[0014] 以下詳細說明本發明之實施形態，但以下記載之構成要件的說明係本發明實施態樣之一例(代表例)，本發明只要不變更其要旨，則不限定於以下內容。又，本說明書中使用「~」表現時，係作為包含其前後數值之表現使用。 [0015] 本發明有關化學發光體，其係藉由將第一組成物與第二組成物混合而發光之化學發光體，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑、觸媒及螢光物質之組成物。 藉由成為此等化學發光體，以於化學發光體內混合組成物而產生安定發光。更具體而言，彎折化學發光體，進行敲打等而破壞化學發光體用容器內之破壞性內側容器，於化學發光體用容器內混合化學發光體用組成物時，第一組成物中之草酸酯濃度高，可防止螢光物質之析出，故發光亮度高，可使發光時間長時間化。 [0016] 又，本發明有關化學發光系統，其係藉由使第一組成物與第二組成物混合而發光之化學發光系統，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑、觸媒及螢光物質之組成物。 作為此等化學發光系統，欲產生化學發光時，使第一組成物及第二組成物反應。此時，第一組成物中之草酸酯類濃度高，藉由於第二組成物中含有螢光物質，可防止於第一組成物中析出，故產生安定發光。 [0017] 本發明人等對變更螢光液(螢光組成物)之組成，於液中殘留螢光物質之固體，或將螢光組成物作成粉末狀，作為化學發光體予以混合時，產生不易混合之塊(所謂麵團狀)之原因進行檢討。其結果，發現螢光組成物中所含之螢光物質析出的影響較大。因此，檢討將該螢光物質混合於一般認為不安定而避免的氧化液側的組成物中。 [0018] 圖1係顯示本發明有關之代表化學發光體之構造的圖。本發明可設為圖1(a)所示之化學發光體10的實施形態。該實施形態係有關具有封入於破壞性內側容器3之第一組成物1與於內包破壞性內側容器3的化學發光體用容器4內而與第一組成物1分離封入之第二組成物2之化學發光體10。該化學發光體10於使用時，藉由於化學發光體用容器4內使破壞性內側容器3破壞，使第一組成物1與第二組成物2混合，進行化學發光。 [0019] 基於該圖1(a)所示之化學發光體10之態樣，作為第一組成物1，以粉末狀單獨封入草酸酯(CIPO)，作為第二組成物2，使用氧化液用溶劑(DMP及t-BuOH之混合溶劑)、過氧化氫、觸媒(SS)及螢光物質(Lumogen(註冊商標) F Red)之混合物而製造。彎折該化學發光體，使破壞性內側容器3破壞，藉由輕振，未見到螢光物質析出，且迅速混合產生安定發光。 [0020] 且，本發明可設為圖1(b)所示之化學發光體11之實施形態。該實施形態係有關具有封入於破壞性內側容器3之第二組成物2與於內包破壞性內側容器3的化學發光體用容器4內而與第二組成物2分離封入之第一組成物1之化學發光體11。該化學發光體11係將化學發光體10中之第一組成物與第二組成物變更內容之形態者。該化學發光體11與化學發光體10同樣，於使用時，藉由於化學發光體用容器4內使破壞性內側容器3破壞，使第一組成物1與第二組成物2混合，進行化學發光。 [0021] 又，本發明可設為圖2所示之化學發光系統之實施形態。該實施形態中，首先準備於圖2(a)不織布5中含浸第一組成物6者。此時，第一組成物可為實質上僅由草酸酯類所成之構成，或實質上僅由草酸酯類與溶劑等之構成，故成為無色且不易視認第一組成物如何配置之狀態(圖2(a)中以虛線表示之部分)。 此處，如圖2(b)所示，第二組成物7自容器71接觸於不織布5上。如此，藉由接觸，使含浸於不織布5之第一組成物6與第二組成物7反應，產生化學發光部100。如此，本發明之化學發光系統於非接觸(混合)狀態，以隱藏無色之第一組成物之如文字形態配置，使用時產生化學發光，可成為化學發光系統。 [0022] [第一組成物] 本發明所用之第一組成物係含有草酸酯類之組成物。若為此組成物，由於含有草酸酯類，故與詳情如後述之第二組成物混合時，產生化學發光。 [0023] 本發明所用之第一組成物含有有助於其化學發光之作為主要成分的草酸酯類。此處使用之草酸酯類可適當地使用可使含有其之第一組成物與第二組成物混合時開始化學發光者。作為具體之草酸酯類舉例為例如雙(2,4,5-三氯-6-碳丁氧基苯基)草酸酯、雙(2,4,5-三氯-6-碳戊氧基苯基)草酸酯等。 [0024] 本發明所用之第一組成物較好含有比通常螢光液更高濃度之草酸酯類。藉由作成此等構成，可進行化學發光時之發光特性改善。草酸酯類之濃度越高，基本上化學發光之發光特性更被改善。 [0025] 該第一組成物因以高濃度含有草酸酯類，而第一組成物成為固體狀或膏狀、漿料狀之組成物。又，以往之技術思想係於草酸酯類濃度低時，為含有大量其他溶劑之設計，作成螢光物質之析出不易發生之以往的螢光液組成者，係不考慮過氧化氫對螢光物質之影響而易於設計。 [0026] 由於草酸酯類濃度越高，越易改善發光特性，故第一組成物中之草酸酯類濃度較好為50質量%以上，更好為80質量%以上，又更好為90質量%以上。草酸酯類濃度為80質量%以上時，實質上其性狀可作為相當於草酸酯單獨者予以處理之方面亦優異。又，本發明中第一組成物可實質上為草酸酯類單獨，亦可作為包含草酸酯類單獨之情況之概念，表現為第一組成物。 [0027] 本發明所用之前述第一組成物較好為固體狀。本發明所用之第一組成物除草酸酯類以外，亦可採用作為後述之任意成分而添加者且常溫亦為固體狀者，將第一組成物全體作成如粉狀體或粒體之固體狀混合物。尤其，藉由設為粉狀體或粒體，於化學發光時，認為液狀之第二組成物容易侵入該粉狀體或粒體之間隙，而可提高混合性，使發光特性良好。 [0028] 且，該第一組成物一般大多封入於化學發光體內側之破壞性內側容器內。該破壞性內側容器由於根據化學發光體大小而成為極細徑，故第一組成物較好為易於封入其內般之流動性較高的粉狀體或粒體。 [0029] 本發明之第一組成物實質上亦可為草酸酯類單獨，但亦可混合其他成分。例如，於第二組成物側含有之較佳觸媒亦可含於第一組成物側。藉由於第一組成物側亦含有觸媒，而更安定地產生化學發光反應。且，亦可含有與第二組成物之混合性或析出的影響較少的螢光物質。例如蒽系螢光物質由於溶解性高不易產生析出，故亦可使用於第一組成物側。作為此等螢光物質，更具體而言，舉例有已某程度實用化之黃色螢光物質之1-氯-9,10-雙(苯基乙炔基)蒽(2-Et-BPEA)。且除此之外，亦可適當含有抗氧化劑或安定化劑、溶劑等。 [0030] 本發明所用之第一組成物可設為以如前述之草酸酯類為主之固體狀設計。另一方面，以漿料狀等設計時，亦可含有溶劑，作為溶劑一般係單獨或混合使用乙醯基檸檬酸三丁酯(ATBC)、苯甲酸苄酯(BeB)、二丙二醇二甲醚(DMM)等。 [0031] 另一方面，本發明所用之第一組成物較好減少於第一組成物之溶液中溶解性低的成分。作為此等成分之典型者，舉例為螢光物質，其中苝系螢光物質或萘醯亞胺系螢光物質等含於溶劑少流動性低之第一組成物中時不易產生析出，易使化學發光特性降低。因此，第一組成物中之苝系螢光物質及萘醯亞胺系螢光物質之含量較好為0.5質量%以下，更好為0.2質量%以下，又更好為0.1質量%以下。該等含量，特佳為不使用作為組成物之原料，而不含(0質量%)。 [0032] 以本發明之化學發光體所用之第一組成物為內容之破壞性內側容器係於化學發光體之化學發光用容器內，僅其破壞性內側容器優先破壞，於化學發光體用容器內，使經內含之第一組成物分散之容器。舉例為例如，玻璃或樹脂製之安瓿瓶狀者，或鋁製或PP製之袋狀者等之構成。 [0033] 本發明係化學發光體用破壞性容器，其係封入有第一組成物之化學發光體用破壞性容器，且其係用於藉由使封入於破壞性容器中之第一組成物與內包前述破壞性容器之化學發光體用容器內之與前述第一組成物分離封入之第二組成物混合而發光之化學發光體，前述第一組成物係含有50質量%以上草酸酯類之組成物。 [0034] 該化學發光體用破壞性容器可成為相當於含有前述第一組成物之破壞性內側容器之構成。該化學發光體用破壞性容器係用以藉由與第二組成物反應而以作為化學發光體之優異混合性混合之發揮優異發光特性。且，該化學發光體用破壞性容器由於係內包於作為化學發光體全體之化學發光體用容器，故大多為比較小且其徑亦為小徑之細長筒狀安瓿瓶。 [0035] 此等安瓿瓶中，亦有因封入其中之組成物之流動性而難以封入之情況，有難以對每次改變組成物之組成而進行之封入條件調整之情況。然而，本發明之安瓿瓶設計時，成為其內容物之第一組成物不含有支配性決定化學發光顏色之螢光物質，亦可做成可作為化學發光體而廣泛共通使用之標準化安瓿瓶。該安瓿瓶中，亦可含有對發光特性之顏色調整時之影響較少，且即使實質上為粉體或漿料狀，與氧化液之混合性亦不易降低之黃色螢光物質(例如1-氯-9,10-雙(苯基乙炔基)蒽(2-Et-BPEA))。 [0036] [第二組成物] 本發明所用之第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。作為此等第二組成物，可調製液狀組成物而使用，作為化學發光體使用時以與前述第一組成物之優異混合性混合產生安定之化學發光。其原因係藉由於第二組成物側含有螢光物質，而不易發生起因於固體或漿料狀等之第一組成物與氧化液之混合性或溶解性問題的問題。 [0037] 本發明所用之第二組成物含有過氧化氫。第二組成物係以氧化劑的過氧化氫為必須成分，且為了調整該過氧化氫濃度、提高與第一組成物之相溶性(混合性)，進而提高為了提高發光效率而添加之水楊酸鹽等之溶解度而含有溶劑。作為第二組成物中之過氧化氫濃度標準，為1~10質量%左右。 [0038] 本發明所用之第二組成物含有氧化液用溶劑。作為本發明之氧化液所含之溶劑之具體例較好包含使用檸檬酸酯類、苯二甲酸酯類、苯甲酸酯類、苯偏三酸酯類、己二酸酯類、癸二酸酯類、杜鵑花酸酯類、甘油酯類、內酯類、二醇類、烷基二醇醚類等之有機系溶劑的溶劑。該等溶劑中，基於安全性之觀點，較好使用引火點為60℃以上者作為主要溶劑，且作為全體之引火點為70℃以上。又，溶劑之選擇中，所謂主要溶劑係指以可達成引火點成為本發明之目的溫度之方式調整摻合量時，基於引火點高則摻合比例較多而設計時成為中心之溶劑。且，溶劑亦可為主要溶劑單獨的溶劑。第二組成物中之氧化液用溶劑之量成為第二組成物含有之過氧化氫或觸媒、螢光物質等之其他成分的其餘部分。 [0039] 本發明所用之第一組成物及第二組成物之至少一者中，較好含有觸媒。該觸媒較好含於使用溶劑之第二組成物中。另一方面，觸媒亦可僅含於第一組成物中。又，於兩組成物中含有時，如一部分前述而有助於更快速發光或安定發光。通常，期望含有少量(通常對於氧化液為0.1mmol/L至10mmol/L)之例如水楊酸鋰、水楊酸銨、水楊酸鈉、水楊酸四烷銨鹽等之水楊酸及其衍生物作為作為觸媒成分。 [0040] 本發明所用之第二組成物含有螢光物質。藉由使該螢光物質含於使用溶劑之第二組成物側，而不會發生提高第一組成物中之草酸酯濃度且如以往含有螢光物質時所發生之混合性問題。因此，第一組成物與第二組成物快速混合，可於化學發光體內安定獲得草酸酯、過氧化氫、觸媒、螢光物質之化學發光所必須之成分成為適當存在狀態的反應場所。藉此，獲得初期發光強度或發光時間提高之效果。第二組成物中之螢光物質濃度標準為0.01~5質量%左右，係根據顏色、強度、時間等之發光性能或混合性等而設定。其濃度基於溶解性(防止析出等)之觀點，使用複數螢光物質時，作為以其合計量之濃度標準，較好為上述範圍。前述螢光物質之濃度下限，為了提高發光時之發色性更好設為0.05質量%以上。前述螢光物質之濃度上限，即使過量混合螢光物質亦有發色性等飽和之情況，相對地提高有助於化學發光之成分濃度，且易發生螢光物質析出等，故更好為2質量%以下。 [0041] 作為螢光物質若於300~1200nm具有發光光譜且於氧化液溶劑中亦至少部分可溶之螢光化合物則未特別限制。作為該等螢光化合物，例示有蒽、取代蒽、苯并蒽、菲、取代菲、并四苯、取代并四苯、并五苯、取代并五苯、苝、取代苝、蒽酮紫(violanthrone)、取代蒽酮紫、萘醯亞胺、取代萘醯亞胺等之具有縮合環之共軛多環芳香族化合物。作為上述化合物之取代基，只要不妨礙發光反應則未特別限制，可例示苯基、低級烷基、氯基、溴基、氰基、烷氧基、苯基萘基等。該等中，於以草酸酯類為主成分之第一組成物中含有苝、取代苝等之苝系螢光物質、或萘醯亞胺、取代萘醯亞胺等之萘醯亞胺系螢光物質時，容易產生析出，亦成為發光特性不安定之原因。因此，本發明中，第二組成物中含有之螢光物質較好為苝系螢光物質及/或萘醯亞胺系螢光物質。該等苝系螢光物質及萘醯亞胺系螢光物質的螢光物質基於在第二組成物中長時間安定之觀點亦較佳。 [0042] 作為前述螢光物質之具體例者，例示有2-氯-9,10-雙(4-甲基乙炔基)蒽、9,10-雙(苯基乙炔基)蒽、1-甲氧基-9,10-雙(苯基乙炔基)蒽、1,5-二氯-9,10-雙(苯基乙炔基)蒽、1,8-二氯-9,10-雙(苯基乙炔基)蒽、單氯及二氯取代之9,10-雙(苯基乙炔基)蒽、5,12-雙(苯基乙炔基)四并苯、9,10-二苯基蒽、16,17-二己氧基蒽酮紫、2-甲基-9,10-雙(苯基乙炔基)蒽、9,10-雙(4-甲氧基苯基)-2-氯蒽、9,10-雙(4-乙氧基苯基)-2-氯蒽、5,12-雙(苯基乙炔基)五并苯、5,6,11,12-四苯基并五苯(紅螢烯(rubrene))、苝及該等之混合物。 [0043] 本發明之第二組成物中含有之螢光物質較好為苝系螢光物質。所謂苝系螢光物質為具有苝或取代苝之骨架之螢光物質。所謂苝係下述式(1)表示之構造，苝系螢光物質具有該構造作為骨架。此等苝系螢光物質尤其含於所謂氧化液之第二組成物中時，亦長時間安定且長期保存性亦優異。 [0044][0045] 該等苝系螢光物質中，特佳為苝二羧醯亞胺系螢光物質。作為該苝二羧醯亞胺系螢光物質之具體製品舉例有例如LUMOGEN RED(發出紅色之苝二羧醯亞胺系螢光劑，BASF公司，商品名)、LUMOGEN YELLOW(發出黃色之苝二羧醯亞胺系螢光劑，BASF公司，商品名)、LUMOGEN ORANGE(發出橙色之苝二羧醯亞胺系螢光劑，BASF公司，商品名)。 [0046] 本發明之第二組成物中含有之螢光物質較好為萘醯亞胺系螢光物質。作為萘醯亞胺系螢光物質使用之化合物係具有萘醯亞胺骨架之化合物，係使用可作為化學發光中之螢光物質使用者。萘醯亞胺骨架亦可具有取代基。萘醯亞胺骨架以下述式(2)表示。 [0047][0048] 上述式中之氮原子可與例如氫原子；可具有如氧原子、氮原子、硫原子之雜原子之烴基鍵結者。烴基與上述同義。作為具有萘醯亞胺骨架之化合物之市售品舉例為例如LUMOGEN F Violet 570(BASF公司製)。 [0049] 本發明所用之第二組成物中，在不損及本發明目的之範圍內亦可含有其他成分。例如為了使第二組成物中之過氧化氫等於保存時安定而可添加抗氧化劑。 [0050] 本發明可為含有過氧化氫、氧化液用溶劑、觸媒與螢光物質之組成物的氧化液，其係用於藉由使封入於破壞性內側容器中之第一組成物與內包前述破壞性內側容器之化學發光體用容器內之與前述第一組成物分離封入之第二組成物混合而發光之化學發光體的氧化液。該氧化液相當於前述本發明所用之第二組成物。 [0051] 該氧化液係被封入破壞性內側容器之外部等而利用。且藉由變更該氧化液之螢光物質，易改變作為化學發光體之顏色。且，如前述於破壞性內側容器所用之安瓿瓶為小徑而不易填充內容物，另一方面填充有該氧化液之化學發光體用容器以更廣徑設計，故易進行液的填充。再者，與該氧化液組合使用時，安瓿瓶側之設計亦可設為標準化且作為既定者而製造，僅藉由變更氧化液之螢光物質顏色即可效率良好地製造顯示任意發色之化學發光體。 [0052] 作為本發明所用之化學發光體用容器，可採用作為化學發光體使用之任意形狀。且，根據該化學發光體之用途，適當調整顏色、大小、發光強度・時間等與內包之破壞性內側容器等之組合。例如可作為釣具用之小型化學發光體或發光棒狀之演唱會光棒、或警示燈、緊急燈。又，亦可作為採用遮罩狀之容器而發光之會場用發光體，亦可作為星形或心型等之玩具形狀。 [0053] 本發明之化學發光系統係使第一組成物或第二組成物於任意場所接觸並反應者。因此，可設成第一組成物與第二組成物之化學發光用套組。又，本發明亦可為化學發光方法，其係藉由使第一組成物與第二組成物混合而發光之化學發光方法，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。 [0054] 如前述實施形態所示，例如亦可預先配置(含浸)一組成物後，另外接觸另一組成物，而發生其形狀或含浸狀態的文字、圖形等之發光。此由於本發明之化學發光系統有關之第一組成物中顯示著色之螢光物質含量極微量且可為實質上不含之構成，故將預先配置之組成物設為第一組成物時，第二組成物接觸前可為無色。且，由於使用時其為無色且配置有第一組成物之場所發光，故可如隱藏文字般加以利用。 [0055] 或，作為本發明之化學發光系統之一例，為典禮等之演出用，可預先於任意容器中容納一組成物，使用時自開口部等添加另一組成物而發光。此時，亦可以如相當於隱藏文字般之構成而發光，可以不同顏色設定各組成物而將該等混合，作為新的顏色予以發光者。 [0056] 又，此等化學發光系統中，亦可預先減低第一組成物之草酸酯類之濃度。具體而言，草酸酯類之濃度可設為3質量%以上。且，作為隱藏文字用，由於第一組成物中之螢光物質越無著色越佳，故而減低其含量，而較好設為0.1質量%以下，更好為0.05質量%以下。此時，螢光物質之含量下限係不使用作為原料而為0質量%。 [0057] 或者，考慮保存時分離之各組成物狀態，鑒於第二組成物的氧化液中之安定性，可於第二組成物中含有苝系螢光物質及/或萘醯亞胺系螢光物質，於第一組成物中預先含有其他先前例示之螢光物質。藉由該設計，對應於螢光物質種類，對第一組成物與第二組成物分別施以著色，於使用時亦可演出發出該等混合而成之顏色。 [實施例] [0058] 以下，藉由實施例更詳細說明本發明，但本發明只要不變更其要旨，則不限定於以下實施例。 [0059] [評價項目] [亮度] 使用“亮度計LS-100(Close Up Lens No.122)”(Konica Minolta)測定亮度。 [HPLC] 使用下述裝置進行HPLC試驗。 ・HPLC吸光檢測器：“SPD-10A vp”(島津製作所) ・HPLC送液單元：“LC-10AT” (島津製作所) ・管柱烘箱：“CTO-10A” (島津製作所) ・數據處理裝置：“Chromato Pack C-R6A” (島津製作所) [0060] [試驗用試藥等] DMP：鄰苯二甲酸二甲酯 t-BuOH：第三丁醇(tert-Butanol)(東京化成工業股份有限公司) ATBC：乙醯基檸檬酸三丁酯(東京化成工業股份有限公司) BeB：苯甲酸苄酯(東京化成工業股份有限公司) H2
O2
：過氧化氫(過氧化氫水(和光純藥工業)經脫水處理後使用) SS：水楊酸鈉(關東化學股份有限公司) CIPO：雙(2,4,5-三氯-6-異戊氧基羰基苯基)草酸酯(東京化成工業股份有限公司) CPPO：雙[2,4,5-三氯-6-(戊氧基羰基)苯基]草酸酯(東京化成工業股份有限公司) [0061] [實施例1] [0062] 為了明確出於成為第二組成物之氧化液中加入色素(螢光物質)之情況，與於成為第一組成物之粉末中加入色素(螢光物質)之情況的發光差異，而進行發光特性比較。 [0063] 螢光物質(a)：使用以下述式(3)表示之苝系螢光物質。又，後述之試驗方法中，各試驗中有助於發光亮度之成分的量係總量為相同，故各氧化液中與粉末中之螢光物質量調製為同量。 [0064][0065] [試驗方法1. 第一組成物(粉末)側含有螢光物質之實驗(粉末中)] (1)調製氧化液(組成概要：DMP 81.6質量%，t-BuOH 13.4質量%，H2
O2
5質量%，SS 0.04質量%)。 (2)量取CIPO 9.85g與螢光物質(a) 0.15g，使用研缽混合。 (3)於4mL之樣本管瓶內量入(1)之混合粉末0.14g。 (4)將(1)之氧化液0.43mL加入(3)之樣本管瓶中予以發光。 (5)以均質機(25M手攪拌機+215A型微均質機)攪拌10秒(於容器底面攪拌使粉末於氧化液中擴散)。 (6)以攪拌結束時為基準的0點(初始)，於每下述特定測定時間，自採樣瓶容器上部測定發光亮度。 測定時間：30秒、1分鐘、5分鐘、15分鐘 [0066] [試驗方法2. 第二組成物(氧化液)側含有螢光物質之實驗(氧化液中)] (1)調製氧化液(組成概要：DMP 81.6質量%，t-BuOH 13.4質量%，H2
O2
5質量%，SS 0.04質量%)。 (2)量取(1)之氧化液100g，於其中添加螢光物質0.5g (0.5質量%)，於常溫攪拌溶解。 (3)於4ml樣本管瓶中量取CIPO粉末0.14g。 (4)於(3)之樣本管瓶中添加(2)之已加入螢光物質之氧化液0.43ml使其發光。 (5)以均質機攪拌10秒(於容器底面攪拌使粉末於氧化液中擴散)。 (6)以攪拌結束時為基準的0點(初始)，於每下述特定測定時間，自採樣瓶容器上部測定發光亮度。 測定時間：30秒、1分鐘、5分鐘、15分鐘 [0067] 「實驗結果」亮度測定 圖3及表1中，分別顯示於粉末中與氧化液中分別含有螢光物質(a)時之發光亮度曲線、每時間之發光亮度。又，於各條件各進行2次試驗。 [0068][0069] 於粉末中(第一組成物)中含有螢光物質時，與於氧化液中(第二組成物)中含有螢光物質時，直至1分鐘後之初期發光產生差異，開始發光初期之亮度有差異。於粉末側添加螢光物質時，由於螢光物質之溶解性低而析出，故即使混合，於粉末與氧化液混合而成之液中亦立即不溶解分散，認為使初期發光變差。 [0070] [實施例2] 針對氧化液組成物中之螢光物質安定性進行試驗。 [0071] [螢光物質] [0072] [苝系螢光物質] ・“Lumogen F Red 305”：1,6,7,12-四苯氧基-N,N’-雙(2,6-二異丙基苯基)苝二碳醯亞胺 ・“Lumogen F Yellow 083”：4,10-二氰基-3,9-苝二羧酸二異丁酯 ・“Lumogen F Orange 240”：2,9-雙(2,6-二異丙基苯基)-1,2,3,8,9,10-六氫蒽并[2,1,9-def:6,5,10-d’e’f’]二異喹啉-1,3,8,10-四酮 [0073] [萘醯亞胺系螢光物質] ・“Lumogen F Violet 570” [0074] [蒽系螢光物質] [黃色色素] ・“1-ClBPEA”：1-氯-9,10-雙(苯基乙炔基)蒽 ・“1,8-dClBPEA”：1,8-二氯-9,10-雙(苯基乙炔基)蒽 [綠色色素] ・“2-EtBPEA”：2-乙基-9,10-雙(苯基乙炔基)蒽 [藍色色素] ・“2-ClBMPA”：2-氯-9,10-雙(4-甲氧基苯基)蒽 ・“DPA”：9,10-二苯基蒽 [0075] [并四苯系螢光物質] [橙色色素] ・“BPEN”：5,12-雙(苯基乙炔基)并四苯 ・“紅螢烯”：5,6,11,12-四苯基并四苯 [0076] [實驗操作] 1. 試驗試料之準備 (1)調製氧化液(組成概要：DMP 81.6質量%，t-BuOH 13.4質量%，H2
O2
5質量%，SS 0.04質量%)。 (2)量取前述(1)之氧化液100g，於其中添加螢光物質0.15g(0.15質量%)，於常溫攪拌溶解。 (3)將前述(2)之氧化液小分地分裝於旋蓋管中，於恆溫庫60℃中進行加速處理試驗。 (4)於恆溫庫60℃中進行加速處理試驗者，於1週後取出。 (5)針對加速處理試驗前與加速處理試驗後之試料，關於殘留螢光物質(色素)析出者，使用超音波洗淨機完全溶解後進行測定。 [0077] 2. HPLC測定 (1)藉以下條件，藉由HPLC測定之試驗評價於前述試驗試料之準備步驟中準備之氧化液中之螢光物質安定性。 測定條件： 稀釋操作：於試料10μL中添加4mL乙腈 檢測波長：254nm 移動相：乙腈100%，管柱烘箱：40℃ 流速：0.7mL/min，注入量：5μL，檢測時間：20分鐘 [0078] 3. 亮度測定 (1)於含草酸酯之組成物的空白液(溶質：CPPO，溶劑：ATBC、BeB) 2.0mL加入採樣瓶容器中。 (2)量取1.0mL之含各螢光物質之氧化液，添加於前述(1)，開始發光。 (3)以均質機攪拌10秒。 (4)攪拌結束時設為0秒，測定發光亮度。 [0079] [實驗結果] [實驗結果1. HPLC測定] 藉由前述實驗操作，進行HPLC試驗時之各螢光物質波峰之數據測定結果示於表2。表2(螢光物質波峰之數據(面積比))中，進行加速處理試驗之前者表示為「加速前」，進行加速處理試驗1週後者表示為「加速1週後」，進行加速處理試驗2週後者表示為「加速2週後」。又，「1週後之殘存量」、「2週後之殘存量」均係將加速前作為100%進行比較者。 [0080][0081] 作為HPLC試驗結果，於苝系、萘醯亞胺系螢光物質於加速處理試驗前後未見到太大劣化。於其他螢光物質，於BPEN、紅螢烯大幅劣化(HPLC試驗結果，由於未確認到明顯波峰，故於表中記載為「無」)，其他螢光物質之波峰值亦降低。 [0082] [實驗結果2. 發光亮度之測定結果] 使用含有各螢光物質之氧化液的亮度測定結果示於下表。又，以下表中，加速處理試驗之前表示為「加速前」，進行加速處理試驗1週後表示為「加速1w」(亮度測定溫度22℃)，進行加速處理試驗2週後表示為「加速2w」(亮度測定溫度23℃)。又，「加速1w後之亮度」係將加速前設為100%者。表中之發光亮度之數值單位為「cd/m2
」。 [0083] Lumogen F Red之試驗結果示於表3(1週)、表4(2週)。 [0084][0085][0086] Lumogen F Yellow 083之試驗結果示於表5(1週)、表6(2週)。 [0087][0088][0089] Lumogen F Orange 240之試驗結果示於表7(1週)、表8(2週)。 [0090][0091][0092] Lumogen F Violet 570之試驗結果示於表9(1週)、表10(2週)。 [0093][0094][0095] 1-ClBPEA之試驗結果示於表11(1週)、表12(2週)。 [0096][0097][0098] 1,8-dClBPEA之試驗結果示於表13(1週)、表14(2週)。 [0099][0100][0101] 2-EtBPEA之試驗結果示於表15(1週)、表16(2週)。 [0102][0103][0104] 2-ClBMPA之試驗結果示於表17(1週)、表18(2週)。 [0105][0106][0107] DPA之試驗結果示於表19(1週)、表20(2週)。 [0108][0109][0110] BPEN之試驗結果示於表21(1週)、表22(2週)。 [0111][0112][0113] 紅螢烯之試驗結果示於表23(1週)、表24(2週)。 [0114][0115][0116] 亮度測定之實驗結果，任一化學發光體，於加速試驗前之初期發光的發光亮度，並無產生析出問題等，而發光。另一方面，加速試驗後見到其安定性較差。 苝系及萘醯亞胺系螢光物質，於加速試驗前後，其發光亮度並未見到太大劣化。使用其他螢光物質之氧化液，與使用苝系及萘醯亞胺系螢光物質者比較時，見到劣化且發光亮度降低。尤其於1,8-dClBPEA、BPEN、紅螢烯，於發光時顏色變淡至以目視即可了解變化之程度。 [產業上之可利用性] [0117] 依據本發明，提供安定且發光亮度、發光時間優異之化學發光體及化學發光系統。例如該化學發光體可利用於如演唱會光棒等之會場用、釣具用之發光體、防災用簡易光、標誌燈、警示燈之各種用途而於產業上有用。Embodiments of the present invention will be described in detail below, but the description of the constituent elements described below is an example (representative example) of embodiments of the present invention, and the present invention is not limited to the following contents as long as its gist is not changed. In addition, when the expression "~" is used in this specification, it is used as the expression including the numerical value before and after it. The present invention relates to a chemiluminescent body, which is a chemiluminescent body that emits light by mixing the first composition with the second composition, the aforementioned first composition is the composition containing oxalate, the aforementioned second composition The composition contains hydrogen peroxide, solvent for oxidizing liquid, catalyst and fluorescent substance. By becoming these chemiluminescent bodies, the composition is mixed in the chemiluminescent body to generate stable light emission. More specifically, when the chemiluminescent body is folded, knocked, etc. to destroy the destructive inner container in the chemiluminescent body container, and the composition for the chemiluminescent body is mixed in the chemiluminescent body container, among the first composition The high concentration of oxalate can prevent the precipitation of fluorescent substances, so the luminous brightness is high, and the luminous time can be prolonged. Also, the present invention