TWI787886B - Textile structure - Google Patents
Textile structure Download PDFInfo
- Publication number
- TWI787886B TWI787886B TW110123379A TW110123379A TWI787886B TW I787886 B TWI787886 B TW I787886B TW 110123379 A TW110123379 A TW 110123379A TW 110123379 A TW110123379 A TW 110123379A TW I787886 B TWI787886 B TW I787886B
- Authority
- TW
- Taiwan
- Prior art keywords
- adhesive layer
- fabric structure
- layer
- present
- coating
- Prior art date
Links
Images
Landscapes
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
本發明是有關於一種織物結構,且特別是有關於一種可降解的織物結構。The present invention relates to a fabric structure, and in particular to a degradable fabric structure.
一般而言,最早期應用於廣告或店面建物之遮陽或遮陽棚上的織物結構(如帆布)通常為PE編織而成,其係PE織帶經緯交錯而成單一色或條紋色彩之編織層,由於編織層不具防水性,故須於表面塗佈一淋膜層,藉以達到防水功能,其雖具有比重低之優點,但因該淋膜層不易附著在編織層表面,且僅有薄薄的一層,加上其本身材質上柔軟度不足,當PE編織而成的織物結構呈彎摺或碰撞時,其摺處極易發生該淋膜層破損或剝落之情況,此時即失去防水功能。Generally speaking, the fabric structure (such as canvas) that was first applied to the sunshade or sunshade of advertisements or storefront buildings is usually woven from PE. The braided layer is not waterproof, so a coating layer must be coated on the surface to achieve waterproof function. Although it has the advantage of low specific gravity, the coating layer is not easy to adhere to the surface of the braided layer, and there is only a thin layer , and the softness of its own material is insufficient, when the fabric structure made of PE is bent or collided, the coating layer is easily damaged or peeled off at the fold, and the waterproof function will be lost at this time.
於是,如圖1、2所示之以PVC編織而成的織物結構10遂因應而生,其係在中間之纖維基布層11的上、下表面膠合或熱壓一層PVC12、13所構成,其具有抗拉強度佳,且防水性亦優之特點,因此常被用來作為防水遮陽及廣告用帆布。然而,而PVC是聚氯乙烯的簡稱,英文為Polyvinylchloride,被國際綠色和平組織稱為「毒塑膠」,卻也因為便宜、製造方便,而成為產量僅次於PE的第二大泛用塑膠,廣泛存在於我們的生活周遭,嚴重威脅著我們的環境與身體健康。Then, as shown in Figures 1 and 2, a
再者,PVC是五大泛用塑膠(PE、PVC、PP、PS、ABS)中唯一的含氯塑膠。由於含氯的緣故,使其可藉由塑化劑的添加,而改變柔軟度。除了塑化劑外,PVC的熱安定性是很差的。為了避免PVC產品在太陽或高溫下的裂解,還必須添加安定劑,通常為鉛、鎘、鋅等重金屬。因此,PVC並不只是PVC,還含有一些對健康與環境有害的塑化劑與安定劑;完全不添加任何東西的PVC本身雖不毒,但也沒有用處。Furthermore, PVC is the only chlorine-containing plastic among the five general-purpose plastics (PE, PVC, PP, PS, and ABS). Due to the chlorine content, the softness can be changed by adding plasticizers. In addition to plasticizers, the thermal stability of PVC is very poor. In order to avoid cracking of PVC products under the sun or high temperature, stabilizers must be added, usually heavy metals such as lead, cadmium, and zinc. Therefore, PVC is not just PVC, but also contains some plasticizers and stabilizers that are harmful to health and the environment; PVC itself that does not add anything at all is not poisonous, but it is also useless.
是故,國際綠色和平組織之所以會稱PVC為「毒塑膠」,不是指不含任何添加劑的PVC本身而言,但也不光指含有添加劑的PVC產品而言,而是因為其整個生命週期,從原料開採、製造、使用、到廢棄的所有階段,皆會對環境與人體健康造成危害。Therefore, the reason why Greenpeace International calls PVC "toxic plastic" does not refer to PVC itself without any additives, but it does not only refer to PVC products containing additives, but because of its entire life cycle, All stages from raw material mining, manufacturing, use, to disposal will cause harm to the environment and human health.
