TWI748923B - Winding electrolytic capacitor package structure and winding anti-corrosive negative foil - Google Patents

Abstract

A winding electrolytic capacitor package structure and a winding anti-corrosive negative foil are provided. The winding electrolytic capacitor package structure includes a winding capacitor, a package structure, a first conductive pin and a second conductive pin. The winding capacitor includes a winding positive foil and a winding anti-corrosive negative foil. The winding capacitor is disposed in the package structure. The first conductive pin and the second conductive pin are electrically connected to the winding capacitor. The anti-corrosive negative foil includes a conductive substrate, two zinc-containing material layers that are respectively disposed on the two opposite surfaces of the conductive substrate, and two conductive compound layers that are respectively disposed on the two zinc-containing material layers. Therefore, an overall structural strength of the winding anti-corrosive negative foil can be increased by using of the zinc-containing material layer.

Description

Winding type electrolytic capacitor packaging structure and winding type anticorrosive negative electrode foil

The invention relates to a capacitor packaging structure and a winding type negative electrode foil, in particular to a winding type electrolytic capacitor packaging structure and a winding type anticorrosive negative electrode foil.

Capacitors have been widely used in basic components of consumer home appliances, computer motherboards, power supplies, communication products, and automobiles. Its main functions include filtering, bypassing, rectification, coupling, decoupling, phase inversion, etc. One of the indispensable components in electronic products. However, the negative electrode foil of the wound capacitor in the prior art is easily corroded by the electrolyte solution and reduces its original thickness, and when the thickness of the negative electrode foil is reduced, the overall structural strength of the negative electrode foil will also decrease.

The technical problem to be solved by the present invention is to provide a wound type electrolytic capacitor packaging structure and a wound type anticorrosive negative electrode foil for the disadvantages of the prior art.

In order to solve the above technical problems, one of the technical solutions adopted by the present invention is to provide a winding type electrolytic capacitor packaging structure, which includes: a winding type capacitor, a packaging structure, a first conductive pin and a second Conductive pins. The winding type capacitor includes a winding type positive electrode foil, a winding type anticorrosive negative electrode foil and two winding type insulating separator papers. One of the two winding type insulating separator papers is set on the winding type positive electrode. Between the foil and the coiled anticorrosive negative electrode foil, one of the coiled positive electrode foil and the coiled anticorrosive negative electrode foil is arranged between two coiled insulating separator papers. The wound capacitor is housed in the package structure. The first conductive pin includes a first buried portion housed inside the package structure and a first exposed portion exposed on the outside of the package structure. The first conductive pin electrically contacts the wound positive foil and One of the two coiled anti-corrosion negative foils. The second conductive pin includes a second buried portion housed in the package structure and a second exposed portion exposed on the outside of the package structure. The second conductive pin electrically contacts the wound positive foil and The other of the two coiled anti-corrosion negative foils. Wherein, the wound type anticorrosive negative electrode foil includes a conductive substrate, two zinc-containing material layers respectively arranged on two opposite surfaces of the conductive substrate, and two conductive compound layers respectively arranged on the two zinc-containing material layers.

In order to solve the above technical problem, another technical solution adopted by the present invention is to provide a winding type electrolytic capacitor packaging structure, which includes: a winding type capacitor, a packaging structure, a first conductive pin and a second Conductive pins. The wound capacitor includes a wound positive electrode foil and a wound anticorrosive negative electrode foil. The wound capacitor is housed in the package structure. The first conductive pin electrically contacts one of the coiled positive electrode foil and the coiled anticorrosive negative electrode foil. The second conductive pin electrically contacts the other one of the wound positive electrode foil and the wound anticorrosive negative electrode foil. Wherein, the wound type anticorrosive negative electrode foil includes a conductive substrate, two zinc-containing material layers respectively arranged on two opposite surfaces of the conductive substrate, and two conductive compound layers respectively arranged on the two zinc-containing material layers.

In order to solve the above technical problems, another technical solution adopted by the present invention is to provide a winding type electrolytic capacitor packaging structure, which includes: a winding type capacitor, a packaging structure, a first conductive pin, and a first conductive pin. Two conductive pins. The wound capacitor includes a wound positive electrode foil and a wound anticorrosive negative electrode foil. The wound capacitor is housed in the package structure. The first conductive pin electrically contacts one of the coiled positive electrode foil and the coiled anticorrosive negative electrode foil. The second conductive pin electrically contacts the other one of the wound positive electrode foil and the wound anticorrosive negative electrode foil. Wherein, the wound type anticorrosive negative electrode foil includes a conductive substrate, two zinc-containing material layers respectively arranged on two opposite surfaces of the conductive substrate, and two conductive compound layers respectively arranged on the two zinc-containing material layers.

