TWI789210B - Modified composition and manufacturing method thereof - Google Patents

Modified composition and manufacturing method thereof Download PDF

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TWI789210B
TWI789210B TW111101780A TW111101780A TWI789210B TW I789210 B TWI789210 B TW I789210B TW 111101780 A TW111101780 A TW 111101780A TW 111101780 A TW111101780 A TW 111101780A TW I789210 B TWI789210 B TW I789210B
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powder
inorganic material
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TW202330887A (en
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康廷 熊
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康廷 熊
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Abstract

A modified composition and a manufacturing method thereof are provided. The manufacturing method of the modified composition includes the following steps: providing a modified liquid, wherein the modified liquid includes a nano-inorganic material, and the nano-inorganic material includes: at least one of silicon carbide, silicon dioxide, graphite and quartz; converting the modified liquid from an aqueous to an oily by a conversion means; and adding the modified liquid in the oily state to a conductive groove and providing a low-current charge energy to the modified liquid in the conductive groove to obtain the modified composition.

Description

改質組合物及其製造方法Modified composition and its production method

本發明關於一種組合物及其製造方法，特別是關於一種用於對機油進行改質的改質組合物及其製造方法。The invention relates to a composition and a manufacturing method thereof, in particular to a modifying composition for modifying engine oil and a manufacturing method thereof.

機油具有潤滑、清潔、冷卻、防銹和緩衝的作用，能確保引擎性能維持最佳運轉，是直接影響到行動載具的工作狀態和使用壽命的重要因素。近年來隨著引擎性能不斷改進，輸出功率不斷增加，相對使機油的性能要求也越來越高。Engine oil has the functions of lubricating, cleaning, cooling, anti-rust and buffering, which can ensure the optimal performance of the engine and is an important factor that directly affects the working condition and service life of mobile vehicles. In recent years, with the continuous improvement of engine performance and output power, the performance requirements of engine oil are also getting higher and higher.

市面上的機油種類大致分為合成油與礦物油；其中，礦物油相較於合成油雖然具備高抗剪性、耐高壓以及高潤滑度等優點，但礦物油也存在了不安定、分子大小不均勻以及純度不夠高等缺陷問題。The types of engine oils on the market are roughly divided into synthetic oils and mineral oils. Compared with synthetic oils, mineral oils have the advantages of high shear resistance, high pressure resistance, and high lubricity, but mineral oils also have instability and molecular size. Defects such as unevenness and insufficient purity.

因此，如何透過改良、改質等方式，來使得機油可具備礦物油的優點並克服前述缺陷，已成為該項事業所欲解決的重要課題之一。Therefore, how to make the engine oil have the advantages of mineral oil and overcome the above-mentioned defects by means of improvement and upgrading has become one of the important issues to be solved by this business.

本發明所要解決的技術問題在於，針對現有技術的不足提供一種改質組合物及其製造方法。The technical problem to be solved by the present invention is to provide a modified composition and a manufacturing method thereof in view of the deficiencies of the prior art.

為了解決上述的技術問題，本發明所採用的其中一技術方案是提供一種改質組合物，其包括一改質液，該改質液包含一奈米無機材料，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；其中，該改質液經由一轉化手段而由一水性轉換成一油性，且該改質液被添加至一導電槽中且被給予一低電流電荷能。In order to solve the above-mentioned technical problems, one of the technical solutions adopted by the present invention is to provide a modifying composition, which includes a modifying liquid, and the modifying liquid contains a nanometer inorganic material, which includes: silicon carbide, At least one of silicon, graphite and quartz; wherein, the modifying solution is converted from water to oil through a conversion means, and the modifying solution is added into a conductive tank and given a low current charge energy.

為了解決上述的技術問題，本發明所採用的另外一技術方案是提供一種改質組合物之製造方法，其包括下列步驟：提供一改質液，該改質液包含一奈米無機材料，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；通過一轉化手段將該改質液由一水性轉換成一油性；以及藉由將呈該油性的該改質液添加至一導電槽中，並提供一低電流電荷能給位於該導電槽中的該改質液，以獲得該改質組合物。In order to solve the above-mentioned technical problems, another technical solution adopted by the present invention is to provide a method for manufacturing a modifying composition, which includes the following steps: providing a modifying liquid, which contains a nanometer inorganic material, which Including: at least one of silicon carbide, silicon dioxide, graphite, and quartz; converting the modifying fluid from a water-based to an oil-based by a conversion method; and adding the oil-based modifying liquid to a conductive In the tank, and provide a low current charge energy to the modifying solution in the conduction tank, so as to obtain the modifying composition.