進一步而言,PVC色澤鮮豔,耐腐蝕,牢固耐用,但熱穩定性和耐光性較差,100℃以上或長時間陽光曝曬開始分解出氯化氫,因此製造塑膠時需加入穩定劑、增塑劑、抗老化劑等一些有毒輔助材料來增強其耐熱性、韌性、延展性等。純的PVC密度為1.4g/cm3,加入增塑劑等的PVC密度一般為1.15~2.00g/cm 3;但PVC內的這些有害添加劑和增塑劑可能滲出或氣化,干擾生物內分泌,影響生殖機能,可增加致癌風險,因此部分類型的增塑劑己被歐盟國家列為高關注物質,並全面禁止使用。再者,以美國為例有75%的塑膠垃圾最終是以填埋的方式處理,不利於環境,是以,以PVC編織而成的織物結構具有上述問題點,因此尚有改善空間。 Furthermore, PVC is bright in color, corrosion-resistant, and durable, but its thermal stability and light resistance are poor. It begins to decompose hydrogen chloride when it is above 100°C or exposed to sunlight for a long time. Therefore, it is necessary to add stabilizers, plasticizers, anti- Some toxic auxiliary materials such as aging agents are used to enhance its heat resistance, toughness, ductility, etc. The density of pure PVC is 1.4g/cm3, and the density of PVC added with plasticizers is generally 1.15~2.00g/ cm3 ; however, these harmful additives and plasticizers in PVC may seep or gasify, interfere with biological endocrine, and affect Reproductive function can increase the risk of cancer, so some types of plasticizers have been listed as substances of high concern by EU countries and their use is completely banned. Furthermore, taking the United States as an example, 75% of plastic waste is finally disposed of in landfills, which is not conducive to the environment. Therefore, the fabric structure made of PVC has the above-mentioned problems, so there is still room for improvement.
本發明提供一種織物結構,其可以在解決處理不易的問題的同時達到環保的目的。The invention provides a fabric structure, which can achieve the purpose of environmental protection while solving the problem of difficult disposal.
本發明的一種織物結構,包括纖維基布層以及膠層。纖維基布層具有網孔且包括基本組成為纖維素的纖維。膠層滲入網孔。A fabric structure of the present invention includes a fiber base cloth layer and an adhesive layer. The fibrous base cloth layer has a mesh and includes fibers whose basic composition is cellulose. The glue layer penetrates into the mesh.
在本發明的一實施例中,上述的織物結構更包括配置於膠層位於網孔上方的表面上的塗層。塗層包括壓克力樹酯材料。In an embodiment of the present invention, the above-mentioned fabric structure further includes a coating disposed on the surface of the adhesive layer above the mesh. Coating includes acrylic resin material.
在本發明的一實施例中,上述的塗層的厚度範圍介於0.01毫米至0.15毫米。In an embodiment of the present invention, the thickness of the above-mentioned coating ranges from 0.01 mm to 0.15 mm.
在本發明的一實施例中,上述的膠層包括漿料,所述漿料包括以磷、銻或溴為主之添加劑。In an embodiment of the present invention, the above-mentioned adhesive layer includes slurry, and the slurry includes additives mainly composed of phosphorus, antimony or bromine.
在本發明的一實施例中,上述的膠層包括增白劑。In an embodiment of the present invention, the above-mentioned adhesive layer includes a whitening agent.
在本發明的一實施例中,上述的膠層包括助劑。In an embodiment of the present invention, the above-mentioned adhesive layer includes additives.
在本發明的一實施例中,上述的纖維基布層的厚度範圍介於0.2毫米至0.8毫米。In an embodiment of the present invention, the thickness of the above-mentioned fibrous base cloth layer ranges from 0.2 mm to 0.8 mm.
在本發明的一實施例中,上述的膠層包括位於纖維基布層的第一表面上的第一膠層及位於纖維基布層相對於第一表面的第二表面上的第二膠層,第一膠層與第二膠層的厚度範圍介於0.2毫米至0.8毫米。In one embodiment of the present invention, the above-mentioned adhesive layer includes a first adhesive layer located on the first surface of the fiber base cloth layer and a second adhesive layer located on the second surface of the fiber base cloth layer opposite to the first surface , the thickness of the first adhesive layer and the second adhesive layer ranges from 0.2 mm to 0.8 mm.
在本發明的一實施例中,上述的織物結構更包括配置於膠層的表面上遮光層。In an embodiment of the present invention, the above-mentioned fabric structure further includes a light-shielding layer disposed on the surface of the adhesive layer.
基於上述,本發明的纖維基布層具有網孔且包括基本組成為纖維素的纖維,由於纖維素為天然纖維,其在處理過程中具有較佳的降解率與生物相容性,因此可以在解決織物結構處理不易的問題的同時達到環保的目的。Based on the above, the fibrous base cloth layer of the present invention has a mesh and includes fibers that are basically composed of cellulose. Since cellulose is a natural fiber, it has better degradation rate and biocompatibility during processing, so it can be used in The purpose of environmental protection is achieved while solving the problem that the fabric structure is not easy to handle.
為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。In order to make the above-mentioned features and advantages of the present invention more comprehensible, the following specific embodiments are described in detail together with the accompanying drawings.
參照本實施例之圖式以更全面地闡述本發明。然而,本發明亦可以各種不同的形式體現,而不應限於本文中所述之實施例。圖式中的層或區域的厚度、尺寸或大小會為了清楚起見而放大。相同或相似之參考號碼表示相同或相似之元件,以下段落將不再一一贅述。The present invention will be described more fully with reference to the drawings of this embodiment. However, the present invention can also be embodied in various forms and should not be limited to the embodiments described herein. The thickness, size or magnitude of layers or regions in the drawings may be exaggerated for clarity. The same or similar reference numbers indicate the same or similar elements, and the following paragraphs will not repeat them one by one.