In order to solve the above technical problems, another technical solution adopted by the present invention is to provide a wound-type anticorrosive negative electrode foil, which includes: a conductive substrate, two zinc-containing material layers, and two conductive compound layers. Two zinc-containing material layers are respectively arranged on two opposite surfaces of the conductive substrate to respectively contact the two opposite surfaces of the conductive substrate. The two conductive compound layers are respectively arranged on the two zinc-containing material layers to contact the two zinc-containing material layers respectively. Wherein, the conductive compound layer is at least one of a nitride layer, a carbide layer, a carbonitride layer, an oxynitride layer, and a carbon oxide layer. Wherein, the nitride layer is made of at least nitride (nitride), and the nitride is selected from silicon nitride (Si3N4), titanium nitride (TiN), aluminum nitride (AlN), titanium aluminum nitride (( Ti,Al)N), chromium nitride (CrN), molybdenum nitride (MoN), tungsten nitride (WN) and tantalum nitride (TaN); wherein the carbide layer at least consists of carbide ( carbide), and the carbide is selected from titanium carbide (TiC), aluminum carbide (AlC), chromium carbide (CrC), molybdenum carbide (MoC), tungsten carbide (WC) and tantalum carbide (TaC) Wherein, the carbonitride layer is made of at least carbon nitride (carbon nitride), and the carbonitride is selected from titanium carbonitride (TiC _x N _y ), aluminum carbonitride (AlC _x N _y ), chromium carbonitride (CrC _x N _y ), molybdenum carbonitride (MoC _x N _y ), tungsten carbonitride (WC _x N _y ), and tantalum carbonitride (TaC _x N _y ) Group; wherein the oxynitride layer is made of at least oxynitride, and the oxynitride is selected from titanium oxynitride (TiO _x N _y ), aluminum oxynitride (AlO _x N _y ), chromium oxynitride (CrO _x N _y ), molybdenum oxynitride (MoO _x N _y ), tungsten oxynitride (WO _x N _y ), and tantalum oxynitride (TaO _x N _y ); wherein the carbon oxide layer is at least oxidized by carbon It is made of carbon oxide, and the carbon oxide is selected from titanium oxycarbide (TiO _x C _y ), aluminum oxycarbide (AlO _x C _y ), chromium oxycarbide (CrO _x C _y ), molybdenum oxycarbide (MoO _x C _y ), tungsten oxycarbide (WO _x C _y ), and tantalum oxycarbide (TaO _x C _y ); wherein the zinc-containing material layer is a pure zinc material layer or a zinc alloy material layer , And the coiled anticorrosive negative electrode foil is an annealed negative electrode foil; wherein the structural strength of the zinc-containing material layer is greater than the structural strength of the conductive compound layer, and the structural strength of the conductive compound layer is greater than that of the conductive substrate; Wherein, the conductivity of the conductive substrate is greater than that of the zinc-containing material layer, and the conductivity of the zinc-containing material layer is greater than that of the conductive compound layer; wherein, the adhesion between the zinc-containing material layer and the conductive substrate and the The adhesion between the zinc material layer and the conductive compound layer is greater than the adhesion between the conductive material used for making the conductive substrate and the conductive material used for making the conductive compound layer.

One of the beneficial effects of the present invention is that the winding type electrolytic capacitor packaging structure and the winding type anti-corrosion negative foil provided by the present invention can pass through the "winding type anti-corrosion negative foil including a conductive base, The two zinc-containing material layers respectively arranged on the two opposite surfaces of the conductive substrate and the two conductive compound layers respectively arranged on the two zinc-containing material layers" technical solution, so that the wound type anticorrosive negative electrode foil The overall structural strength (or overall structural rigidity) can be improved through the use of zinc-containing material layers. It is worth noting that the conductive compound layer can be used to prevent the conductive substrate from being corroded by contact with the electrolyte solution, so the thickness of the conductive substrate can be protected by the conductive compound layer without changing.

In order to further understand the features and technical content of the present invention, please refer to the following detailed description and drawings about the present invention. However, the provided drawings are only for reference and description, and are not used to limit the present invention.

The following is a specific embodiment to illustrate the implementation of the “wound type electrolytic capacitor packaging structure and its wound type anti-corrosion negative electrode foil” disclosed in the present invention. Those skilled in the art can understand from the content disclosed in this specification. The advantages and effects of the present invention. The present invention can be implemented or applied through other different specific embodiments, and various details in this specification can also be based on different viewpoints and applications, and various modifications and changes can be made without departing from the concept of the present invention. In addition, the drawings of the present invention are merely schematic illustrations, and are not depicted in accordance with actual dimensions, and are stated in advance. The following embodiments will further describe the related technical content of the present invention in detail, but the disclosed content is not intended to limit the protection scope of the present invention. In addition, the term "or" used in this document may include any one or a combination of more of the associated listed items depending on the actual situation.

[First Embodiment]

As shown in FIGS. 1 to 5, the first embodiment of the present invention provides a winding type electrolytic capacitor packaging structure Z, which includes: a winding type capacitor 1, a packaging structure 2, a first conductive pin 3, and a The second conductive pin 4.

