TWI784266B - Semiconductor device and the manufacturing method thereof - Google Patents

Semiconductor device and the manufacturing method thereof Download PDF

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TWI784266B
TWI784266B TW109114437A TW109114437A TWI784266B TW I784266 B TWI784266 B TW I784266B TW 109114437 A TW109114437 A TW 109114437A TW 109114437 A TW109114437 A TW 109114437A TW I784266 B TWI784266 B TW I784266B
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TW202143506A (en
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蕭長泰
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晶元光電股份有限公司
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Abstract

The present disclosure provides a semiconductor device comprising a substrate, a first semiconductor contact layer disposed on the substrate, an active structure disposed on the first semiconductor contact layer, and an electrode disposed on the first semiconductor contact layer. The first semiconductor contact layer includes a first region, a second region, and a dopant. The active structure is disposed on the first region and not disposed on the second region. The second region further includes a first sub-region and a second sub-region wherein the electrode is disposed on the first sub-region and not disposed on the second sub-region. The first sub-region is lower than the second sub-region. The present disclosure further provides a method for manufacturing the above-mentioned semiconductor device.

Description

半導體元件及其製造方法Semiconductor element and its manufacturing method

本揭露係關於一種半導體元件及其製造方法,特別關於一種具有處理區之半導體元件及其製造方法。The present disclosure relates to a semiconductor device and a manufacturing method thereof, in particular to a semiconductor device with a processing region and a manufacturing method thereof.

隨著科技的發展,III-V族半導體材料已可被製造成各種半導體元件,並廣泛應用於照明、醫療、顯示、通訊、感測、電源系統等領域。本揭露即在提出一新穎的半導體元件及其製造方法以改善元件的電性特性。With the development of science and technology, III-V semiconductor materials can be manufactured into various semiconductor components, and are widely used in lighting, medical treatment, display, communication, sensing, power supply systems and other fields. This disclosure proposes a novel semiconductor device and its manufacturing method to improve the electrical properties of the device.

本揭露在提供一種半導體元件,包括一基板、一第一半導體接觸層位於所述之基板上、一主動結構位於所述之第一半導體接觸層上、一電極位於所述之主動結構上。其中,所述之第一半導體接觸層包含一第一區、一第二區、及一摻雜質,所述之主動結構位於所述之第一區且不位於所述之第二區。其中,所述之第二區更包含一第一子區及一第二子區,所述之電極位於所述之第一子區且不位於所述之第二子區,並且,所述之第一子區係低於所述之第二子區。The present disclosure provides a semiconductor element, which includes a substrate, a first semiconductor contact layer on the substrate, an active structure on the first semiconductor contact layer, and an electrode on the active structure. Wherein, the first semiconductor contact layer includes a first region, a second region, and a dopant, and the active structure is located in the first region and not in the second region. Wherein, the second region further includes a first subregion and a second subregion, the electrode is located in the first subregion and not in the second subregion, and the The first sub-section is lower than said second sub-section.

於一實施例,所述之主動結構包含一量子井層包含AlxGa1-xN,其中0.05≤x≤0.5。於一實施例,於所述之半導體元件之一剖面,所述之第一子區之一表面係低於所述之第二子區之表面 6~30 nm。於一實施例,所述之第一子區具有一剖面形狀大約為淺碟狀。於一實施例,所述之第二子區環繞所述之第一子區。於一實施例,於所述之半導體元件之一剖面,所述之第一子區具有一處理區自所述之第一子區之一表面向所述之基板延伸。於一實施例,於所述之第一半導體接觸層內,所述之摻雜質於所述之處理區內之一摻雜濃度大於超出所述之處理區之一區域之一摻雜濃度。於一實施例,所述之第一半導體接觸層包含AlxGa1-xN,0.3≤x≤0.7。於一實施例,所述之半導體元件更包含一高摻雜半導體接觸層形成於所述之第一半導體接觸層及所述之電極之間。於一實施例,所述之高摻雜半導體接觸層不含有鋁或包含一鋁含量小於所述之第一半導體接觸層之一鋁含量。於一實施例,所述之第一半導體接觸層與所述之高摻雜半導體接觸層包含相同之所述之摻雜質,且所述之摻雜質在所述之高摻雜半導體接觸層之一摻雜濃度大於在所述之第一半導體接觸層之一摻雜濃度。於一實施例,所述之摻雜質在所述之高摻雜半導體接觸層之一摻雜濃度大於在所述之第一半導體接觸層之所述之處理區內之所述之摻雜濃度。In one embodiment, the active structure includes a quantum well layer including AlxGa1-xN, where 0.05≤x≤0.5. In one embodiment, in a cross section of the semiconductor device, a surface of the first sub-region is 6-30 nm lower than a surface of the second sub-region. In one embodiment, the first sub-region has a cross-sectional shape of approximately a shallow dish. In one embodiment, the second sub-region surrounds the first sub-region. In one embodiment, in a cross section of the semiconductor device, the first sub-region has a processing region extending from a surface of the first sub-region to the substrate. In one embodiment, in the first semiconductor contact layer, a doping concentration of the dopant in the processing region is greater than a doping concentration in a region beyond the processing region. In one embodiment, the first semiconductor contact layer includes AlxGa1-xN, 0.3≤x≤0.7. In one embodiment, the semiconductor device further includes a highly doped semiconductor contact layer formed between the first semiconductor contact layer and the electrode. In one embodiment, the highly doped semiconductor contact layer does not contain aluminum or contains an aluminum content smaller than that of the first semiconductor contact layer. In one embodiment, the first semiconductor contact layer and the highly doped semiconductor contact layer contain the same dopant, and the dopant is in the highly doped semiconductor contact layer A doping concentration is greater than a doping concentration in the first semiconductor contact layer. In one embodiment, the doping concentration of the dopant in the highly doped semiconductor contact layer is greater than the doping concentration in the treatment region of the first semiconductor contact layer .

本揭露又提供一種半導體元件之製造方法,包括提供一基板、形成一半導體接觸層位於所述之基板上,其中,所述之第一半導體接觸層包含一第一區、一第二區、及一摻雜質、形成一主動結構於所述之第一半導體接觸層之第一區及第二區上、移除位於所述之第二區上之所述之主動結構以露出所述之第二區之所述之第一半導體接觸層,其中,所述之第二區更包含一第一子區及一第二子區、形成一遮罩於所述之主動結構及所述之第一半導體接觸層上,其中,所述之遮罩覆蓋所述之第二子區並且包含一開口露出所述之第一子區、處理所述之開口所露出之所述之第一子區以形成一處理區、以及形成一電極於所述之第一子區上,其中,所述之第一子區之一上表面低於未被處理的所述之第二子區之一上表面。The disclosure further provides a method for manufacturing a semiconductor device, including providing a substrate, forming a semiconductor contact layer on the substrate, wherein the first semiconductor contact layer includes a first region, a second region, and A dopant, forming an active structure on the first region and the second region of the first semiconductor contact layer, removing the active structure on the second region to expose the first The first semiconductor contact layer of the second region, wherein the second region further includes a first sub-region and a second sub-region, forming a mask on the active structure and the first On the semiconductor contact layer, wherein the mask covers the second sub-region and includes an opening exposing the first sub-region, processing the first sub-region exposed by the opening to form A treatment area, and forming an electrode on the first sub-area, wherein an upper surface of the first sub-area is lower than an upper surface of the second sub-area that has not been processed.