圖3A是依據本發明一些實施例之纖物結構的纖維基布層外觀示意圖。圖3B是圖3A中3B-3B’斷面的剖面示意圖。圖4是依據本發明一些實施例之纖物結構的立體剖視圖。圖5是是圖4中5-5’斷面的剖面示意圖。Fig. 3A is a schematic view showing the appearance of the fiber base cloth layer of the fiber structure according to some embodiments of the present invention. Fig. 3B is a schematic cross-sectional view of
首先,本實施例的織物結構60以噴繪廣告布為例,但本發明不以此為限制,織物結構可以是其他任何適宜的織物結構。請參考圖3A、圖3B、圖4與圖5,在本實施例中,織物結構60包括纖維基布層20以及膠層(可選地如膠層30或膠層40),其中纖維基布層20具有網孔23且包括基本組成為纖維素(C
6H
10O
5)
n的纖維,而膠層(可選地如膠層30或膠層40)滲入網孔23。據此,本實施例的纖維基布層20具有網孔且包括基本組成為纖維素的纖維,由於纖維素為天然纖維,其在處理過程中具有較佳的降解率與生物相容性,因此可以在解決織物結構處理不易的問題的同時達到環保的目的。
Firstly, the
在一些實施例中,纖維基布層20可以是是由基本組成為纖維素的木漿黏膠纖維(Viscose Fiber)的經線21及緯線22所編織而成之網狀編織物因而具有網孔23,如圖3A、3B所示。在此,木漿黏膠纖維是以天然纖維(木纖維、棉短絨)為原料,經鹼化、老化、磺化等工序製成可溶性纖維素黃原酸酯,再溶於稀鹼液製成黏膠,經濕法紡絲而製成。進一步而言,木漿黏膠纖維其乾態強度(baked strength)超過30.0cN/tex,並具有良好的吸濕性,在一般大氣條件下,回潮率在13%左右,吸濕後顯著膨脹,直徑增加可達50%,但本發明不限於此,在其他的實施例中,纖維基布層20可以是是由基本組成為纖維素的棉紗所製成。進一步而言,天然纖維在處理過程中與在自然水生環境中的降解效果好,因此可以具有較佳的生物相容性與環保效益。In some embodiments, the fibrous
在一些實施例中,纖維基布層20基本重量介於170克/平方米(gsm)至200克/平方米範圍內,厚度介於0.2毫米(mm, millimeter)至0.8毫米,使該纖維基布層20具有高密度的網孔23及抗拉性,舉例而言,纖維基布層20的厚度可以為0.3毫米,但本發明不限於此。In some embodiments, the base weight of the fibrous
在一些實施例中,經線21及緯線22的相交角度為90度,且經線21及緯線22的寬度介於0.2毫米至1毫米之間,但本發明不限於此。In some embodiments, the intersecting angle of the
在一些實施例中,網孔23的形狀可以是方形或其他適宜的形狀,且一個平方英寸的密度為經向34~50根,緯向35~50根。此外,每個網孔23可以具有實質上相同的尺寸,但本發明不限於此。In some embodiments, the shape of the
在一些實施例中,纖維基布層20具有第一表面24及相對於第一表面24的第二表面25,且膠層30位於纖維基布層20的第一表面24上,而膠層40位於纖維基布層20的第二表面25上。進一步而言,膠層30與膠層40附著在纖維基布層20並部分被纖維基布層20吸收進而滲透入網孔23,因此膠層30與膠層40可以部分包覆覆蓋網孔23,但本發明不限於此。In some embodiments, the fibrous
在一些實施例中,膠層30與膠層40可以是分別塗布於纖維基布層20的第一表面24與第二表面25,以使膠層30與膠層40可以滲入網孔23。舉例而言,可以藉由塗刮刮刀將液態的膠材料塗布於纖維基布層20上,但本發明不限於此,在其他實施例中,膠層30與膠層40也可以使用淋膜或其他適宜的方式形成於纖維基布層20上。In some embodiments, the
在一些實施例中,膠層30與膠層40的材料可以是具有防水防火特性的水性聚丙烯酸酯類織物塗層膠(Polyacrylate, PA),但本發明不限於此,在替代實施例中,膠層30與膠層40的材料可以是PU、PP、PE等材質。在此,水性聚丙烯酸酯類織物塗層膠可以是由下列成分所組成:以所有組合成分的含量之和為100wt%作基準:其中包含200克/平方米~230克/平方米範圍內45wt%~65wt%作為主材料的水性聚丙烯酸酯,20wt%~35wt%的防火漿,4wt%~12wt%的增白劑(Brightener),2 wt%~8wt%的水,以及0.4wt%~3wt%的助劑,如此一來,可以使織物結構60的基本重量介於370克/平方米~430克/平方米範圍內,但本發明不限於此。In some embodiments, the material of the
進一步而言,水性聚丙烯酸酯類織物塗層膠具有防水、阻燃等多種功能,且一般均由硬組分(如聚丙烯酸甲酯等)和軟組分(如聚丙烯酸丁酯等)共聚而成,其中聚丙烯酸酯塗層的主要單體有丙烯酸、丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯等,為了提高其防水性能,必要時可加入丙烯醯胺和丙烯腈,聚合引發劑一般用過氧化物(如過硫 酸鉀等)。是以,水性聚丙烯酸酯類織物塗層膠可以具有下列耐日光和氣候牢度好、不易泛黃、透明度和共容性好、有利於生產有色塗層產品、耐洗性好、黏著力強、成本較低等功能,但本發明不限於此。Furthermore, water-based polyacrylate fabric coating adhesives have multiple functions such as waterproof and flame retardant, and are generally copolymerized by hard components (such as polymethyl acrylate, etc.) and soft components (such as polybutyl acrylate, etc.) Among them, the main monomers of polyacrylate coating are acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, etc. In order to improve its waterproof performance, acrylamide and acrylonitrile can be added if necessary. The polymerization initiator is generally Use peroxides (such as potassium persulfate, etc.). Therefore, the water-based polyacrylate fabric coating adhesive can have the following properties: good light and weather fastness, not easy to yellow, good transparency and compatibility, conducive to the production of colored coating products, good washability, and strong adhesion , lower cost and other functions, but the present invention is not limited thereto.
