黏著劑的交聯反應,亦可於黏著劑塗佈液的乾燥結束後,於40℃~80℃下加熱5小時~300小時左右。 The adhesive coating liquid can be applied by any known coating method, such as a roller coater method, a reverse roller coater method, a gravure roller method, a rod coater method, a notched wheel coater method, a die coater method, etc. There is no particular restriction on the drying conditions of the applied adhesive, but generally speaking, it is preferably dried at a temperature range of 80°C to 200°C for 10 seconds to 10 minutes. It is further preferably dried at 80°C to 170°C for 15 seconds to 5 minutes. In order to fully promote the crosslinking reaction between the crosslinking agent and the adhesive, the adhesive coating liquid can also be heated at 40℃~80℃ for about 5 hours to 300 hours after drying.
本實施形態的黏著性積層膜50的全光線透過率較佳為85%以上,更佳為90%以上。藉此,可對黏著性積層膜50賦予透明性。而且,藉由將黏著性積層膜50的全光線透過率設為所述下限值以上,可於對本實施形態的黏著性積層膜50,從基材層20側照射放射線時,對黏著性樹脂層40更有效果地照射放射線,可提高放射線照射效率。再者,黏著性積層膜50的全光線透過率可依據日本工業標準(Japanese Industrial Standards,JIS)K7105(1981)來測定。
The total light transmittance of the
就機械特性與操作性的平衡而言,本實施形態的黏著性積層膜50整體的厚度較佳為25μm以上且1100μm以下,更佳為100μm以上且900μm以下,進而佳為200μm以上且800μm以下。
In terms of the balance between mechanical properties and operability, the overall thickness of the
本實施形態的黏著性積層膜50可於各層之間設置黏接層(未圖示)。藉由該黏接層,可提高各層之間的黏接性。
The
繼而,對本實施形態的黏著性積層膜50的製造方法的
一例進行說明。
Next, an example of a method for manufacturing the
首先,於基材層20的其中一面上,利用擠出層壓法來形成凹凸吸收性樹脂層30。繼而,藉由在凹凸吸收性樹脂層30上塗佈黏著劑塗佈液,使其乾燥而形成黏著性樹脂層40,獲得黏著性積層膜50。
First, an uneven
另外,基材層20與凹凸吸收性樹脂層30可藉由共擠出成形而形成,亦可將膜狀的基材層20與膜狀的凹凸吸收性樹脂層30進行層壓(積層)而形成。
In addition, the
2.電子裝置的製造方法 2. Manufacturing method of electronic device
繼而,對本實施形態的電子裝置的製造方法的各步驟進行說明。 Next, each step of the method for manufacturing the electronic device of this embodiment is described.
(步驟(A)) (Step (A))
首先,準備具備電子零件10與黏著性積層膜50的結構體60,所述電子零件10具有電路形成面10A且進行了半切割,所述黏著性積層膜50以保護電路形成面10A的方式將黏著性樹脂層40側貼附於電子零件10的電路形成面10A。
First, a
所述結構體60例如可藉由進行步驟(A1)或步驟(A2)來製作,所述步驟(A1)對具有電路形成面10A的電子零件10進行半切割,繼而於進行了半切割的電子零件10的電路形成面10A上貼附黏著性積層膜50,所述步驟(A2)於具有電路形成面10A的電子零件10的電路形成面10A上貼附黏著性積層膜50,繼而對貼附於黏著性積層膜50上的電子零件10進行半切割。