First, as shown in FIG. 1, the wound capacitor 1 includes a wound positive foil 11, a wound anticorrosive negative foil 12, and two wound insulating separator papers 13. Furthermore, one of the two wound-type insulating separator papers 13 is arranged between the wound-type positive electrode foil 11 and the wound-type anticorrosive negative electrode foil 12, and the wound-type positive electrode foil 11 One of the winding type anticorrosive negative electrode foil 12 and the winding type anticorrosive negative electrode foil 12 are arranged between the two winding type insulating separator papers 13. For example, as shown in FIG. 1, the wound positive foil 11 is arranged between two wound insulation papers 13. In addition, the wound insulating separator paper 13 may be a separator paper or a paper foil to which an electrolyte solution is adhered by an impregnation method. However, the present invention is not limited to the examples cited above.

Furthermore, as shown in FIG. 1 and FIG. 2, the wound capacitor 1 will be housed in the package structure 2. For example, the packaging structure 2 includes a shell structure 20 (such as an aluminum shell or other metal shell), but the present invention is not limited to this example. In addition, the first conductive pin 3 includes a first buried portion 31 housed inside the package structure 2 and a first exposed portion 32 exposed on the outside of the package structure 2, and the first conductive pin 3 is electrically connected. One of the wound type positive electrode foil 11 and the wound type anticorrosive negative electrode foil 12 is in sexual contact. In addition, the second conductive pin 4 includes a second buried portion 41 housed inside the package structure 2 and a second exposed portion 42 exposed on the outside of the package structure 2, and the second conductive pin 4 is electrically connected. The other one of the wound type positive electrode foil 11 and the wound type anticorrosive negative electrode foil 12 is in sexual contact.

In addition, as shown in FIGS. 3 to 5, the wound anticorrosive negative electrode foil 12 includes a conductive substrate 120, two zinc-containing material layers 121 and two conductive compound layers 122. Two zinc-containing material layers 121 are respectively disposed on two opposite surfaces of the conductive substrate 120 so as to contact the two opposite surfaces of the conductive substrate 120 respectively. The two conductive compound layers 122 are respectively disposed on the two zinc-containing material layers 121 to contact the two zinc-containing material layers 121 respectively. For example, the thickness of the wound type anticorrosive negative electrode foil 12 is less than or equal to 50 μm, and the thickness of the conductive compound layer 122 formed on the wound type anticorrosive negative electrode foil 12 may be between 10 nm and 2000 nm (Another preferred thickness range is between 10 nm and 500 nm). In addition, both surfaces of the conductive substrate 120 may be a roughened surface 12000 formed by mechanical processing (for example, rolling, embossing, etc.), and the roughness of the roughened surface 12000 may be less than or equal to 50 μm. Thereby, since the surface area of the conductive substrate 120 is increased through the formation of the roughened surface 12000, the adhesion strength of the zinc-containing material layer 121 to the conductive substrate 120 can also be improved, so the zinc-containing material layer 121 is not easily separated from the conductive substrate 120 , In order to effectively improve the reliability of the wound anticorrosive negative electrode foil 12 (that is, to improve the adhesion of the zinc-containing material layer 121 to the conductive substrate 120). However, the present invention is not limited to the examples cited above.

In addition, as shown in FIG. 4 or FIG. 5, the conductive substrate 120 may be an Al material, and the conductive substrate 120 has no oxide layer and no corrosion layer. That is to say, before the conductive substrate 120 is oxidized, the two zinc-containing material layers 121 may be separately disposed on the two roughened surfaces 12000 of the conductive substrate 120 in advance. For example, the zinc-containing material layer 121 may be a pure zinc material layer or a zinc alloy material layer. In addition, after the structural strength test is performed by a "structural strength testing machine" (or after the structural rigidity test is performed by a structural rigidity testing machine), the structural strength (or structural rigidity) of the zinc-containing material layer 121 will be greater than that of the conductive compound layer 122 The structural strength (or structural rigidity), and the structural strength (or structural rigidity) of the conductive compound layer 122 may be greater than the structural strength (or structural rigidity) of the conductive substrate 120. In addition, after conducting a conductivity test by a “conductivity tester”, the conductivity (conductivity) of the conductive substrate 120 will be greater than that of the zinc-containing material layer 121, and the conductivity of the zinc-containing material layer 121 will be greater than that of the conductive compound The conductivity of layer 122. Furthermore, after a "adhesion tester (such as a cross-cut adhesion tester)" is used for the adhesion test, the adhesion (adhesion degree) between the zinc-containing material layer 121 and the conductive substrate 120 ) And the adhesion between the zinc-containing material layer 121 and the conductive compound layer 122 will be greater than the "conductive material used to make the conductive base 120" and "the conductive material used to make the conductive compound layer 122" (That is, when the conductive substrate 120 and the conductive compound layer 122 are connected to each other, the adhesive force between the conductive substrate 120 and the conductive compound layer 122). Thereby, the overall structural strength (or overall structural rigidity) of the wound anticorrosive negative electrode foil 12 can be improved through the use of the zinc-containing material layer 121. It is worth noting that the coiled anticorrosive negative electrode foil 12 can be an annealed negative electrode foil or an unannealed negative electrode foil. However, the present invention is not limited to the examples cited above.