relates to a chemiluminescence system, which is a chemiluminescence system that emits light by mixing the first composition with the second composition, wherein the first composition contains the composition of oxalate, the first composition The second composition is a composition containing hydrogen peroxide, a solvent for an oxidizing solution, a catalyst and a fluorescent substance. As these chemiluminescence systems, when chemiluminescence is to be generated, the first composition and the second composition are reacted. At this time, the concentration of oxalate in the first composition is high, and since the second composition contains a fluorescent substance, precipitation in the first composition can be prevented, and stable light emission is generated. The inventors etc. are to change the composition of fluorescent liquid (fluorescent composition), the solid of fluorescent substance remains in the liquid, or the fluorescent composition is made into powder, when mixed as chemiluminescent body, produce The reasons for the lumps that are not easy to mix (so-called doughy) are reviewed. As a result, it was found that the precipitation of the fluorescent substance contained in the fluorescent composition has a great influence. Therefore, it is considered that the fluorescent substance is mixed with the composition on the oxidizing liquid side, which is generally considered to be unstable and avoided. [0018] FIG. 1 is a diagram showing the structure of a representative chemiluminescent body related to the present invention. The present invention can be set as an embodiment of the chemiluminescent body 10 shown in FIG. 1( a ). This embodiment relates to a second composition including a first composition 1 enclosed in a destructive inner container 3 and a chemiluminescent container 4 enclosed in a destructive inner container 3 and sealed separately from the first composition 1 2. The chemiluminescent body 10. When the chemiluminescent body 10 is used, the destructive inner container 3 is destroyed in the container 4 for the chemiluminescent body, and the first composition 1 and the second composition 2 are mixed to perform chemiluminescence. Based on the state of the chemiluminescent body 10 shown in this Fig. 1 (a), as the first composition 1, encapsulate oxalic acid ester (CIPO) in powder form separately, as the second composition 2, use oxidizing liquid It is produced with a mixture of a solvent (a mixed solvent of DMP and t-BuOH), hydrogen peroxide, a catalyst (SS) and a fluorescent substance (Lumogen (registered trademark) F Red). By bending the chemiluminescent body, the destructive inner container 3 was destroyed, and by light vibration, no fluorescent substance was seen to precipitate, and the chemiluminescent material was rapidly mixed to produce stable light emission. [0020] Moreover, the present invention can be set as an embodiment of the chemiluminescent body 11 shown in FIG. 1(b). This embodiment relates to a first composition including a second composition 2 enclosed in a destructive inner container 3 and a chemiluminescent container 4 enclosed in a destructive inner container 3 and sealed separately from the second composition 2 1. The chemiluminescent body 11. The chemiluminescent body 11 is a form in which the content of the first composition and the second composition of the chemiluminescent body 10 is changed. Similar to the chemiluminescent body 10, the chemiluminescent body 11 is in use by destroying the destructive inner container 3 in the chemiluminescent body container 4 to mix the first composition 1 and the second composition 2 to perform chemiluminescence . [0021] Also, the present invention can be set as an embodiment of the chemiluminescence system shown in FIG. 2 . In this embodiment, first, the nonwoven fabric 5 of FIG. 2( a ) is prepared by impregnating the first composition 6 . In this case, the first composition may consist of substantially only oxalates, or substantially consist only of oxalates and a solvent, so that it is colorless and it is difficult to see how the first composition is arranged ( The part indicated by the dotted line in Fig. 2(a)). Here, as shown in FIG. 2( b ), the second composition 7 is brought into contact with the nonwoven fabric 5 from the container 71 . In this way, the first composition 6 and the second composition 7 impregnated in the non-woven fabric 5 are reacted by the contact, thereby generating the chemiluminescent portion 100 . In this way, the chemiluminescence system of the present invention is in a non-contact (mixed) state, and is configured in the form of a text to hide the colorless first composition, and generates chemiluminescence when used, which can become a chemiluminescence system. [First composition] The first composition used in the present invention is a composition containing oxalate. Since this composition contains oxalates, chemiluminescence is generated when it is mixed with the second composition whose details will be described later. [0023] The first composition used in the present invention contains oxalates as main components that contribute to its chemiluminescence. The oxalate used here can be suitably used which can start chemiluminescence when the first composition and the second composition containing them are mixed. Examples of specific oxalates include, for example, bis(2,4,5-trichloro-6-carbon butoxyphenyl) oxalate, bis(2,4,5-trichloro-6-carbon pentyloxy) phenyl) oxalate, etc. [0024] The first composition used in the present invention preferably contains the oxalates of higher concentration than usual fluorescent liquids. By making such a structure, the luminescent characteristic at the time of chemiluminescence can be improved. The higher the concentration of oxalates, the more substantially the luminescence properties of chemiluminescence are improved. This first composition contains oxalic acid esters with high concentration, and the first composition becomes a solid or paste, slurry composition. In addition, the conventional technical idea is that when the concentration of oxalate is low, it is designed to contain a large amount of other solvents, and the composition of the conventional fluorescent liquid that the precipitation of the fluorescent substance is not easy to occur does not consider the effect of hydrogen peroxide on the fluorescent substance. easy to design. Because the higher the oxalate concentration is, the easier it is to improve the luminous properties, so the oxalate concentration in the first composition is preferably more than 50 mass %, more preferably more than 80 mass %, and more preferably 