The
貼附於黏著性積層膜50的黏著性樹脂層40上的電子零件10可為一個,亦可為兩個以上。
The number of
以下,對結構體60的製造方法進行說明。
The following is a description of the manufacturing method of the
電子零件10的半切割可使用切割刀片(切割鋸)、雷射光、電漿等於公知的條件下進行。
The half-cutting of the
於步驟(A1)的半切割中,為了不達到切斷的程度,可較佳地使用在電子零件10的深度方向的中途藉由切割刀片切入切口的方式。例如於小於電子零件10的厚度切入切口。或者亦可為後述的隱形(stealth)切割。
In the half-cutting of step (A1), in order to avoid cutting, it is preferable to use a cutting blade to cut a notch in the middle of the depth direction of the
另外,於步驟(A2)的實施形態中,電子零件10的半切割包括藉由照射雷射光或電漿對電子零件10(例如半導體基板)設置未達到電子零件10的切斷的程度的變質區域的操作(以下「隱形切割」)。根據隱形切割,可隔著預先貼附的黏著性積層膜50對電子零件10進行半切割,因此較佳。
In addition, in the embodiment of step (A2), the half-cutting of the
於該隱形切割中,電子零件10僅發生變質、脆化,未達到電子零件10被分割為多個的程度。於後述步驟中,藉由黏著性積層膜50的擴張,電子零件10被分割而獲得多個經分割的電子零件10。於步驟(A1)的情況下,於黏著性積層膜50的黏著性樹脂層40上貼附進行了半切割的電子零件10。另外,於步驟(A2)的情況下,於黏著性積層膜50的黏著性樹脂層40上貼附尚未進行半切割的電子零件10。
In this invisible cutting, the
作為貼附於黏著性積層膜50上的電子零件10,只要為具有
電路形成面且要求電磁波屏蔽性的電子零件,則並無特別限定,例如可列舉:半導體晶圓、模具晶圓、模具面板、模具陣列封裝、半導體基板等。
The
另外,作為半導體基板,例如可列舉:矽基板、藍寶石基板、鍺基板、鎵-砷基板、鎵-磷基板、鎵-砷-鋁基板、鎵-砷基板、鉭酸鋰基板等。 In addition, as semiconductor substrates, for example, there can be listed: silicon substrates, sapphire substrates, germanium substrates, gallium-arsenic substrates, gallium-phosphorus substrates, gallium-arsenic-aluminum substrates, gallium-arsenic substrates, lithium tantalum substrates, etc.
另外,電子零件10可為任意用途的電子零件,例如可列舉邏輯用途(例如通信用途、高頻信號處理用途等)、記憶用途、感測器用途、電源用途的電子零件等。該些可僅使用一種,亦可併用兩種以上。
In addition, the
電子零件10的電路形成面10A例如藉由具有電極10B而成為凹凸面。
The
另外,電極10B是於將電子裝置安裝於安裝面時接合於形成於安裝面上的電極上而形成電子裝置與安裝面(印刷基板等的安裝面)之間的電性連接者。
In addition, the
作為電極10B,例如可列舉球凸塊、印刷凸塊、螺栓凸塊、鍍敷凸塊、柱凸塊等凸塊電極。即,電極10B通常為凸電極。該些凸塊電極可單獨使用一種,亦可併用兩種以上。
As the
另外,構成凸塊電極的金屬種並無特別限定,例如可列舉銀、金、銅、錫、鉛、鉍及該些的合金等。該些金屬種可單獨使用一種,亦可併用兩種以上。 In addition, the metal types that constitute the bump electrode are not particularly limited, and examples thereof include silver, gold, copper, tin, lead, bismuth, and alloys thereof. These metal types may be used alone or in combination of two or more.