在一些實施例中,防火漿包括但不限定於:以磷為主之添加劑、銻為主之添加劑、溴為主之添加劑、聚磷酸銨、磷酸二氫銨、膠狀五氧化銻、三氧 化銻、亞銻酸鈉、硼酸鋅、氧化鋯、磷酸二銨、胺磺酸、胺磺酸鹽、硼酸、 硼酸鹽或水合氧化鋁中之至少一者,但本發明不限於此。In some embodiments, the fireproof slurry includes but is not limited to: phosphorus-based additives, antimony-based additives, bromine-based additives, ammonium polyphosphate, ammonium dihydrogen phosphate, colloidal antimony pentoxide, trioxide At least one of antimony, sodium antimonite, zinc borate, zirconia, diammonium phosphate, sulfamic acid, sulfamic acid salt, boric acid, borate or alumina hydrate, but the present invention is not limited thereto.
在一些實施例中,增白劑包括為:螢光增白劑(Optical Brightening Agents, OBA),其可由螢光增白劑、分散劑及水所組成,其中螢光增白劑係可為二苯乙烯三嗪類化合物、分散劑可為亞甲基二萘磺酸鈉類化合物,以利用螢光增白劑的光學作用增加製造出織物結構60的白度,但本發明不限於此。In some embodiments, the brightening agent includes: optical brightening agent (Optical Brightening Agents, OBA), which can be composed of optical brightening agent, dispersant and water, wherein the optical brightening agent can be two The styrene triazine compound and the dispersant may be sodium methylene dinaphthalene sulfonate compound to increase the whiteness of the fabricated
在一些實施例中,助劑可包括為:紫外線穩定劑、抗氧化劑或抗靜電劑其中任一或其組合式所構成,但本發明不限於此。In some embodiments, the auxiliary agent may include any one of ultraviolet stabilizer, antioxidant or antistatic agent or a combination thereof, but the present invention is not limited thereto.
在一些實施例中,膠層30與膠層40的厚度介於0.2毫米至0.8毫米之間;舉例而言,膠層30與膠層40的厚度可以為0.3毫米,但本發明不限於此。In some embodiments, the thickness of the
在一些實施例中,織物結構60更包括配置於膠層(如膠層40)位於網孔23上方的表面上的塗層50,其中塗層50包括壓克力樹酯材料(具有吸水性),但本發明不限於此,在替代實施例中,膠層30與膠層40的材料可以是PU、PP、PE等材質。進一步而言,塗層50可以具有吸墨特性,但本發明不限於此。In some embodiments, the
在一些實施例中,塗層50可以是塗布於膠層40的表面。舉例而言,可以藉由塗刮刮刀將液態的塗層材料塗布於膠層40上,但本發明不限於此,在其他實施例中,塗層50也可以使用淋膜或其他適宜的方式形成於膠層40上。In some embodiments, the
在一些實施例中,塗層50的厚度介於0.01毫米至0.15毫米之間,舉例而言,塗層50的厚度可以為0.02毫米,且塗層50的上表面51可以用作吸附數碼噴繪廣告塗料,但本發明不限於此。In some embodiments, the thickness of the
在一些實施例中,塗層50表面的凹凸微結構是基於織物結構60的材料特性,但本發明不限於此。In some embodiments, the concave-convex microstructure on the surface of the
在此必須說明的是,以下實施例沿用上述實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明,關於省略部分的說明可參考前述實施例,下述實施例不再重複贅述。It must be noted here that the following embodiments continue to use the component numbers and part of the content of the above-mentioned embodiments, wherein the same or similar numbers are used to indicate the same or similar components, and the description of the same technical content is omitted, and the description of the omitted part Reference can be made to the aforementioned embodiments, and the following embodiments will not be repeated.