本發明的其中一有益效果在於，本發明所提供的改質組合物，其能通過“該改質液包含一奈米無機材料，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；其中，該改質液經由一轉化手段而由一水性轉換成一油性，且該改質液被添加至一導電槽中且被給予一低電流電荷能”的技術方案，可用於提升機油的良好特性。One of the beneficial effects of the present invention is that the modifying composition provided by the present invention can pass through "the modifying solution contains a nanometer inorganic material, which includes: silicon carbide, silicon dioxide, graphite and quartz at least One; wherein, the modifying fluid is converted from a water-based to an oil-based through a conversion means, and the modifying fluid is added to a conductive tank and is given a low current charge energy "technical scheme, which can be used to upgrade engine oil good characteristics.

本發明的另外一有益效果在於，本發明所提供的改質組合物之製造方法，其能通過“提供一改質液，該改質液包含一奈米無機材料，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；通過一轉化手段將該改質液由一水性轉換成一油性；以及藉由將呈該油性的該改質液添加至一導電槽中，並提供一低電流電荷能給位於該導電槽中的該改質液，以獲得該改質組合物”的技術方案，可用於提升機油的良好特性。Another beneficial effect of the present invention is that the manufacturing method of the modifying composition provided by the present invention can be achieved by "providing a modifying solution, the modifying solution comprising a nanometer inorganic material, which includes: silicon carbide, di At least one of silicon oxide, graphite and quartz; converting the modifying solution from water to oil by a conversion means; Low current charges can be given to the modifying fluid in the conductive tank to obtain the technical solution of the modifying composition, which can be used to improve the good characteristics of engine oil.

為使能更進一步瞭解本發明的特徵及技術內容，請參閱以下有關本發明的詳細說明與圖式，然而所提供的圖式僅用於提供參考與說明，並非用來對本發明加以限制。In order to further understand the features and technical content of the present invention, please refer to the following detailed description and drawings related to the present invention. However, the provided drawings are only for reference and description, and are not intended to limit the present invention.

以下是通過特定的具體實施例來說明本發明所公開有關“改質組合物及其製造方法”的實施方式，本領域技術人員可由本說明書所公開的內容瞭解本發明的優點與效果。本發明可通過其他不同的具體實施例加以施行或應用，本說明書中的各項細節也可基於不同觀點與應用，在不背離本發明的構思下進行各種修改與變更。另外，本發明的附圖僅為簡單示意說明，並非依實際尺寸的描繪，事先聲明。以下的實施方式將進一步詳細說明本發明的相關技術內容，但所公開的內容並非用以限制本發明的保護範圍。另外，本文中所使用的術語“或”，應視實際情況可能包括相關聯的列出項目中的任一個或者多個的組合。The following are specific examples to illustrate the implementation of the "modified composition and its manufacturing method" disclosed in the present invention. Those skilled in the art can understand the advantages and effects of the present invention from the content disclosed in this specification. The present invention can be implemented or applied through other different specific embodiments, and various modifications and changes can be made to the details in this specification based on different viewpoints and applications without departing from the concept of the present invention. In addition, the drawings of the present invention are only for simple illustration, and are not drawn according to the actual size, which is stated in advance. The following embodiments will further describe the relevant technical content of the present invention in detail, but the disclosed content is not intended to limit the protection scope of the present invention. In addition, the term "or" used herein may include any one or a combination of more of the associated listed items depending on the actual situation.

[實施例][Example]

請參閱圖1至圖5，分別為本發明實施例的改質組合物的製造方法的第一流程示意圖、第一使用狀態示意圖、第二使用狀態示意圖、實測結果扭力示意圖以及實測結果馬力示意圖。如圖所示，本發明實施例提供一種改質組合物的製造方法，其至少包括下列幾個步驟：Please refer to FIG. 1 to FIG. 5 , which are respectively the first schematic flow chart, the first use state schematic diagram, the second use state schematic diagram, the measured torque schematic diagram and the measured horsepower schematic diagram of the manufacturing method of the modified composition according to the embodiment of the present invention. As shown in the figure, an embodiment of the present invention provides a method for manufacturing a modified composition, which at least includes the following steps:

首先，提供一改質液1（步驟S100）。舉例來說，配合圖1及圖2所示，本發明的改質液1可至少包括奈米無機材料10，奈米無機材料10可以是零維（或稱無維）奈米顆粒，奈米無機材料10可包含：碳化矽、二氧化矽、石墨以及石英之至少一者，奈米無機材料10的粒徑可介於1 nm至40 nm，較佳可介於5 nm至20 nm，且改質液1包含11%至33%的奈米無機材料10；其中，改質液1較佳可包含低於22%的奈米無機材料10。於其他實施例中，奈米無機材料10也可以是二維的奈米片或三維的奈米粒子；其中，奈米片的材料可以是石英，奈米片因片狀的結構而具有表面光滑的特性，因此，可進一步提升改質組合物的流動性。此外，本發明的改質液1還可進一步包括水、醇類或芳香烴類，但不以此為限；也就是說，本發明可將奈米無機材料10添加於水、醇類或芳香烴類中，以形成改質液1，如此一來，本發明的改質液1也可與一般市售的潤滑油相混。First, a modifying solution 1 is provided (step S100 ). For example, as shown in Figure 1 and Figure 2, the modifying fluid 1 of the present invention may at least include nano-inorganic materials 10, and the nano-inorganic materials 10 may be zero-dimensional (or dimensionless) nanoparticles, nano The inorganic material 10 may include: at least one of silicon carbide, silicon dioxide, graphite, and quartz. The particle size of the nano-inorganic material 10 may be between 1 nm and 40 nm, preferably between 5 nm and 20 nm, and The modifying solution 1 contains 11% to 33% of the nano-inorganic material 10 ; wherein, the modifying solution 1 preferably contains less than 22% of the nano-inorganic material 10 . In other embodiments, the nano-inorganic material 10 can also be a two-dimensional nanosheet or a three-dimensional nanoparticle; wherein, the material of the nanosheet can be quartz, and the nanosheet has a smooth surface due to its sheet-like structure. Therefore, the fluidity of the modified composition can be further improved. In addition, the modifying fluid 1 of the present invention may further include water, alcohols or aromatic hydrocarbons, but not limited thereto; that is, the present invention may add nano-inorganic materials 10 to water, alcohols or aromatic hydrocarbons Hydrocarbons to form the upgrading fluid 1, so that the upgrading fluid 1 of the present invention can also be mixed with common commercially available lubricating oils.

進一步來說，本發明的奈米無機材料10還可包括奈米氧化鋅、奈米氮化硼、奈米氮化鋁、奈米氮化矽、奈米氧化矽、奈米氧化鋯粉、奈米碳、奈化矽粉、奈米石墨、奈米錫、奈米鎳、奈米鉬粉、奈米鉍粉、奈米鈷粉、奈米銅粉、氧化銅粉、碳化鈮粉、碳化鉻粉、碳化釩粉以及奈米鐵中之至少一者。其中，改質液1可包括1 wt%至3 wt%的奈米氧化鋅、0.5 wt%至2 wt%的奈米氮化硼、0.3 wt%至0.7 wt%的奈米氮化鋁、1 wt%至3 wt%的奈米氮化矽、1 wt%至4 wt%的奈米氧化矽、0.1 wt%至0.3 wt%的奈米氧化鋯粉、0.05 wt%至0.2 wt%的奈米碳、3 wt%至7 wt%的奈化矽粉、0.3 wt%至0.7 wt%的奈米石墨、0.3 wt%至0.7 wt%的奈米錫、0.5 wt%至2 wt%的奈米鎳、0.5 wt%至2 wt%的奈米鐵、1 wt%至5 wt%的奈米鉬粉、1 wt%至3 wt%的奈米鉍粉、1 wt%至5 wt%的奈米鈷粉、1 wt%至5 wt%的奈米銅粉、1 wt%至3 wt%的氧化銅粉、1 wt%至3 wt%的碳化鈮粉、1 wt%至5 wt%的碳化鉻粉、1 wt%至5 wt%的碳化釩粉以及3 wt%至7 wt%的石英中之至少一者；較佳地，改質液1可包括2 wt%的奈米氧化鋅、1 wt%的奈米氮化硼、0.5 wt%的奈米氮化鋁、2 wt%的奈米氮化矽、3 wt%的奈米氧化矽、0.2 wt%的奈米氧化鋯粉、0.1 wt%的奈米碳、5 wt%的奈化矽粉、0.5 wt%的奈米石墨、0.5 wt%的奈米錫、1 wt%的奈米鎳、1 wt%的奈米鐵、2 wt%的奈米鉬粉、1 wt%的奈米鉍粉、3 wt%的奈米鈷粉、1 wt%的奈米銅粉、2 wt%的氧化銅粉、1 wt%的碳化鈮粉、2 wt%的碳化鉻粉、2 wt%的碳化釩粉以及5 wt%的石英中之至少一者。此外，奈米無機材料10還可進一步包括奈米氧化鋁、奈米碳化鋁、奈米碳化鎢以及奈米鉍粉中之至少一者。Further, the nano-inorganic material 10 of the present invention may also include nano-zinc oxide, nano-boron nitride, nano-aluminum nitride, nano-silicon nitride, nano-silicon oxide, nano-zirconia powder, nano Nano-carbon, nano-silicon powder, nano-graphite, nano-tin, nano-nickel, nano-molybdenum powder, nano-bismuth powder, nano-cobalt powder, nano-copper powder, copper oxide powder, niobium carbide powder, chromium carbide powder, vanadium carbide powder and nano-iron at least one. Among them, the modifying solution 1 may include 1 wt% to 3 wt% of nano-zinc oxide, 0.5 wt% to 2 wt% of nano-boron nitride, 0.3 wt% to 0.7 wt% of nano-aluminum nitride, 1 wt% to 3 wt% of nano silicon nitride, 1 wt% to 4 wt% of nano silicon oxide, 0.1 wt% to 0.3 wt% of nano zirconia powder, 0.05 wt% to 0.2 wt% of nano Carbon, 3 wt% to 7 wt% silicon nitride powder, 0.3 wt% to 0.7 wt% nanographite, 0.3 wt% to 0.7 wt% nano tin, 0.5 wt% to 2 wt% nano nickel , 0.5 wt% to 2 wt% nano iron, 1 wt% to 5 wt% nano molybdenum powder, 1 wt% to 3 wt% nano bismuth powder, 1 wt% to 5 wt% nano cobalt powder, 1 wt% to 5 wt% copper nano powder, 1 wt% to 3 wt% copper oxide powder, 1 wt% to 3 wt% niobium carbide powder, 1 wt% to 5 wt% chromium carbide powder , 1 wt% to 5 wt% of vanadium carbide powder and at least one of 3 wt% to 7 wt% of quartz; preferably, the modifying solution 1 may include 2 wt% of nano zinc oxide, 1 wt% Nano-boron nitride, 0.5 wt% nano-aluminum nitride, 2 wt% nano-silicon nitride, 3 wt% nano-silicon oxide, 0.2 wt% nano-zirconia powder, 0.1 wt% Nano-carbon, 5 wt% silicon nitride powder, 0.5 wt% nano-graphite, 0.5 wt% nano-tin, 1 wt% nano-nickel, 1 wt% nano-iron, 2 wt% nano Molybdenum powder, 1 wt% nano-bismuth powder, 3 wt% nano-cobalt powder, 1 wt% nano-copper powder, 2 wt% copper oxide powder, 1 wt% niobium carbide powder, 2 wt% At least one of chromium carbide powder, 2 wt% vanadium carbide powder and 5 wt% quartz. In addition, the nano-inorganic material 10 may further include at least one of nano-alumina, nano-aluminum carbide, nano-tungsten carbide, and nano-bismuth powder.

