TWI776027B - Collector member for cylinder plating apparatus and plating apparatus - Google Patents

Collector member for cylinder plating apparatus and plating apparatus Download PDF

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TWI776027B
TWI776027B TW108108570A TW108108570A TWI776027B TW I776027 B TWI776027 B TW I776027B TW 108108570 A TW108108570 A TW 108108570A TW 108108570 A TW108108570 A TW 108108570A TW I776027 B TWI776027 B TW I776027B
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cylinder
electroplating
current collecting
oil
collecting member
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TW201938847A (en
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千葉𨺓永
菅原申太郎
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日商新克股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/18Curved printing formes or printing cylinders
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/005Contacting devices
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/06Suspending or supporting devices for articles to be coated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • C25D17/12Shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/04Electroplating with moving electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/10Bearings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C13/00Rolls, drums, discs, or the like; Bearings or mountings therefor

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Sliding-Contact Bearings (AREA)

Abstract

本發明提供缸體電鍍裝置用集電構件以及電鍍裝置,是使用於夾頭錐的心軸的基端部因而可在滑動面上免注油進行電鍍處理,不發生異常放電,低電壓、高效率並且可以防止高溫發熱。 一種缸體電鍍裝置用集電構件,是安裝於以夾頭錐來把持缸體的兩端部,使前述缸體旋轉來進行電鍍的缸體電鍍裝置的前述夾頭錐的基端部,並使該基端部旋轉,該集電構件,具備:圓筒狀基材,是由金屬體所成;以及複數的潤滑區域,是由散佈設置於前述圓筒狀基材的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成。The present invention provides a collector member for a cylinder electroplating device and an electroplating device, which are used for the base end portion of the mandrel of the collet cone, so that the sliding surface can be electroplated without oil injection, abnormal discharge does not occur, low voltage, high efficiency And can prevent high temperature heating. A current collecting member for a cylinder electroplating device is attached to the base end of the collet cone of a cylinder electroplating device that holds both ends of a cylinder with a collet cone and rotates the cylinder to perform electroplating, and The base end portion is rotated, and the current collecting member includes: a cylindrical base material made of a metal body; and a plurality of lubricating regions impregnated with oil dispersed and provided on the sliding surface of the cylindrical base material Constructed of carbon or oil-impregnated carbon resin.

Description

缸體電鍍裝置用集電構件以及電鍍裝置Current collector member for cylinder electroplating device and electroplating device

本發明是有關於缸體電鍍裝置用集電構件以及使用其之電鍍裝置,尤其有關於特別適合使用在夾頭錐的心軸的基端部的缸體電鍍裝置用集電構件以及使用其之電鍍裝置。The present invention relates to a collector member for a cylinder electroplating device and an electroplating device using the same, and more particularly, to a collector member for a cylinder electroplating device which is particularly suitable for use at the base end portion of a mandrel of a collet taper and using the same Electroplating device.

以往,在以電鍍裝置來將缸體等的加工物進行電鍍處理時,已知有記載於專利文獻1的缸用電鍍裝置。另外,作為如記載於專利文獻1般的具備缸用電鍍裝置的全自動凹版製版用處理系統,則有記載於專利文獻2的全自動凹版製版用處理系統。Conventionally, when an electroplating apparatus is used to electroplate a processed object such as a cylinder block, an electroplating apparatus for a cylinder described in Patent Document 1 is known. In addition, as a processing system for fully automatic gravure plate making including a plating apparatus for a cylinder as described in Patent Document 1, there is a processing system for fully automatic gravure plate making described in Patent Document 2.

在記載於專利文獻1的缸用電鍍裝置中,在將電力供給於缸體,或從缸體側將電力供給於外部時,鐵等的金屬製的集電構件被使用於夾頭錐的基端部的旋轉部。該鐵的進行旋轉的集電構件和銅等的導電性金屬製的固定構件進行接觸,從連接於前述導電性金屬製固定構件的電線將電力供給於缸體,或從缸體側將電力供給於外部。In the electroplating apparatus for a cylinder described in Patent Document 1, when electric power is supplied to the cylinder block or power is supplied to the outside from the cylinder block side, a metal current collecting member such as iron is used for the base of the collet cone Rotary part of the end. The iron rotating current collecting member is in contact with a conductive metal fixing member such as copper, and electric power is supplied to the cylinder from an electric wire connected to the conductive metal fixing member, or power is supplied to the cylinder from the cylinder side. external.

然而,在上述之以往的金屬製的集電構件中,為了在旋轉時抑制滑動面的摩擦,所以必須將油(潤滑油)供給於集電構件。而且,因為藉由於將油供給於前述集電構件,容易引起異常放電,所以常有在油中發生異常放電的此類問題。However, in the above-described conventional metal current collecting member, in order to suppress friction on the sliding surfaces during rotation, it is necessary to supply oil (lubricating oil) to the current collecting member. Furthermore, since abnormal discharge is likely to be caused by supplying oil to the current collecting member, such a problem that abnormal discharge occurs in oil often occurs.

而且,當在前述集電構件的滑動面發生異常放電時,與進行放電加工的情況相同,被膜形成於前述滑動面,前述滑動面成為凸凹的狀態。而且,前述滑動面成為凸凹的狀態時供給於前述滑動面的油的量進一步增加,因此陷入進一步發生異常放電的惡性循環。Furthermore, when abnormal discharge occurs on the sliding surface of the current collecting member, a film is formed on the sliding surface, as in the case of performing electrical discharge machining, and the sliding surface is in a state of projections and depressions. Furthermore, when the sliding surface is in a convex and concave state, the amount of oil supplied to the sliding surface further increases, and thus a vicious cycle in which abnormal discharge occurs further occurs.

