TWI789582B - Memory device - Google Patents
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Description
本發明是有關於一種記憶元件。The present invention relates to a memory element.
隨著科技日新月異,電子元件的進步增加了對更大儲存能力的需要。為了滿足高儲存密度(high storage density)的需求,記憶體元件尺寸變得更小而且積集度更高。因此,記憶體元件的型態已從平面型閘極(planar gate)結構的二維記憶體元件(2D memory device)發展到具有垂直通道(vertical channel,VC)結構的三維記憶體元件(3D memory device)。As technology advances with each passing day, advances in electronic components have increased the need for greater storage capacity. In order to meet the demand of high storage density (high storage density), the size of memory components has become smaller and more densely packed. Therefore, the type of memory device has developed from a planar gate (2D memory device) structure to a 3D memory device (3D memory device) with a vertical channel (vertical channel, VC) structure. device).
然而,隨著複合膜堆疊(composite film stack)的堆疊層數增加,具有高高寬比(high aspect ratio)的複合膜堆疊的彎曲現象也變得越來越嚴重。嚴重的彎曲現象甚至會導致位元線與頂部字元線之間的短路,進而影響記憶元件的運作。因此,如何發展出一種高積集度之記憶元件及其製造方法,以減少複合膜堆疊的彎曲現象將成為未來重要的一門課題。However, as the number of stacked layers of the composite film stack increases, the bending phenomenon of the composite film stack with high aspect ratio becomes more and more serious. Severe bending can even cause a short circuit between the bit line and the top word line, thereby affecting the operation of the memory device. Therefore, how to develop a high-density memory element and its manufacturing method to reduce the bending phenomenon of the composite film stack will become an important issue in the future.
本發明提供一種記憶元件及其製造方法,其將兩組垂直通道結構之間的狹縫分成多個子狹縫,以強化記憶元件的機械強度,進而減少記憶元件之堆疊結構的彎曲現象。The invention provides a memory element and its manufacturing method, which divides the slit between two sets of vertical channel structures into multiple sub-slits to enhance the mechanical strength of the memory element and reduce the bending phenomenon of the stacked structure of the memory element.
本發明提供一種記憶元件,包括:基底、堆疊結構、第一組垂直通道結構、第二組垂直通道結構以及第一狹縫。堆疊結構配置在基底上。第一組垂直通道結構與第二組垂直通道結構沿著Y方向排列,且貫穿堆疊結構以與基底接觸。第一狹縫配置在第一組垂直通道結構與第二組垂直通道結構之間,且貫穿堆疊結構以暴露出基底。第一狹縫包括多個第一子狹縫,其沿著X方向離散配置。The invention provides a memory element, including: a base, a stack structure, a first group of vertical channel structures, a second group of vertical channel structures and a first slit. The stack structure is configured on the base. The first group of vertical channel structures and the second group of vertical channel structures are arranged along the Y direction and penetrate through the stacked structure to contact the substrate. The first slit is disposed between the first set of vertical channel structures and the second set of vertical channel structures, and runs through the stacked structures to expose the base. The first slit includes a plurality of first sub-slits which are discretely arranged along the X direction.
在本發明的一實施例中,上述的基底包括陣列區與階梯區,第一組垂直通道結構與第二組垂直通道結構配置在陣列區的基底上。In an embodiment of the present invention, the above-mentioned substrate includes an array area and a stepped area, and the first group of vertical channel structures and the second group of vertical channel structures are disposed on the substrate of the array area.
在本發明的一實施例中,上述的記憶元件,更包括第一串選擇線切割位於離散的多個第一子狹縫之間。In an embodiment of the present invention, the above-mentioned memory device further includes a first string of selection line cuts located between a plurality of discrete first sub-slits.
在本發明的一實施例中,上述的第一串選擇線切割至少延伸超過階梯區中的第一行接觸窗。In an embodiment of the present invention, the above-mentioned first series of selection line cuts at least extend beyond the first row of contact windows in the step region.
在本發明的一實施例中,上述的堆疊結構包括沿著Z方向交替堆疊的多個導體層與多個介電層,最頂層的導體層為串選擇線(SSL)以控制第一組垂直通道結構與第二組垂直通道結構開關。In an embodiment of the present invention, the above-mentioned stack structure includes a plurality of conductor layers and a plurality of dielectric layers alternately stacked along the Z direction, and the topmost conductor layer is a string selection line (SSL) to control the first group of vertical The channel structure switches with the second set of vertical channel structures.
在本發明的一實施例中,上述的記憶元件,更包括:第二串選擇線切割,內埋在串選擇線中,且沿著X方向延伸以將第一組垂直通道結構分成兩個第一群組;以及第三串選擇線切割,內埋在串選擇線中,且沿著X方向延伸以將第二組垂直通道結構分成兩個第二群組。In an embodiment of the present invention, the above-mentioned memory element further includes: a second string selection line cut, embedded in the string selection line, and extending along the X direction to divide the first set of vertical channel structures into two second string selection lines. a group; and a third string selection line cut embedded in the string selection line and extending along the X direction to divide the second group of vertical channel structures into two second groups.