於一實施例,處理所述之開口所露出之所述之第一子區的步驟包含以一矽氯烷電漿處理所述之第一子區。於一實施例,處理所述之開口所露出之所述之第一子區之步驟對於所述之第一半導體接觸層具有一蝕刻率為 0.1 ~ 0.6 nm/sec。In one embodiment, the step of treating the first sub-region exposed by the opening includes treating the first sub-region with a siloxane plasma. In one embodiment, the step of processing the first sub-region exposed by the opening has an etching rate of 0.1˜0.6 nm/sec for the first semiconductor contact layer.

請參照第1圖,顯示符合本揭露之半導體元件10之第一實施例。半導體元件10例如為一發光元件,包含基板100、第一半導體接觸層102、主動結構103例如為一發光疊層、以及第二半導體接觸層104依序形成於基板100上、第一電極105與第一半導體接觸層102電性連接、第二電極106與第二半導體接觸層104電性連接。具體而言,第一半導體接觸層102包含第一區102a、第二區102b、及摻雜質,其中,第一半導體接觸層102之第一區102a之厚度大於第二區102b之厚度。主動結構103位於第一區102a且不位於第二區102b。第二區更包含第一子區102b1及第二子區102b2,第一電極105位於第一子區102b1且不位於第二子區102b2,並且第一電極105與第一子區102b1之第一半導體接觸層102形成良好的電性接觸,例如歐姆接觸;其中,第一子區102b1之上表面係低於第二子區102b2之上表面,例如低於6~30 nm,較佳為低於10~20 nm。其中,第一子區102b1具有一剖面形狀大約為淺碟狀。於一實施例,第二子區102b2環繞第一子區102b1。如第1圖所示,第一半導體接觸層102於第一子區102b1具有一處理區107自第一子區102b1之上表面向基板延伸一深度,其中,所述之深度例如為0.1~50nm。第一半導體接觸層102之摻雜質於處理區107內包含第一摻雜濃度,第一半導體接觸層102之摻雜質於超出處理區107之區域包含第二摻雜濃度,且第一摻雜濃度大於第二摻雜濃度。較佳地,第一摻雜濃度自第一子區102b1之上表面朝向基板方向遞減。於一實施例,第一半導體接觸層102包含Alx Ga1-x N,0.3≤x≤0.7,所述之摻雜質例如為矽,第一摻雜濃度為5*1019 cm-3 ~5*1020 cm-3 ,第二摻雜濃度為1019 cm-3 ~1020 cm-3 。主動結構103包含一第一載子阻擋層(carrier blocking layer) 103a位於第一半導體接觸層102上、一主動層(active layer) 103b例如為一發光層,位於第一載子阻擋層103a上、以及一第二載子阻擋層103c位於主動層103b上。其中,第一載子阻擋層103a具有第一導電型並且第二載子阻擋層103c具有第二導電型相反於第一導電型,其中,第一導電型例如為n型且第二導電型例如為p型。第一載子阻擋層103a及第二載子阻擋層103c用以侷限載子(電子及電洞)於主動層103b內以避免載子溢流出主動層103b而降低發光效率。主動層103b包含多重量子井(Multiple Quantum Wells; MQW)結構,其中多重量子井結構係包含複數個阻障層(barrier layer)103b1及複數個量子井層(quantum well layer)103b2交互堆疊,並於驅動時發出可見光或不可見光,其中,交疊之對數例如3~15對(pairs) 。量子井層103b1之材料具有一能隙(energy band gap) 對應發出光之波長並且小於阻障層103b2之能隙。第一載子阻擋層103a及第二載子阻擋層103c各具有一能隙高於量子井層103b1之能隙。於驅動時,載子(電子及電洞)於量子井層103b1結合以發出特定波長之光線,例如峰波長為190 ~ 400 nm之紫外光。第一半導體接觸層102與第一載子阻擋層103a具有相同之第一導電型並且第二半導體接觸層104與第二載子阻擋層103c具有相同之第二導電型,第一導電型例如為n型且第二導電型例如為p型。於一實施例,第一半導體接觸層102包含Alx Ga1-x N,0.3≤x≤0.7,且包含一n型摻雜質(例如為矽)以及一n型摻雜濃度為1019 cm-3 ~1020 cm-3 ;第一載子阻擋層103a及/或阻障層103b1包含一n型摻雜質(例如為矽)以及一n型摻雜濃度,例如為101 8 cm-3 ~1019 cm-3 ,小於第一半導體接觸層102之摻雜濃度;量子井層103b1包含非故意摻雜 (unintentionally doped) 之Alx Ga1–xN (0.05 ≤ x ≤ 0.5) 並具有一厚度介於1~5 nm之間,阻障層103b2例如包含摻雜或非故意摻雜Alx Ga1-x N(0.3≤x≤0.7)並且具有一厚度介於5~15 nm之間;第二載子阻擋層103c包含Alx Ga1-x N,0.3≤x≤0.7,且包含一p型摻雜質(例如為鎂)以及一p型摻雜濃度,例如為101 7 cm-3 ~1018 cm-3 ,小於第二半導體接觸層102之摻雜濃度;第二半導體接觸層104包含GaN,且包含一p型摻雜質(例如為鎂)以及一p型摻雜濃度為1019 cm-3 ~5*1020 cm-3Please refer to FIG. 1 , which shows a first embodiment of a semiconductor device 10 according to the present disclosure. The semiconductor element 10 is, for example, a light emitting element, comprising a substrate 100, a first semiconductor contact layer 102, an active structure 103 such as a light emitting stack, and a second semiconductor contact layer 104 sequentially formed on the substrate 100, a first electrode 105 and The first semiconductor contact layer 102 is electrically connected, and the second electrode 106 is electrically connected to the second semiconductor contact layer 104 . Specifically, the first semiconductor contact layer 102 includes a first region 102a, a second region 102b, and dopants, wherein the thickness of the first region 102a of the first semiconductor contact layer 102 is greater than the thickness of the second region 102b. The active structure 103 is located in the first area 102a and not located in the second area 102b. The second area further includes a first sub-area 102b1 and a second sub-area 102b2, the first electrode 105 is located in the first sub-area 102b1 and not in the second sub-area 102b2, and the first electrode 105 and the first sub-area 102b1 The semiconductor contact layer 102 forms a good electrical contact, such as an ohmic contact; wherein, the upper surface of the first sub-region 102b1 is lower than the upper surface of the second sub-region 102b2, for example, lower than 6-30 nm, preferably lower than 10~20nm. Wherein, the first sub-region 102b1 has a cross-sectional shape of approximately a shallow dish. In one embodiment, the second sub-region 102b2 surrounds the first sub-region 102b1. As shown in FIG. 1, the first semiconductor contact layer 102 has a treatment region 107 extending from the upper surface of the first sub-region 102b1 to the substrate at a depth in the first sub-region 102b1, wherein the depth is, for example, 0.1-50nm . The dopant of the first semiconductor contact layer 102 contains a first dopant concentration in the processing region 107, the dopant of the first semiconductor contact layer 102 contains a second dopant concentration in a region beyond the processing region 107, and the first dopant The dopant concentration is greater than the second dopant concentration. Preferably, the first doping concentration decreases gradually from the upper surface of the first sub-region 102b1 toward the substrate. In one embodiment, the first semiconductor contact layer 102 includes AlxGa1 - xN , 0.3≤x≤0.7, the dopant is silicon, for example, the first doping concentration is 5*10 19 cm -3 ~ 5*10 20 cm -3 , the second doping concentration is 10 19 cm -3 to 10 20 cm -3 . The active structure 103 includes a first carrier blocking layer (carrier blocking layer) 103a located on the first semiconductor contact layer 102, an active layer (active layer) 103b such as a light emitting layer located on the first carrier blocking layer 103a, And a second carrier blocking layer 103c is located on the active layer 103b. Wherein, the first carrier blocking layer 103a has a first conductivity type and the second carrier blocking layer 103c has a second conductivity type opposite to the first conductivity type, wherein the first conductivity type is, for example, n-type and the second conductivity type is, for example, For p-type. The first carrier blocking layer 103a and the second carrier blocking layer 103c are used to confine carriers (electrons and holes) in the active layer 103b to prevent carriers from overflowing out of the active layer 103b to reduce luminous efficiency. The active layer 103b includes a multiple quantum well (Multiple Quantum Wells; MQW) structure, wherein the multiple quantum well structure includes a plurality of barrier layers (barrier layer) 103b1 and a plurality of quantum well layers (quantum well layer) 103b2 stacked alternately, and in Visible light or invisible light is emitted during driving, wherein the number of overlapping pairs is, for example, 3-15 pairs. The material of the quantum well layer 103b1 has an energy band gap corresponding to the wavelength of the emitted light and smaller than the energy band gap of the barrier layer 103b2. Each of the first carrier blocking layer 103a and the second carrier blocking layer 103c has an energy gap higher than that of the quantum well layer 103b1. During driving, carriers (electrons and holes) combine in the quantum well layer 103b1 to emit light of a specific wavelength, such as ultraviolet light with a peak wavelength of 190-400 nm. The first semiconductor contact layer 102 has the same first conductivity type as the first carrier blocking layer 103a and the second semiconductor contact layer 104 has the same second conductivity type as the second carrier blocking layer 103c. The first conductivity type is, for example, n-type and the second conductivity type is, for example, p-type. In one embodiment, the first semiconductor contact layer 102 includes AlxGa1 - xN , 0.3≤x≤0.7, and includes an n-type dopant (such as silicon) and an n-type dopant concentration of 10 19 cm -3 to 10 20 cm -3 ; the first carrier blocking layer 103a and/or the blocking layer 103b1 includes an n-type dopant (such as silicon) and an n-type dopant concentration, such as 10 18 cm - 3 ~ 10 19 cm -3 , less than the doping concentration of the first semiconductor contact layer 102; the quantum well layer 103b1 contains unintentionally doped (unintentionally doped) Al x Ga 1–xN (0.05 ≤ x ≤ 0.5) and has a The thickness is between 1~5 nm, and the barrier layer 103b2, for example, includes doped or unintentionally doped AlxGa1 - xN (0.3≤x≤0.7) and has a thickness between 5~15 nm; The second carrier blocking layer 103c includes Al x Ga 1-x N, 0.3≤x≤0.7, and includes a p-type dopant (such as magnesium) and a p-type dopant concentration, such as 10 1 7 cm - 3 to 10 18 cm -3 , less than the doping concentration of the second semiconductor contact layer 102; the second semiconductor contact layer 104 includes GaN, and includes a p-type dopant (such as magnesium) and a p-type dopant concentration of 10 19 cm -3 ~5*10 20 cm -3 .