另外,尚有供給於前述滑動面的油飛散且油滴入電鍍裝置的電鍍槽,導致電鍍液劣化的問題。並且,更有油流入前述集電構件和其他構件之間,且因前述集電構件的滑動面的油使電流不易流動,必須9V等的比通常更高的電壓的問題。不但如此,也有發熱至120℃等的比通常更高的溫度的問題。另外,尚有使用石墨製的集電構件的情況下,因旋轉進行集電,造成磨耗而產生粉末的問題。 [先前技術文獻] [專利文獻]In addition, there is a problem that the oil supplied to the sliding surface scatters and the oil drips into the plating tank of the plating apparatus, resulting in deterioration of the plating solution. In addition, oil flows between the current collecting member and other members, and the oil on the sliding surface of the current collecting member makes it difficult for current to flow, requiring a higher voltage than usual, such as 9V. Not only that, but there is also a problem of generating heat to a higher temperature than usual, such as 120°C. In addition, when a graphite current collecting member is used, there is a problem that the current is collected due to rotation, and the powder is generated due to abrasion. [Prior Art Literature] [Patent Literature]

[專利文獻1]WO2015/151665 [Patent Document 1] WO2015/151665

[專利文獻2]WO2011/125926 [Patent Document 2] WO2011/125926

本發明是有鑑於上述以往技術的問題所發明,其目地在於提供:一種缸體電鍍裝置用集電構件以及電鍍裝置,是使用於夾頭錐的心軸的基端部因而可在滑動面上免注油進行電鍍處理,不發生異常放電,低電壓、高效率並且可以防止高溫發熱。 The present invention has been made in view of the above-mentioned problems of the prior art, and an object of the present invention is to provide a current collector member for a cylinder electroplating apparatus and an electroplating apparatus, which are used for the base end portion of the mandrel of the collet cone so that the sliding surface can be Electroplating without oil injection, no abnormal discharge occurs, low voltage, high efficiency, and can prevent high temperature heat generation.

為了解決上述問題,本發明的缸體電鍍裝置用集電構件,是安裝於以夾頭錐來把持缸體的兩端部使前述缸體旋轉來進行電鍍的缸體電鍍裝置的前述夾頭錐的基端部,並進行旋轉,該集電構件,具備:圓筒狀基材,是由金屬體所成;以及複數的潤滑區域,是由散佈設置於前述圓筒狀基材的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成。 In order to solve the above-mentioned problems, the current collecting member for a cylinder electroplating apparatus of the present invention is the collet cone attached to the cylinder electroplating apparatus that performs electroplating by holding both ends of the cylinder block with a collet cone and rotating the cylinder block. The base end portion of the current collecting member is rotated, and the current collecting member includes: a cylindrical base material made of a metal body; Oil-impregnated carbon or resin containing oil-impregnated carbon.

較佳為前述潤滑區域為圓形。 Preferably, the aforementioned lubricating region is circular.

本發明的缸體電鍍裝置,具備:電鍍槽;夾頭錐,是設置於前述電鍍槽,用來將缸體把持旋轉;集電構件,是安裝於前述夾頭錐的基端部並進行旋轉;導電性金屬製固定構件,是接觸於前述集電構件的滑動表面;以 及電線,是連接於前述導電性金屬製固定構件,前述集電構件,具有:圓筒狀基材,是由金屬體所成;以及複數的潤滑區域,是由散佈設置於前述圓筒狀基材的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成缸體電鍍裝置。 The cylinder electroplating apparatus of the present invention includes: a plating tank; a collet cone installed in the plating tank for holding and rotating the cylinder; and a current collector member attached to the base end of the collet cone and rotating ; The conductive metal fixing member is in contact with the sliding surface of the aforementioned current collecting member; to and an electric wire connected to the conductive metal fixing member, the current collecting member having: a cylindrical base material made of a metal body; and a plurality of lubricating regions provided on the cylindrical base The cylinder body plating device is composed of oil-impregnated carbon or resin containing oil-impregnated carbon on the sliding surface of the material.

較佳為前述潤滑區域為圓形。 Preferably, the aforementioned lubricating region is circular.

較佳為前述集電構件是作為前述夾頭錐的心軸的軸承。 Preferably, the current collecting member is a bearing serving as a mandrel of the collet cone.

本發明的全自動凹版製版用處理系統是具備前述缸體電鍍裝置的全自動凹版製版用處理系統。 The processing system for fully automatic gravure plate making of the present invention is a fully automatic gravure plate making processing system including the above-mentioned cylinder electroplating device.

依據本發明,可以提供缸體電鍍裝置用集電構件以及電鍍裝置,是使用於夾頭錐的心軸的基端部因而可在滑動面上免注油進行電鍍處理,不發生異常放電,低電壓、高效率並且可以防止高溫發熱,藉此達到莫大的效果。本發明的缸體電鍍裝置用集電構件,因為不須注油,所以不會發生因油所導致的問題,電壓相較於以往只須大約2/3的電壓即可,高效率,並且發熱也可以抑制在40℃左右。並且,本發明的缸體電鍍裝置,可以防止火花的發生,耐磨耗性、導電性以及耐久性優異。本發明特別適合使用於凹版製版用的電鍍裝置。 According to the present invention, it is possible to provide a collector member for a cylinder electroplating device and an electroplating device, which are used for the base end portion of the mandrel of the collet cone, so that the sliding surface can be electroplated without oil injection, abnormal discharge does not occur, and low voltage is possible. , High efficiency and can prevent high temperature heat generation, thereby achieving great results. The current collecting member for the cylinder electroplating device of the present invention does not need to be filled with oil, so there is no problem caused by oil, and the voltage only needs about 2/3 of the voltage compared with the conventional one, high efficiency, and low heat generation. It can be suppressed at around 40°C. Furthermore, the cylinder plating apparatus of the present invention can prevent the occurrence of sparks, and is excellent in wear resistance, electrical conductivity, and durability. The present invention is particularly suitable for use in an electroplating apparatus for gravure plate making.