接著，通過一轉化手段將改質液1由一水性轉換成一油性（步驟S102）。舉例來說，配合圖1所示，本發明在進入步驟S104之前，可將水性的改質液1經由蒸發、濃縮、分餾以及萃取等轉化手段而轉變為油性。進一步來說，改質液1由水性轉換成油性時，奈米無機材料10的一比表面積會降低到0.2至0.3倍。以氧化鋅為例，氧化鋅在水性時，比表面積為200 m 2/g；而當氧化鋅轉為油性時，比表面積大致上會降低到32 m 2/g至60 m 2/g。 Next, the upgrading liquid 1 is converted from water-based to oil-based by a conversion means (step S102 ). For example, as shown in FIG. 1 , before entering step S104 in the present invention, the water-based modifying liquid 1 can be transformed into oil-based through transformation methods such as evaporation, concentration, fractionation, and extraction. Furthermore, when the modifying fluid 1 changes from water-based to oil-based, the specific surface area of the nano-inorganic material 10 will be reduced to 0.2 to 0.3 times. Taking zinc oxide as an example, when zinc oxide is water-based, the specific surface area is 200 m 2 /g; and when zinc oxide turns oily, the specific surface area will generally decrease to 32 m 2 /g to 60 m 2 /g.

接下來，藉由將呈油性的改質液1添加至一導電槽2中，並提供一低電流電荷能給位於導電槽2中的改質液1，以獲得改質組合物（步驟S104）。舉例來說，配合圖1所示，在獲得油性的改質液1之後，將油性的改質液1添加到導電槽2中；其中，導電槽2可為低電流導電槽，但不以此為限。接著，提供一低電流電荷能給導電槽2中的改質液1，以使奈米無機材料10獲得電荷，進而放大奈米無機材料10本身電荷；同時，也獲得改質組合物。Next, by adding the oily modifying solution 1 into a conductive tank 2, and providing a low current charge energy to the modifying solution 1 located in the conductive tank 2, to obtain a modifying composition (step S104) . For example, as shown in Figure 1, after the oily modifying fluid 1 is obtained, the oily modifying fluid 1 is added to the conduction tank 2; wherein, the conduction tank 2 can be a low-current conduction tank, but not in this way limit. Next, provide a low-current charge energy to the modifying solution 1 in the conductive tank 2, so that the nano-inorganic material 10 can obtain a charge, and then amplify the charge of the nano-inorganic material 10 itself; at the same time, a modifying composition is also obtained.