For example, the conductive compound layer 122 may be an electrolyte solution barrier layer with a thickness between 10 nm and 2000 nm to prevent the conductive substrate 120 (or the zinc-containing material layer 121) from being contacted by the electrolyte solution. It is corroded, so the thickness of the conductive substrate 120 (or the zinc-containing material layer 121) can be protected by the conductive compound layer 122 without changing. In other words, since the conductive substrate 120 (or the zinc-containing material layer 121) can pass through the protection of the conductive compound layer 122 without being corroded by the electrolyte solution and reduce the original thickness, the conductive compound layer 122 used in the present invention Even if the thickness is only 10 nm, the conductive substrate 120 can still pass through the protection of the conductive compound layer 122 without being corroded by the electrolyte solution and reduce the original thickness, so that the coiled anti-corrosion negative electrode foil 12 can still maintain The structural strength that meets the subsequent processing conditions. However, the present invention is not limited to the examples cited above.

For example, the conductive compound layer 122 may be at least one of a nitride layer, a carbide layer, a carbonitride layer, an oxynitride layer, and a oxycarbide layer. However, the present invention is not limited to the examples cited above.

Furthermore, when the conductive compound layer 122 is a nitride layer, the nitride layer is made of at least nitride, and the nitride may be selected from silicon nitride (Si3N4), titanium nitride (TiN ), aluminum nitride (AlN), titanium aluminum nitride ((Ti,Al)N), chromium nitride (CrN), molybdenum nitride (MoN), tungsten nitride (WN) and tantalum nitride (TaN) Groups formed. However, the present invention is not limited to the examples cited above.

Furthermore, when the conductive compound layer 122 is a carbide layer, the carbide layer is at least made of carbide, and the carbide can be selected from titanium carbide (TiC), aluminum carbide (AlC), A group consisting of chromium carbide (CrC), molybdenum carbide (MoC), tungsten carbide (WC), and tantalum carbide (TaC). However, the present invention is not limited to the examples cited above.

Furthermore, when the conductive compound layer 122 is a carbonitride layer, the carbonitride layer is made of at least carbon nitride, and the carbonitride can be selected from titanium carbonitride (TiC _x N _y ), aluminum carbonitride (AlC _x N _y ), chromium carbonitride (CrC _x N _y ), molybdenum carbonitride (MoC _x N _y ), tungsten carbonitride (WC _x N _y ) and carbon nitrogen A group of tantalum (TaC _x N _y ). However, the present invention is not limited to the examples cited above.

Furthermore, when the conductive compound layer 122 is an oxynitride layer, the oxynitride layer is made of at least oxynitride, and the oxynitride can be selected from titanium oxynitride (TiO _x N _y ), nitrogen oxide Aluminum oxide (AlO _x N _y ), chromium oxynitride (CrO _x N _y ), molybdenum oxynitride (MoO _x N _y ), tungsten oxynitride (WO _x N _y ) and tantalum oxynitride (TaO _x N _y ) 'S group. However, the present invention is not limited to the examples cited above.

Furthermore, when the conductive compound layer 122 is a carbon oxide layer, the carbon oxide layer is made of carbon oxide at least, and the carbon oxide can be selected from titanium carbon oxide (TiO _x C _y ), carbon aluminum oxide (AlO _x C _y ), chromium oxycarbide (CrO _x C _y ), molybdenum oxycarbide (MoO _x C _y ), tungsten oxycarbide (WO _x C _y ), and tantalum oxycarbide (TaO _x C _y ). However, the present invention is not limited to the examples cited above.

It is worth mentioning that the coiled anti-corrosion negative electrode foil 12 adopts the water resistance and resistance test method of Japan Electronics and Information Technology Industries Association (JEITA) standard EIAJ RC-2364A before and after the test, and the result is between 1~10% Between the "capacitance change rate" and the "withstand voltage change rate" between 0~5%.

[Second Embodiment]

As shown in FIGS. 1, 2 and 6 to 8, the second embodiment of the present invention provides a winding type electrolytic capacitor packaging structure Z, which includes: a winding type capacitor 1, a packaging structure 2, a first Conductive pin 3 and a second conductive pin 4. From the comparison between FIG. 7 and FIG. 4, and the comparison between FIG. 8 and FIG. 5, the biggest difference between the second embodiment of the present invention and the first embodiment is that: in the second embodiment, the conductive substrate 120 has an oxide layer 1200 and No corrosion layer. That is, after the conductive substrate 120 has been oxidized to form the oxide layer 1200, the two zinc-containing material layers 121 are then respectively disposed on the two roughened surfaces 12000 of the conductive substrate 120.

It is worth noting that whether it is "the conductive substrate 120 has no oxide layer and no corrosion layer (first embodiment)" or "the conductive substrate 120 has an oxide layer 1200 without corrosion layer (second embodiment)", the winding type The overall structural strength (or overall structural rigidity) of the corrosion-resistant negative electrode foil 12 can be improved through the use of the zinc-containing material layer 121. In addition, the conductive compound layer 122 can be used to prevent the conductive substrate 120 (or the zinc-containing material layer 121) from being corroded when contacted by the electrolyte solution, so the thickness of the conductive substrate 120 (or the zinc-containing material layer 121) can penetrate the conductive compound layer. 122 without changing the protection (that is, the conductive substrate 120 (or the zinc-containing material layer 121) can penetrate the protection of the conductive compound layer 122 without being corroded by the electrolyte solution and reduce the original thickness), so that The wound type anticorrosive negative electrode foil 12 can still maintain the structural strength that can meet the subsequent processing conditions.