以下依據添加圖式來說明本發明的實施方式,但圖示例是做示例性表示,只要不脫離本發明的技術思想當然可做各種變形。 The embodiments of the present invention will be described below based on the attached drawings, but the examples in the drawings are illustrative, and various modifications can of course be made without departing from the technical idea of the present invention.

在第1圖中,符號10是本發明的缸體電鍍裝置,符號12是本發明的缸體電鍍裝置用集電構件。 In Fig. 1, reference numeral 10 is a cylinder plating apparatus of the present invention, and reference numeral 12 is a current collecting member for a cylinder plating apparatus of the present invention.

本發明的缸體電鍍裝置用集電構件12,是安裝於以夾頭錐來把持缸體的兩端部使前述缸體旋轉來進行電鍍的缸體電鍍裝置10的前述夾頭錐的基端部,並進行旋轉,具備:圓筒狀基材14,是由金屬體所成;以及複數的潤滑區域16,是由散佈設置於前述圓筒狀基材14的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成。 The collector member 12 for a cylinder electroplating apparatus of the present invention is attached to the base end of the collet cone of the cylinder electroplating apparatus 10 that performs electroplating by holding both ends of the cylinder with a collet cone and rotating the cylinder to perform electroplating. The part is rotated and includes: a cylindrical base 14 made of a metal body; and a plurality of lubricating regions 16 made of oil-impregnated carbon or oil-containing oil dispersed on the sliding surface of the cylindrical base 14 Constructed of oil-impregnated carbon resin.

本發明的缸體電鍍裝置10是使用前述缸體電鍍裝置用集電構件12的電鍍裝置,該缸體電鍍裝置,具備:電鍍槽;夾頭錐,是設置於前述電鍍槽,用來將缸體把持旋轉;集電構件12,是安裝於前述夾頭錐的心軸30的基端部;導電性金屬製固定構件18,是接觸於前述集電構件12的滑動表面;以及電線20,是連接於前述導電性金屬製固定構件18,前述集電構件12,具有:圓筒狀基材14,是由金屬體所成;以及複數的潤滑區域16,是由散佈設置 於前述圓筒狀基材14的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成。 The cylinder electroplating apparatus 10 of the present invention is an electroplating apparatus using the current collecting member 12 for the cylinder electroplating apparatus. The cylinder electroplating apparatus includes an electroplating tank and a collet cone, which is provided in the electroplating tank and is used to attach the cylinder to the electroplating tank. The body is held and rotated; the collector member 12 is the base end portion of the mandrel 30 attached to the aforementioned collet cone; the conductive metal fixing member 18 is the sliding surface in contact with the aforementioned collector member 12; and the electric wire 20 is Connected to the conductive metal fixing member 18, the current collecting member 12 includes: a cylindrical base material 14 made of a metal body; and a plurality of lubricating regions 16 provided by scattering The sliding surface of the cylindrical substrate 14 is composed of oil-impregnated carbon or resin containing oil-impregnated carbon.

前述缸體電鍍裝置10是藉由使前述集電構件12,在接觸於作為通電金屬的前述導電性金屬製固定構件18的狀態下進行旋轉,以使電流流通於前述導電性金屬製固定構件18而進行集電。將缸體作為負電極側的話,電流可以從連接於前述導電性金屬製固定構件18的電線20流往缸體進行供電,而且將缸體作為正電極側的話,由於電流經由電線20流動所以可以將電力供給於外部連接機器。如此,以本發明的集電構件12,藉由將缸體側作為負電極或正電極,往缸體側的電力的供給以及從缸體側往外部連接機器的電力的供給皆能進行。 The cylinder electroplating apparatus 10 rotates the current collecting member 12 in contact with the conductive metal fixing member 18 which is a current-carrying metal, so that a current flows through the conductive metal fixing member 18 to collect electricity. When the cylinder is on the negative electrode side, current can flow from the wire 20 connected to the conductive metal fixing member 18 to the cylinder to supply power, and when the cylinder is on the positive electrode side, the current can flow through the wire 20. Power is supplied to externally connected equipment. In this way, with the current collecting member 12 of the present invention, by using the cylinder side as a negative electrode or a positive electrode, both power supply to the cylinder side and power supply from the cylinder side to externally connected equipment can be performed.

在本發明中,藉由將由油浸漬碳或含有油浸漬碳樹脂所構成的複數的潤滑區域16,散佈設置於集電構件12的圓筒狀基材14的滑動表面,可不在滑動面注油下進行電鍍處理,低電壓、高效率而且可以防止高溫發熱。 In the present invention, the sliding surface of the cylindrical base material 14 of the current collector member 12 is dispersed and provided with a plurality of lubricating regions 16 composed of oil-impregnated carbon or resin containing oil-impregnated carbon, so that the sliding surface does not need to be oiled. Electroplating treatment, low voltage, high efficiency and can prevent high temperature heat generation.