進一步來說，呈油性的改質液1在獲得低電流電荷能時，奈米無機材料10的比表面積提升到1.5至1.8倍。以氧化鋅為例，油性的氧化鋅在接收低電流電荷能之後，油性的氧化鋅的比表面積大致會提升到60 m 2/g至100 m 2/g。 Furthermore, when the oily modifying solution 1 obtains low current charge energy, the specific surface area of the nano-inorganic material 10 increases to 1.5 to 1.8 times. Taking zinc oxide as an example, after the oily zinc oxide receives low current charge energy, the specific surface area of the oily zinc oxide will roughly increase to 60 m 2 /g to 100 m 2 /g.

因此，配合圖1及圖3所示，將改質組合物添加到機油中後，包含奈米礦物材料的奈米無機材料10可提供電荷給機油3中的長碳鏈分子30，活化衰退狀態的機油3中的長碳鏈分子30，而提升機油3的黏性與潤滑度，進而提高了改質組合物整體的潤滑度以及散熱效果。換句說話，含有本發明所提供的改質組合物的機油添加到行動載具的動力裝置E（例如引擎室）內之後，不僅能增加動力裝置中機件間的潤滑度，以避免機件間的磨損；同時，藉由機油的高流動率，也能增加動力裝置內的機件散熱效率。並且，本發明的改質組合物也能使得機油具備高抗剪性、耐擠壓以及耐高壓等特性。Therefore, as shown in Figures 1 and 3, after adding the modifying composition to the engine oil, the nano-inorganic material 10 comprising nano-mineral materials can provide charges to the long carbon chain molecules 30 in the engine oil 3, and activate the decay state The long carbon chain molecules 30 in the engine oil 3 improve the viscosity and lubricity of the engine oil 3, thereby improving the overall lubricity and heat dissipation effect of the modified composition. In other words, after the engine oil containing the modified composition provided by the present invention is added to the power unit E (such as the engine room) of the mobile vehicle, it can not only increase the degree of lubrication between the parts in the power unit, so as to avoid the At the same time, the high flow rate of engine oil can also increase the heat dissipation efficiency of the parts in the power plant. Moreover, the modifying composition of the present invention can also make the engine oil have properties such as high shear resistance, extrusion resistance and high pressure resistance.

進一步地，配合圖4以及圖5所示，其分別顯示以兩個使用原廠機油的四缸渦輪增壓引擎進行測試的效能實測結果，其中一個四缸渦輪增壓引擎添加了本發明的改質組合物。Further, in conjunction with Fig. 4 and Fig. 5, they respectively show the performance measurement results of two four-cylinder turbocharged engines using original oil, and one of the four-cylinder turbocharged engines is added with the improvement of the present invention. quality composition.

首先，由圖4可知，未添加本發明的改質組合物的四缸渦輪增壓引擎的扭力曲線T1在引擎轉速3000轉時，扭力即開始衰退；而添加本發明的改質組合物後的四缸渦輪增壓引擎的扭力曲線M1則在引擎轉速3600轉左右時才開始往下。並且，添加本發明的改質組合物後的四缸渦輪增壓引擎的扭力曲線M1，相較於未添加本發明的改質組合物的四缸渦輪增壓引擎的扭力曲線T1，明顯提升。由此可見，本發明所提供的改質組合物不僅能延後機油衰退的時間，同時也能提升引擎的扭力；換句話說，本發明的改質組合物不僅能延長機油使用效期，而降低使用者的換油成本且能達到環保的效果，而且，藉由引擎扭力的提升，能提供車輛充足的加速力道，同時，也能大幅降低車輛的油耗。First, as can be seen from Fig. 4, the torque curve T1 of the four-cylinder turbocharged engine without adding the modified composition of the present invention begins to decline when the engine speed is 3000 revolutions; and after adding the modified composition of the present invention The torque curve M1 of the four-cylinder turbocharged engine starts to go down when the engine speed is around 3600 rpm. Moreover, the torque curve M1 of the four-cylinder turbocharged engine after adding the modified composition of the present invention is significantly improved compared to the torque curve T1 of the four-cylinder turbocharged engine without the modified composition of the present invention. It can be seen that the modified composition provided by the present invention can not only delay the time of engine oil decay, but also improve the torque of the engine; in other words, the modified composition of the present invention can not only prolong the service life of the engine oil, but also It reduces the user's oil change cost and achieves the effect of environmental protection. Moreover, by increasing the engine torque, it can provide sufficient acceleration force for the vehicle, and at the same time, it can also greatly reduce the fuel consumption of the vehicle.