在本發明的一實施例中,上述的記憶元件,更包括兩個第二狹縫分別配置在第一組垂直通道結構的第一側與第二組垂直通道結構的相對於第一側的第二側,且貫穿堆疊結構以暴露出基底,其中兩個第二狹縫分別沿著X方向自陣列區連續延伸至階梯區中。In an embodiment of the present invention, the above-mentioned memory element further includes two second slits respectively disposed on the first side of the first group of vertical channel structures and on the second side of the second group of vertical channel structures opposite to the first side. two sides, and through the stack structure to expose the base, wherein the two second slits respectively extend continuously from the array area to the step area along the X direction.
在本發明的一實施例中,上述的兩個第二狹縫中的一者的長度大於多個第一子狹縫的長度總合。In an embodiment of the present invention, the length of one of the above-mentioned two second slits is greater than the sum of the lengths of the plurality of first sub-slits.
在本發明的一實施例中,上述的多個第一子狹縫的長度總合與兩個第二狹縫中的一者的長度的比介於0.35至0.9之間。In an embodiment of the present invention, the ratio of the sum of the lengths of the plurality of first sub-slits to the length of one of the two second slits is between 0.35 and 0.9.
在本發明的一實施例中,上述的記憶元件,更包括:第三組垂直通道結構與第四組垂直通道結構,與第一組垂直通道結構與第二組垂直通道結構沿著Y方向排列,且貫穿堆疊結構以與基底接觸;第三狹縫,配置在第二組垂直通道結構與第三組垂直通道結構之間,且貫穿堆疊結構以暴露出基底,其中第三狹縫包括多個第三子狹縫,其沿著X方向離散配置;以及第四狹縫,配置在第三組垂直通道結構與第四組垂直通道結構之間,且貫穿堆疊結構以暴露出基底,其中第四狹縫包括多個第四子狹縫,其沿著X方向離散配置。In an embodiment of the present invention, the above-mentioned memory element further includes: a third group of vertical channel structures and a fourth group of vertical channel structures, arranged along the Y direction with the first group of vertical channel structures and the second group of vertical channel structures , and penetrate the stack structure to contact the substrate; the third slit is configured between the second group of vertical channel structures and the third group of vertical channel structures, and penetrates the stack structure to expose the substrate, wherein the third slit includes a plurality of The third sub-slits are discretely arranged along the X direction; and the fourth slits are arranged between the third group of vertical channel structures and the fourth group of vertical channel structures, and penetrate through the stacked structure to expose the substrate, wherein the fourth The slit includes a plurality of fourth sub-slits which are discretely arranged along the X direction.
在本發明的一實施例中,上述的記憶元件,更包括:第四串選擇線切割,內埋在串選擇線中,且位於多個第三子狹縫之間。In an embodiment of the present invention, the above-mentioned memory device further includes: a fourth string selection line cut, embedded in the string selection line, and located between the plurality of third sub-slits.
本發明提供一種記憶元件的製造方法,包括:在基底上形成堆疊層,其中堆疊層包括交替堆疊的多個第一材料與多個第二材料;在最頂層的第二材料中形成沿著X方向延伸的串選擇線切割;在串選擇線切割的兩側分別形成第一組垂直通道結構與第二組垂直通道結構,其貫穿堆疊層以與基底接觸;以及第一組垂直通道結構與第二組垂直通道結構之間形成第一狹縫,其中第一狹縫貫穿堆疊層以暴露出基底,第一狹縫包括沿著X方向離散配置的多個子狹縫,且串選擇線切割被第一狹縫分隔成多個第一串選擇線切割,其中多個第一串選擇線切割位於多個子狹縫之間且沿著X方向離散配置。The invention provides a method for manufacturing a memory element, comprising: forming a stacked layer on a substrate, wherein the stacked layer includes a plurality of first materials and a plurality of second materials stacked alternately; The string selection line extending in the direction is cut; the first group of vertical channel structures and the second group of vertical channel structures are respectively formed on both sides of the string selection line cutting, which penetrate the stacked layer to contact the substrate; and the first group of vertical channel structures and the second group of vertical channel structures A first slit is formed between two sets of vertical channel structures, wherein the first slit penetrates the stacked layer to expose the substrate, the first slit includes a plurality of sub-slits discretely arranged along the X direction, and the string selection line is cut by the second A slit is divided into a plurality of first strings of selected wire cuts, wherein the plurality of first strings of selected wire cuts are located between the plurality of sub-slits and are discretely arranged along the X direction.
在本發明的一實施例中,上述的記憶元件的製造方法更包括:進行蝕刻製程,移除多個第二材料,以在多個第一材料之間形成多個空隙;以及於多個空隙中形成多個導體層,使得多個導體層環繞第一組垂直通道結構與第二組垂直通道結構。In an embodiment of the present invention, the above method of manufacturing a memory device further includes: performing an etching process to remove a plurality of second materials to form a plurality of gaps between the plurality of first materials; A plurality of conductor layers are formed, so that the plurality of conductor layers surround the first group of vertical channel structures and the second group of vertical channel structures.
在本發明的一實施例中,上述的形成串選擇線切割包括:形成第二串選擇線切割,以將第一組垂直通道結構分成兩個第一群組;以及形成第三串選擇線切割,以將以將第二組垂直通道結構分成兩個第二群組。In an embodiment of the present invention, the formation of the string selection line cut includes: forming a second string selection line cut to divide the first group of vertical channel structures into two first groups; and forming a third string selection line cut , to divide the second set of vertical channel structures into two second groups.