[Beneficial effects of the embodiment]

One of the beneficial effects of the present invention is that the winding type electrolytic capacitor packaging structure Z and the winding type anti-corrosion negative electrode foil 12 provided by the present invention can be passed through "the winding type anti-corrosion negative electrode foil 12 includes a The technical solutions of the conductive substrate 120, the two zinc-containing material layers 121 respectively disposed on two opposite surfaces of the conductive substrate 120, and the two conductive compound layers 122" respectively disposed on the two zinc-containing material layers 121, so as to make the coil The overall structural strength (or overall structural rigidity) of the wound anticorrosive negative electrode foil 12 can be improved through the use of the zinc-containing material layer 121. It is worth noting that the conductive compound layer 122 can be used to prevent the conductive substrate 120 from being corroded 120 by being contacted by the electrolyte solution, so the thickness of the conductive substrate 120 can be protected by the conductive compound layer 122 without changing.

The content disclosed above is only a preferred and feasible embodiment of the present invention, and does not limit the scope of the patent application of the present invention. Therefore, all equivalent technical changes made using the description and schematic content of the present invention are included in the application of the present invention. Within the scope of the patent.

Z: Wound type electrolytic capacitor packaging structure 1: Wound capacitor 11: Wound positive foil 12: Coiled anti-corrosion negative electrode foil 120: conductive substrate 1200: oxide layer 12000: roughened surface 121: Zinc-containing material layer 122: conductive compound layer 13: Winding insulation paper 2: Package structure 20: Shell structure 3: The first conductive pin 31: The first buried part 32: The first naked part 4: The second conductive pin 41: The second buried part 42: The second naked part

FIG. 1 is a schematic diagram of a wound capacitor with a wound electrolytic capacitor packaging structure provided by the present invention.

FIG. 2 is a schematic diagram of the packaging structure of a wound electrolytic capacitor provided by the present invention.

FIG. 3 is a schematic diagram of the wound type anticorrosive negative electrode foil of the wound type electrolytic capacitor packaging structure provided by the first embodiment of the present invention.

Fig. 4 is an enlarged schematic diagram of part IV of Fig. 3.

Fig. 5 is an enlarged schematic diagram of part V of Fig. 3.

FIG. 6 is a schematic diagram of a wound type anticorrosive negative electrode foil of a wound type electrolytic capacitor packaging structure provided by a second embodiment of the present invention.

Fig. 7 is an enlarged schematic diagram of part VII of Fig. 6.

Fig. 8 is an enlarged schematic diagram of part VIII of Fig. 6.

120: conductive substrate

12000: roughened surface

121: Zinc-containing material layer

122: conductive compound layer

Claims (10)