(步驟(B)) (Step (B))
於貼附於黏著性積層膜50的狀態下,對與電子零件10的電路形成面10A為相反側的面(以下,亦稱為背面)進行背面研磨。
While attached to the
此處,所謂進行背面研磨,是指於不會使電子零件10破裂、或破損的情況下,進行薄化加工至既定的厚度為止。
Here, back grinding refers to thinning to a predetermined thickness without breaking or damaging the
電子零件10的背面研磨可利用公知的方法進行。例如,可列舉於研削機的夾盤等上固定結構體60,對電子零件10的背面(電路非形成面)進行研削的方法。
The back grinding of the
背面研削方式並無特別限定,例如可採用貫穿進給(through feed)方式、切入進給(in feed)方式等公知的研削方式。各種研削是一邊將水供給至電子零件10及研磨石上冷卻一邊進行。
The back grinding method is not particularly limited, and for example, known grinding methods such as through feed method and in feed method can be used. Various grinding methods are performed while supplying water to the
(步驟(C)) (Step (C))
繼而,於貼附於黏著性積層膜50的狀態下,對進行了背面研磨的電子零件10進行全切割。電子零件10的切割可利用公知的方法進行。例如藉由對黏著性積層膜50進行擴張,對進行了半切割的電子零件10進行分割,藉此可對電子零件10進行全切割。
Then, the
僅藉由步驟(A)的半切割,未達到電子零件10被分割為多個電子零件10的程度,於步驟(C)中,藉由黏著性積層膜50的擴張,電子零件10被分割而獲得多個經分割的電子零件10。
The
另外,於本實施形態的電子裝置的製造方法中,於步驟(B)中,於對半切割的電子零件10進行背面研磨時,研削到達半切割的切口,全切割完成的態樣亦包含於對電子零件10進行全切割的
步驟(C)中。
In addition, in the manufacturing method of the electronic device of this embodiment, in step (B), when the back of the half-cut
(步驟(D)) (Step (D))
繼而,於貼附於黏著性積層膜50的狀態下,於經單片化的電子零件10上形成電磁波屏蔽層70。
Then, an electromagnetic
步驟(D)中,例如如圖2(D)所示,於電子零件10中的與電路形成面10A對向的對向面以及連接電路形成面10A與對向面的側面形成電磁波屏蔽層70。
In step (D), for example, as shown in FIG. 2 (D), an electromagnetic
作為於電子零件10上形成電磁波屏蔽層70的方法,並無特別限定,可使用公知的方法。例如,可列舉濺鍍法、蒸鍍法、噴塗法、電鍍法及非電鍍法等。
The method for forming the electromagnetic
作為濺鍍法,例如可列舉直流電(Direct Current,DC)濺鍍法、無線電頻率(Radio Frequency,RF)濺鍍法、磁控濺鍍法、離子束濺鍍法、反應性濺鍍法等。該些可僅使用一種,亦可併用兩種以上。 Examples of sputtering methods include direct current (DC) sputtering, radio frequency (RF) sputtering, magnetron sputtering, ion beam sputtering, and reactive sputtering. Only one of these methods may be used, or two or more of them may be used in combination.
作為蒸鍍法,例如可列舉真空蒸鍍法、化學氣相沈積法(CVD(Chemical Vapor Deposition)法)等。該些可僅使用一種,亦可併用兩種以上。 As the evaporation method, for example, vacuum evaporation method, chemical vapor deposition method (CVD (Chemical Vapor Deposition) method), etc. can be listed. Only one of these methods can be used, or two or more of them can be used in combination.
作為真空蒸鍍法,例如可列舉分子束外延法(MBE(Molecular Beam Epitaxy)法)、物理氣相沈積法(PVD(Physical Vapor Deposition)法)等。該些可僅使用一種,亦可併用兩種以上。 Examples of vacuum deposition methods include molecular beam epitaxy (MBE (Molecular Beam Epitaxy) method) and physical vapor deposition (PVD (Physical Vapor Deposition) method). Only one of these methods may be used, or two or more may be used in combination.
作為CVD法,例如可列舉熱CVD法、觸媒CVD法、光CVD法、電漿CVD法、雷射CVD法、磊晶CVD法、原子層CVD法、 有機金屬CVD法、氯化物CVD法等。該些可僅使用一種,亦可併用兩種以上。 Examples of CVD methods include thermal CVD, catalytic CVD, optical CVD, plasma CVD, laser CVD, epitaxial CVD, atomic layer CVD, organometallic CVD, and chloride CVD. Only one of these methods may be used, or two or more may be used in combination.