在本發明的一實施例中,上述的基底包括陣列區與階梯區,第一組垂直通道結構與第二組垂直通道結構形成在階梯區的基底上,且多個第一串選擇線切割與第一狹縫自陣列區延伸至階梯區中。In an embodiment of the present invention, the above-mentioned substrate includes an array area and a stepped area, the first set of vertical channel structures and the second set of vertical channel structures are formed on the base of the stepped area, and a plurality of first string selection lines cutting and The first slit extends from the array area to the step area.
在本發明的一實施例中,上述的形成第一狹縫包括:在第一組垂直通道結構的第一側處與第二組垂直通道結構的相對於第一側的第二側處分別形成兩個第二狹縫,兩個第二狹縫貫穿堆疊層以暴露出基底,其中兩個第二狹縫分別沿著X方向自陣列區連續延伸至階梯區中。In an embodiment of the present invention, the above-mentioned forming of the first slit includes: respectively forming Two second slits, the two second slits penetrate through the stacked layer to expose the base, wherein the two second slits respectively extend continuously from the array area to the step area along the X direction.
在本發明的一實施例中,上述的形成第一組垂直通道結構與第二組垂直通道結構包括:形成貫穿階梯區的堆疊層的多組虛擬垂直通道結構,以與階梯區的基底接觸。In an embodiment of the present invention, the formation of the first set of vertical channel structures and the second set of vertical channel structures includes: forming a plurality of sets of virtual vertical channel structures penetrating through the stacked layers of the step region to contact the base of the step region.
在本發明的一實施例中,上述的多個第一串選擇線切割與多個第二材料具有不同材料或是具有不同蝕刻選擇性的材料。In an embodiment of the present invention, the above-mentioned plurality of first string selective wire cuts and the plurality of second materials have different materials or materials with different etching selectivities.
本發明提供一種記憶元件,包括:基底、堆疊結構、第一組垂直通道結構、第二組垂直通道結構以及隔離結構。堆疊結構配置在基底上。第一組垂直通道結構與第二組垂直通道結構沿著Y方向排列,且貫穿堆疊結構以與基底接觸。隔離結構配置在第一組垂直通道結構與第二組垂直通道結構之間。隔離結構包括沿著X方向交替排列的多個子狹縫與多個串選擇線切割。The invention provides a memory element, including: a base, a stack structure, a first group of vertical channel structures, a second group of vertical channel structures and an isolation structure. The stack structure is configured on the base. The first group of vertical channel structures and the second group of vertical channel structures are arranged along the Y direction and penetrate through the stacked structure to contact the substrate. The isolation structure is disposed between the first group of vertical channel structures and the second group of vertical channel structures. The isolation structure includes a plurality of sub-slits and a plurality of string selection line cuts arranged alternately along the X direction.
在本發明的一實施例中,上述的記憶元件更包括第二狹縫配置在第一組垂直通道結構的第一側,且貫穿堆疊結構以暴露出基底,其中第二狹縫沿著X方向連續延伸,且第二狹縫的長度大於多個子狹縫的長度總合。In an embodiment of the present invention, the above-mentioned memory element further includes a second slit disposed on the first side of the first group of vertical channel structures, and penetrates through the stacked structure to expose the substrate, wherein the second slit is along the X direction extending continuously, and the length of the second slit is greater than the sum of the lengths of the multiple sub-slits.
基於上述,本發明實施例將連續延伸的第一狹縫替換成沿著X方向離散配置的多個第一子狹縫。在高高寬比的堆疊結構的情況下,第一子狹縫之間的第一串選擇線切割與部分堆疊結構可強化整個記憶元件的機械強度,以在一連串的製程(例如濕式蝕刻製程、膜沉積製程以及熱製程等)期間減少堆疊結構的彎曲現象,進而提升記憶元件的良率與可靠度。另外,第一子狹縫與其之間的第一串選擇線切割可視為一種隔離結構,以電性分隔第一組垂直通道結構與第二組垂直通道結構,進而增加記憶元件操作的彈性。Based on the above, the embodiment of the present invention replaces the continuously extending first slits with a plurality of first sub-slits discretely arranged along the X direction. In the case of a high aspect ratio stack structure, the first string of selective wire cuts between the first sub-slits and the partial stack structure can strengthen the mechanical strength of the entire memory device to withstand a series of processes (such as wet etching process , film deposition process and thermal process, etc.) to reduce the bending phenomenon of the stacked structure, thereby improving the yield and reliability of the memory device. In addition, the first sub-slit and the first series of selection line cuts therebetween can be regarded as an isolation structure to electrically separate the first group of vertical channel structures from the second group of vertical channel structures, thereby increasing the flexibility of the operation of the memory device.
參照本實施例之圖式以更全面地闡述本發明。然而,本發明亦可以各種不同的形式體現,而不應限於本文中之實施例。圖式中的層與區域的厚度會為了清楚起見而放大。相同或相似之標號表示相同或相似之元件,以下段落將不再一一贅述。The present invention will be described more fully with reference to the drawings of this embodiment. However, the present invention can also be embodied in various forms and should not be limited to the embodiments herein. The thicknesses of layers and regions in the drawings may be exaggerated for clarity. The same or similar symbols indicate the same or similar elements, and the following paragraphs will not repeat them one by one.
