TWI814224B - Photovoltaic module with light guide structure - Google Patents
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Abstract
Description
本發明係關於一種光電轉換裝置,尤其是一種提升太陽光利用率以增加發電量的具有導光結構的太陽能模組。 The present invention relates to a photoelectric conversion device, in particular to a solar module with a light guide structure that improves the utilization rate of sunlight to increase power generation.
太陽能是目前發展快速的再生能源,相較於水力及風力的應用門檻高且受限於設置地點,太陽能發電裝置可以安裝於住宅而容易推廣普及,又,常見的太陽能發電係利用光電效應,由材料吸收光子能量而產生自由電子溢出材料表面,據此,以半導體材料製成的太陽能電池片(Photovoltaic Cell)受到陽光或其他電磁輻射照射後,可以在半導體接面或與金屬的組合部位產生電壓及電流。 Solar energy is a rapidly developing renewable energy source. Compared with water power and wind power, which have high application thresholds and are limited by installation locations, solar power generation devices can be installed in residences and are easily popularized. In addition, common solar power generation systems utilize the photoelectric effect. The material absorbs photon energy and generates free electrons that overflow from the surface of the material. Accordingly, when a solar cell (Photovoltaic Cell) made of semiconductor material is irradiated by sunlight or other electromagnetic radiation, it can generate a voltage at the semiconductor junction or the combination with the metal. and current.
一般的太陽能模組(Photovoltaic Module)係由上述數個太陽能電池片排列成陣列,並將該數個太陽能電池片互相電性連接以收集所產生的電流,惟,相鄰的太陽能電池片之間存在2~10毫米的排列間隙,及用於導引電流的匯流柵線(Finger/Busbar),這些區域未覆蓋光電半導體材料,當然無法吸收太陽光並轉換為電能。習知的太陽能模組在太陽能電池片之間增加反射結構,將原本在間隙處逸散的光線能夠反射至太陽能電池片以增加發電量,但是,在太陽能模組上加工反射結構係提高製造難度及成本,且可能破壞太陽能模組的結構強度,又,該反射結構僅隨機反射光線,難以將光線確實導引至太陽能電池片或其中心位置,導致反射的光線在太陽能電池片表 面呈現分散且不均勻,係無法有效提升習知太陽能模組的總發電量。 A general solar module (Photovoltaic Module) is composed of the above-mentioned several solar cells arranged in an array, and the several solar cells are electrically connected to each other to collect the generated current. However, between adjacent solar cells There is an arrangement gap of 2 to 10 mm and a busbar (finger/busbar) used to guide current. These areas are not covered with optoelectronic semiconductor materials, and of course cannot absorb sunlight and convert it into electrical energy. Conventional solar modules add reflective structures between solar cells to reflect light that originally escapes in the gaps to the solar cells to increase power generation. However, processing reflective structures on solar modules increases manufacturing difficulty. and cost, and may damage the structural strength of the solar module. In addition, the reflective structure only reflects light randomly, making it difficult to guide the light to the solar cell or its center, causing the reflected light to appear on the surface of the solar cell. The surface is scattered and uneven, and the total power generation capacity of the conventional solar module cannot be effectively increased.
有鑑於此,習知的太陽能模組確實仍有加以改善之必要。 In view of this, conventional solar modules still need to be improved.
為解決上述問題,本發明的目的是提供一種具有導光結構的太陽能模組,係可以增加總發電量。 In order to solve the above problems, the purpose of the present invention is to provide a solar module with a light guide structure, which can increase the total power generation capacity.
本發明的次一目的是提供一種具有導光結構的太陽能模組,係可以降低製造難度及生產成本。 A secondary object of the present invention is to provide a solar module with a light guide structure, which can reduce manufacturing difficulty and production costs.
本發明的又一目的是提供一種具有導光結構的太陽能模組,係可以免於加工所造成的模組結構破壞。 Another object of the present invention is to provide a solar module with a light guide structure that can avoid damage to the module structure caused by processing.
本發明全文所述方向性或其近似用語,例如「上(頂)」、「下(底)」、「內」、「外」、「側面」等,主要係參考附加圖式的方向,各方向性或其近似用語僅用以輔助說明及理解本發明的各實施例,非用以限制本發明。 Directionality or similar terms used throughout the present invention, such as "upper (top)", "lower (bottom)", "inner", "outer", "side", etc., mainly refer to the directions of the attached drawings, each of which Directionality or similar terms are only used to assist in explaining and understanding the embodiments of the present invention, but are not intended to limit the present invention.