其次，配合圖5所示，由於本發明的改質組合物也能增加動力裝置中機件間的潤滑度，而降低機件間運作時所產生阻力，因此，添加本發明的改質組合物後的四缸渦輪增壓引擎的馬力曲線M2，相較於未添加本發明的改質組合物的四缸渦輪增壓的馬力曲線T2，特別是從5000轉至5750轉的高轉速區段，很明顯地降低引擎的高速運行阻力及負載，表示潤滑效果優異、機油油膜強韌、安定性好，所以馬力能明顯提升（馬力最大值從約230 Hp提升至約270 Hp），同時也因為具有超高潤滑度，所以也能增加車輛的滑行距離。由此可見，本發明的改質組合物不僅能延長機件的壽命，也能達到省油的功效。Secondly, as shown in Figure 5, because the modified composition of the present invention can also increase the lubricity between the parts in the power plant, and reduce the resistance generated during the operation between the parts, therefore, adding the modified composition of the present invention The horsepower curve M2 of the rear four-cylinder turbocharged engine, compared to the horsepower curve T2 of the four-cylinder turbocharged engine without adding the modified composition of the present invention, especially the high speed section from 5000 to 5750, It obviously reduces the high-speed running resistance and load of the engine, which means that the lubricating effect is excellent, the oil film is strong and stable, so the horsepower can be significantly improved (the maximum horsepower is increased from about 230 Hp to about 270 Hp), and because of its Ultra-high lubricity, so it can also increase the sliding distance of the vehicle. It can be seen that the modifying composition of the present invention can not only prolong the service life of machine parts, but also achieve the effect of saving fuel.

藉此，本發明所提供的改質組合物之製造方法通過上述的技術方案，能大幅減緩、降低機油裂解的速度，而提高改質組合物的使用時效。而且，當改質組合物添加到合成油的機油中後，還能使機油能額外具備礦物油的優點，同時又不具有礦物油的缺點。Thereby, the manufacturing method of the modified composition provided by the present invention can greatly slow down and reduce the cracking speed of the engine oil through the above-mentioned technical solution, and improve the service life of the modified composition. Moreover, when the modifying composition is added to synthetic oil, the engine oil can additionally have the advantages of mineral oil without the disadvantages of mineral oil.

根據上述的內容，配合圖1至圖3所示，本發明還提供一種改質組合物，其包括一改質液1，改質液1包含一奈米無機材料10，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；其中，改質液1經由一轉化手段而由一水性轉換成一油性，且改質液1被添加至一導電槽2中且被給予一低電流電荷能。According to the above content, the present invention also provides a modification composition as shown in Figs. At least one of silicon dioxide, graphite, and quartz; wherein, the modifying solution 1 is converted from a water-based to an oil-based through a conversion means, and the modifying solution 1 is added to a conductive tank 2 and given a low current charge energy.

此外，本發明的改質組合物還可包含一界面活性劑。界面活性劑可為陰離子界面活性劑、陽離子界面活性劑、非離子界面活性劑或兩性離子界面活性劑。In addition, the modifying composition of the present invention may further include a surfactant. The surfactant can be anionic surfactant, cationic surfactant, nonionic surfactant or zwitterionic surfactant.

然而，上述所舉的例子只是其中一個可行的實施例而並非用以限定本發明。However, the above-mentioned example is only one possible embodiment and is not intended to limit the present invention.

[實施例的有益效果][Advantageous Effects of Embodiment]

本發明的其中一有益效果在於，本發明所提供的改質組合物，其能通過“改質液1包含一奈米無機材料10，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；其中，改質液1由一水性轉換成一油性，且改質液1被添加至一導電槽2中且被給予一低電流電荷能”的技術方案，可用於提升機油的潤滑度以及提高機油的抗剪性與耐溫性。One of the beneficial effects of the present invention is that the modifying composition provided by the present invention can be passed through "the modifying solution 1 contains a nanometer inorganic material 10, which includes: silicon carbide, silicon dioxide, graphite and quartz At least one; wherein the modifying fluid 1 is converted from a water-based to an oil-based, and the modifying fluid 1 is added to a conductive tank 2 and given a low current charge energy "technical scheme, which can be used to improve the lubricity of the engine oil And improve the shear resistance and temperature resistance of the oil.