在第1圖,雖表示使用黃銅作為前述金屬體的例子,但前述圓筒狀基材14的材質只要是金屬則未特別限制,可列舉例如,鐵、銅、鋁以及這些的合金等。 Although FIG. 1 shows an example using brass as the metal body, the material of the cylindrical base 14 is not particularly limited as long as it is a metal, and examples thereof include iron, copper, aluminum, and alloys thereof.

前述潤滑區域16的形狀未特別限制,但如第1圖所示,較佳為圓形。另外,前述複數的潤滑區域16,也可以隨機設置於前述圓筒狀基材14的滑動表面,但較佳為複數的潤滑區域16均勻地形成於滑動表面。 The shape of the aforementioned lubricating region 16 is not particularly limited, but as shown in FIG. 1 , it is preferably circular. In addition, the plurality of lubricating regions 16 may be randomly provided on the sliding surface of the cylindrical base 14, but it is preferable that the plurality of lubricating regions 16 are formed uniformly on the sliding surface.

前述潤滑區域16的形成方法未特別限制,例如,也可以使用圓筒狀的金屬體作為前述圓筒狀基材14,將油浸漬碳或含有油浸漬碳樹脂被覆於該金屬體的既定的表面來設置潤滑區域16,另外,也可以使用網狀體的金屬體來作為前述圓筒狀基材14,並將油浸漬碳或含有油浸漬碳樹脂充填和被覆於該網狀體的金屬體的網目及表面來設置潤滑區域16。並且,也可以使用具有複數的孔或凹部的金屬體作為前述圓筒狀基材14,將油浸漬碳或含有油浸漬碳樹脂嵌入於該金屬體的孔或凹部來設置潤滑區域16。The method for forming the lubricating region 16 is not particularly limited. For example, a cylindrical metal body may be used as the cylindrical base material 14, and a predetermined surface of the metal body may be coated with oil-impregnated carbon or resin containing oil-impregnated carbon. The lubricating region 16 may be provided, and a metal body of a mesh body may be used as the cylindrical base 14, and oil-impregnated carbon or resin containing oil-impregnated carbon may be filled and coated on the metal body of the mesh body. Mesh and surface to provide lubricating area 16 . Further, a metal body having a plurality of holes or recesses may be used as the cylindrical base material 14, and oil-impregnated carbon or resin containing oil-impregnated carbon may be embedded in the holes or recesses of the metal body to provide the lubricating region 16.

以前述油浸漬碳而言,適合使用混入潤滑油等的油的碳粉。以前述含有油浸漬碳樹脂而言,適合使用含有碳粉的合成樹脂,該碳粉中混入潤滑油等的油。以前述碳粉而言,較佳為,例如碳粉末或石墨粉末,更佳為多孔狀的石墨粉末。 以前述合成樹脂而言未特別限制,可以使用公知的合成樹脂,例如,可列舉:氟素樹脂、聚醯胺樹脂、聚乙烯樹脂、聚縮醛樹脂、聚氨酯樹脂、酚醛樹脂、環氧樹脂、聚酯樹脂、聚酮樹脂等。前述油浸漬碳以及含有油浸漬碳樹脂也可以含有其他的添加劑。As the oil-impregnated carbon, carbon powder mixed with oil such as lubricating oil is suitably used. As the aforementioned oil-containing impregnated carbon resin, a synthetic resin containing carbon powder into which oil such as lubricating oil is mixed is suitably used. For the aforementioned carbon powder, for example, carbon powder or graphite powder is preferable, and porous graphite powder is more preferable. The aforementioned synthetic resin is not particularly limited, and known synthetic resins can be used, for example, fluorine resins, polyamide resins, polyethylene resins, polyacetal resins, polyurethane resins, phenolic resins, epoxy resins, Polyester resin, polyketone resin, etc. The aforementioned oil-impregnated carbon and oil-impregnated carbon-containing resin may contain other additives.

在第1圖,作為前述導電性金屬製固定構件18,雖表示銅製的固定構件,但前述導電性金屬製固定構件18的材質只要是導電性金屬則未特別限制,可列舉例如:鐵、銅、鋁以及這些的合金等。In FIG. 1, although the fixing member made of copper is shown as the conductive metal fixing member 18, the material of the conductive metal fixing member 18 is not particularly limited as long as it is a conductive metal, and examples thereof include iron and copper. , aluminum and alloys of these.

較佳為前述集電構件12是作為前述夾頭錐的心軸30的軸承。Preferably, the aforementioned current collecting member 12 is a bearing serving as the aforementioned mandrel 30 of the collet cone.

將本發明的缸體電鍍裝置10,例如,組合於專利文獻2的全自動凹版製版處理系統,從而成為本發明的全自動凹版製版處理系統。其中,尤其適合將本發明的電鍍裝置,合併於如專利文獻2所揭示般的不使用堆高式起重機僅使用非移動式的工業用機器人而將被製版輥陸續收授於製版處理單元來進行製版處理的類型的全自動凹版製版處理系統內。如專利文獻2所揭示般類型的全自動凹版製版用處理系統,是一種可以比以往更迅速進行凹版製版輥的製造,可以達成節省空間,此外夜間也能無人作業,並且,可以將製造線予以彈性自定,可以對應顧客的各種需求的高自由度的全自動凹版製版用處理系統。The cylinder electroplating apparatus 10 of the present invention is combined with, for example, the fully automatic gravure plate-making processing system of Patent Document 2, and becomes the fully automatic gravure plate-making processing system of the present invention. Among them, it is particularly suitable to incorporate the electroplating apparatus of the present invention as disclosed in Patent Document 2, without using a stacker crane and only using a non-mobile industrial robot, and the plate-making rolls are successively transferred to the plate-making processing unit to perform the process. The type of plate-making processing within the fully automatic gravure plate-making processing system. A fully automatic processing system for gravure plate making of the type disclosed in Patent Document 2 is a kind of gravure plate making roll that can be manufactured more quickly than before, can achieve space saving, can also be unmanned at night, and can Fully automatic gravure plate-making processing system with a high degree of freedom that can be customized with flexibility and can meet various needs of customers.