本發明全文所記載的元件及構件使用「一」或「一個」之量詞,僅是為了方便使用且提供本發明範圍的通常意義;於本發明中應被解讀為包括一個或至少一個,且單一的概念也包括複數的情況,除非其明顯意指其他意思。 The use of the quantifier "a" or "an" in the elements and components described throughout the present invention is only for convenience of use and to provide a common sense of the scope of the present invention; in the present invention, it should be interpreted as including one or at least one, and single The concept of also includes the plural unless it is obvious that something else is meant.
本發明的具有導光結構的太陽能模組,包含:數個太陽能電池片,以陣列方式排列於同一平面上;數個導光結構,各該導光結構位於相鄰二該太陽能電池片之間的間隙,各該導光結構係由一高折射率材料包覆一低折射率材料,該高折射率材料的折射率大於該低折射率材料,該低折射率材料係形成並列的數個柱狀結構,各該柱狀結構的橫截面係一幾何形狀,該幾何形狀具有至少一斜邊朝向鄰近之該太陽能電池片,當一光線照射於該太陽 能模組,部份該光線照射於該數個太陽能電池片,另一部份該光線照射該數個導光結構,並在各該柱狀結構以該斜邊所延伸的側面發生全反射,且該光線會在各該導光結構發生數次折射及反射,而被導引至鄰近之太陽能電池片;二保護膜,分別貼合於該數個太陽能電池片及該數個導光結構的上、下表面,該二保護膜封裝該數個導光結構固定於該數個太陽能電池片之間;及二覆蓋層,分別位於該數個太陽能電池片及該數個導光結構的上、下兩面,各該覆蓋層貼合於各該保護膜的外側表面,該光線穿透至少一該覆蓋層,該光線在該覆蓋層與空氣的交界面再做一次全反射後,進入該太陽能電池片。 The solar module with a light guide structure of the present invention includes: several solar cells arranged in an array on the same plane; several light guide structures, each light guide structure is located between two adjacent solar cells. gap, each light guide structure is made of a high refractive index material covering a low refractive index material. The refractive index of the high refractive index material is greater than the low refractive index material. The low refractive index material forms several columns in parallel. The cross-section of each columnar structure is a geometric shape, and the geometric shape has at least one bevel facing the adjacent solar cell. When a light shines on the sun In the energy module, part of the light irradiates the plurality of solar cells, and another part of the light irradiates the plurality of light guide structures, and total reflection occurs on the side of each columnar structure where the hypotenuse extends, And the light will be refracted and reflected several times in each light guide structure, and then be guided to adjacent solar cells; two protective films are respectively attached to the solar cells and the light guide structures. On the upper and lower surfaces, the two protective films encapsulate the light guide structures and are fixed between the solar cells; and the two covering layers are respectively located on the solar cells and the light guide structures. On the lower two sides, each covering layer is attached to the outer surface of each protective film. The light penetrates at least one of the covering layers. The light enters the solar cell after total reflection at the interface between the covering layer and the air. piece.
據此,本發明的具有導光結構的太陽能模組,藉由在太陽能電池片陣列的間隙設置該導光結構,使照射於該導光結構的光線經由兩次全反射後抵達太陽能電池片,係可以將原本會穿過間隙而散逸的光線導引至太陽能電池片,以增加太陽能模組能夠接收的光通量及發電總量,又,該導光結構可以預先量產,並在太陽能模組的封裝過程中設置於數個太陽能電池片之間,不需要在太陽能模組上加工反射結構,係具有降低製造難度、節省成本及維持結構強度等功效。 Accordingly, in the solar module with a light guide structure of the present invention, by arranging the light guide structure in the gap of the solar cell array, the light irradiated on the light guide structure reaches the solar cells after two total reflections. The system can guide the light that would otherwise escape through the gap to the solar cells to increase the luminous flux that the solar module can receive and the total amount of power generated. In addition, the light guide structure can be mass-produced in advance and installed on the solar module. During the packaging process, it is placed between several solar cells and does not require processing of reflective structures on the solar module. This has the effect of reducing manufacturing difficulty, saving costs and maintaining structural strength.