請參照第2圖,顯示符合本揭露之半導體元件之第二實施例。於本實施例中,具有與第一實施例相同名稱或標號之組成構件代表為相對應之構件,具有相同之結構、組成材料及功效等特性及性質,其具體描述,如未特別描述於本實施例,則可參照第一實施例之內容,不在此詳細贅述。本實施例與第一實施例之主要差異在於半導體元件20包含第一實施例之全部構件且更包含一高摻雜半導體接觸層108形成於第一半導體接觸層102及第一電極105之間,其中,高摻雜半導體接觸層108不包含鋁或包含鋁含量小於第一半導體接觸層102之鋁含量。於一實施例,高摻雜半導體接觸層108包含Alx Ga1-x N(0>x≤0.3)或GaN,且包含一n型摻雜質(例如為矽)以及一第三摻雜濃度,例如為1020 cm-3 ~1021 cm-3 ,其中,第三摻雜濃度大於第一摻雜濃度,較佳地,第三摻雜濃度大於第一摻雜濃度以及第二摻雜濃度。Please refer to FIG. 2, which shows a second embodiment of a semiconductor device according to the present disclosure. In this embodiment, the components having the same names or labels as those in the first embodiment represent corresponding components, which have the same characteristics and properties such as structure, composition material and function, and their specific descriptions, if not specifically described in this For the embodiment, reference may be made to the content of the first embodiment, and details are not repeated here. The main difference between this embodiment and the first embodiment is that the semiconductor element 20 includes all components of the first embodiment and further includes a highly doped semiconductor contact layer 108 formed between the first semiconductor contact layer 102 and the first electrode 105, Wherein, the highly doped semiconductor contact layer 108 does not contain aluminum or contains an aluminum content smaller than that of the first semiconductor contact layer 102 . In one embodiment, the highly doped semiconductor contact layer 108 includes AlxGa1 - xN (0>x≤0.3) or GaN, and includes an n-type dopant (such as silicon) and a third dopant concentration , for example, 10 20 cm -3 to 10 21 cm -3 , wherein the third doping concentration is greater than the first doping concentration, preferably, the third doping concentration is greater than the first doping concentration and the second doping concentration .