A winding type electrolytic capacitor packaging structure, which includes: A wound-type capacitor, the wound-type capacitor includes a wound-type positive electrode foil, a wound-type anti-corrosion negative electrode foil, and two wound-type insulating separator papers One of them is provided between the wound positive electrode foil and the wound anticorrosive negative electrode foil, and the wound positive electrode foil and the wound anticorrosive negative electrode foil are both One of them is arranged between the two wound insulation papers; A packaging structure in which the winding capacitor is housed in the packaging structure; A first conductive pin, the first conductive pin includes a first buried portion housed in the package structure and a first exposed portion exposed on the outside of the package structure, the The first conductive pin electrically contacts one of the coiled positive electrode foil and the coiled anticorrosive negative electrode foil; and A second conductive pin, the second conductive pin includes a second buried portion housed in the package structure and a second exposed portion exposed on the outside of the package structure, the The second conductive pin electrically contacts the other one of the wound positive electrode foil and the wound anticorrosive negative electrode foil; Wherein, the wound type anticorrosive negative electrode foil includes a conductive substrate, two zinc-containing material layers respectively arranged on two opposite surfaces of the conductive substrate, and two zinc-containing material layers respectively arranged on the two zinc-containing material layers. Two conductive compound layers. The winding type electrolytic capacitor packaging structure as described in claim 1, Wherein, the thickness of the rolled anticorrosive negative electrode foil is less than or equal to 50 µm, the two surfaces of the conductive substrate are both roughened surfaces, and the roughness of the roughened surface is less than or equal to 50 µm; Wherein, the conductive substrate is made of Al material, and the conductive substrate has no oxide layer and no corrosion layer, or the conductive substrate has an oxide layer but no corrosion layer; Wherein, the conductive compound layer is an electrolyte solution barrier layer with a thickness between 10 nm and 2000 nm to prevent the conductive substrate from being corroded when contacted by the electrolyte solution. Therefore, the conductive substrate is The thickness will not change through the protection of the conductive compound layer; Wherein, the coiled anti-corrosion negative electrode foil uses the water resistance and resistance test method of the Japan Electronics and Information Technology Industries Association before and after the test to obtain a capacitance change between 1 and 10% and a capacitance change between 0 Withstand voltage change rate between ~5%; Wherein, the zinc-containing material layer is a pure zinc material layer or a zinc alloy material layer, and the wound anticorrosive negative electrode foil is an annealed negative electrode foil; Wherein, the structural strength of the zinc-containing material layer is greater than the structural strength of the conductive compound layer, and the structural strength of the conductive compound layer is greater than the structural strength of the conductive substrate; Wherein, the conductivity of the conductive substrate is greater than the conductivity of the zinc-containing material layer, and the conductivity of the zinc-containing material layer is greater than the conductivity of the conductive compound layer; Wherein, the adhesion between the zinc-containing material layer and the conductive substrate and the adhesion between the zinc-containing material layer and the conductive compound layer are both greater than those used for making the conductive substrate The adhesive force between the conductive material and the conductive material used to make the conductive compound layer. The winding type electrolytic capacitor packaging structure according to claim 1, wherein the conductive compound layer is a nitride layer, a carbide layer, a carbonitride layer, an oxynitride layer, and a carbon oxide layer At least one of; wherein, the nitride layer is made of at least nitride, and the nitride is selected from silicon nitride (Si3N4), titanium nitride (TiN), nitride A group consisting of aluminum (AlN), titanium aluminum nitride ((Ti,Al)N), chromium nitride (CrN), molybdenum nitride (MoN), tungsten nitride (WN), and tantalum nitride (TaN) ; Wherein, the carbide layer is made of at least carbide (carbide), and the carbide is selected from titanium carbide (TiC), aluminum carbide (AlC), chromium carbide (CrC), molybdenum carbide (MoC) ), tungsten carbide (WC), and tantalum carbide (TaC); wherein, the carbonitride layer is made of at least carbon nitride (carbon nitride), and the carbonitride is selected from Titanium carbonitride (TiC _x N _y ), aluminum carbonitride (AlC _x N _y ), chromium carbonitride (CrC _x N _y ), molybdenum carbonitride (Mo C _x N _y ), tungsten carbonitride ( WC _x N _y ) and tantalum carbonitride (TaC _x N _y ); wherein the oxynitride layer is made of at least oxynitride, and the oxynitride is selected from the group consisting of nitrogen Titanium oxide (TiO _x N _y ), aluminum oxynitride (AlO _x N _y ), chromium oxynitride (CrO _x N _y ), molybdenum oxynitride (MoO _x N _y ), tungsten oxynitride (WO _x N _y ), and nitrogen Tantalum oxide (TaO _x N _y ); wherein the carbon oxide layer is made of at least carbon oxide, and the carbon oxide is selected from the group consisting of titanium oxycarbide (TiO _x C _y ), carbon aluminum oxide (AlO _x C _y ), chromium oxycarbide (CrO _x C _y ), molybdenum oxycarbide (MoO _x C _y ), tungsten oxycarbide (WO _x C _y ), and tantalum oxycarbide (TaO _x C _y ). A winding type electrolytic capacitor packaging structure, which includes: A wound capacitor, the wound capacitor includes a wound positive foil and a wound anticorrosive negative foil; A packaging structure in which the winding capacitor is housed in the packaging structure; A first conductive pin, the first conductive pin electrically contacting one of the wound type positive electrode foil and the wound type anticorrosive negative electrode foil; and A second conductive pin, the second conductive pin electrically contacting the other one of the wound type positive electrode foil and the wound type anticorrosive negative electrode foil; Wherein, the wound type anticorrosive negative electrode