其中,該幾何形狀為直角三角形,該斜邊係直角的對邊,該斜邊兩端分別為直角三角形的另外兩角,係一第一夾角及一第二夾角,該第一夾角相對靠近該光線入射端,而該第二夾角相對遠離該光線入射端,該第一夾角的角度是42度~46度,該第二夾角為該第一夾角的餘角。如此,各該柱狀結構對立於反射面的另一面為垂直平面,係可以避免二次全內反射導致光線逸散回空氣中,係具有增加光線被導引至太陽能電池之比率的功效。 Wherein, the geometric shape is a right-angled triangle, the hypotenuse is the opposite side of the right angle, and the two ends of the hypotenuse are the other two angles of the right-angled triangle, which are a first included angle and a second included angle, and the first included angle is relatively close to the The light incident end, and the second included angle is relatively far away from the light incident end, the first included angle is 42 degrees to 46 degrees, and the second included angle is the supplementary angle of the first included angle. In this way, the other side of each columnar structure opposite to the reflective surface is a vertical plane, which can prevent the light from escaping back into the air due to secondary total internal reflection, and has the effect of increasing the rate of light being directed to the solar cell.
其中,該幾何形狀是平行四邊形、菱形、上半部三角形結合下半部三角形或上半部三角形結合下半部半圓。如此,各該柱狀結構具有一個以上的反射面,由太陽能模組下方入射的光線係可以被導引,係具有收集散 射光線用於轉換電能的功效。 Wherein, the geometric shape is a parallelogram, a rhombus, an upper half triangle combined with a lower half triangle, or an upper half triangle combined with a lower half semicircle. In this way, each columnar structure has more than one reflective surface, and the light incident from below the solar module can be guided, and has the ability to collect and disperse light. Radiation light is used to convert electrical energy.
其中,該低折射率材料所形成的該數個柱狀結構緊密排列於同一平面上,且該平面係平行該數個太陽能電池片所排列的平面,各該柱狀結構的延伸方向平行於鄰近之該太陽能電池片的邊緣。如此,照射於間隙的光線被該導光結構反射後,係可以均勻照射於該太陽能電池片,係具有光通量均勻作用光電轉換的功效。 Wherein, the plurality of columnar structures formed by the low refractive index material are closely arranged on the same plane, and the plane is parallel to the plane on which the plurality of solar cells are arranged, and the extension direction of each columnar structure is parallel to the adjacent one. the edge of the solar cell. In this way, after the light irradiating the gap is reflected by the light guide structure, it can be irradiated uniformly on the solar cell sheet, which has the effect of uniform luminous flux and photoelectric conversion.
其中,該導光結構之寬度為2毫米~10毫米,各該柱狀結構的寬度是0.125毫米~1毫米。如此,該導光結構可以依據所在的太陽能模組規格調整尺寸,以填滿電池片之間的間隙且包含數個柱狀結構,係具有製造及安裝便利的功效。 The width of the light guide structure is 2 mm to 10 mm, and the width of each columnar structure is 0.125 mm to 1 mm. In this way, the size of the light guide structure can be adjusted according to the specifications of the solar module to fill the gaps between the cells and includes several columnar structures, which is convenient for manufacturing and installation.
其中,該二覆蓋層為透光玻璃,各該覆蓋層的折射率大於或等於該高折射率材料。如此,光線係可以通過該高折射率材料與該二覆蓋層的交界面向外射出,並在該覆蓋層與空氣的交界面形成全反射,係具有導引光線反射至電池片靠中心位置的功效。 Wherein, the two covering layers are light-transmitting glass, and the refractive index of each covering layer is greater than or equal to the high refractive index material. In this way, light can be emitted outward through the interface between the high refractive index material and the two covering layers, and total reflection is formed at the interface between the covering layer and the air, which has the effect of guiding the reflected light to the center of the cell piece. .
其中,上層之該覆蓋層為透光玻璃且直接面對該光線照射,下層之該覆蓋層為背板,上層之該覆蓋層的折射率大於或等於該高折射率材料。如此,逸散至下層的光線係可以由背板反射回到太陽能電池片,係具有提升光利用率的功效。 Wherein, the covering layer of the upper layer is made of light-transmitting glass and directly faces the light irradiation, the covering layer of the lower layer is a back plate, and the refractive index of the covering layer of the upper layer is greater than or equal to the high refractive index material. In this way, the light that escapes to the lower layer can be reflected back to the solar cell through the backsheet, which has the effect of improving light utilization efficiency.