圖6是依據本發明一些實施例之纖物結構的剖面示意圖。圖7是依據本發明一些實施例之織物結構的應用示意圖。請參考圖6與圖7,本實施例的織物結構60更包括配置於膠層30的表面上的遮光層80,但本發明不限於此,在其他實施例中,遮光層80可以是配置於膠層40的表面上(未繪示)。進一步而言,遮光層80可以是僅配置於膠層30的表面上、僅配置於膠層40的表面上或同時配置於膠層30與膠層40的表面上。FIG. 6 is a schematic cross-sectional view of a fiber structure according to some embodiments of the present invention. Fig. 7 is a schematic diagram of the application of the fabric structure according to some embodiments of the present invention. Please refer to FIG. 6 and FIG. 7, the
在一些實施例中,遮光層80可以是塗布於膠層(膠層30及/或膠層40)的表面。舉例而言,可以藉由塗刮刮刀將液態的塗層材料塗布於膠層(膠層30及/或膠層40)上,但本發明不限於此,在其他實施例中,遮光層80也可以使用淋膜或其他適宜的方式形成於膠層(膠層30及/或膠層40)上。In some embodiments, the
另一方面,本實施例可以更包括配置於織物結構60上上的油墨70,如圖6與圖7所示,由於織物結構60的塗層50具有吸墨功能,如此一來,塗層50在噴繪油墨70後無須另外噴塗金油層或保護層,且噴繪後的視覺效果及質感,因此可以提升此產品的經濟價值,但本發明不限於此。On the other hand, this embodiment may further include the
在一些實施例中,織物結構60的尺寸大於油墨70的尺寸,以使織物結構60可以作為油墨70的載體,但本發明不限於此。In some embodiments, the size of the
圖8是係依據本發明一些實施例之木漿黏膠纖維與其他材質可降解的生物降解率比較座標圖。請參考圖8,縱軸為生物降解率%,橫軸為天數,其中聚酯纖維經過180天的生物降解率約只有10%,聚酯棉混紡織物的生物降解率約為45%,不符合環保標準。而木漿黏膠纖維的生物降解率,45天時可超過75%,180天時可超過90%,且最終可達到完全降解的目標,因此優於聚酯纖維及聚酯棉混紡織物甚多。至於PVC因為無法降解,所以不列入座標圖比較。據此,本發明以木漿黏膠纖維作為纖維基布層20,由於木漿黏膠纖維其乾態強度(baked strength)超過30.0cN/tex,並具有良好的吸濕性,因此配合水性聚丙烯酸酯類織物塗層膠的使用,可以使織物結構具有良好的共容性及相互結合力強等特性,因此可以成為較佳的產品(如成為非常優質環保噴繪廣告布),但本發明不限於此。Fig. 8 is a graph comparing the biodegradation rate of wood pulp viscose fiber and other materials according to some embodiments of the present invention. Please refer to Figure 8. The vertical axis is the biodegradation rate %, and the horizontal axis is the number of days. The biodegradation rate of polyester fiber after 180 days is only about 10%, and the biodegradation rate of polyester-cotton blended fabric is about 45%. Environmental standards. The biodegradation rate of wood pulp viscose fiber can exceed 75% in 45 days, and can exceed 90% in 180 days, and can finally achieve the goal of complete degradation, so it is much better than polyester fiber and polyester-cotton blended fabrics. . As for PVC, because it cannot be degraded, it is not included in the comparison of the coordinate chart. Accordingly, the present invention uses wood pulp viscose fiber as the fiber
在本發明中,由於當織物結構60纖維基布層20所使用的木漿黏膠纖維具有高密度的網孔23及抗拉性,而膠層30及膠層40是以水性聚丙烯酸酯類織物塗層膠分別塗布在纖維基布層20的第一表面24及第二表面25上時,該些膜層為無毒、無臭、無味的乳白色高結晶聚合物,是目前塑膠中最輕的品種之一,密度僅為0.90~0.91g/cm
3,是PVC密度的60%左右,而在塑膠中,聚丙烯酸樹酯類的耐熱性最好,其熱變形溫度為80~100℃,同時具有良好的耐應力開裂性,有很高的彎曲疲勞壽命。再者,塗層50,以壓克力樹酯構成為主,其可以與聚丙烯酸樹酯類的適當配比而具有吸墨特性。據此,本發明的織物結構60可以是防火、防水及吸墨塗層的複合結構,但本發明不限於此。
In the present invention, since the wood pulp viscose fiber used in the
進一步而言,織物結構60由於具有無PVC及無毒的特性,因此特別適用於室內、外廣告、室內裝飾用,並符合醫療等級之使用。再者,織物結構60較現行市場上的產品可以減少近35%的重量而輕便柔軟,且安裝拆卸更為簡單快捷具有移除容易的特性。此外,由於織物結構60的組合結構強度佳,可配合預定的成型機加工,使織物結構60其寬幅(W)可根據客戶要求訂制,且最大寬幅(W)可達5.0米(M),如此一來,可彈性地依照實際設計上的需求進行噴繪。進而使織物結構60可以具有更多的適用性及選擇性。Furthermore, since the