該些各種乾式成膜法中,就可將負荷溫度抑制地較低的觀點而言,較佳為磁控濺鍍法、電漿CVD法等。 Among these various dry film forming methods, magnetron sputtering method, plasma CVD method, etc. are preferred from the viewpoint of being able to suppress the load temperature to a lower level.
構成電磁波屏蔽層70的材料較佳為導電性。具體而言,較佳為具有20℃下的電阻率為10000μΩ.cm以下的導電性。所述電阻率更佳為200μΩ.cm以下,尤佳為100μΩ.cm以下。
The material constituting the electromagnetic
構成電磁波屏蔽層70的導電性成分並無特別限定,但較佳為金屬,例如可使用Mg、Al、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Nb、Mo、Ru、Rh、Pd、Ag、In、Sn、Sb、W、Re、Ir、Pt、Au、Bi等金屬、包含選自該些金屬中的兩種以上的金屬的合金、氧化物(ITO(In2O3-SnO2)、ATO(SnO2-Sb)、FTO(SnO2-F)等)等。該些可僅使用一種,亦可併用兩種以上。
The conductive component constituting the electromagnetic
該些中,較佳為包含Au、Pt、Ag、Cu、Ni、Al及Fe中的一種或兩種以上的金屬膜、ITO膜、ATO膜。 Among these, preferred are metal films containing one or more of Au, Pt, Ag, Cu, Ni, Al and Fe, ITO films and ATO films.
電磁波屏蔽層70的膜厚只要可發揮屏蔽特性即可,並無特別限定,較佳為100μm以下,更佳為50μm以下。另一方面,電磁波屏蔽層70的膜厚的下限並無特別限定,較佳為0.5μm以上。
The thickness of the electromagnetic
(步驟(E)) (Step (E))
於在所述步驟(D)中形成電磁波屏蔽層70時,有時藉由濺鍍法或蒸鍍法將凹凸吸收性樹脂層30加溫為高溫。另外,於電鍍法或非電鍍法中,有時藉由對電磁波屏蔽層70進行退火的後步
驟,凹凸吸收性樹脂層30仍然暴露於高溫下。因此,於本實施形態的電子裝置的製造方法中,較佳為於步驟(A)與步驟(D)之間進一步包括步驟(E),所述步驟(E)是藉由使凹凸吸收性樹脂層30交聯而提高凹凸吸收性樹脂層30的耐熱性。藉此,於步驟(D)中即便將黏著性積層膜50暴露於高溫下,亦可更進一步抑制黏著性積層膜50的變形或熔融。若進行步驟(E)的時機為步驟(A)與步驟(D)之間,則並無特別限定,可於任一時機進行。
When the electromagnetic
作為凹凸吸收性樹脂層30的交聯方法,只要為可對交聯性樹脂進行交聯的方法,則並無特別限定,可列舉利用自由基聚合起始劑進行的交聯;利用硫或硫系化合物進行的交聯;利用紫外線或電子束、γ射線等放射線進行的交聯等交聯方法。
As a crosslinking method for the concavoconvex
利用自由基聚合起始劑進行的交聯可使用用於交聯性樹脂的交聯的自由基聚合起始劑。作為自由基聚合起始劑,可將公知的熱自由基聚合起始劑、光自由基聚合起始劑及該些併用。 Crosslinking using a radical polymerization initiator can use a radical polymerization initiator used for crosslinking of a crosslinking resin. As the radical polymerization initiator, a known thermal radical polymerization initiator, a photoradical polymerization initiator, and a combination of these can be used.