其中,該二保護膜是熱固化熱融膠膜。如此,該二保護膜固化後具有高透光性、耐衝擊性及柔韌性,係可以保護該數個太陽能電池片免於環境破壞,還可以封裝固定該數個導光結構在正確的位置上,係具有延長太陽能模組使用壽命的功效。 Wherein, the two protective films are heat-curing hot-melt adhesive films. In this way, after curing, the two protective films have high light transmittance, impact resistance and flexibility, can protect the solar cells from environmental damage, and can also encapsulate and fix the light guide structures in the correct position. , which has the effect of extending the service life of solar modules.
1:太陽能電池片 1: Solar cells
2:導光結構 2:Light guide structure
21:高折射率材料 21:High refractive index materials
22:低折射率材料 22: Low refractive index materials
3:覆蓋層 3: Covering layer
4:保護膜 4: Protective film
H:斜邊 H: hypotenuse
α:第一夾角 α: first included angle
β:第二夾角 β: the second included angle
L:光線 L:Light
〔第1圖〕本發明較佳實施例的組合立體圖。 [Figure 1] A combined perspective view of a preferred embodiment of the present invention.
〔第2圖〕沿第1圖的A-A線剖面圖。 [Figure 2] Cross-sectional view along line A-A in Figure 1.
〔第3圖〕如第2圖所示的B區域局部構造放大圖。 [Picture 3] An enlarged view of the local structure of area B shown in Figure 2.
為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,並配合所附圖式作詳細說明;此外,在不同圖式中標示相同符號者視為相同,會省略其說明。 In order to make the above and other objects, features and advantages of the present invention more obvious and understandable, preferred embodiments of the present invention are illustrated below and described in detail with reference to the accompanying drawings; in addition, the same symbols are used in different drawings. are considered to be the same and their description will be omitted.
請參照第1及2圖所示,其係本發明具有導光結構的太陽能模組的較佳實施例,係包含數個太陽能電池片1、數個導光結構2及二覆蓋層3,各該導光結構2位於相鄰二該太陽能電池片1之間的間隙,該二覆蓋層3分別位於該數個太陽能電池片1及該數個導光結構2的上、下兩面。
Please refer to Figures 1 and 2, which is a preferred embodiment of a solar module with a light guide structure of the present invention, which includes a plurality of
該數個太陽能電池片1係用於將光能轉換為電能,由於單獨一片太陽能電池片1能夠轉換的功率及電壓值有限,為了符合用電需求,通常以陣列方式排列該數個太陽能電池片1於同一平面上,並設置於光通量充足且均勻的地點,使各該太陽能電池片1的發電量穩定,再以串聯及並聯方式匯流該數個太陽能電池片1的發電量,又,該數個太陽能電池片1之間存在陣列間隙及匯流導線的區域,係無法由該數個太陽能電池片1直接吸收光能。
The several
請參照第2及3圖所示,該數個導光結構2分別位於該數個太陽能電池片1之間的間隙,各該導光結構係由一高折射率材料21包覆一低折射率材料22,該高折射率材料21的折射率(Refractive Index)大於該低折射率材料22,該高折射率材料21可以是玻璃、聚甲基丙烯酸甲酯(Polymethyl Methacrylate,PMMA)、環氧樹脂(Epoxy)或液態光學膠(Liquid Optically
Clear Adhesive,LOCA)等,該低折射率材料22可以是空腔(空氣或真空)或聚二甲基矽氧烷(Polydimethylsiloxane,PDMS)等,該低折射率材料22係形成並列的數個柱狀結構,各該柱狀結構的橫截面係一幾何形狀,該幾何形狀具有至少一斜邊H朝向鄰近之該太陽能電池片1,如第3圖所示,在本實施例中係以該幾何形狀為直角三角形作說明,該幾何形狀還可以是平行四邊形、菱形、上半部三角形結合下半部三角形、上半部三角形結合下半部半圓等,本發明不以此為限。該幾何形狀為直角三角形則該斜邊H係直角的對邊,該斜邊H兩端分別為直角三角形的另外兩角,係一第一夾角α及一第二夾角β,該第一夾角α與該第二夾角β互為餘角(角度和為90度),該第一夾角α係相對靠近光線入射端,而該第二夾角β係相對遠離光線入射端。該第一夾角α的角度可以是42度~46度,較佳為42度;該第二夾角β的角度可以是44度~48度,較佳為48度。
Please refer to Figures 2 and 3. The