請參照第3A-3E圖以及第1圖,顯示符合本揭露第一實施例之半導體元件之製造方法,其包括以下步驟(步驟S1~S3請參照第3A圖、步驟S4請參照第3B圖、步驟S5~S6請參照第3C圖、步驟S7請參照第3D圖、步驟S8請參照第3E圖、步驟S9~S10請參照第1圖): S1. 請參照第3A圖,提供基板100; S2. 形成第一半導體接觸層102於基板100上,其中,第一半導體接觸層102包含第一區102a、第二區102b; S3. 形成主動結構103及第二半導體接觸層104於第一半導體接觸層102之第一區102a及第二區102b上; S4. 請參照第3B圖,形成第一遮罩MK1於第二半導體接觸層104上,其中,第一遮罩MK1對應形成於第一半導體接觸層102之第一區102a上; S5. 請參照第3C圖,蝕刻移除對應第二區102b上之主動結構103及第二半導體接觸層104以露出第一半導體接觸層102之第二區102b,其中,第二區102b更包含第一子區102b1及第二子區102b2; S6. 移除第一遮罩M1; S7. 請參照第3D圖,形成第二遮罩MK2於第二半導體接觸層104及第一半導體接觸層102之第二區102b上,其中,第二遮罩MK2覆蓋第二子區102b2並且包含一開口露出第一子區102b1; S8. 請參照第3E圖,處理開口所露出之第一子區102b1; S9. 移除第二遮罩MK2;以及 S10.形成第一電極105於處理過的第一子區102b1上以及形成第二電極106於第二半導體接觸層104上,以形成如第1圖所示之半導體元件10。Please refer to FIG. 3A-3E and FIG. 1, which shows the manufacturing method of the semiconductor device according to the first embodiment of the present disclosure, which includes the following steps (steps S1~S3 please refer to FIG. 3A, step S4 please refer to FIG. 3B, For steps S5~S6, please refer to Figure 3C, for step S7, please refer to Figure 3D, for step S8, please refer to Figure 3E, for steps S9~S10, please refer to Figure 1): S1. Please refer to Figure 3A to provide a substrate 100; S2. Forming a first semiconductor contact layer 102 on the substrate 100, wherein the first semiconductor contact layer 102 includes a first region 102a and a second region 102b; S3. Forming the active structure 103 and the second semiconductor contact layer 104 on the first region 102a and the second region 102b of the first semiconductor contact layer 102; S4. Referring to FIG. 3B, a first mask MK1 is formed on the second semiconductor contact layer 104, wherein the first mask MK1 is correspondingly formed on the first region 102a of the first semiconductor contact layer 102; S5. Please refer to FIG. 3C, etch and remove the active structure 103 and the second semiconductor contact layer 104 corresponding to the second region 102b to expose the second region 102b of the first semiconductor contact layer 102, wherein the second region 102b further includes the first sub-area 102b1 and the second sub-area 102b2; S6. Remove the first mask M1; S7. Referring to FIG. 3D, a second mask MK2 is formed on the second semiconductor contact layer 104 and the second region 102b of the first semiconductor contact layer 102, wherein the second mask MK2 covers the second sub-region 102b2 and includes an opening exposing the first sub-region 102b1; S8. Referring to Figure 3E, process the first sub-area 102b1 exposed by the opening; S9. Removing the second mask MK2; and S10. Forming the first electrode 105 on the processed first sub-region 102b1 and forming the second electrode 106 on the second semiconductor contact layer 104, so as to form the semiconductor device 10 as shown in FIG. 1 .

請參照第3A-3F圖以及第2圖,顯示符合本揭露第二實施例之半導體元件之製造方法,其中,包括以下步驟(步驟S1~S3請參照第3A圖、步驟S4請參照第3B圖、步驟S5~S6請參照第3C圖、步驟S7請參照第3D圖、步驟S8請參照第3E圖、步驟S9請參照第3F圖、步驟S10-S11請參照第2圖): S1. 請參照第3A圖,提供基板100; S2. 形成第一半導體接觸層102於基板100上,其中,第一半導體接觸層102包含第一區102a、第二區102b; S3. 形成主動結構103及第二半導體接觸層104於第一半導體接觸層102之第一區102a及第二區102b上; S4. 請參照第3B圖,形成第一遮罩MK1於第二半導體接觸層104上,其中,第一遮罩MK1對應形成於第一半導體接觸層102之第一區102a上; S5. 請參照第3C圖,蝕刻移除對應第二區102b上之主動結構103及第二半導體接觸層104以露出第一半導體接觸層102之第二區102b,其中,第二區102b更包含第一子區102b1及第二子區102b2; S6. 移除第一遮罩MK1; S7. 請參照第3D圖,形成第二遮罩MK2於主動結構103及第一半導體接觸層102之第二區102b上,其中,第二遮罩MK2覆蓋第二子區102b2並且包含一開口露出第一子區102b1; S8. 請參照第3E圖,處理開口所露出之第一子區102b1; S9. 請參照第3F圖,形成高摻雜半導體接觸層108於處理後之第一子區102b1; S10. 移除第二遮罩MK2;以及 S11.形成第一金屬電極105於高摻雜半導體接觸層108上以及形成第二金屬電極106於第二半導體接觸層104上,以形成如第2圖所示之半導體元件20。Please refer to FIG. 3A-3F and FIG. 2, showing the manufacturing method of the semiconductor device according to the second embodiment of the present disclosure, which includes the following steps (steps S1~S3 please refer to FIG. 3A, and step S4 please refer to FIG. 3B , Steps S5~S6, please refer to Figure 3C, Step S7, please refer to Figure 3D, Step S8, please refer to Figure 3E, Step S9, please refer to Figure 3F, Steps S10-S11, please refer to Figure 2): S1. Please refer to Figure 3A to provide a substrate 100; S2. forming a first semiconductor contact layer 102 on the substrate 100, wherein the first semiconductor contact layer 102 includes a first region 102a and a second region 102b; S3. Forming the active structure 103 and the second semiconductor contact layer 104 on the first region 102a and the second region 102b of the first semiconductor contact layer 102; S4. Referring to FIG. 3B, a first mask MK1 is formed on the second semiconductor contact layer 104, wherein the first mask MK1 is correspondingly formed on the first region 102a of the first semiconductor contact layer 102; S5. Please refer to FIG. 3C, etch and remove the active structure 103 and the second semiconductor contact layer 104 corresponding to the second region 102b to expose the second region 102b of the first semiconductor contact layer 102, wherein the second region 102b further includes the first sub-area 102b1 and the second sub-area 102b2; S6. Remove the first mask MK1; S7. Referring to FIG. 3D, a second mask MK2 is formed on the active structure 103 and the second region 102b of the first semiconductor contact layer 102, wherein the second mask MK2 covers the second sub-region 102b2 and includes an opening exposed the first sub-area 102b1; S8. Referring to Figure 3E, process the first sub-area 102b1 exposed by the opening; S9. Please refer to FIG. 3F, forming a highly doped semiconductor contact layer 108 in the processed first sub-region 102b1; S10. Removing the second mask MK2; and S11. Form the first metal electrode 105 on the highly doped semiconductor contact layer 108 and form the second metal electrode 106 on the second semiconductor contact layer 104 to form the semiconductor device 20 as shown in FIG. 2 .