圖1是依照本發明第一實施例的一種記憶元件的上視示意圖。以下實施例中所述記憶元件可以是反及(NAND)快閃記憶體,但本發明不以此為限。在其他實施例中,所述的記憶元件亦可以是反或(NOR)快閃記憶體、唯讀(ROM)記憶體或其他三維記憶體。FIG. 1 is a schematic top view of a memory device according to a first embodiment of the present invention. The memory element described in the following embodiments may be a NAND flash memory, but the present invention is not limited thereto. In other embodiments, the memory element may also be a Negative OR (NOR) flash memory, a Read Only (ROM) memory or other three-dimensional memory.
請參照圖1,本發明第一實施例的記憶元件1包括:基底100、堆疊結構202、第一組垂直通道結構VC1、第二組垂直通道結構VC2、多組虛擬垂直通道結構DVC、第一狹縫12a以及第二狹縫12b。具體來說,基底100包括第一區R1與第二區R2。在一些實施例中,第一區R1可以是陣列區,其具有記憶體陣列,以下稱為陣列區R1。第二區R2可以是階梯區,其具有多個接觸窗以分別與字元線電性連接,以下稱為階梯區R2。堆疊結構202配置在基底100上(如圖2I所示)。第一組垂直通道結構VC1與第二組垂直通道結構VC2配置在陣列區R1中並沿著Y方向排列。雖然圖1中僅繪示出兩個第一組垂直通道結構VC1與兩個第二組垂直通道結構VC2,但本發明不以此為限。在其他實施例中,多個第一組垂直通道結構VC1與多個第二組垂直通道結構VC2可沿著Y方向排列。第一組垂直通道結構VC1與第二組垂直通道結構VC2包括多個垂直通道結構120。在一些實施例中,垂直通道結構120是以六方最密堆積的形式排列,以提升記憶單元的積集度。垂直通道結構120貫穿陣列區R1的堆疊結構202以與基底100接觸(如圖2I所示)。在本實施例中,垂直通道結構120可電性連接至位元線。另一方面,多組虛擬垂直通道結構DVC配置在階梯區R2中並沿著Y方向排列。多組虛擬垂直通道結構DVC包括多個虛擬垂直通道結構220。在一些實施例中,虛擬垂直通道結構220是以m×n陣列的形式排列。虛擬垂直通道結構220貫穿階梯區R2的堆疊結構202,以與階梯區R2的基底100接觸。在本實施例中,虛擬垂直通道結構220是電性浮置或是未電性連接至其他外部電源(例如位元線)。在一些實施例中,虛擬垂直通道結構220的排列密度小於垂直通道結構120的排列密度。虛擬垂直通道結構220可用以支撐階梯區R2的堆疊層的強度,以避免堆疊層在進行後續圖2G至圖2H的蝕刻製程時崩塌。Please refer to FIG. 1, the
在一些實施例中,第一狹縫12a配置在第一組垂直通道結構VC1與第二組垂直通道結構VC2之間,且貫穿堆疊結構202以暴露出基底100(如圖2I所示)。如圖1所示,第一狹縫12a沿著X方向自陣列區R1延伸至階梯區R2中。值得注意的是,第一狹縫12a包括多個第一子狹縫12a1、12a2、12a3、12a4、12a5,其沿著X方向離散配置。另外,記憶元件1更包括第一串選擇線切割105a,其位於第一子狹縫12a1、12a2、12a3、12a4、12a5之間。也就是說,第一子狹縫12a1、12a2、12a3、12a4、12a5在X方向上被第一串選擇線切割105a與部分堆疊結構202分隔。在此情況下,第一子狹縫12a1、12a2、12a3、12a4、12a5之間的第一串選擇線切割105a與部分堆疊結構202可強化整個記憶元件1的機械強度,進而減少記憶元件1的堆疊結構202的彎曲現象。從另一角度來看,第一子狹縫12a1、12a2、12a3、12a4、12a5與其之間的第一串選擇線切割105a可視為一種隔離結構,以分隔第一組垂直通道結構VC1與第二組垂直通道結構VC2。在一些實施例中,所述隔離結構(包括沿著X方向交替排列的第一子狹縫12a1、12a2、12a3、12a4、12a5與第一串選擇線切割105a)自陣列區R1延伸至階梯區R2中。在本實施例中,第一串選擇線切割105a至少延伸超過階梯區R2中的第一行(first column)接觸窗(未繪示)。In some embodiments, the first slit 12 a is disposed between the first set of vertical channel structures VC1 and the second set of vertical channel structures VC2 , and penetrates through the
在一些實施例中,第二狹縫12b分別配置在第一組垂直通道結構VC1的第一側(例如上側)與第二組垂直通道結構VC2的相對於第一側的第二側(例如下側)。具體來說,第二狹縫12b亦貫穿堆疊結構202以暴露出基底100(如圖2I所示)。如圖1所示,第二狹縫12b沿著X方向自陣列區R1連續延伸至階梯區R2中。In some embodiments, the
另外,記憶元件1更包括第二串選擇線切割105b與第三串選擇線切割105c。如圖1所示,第二串選擇線切割105b沿著X方向自陣列區R1延伸至階梯區R2中,以將第一組垂直通道結構VC1分成兩個第一群組G1。在一些實施例中,每一個第一群組G1具有相同數量的垂直通道結構120。在本實施例中,第二串選擇線切割105b至少延伸超過階梯區R2中的第一行接觸窗(未繪示)。相似地,第三串選擇線切割105c沿著X方向自陣列區R1延伸至階梯區R2中,以將第二組垂直通道結構VC2分成兩個第二群組G2。在一些實施例中,每一個第二群組G2具有相同數量的垂直通道結構120。在本實施例中,第三串選擇線切割105c至少延伸超過階梯區R2中的第一行接觸窗(未繪示)。In addition, the