90 mass % %above. When the concentration of oxalates is 80% by mass or more, the properties are also excellent in that the properties can be handled as those corresponding to oxalates alone. In addition, in the present invention, the first composition may be substantially oxalate alone, or may be expressed as the first composition as a concept including the case of oxalate alone. The aforementioned first constituent used in the present invention is preferably solid. In addition to oxalate esters, the first composition used in the present invention can also be added as an optional component to be described later and is also solid at room temperature, and the entire first composition is made into a solid such as powder or granule mixture. In particular, by setting it as a powder or granular body, it is considered that the liquid second composition easily penetrates into the gaps of the powder or granular body during chemiluminescence, so that the mixing property can be improved, and the luminescence characteristics can be improved. [0028] And, the first composition is generally enclosed in the destructive inner container inside the chemiluminescent body. Since the destructive inner container has an extremely fine diameter according to the size of the chemiluminescent body, the first composition is preferably a powder or granular body with high fluidity so that it can be easily enclosed therein. [0029] The first composition of the present invention can also be oxalic acid esters alone, but can also be mixed with other components. For example, the preferable catalyst contained on the side of the second composition may be contained on the side of the first composition. Since the catalyst is also contained on the first composition side, the chemiluminescence reaction is more stably generated. In addition, a fluorescent substance having little influence on the miscibility or precipitation with the second composition may be contained. For example, the anthracene-based fluorescent substance has high solubility and is unlikely to cause precipitation, so it can also be used on the side of the first composition. As these fluorescent substances, more specifically, 1-chloro-9,10-bis(phenylethynyl)anthracene (2-Et-BPEA), which is a yellow fluorescent substance that has been practically used to some extent, is exemplified. In addition to this, an antioxidant, a stabilizer, a solvent, and the like may be appropriately contained. [0030] The first composition used in the present invention can be set as a solid design based on the aforementioned oxalates. On the other hand, when designing in the form of a slurry or the like, a solvent may be contained, and as a solvent, acetyl tributyl citrate (ATBC), benzyl benzoate (BeB), and dipropylene glycol dimethyl ether are generally used alone or in combination. (DMM) et al. [0031] On the other hand, the first composition used in the present invention is preferably reduced to a low solubility component in the solution of the first composition. Typical examples of these components are fluorescent substances. Among them, perylene-based fluorescent substances or naphthalimide-based fluorescent substances are not easily precipitated when they are contained in the first composition with less solvent and low fluidity, which is easy to cause Chemiluminescence properties are reduced. Therefore, the content of the perylene-based fluorescent substance and the naphthalimide-based fluorescent substance in the first composition is preferably 0.5 mass % or less, more preferably 0.2 mass % or less, and still more preferably 0.1 mass % or less. It is particularly preferable that these contents are not used (0 mass %) without using a raw material as a composition. Taking the first composition used for the chemiluminescent body of the present invention as the destructive inner container of the content is in the chemiluminescent container of the chemiluminescent body, only its destructive inner container is preferentially destroyed, in the chemiluminescent body container Inside, a container for dispersing the contained first composition. For example, the composition of the ampoule-shaped one made of glass or resin, or the pouch-shaped one made of aluminum or PP is exemplified. The present invention is a destructive container for a chemiluminescent body, which is a destructive container for a chemiluminescent body enclosed with a first composition, and it is used for the first composition enclosed in the destructive container by making A chemiluminescent body that emits light by mixing with a second composition separated and enclosed with the first composition in a container for chemiluminescent bodies containing the destructive container, wherein the first composition contains 50% by mass or more of oxalates composition. [0034] The destructive container for the chemiluminescent body can have a structure corresponding to the destructive inner container containing the first composition. The destructive container for a chemiluminescent body is used to exhibit excellent light-emitting properties by being mixed with the second composition with excellent mixing properties as a chemiluminescent body. In addition, since the destructive container for chemiluminescent body is contained in the container for chemiluminescent body which is the whole of the chemiluminescent body, many are relatively small and elongated cylindrical ampoules whose diameter is also small. In these ampoules, there is also a situation that it is difficult to seal due to the fluidity of the composition enclosed therein, and there is a situation that it is difficult to adjust the sealing conditions of each time the composition of the composition is changed. However, in the design of the ampoule of the present invention, the first composition that becomes the content does not contain the fluorescent substance that dominates the color of the chemiluminescence, and can also be made into a standardized ampoule that can be widely used as a chemiluminescent body. The ampoule can also contain a yellow fluorescent substance (such as 1- Chloro-9,10-bis(phenylethynyl)anthracene (2-Et-BPEA)). [Second composition] The second composition used in the present invention is a composition containing hydrogen peroxide, an oxidizing solution solvent and a fluorescent substance. As these second compositions, a liquid composition can be prepared and used, and when used as a chemiluminescent body, stable chemiluminescence can be produced by mixing with the above-mentioned first composition with excellent mixing properties. The reason for this is that since the second