另外,該低折射率材料22所形成的數個柱狀結構較佳緊密排列於同一平面上而互不重疊,且該平面較佳與該數個太陽能電池片1所排列的平面呈平行,又,各該柱狀結構的延伸方向較佳平行於鄰近之該太陽能電池片1的邊緣,係可以完整收集照射於間隙的光線,並使導引後的光線均勻照射於該太陽能電池片1。各該柱狀結構係以該斜邊H所延伸的側面為一反射面,該反射面係該高折射率材料21與該低折射率材料22的交界面,由於該高折射率材料21的折射率大於該低折射率材料22,特定角度的入射光係可以在該反射面形成全反射。
In addition, the plurality of columnar structures formed by the low
上述各該柱狀結構的寬度可以是0.125毫米~1毫米,而該導光結構2之寬度為2毫米~10毫米,以10毫米寬度為例,該導光結構2最多可以包含80個0.125毫米的柱狀結構,且至少可以包含10個1毫米的柱狀結構。
The width of each of the above-mentioned columnar structures can be 0.125 mm ~ 1 mm, and the width of the
該導光結構2可以由軟微影技術(Soft Lithography)製造,係在具有該數個柱狀結構的模具上,塗布該高折射率材料21,例如:液態光學膠,係以紫外光照射使液態光學膠固化,脫模後在凸起部位塗膠以連接相同材質所製成的平面薄膜,再次固化後形成具有柱狀空腔的導光結構2,其低折射率材料22為空氣。
The
該二覆蓋層3係可以上、下雙層皆為透光玻璃,也可以上層(正面,光源照射面)為透光玻璃,下層(背面)為太陽能背板,該二覆蓋層3係用於防止高溫、濕氣、酸蝕及衝擊等外在環境傷害對各該太陽能電池片1造成損壞,又,各該覆蓋層3為透光玻璃,使光線能夠通過玻璃且其折射率大於外界環境之空氣,當光線由該二覆蓋層3之間向外射出時,在該覆蓋層3與空氣的交界面,係由光的密介質到光的疏介質,使特定角度的光線可以在該交界面形成全反射。各該覆蓋層3的折射率可以大於或等於該高折射率材料21;該低折射率材料22的折射率可以大於或等於空氣。
The two covering
本發明的太陽能模組還可以具有二保護膜4,該二保護膜4分別緊密貼合於該數個太陽能電池片1及該數個導光結構2的上、下表面,該二覆蓋層3再貼合於該二保護膜4的外側表面,該二保護膜4可以是熱固化熱融膠膜,例如:乙酸/醋酸乙烯酯共聚物(Ethylene Vinyl Acetate,EVA),該二保護膜4經熱壓後可以良好黏接金屬、玻璃及塑膠,且固化後的該二保護膜4具有高透光性、耐衝擊性及柔韌性,係可以保護該數個太陽能電池片1免於環境破壞,還可以封裝固定該數個導光結構2在正確的位置上,且該二保護膜4完全透明係不會影響光線入射,具有延長太陽能模組使用壽命及提升發電效率的作用。
The solar module of the present invention can also have two protective films 4. The two protective films 4 are closely attached to the upper and lower surfaces of the plurality of
請參照第2及3圖所示,當一光線L照射於太陽能模組,通過該覆蓋層3及該保護膜4後,散佈於該數個太陽能電池片1上的光線L能夠
轉換為電能,而分散至該數個太陽能電池片1之間的間隙上的光線L,會在各該導光結構2發生數次折射及反射,以重新被導引至鄰近之太陽能電池片1,最靠近各該太陽能電池片1之該柱狀結構的反射面(該斜邊H所延伸的側面)所反射的光線,能夠在該覆蓋層3與空氣的交界面再做一次全反射後,進入該太陽能電池片1;如第3圖所示,其餘柱狀結構的反射面所反射的光線,則必須反覆穿過數個該柱狀結構後,再依序到達該覆蓋層3及該太陽能電池片1,該導光結構2係可以增加該太陽能電池片1所接收到的光通量。請參照表一所示,其係具有本發明之導光結構的太陽能模組相較於無導光結構的太陽能模組,對於不同角度的入射光所能夠轉換的輻射通量(Radiant Flux)。
Please refer to Figures 2 and 3. When a light L irradiates the solar module and passes through the
由表一可知,當光線直射於太陽能模組時,能夠接收並轉換的功率為極大值,而使用導光結構係可以使功率再提升13.31%,但是,日光照射的角度係隨時間做週期變化,而越接近日出或日落的照射偏斜角度越大,導致相對應可接收到的功率也越小,此時使用導光結構仍可以提升功率,惟,光照的偏斜角度越大,功率所能夠提升的比例越小。總結來說,以一整天的日照情形統計,使用導光結構係可以提升太陽能模組5.77%的發電量。 It can be seen from Table 1 that when light shines directly on the solar module, the power that can be received and converted is a maximum value. Using a light guide structure can increase the power by another 13.31%. However, the angle of sunlight changes periodically with time. , and the closer to sunrise or sunset, the greater the deflection angle of the illumination, resulting in the smaller the corresponding power that can be received. At this time, using a light guide structure can still increase the power, but the greater the deflection angle of the illumination, the lower the power The smaller the proportion that can be improved. In summary, based on a whole day's sunshine statistics, the use of light guide structures can increase the power generation of solar modules by 5.77%.