如此般,使用本發明的缸體電鍍裝置的話,在全自動凹版製版處理系統之電鍍裝置的製版處理時,可在滑動面無注油進行電鍍處理,不發生異常放電,另外,不會發生因油所導致的問題,相較於以往只須大約2/3的低電壓即可,高效率、而且發熱也可以抑制在40℃左右,可以防止高溫發熱。並且,本發明的缸體電鍍裝置,可以防止火花的發生,不發生火花痕跡,耐磨耗性優異,另外,集電構件以及導電性金屬製固定構件即使進行長時間電鍍仍可以維持良好的導電性,耐久性也優異。 [實施例]In this way, if the cylinder electroplating apparatus of the present invention is used, in the plate making process of the electroplating apparatus of the automatic gravure plate making processing system, the electroplating process can be performed on the sliding surface without oil injection, and abnormal discharge will not occur. The problem caused is that compared with the past, only about 2/3 of the low voltage is required, high efficiency, and the heat generation can be suppressed to about 40°C, which can prevent high temperature heat generation. In addition, the cylinder electroplating apparatus of the present invention can prevent the occurrence of sparks, prevent the occurrence of spark marks, and is excellent in wear resistance. In addition, the current collecting member and the conductive metal fixing member can maintain good electrical conductivity even after long-term electroplating. properties and durability. [Example]

以下舉實施例來進一步具體說明本發明,但這些實施例是示例性表示用,自然是不應做限定性解釋。The following examples are given to further illustrate the present invention, but these examples are for illustrative purposes and should not be interpreted as limiting.

(實施例1) 作為缸體電鍍裝置除了第1圖所示的構造以外,基本上使用與以往的缸體電鍍裝置相同的構造的裝置。在夾頭錐的心軸的基端部使用集電構件12。以集電構件12而言,使用OILES工業株式會社製的SPB-7590100。使用鉻酸濃度250g/L、硫酸濃度2.5g/L的鉻電鍍液,作為電鍍液。(Example 1) Except for the structure shown in FIG. 1, the cylinder electroplating apparatus basically used the same structure as the conventional cylinder electroplating apparatus. A collector member 12 is used at the base end portion of the mandrel of the collet cone. As the collector member 12, SPB-7590100 manufactured by Oiles Industry Co., Ltd. was used. A chromium plating solution with a chromic acid concentration of 250 g/L and a sulfuric acid concentration of 2.5 g/L was used as the plating solution.

使用圓周800mm、面長1250mm的鋁芯的圓筒型基材,作為被處理缸,將被處理缸的兩端卡緊來裝設於電鍍槽,使鉻電鍍液溢流,將被處理缸整個淹沒。將被處理缸的旋轉次數設為100rpm,且電鍍液溫度55℃、電流密度30A/dm2 (電流3000A)、電壓6V。以該條件進行10分鐘電鍍處理,取得表面不發生凸起和凹坑的厚度6μm的均勻的電鍍被膜。並且,集電構件的發熱也可以抑制在40℃左右。A cylindrical base material of aluminum core with a circumference of 800mm and a surface length of 1250mm is used as the cylinder to be treated. The two ends of the cylinder to be treated are clamped and installed in the electroplating tank, so that the chromium plating solution overflows, and the entire cylinder to be treated is installed. submerged. The number of rotations of the cylinder to be treated was 100 rpm, the temperature of the plating solution was 55° C., the current density was 30 A/dm 2 (current 3000 A), and the voltage was 6V. The electroplating treatment was carried out under these conditions for 10 minutes, and a uniform electroplating coating film having a thickness of 6 μm and no protrusions and pits on the surface was obtained. In addition, the heat generation of the current collecting member can also be suppressed to about 40°C.

<異常放電發生試驗> 以與實施例1相同的條件來重覆144次10分鐘電鍍處理(合計24小時)。在電鍍中所消費的鉻以及添加劑成分(奧野製藥工業株式會社製的CHRIO RX-R)是藉由自動補給裝置自動地進行補給。觀察有無異常放電的發生,但未確認有異常放電的發生。<Abnormal discharge occurrence test> The 10-minute electroplating treatment was repeated 144 times under the same conditions as in Example 1 (24 hours in total). Chromium and additive components (CHRIO RX-R, manufactured by Okuno Pharmaceutical Co., Ltd.) consumed in electroplating are automatically replenished by an automatic replenishment device. The occurrence of abnormal discharge was observed, but the occurrence of abnormal discharge was not confirmed.