composition side contains a fluorescent substance, problems caused by the miscibility or solubility of the solid or slurry-like first composition and the oxidizing liquid are less likely to occur. The second composition used in the present invention contains hydrogen peroxide. The second composition has hydrogen peroxide as an oxidizing agent as an essential component, and in order to adjust the concentration of the hydrogen peroxide, improve the compatibility (mixability) with the first composition, and further increase the salicylic acid added to improve the luminous efficiency Solubility of salts etc. and containing solvent. As a standard of the hydrogen peroxide concentration in the second composition, it is about 1 to 10 mass %. The second constituent used in the present invention contains oxidizing solution solvent. Specific examples of the solvent contained in the oxidizing liquid of the present invention preferably include citric acid esters, phthalic acid esters, benzoic acid esters, trimellitic acid esters, adipic acid esters, and sebacate esters. It is a solvent for organic solvents such as azaleas, azaleas, glycerides, lactones, glycols, and alkyl glycol ethers. Among these solvents, from the viewpoint of safety, it is preferable to use those having a flash point of 60° C. or higher as the main solvent, and the flash point of the whole to be 70° C. or higher. In the selection of the solvent, the main solvent refers to a central solvent when the blending amount is adjusted so that the flash point can be achieved at the temperature which is the objective of the present invention, and the blend ratio is large when the flash point is high. In addition, the solvent may be the main solvent alone. The amount of the solvent for the oxidizing liquid in the second composition becomes the remainder of the hydrogen peroxide or other components such as catalysts and fluorescent substances contained in the second composition. In at least one of the first constituent used in the present invention and the second constituent, preferably a catalyst is contained. The catalyst is preferably contained in the second composition using a solvent. On the other hand, the catalyst may be contained only in the first composition. In addition, when contained in the two compositions, it contributes to more rapid light emission or stable light emission as described above. Generally, it is desirable to contain small amounts (usually 0.1 mmol/L to 10 mmol/L for the oxidizing solution) of salicylic acid such as lithium salicylate, ammonium salicylate, sodium salicylate, tetraalkylammonium salicylate, etc. and Its derivatives are used as catalyst components. The second composition used in the present invention contains fluorescent substance. By containing the fluorescent substance on the side of the second composition using the solvent, the problem of mixing that occurs when the oxalate concentration in the first composition is increased and the fluorescent substance is contained in the past does not occur. Therefore, the first composition and the second composition are quickly mixed, and the oxalate, hydrogen peroxide, catalyst, and fluorescent substance necessary for the chemiluminescence can be stably obtained in the chemiluminescent body. Thereby, the effect of improving the initial luminous intensity or the luminous time is obtained. The standard concentration of the fluorescent substance in the second composition is about 0.01 to 5 mass %, which is set according to the luminescence properties such as color, intensity, time, or mixing properties. From the viewpoint of solubility (prevention of precipitation, etc.), when a plurality of fluorescent substances are used, the concentration is preferably within the above-mentioned range as a concentration standard of the total amount thereof. The lower limit of the concentration of the fluorescent substance is preferably set to 0.05 mass % or more in order to improve the color-developing property during light emission. The upper limit of the concentration of the above-mentioned fluorescent substances, even if the fluorescent substances are mixed excessively, the color development will be saturated, and the concentration of the components that contribute to chemiluminescence is relatively increased, and the precipitation of the fluorescent substances is easy to occur, so it is more preferably 2. mass % or less. [0041] As a fluorescent substance, it is not particularly limited if it has an emission spectrum at 300-1200 nm and is also at least partially soluble in an oxidizing solution solvent. Examples of such fluorescent compounds include anthracene, substituted anthracene, benzanthracene, phenanthrene, substituted phenanthrene, tetracene, substituted tetracene, pentacene, substituted pentacene, perylene, substituted perylene, anthrone violet ( violanthrone), substituted anthrone violet, naphthalimide, substituted naphthalimide and other conjugated polycyclic aromatic compounds with condensed rings. The substituent of the above-mentioned compound is not particularly limited as long as it does not inhibit the light-emitting reaction, and examples thereof include a phenyl group, a lower alkyl group, a chloro group, a bromo group, a cyano group, an alkoxy group, and a phenylnaphthyl group. Among these, the first composition containing oxalates as the main component contains perylene-based fluorescent substances such as perylene and substituted perylene, or naphthimide-based fluorescent substances such as naphthimide and substituted naphthimide. In the case of light substances, precipitation is likely to occur, which also causes unstable light emission characteristics. Therefore, in the present invention, the fluorescent substance contained in the second composition is preferably a perylene-based fluorescent substance and/or a naphthalimide-based fluorescent substance. These perylene-based fluorescent substances and naphthalimide-based fluorescent substances are also preferable from the viewpoint of long-term stability in the second composition. As the specific example of aforementioned fluorescent substance, exemplify 2-chloro-9,10-bis(4-methylethynyl)anthracene, 9,10-bis(phenylethynyl)anthracene, 1-methylethynyl Oxy-9,10-bis(phenylethynyl)anthracene, 1,5-dichloro-9,10-bis(phenylethynyl)anthracene, 1,8-dichloro-9,10-bis(benzene ethynyl)anthracene, mono- and dichloro-substituted 9,10-bis(phenylethynyl)anthracene, 5,12-bis(phenylethynyl)tetraacene, 9,10-diphenylanthracene, 16,17-Dihexyloxyanthrone violet, 2-methyl-9,10-bis(phenylethynyl)anthracene, 9,10-bis(4-methoxyphenyl)-2-chloroanthracene, 