在本實施例中,第一狹縫12a是沿著X方向不連續地延伸;而第二狹縫12b則是沿著X方向連續地延伸。因此,第二狹縫12b的長度L2大於第一子狹縫12a1、12a2、12a3、12a4、12a5的長度L1總合。另外,第一子狹縫12a1、12a2、12a3、12a4、12a5的長度L1總合與第二狹縫12b的長度L2的比可介於0.35至0.9之間。雖然圖1所繪示的第一子狹縫12a1、12a2、12a3、12a4、12a5具有相同的長度L1,但本發明不以此為限。在其他實施例中,第一子狹縫12a1、12a2、12a3、12a4、12a5亦可具有不同的長度且彼此可相距不同間距。In this embodiment, the
圖2A至圖2I是沿著圖1的切線A-A的製造流程剖面示意圖。圖3是沿著圖1的切線B-B的剖面示意圖。2A to 2I are schematic cross-sectional views of the manufacturing process along the line A-A of FIG. 1 . FIG. 3 is a schematic cross-sectional view along the line B-B in FIG. 1 .
請參照圖2A,記憶元件10(如圖1所示)的製造方法如下。首先,提供基底100。在一實施例中,基底100包括半導體基底,例如是矽基底。Referring to FIG. 2A , the manufacturing method of the memory element 10 (shown in FIG. 1 ) is as follows. First, a
接著,在基底100上形成堆疊層102。具體來說,堆疊層102包括相互堆疊的多個第一材料104與多個第二材料106。在一實施例中,第一材料104與第二材料106可以是不同的介電材料。舉例來說,第一材料104可以是氧化矽;第二材料106可以是氮化矽。但本發明不以此為限,在其他實施例中,第一材料104可以是氧化矽;第二材料106可以是多晶矽。在一實施例中,第一材料104與第二材料106的數量可以是8層、16層、32層、64層、72層或更多層。Next, a
請參照圖2B,在最頂層的第二材料106t中形成沿著X方向延伸的多個串選擇線切割105。在一些實施例中,串選擇線切割105的形成方法包括圖案化最頂層的第二材料106t以形成開口;將介電材料填入開口中,其中介電材料覆蓋最頂層的第二材料106t;以及進行化學機械研磨(CMP)製程以暴露出最頂層的第二材料106t。在一些實施例中,串選擇線切割105具有與第二材料106不同的介電材料,例如是氧化矽、高介電常數材料(氧化鋁)或其組合。Referring to FIG. 2B , a plurality of string selection line cuts 105 extending along the X direction are formed in the topmost
請參照圖2C,在堆疊層102上形成介電層108。在一些實施例中,介電層108的材料包括與第二材料106不同的介電材料,例如是氧化矽、高介電常數材料(氧化鋁)或其組合。接著,在介電層108與堆疊層102中形成多個開口10。開口10位於串選擇線切割105之間且貫穿堆疊層102,藉此暴露出基底100的一部分。在一實施例中,開口10的形成方法包括對介電層108與堆疊層102進行圖案化製程。為了使堆疊層102中最底層被完全移除,因此,在進行所述圖案化製程時會移除部分基底100。在此情況下,如圖2C所示,開口10的底面可低於基底100的頂面。Referring to FIG. 2C , a
請參照圖2C與圖2D,在外露於開口10的基底100上選擇性磊晶生長磊晶層110。在一實施例中,磊晶層110的材料可源自於基底100,例如是磊晶矽。磊晶層110可增加導電面積,以降低電阻值。雖然圖2D所繪示的磊晶層110的頂面高於基底100的頂面,但本發明不以此為限。在其他實施例中,磊晶層110的頂面亦可低於或等於基底100的頂面。Referring to FIG. 2C and FIG. 2D , an
接著,在開口10中形成電荷儲存結構112。詳細地說,在基底100上形成電荷儲存材料(未繪示)。所述電荷儲存材料共形地覆蓋介電層108的頂面、堆疊層102的側壁以及磊晶層110的頂面。之後,進行蝕刻製程,以移除磊晶層110的頂面上以及介電層108的頂面上的電荷儲存材料,使得電荷儲存結構112以類似間隙壁形式形成在介電層108與堆疊層102中的開口10的側壁上。在一實施例中,電荷儲存結構112可以是氧化物層/氮化物層/氧化物層(ONO)的複合層。在一實施例中,所述蝕刻製程包括非等向性蝕刻製程,例如是反應性離子蝕刻(RIE)製程。Next, a
請參照圖2E,在基底100上形成第一通道材料116。第一通道材料116共形地覆蓋磊晶層110的頂面、電荷儲存結構112的表面以及介電層108的頂面。在一實施例中,第一通道材料116包括半導體材料,其可例如是多晶矽。第一通道材料116的形成方法例如是化學氣相沉積法(CVD)。Referring to FIG. 2E , a