本發明木漿黏膠纖維經過生態紡織品100(簡稱OEKO-TEX STANDARD 100)(織物結構60)的檢測報告test report SH004 133085.1,已獲得STANDARD 100 by OEKO-TEX®的授權,使用OEKO-TEX®標籤。其報告內容如下: 「按STANDARD 100 BY OEKO-TEX®第產品級別I,根據附錄4類產品而作出之檢測結果顯示,以上貨品符合該級標准對嬰幼兒產品而設立的最新紡織品,符合了現時歐盟REACH法規附錄,XVII中的法律規定(當中包括使用偶氮染料及鎳 等的限制)同時也符合了CPSIA美國消費品安全改進法案中對兒童用品的總含鉛量要求。持此證書的公司,已作出根據ISO17050 1之質量相符聲明,確保只應用OEKO- TEX®標簽於與測試樣本相符合之貨品上,審查以核實聲明」。The wood pulp viscose fiber of the present invention has passed the test report SH004 133085.1 of ecological textile 100 (abbreviated as OEKO-TEX STANDARD 100) (fabric structure 60), has obtained the authorization of
本發明織物結構60相較於傳統PVC織物結構之比較如下。
相較於傳統PVC織物結構,具有克重較輕而可快速替換,無刺激性氣味、對身體無害、無致敏、無毒性等特性,因無塑化劑,貯藏保質期可達二年以上,可掩埋、焚燒均不會造成較大污染,塗料可降解、可回收,且木漿黏膠纖維的生物降解率為90%以上。Compared with the traditional PVC fabric structure, it has the characteristics of lighter weight and quick replacement, no irritating smell, no harm to the body, no allergies, and no toxicity. Because there is no plasticizer, the storage shelf life can reach more than two years. Landfill and incineration will not cause major pollution, the paint is degradable and recyclable, and the biodegradation rate of wood pulp viscose fiber is over 90%.
本發明的織物結構60,經送到歐盟公告的實驗室授權機構,『SGS』通達標準技術服務(上海)有限公司檢測,達到歐盟防火等級標準EN13501-1-B -s1-d0標準中防火等級『B級』,製品的燃燒性能,其中該產煙量的附加等級:『s1』。另該燃燒滴落物/微粒的附加等級:『d0』。是以,本發明的織物結構60符合防火等級安全性較高的歐盟標準,換句話說,本發明的織物結構60具有符合國際標準規範的阻燃性及防火性。The
本發明的織物結構60通過歐洲TUV「致敏」及「皮膚刺激」的認證,其測試報告如下。The
<致敏試驗><Sensitization test>
測試環境:室溫22˚C~26˚C;濕度:50%~70%。檢測依據:ISO 10993-10:2010。檢測動物:白色豚鼠30只,302.4g~362.8g,雄性。浸提介質:10.9%氯化鈉浸提介質2棉籽油。陰性對照:同批浸提介質。浸提液製備:按照6cm²/ml比例,70˚C、24h分別製備兩種介質樣品浸提液試驗方法:最大劑量法。試驗步驟:1.誘導:用浸提液在動物背部對稱注射,注射一周後,再注射區用浸提液貼敷固定48h。激發:動物腹側備皮貼敷浸提液固定24h。評判指標:去除貼敷後24h、48h,觀察腹側皮膚紅斑水腫反應程度。Test environment:
結論:48h觀察期內對照組皮膚放應等級為0;試驗組皮膚放應等級為0,無致敏反應。參照ISO10993-10:2010的方法,該試驗樣品浸提液的皮膚致敏試驗結果符合要求。Conclusion: During the 48-hour observation period, the skin radiation level of the control group was 0; the skin radiation level of the test group was 0, and there was no allergic reaction. Referring to the method of ISO10993-10:2010, the skin sensitization test results of the test sample extract meet the requirements.
<皮膚刺激試驗><Skin irritation test>
測試環境:室溫22˚C~26˚C;濕度:50%~70%。檢測依據:ISO 10993-10:2010。檢測動物:健康新西蘭兔6只,2.3kg~2.7kg,雄性。浸提介質:10.9%氯化鈉浸提介質2棉籽油。陰性對照:同批浸提介質。接觸途徑:皮膚貼敷。接觸時間:24h。評判指標:觀察24h、48h、72h接觸部位皮膚組織紅斑水腫反應程度。Test environment:
結論:去除貼敷後24h、48h、72h,試驗樣品的0.9%氯化鈉注射液浸提液接觸部位皮膚組織的原發性刺激指數為0,(平均計分為0);棉籽油浸提液接觸部 位皮膚組織的原發性刺激指數為0,(平均計分為0)。參照ISO10993-10:2010的方法,該試驗樣品浸提液的皮膚刺激試驗結果 符合要求。Conclusion: 24h, 48h, and 72h after removing the sticking, the primary irritation index of the skin tissue at the contact site of the 0.9% sodium chloride injection extract of the test sample is 0 (average score is 0); The primary irritation index of the skin tissue at the liquid contact site is 0, (mean score is 0). With reference to the method of ISO10993-10:2010, the skin irritation test result of the test sample extract meets the requirements.