於上述各實施例所述之製造方法,其中,處理所述之開口所露出之第一子區102b1之步驟包含以一電漿處理第一子區102b1,其中,所述之電漿處理第一子區102b1之第一半導體接觸層102之蝕刻率例如為 0.1 ~ 0.6 nm/sec,處理時間例如為30~90 sec。所述之電漿處理使得第一子區102b1之上表面低於第二子區102b2之上表面,例如低於6~30 nm,較佳為低於10~20 nm。其中,第一子區102b1具有一剖面形狀大約為淺碟狀。所述之電漿處理使得第一半導體接觸層102於第一子區102b1形成一處理區107,其中,處理區107之範圍係自第一子區102b1之上表面向基板延伸一深度,其中,所述之深度例如為0.1~50nm。於一實施例,所述之電漿包含與第一半導體接觸層102之摻雜質相同之元素,例如所述之電漿包含矽氯烷(SiCl4 )電漿且所述之摻雜質包含矽(Si) 。所述之電漿處理使得第一半導體接觸層102之摻雜質於處理區107內包含第一摻雜濃度,第一半導體接觸層102之摻雜質於超出處理區107之區域包含第二摻雜濃度,且第一摻雜濃度大於第二摻雜濃度。較佳地,第一摻雜濃度自第一子區102b1之上表面朝向基板方向遞減。於一實施例,第一半導體接觸層102包含Alx Ga1-x N,0.3≤x≤0.7,所述之摻雜質例如為矽,第一摻雜濃度為5*1019 cm-3 ~5*1020 cm-3 ,第二摻雜濃度為1019 cm-3 ~1020 cm-3 。其中,形成高摻雜半導體接觸層108於處理後之第一子區102b1之步驟係透過例如有機金屬化學氣相沉積法(MOCVD)直接磊晶成長於第一子區102b1露出之表面上。In the manufacturing method described in each of the above embodiments, wherein the step of treating the first sub-region 102b1 exposed by the opening includes treating the first sub-region 102b1 with a plasma, wherein the plasma treatment of the first The etch rate of the first semiconductor contact layer 102 of the sub-region 102b1 is, for example, 0.1-0.6 nm/sec, and the processing time is, for example, 30-90 sec. The plasma treatment makes the upper surface of the first sub-region 102b1 lower than the upper surface of the second sub-region 102b2, for example, lower than 6-30 nm, preferably lower than 10-20 nm. Wherein, the first sub-region 102b1 has a cross-sectional shape of approximately a shallow dish. The plasma treatment makes the first semiconductor contact layer 102 form a treatment region 107 in the first sub-region 102b1, wherein the range of the treatment region 107 extends from the upper surface of the first sub-region 102b1 to a depth to the substrate, wherein, The said depth is, for example, 0.1-50 nm. In one embodiment, the plasma contains the same elements as the dopant of the first semiconductor contact layer 102, for example, the plasma contains silane (SiCl 4 ) plasma and the dopant contains Silicon (Si). The plasma treatment makes the dopant of the first semiconductor contact layer 102 contain the first dopant concentration in the treatment region 107, and the dopant of the first semiconductor contact layer 102 contains the second dopant concentration in the region beyond the treatment region 107. impurity concentration, and the first doping concentration is greater than the second doping concentration. Preferably, the first doping concentration decreases gradually from the upper surface of the first sub-region 102b1 toward the substrate. In one embodiment, the first semiconductor contact layer 102 includes AlxGa1 - xN , 0.3≤x≤0.7, the dopant is silicon, for example, the first doping concentration is 5*10 19 cm -3 ~ 5*10 20 cm -3 , the second doping concentration is 10 19 cm -3 to 10 20 cm -3 . The step of forming the highly doped semiconductor contact layer 108 on the processed first sub-region 102b1 is directly epitaxially grown on the exposed surface of the first sub-region 102b1 by, for example, metal organic chemical vapor deposition (MOCVD).

請參照第4圖,顯示符合本揭露第三實施例之半導體元件。 半導體元件40包含實施例一之半導體元件10或實施例二之半導體元件20之所有結構,並且更包含電性絶緣層409覆蓋於第二半導體接觸層104、第一電極105、以及第二電極106上,其中電性絶緣層409具有開口分別露出第一電極105及第二電極106之一部份上表面使得第一電極墊410及第二電極墊411分別填入開口並與第一電極105及第二電極106電性連接。於一實施例,電性絶緣層409包含一平面,且第一電極墊410及第二電極墊411延伸覆蓋於電性絶緣層409之平面上。於一實施例,第一電極墊410及第二電極墊411投影在基板100的面積實質上相等。於一實施例,第一電極105及第二電極106投影在基板100的面積與基板100的面積的比值約為0.6~0.95。第一電極墊410及第二電極墊411用以電性連接至其他元件或外部電源。Please refer to FIG. 4, which shows a semiconductor device according to the third embodiment of the present disclosure. The semiconductor element 40 includes all the structures of the semiconductor element 10 of the first embodiment or the semiconductor element 20 of the second embodiment, and further includes an electrical insulating layer 409 covering the second semiconductor contact layer 104, the first electrode 105, and the second electrode 106 , wherein the electrical insulation layer 409 has openings that respectively expose a part of the upper surface of the first electrode 105 and the second electrode 106 so that the first electrode pad 410 and the second electrode pad 411 respectively fill the opening and are connected to the first electrode 105 and the second electrode 106. The second electrode 106 is electrically connected. In one embodiment, the electrical insulation layer 409 includes a plane, and the first electrode pad 410 and the second electrode pad 411 extend to cover the plane of the electrical insulation layer 409 . In one embodiment, the projected areas of the first electrode pad 410 and the second electrode pad 411 on the substrate 100 are substantially equal. In one embodiment, the ratio of the projected area of the first electrode 105 and the second electrode 106 on the substrate 100 to the area of the substrate 100 is about 0.6˜0.95. The first electrode pad 410 and the second electrode pad 411 are used to electrically connect to other components or external power sources.