請參照圖2E與圖2F,在開口10中形成介電柱115。介電柱115填充開口10,且介電柱115的頂面可低於介電層108的頂面。也就是說,介電柱115並未填滿整個開口10。在一實施例中,介電柱115的材料包括旋塗式介電質(SOD)。之後,於介電柱115上形成第二通道材料118,以覆蓋介電柱115的頂面並延伸覆蓋至介電層108的頂面。接著,圖案化第二通道材料118與第一通道材料116,以形成垂直通道結構120。如圖2F所示,垂直通道結構120包括介電柱115以及由第一通道材料116與第二通道材料118所構成的通道層114,其中通道層114包封介電柱115。電荷儲存結構112環繞垂直通道結構120的側壁。在一實施例中,第二通道材料118包括半導體材料,其可例如是多晶矽。第二通道材料118的形成方法例如是CVD。Referring to FIG. 2E and FIG. 2F , a
請參照圖2F與圖2G,在基底100上形成介電層122,以覆蓋介電層108的頂面以及垂直通道結構120的頂面。在一實施例中,介電層122包括但不限於氧化矽,其形成方法例如是CVD。在形成介電層122之後,於相鄰兩個垂直通道結構120之間的堆疊層102中形成狹縫12。狹縫12貫穿介電層122、108以及堆疊層102,且暴露出基底100的一部分。為了使堆疊層102中最底層被完全移除,因此,在形成狹縫12時會移除部分基底100。在此情況下,狹縫12的底面可低於基底100的頂面。對應於上視圖1,狹縫12包括第一狹縫12a與第二狹縫12b。第一狹縫12a包括沿著X方向離散配置的多個第一子狹縫12a1、12a2、12a3、12a4、12a5。第一子狹縫12a1、12a2、12a3、12a4、12a5將原本沿著X方向連續延伸的串選擇線切割105分隔成多個第一串選擇線切割105a,如圖1所示。在一些實施例中,第一子狹縫12a1、12a2、12a3、12a4、12a5可橫向暴露出第一串選擇線切割105a。由於串選擇線切割105的部分位置已被第一狹縫12a取代,因此,圖2G的剖面中並未示出第一串選擇線切割105a。在此情況下,圖2G的剖面中所示的串選擇線切割105則可視為第二串選擇線切割105b與第三串選擇線切割105c。如圖1所示,第二串選擇線切割105b與第三串選擇線切割105c自陣列區R1連續延伸至階梯區R2中。Referring to FIG. 2F and FIG. 2G , a
請參照圖2G與圖2H,進行蝕刻製程,移除第二材料106,以在第一材料104之間形成多個空隙16。空隙16橫向暴露出電荷儲存結構112的部分側壁。也就是說,空隙16是由第一材料104與電荷儲存結構112所定義的。在一實施例中,所述蝕刻製程可以是濕式蝕刻製程。舉例來說,當第二材料106為氮化矽,所述蝕刻製程可以是使用含有磷酸的蝕刻液,並將所述蝕刻液倒入狹縫12中,藉此移除第二材料106。由於所述蝕刻液對於第二材料106具有高蝕刻選擇性,因此,第二材料106可被完全移除,而第一材料104與電荷儲存結構112未被移除或僅少量移除。值得注意的是,由於串選擇線切割105的材料與第二材料106具有不同蝕刻選擇性,因此,串選擇線切割105亦未被移除或僅少量移除。在此情況下,如圖2H所示,第二串選擇線切割105b與第三串選擇線切割105c皆外露於空隙16。Referring to FIG. 2G and FIG. 2H , an etching process is performed to remove the
請參照圖2H與圖2I,在空隙16中形成導體層126。在一實施例中,導體層126的形成方法包括在基底100上形成導體材料(未繪示)。所述導體材料填入空隙16中且覆蓋第一材料104的側壁與介電層108、122的側壁。之後,進行蝕刻製程,以移除第一材料104的側壁與介電層108、122的側壁上的導體材料。為了使第一材料104的側壁與介電層108、122的側壁上的導體材料被完全移除,因此,在進行所述蝕刻製程時會移除空隙16中的部分導體材料。在此情況下,如圖2I所示,所形成的導體層126的側壁126s會內凹於第一材料104的側壁104s。在一實施例中,導體層126的材料包括金屬、阻障金屬、多晶矽或其組合,其形成可以是CVD或物理氣相沉積法(PVD)。Referring to FIG. 2H and FIG. 2I , a
請參照圖2I與圖3,本實施例的記憶元件1包括:基底100、堆疊結構202、垂直通道結構120以及電荷儲存結構112。堆疊結構202配置在基底100上。堆疊結構202包括沿著Z方向交替堆疊的多個第一材料(可例如是介電層)104與多個導體層126。垂直通道結構120貫穿堆疊結構202。電荷儲存結構112環繞垂直通道結構120的側壁。在一實施例中,記憶元件1可以是環繞式閘極(gate-all-around,GAA)記憶元件。也就是說,導體層126可視為閘極或是字元線,而垂直通道結構120可視為電流通道。在替代實施例中,記憶元件1可以是NAND記憶元件。Referring to FIG. 2I and FIG. 3 , the
在一些實施例中,最頂層的導體層126t可用以當作串選擇線(String Select Line,SSL)。串選擇線SSL可與選擇電晶體電性連接,以控制其環繞的垂直通道結構120的開關。雖然圖2I與圖3僅繪示出一層串選擇線SSL,但本發明不以此為限。在其他實施例中,最頂層的導體層126t及其下方的導體層126皆可用以當作串選擇線。值得注意的是,第一串選擇線切割105a、第二串選擇線切割105b以及第三串選擇線切割105c皆內埋在串選擇線SSL中,以將串選擇線SSL分隔成4個串選擇線SSL1、SSL2、SSL3、SSL4,如圖3所示。圖3是沿著圖1的切線B-B的剖面示意圖。在此情況下,串選擇線SSL1、SSL2、SSL3、SSL4彼此電性隔離。詳細地說,串選擇線SSL1環繞垂直通道結構120a並用以控制垂直通道結構120a的開關。相似地,串選擇線SSL2環繞垂直通道結構120b並用以控制垂直通道結構120b的開關;串選擇線SSL3環繞垂直通道結構120c並用以控制垂直通道結構120c的開關;而串選擇線SSL4環繞垂直通道結構120d並用以控制垂直通道結構120d的開關。如圖1與圖3所示,由於第一子狹縫12a1、12a2、12a3、12a4、12a5之間具有第一串選擇線切割105a與部分堆疊結構202,其可強化第二狹縫之間的整個記憶元件1的機械強度,進而減少記憶元件1的堆疊結構202的彎曲現象。此外,在一些實施例中,最底層的導體層126b可用以當作接地選擇線(Ground Select Line,GSL),以與接地電晶體電性連接。In some embodiments, the topmost