foil includes a conductive substrate, two zinc-containing material layers respectively arranged on two opposite surfaces of the conductive substrate, and two zinc-containing material layers respectively arranged on the two zinc-containing material layers. Two conductive compound layers. The winding type electrolytic capacitor packaging structure as described in claim 4, Wherein, the thickness of the rolled anticorrosive negative electrode foil is less than or equal to 50 µm, the two surfaces of the conductive substrate are both roughened surfaces, and the roughness of the roughened surface is less than or equal to 50 µm; Wherein, the conductive substrate is made of Al material, and the conductive substrate has no oxide layer and no corrosion layer, or the conductive substrate has an oxide layer but no corrosion layer; Wherein, the conductive compound layer is an electrolyte solution barrier layer with a thickness between 10 nm and 2000 nm to prevent the conductive substrate from being corroded when contacted by the electrolyte solution. Therefore, the conductive substrate is The thickness will not change through the protection of the conductive compound layer; Wherein, the coiled anti-corrosion negative electrode foil uses the water resistance and resistance test method of the Japan Electronics and Information Technology Industries Association before and after the test to obtain a capacitance change between 1 and 10% and a capacitance change between 0 Withstand voltage change rate between ~5%; Wherein, the zinc-containing material layer is a pure zinc material layer or a zinc alloy material layer, and the wound anticorrosive negative electrode foil is an annealed negative electrode foil; Wherein, the structural strength of the zinc-containing material layer is greater than the structural strength of the conductive compound layer, and the structural strength of the conductive compound layer is greater than the structural strength of the conductive substrate; Wherein, the conductivity of the conductive substrate is greater than the conductivity of the zinc-containing material layer, and the conductivity of the zinc-containing material layer is greater than the conductivity of the conductive compound layer; Wherein, the adhesion between the zinc-containing material layer and the conductive substrate and the adhesion between the zinc-containing material layer and the conductive compound layer are both greater than those used for making the conductive substrate The adhesive force between the conductive material and the conductive material used to make the conductive compound layer. The winding type electrolytic capacitor packaging structure according to claim 4, wherein the conductive compound layer is a nitride layer, a carbide layer, a carbonitride layer, an oxynitride layer, and a carbon oxide layer At least one of; wherein, the nitride layer is made of at least nitride, and the nitride is selected from silicon nitride (Si3N4), titanium nitride (TiN), nitride A group consisting of aluminum (AlN), titanium aluminum nitride ((Ti,Al)N), chromium nitride (CrN), molybdenum nitride (MoN), tungsten nitride (WN), and tantalum nitride (TaN) ; Wherein, the carbide layer is made of at least carbide (carbide), and the carbide is selected from titanium carbide (TiC), aluminum carbide (AlC), chromium carbide (CrC), molybdenum carbide (MoC) ), tungsten carbide (WC), and tantalum carbide (TaC); wherein, the carbonitride layer is made of at least carbon nitride (carbon nitride), and the carbonitride is selected from Titanium carbonitride (TiC _x N _y ), aluminum carbonitride (AlC _x N _y ), chromium carbonitride (CrC _x N _y ), molybdenum carbonitride (MoC _x N _y ), tungsten carbonitride (WC _x N _y ) and tantalum carbonitride (TaC _x N _y ); wherein the oxynitride layer is made of at least oxynitride, and the oxynitride is selected from the group consisting of oxynitride Titanium (TiO _x N _y ), aluminum oxynitride (AlO _x N _y ), chromium oxynitride (CrO _x N _y ), molybdenum oxynitride (MoO _x N _y ), tungsten oxynitride (WO _x N _y ), and oxynitride Tantalum (TaO _x N _y ); wherein the carbon oxide layer is made of at least carbon oxide, and the carbon oxide is selected from the group consisting of titanium carbon oxide (TiO _x C _y ), carbon aluminum oxide (AlO _x C _y ), chromium oxycarbide (CrO _x C _y ), molybdenum oxycarbide (MoO _x C _y ), tungsten oxycarbide (WO _x C _y ), and tantalum oxycarbide (TaO _{x C y)} C _y ). A winding type electrolytic capacitor packaging structure, which includes: A wound capacitor, the wound capacitor includes a wound positive foil and a wound anticorrosive negative foil; A packaging structure in which the winding capacitor is housed in the packaging structure; A first conductive pin, the first conductive pin electrically contacting one of the wound type positive electrode foil and the wound type anticorrosive negative electrode foil; and A second conductive pin, the second conductive pin electrically contacting the other one of the wound type positive electrode foil and the wound type anticorrosive negative electrode foil; Wherein, the wound type anticorrosive negative electrode foil includes a conductive substrate, two zinc-containing material layers respectively arranged on two opposite surfaces of the conductive substrate, and two zinc-containing material layers respectively arranged on the two zinc-containing material layers. Two conductive compound layers. The winding type electrolytic capacitor packaging structure as described in claim 7, Wherein, the thickness of the rolled anticorrosive negative electrode foil is less than or equal to 50 µm, the two surfaces of the conductive substrate are both roughened surfaces, and the roughness of the roughened surface is less than or equal to 50 µm; Wherein, the conductive substrate is made of Al material, and the conductive substrate has no oxide layer and no corrosion layer, or the conductive substrate has an oxide layer but no corrosion layer; Wherein, the conductive compound layer is an electrolyte solution barrier layer with a thickness between 10 nm and 2000 nm to prevent the electrolyte solution from contacting and eroding the conductive substrate, so the thickness of the conductive substrate penetrates The protection of the conductive compound layer will not change; Wherein, the coiled anti-corrosion negative electrode foil uses the water resistance and resistance test method of the Japan Electronics and Information Technology Industries Association before and after the test to obtain a