<狀態確認試驗> 藉由與實施例1相同的條件,將集電構件12安裝於電鍍槽,連續地進行鉻電鍍,並針對試驗時的導電性金屬製固定構件18的溫度、試驗後的導電性金屬製固定構件18的磨耗、試驗前後之集電構件12和導電性金屬製固定構件18的導電性的變化,確認狀態。試驗條件是如以下所述。 試驗時間:22小時、使用的缸的隻數:57隻、流通於缸的電流值:3000A、電鍍電壓:7.0V-7.2V、缸旋轉次數:340rpm。 試驗時,未確認有火花的發生,導電性金屬製固定構件18的溫度是平均溫度:左43.5℃、右49.9℃,最高到達溫度:左51.0℃、右59.0℃,可以防止高溫發熱。另外,試驗後,無火花痕跡,也無導電性金屬製固定構件18的磨耗。並且,集電構件12和導電性金屬製固定構件18的導電性,在試驗前後無變化,取得極為良好的結果。<Condition confirmation test> Under the same conditions as in Example 1, the current collecting member 12 was mounted in a plating tank, and chrome plating was continuously performed to measure the temperature of the conductive metal fixing member 18 during the test and the conductive metal fixing member after the test. The wear of 18 and the change in conductivity of the current collecting member 12 and the conductive metal fixing member 18 before and after the test were checked to confirm the state. The test conditions were as described below. Test time: 22 hours, the number of cylinders used: 57, the current value flowing through the cylinder: 3000A, the plating voltage: 7.0V-7.2V, the number of cylinder rotations: 340rpm. During the test, the occurrence of sparks was not confirmed, and the temperature of the conductive metal fixing member 18 was average temperature: left 43.5°C, right 49.9°C, maximum reached temperature: left 51.0°C, right 59.0°C, which can prevent high temperature heat generation. In addition, after the test, there were no spark marks and no abrasion of the conductive metal fixing member 18 . In addition, the electrical conductivity of the current collecting member 12 and the conductive metal fixing member 18 did not change before and after the test, and very good results were obtained.

(實施例2) 使用第1圖所示的構造的裝置來作為電鍍裝置。在夾頭錐的心軸的基端部使用集電構件12。以集電構件12而言,使用OILES工業株式會社製的SPB-7590100。使用硫酸銅200g/L、硫酸100g/L、氯離子100mg/L的銅電鍍液,作為電鍍液。 使用圓周800mm、面長1250mm的鋁芯的圓筒型基材,作為被處理缸,將被處理缸的兩端卡緊來裝設於電鍍槽,使銅電鍍液溢流,將被處理缸整個淹沒。將被處理缸的旋轉次數設為250rpm,且電鍍液溫度45℃、電流密度30A/dm2 (電流3000A)、電壓6V。以該條件進行10分鐘電鍍處理,取得表面不發生凸起和凹坑的厚度60μm的均勻的電鍍被膜。並且,集電構件的發熱也可以抑制在40℃左右。(Example 2) An apparatus having the structure shown in FIG. 1 was used as a plating apparatus. A collector member 12 is used at the base end portion of the mandrel of the collet cone. As the collector member 12, SPB-7590100 manufactured by Oiles Industry Co., Ltd. was used. A copper electroplating solution containing 200 g/L of copper sulfate, 100 g/L of sulfuric acid, and 100 mg/L of chloride ions was used as the electroplating solution. A cylindrical base material of aluminum core with a circumference of 800mm and a surface length of 1250mm is used as the cylinder to be treated, and the two ends of the cylinder to be treated are clamped to be installed in the electroplating tank, so that the copper electroplating solution overflows, and the entire cylinder to be treated is installed. submerged. The number of rotations of the cylinder to be treated was 250 rpm, the temperature of the plating solution was 45° C., the current density was 30 A/dm 2 (current 3000 A), and the voltage was 6 V. The electroplating treatment was carried out under these conditions for 10 minutes, and a uniform electroplating coating film having a thickness of 60 μm was obtained with no projections and pits on the surface. In addition, the heat generation of the current collecting member can also be suppressed to about 40°C.

<異常放電發生試驗> 以與實施例2相同的條件來重覆144次10分鐘電鍍處理(合計24小時)。關於在電鍍中所消費的銅電鍍成分,是藉由自動補給裝置自動地進行補給。觀察有無異常放電的發生,但未確認有異常放電的發生。<Abnormal discharge occurrence test> The 10-minute electroplating treatment was repeated 144 times under the same conditions as in Example 2 (24 hours in total). The copper electroplating component consumed in electroplating is automatically replenished by an automatic replenishment device. The occurrence of abnormal discharge was observed, but the occurrence of abnormal discharge was not confirmed.

(比較例1) 使用第2圖所示的先前的電鍍裝置40作為電鍍裝置,除了將潤滑油供給於集電構件以外,與實施例1同樣地進行10分鐘電鍍處理。以往的前述電鍍裝置40,使用滑動表面為鐵製的集電構件來作為使用於夾頭錐的心軸的基端部集電構件32。 在比較例1中,潤滑油進入於進行旋轉的鐵製的集電構件32和導電性金屬製固定構件18之間且電流不易流動,以電壓6V無法取得充分的電鍍被膜,為了取得厚度6μm的均勻的電鍍被膜必須9V的高電壓,並且因為摩擦及電流的流動不易,使集電構件發熱至120℃。(Comparative Example 1) The conventional electroplating apparatus 40 shown in FIG. 2 was used as the electroplating apparatus, and the electroplating treatment was performed in the same manner as in Example 1 for 10 minutes, except that lubricating oil was supplied to the current collecting member. In the conventional electroplating apparatus 40 , a current collecting member whose sliding surface is made of iron is used as the base end portion current collecting member 32 used for the mandrel of the collet cone. In Comparative Example 1, lubricating oil entered between the rotating iron current collecting member 32 and the conductive metal fixing member 18, and the current did not flow easily, so that a sufficient plating film could not be obtained at a voltage of 6V. A high voltage of 9V is required for a uniform plating film, and the current collecting member is heated to 120° C. due to friction and the flow of current is not easy.