9,10-bis(4-ethoxyphenyl)-2-chloroanthracene, 5,12-bis(phenylethynyl)pentacene, 5,6,11,12-tetraphenylpentacene ( rubrene), perylene and mixtures of these. [0043] The fluorescent substance contained in the second composition of the present invention is preferably a perylene-based fluorescent substance. The so-called perylene-based fluorescent substance is a fluorescent substance having a perylene or a skeleton substituted for perylene. The so-called perylene-based structure is represented by the following formula (1), and the perylene-based fluorescent substance has this structure as a skeleton. In particular, when these perylene-based fluorescent substances are contained in the second composition of the so-called oxidizing solution, they are stable for a long time and have excellent long-term storage properties. [0044] [0045] Among these perylene-based fluorescent substances, perylene dicarboxyimide-based fluorescent substances are particularly preferred. Examples of specific products of the perylene dicarboxyimide fluorescent substance include LUMOGEN RED (perylene dicarboxyimide fluorescent agent that emits red, BASF company, trade name), LUMOGEN YELLOW (perylene dicarboxylate that emits yellow). Carboxyimide-based fluorescent agent, BASF company, trade name), LUMOGEN ORANGE (perylene dicarboxyimide-based fluorescent agent that emits orange, BASF company, trade name). [0046] The fluorescent substance contained in the second composition of the present invention is preferably a naphthalimide-based fluorescent substance. The compound used as a naphthalimide-based fluorescent substance is a compound having a naphthalimide skeleton, which can be used as a fluorescent substance in chemiluminescence. The naphthimide skeleton may also have a substituent. The naphthalimide skeleton is represented by the following formula (2). [0047] [0048] The nitrogen atom in the above formula can be bonded with, for example, a hydrogen atom; a hydrocarbyl bond that can have a heteroatom such as an oxygen atom, a nitrogen atom, and a sulfur atom. Hydrocarbyl is synonymous with the above. As a commercial item of the compound which has a naphthimide skeleton, for example, LUMOGEN F Violet 570 (made by BASF Corporation) is mentioned, for example. In the second composition used in the present invention, other components can also be contained within the scope that does not impair the purpose of the present invention. For example, an antioxidant may be added in order to make the hydrogen peroxide in the second composition equal to the stability during storage. The present invention can be the oxidizing liquid containing the composition of hydrogen peroxide, oxidizing liquid solvent, catalyst and fluorescent substance, and it is used for by making the first composition enclosed in the destructive inner container and The oxidizing solution of the chemiluminescent body which is mixed with the second composition separated and sealed from the above-mentioned first composition in the container for chemiluminescent body enclosing the destructive inner container and emits light. The oxidizing solution corresponds to the second composition used in the present invention. [0051] This oxidizing liquid is used by being enclosed in the outside of the destructive inner container or the like. And by changing the fluorescent substance of the oxidizing solution, the color of the chemiluminescent body can be easily changed. Furthermore, as the ampoules used in the destructive inner container have a small diameter and are not easily filled with the contents, on the other hand, the container for chemiluminescent bodies filled with the oxidizing liquid is designed with a wider diameter, so liquid filling is easy. Furthermore, when used in combination with the oxidizing solution, the design of the ampoule side can be standardized and manufactured as a predetermined one, and it is possible to efficiently manufacture a product showing any color development simply by changing the color of the fluorescent substance in the oxidizing solution. Chemiluminescent. [0052] As the container for the chemiluminescent body used in the present invention, any shape used as the chemiluminescent body can be adopted. Furthermore, according to the application of the chemiluminescent substance, the combination of the color, size, luminous intensity, time, etc., and the destructive inner container etc. contained therein is appropriately adjusted. For example, it can be used as a small chemiluminescent body for fishing tackle or a concert light bar in the shape of a luminous stick, or as a warning light and an emergency light. In addition, it can be used as a luminous body for a venue that emits light by using a mask-shaped container, and can also be used as a toy shape such as a star shape or a heart shape. [0053] The chemiluminescence system of the present invention makes the first composition or the second composition contact and react in any place. Therefore, a chemiluminescence kit of the first composition and the second composition can be provided. In addition, the present invention may also be a chemiluminescence method, which is a chemiluminescence method for emitting light by mixing a first composition and a second composition, wherein the first composition is a composition containing oxalates, and the second composition The composition is a composition containing hydrogen peroxide, a solvent for an oxidizing solution and a fluorescent substance. [0054] As shown in the above-mentioned embodiment, for example, after pre-arranging (impregnating) one composition, it is also possible to contact another composition, so that the shape or the characters, figures, etc. of the impregnated state emit light. This is because the first composition related to the chemiluminescence system of the present invention contains a very small amount of fluorescent substance showing coloring and can be substantially free. Therefore, when the pre-configured composition is set as the first composition, the first composition The two components may be colorless before contact. In addition, since it is colorless in use and emits light at the place where the first composition is arranged, it can be used like a hidden character. Or, as an example of the chemiluminescence system of the present invention, for performances such as ceremonies, a composition can be accommodated in any container in advance, and another composition can be added from the opening and the like during use to emit light. In this case, it is possible to emit light with a structure equivalent to a hidden character, and each composition can