圖4是依照本發明第二實施例的一種記憶元件的上視示意圖。FIG. 4 is a schematic top view of a memory device according to a second embodiment of the present invention.
請參照圖4,第二實施例的記憶元件2與第一實施例的記憶元件1相似。上述兩者主要的不同之處在於:記憶元件2包括第三組垂直通道結構VC3、第四組垂直通道結構VC4、第三狹縫12c以及第四狹縫12d。第一組垂直通道結構VC1、所述第二組垂直通道結構VC2、第三組垂直通道結構VC3以及第四組垂直通道結構VC4沿著Y方向排列。在一些實施例中,第三組垂直通道結構VC3與第四組垂直通道結構VC4亦包括多個垂直通道結構120。垂直通道結構120貫穿堆疊結構202以與基底100接觸。Referring to FIG. 4 , the
如圖4所示,第三狹縫12c配置在第二組垂直通道結構VC2與第三組垂直通道結構VC3之間,且貫穿堆疊結構202以暴露出基底100。第四狹縫12d配置在第三組垂直通道結構VC3與第四組垂直通道結構VC4之間,且貫穿堆疊結構202以暴露出基底100。第三狹縫12c與第四狹縫12d皆沿著X方向自陣列區R1延伸至階梯區R2中。值得注意的是,第三狹縫12c包括沿著X方向離散配置多個第三子狹縫,且第六串選擇線切割105f位於第三子狹縫之間。第四狹縫12d亦包括沿著X方向離散配置多個第四子狹縫,而第七串選擇線切割105g位於第四子狹縫之間。在此情況下,第三子狹縫之間的第六串選擇線切割105f與部分堆疊結構202以及第四子狹縫之間的第七串選擇線切割105g與部分堆疊結構202可更進一步地強化整個記憶元件2的機械強度,進而減少記憶元件2的堆疊結構202的彎曲現象。雖然圖4所繪示的第一串選擇線切割105a、第六串選擇線切割105f以及第七串選擇線切割105g是彼此相應的,但本發明不以此為限。在其他實施例中,第一串選擇線切割105a、第六串選擇線切割105f以及第七串選擇線切割105g亦可交錯配置。As shown in FIG. 4 , the
此外,記憶元件2更包括第四串選擇線切割105d與第五串選擇線切割105e。第四串選擇線切割105d沿著X方向延伸以將第三組垂直通道結構VC3分成兩個第三群組G3。第五串選擇線切割105e沿著X方向延伸以將第四組垂直通道結構VC4分成兩個第四群組G4。每一個第三群組G3或是每一個第四群組G4具有相同數量的垂直通道結構120。In addition, the
綜上所述,本發明實施例將連續延伸的第一狹縫替換成沿著X方向離散配置的多個第一子狹縫。在高高寬比的堆疊結構的情況下,第一子狹縫之間的第一串選擇線切割與部分堆疊結構可強化整個記憶元件的機械強度,以在一連串的製程(例如濕式蝕刻製程、膜沉積製程以及熱製程等)期間減少堆疊結構的彎曲現象,進而提升記憶元件的良率與可靠度。另外,第一子狹縫與其之間的第一串選擇線切割可視為一種隔離結構,以電性分隔第一組垂直通道結構與第二組垂直通道結構,進而增加記憶元件操作的彈性。To sum up, in the embodiment of the present invention, the continuously extending first slit is replaced by a plurality of first sub-slits discretely arranged along the X direction. In the case of a high aspect ratio stack structure, the first string of selective wire cuts between the first sub-slits and the partial stack structure can strengthen the mechanical strength of the entire memory device to withstand a series of processes (such as wet etching process , film deposition process and thermal process, etc.) to reduce the bending phenomenon of the stacked structure, thereby improving the yield and reliability of the memory device. In addition, the first sub-slit and the first series of selection line cuts therebetween can be regarded as an isolation structure to electrically separate the first group of vertical channel structures from the second group of vertical channel structures, thereby increasing the flexibility of the operation of the memory device.