<異常放電發生試驗> 以與比較例1相同的條件來重覆144次10分鐘電鍍處理(合計24小時)。在電鍍中所消費的鉻以及添加劑成分(奧野製藥工業株式會社製的CHRIO RX-R)是藉由自動補給裝置自動地進行補給。觀察有無異常放電的發生,確認有數十次異常放電的發生。<Abnormal discharge occurrence test> The 10-minute electroplating treatment was repeated 144 times under the same conditions as in Comparative Example 1 (24 hours in total). Chromium and additive components (CHRIO RX-R, manufactured by Okuno Pharmaceutical Co., Ltd.) consumed in electroplating are automatically replenished by an automatic replenishment device. The occurrence of abnormal discharge was observed, and it was confirmed that dozens of abnormal discharges occurred.

<狀態確認試驗> 藉由與比較例1相同的條件,將滑動表面為鐵製的集電構件32安裝於電鍍槽,並將潤滑油供給於集電構件,連續地進行鉻電鍍,藉由與實施例1的狀態確認試驗相同的試驗條件,來確認狀態。 試驗時,因為發生火花,且在試驗途中集電構件32和導電性金屬製固定構件18為不通電,所以在途中將試驗中止。試驗時的導電性金屬製固定構件18的溫度是平均溫度:70℃左右,最高到達溫度:120℃以上,確認有高溫發熱。另外,試驗後,確認有無數的火花痕跡,導電性金屬製固定構件18以火花痕跡為起點磨耗嚴重。<Condition confirmation test> Under the same conditions as in Comparative Example 1, the current collecting member 32 whose sliding surface was made of iron was mounted in a plating tank, and lubricating oil was supplied to the current collecting member, and chromium plating was continuously performed, in the same state as in Example 1. Confirm the test with the same test conditions to confirm the status. During the test, since sparks occurred and the current collecting member 32 and the conductive metal fixing member 18 were not energized during the test, the test was stopped during the test. The temperature of the conductive metal fixing member 18 at the time of the test was an average temperature: about 70° C., a maximum temperature: 120° C. or higher, and high temperature heat generation was confirmed. In addition, after the test, it was confirmed that there were numerous spark marks, and the conductive metal fixing member 18 was severely worn from the spark marks as a starting point.

10‧‧‧缸體電鍍裝置 12‧‧‧缸體電鍍裝置用集電構件 14‧‧‧圓筒狀基材 16‧‧‧潤滑區域 18‧‧‧導電性金屬製固定構件 20‧‧‧電線 30‧‧‧夾頭錐的心軸 32‧‧‧鐵製的集電構件 40‧‧‧先前的電鍍裝置10‧‧‧Cylinder body electroplating device 12‧‧‧Current collector components for electroplating equipment of cylinder block 14‧‧‧Cylinder substrate 16‧‧‧Lubrication area 18‧‧‧Conductive metal fixing member 20‧‧‧Wire 30‧‧‧Spindle of collet cone 32‧‧‧Iron current collector 40‧‧‧Previous electroplating equipment

第1圖是表示本發明的缸體電鍍裝置的一個實施方式的示意圖。 FIG. 1 is a schematic diagram showing an embodiment of a cylinder plating apparatus of the present invention.

第2圖是表示以往的缸體電鍍裝置的示意圖。 FIG. 2 is a schematic diagram showing a conventional cylinder plating apparatus.

10‧‧‧缸體電鍍裝置 10‧‧‧Cylinder body electroplating device

12‧‧‧缸體電鍍裝置用集電構件 12‧‧‧Current collector components for electroplating equipment of cylinder block

14‧‧‧圓筒狀基材 14‧‧‧Cylinder substrate

16‧‧‧潤滑區域 16‧‧‧Lubrication area

18‧‧‧導電性金屬製固定構件 18‧‧‧Conductive metal fixing member

20‧‧‧電線 20‧‧‧Wire

30‧‧‧夾頭錐的心軸 30‧‧‧Spindle of collet cone

Claims (6)