be set in different colors, and these can be mixed to emit light as a new color. [0056] In addition, in these chemiluminescence systems, the concentration of the oxalates of the first composition can also be reduced in advance. Specifically, the concentration of oxalates can be set to 3 mass % or more. In addition, since the fluorescent substance in the first composition is preferably used for hidden characters, the less coloring it is, the less the content thereof is, and it is preferably 0.1 mass % or less, more preferably 0.05 mass % or less. In this case, the lower limit of the content of the fluorescent substance is 0 mass % without using it as a raw material. Or, considering the state of each composition separated during preservation, in view of the stability in the oxidizing solution of the second composition, the second composition may contain a perylene-based fluorescent substance and/or a naphthalimide-based fluorescent substance. As for the light substance, other previously exemplified fluorescent substances are contained in the first composition in advance. With this design, the first composition and the second composition are colored respectively according to the type of fluorescent material, and the mixed colors can also be displayed during use. [Examples] [0058] Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to the following examples as long as the gist of the present invention is not changed. [Evaluation Items] [Brightness] The brightness was measured using "Luminometer LS-100 (Close Up Lens No. 122)" (Konica Minolta). [HPLC] The HPLC test was carried out using the following apparatus.・HPLC absorbance detector: "SPD-10A vp" (Shimadzu Corporation) ・HPLC liquid delivery unit: "LC-10AT" (Shimadzu Corporation) ・Column oven: "CTO-10A" (Shimadzu Corporation) ・Data processing device: "Chromato Pack C-R6A" (Shimadzu Corporation) [0060] [Test reagents, etc.] DMP: dimethyl phthalate t-BuOH: tert-Butanol (Tokyo Chemical Industry Co., Ltd. ) ATBC: Acetyl tributyl citrate (Tokyo Chemical Industry Co., Ltd.) BeB: Benzyl benzoate (Tokyo Chemical Industry Co., Ltd.) H 2 O 2 : Hydrogen peroxide (hydrogen peroxide water (Wako Pure Chemical Industries, Ltd.) Industrial) used after dehydration treatment) SS: Sodium salicylate (Kanto Chemical Co., Ltd.) CIPO: Bis(2,4,5-trichloro-6-isopentyloxycarbonylphenyl)oxalate (Tokyo Chemical Co., Ltd.) Industrial Co., Ltd.) CPPO: bis[2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl]oxalate (Tokyo Chemical Industry Co., Ltd.) [0061] [Example 1] [0062] ] In order to clarify the difference in luminescence between the case where a dye (fluorescent substance) is added to the oxidizing liquid that becomes the second composition, and the case where a dye (fluorescent substance) is added to the powder that becomes the first composition, light emission is performed. Feature comparison. Fluorescent substance (a): A perylene-based fluorescent substance represented by the following formula (3) was used. In addition, in the test method described later, the amounts of the components contributing to the luminous brightness in each test are the same as the total amount, so the amounts of phosphors in each oxidizing solution and in the powder were adjusted to the same amount. [0064] [Test method 1. Experiment (in powder) containing fluorescent substance on the first composition (powder) side] (1) Preparation of oxidizing solution (outline of composition: DMP 81.6 mass %, t-BuOH 13.4 mass %, H 2 O 2 5 mass %, SS 0.04 mass %). (2) 9.85 g of CIPO and 0.15 g of the fluorescent substance (a) were measured and mixed using a mortar. (3) Measure 0.14 g of the mixed powder of (1) into a 4 mL sample vial. (4) Add 0.43 mL of the oxidizing solution of (1) into the sample vial of (3) to emit light. (5) Stir with a homogenizer (25M hand mixer + 215A type micro-homogenizer) for 10 seconds (stir on the bottom surface of the container to diffuse the powder in the oxidizing liquid). (6) The light emission luminance was measured from the upper part of the sampling bottle container at every specific measurement time described below at 0 point (initial time) based on the completion of stirring. Measurement time: 30 seconds, 1 minute, 5 minutes, 15 minutes Outline of composition: DMP 81.6 mass %, t-BuOH 13.4 mass %, H 2 O 2 5 mass %, SS 0.04 mass %). (2) 100 g of the oxidation solution of (1) was weighed, 0.5 g (0.5 mass %) of a fluorescent substance was added to it, and the solution was stirred and dissolved at room temperature. (3) Measure 0.14g of CIPO powder in a 4ml sample vial. (4) 0.43 ml of the oxidizing solution to which the fluorescent substance was added in (2) was added to the sample vial of (3) to make it emit light. (5) Stir with a homogenizer for 10 seconds (stir on the bottom surface of the container to diffuse the powder in the oxidizing liquid). (6) The light emission luminance was measured from the upper part of the sampling bottle container at every specific measurement time described below at 0 point (initial time) based on the completion of stirring. Measurement time: 30 seconds, 1 minute, 5 minutes, 15 minutes Brightness curve, luminous brightness per time. In addition, the test was performed twice under each condition. [0068] When the fluorescent substance is contained in the powder (the first composition), and when the fluorescent substance is contained in the oxidizing solution (the second composition), there is a difference in the initial light emission after 1 minute, and the initial light emission begins. The brightness is different. When a fluorescent substance is added to the powder side, since the fluorescent substance has low solubility and is precipitated, even if it is mixed, it is not dissolved and dispersed in the liquid obtained by mixing the powder and the oxidizing liquid, and it is considered that the initial light emission is deteriorated. [0070] [Example 2] The stability of the fluorescent substance in the oxidation solution composition was tested. [Fluorescent substance] [0072] [Perylene-based fluorescent substance] ・"Lumogen F Red 305": 1,6,7,12-tetraphenoxy-N,N'-bis(2,6- Diisopropylphenyl)perylenedicarbimide・"Lumogen F Yellow 083": 4,10-dicyano-3,9-perylenedicarboxylate diisobutyl ester・"Lumogen F Orange 240": 2 ,9-bis(2,6-diisopropylphenyl)-1,2,3,8,9,10-hexahydroanthra[2,1,9-def:6,5,10-d'e'f']Diisoquinoline-1,3,8,10-tetraketone [0073] [Naphthylimide-based fluorescent substance] ・“Lumogen F Violet 570” [0074] [Anthracene-based fluorescent substance] [Yellow pigment] ・"1-ClBPEA": 1-chloro-9,10-bis(phenylethynyl)anthracene ・"1,8-dClBPEA": 1,8-dichloro-9,10-bis(benzene