於使用硫或硫系化合物對凹凸吸收性樹脂層30進行交聯的情況下,可對凹凸吸收性樹脂層30調配加硫促進劑、加硫促進助劑等而進行交聯。
When sulfur or a sulfur-based compound is used to crosslink the uneven
另外,於任一交聯方法中,可對凹凸吸收性樹脂層30調配交聯助劑而進行凹凸吸收性樹脂層30的交聯。
In addition, in any crosslinking method, a crosslinking aid can be formulated into the uneven
(步驟(F)) (Step (F))
另外,於本實施形態的電子裝置的製造方法中,可於步驟(D)後進一步進行將電子零件10與黏著性積層膜50剝離的步驟(F)。
藉由進行所述步驟(F),可自黏著性積層膜50剝離電子零件10。
In addition, in the manufacturing method of the electronic device of this embodiment, a step (F) of peeling the
電子零件10與黏著性積層膜50的剝離可利用公知的方法來進行。
The
步驟(F)中,較佳為於使黏著性積層膜50中的貼附有電子零件10的區域於膜的面內方向上擴張,使鄰接的電子零件10間的間隔擴大的狀態下,自黏著性積層膜50剝離電子零件10。
In step (F), it is preferred to peel off the
藉此,鄰接的電子零件10間的間隔擴大,因此容易自黏著性積層膜50剝離電子零件10。進而,藉由因黏著性樹脂層40的面內方向的擴張而產生的電子零件10與黏著性樹脂層40的剪切應力,電子零件10與黏著性樹脂層40的黏著力下降,因此容易自黏著性積層膜50剝離電子零件10。
As a result, the distance between adjacent
(步驟(G)) (Step (G))
本實施形態的電子裝置的製造方法中,可進一步進行如下的步驟(G):藉由於步驟(F)之前對黏著性樹脂層40照射放射線,使黏著性樹脂層40進行交聯,而使黏著性樹脂層40對於電子零件10的黏著力下降。若進行步驟(G)的時機為步驟(A)與步驟(F)之間,則並無特別限定,可於任一時機進行。
In the manufacturing method of the electronic device of this embodiment, the following step (G) can be further performed: by irradiating the
藉由進行步驟(G),可容易自黏著性樹脂層40剝離電子零件10。另外,可抑制藉由構成黏著性樹脂層40的黏著成分而污染電子零件10的表面。
By performing step (G), the
放射線例如自黏著性積層膜50的與黏著性樹脂層40側的面為相反側的面照射。
The radiation is irradiated, for example, on the surface of the self-
(其他步驟) (Other steps)
本實施形態的電子裝置的製造方法亦可包括所述以外的其他步驟。其他步驟可使用電子裝置的製造方法中公知的步驟。 The manufacturing method of the electronic device of this embodiment may also include other steps other than those described above. The other steps may use the steps known in the manufacturing method of the electronic device.
例如,於進行背面研磨的步驟(B)後,亦可於研削面(電路非形成面)黏貼保護膜後,對膜進行硬化,而形成背面保護層。 For example, after the back grinding step (B), a protective film may be attached to the ground surface (circuit non-forming surface) and then the film may be hardened to form a back protective layer.
另外,於進行步驟(F)之後,亦可進一步進行將所獲得的電子零件10安裝於安裝基板(印刷基板等)上的步驟,或引線接合(wire bonding)步驟、密封步驟等電子零件的製造步驟中通常進行的任意步驟等。
In addition, after performing step (F), the obtained
以上,已對本發明的實施形態進行了說明,但該些為本發明的例示,亦可採用所述以外的多種構成。 The above has described the implementation forms of the present invention, but these are examples of the present invention, and various structures other than those described above may also be adopted.
再者,本發明並不限定於所述的實施形態,可達成本發明的目的的範圍內的變形、改良等包含於本發明中。 Furthermore, the present invention is not limited to the above-mentioned implementation forms, and modifications and improvements within the scope of achieving the purpose of the present invention are included in the present invention.
本申請案主張以2018年9月20日提出申請的日本申請特願2018-175939號作為基礎的優先權,將其揭示的全部併入本申請案中。 This application claims priority based on Japanese patent application No. 2018-175939 filed on September 20, 2018, and all the disclosures therein are incorporated into this application.
A~D:步驟 A~D: Steps
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