本發明的另外一有益效果在於，本發明所提供的改質組合物之製造方法，其能通過“提供一改質液，改質液1包含一奈米無機材料10，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；通過一轉化手段將改質液1由一水性轉換成一油性；以及藉由將呈油性的改質液1添加至一導電槽2中，並提供一低電流電荷能給位於導電槽2中的改質液1，以獲得改質組合物”的技術方案，可用於提升機油的潤滑度以及提高潤滑油的抗剪性與耐溫性。Another beneficial effect of the present invention is that the manufacturing method of the modifying composition provided by the present invention can be achieved by "providing a modifying liquid, the modifying liquid 1 comprising a nanometer inorganic material 10, which includes: silicon carbide, At least one of silicon dioxide, graphite, and quartz; converting the modifying solution 1 from water to oil by a conversion means; and by adding the oily modifying solution 1 into a conductive tank 2, and providing A low-current electric charge can be given to the modifying liquid 1 in the conductive groove 2 to obtain the technical solution of the modifying composition, which can be used to improve the lubricity of the engine oil and improve the shear resistance and temperature resistance of the lubricating oil.

更進一步來說，本發明所提供的改質組合物之製造方法通過上述的技術方案，能大幅減緩、降低機油裂解的速度，以提高改質組合物的使用時效。並且，本發明的改質組合物也能使得機油具備高抗剪性、耐擠壓以及耐高壓等特性。Furthermore, the manufacturing method of the modified composition provided by the present invention can greatly slow down and reduce the cracking speed of engine oil through the above-mentioned technical solution, so as to improve the service life of the modified composition. Moreover, the modifying composition of the present invention can also make the engine oil have properties such as high shear resistance, extrusion resistance and high pressure resistance.

以上所公開的內容僅為本發明的優選可行實施例，並非因此侷限本發明的申請專利範圍，所以凡是運用本發明說明書及圖式內容所做的等效技術變化，均包含於本發明的申請專利範圍內。The content disclosed above is only a preferred feasible embodiment of the present invention, and does not therefore limit the scope of the patent application of the present invention. Therefore, all equivalent technical changes made by using the description and drawings of the present invention are included in the application of the present invention. within the scope of the patent.

1:改質液 10:奈米無機材料 2:導電槽 3:機油 30:長碳鏈分子 E:動力裝置 M1、T1:扭力曲線 M2、T2:馬力曲線 1:Modifier 10: Nano inorganic materials 2: Conductive groove 3: engine oil 30: long carbon chain molecules E: power unit M1, T1: Torque curve M2, T2: horsepower curve

圖1為本發明實施例的改質組合物的製造方法的第一流程示意圖。FIG. 1 is a first schematic flow chart of a method for manufacturing a modified composition according to an embodiment of the present invention.

圖2為本發明實施例的改質組合物的第一使用狀態示意圖。Fig. 2 is a schematic diagram of the first use state of the modifying composition according to the embodiment of the present invention.

圖3為本發明實施例的改質組合物的第二使用狀態示意圖。Fig. 3 is a schematic diagram of the second use state of the modifying composition according to the embodiment of the present invention.

圖4為本發明實施例的改質組合物的實測結果扭力示意圖。Fig. 4 is a schematic diagram of the measured torque of the modified composition of the embodiment of the present invention.

圖5為本發明實施例的改質組合物的實測結果馬力示意圖。Fig. 5 is a schematic diagram of the measured horsepower of the modified composition of the embodiment of the present invention.

指定代表圖為流程圖，故無符號簡單說明。 The designation representative figure is a flow chart, so it is simply explained without symbols.

Claims (8)