一種缸體電鍍裝置用集電構件,是安裝於以夾頭錐來把持缸體的兩端部使前述缸體旋轉來進行電鍍的缸體電鍍裝置的前述夾頭錐的基端部,並進行旋轉,該集電構件,具備:圓筒狀基材,是由金屬體所成;以及複數的潤滑區域,是由散佈設置於前述圓筒狀基材的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成。 A collector member for a cylinder electroplating apparatus is attached to the base end portion of the collet cone of a cylinder electroplating apparatus in which a collet cone holds both ends of a cylinder block and rotates the cylinder block to perform electroplating, and performs electroplating. Rotating, the current collecting member includes: a cylindrical base material made of a metal body; and a plurality of lubricating regions made of oil-impregnated carbon or oil-impregnated dispersed and provided on the sliding surface of the cylindrical base material Made of carbon resin. 如申請專利範圍第1項所述的缸體電鍍裝置用集電構件,其中,前述潤滑區域為圓形。 The current collecting member for a cylinder electroplating apparatus according to claim 1, wherein the lubricating region has a circular shape. 一種缸體電鍍裝置,具備:電鍍槽;夾頭錐,是設置於前述電鍍槽,用來將缸體把持旋轉;集電構件,是安裝於前述夾頭錐的基端部並進行旋轉;導電性金屬製固定構件,是接觸於前述集電構件的滑動表面;以及電線,是連接於前述導電性金屬製固定構件,前述集電構件,具有:圓筒狀基材,是由金屬體所 成;以及複數的潤滑區域,是由散佈設置於前述圓筒狀基材的滑動表面的油浸漬碳或含有油浸漬碳樹脂所構成。 An electroplating device for a cylinder body, comprising: an electroplating tank; a collet cone, which is arranged in the above-mentioned electroplating tank, for holding and rotating the cylinder body; a current collecting member, which is installed on the base end of the collet cone and rotates; a conductive metal fixing member, which is in contact with the sliding surface of the current collecting member; and an electric wire, which is connected to the conductive metal fixing member, and the current collecting member has: a cylindrical base material formed by a metal body and the plurality of lubricating regions are composed of oil-impregnated carbon or resin containing oil-impregnated carbon dispersed on the sliding surface of the cylindrical base material. 如申請專利範圍第3項所述的缸體電鍍裝置,其中,前述潤滑區域為圓形。 The cylinder electroplating apparatus according to claim 3, wherein the lubricating region is circular. 如申請專利範圍第3項所述的缸體電鍍裝置,其中,前述集電構件是作為前述夾頭錐的心軸的軸承。 The cylinder electroplating apparatus according to claim 3, wherein the current collecting member is a bearing serving as a spindle of the collet cone. 一種全自動凹版製版用處理系統,具備申請專利範圍第3、4或5項所述的缸體電鍍裝置。A fully automatic gravure plate-making processing system is provided with the cylinder electroplating device described in item 3, 4 or 5 of the patent application scope.
TW108108570A 2018-03-16 2019-03-14 Collector member for cylinder plating apparatus and plating apparatus TWI776027B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050284750A1 (en) * 2002-12-27 2005-12-29 Matsushita Electric Industrial Co., Ltd. Current collector sheet and electrochemical device
TW201602421A (en) * 2014-03-31 2016-01-16 新克股份有限公司 Plating apparatus for cylinder and plating method for the same
CN105899823A (en) * 2014-01-21 2016-08-24 奥依列斯工业株式会社 Sliding bearing
TW201807260A (en) * 2016-06-14 2018-03-01 古河電氣工業股份有限公司 Electrolytic copper foil, lithium ion secondary cell negative electrode, lithium ion secondary cell, and printed wiring board

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4267476A (en) * 1979-06-25 1981-05-12 Westinghouse Electric Corp. Metal-solid lubricant brushes for high-current rotating electrical machinery
JPS6243459A (en) * 1985-08-20 1987-02-25 Youbea Le-Ron Kogyo Kk Electrically conductive sliding material composition
GB2192407B (en) * 1986-07-07 1990-12-19 Metal Box Plc Electro-coating apparatus and method
US5164059A (en) * 1991-03-11 1992-11-17 Newcor, Inc. Electroplating apparatus with improved current collector
JP2638375B2 (en) * 1992-02-20 1997-08-06 株式会社日立製作所 Continuous molten metal plating equipment and bearings for continuous molten metal plating equipment
JPH06313432A (en) * 1993-04-28 1994-11-08 Hitachi Ltd Sliding structure and continuous molten metal plating device using it
JPH08188860A (en) * 1995-01-10 1996-07-23 Hitachi Ltd Continuous hot-dip metal plating equipment
JP2000201455A (en) * 1999-01-06 2000-07-18 Hitachi Engineering & Services Co Ltd Earth brush unit of electric rotating machine
JP2003120673A (en) * 2001-10-10 2003-04-23 Ntn Corp Electric sintered bearing unit
US20060099443A1 (en) * 2003-01-16 2006-05-11 Kunio Nakashima Metal plating coating film having sliding function and article coated therewith
JP4369722B2 (en) * 2003-10-30 2009-11-25 株式会社シンク・ラボラトリー Method and apparatus for copper sulfate plating of plate roll
US7396448B2 (en) * 2004-09-29 2008-07-08 Think Laboratory Co., Ltd. Method for roll to be processed before forming cell and method for grinding roll
JP4794922B2 (en) * 2005-06-27 2011-10-19 Ntn株式会社 Hydrodynamic bearing device and motor having the same
JP2010106257A (en) * 2008-09-30 2010-05-13 Ntn Corp Conductive polyethylene resin composition, conductive polyethylene resin molding, sliding bearing, and sliding sheet
ES2651587T3 (en) 2010-04-06 2018-01-29 Think Laboratory Co., Ltd. Processing system to prepare a gravure plate completely automatically
CN102933751B (en) * 2010-10-01 2016-01-13 株式会社新克 Cylinder plating apparatus
WO2012055827A1 (en) * 2010-10-25 2012-05-03 Aktiebolaget Skf Dry lubricant containing fibers and method of using the same
US9199443B2 (en) * 2011-12-07 2015-12-01 Think Laboratory Co., Ltd. Single motor-driven gravure cylinder chuck mechanism
HRP20120309A2 (en) * 2012-04-10 2013-10-11 Radionica ĹľeljezniÄŤkih vozila ÄŚakovec d.o.o. Wagon for transport and controlled unloading of hydroscopic material
JP6114007B2 (en) * 2012-11-08 2017-04-12 Ntn株式会社 Roller bearing cage and rolling bearing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050284750A1 (en) * 2002-12-27 2005-12-29 Matsushita Electric Industrial Co., Ltd. Current collector sheet and electrochemical device
CN105899823A (en) * 2014-01-21 2016-08-24 奥依列斯工业株式会社 Sliding bearing
TW201602421A (en) * 2014-03-31 2016-01-16 新克股份有限公司 Plating apparatus for cylinder and plating method for the same
TW201807260A (en) * 2016-06-14 2018-03-01 古河電氣工業股份有限公司 Electrolytic copper foil, lithium ion secondary cell negative electrode, lithium ion secondary cell, and printed wiring board

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