於上述之各實施例中,基板100為一磊晶基板,例如為藍寶石基板,第一半導體接觸層102、主動結構103、第二半導體接觸層104、以及高摻雜半導體接觸層108係可透過例如有機金屬化學氣相沉積法(MOCVD)磊晶成長於基板100上。於一實施例,半導體元件之主要出光面係朝向基板100之背面發出,基板之材料對於主動層103a所發出的光為透明;於另一實施例,半導體元件之主要出光面係朝向第二半導體接觸層104發出,基板100之材料對於主動層103a所發出的光可為透明或不透明。於一實施例,基板100的上表面具有複數個彼此分開之凸起,用以改變光的行進路徑以增加光摘出效率。於一實施例中,所述之凸起係直接圖案化基板100之表面至一深度所形成,因此具有與基板100相同之組成材料。於另一實施例中,先於基板100的上表面形成一透光材料層後,再將透光材料層圖案化以形成所述之凸起,其中,所述之凸起與基板100具有不同之組成材料。In each of the above-mentioned embodiments, the substrate 100 is an epitaxial substrate, such as a sapphire substrate, and the first semiconductor contact layer 102, the active structure 103, the second semiconductor contact layer 104, and the highly doped semiconductor contact layer 108 are transparent For example, the epitaxy is grown on the substrate 100 by metal organic chemical vapor deposition (MOCVD). In one embodiment, the main light-emitting surface of the semiconductor element is emitted toward the back of the substrate 100, and the material of the substrate is transparent to the light emitted by the active layer 103a; in another embodiment, the main light-emitting surface of the semiconductor element is directed toward the second semiconductor The contact layer 104 emits light, and the material of the substrate 100 can be transparent or opaque to the light emitted by the active layer 103a. In one embodiment, the upper surface of the substrate 100 has a plurality of protrusions separated from each other for changing the path of the light to increase the light extraction efficiency. In one embodiment, the protrusions are formed by directly patterning the surface of the substrate 100 to a depth, and thus have the same composition material as the substrate 100 . In another embodiment, after forming a light-transmitting material layer on the upper surface of the substrate 100, the light-transmitting material layer is patterned to form the protrusions, wherein the protrusions and the substrate 100 have different The constituent materials.

於上述之各實施例中,第一半導體接觸層102、第一載子阻擋層103a、主動層103b、第二載子阻擋層103c、第二半導體接觸層104、以及高摻雜半導體接觸層108包含相同系列之III-V族化合物半導體材料,例如AlInGaN系列。其中, AlInGaN 系列可表示為(Alx1 In(1-x1) )1-x2 Gax2 N,其中,0≦x1 ≦1,0≦x2 ≦1。半導體元件發出之光線決定於主動層103b之材料組成,例如當主動層103b之材料包含AlGaN系列時,可發出峰值波長為190 nm~400 nm的紫外光。In the above-mentioned embodiments, the first semiconductor contact layer 102, the first carrier blocking layer 103a, the active layer 103b, the second carrier blocking layer 103c, the second semiconductor contact layer 104, and the highly doped semiconductor contact layer 108 Contains the same series of III-V compound semiconductor materials, such as AlInGaN series. Wherein, the AlInGaN series can be expressed as (Al x1 In (1-x1) ) 1-x2 Ga x2 N, where 0≦x 1 ≦1, 0≦x 2 ≦1. The light emitted by the semiconductor device depends on the material composition of the active layer 103b. For example, when the material of the active layer 103b includes AlGaN series, it can emit ultraviolet light with a peak wavelength of 190 nm~400 nm.

於上述之各實施例中,第一電極105及第二電極106係包含單層或多層金屬結構,例如包含鉻(Cr)、鈦(Ti)、鎢(W)、銀(Ag)、金(Au)、鋁(Al)、銦(In)、錫(Sn)、鎳(Ni)、鉑(Pt)或上述材料之合金,較佳地,包含對主動層103b發出之光線具有大於80%之反射率之金屬,例如銀(Ag)、鋁(Al)、或鉑(Pt)。第一電極墊410及第二電極墊411包含至少一材料選自於鎳(Ni)、鈦 (Ti)、鉑(Pt)、鈀(Pd)、銀(Ag)、金 (Au) 、鋁(Al)及銅(Cu)所組成之群組。第一電極墊410及第二電極墊411係作為銲接墊以連接於外部線路。In each of the above-mentioned embodiments, the first electrode 105 and the second electrode 106 are composed of a single-layer or multi-layer metal structure, such as chromium (Cr), titanium (Ti), tungsten (W), silver (Ag), gold ( Au), aluminum (Al), indium (In), tin (Sn), nickel (Ni), platinum (Pt), or alloys of the above materials, preferably, include a light emitting element having a ratio greater than 80% to the light emitted by the active layer 103b. Reflective metals, such as silver (Ag), aluminum (Al), or platinum (Pt). The first electrode pad 410 and the second electrode pad 411 comprise at least one material selected from nickel (Ni), titanium (Ti), platinum (Pt), palladium (Pd), silver (Ag), gold (Au), aluminum ( A group consisting of Al) and copper (Cu). The first electrode pad 410 and the second electrode pad 411 are used as welding pads to connect to external circuits.

於上述之各實施例中,第一遮罩MK1及第二遮罩MK2包含介電材料,例如氧化鉭(TaOx)、氧化鋁(AlOx )、二氧化矽(SiOx )、氧化鈦(TiOx )、氧化鈮(Nb2 O5 ) 、氮化矽(SiNx )或旋塗玻璃(SOG)。電性絶緣層409包含介電材料並可包含一分散式布拉格反射鏡 (DBR; Distributed Bragg Reflector) 結構,其中,所述之DBR結構係包含複數個第一介電層及複數個第二介電層相互交疊,且所述之第一介電層與所述之第二介電層具有不同的折射率,當半導體元件發出之光透過基板100摘出時,電性絶緣層409包含介電材料包含DBR結構有助於將光反射朝向基板100摘出,以增加半導體元件的發光效率。In the above-mentioned embodiments, the first mask MK1 and the second mask MK2 include dielectric materials such as tantalum oxide (TaOx), aluminum oxide ( AlOx ), silicon dioxide ( SiOx ), titanium oxide (TiO x ), niobium oxide (Nb 2 O 5 ), silicon nitride (SiN x ), or spin-on-glass (SOG). The electrically insulating layer 409 includes a dielectric material and may include a distributed Bragg reflector (DBR; Distributed Bragg Reflector) structure, wherein the DBR structure includes a plurality of first dielectric layers and a plurality of second dielectric layers. The layers overlap each other, and the first dielectric layer and the second dielectric layer have different refractive indices. When the light emitted by the semiconductor element is extracted through the substrate 100, the electrically insulating layer 409 includes a dielectric material The inclusion of the DBR structure helps to reflect light out towards the substrate 100 to increase the luminous efficiency of the semiconductor device.