capacitance change between 1 and 10% and a capacitance change between 0 Withstand voltage change rate between ~5%; Wherein, the zinc-containing material layer is a pure zinc material layer or a zinc alloy material layer, and the wound anticorrosive negative electrode foil is an annealed negative electrode foil; Wherein, the structural strength of the zinc-containing material layer is greater than the structural strength of the conductive compound layer, and the structural strength of the conductive compound layer is greater than the structural strength of the conductive substrate; Wherein, the conductivity of the conductive substrate is greater than the conductivity of the zinc-containing material layer, and the conductivity of the zinc-containing material layer is greater than the conductivity of the conductive compound layer; Wherein, the adhesion between the zinc-containing material layer and the conductive substrate and the adhesion between the zinc-containing material layer and the conductive compound layer are both greater than those used for making the conductive substrate The adhesive force between the conductive material and the conductive material used to make the conductive compound layer. The winding type electrolytic capacitor packaging structure according to claim 7, wherein the conductive compound layer is a nitride layer, a carbide layer, a carbonitride layer, an oxynitride layer, and a carbon oxide layer At least one of; wherein, the nitride layer is made of at least nitride, and the nitride is selected from silicon nitride (Si3N4), titanium nitride (TiN), nitride A group consisting of aluminum (AlN), titanium aluminum nitride ((Ti,Al)N), chromium nitride (CrN), molybdenum nitride (MoN), tungsten nitride (WN), and tantalum nitride (TaN) ; Wherein, the carbide layer is made of at least carbide (carbide), and the carbide is selected from titanium carbide (TiC), aluminum carbide (AlC), chromium carbide (CrC), molybdenum carbide (MoC) ), tungsten carbide (WC), and tantalum carbide (TaC); wherein, the carbonitride layer is made of at least carbon nitride (carbon nitride), and the carbonitride is selected from Titanium carbonitride (TiC _x N _y ), aluminum carbonitride (AlC _x N _y ), chromium carbonitride (CrC _x N _y ), molybdenum carbonitride (Mo C _x N _y ), tungsten carbonitride ( WC _x N _y ) and tantalum carbonitride (TaC _x N _y ); wherein the oxynitride layer is made of at least oxynitride, and the oxynitride is selected from the group consisting of nitrogen Titanium oxide (TiO _x N _y ), aluminum oxynitride (AlO _x N _y ), chromium oxynitride (CrO _x N _y ), molybdenum oxynitride (MoO _x N _y ), tungsten oxynitride (WO _x N _y ), and nitrogen Tantalum oxide (TaO _x N _y ); wherein the carbon oxide layer is made of at least carbon oxide, and the carbon oxide is selected from the group consisting of titanium oxycarbide (TiO _x C _y ), carbon aluminum oxide (AlO _x C _y ), chromium oxycarbide (CrO _x C _y ), molybdenum oxycarbide (MoO _x C _y ), tungsten oxycarbide (WO _x C _y ), and tantalum oxycarbide (TaO _x C _y ). A wound type anticorrosive negative electrode foil, comprising: a conductive substrate; two zinc-containing material layers, the two zinc-containing material layers are respectively arranged on two opposite surfaces of the conductive substrate to contact the Two opposite surfaces of the conductive substrate; and two conductive compound layers, the two conductive compound layers are respectively disposed on the two zinc-containing material layers to respectively contact the two zinc-containing material layers; wherein, the The conductive compound layer is at least one of a nitride layer, a carbide layer, a carbonitride layer, an oxynitride layer, and a oxycarbide layer; wherein the nitride layer is at least made of nitride ( nitride), and the nitride is selected from silicon nitride (Si3N4), titanium nitride (TiN), aluminum nitride (AlN), titanium aluminum nitride ((Ti, Al)N), nitrogen The group consisting of chromium (CrN), molybdenum nitride (MoN), tungsten nitride (WN), and tantalum nitride (TaN); wherein the carbide layer is made of at least carbide, And the carbide is selected from the group consisting of titanium carbide (TiC), aluminum carbide (AlC), chromium carbide (CrC), molybdenum carbide (MoC), tungsten carbide (WC), and tantalum carbide (TaC); Wherein, the carbonitride layer is made of at least carbon nitride (carbon nitride), and the carbonitride is selected from titanium carbonitride (TiC _x N _y ), aluminum carbonitride (AlC _x N _y ), chromium carbonitride (CrC _x N _y ), molybdenum carbonitride (MoC _x N _y ), tungsten carbonitride (WC _x N _y ), and tantalum carbonitride (TaC _x N _y ) Group; wherein the oxynitride layer is made of at least oxynitride, and the oxynitride is selected from titanium oxynitride (TiO _x N _y ), aluminum oxynitride (AlO _x N _y ), nitrogen The group consisting of chromium oxide (CrO _x N _y ), molybdenum oxynitride (MoO _x N _y ), tungsten oxynitride (WO _x N _y ), and tantalum oxynitride (TaO _x N _y ); wherein the carbon is oxidized The material layer is made of at least carbon oxide (carbon oxide), and the carbon oxide is selected from titanium oxycarbide (TiO _x C _y ), carbon aluminum oxide (AlO _x C _y ), chromium oxycarbide (CrO _x C _y ), molybdenum oxycarbide (MoO _x C _y ), tungsten oxycarbide (WO _x C _y ), and tantalum oxycarbide (TaO _x C _y ); wherein the zinc-containing material layer is one A layer of pure zinc material or a layer of zinc alloy material, and the coiled anticorrosive negative electrode foil is an annealed negative electrode foil; wherein the structural strength of the zinc-containing material layer is greater than that of the conductive compound layer Strength, and the structural strength of the conductive compound layer is greater than that of the conductive substrate; wherein the conductivity of the conductive substrate is greater than that of the zinc-containing material layer Electrical conductivity, and the electrical conductivity of the zinc-containing material layer is greater than the electrical conductivity of the conductive compound layer; wherein the adhesion between the zinc-containing material layer and the conductive substrate and the zinc-containing material layer The adhesive force with the conductive compound layer is greater than the adhesive force between the conductive material used for making the conductive base and the conductive material used for making the conductive compound layer.

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