據此,由上述測試報告可以證實,本發明的織物結構60符合醫療等級之使用要求。Accordingly, it can be confirmed from the above test report that the
本發明織物結構60,在不需要添加任何添加劑的情況下,即可耐寒達到零下40˚C。已通過該標準的耐寒實驗(ASTM D2136-2002)。The
綜上所述,本發明的纖維基布層具有網孔且包括基本組成為纖維素的纖維,由於纖維素為天然纖維,其在處理過程中具有較佳的降解率與生物相容性,因此可以在解決織物結構處理不易的問題的同時達到環保的目的。進一步而言,本發明的織物結構為廣告布時可以具有較佳的噴繪效果,相較與現行市場上的廣告布重量減少近一半而輕便柔軟,且安裝拆卸更為簡單快捷。再者,本發明的織物結構材料輕,體積小,能有效地降低運輸成本。此外,本發明的織物結構相較於傳統廣告布所使用的聚氯乙烯(PVC)而言,木漿黏膠纖維的生產較為簡單,耗能較低,而聚氯乙烯(PVC)作為典型的高能耗產品,無論是電石法或是乙烯法來製作的聚氯乙烯(PVC),能耗和成本均較高,不符合當下節能減排,有限資源再利用的全球趨勢,同時,以木漿黏膠纖維為原材料的環保噴繪廣告布,在使用後的處理也符合環保要求。另一方面,本發明的織物結構可以容易地進行粉碎回收,並再生為其它製品,如產品包裝外殼,花盆、皮包硬內襯等,且在燃燒後所產生的氣體不易產生空氣污染,在掩埋分解的情況下不會產生其它有 毒物質污染土壤以及水質,因此可以達到環保的目的。In summary, the fibrous base cloth layer of the present invention has a mesh and includes fibers that are basically composed of cellulose. Since cellulose is a natural fiber, it has a better degradation rate and biocompatibility during processing, so The object of environmental protection can be achieved while solving the problem that the fabric structure is not easy to handle. Furthermore, when the fabric structure of the present invention is advertising cloth, it can have a better inkjet effect. Compared with the advertising cloth currently on the market, the weight is reduced by nearly half, and it is light and soft, and the installation and disassembly are simpler and quicker. Furthermore, the fabric structure material of the present invention is light and small in size, which can effectively reduce transportation costs. In addition, compared with the polyvinyl chloride (PVC) used in traditional advertising cloth, the fabric structure of the present invention has simpler production of wood pulp viscose fibers and lower energy consumption, and polyvinyl chloride (PVC) is used as a typical High-energy-consuming products, whether it is polyvinyl chloride (PVC) made by the calcium carbide method or the ethylene method, have high energy consumption and cost, which does not meet the current global trend of energy conservation and emission reduction, and the reuse of limited resources. At the same time, wood pulp Viscose fiber is the raw material of environmentally friendly inkjet advertising cloth, and the treatment after use also meets the requirements of environmental protection. On the other hand, the fabric structure of the present invention can be easily crushed and recycled, and regenerated into other products, such as product packaging shells, flower pots, leather bag hard linings, etc., and the gas produced after combustion is not easy to produce air pollution. In the case of burying and decomposing, other toxic substances will not be produced to pollute the soil and water quality, so the purpose of environmental protection can be achieved.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed above with the embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the technical field may make some changes and modifications without departing from the spirit and scope of the present invention. The scope of protection of the present invention should be defined by the scope of the appended patent application.
11、20:纖維基布層
12、13:PVC
21:經線
22:緯線
23:網孔
24:第一表面
25:第二表面
30、40:膠層
50:塗層
51:上表面
10、60:織物結構
70:油墨
80:遮光層
11, 20: fiber
圖1是依據習知織物結構之外觀示意圖。
圖2是依據習知織物結構之剖面示意圖。
圖3A是依據本發明一些實施例之纖物結構的纖維基布層外觀示意圖。
圖3B是圖3A中3B-3B’斷面的剖面示意圖。
圖4是依據本發明一些實施例之纖物結構的立體剖視圖。
圖5是是圖4中5-5’斷面的剖面示意圖。
圖6是依據本發明一些實施例之纖物結構的剖面示意圖。
圖7是依據本發明一些實施例之織物結構的應用示意圖。
圖8是係依據本發明一些實施例之木漿黏膠纖維與其他材質可降解的生物降解率比較座標圖。
應說明的是,上述各圖的膜層皆為示意繪示,不用於限制本發明的形狀、層數與厚度比例。
Figure 1 is a schematic diagram of the appearance of a conventional fabric structure.
Fig. 2 is a schematic cross-sectional view of a conventional fabric structure.
Fig. 3A is a schematic view showing the appearance of the fiber base cloth layer of the fiber structure according to some embodiments of the present invention.