phenylethynyl)anthracene [green pigment] ・"2-EtBPEA": 2-ethyl-9,10-bis(phenylethynyl)anthracene [blue pigment] ・"2-ClBMPA": 2-chloro-9 ,10-bis(4-methoxyphenyl)anthracene ・"DPA": 9,10-diphenylanthracene [0075] [tetracene-based fluorescent substance] [orange pigment] ・"BPEN": 5, 12-Bis(phenylethynyl)naphthacene・"rubrene": 5,6,11,12-tetraphenyltetracene [0076] [Experimental operation] 1. Preparation of test sample (1) Preparation Oxidation solution (outline of composition: DMP 81.6 mass %, t-BuOH 13.4 mass %, H 2 O 2 5 mass %, SS 0.04 mass %). (2) 100 g of the oxidizing liquid of the above-mentioned (1) was weighed, 0.15 g (0.15 mass %) of a fluorescent substance was added thereto, and the mixture was stirred and dissolved at room temperature. (3) The oxidizing solution of (2) above is divided into small parts into a screw cap tube, and the accelerated treatment test is carried out in a constant temperature chamber at 60°C. (4) Those who were subjected to the accelerated treatment test in a constant temperature chamber at 60°C were taken out after one week. (5) For the samples before the accelerated treatment test and after the accelerated treatment test, regarding the precipitation of the residual fluorescent substance (dye), it was measured after completely dissolving it using an ultrasonic cleaner. 2. HPLC measurement (1) By the following conditions, the stability of the fluorescent substance in the oxidation solution prepared in the preparation step of the aforementioned test sample is evaluated by the test of HPLC measurement. Measurement conditions: Dilution operation: Add 4 mL of acetonitrile to 10 μL of sample Detection wavelength: 254 nm Mobile phase: 100% acetonitrile, column oven: 40°C Flow rate: 0.7 mL/min, injection volume: 5 μL, detection time: 20 minutes [0078] 3. Brightness measurement (1) Add 2.0 mL of the blank solution containing the composition containing oxalate (solute: CPPO, solvent: ATBC, BeB) to the sampling bottle container. (2) 1.0 mL of the oxidation solution containing each fluorescent substance was weighed, added to the above (1), and light emission was started. (3) Stir with a homogenizer for 10 seconds. (4) At the end of stirring, it was set to 0 second, and the light emission luminance was measured. [Experimental results] [Experimental results 1. HPLC measurement] The data measurement results of the peaks of each fluorescent substance in the HPLC test are shown in Table 2 by the aforementioned experimental operation. In Table 2 (Data (area ratio) of the peaks of fluorescent substances), the former is referred to as "before acceleration" when the accelerated treatment test is performed, and the latter is referred to as "after 1 week of acceleration" after the accelerated treatment test is performed for 1 week, and the accelerated treatment test 2 is performed. The latter is expressed as "accelerated after 2 weeks". In addition, "remaining amount after 1 week" and "remaining amount after 2 weeks" are those before acceleration as 100% for comparison. [0080] [0081] As the result of the HPLC test, the perylene-based and naphthalimide-based fluorescent substances did not see much deterioration before and after the accelerated treatment test. As for other fluorescent substances, BPEN and rubrene were greatly deteriorated (as a result of HPLC test, since no obvious peak was observed, it was recorded as "none" in the table), and the peak value of other fluorescent substances also decreased. [Experimental results 2. Measurement results of luminous brightness] The measurement results of brightness using the oxidation solution containing each fluorescent substance are shown in the following table. In addition, in the following table, before the accelerated treatment test is shown as "before acceleration", after the accelerated treatment test is carried out for 1 week, it is shown as "accelerated 1w" (brightness measurement temperature 22°C), and after the accelerated treatment test is carried out for 2 weeks, it is shown as "accelerated 2w". ” (brightness measurement temperature 23°C). In addition, "brightness after acceleration for 1w" refers to what was set as 100% before acceleration. The numerical unit of luminous brightness in the table is "cd/m 2 ". The test results of Lumogen F Red are shown in Table 3 (1 week) and Table 4 (2 weeks). [0084] [0085] The test results of Lumogen F Yellow 083 are shown in Table 5 (1 week) and Table 6 (2 weeks). [0087] [0088] The test results of Lumogen F Orange 240 are shown in Table 7 (1 week), Table 8 (2 weeks). [0090] [0091] The test results of Lumogen F Violet 570 are shown in Table 9 (1 week), Table 10 (2 weeks). [0093] [0094] The test results of 1-ClBPEA are shown in Table 11 (1 week), Table 12 (2 weeks). [0096] [0097] The test results of 1,8-dClBPEA are shown in Table 13 (1 week), Table 14 (2 weeks). [0099] [0100] The test results of 2-EtBPEA are shown in Table 15 (1 week) and Table 16 (2 weeks). [0102] [0103] The test results of 2-ClBMPA are shown in Table 17 (1 week), Table 18 (2 weeks). [0105] [0106] The test results of DPA are shown in Table 19 (1 week) and Table 20 (2 weeks). [0108] [0109] The test results of BPEN are shown in Table 21 (1 week) and Table 22 (2 weeks). [0111] [0112] The test results of rubrene are shown in Table 23 (1 week), Table 24 (2 weeks). [0114] [0115] [0116] The experimental results of the brightness measurement, any chemiluminescent body, the luminescence brightness of the initial luminescence before the accelerated test, does not produce precipitation problems, etc., and emits light. On the other hand, the stability was seen to be poor after the accelerated test. For the perylene-based and naphthalimide-based fluorescent substances, the luminous brightness did not deteriorate much before and after the accelerated test. When the oxidation solution using other fluorescent substances was compared with those using perylene-based and naphthalimide-based fluorescent substances, deterioration was observed and the luminous brightness decreased. Especially in 1,8-dClBPEA, BPEN, and rubrene, the color fades when emitting light to the extent that the degree of change can be understood visually. [Industrial Applicability] [0117] According to the present invention, a chemiluminescent body and a chemiluminescent system that are stable, have excellent light emission brightness and light emission time are provided. For example, the chemiluminescent body is industrially useful for various uses such as a concert light bar, a light-emitting body for fishing tackle, a simple light for disaster prevention, a sign light, and a warning light.