一種改質組合物，其包括一改質液，該改質液包含一奈米無機材料，其包含：碳化矽、二氧化矽、石墨以及石英中之至少一者；其中，該改質液經由一轉化手段而由一水性轉換成一油性，且該改質液被添加至一導電槽中且被給予一低電流電荷能；其中，該改質液由該水性轉換成該油性時，該奈米無機材料的一比表面積降低到0.2至0.3倍。 A modification composition, which includes a modification solution, the modification solution contains a nano-inorganic material, which includes: at least one of silicon carbide, silicon dioxide, graphite and quartz; wherein, the modification solution passes through A conversion means is converted from a water-based to an oil-based, and the modifying fluid is added to a conductive tank and given a low current charge energy; wherein, when the modifying fluid is converted from the aqueous to the oil-based, the nano A specific surface area of the inorganic material is reduced by 0.2 to 0.3 times. 如請求項1所述的改質組合物，其中，該奈米無機材料的粒徑介於1nm至40nm，且該奈米無機材料佔該改質液總體積的11%至33%；其中，該奈米無機材料還可包含奈米氧化鋅、奈米氮化硼、奈米氮化鋁、奈米氮化矽、奈米氧化矽、奈米氧化鋯粉、奈米碳、奈化矽粉、奈米石墨、奈米錫、奈米鎳、奈米鉬粉、奈米鉍粉、奈米鈷粉、奈米銅粉、氧化銅粉、碳化鈮粉、碳化鉻粉、碳化釩粉以及奈米鐵中之至少一者。 The modifying composition according to claim 1, wherein the particle size of the nano-inorganic material is between 1 nm and 40 nm, and the nano-inorganic material accounts for 11% to 33% of the total volume of the modifying solution; wherein, The nano inorganic material can also include nano zinc oxide, nano boron nitride, nano aluminum nitride, nano silicon nitride, nano silicon oxide, nano zirconia powder, nano carbon, silicon nano powder , nano-graphite, nano-tin, nano-nickel, nano-molybdenum powder, nano-bismuth powder, nano-cobalt powder, nano-copper powder, copper oxide powder, niobium carbide powder, chromium carbide powder, vanadium carbide powder and nano At least one of rice iron. 如請求項1所述的改質組合物，其中，呈該油性的該改質液在獲得該低電流電荷能時，該奈米無機材料的該比表面積提升到1.5至1.8倍。 The modifying composition according to claim 1, wherein the specific surface area of the nano-inorganic material is increased to 1.5 to 1.8 times when the oily modifying solution obtains the low current charge energy. 如請求項1所述的改質組合物，還包含一界面活性劑，該界面活性劑為陰離子界面活性劑、陽離子界面活性劑、非離子界面活性劑或兩性離子界面活性劑。 The modifying composition according to claim 1, further comprising a surfactant, the surfactant is an anionic surfactant, a cationic surfactant, a nonionic surfactant or a zwitterionic surfactant. 一種改質組合物之製造方法，其包括下列步驟：提供一改質液，該改質液包含一奈米無機材料，其係選自由下列所組成之群組：碳化矽、二氧化矽、石墨、石英及其組合； 通過一轉化手段將該改質液由一水性轉換成一油性；以及藉由將呈該油性的該改質液添加至一導電槽中，並提供一低電流電荷能給位於該導電槽中的該改質液，以獲得該改質組合物；其中，該改質液由該水性轉換成該油性時，該奈米無機材料的一比表面積降低到0.2至0.3倍。 A method for manufacturing a modifying composition, which includes the following steps: providing a modifying solution, the modifying solution comprising a nanometer inorganic material, which is selected from the group consisting of: silicon carbide, silicon dioxide, graphite , quartz and their combinations; Converting the modifying solution from water to oil by a conversion means; and by adding the modifying solution in the oily state to a conductive tank, and providing a low current charge to the conductive tank located in the conductive tank A modifying liquid to obtain the modifying composition; wherein, when the modifying liquid is converted from the water-based to the oil-based, a specific surface area of the nano-inorganic material is reduced to 0.2 to 0.3 times. 如請求項5所述的改質組合物之製造方法，其中，該奈米無機材料的粒徑介於1nm至40nm，且該奈米無機材料佔該改質液總體積的11%至33%；其中，該奈米無機材料還可包含奈米氧化鋅、奈米氮化硼、奈米氮化鋁、奈米氮化矽、奈米氧化矽、奈米氧化鋯粉、奈米碳、奈化矽粉、奈米石墨、奈米錫、奈米鎳、奈米鉬粉、奈米鉍粉、奈米鈷粉、奈米銅粉、氧化銅粉、碳化鈮粉、碳化鉻粉、碳化釩粉以及奈米鐵中之至少一者。 The manufacturing method of the modifying composition according to claim 5, wherein the nano-inorganic material has a particle size ranging from 1 nm to 40 nm, and the nano-inorganic material accounts for 11% to 33% of the total volume of the modifying solution ; Wherein, the nano-inorganic material can also include nano-zinc oxide, nano-boron nitride, nano-aluminum nitride, nano-silicon nitride, nano-silicon oxide, nano-zirconia powder, nano-carbon, nano- Silicon powder, nano-graphite, nano-tin, nano-nickel, nano-molybdenum powder, nano-bismuth powder, nano-cobalt powder, nano-copper powder, copper oxide powder, niobium carbide powder, chromium carbide powder, vanadium carbide Powder and at least one of nano-iron. 如請求項5所述的改質組合物之製造方法，其中，呈該油性的該改質液在獲得該低電流電荷能時，該奈米無機材料的該比表面積提升到1.5至1.8倍。 The manufacturing method of the modifying composition according to claim 5, wherein, when the oily modifying solution obtains the low current charge energy, the specific surface area of the nano-inorganic material increases to 1.5 to 1.8 times. 如請求項5所述的改質組合物之製造方法，其中，該改質組合物還包含一界面活性劑，該界面活性劑為陰離子界面活性劑、陽離子界面活性劑、非離子界面活性劑或兩性離子界面活性劑。 The manufacturing method of the modification composition as described in Claim 5, wherein, the modification composition further comprises a surfactant, and the surfactant is an anionic surfactant, a cationic surfactant, a nonionic surfactant or Zwitterionic surfactant.
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