Fig. 3B is a schematic cross-sectional view of
20:纖維基布層 20: fiber base cloth layer
21:經線 21: Warp
22:緯線 22: Weft
23:網孔 23: mesh
24:第一表面 24: First Surface
25:第二表面 25: second surface
30、40:膠層 30, 40: Adhesive layer
50:塗層 50: coating
51:上表面 51: upper surface
60:織物結構 60: fabric structure
Claims (9)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17/534,279 US20220220665A1 (en) | 2021-01-11 | 2021-11-23 | Textile structure |
CN202111483002.7A CN114753158A (en) | 2021-01-11 | 2021-12-07 | Fabric structure |
EP21215090.8A EP4026943A3 (en) | 2021-01-11 | 2021-12-16 | Textile structure |
KR1020210183200A KR20220101561A (en) | 2021-01-11 | 2021-12-20 | Textile structure |
CA3142522A CA3142522A1 (en) | 2021-01-11 | 2021-12-20 | Textile structure |
AU2021290202A AU2021290202A1 (en) | 2021-01-11 | 2021-12-20 | Textile structure |
JP2021214582A JP2022107582A (en) | 2021-01-11 | 2021-12-28 | Textile structure |
BR102022000147-2A BR102022000147A2 (en) | 2021-01-11 | 2022-01-05 | TEXTILE STRUCTURE |
MX2022000331A MX2022000331A (en) | 2021-01-11 | 2022-01-06 | Textile structure. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW110101008 | 2021-01-11 | ||
TW110101008 | 2021-01-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW202227696A TW202227696A (en) | 2022-07-16 |
TWI787886B true TWI787886B (en) | 2022-12-21 |
Family
ID=83437083
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW110123379A TWI787886B (en) | 2021-01-11 | 2021-06-25 | Textile structure |
Country Status (1)
Country | Link |
---|---|
TW (1) | TWI787886B (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWM392826U (en) * | 2010-07-15 | 2010-11-21 | He Ting Co Ltd | canvas |
CN110353354A (en) * | 2019-06-28 | 2019-10-22 | 天津天星科生皮革制品有限公司 | A kind of waterproof and breathable, anti-puncture safe instep and its manufacturing method |
CN111361226A (en) * | 2020-03-17 | 2020-07-03 | 施海峰 | Cloth with waterproof function and preparation process thereof |
CN111719318A (en) * | 2020-06-29 | 2020-09-29 | 刘裕芬 | Novel waterproof moisture-permeable fabric |
-
2021
- 2021-06-25 TW TW110123379A patent/TWI787886B/en active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWM392826U (en) * | 2010-07-15 | 2010-11-21 | He Ting Co Ltd | canvas |
CN110353354A (en) * | 2019-06-28 | 2019-10-22 | 天津天星科生皮革制品有限公司 | A kind of waterproof and breathable, anti-puncture safe instep and its manufacturing method |
CN111361226A (en) * | 2020-03-17 | 2020-07-03 | 施海峰 | Cloth with waterproof function and preparation process thereof |
CN111719318A (en) * | 2020-06-29 | 2020-09-29 | 刘裕芬 | Novel waterproof moisture-permeable fabric |
Also Published As
Publication number | Publication date |
---|---|
TW202227696A (en) | 2022-07-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI777216B (en) | Polypropylene fabric environmental protection inkjet advertising cloth | |
Khan et al. | The use of jute fibers as reinforcements in composites | |
KR20210001299U (en) | Splicable environmentally-friendly non-pvc advertising cloth made of a woven structure | |
CN213092772U (en) | Coating structure of shading type advertisement spray painting cloth | |
CN103668986B (en) | Blade of louver window and preparation method thereof | |
KR100901199B1 (en) | A method for manufacturing a high-visible fluorescent/axis-lighting polyurethane film with enhanced contrast and strength | |
TWI787886B (en) | Textile structure | |
KR101635001B1 (en) | Superior See-Through and Energy Saving Sunscreen Fabrics with Coated Yarn Containing Organic/Inorganic Hybrid Coating Layer and The Preparation Method Thereof | |
CN107075292A (en) | Fire-retardant combination for textile substrates | |
US9869046B2 (en) | Polyester acetate tear-away printed label and methods of manufacturing | |
CN205272714U (en) | Fire -retardant waterproof surface fabric | |
EP4214047A1 (en) | The multi-layer composite sleeve, in particular for trenchless pipeline rehabilitation | |
RU2801648C2 (en) | Textile structure | |
EP4026943A2 (en) | Textile structure | |
NZ783733A (en) | Textile structure | |
JP3651583B2 (en) | Exposed soil prevention sheet and method for producing the same | |
CN217968776U (en) | Flame-retardant water-based suede microfiber automotive interior leather | |
CN217993735U (en) | Tear-resistant flame-retardant curtain decorative fabric | |
JP4541502B2 (en) | Biodegradable mesh sheet for construction work | |
CN221392567U (en) | Anti-fouling rubber cloth for box | |
KR101115401B1 (en) | Fabrics for wall paper | |
KR101600979B1 (en) | Non-toxic blackout blind | |
CN103388264A (en) | Caravan tent fabric and production method thereof | |
CN212895626U (en) | Environment-friendly coating textile fabric | |
BR102021015525A2 (en) | ECOLOGICALLY CORRECT POLYPROPYLENE ADVERTISING FABRIC |