請參照第5圖,顯示符合本揭露之半導體元件覆晶接合(flip-chip bonding)至一載板之半導體發光組件。半導體發光組件50包含複數個實施例三之半導體元件40、載板500、第一導線501、第二導線502、第一焊墊503、及第二焊墊504位於載板500上並電性連接複數個半導體元件40、以及透明保護結構505包覆該些半導體元件40及載板500。其中,第一導線501包含複數個第一凸出部501a朝向第二導線502,第二導線502包含複數個第二凸出部502a朝向第一導線501、且複數個第一凸出部501a係一對一地對應複數個第二凸出部502a。每一半導體元件40之第一電極墊410及第二電極墊411係分別連接至一對應之第一凸出部501a及第二凸出部502a使得複數個發光二極體元件40彼此並聯連接於載板500上。第一焊墊503及第二焊墊504分別電性連接第一導線501及第二導線502,用以電性連接至其他元件或外部電源。載板500例如為封裝次載體(package submount)或印刷電路板(printed circuit board; PCB);第一導線501、第二導線502、第一焊墊503、及第二焊墊504包含單層或多層結構並且包含至少一材料選自於鎳(Ni)、鈦 (Ti)、鉑(Pt)、鈀(Pd)、銀(Ag)、金 (Au) 、鋁(Al)及銅(Cu)所組成之群組。透明保護結構505係包含透明介電材料,例如包含有機透明介電材料包含材料選自於Su8、苯并環丁烯(BCB)、過氟環丁烷(PFCB)、矽膠(Silicone)、環氧樹脂(Epoxy)、丙烯酸樹脂(Acrylic Resin)、環烯烴聚合物(COC)、聚甲基丙烯酸甲酯(PMMA)、聚對苯二甲酸乙二酯(PET) 、聚碳酸酯(PC) 、聚醚醯亞胺(Polyetherimide) 、及氟碳聚合物(Fluorocarbon Polymer)所組成之群組,或是包含無機透明介電材料包含材料選自於氧化鋁(Al2O3)、氮化矽(SiNx)、氧化矽(SiOx)、氧化鈦(TiOx) 、氟化鎂(MgFx) 所組成之群組。Please refer to FIG. 5 , which shows a semiconductor light-emitting device according to the disclosure of flip-chip bonding of a semiconductor device to a carrier. The semiconductor light emitting component 50 includes a plurality of semiconductor elements 40 of the third embodiment, a carrier board 500, a first wire 501, a second wire 502, a first welding pad 503, and a second welding pad 504 located on the carrier board 500 and electrically connected A plurality of semiconductor devices 40 and a transparent protection structure 505 cover the semiconductor devices 40 and the carrier 500 . Wherein, the first wire 501 includes a plurality of first protrusions 501a facing the second wire 502, the second wire 502 includes a plurality of second protrusions 502a facing the first wire 501, and the plurality of first protrusions 501a are The plurality of second protrusions 502a correspond one-to-one. The first electrode pad 410 and the second electrode pad 411 of each semiconductor element 40 are respectively connected to a corresponding first protrusion 501a and second protrusion 502a so that a plurality of light emitting diode elements 40 are connected in parallel to each other. on the carrier board 500. The first pad 503 and the second pad 504 are respectively electrically connected to the first wire 501 and the second wire 502 for electrically connecting to other components or an external power source. The carrier 500 is, for example, a package submount or a printed circuit board (PCB); the first wire 501, the second wire 502, the first pad 503, and the second pad 504 include a single layer or multilayer structure and includes at least one material selected from nickel (Ni), titanium (Ti), platinum (Pt), palladium (Pd), silver (Ag), gold (Au), aluminum (Al) and copper (Cu) composed of groups. The transparent protective structure 505 is composed of a transparent dielectric material, for example, an organic transparent dielectric material is selected from Su8, benzocyclobutene (BCB), perfluorocyclobutane (PFCB), silicone, epoxy Resin (Epoxy), acrylic resin (Acrylic Resin), cycloolefin polymer (COC), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), polycarbonate (PC), poly A group consisting of Polyetherimide and Fluorocarbon Polymer, or inorganic transparent dielectric materials including materials selected from aluminum oxide (Al2O3), silicon nitride (SiNx), oxide A group consisting of silicon (SiOx), titanium oxide (TiOx), and magnesium fluoride (MgFx).

10,20,40:半導體光元件 100:基板 102:第一半導體接觸層 102a:第一區 102b:第二區 102b1:第一子區 102b2:第二子區 103:主動結構 103a:第一載子阻擋層 103b:主動層 103b1:量子井層 103b2:阻障層 103c:第二載子阻擋層 104:第二半導體接觸層 105:第一電極 106:第二電極 107:處理區 108:高摻雜半導體接觸層 409:電性絶緣層 410:第一電極墊 411:第二電極墊 50:半導體發光組件 500:載板 501:第一導線 501a:第一凸出部 502:第二導線 502a:第二凸出部 503:第一焊墊 504:第二焊墊 505:透明保護結構 MK1:第一遮罩 MK2:第二遮罩10,20,40: Semiconductor optical components 100: Substrate 102: the first semiconductor contact layer 102a: District 1 102b: Second District 102b1: The first sub-area 102b2: Second sub-area 103:Active structure 103a: the first carrier blocking layer 103b: active layer 103b1: Quantum well layer 103b2: Barrier layer 103c: second carrier blocking layer 104: the second semiconductor contact layer 105: the first electrode 106: second electrode 107: Processing area 108: Highly doped semiconductor contact layer 409: electrical insulating layer 410: first electrode pad 411: second electrode pad 50:Semiconductor light emitting components 500: carrier board 501: First wire 501a: first protrusion 502: second wire 502a: second protrusion 503: The first welding pad 504: Second welding pad 505: transparent protective structure MK1: First Mask MK2: Second Mask

第1圖為示意圖,顯示符合本揭露之半導體元件之第一實施例。FIG. 1 is a schematic diagram showing a first embodiment of a semiconductor device according to the present disclosure.

第2圖為示意圖,顯示符合本揭露之半導體元件之第二實施例。FIG. 2 is a schematic diagram showing a second embodiment of a semiconductor device according to the present disclosure.

第3A-3F圖為示意圖,顯示符合本揭露之半導體元件之製造方法。3A-3F are schematic diagrams showing a method of manufacturing a semiconductor device according to the present disclosure.

第4圖為示意圖,顯示符合本揭露之半導體元件之第三實施例。FIG. 4 is a schematic diagram showing a third embodiment of a semiconductor device according to the present disclosure.

第5圖為示意圖,顯示符合本揭露之一半導體組件。FIG. 5 is a schematic diagram showing a semiconductor device consistent with the present disclosure.