綜上所述,本發明的具有導光結構的太陽能模組,藉由在太陽能電池片陣列的間隙設置該導光結構,使照射於該導光結構的光線經由兩次全反射後抵達太陽能電池片,係可以將原本會穿過間隙而散逸的光線導引至太陽能電池片,以增加太陽能模組能夠接收的光通量及發電總量,又,該導光結構可以預先量產,並在太陽能模組的封裝過程中設置於數個太陽能電池片之間,不需要在太陽能模組上加工反射結構,係具有降低製造難度、節省成本及維持結構強度等功效。 To sum up, the solar module with a light guide structure of the present invention disposes the light guide structure in the gap of the solar cell array, so that the light irradiated on the light guide structure reaches the solar cell after two total reflections. The light guide structure can guide the light that would otherwise escape through the gap to the solar cells to increase the luminous flux that the solar module can receive and the total power generation. In addition, the light guide structure can be mass-produced in advance and installed on the solar module. During the packaging process of the group, it is placed between several solar cells. There is no need to process reflective structures on the solar module, which has the effect of reducing manufacturing difficulty, saving costs and maintaining structural strength.
雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當包含後附之申請專利範圍所記載的文義及均等範圍內之所有變更。 Although the present invention has been disclosed using the above-mentioned preferred embodiments, they are not intended to limit the invention. Anyone skilled in the art can make various changes and modifications to the above-described embodiments without departing from the spirit and scope of the invention. The technical scope protected by the invention, therefore, the protection scope of the invention shall include all changes within the literal and equivalent scope described in the appended patent application scope.
1:太陽能電池片 1: Solar cells
2:導光結構 2:Light guide structure
3:覆蓋層 3: Covering layer
4:保護膜 4: Protective film
L:光線 L:Light
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TW201024825A (en) * | 2008-09-18 | 2010-07-01 | Qualcomm Mems Technologies Inc | Increasing the angular range of light collection in solar collectors/concentrators |
TW201101516A (en) * | 2009-06-30 | 2011-01-01 | Thinsilicon Corp | Photovoltaic modules and methods of manufacturing photovoltaic modules having multiple semiconductor layer stacks |
TW201128146A (en) * | 2010-02-10 | 2011-08-16 | Tennrich Int Corp | Solar energy module |
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TW201024825A (en) * | 2008-09-18 | 2010-07-01 | Qualcomm Mems Technologies Inc | Increasing the angular range of light collection in solar collectors/concentrators |
TW201101516A (en) * | 2009-06-30 | 2011-01-01 | Thinsilicon Corp | Photovoltaic modules and methods of manufacturing photovoltaic modules having multiple semiconductor layer stacks |
TW201128146A (en) * | 2010-02-10 | 2011-08-16 | Tennrich Int Corp | Solar energy module |
TW201630204A (en) * | 2015-02-03 | 2016-08-16 | Sunvalue Co Ltd | Solar panel module without outer frame and manufacturing method of the same |
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