1、2:記憶元件 10:開口 12:狹縫 12a:第一狹縫 12a1、12a2、12a3、12a4、12a5:第一子狹縫 12b:第二狹縫 16:空隙 100:基底 102:堆疊層 104:第一材料 104s:側壁 105:串選擇線切割 105a:第一串選擇線切割 105b:第二串選擇線切割 105c:第三串選擇線切割 105d:第四串選擇線切割 105e:第五串選擇線切割 105f:第六串選擇線切割 106:第二材料 108、122:介電層 110:磊晶層 112:電荷儲存結構 114:通道層 115:介電柱 116:第一通道材料 118:第二通道材料 120、120a、120b、120c、120d:垂直通道結構 126:導體層 126t:最頂層的導體層 126b:最底層的導體層 126s:側壁 202:堆疊結構 220:虛擬垂直通道結構 DVC:多組虛擬垂直通道結構 G1:第一群組 G2:第二群組 G3:第三群組 G4:第四群組 GSL:接地選擇線 L1、L2:長度 R1:陣列區 R2:階梯區 SSL、SSL1、SSL2、SSL3、SSL4:串選擇線 VC1:第一組垂直通道結構 VC2:第二組垂直通道結構 VC3:第三組垂直通道結構 VC4:第四組垂直通道結構1, 2: memory components 10: opening 12: Slit 12a: First slit 12a1, 12a2, 12a3, 12a4, 12a5: the first sub-slit 12b: Second slit 16: Gap 100: base 102:Stack layers 104: first material 104s: side wall 105: String selection wire cutting 105a: Select wire cutting for the first string 105b: The second string selects wire cutting 105c: The third string chooses wire cutting 105d: The fourth string chooses wire cutting 105e: The fifth string selects wire cutting 105f: The sixth string chooses wire cutting 106: Second material 108, 122: dielectric layer 110: epitaxial layer 112:Charge storage structure 114: Channel layer 115: Dielectric column 116: The first channel material 118:Second channel material 120, 120a, 120b, 120c, 120d: vertical channel structure 126: conductor layer 126t: the topmost conductor layer 126b: The bottom conductor layer 126s: side wall 202:Stack structure 220: Virtual vertical channel structure DVC: multi-group virtual vertical channel structure G1: The first group G2: The second group G3: The third group G4: The fourth group GSL: Ground Selection Line L1, L2: Length R1: array area R2: Ladder area SSL, SSL1, SSL2, SSL3, SSL4: string selection lines VC1: The first set of vertical channel structures VC2: The second set of vertical channel structures VC3: The third vertical channel structure VC4: The fourth vertical channel structure
圖1是依照本發明第一實施例的一種記憶元件的上視示意圖。 圖2A至圖2I是沿著圖1的切線A-A的製造流程剖面示意圖。 圖3是沿著圖1的切線B-B的剖面示意圖。 圖4是依照本發明第二實施例的一種記憶元件的上視示意圖。FIG. 1 is a schematic top view of a memory device according to a first embodiment of the present invention. 2A to 2I are schematic cross-sectional views of the manufacturing process along the line A-A of FIG. 1 . FIG. 3 is a schematic cross-sectional view along the line B-B in FIG. 1 . FIG. 4 is a schematic top view of a memory device according to a second embodiment of the present invention.
1:記憶元件1: memory element
12:狹縫12: Slit
12a:第一狹縫12a: First slit
12a1、12a2、12a3、12a4、12a5:第一子狹縫12a1, 12a2, 12a3, 12a4, 12a5: the first sub-slit
12b:第二狹縫12b: Second slit
100:基底100: base
105:串選擇線切割105: String selection wire cutting
105a:第一串選擇線切割105a: Select wire cutting for the first string
105b:第二串選擇線切割105b: The second string selects wire cutting
105c:第三串選擇線切割105c: The third string chooses wire cutting
120:垂直通道結構120: Vertical channel structure
202:堆疊結構202:Stack structure
220:虛擬垂直通道結構220: Virtual vertical channel structure
DVC:多組虛擬垂直通道結構DVC: multi-group virtual vertical channel structure
G1:第一群組G1: The first group
G2:第二群組G2: The second group
L1、L2:長度L1, L2: Length
R1:陣列區R1: array area
R2:階梯區R2: Ladder area
VC1:第一組垂直通道結構VC1: The first set of vertical channel structures
VC2:第二組垂直通道結構VC2: The second set of vertical channel structures
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