10:半導體元件10: Semiconductor components

100:基板100: Substrate

102:第一半導體接觸層102: the first semiconductor contact layer

102a:第一區102a: District 1

102b:第二區102b: Second District

102b1:第一子區102b1: The first sub-area

102b2:第二子區102b2: Second sub-area

103:主動結構103:Active structure

103a:第一載子阻擋層103a: the first carrier blocking layer

103b:主動層103b: active layer

103b1:量子井層103b1: Quantum well layer

103b2:阻障層103b2: Barrier layer

103c:第二載子阻擋層103c: second carrier blocking layer

104:第二半導體接觸層104: the second semiconductor contact layer

105:第一電極105: the first electrode

106:第二電極106: second electrode

107:處理區107: Processing area

Claims (10)

一種半導體元件,包括:一基板;一第一半導體接觸層位於該基板上,包含一第一區、一第二區、及一摻雜質;一主動結構位於該第一區且不位於該第二區,其中,該第二區更包含一第一子區及一第二子區;以及一電極位於該第一子區;其中,該第一子區具有一凹陷部係低於該第二子區,且該凹陷部僅位於該第一半導體接觸層中。 A semiconductor element, comprising: a substrate; a first semiconductor contact layer located on the substrate, including a first region, a second region, and a dopant; an active structure located in the first region and not located in the first region Two regions, wherein the second region further includes a first subregion and a second subregion; and an electrode is located in the first subregion; wherein the first subregion has a recess that is lower than the second sub-region, and the recessed portion is only located in the first semiconductor contact layer. 如請求項1所述之半導體元件,其中,該主動結構包含一量子井層包含AlxGa1-xN,其中,0.05
Figure 109114437-A0305-02-0015-1
x
Figure 109114437-A0305-02-0015-2
0.5。
The semiconductor device as claimed in item 1, wherein the active structure comprises a quantum well layer comprising AlxGa1 - xN , wherein, 0.05
Figure 109114437-A0305-02-0015-1
x
Figure 109114437-A0305-02-0015-2
0.5.
如請求項1所述之半導體元件,其中,於該半導體元件之一剖面,該第一子區之一表面係低於該第二子區之一表面6~30nm。 The semiconductor device according to claim 1, wherein, in a cross section of the semiconductor device, a surface of the first sub-region is 6-30 nm lower than a surface of the second sub-region. 如請求項1所述之半導體元件,其中,該第二子區環繞該第一子區。 The semiconductor device as claimed in claim 1, wherein the second sub-region surrounds the first sub-region. 如請求項1所述之半導體元件,其中,於該半導體元件之一剖面,該第一子區具有一處理區自該第一子區之一表面向該基板延伸,其中,於該第一半導體接觸層內,該摻雜質於該處理區內之一摻雜濃度大於超出該處理區之一區域之一摻雜濃度。 The semiconductor element as claimed in claim 1, wherein, in a section of the semiconductor element, the first sub-region has a processing region extending from a surface of the first sub-region to the substrate, wherein, in the first semiconductor In the contact layer, a doping concentration of the dopant in the processing region is greater than a doping concentration in a region beyond the processing region. 如請求項1所述之半導體元件,其中,該第一半導體接觸層包含AlxGa1-xN,其中,0.3
Figure 109114437-A0305-02-0015-3
x
Figure 109114437-A0305-02-0015-4
0.7。
The semiconductor device as claimed in claim 1, wherein the first semiconductor contact layer comprises AlxGa1 - xN , wherein, 0.3
Figure 109114437-A0305-02-0015-3
x
Figure 109114437-A0305-02-0015-4
0.7.
如請求項1所述之半導體元件,更包含一高摻雜半導體接觸層形成於該第一半導體接觸層及該電極之間,其中,該高摻雜半導體接觸層不含有鋁或包含一鋁含量小於該第一半導體接觸層之一鋁含量。 The semiconductor device as claimed in claim 1, further comprising a highly doped semiconductor contact layer formed between the first semiconductor contact layer and the electrode, wherein the highly doped semiconductor contact layer does not contain aluminum or contains an aluminum content less than an aluminum content of the first semiconductor contact layer. 如請求項7所述之半導體元件,其中,該第一半導體接觸層與該高摻雜半導體接觸層包含相同之該摻雜質,該摻雜質在該高摻雜半導體接觸層之一摻雜濃度大於在該第一半導體接觸層之一摻雜濃度。 The semiconductor device according to claim 7, wherein the first semiconductor contact layer and the highly doped semiconductor contact layer contain the same dopant, and the dopant is doped in one of the highly doped semiconductor contact layers The concentration is greater than a doping concentration in the first semiconductor contact layer. 一種半導體元件之製造方法,包括:提供一基板;形成一半導體接觸層位於該基板上,其中,該第一半導體接觸層包含一第一區、一第二區、及一摻雜質;形成一主動結構於該第一半導體接觸層之該第一區及該第二區上;移除位於該第二區上之該主動結構以露出該第二區之該第一半導體接觸層,其中,該第二區更包含一第一子區及一第二子區;形成一遮罩於該主動結構及該第一半導體接觸層上,其中,該遮罩覆蓋該第二子區並且包含一開口露出該第一子區;處理該開口所露出之該第一子區以形成一處理區;以及形成一電極於該第一子區上,其中,該第一子區之一上表面低於未被處理的該第二子區之一上表面。 A method for manufacturing a semiconductor element, comprising: providing a substrate; forming a semiconductor contact layer on the substrate, wherein the first semiconductor contact layer includes a first region, a second region, and a dopant; forming a An active structure is on the first region and the second region of the first semiconductor contact layer; the active structure on the second region is removed to expose the first semiconductor contact layer of the second region, wherein the The second region further includes a first subregion and a second subregion; a mask is formed on the active structure and the first semiconductor contact layer, wherein the mask covers the second subregion and includes an opening to expose the the first sub-region; processing the first sub-region exposed by the opening to form a processing region; and forming an electrode on the first sub-region, wherein an upper surface of the first sub-region is lower than the untreated treating the upper surface of one of the second sub-regions. 如請求項9所述之製造方法,其中,處理該開口所露出之該第一子區的步驟包含以一矽氯烷電漿處理該第一子區。 The manufacturing method as claimed in claim 9, wherein the step of treating the first sub-region exposed by the opening comprises treating the first sub-region with a silane plasma.
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TW201316556A (en) * 2011-08-31 2013-04-16 Nichia Corp Semiconductor light emitting device including metal reflecting layer
US20130112988A1 (en) * 2008-09-09 2013-05-09 Kei Kaneko Semiconductor light emitting device and wafer
TW201929258A (en) * 2017-12-19 2019-07-16 晶元光電股份有限公司 Light-emitting element

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130112988A1 (en) * 2008-09-09 2013-05-09 Kei Kaneko Semiconductor light emitting device and wafer
TW201316556A (en) * 2011-08-31 2013-04-16 Nichia Corp Semiconductor light emitting device including metal reflecting layer
TW201929258A (en) * 2017-12-19 2019-07-16 晶元光電股份有限公司 Light-emitting element

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