TWI747577B - Transfer printing and dyeing paper and transfer printing and dyeing method - Google Patents

Abstract

The subject of the present invention is to provide a transfer printing and dyeing paper for the transfer printing and dyeing method with wrinkle resistance, transferability, resistance to image deterioration, and color development. The subject of the present invention is accomplished by a transfer printing and dyeing paper, which is used in a transfer printing and dyeing method using sublimation type dye ink, and has a base paper layer and one side of the base paper layer and polysaccharides as the main component For the coating layer, the polysaccharides contain at least carboxymethyl cellulose and starch. Regarding the air permeability measured in accordance with ISO5636-5:2003, the air permeability of the base paper layer is 30 sec or less, and one side of the base paper layer is coated The air permeability of the transfer printing and dyeing paper of the cloth layer is more than 10 times the air permeability of the base paper layer.

Description

Transfer printing and dyeing paper and transfer printing and dyeing method

The present invention relates to a transfer printing and dyeing paper for transferring patterns in a transfer printing and dyeing method for forming patterns on a printed matter such as fiber materials, and a transfer printing and dyeing method using the same. In particular, it relates to a transfer printing and dyeing paper and a transfer printing and dyeing method suitable for "transfer printing and dyeing using sublimation dye ink as ink".

As a method of forming patterns on printed materials such as fiber materials, the following transfer printing and dyeing method is known: using sublimation dye inks to print patterns on transfer printing and dyeing paper to produce transfer printing and dyeing paper, and making the transfer printing and dyeing paper adhere to the printed material. , And transfer the sublimation type dye ink to the to-be-printed material (for example, refer to Patent Document 1 and Patent Document 2).

The transfer printing and dyeing paper used in the transfer printing and dyeing method is well known. For example, as a sublimation printing and dyeing transfer paper that can suppress the occurrence of stains when reusing waste paper pulp and has excellent transferability, the following sublimation printing and dyeing transfer paper is known, which is characterized by having wood pulp as the main component The base paper and the ink receiving layer containing a pigment and a water-soluble binder contain 5-40% by mass of the above-mentioned pigment relative to the total solid content of the above-mentioned ink receiving layer (for example, refer to Patent Document 3). In addition, as a sublimation type inkjet printing and dyeing transfer paper with excellent transfer density and residual printing density and good ink drying properties, the following sublimation type inkjet printing and dyeing transfer paper is known, which is characterized in that a sublimation is formed on one side of the base paper Type printing and dyeing ink receiving layer, said sublimation type printing and dyeing ink receiving layer is composed of ink receiving layer coating containing at least one kind of binder and inorganic particles, said inorganic particles are light calcium carbonate, and said binder contains at least ethylene vinyl acetate copolymer , Relative to the total of 100 parts by mass of inorganic particles, the ethylene vinyl acetate copolymer is contained in a ratio of 5.0 to 15.0 parts by mass, and the initial water absorption characteristics of the base paper measured by a surface sizing tester have an ultrasonic wave of 100 The time required for% is 0.01 to 3.00 seconds (for example, refer to Patent Document 4).

In the method of making a transfer printing and dyeing paper by using a sublimation printing and dyeing ink to transfer a printing pattern on a printing and dyeing paper, as described in Patent Document 3 and Patent Document 4, an inkjet printing method is often used. [Prior Technical Literature] [Patent Literature]

[Patent Document 1] Japanese Patent Application Publication No. 2015-168705 [Patent Document 2] Japanese Patent Application Publication No. 2015-124324 [Patent Document 3] Japanese Patent Application Publication No. 2019-064186 [Patent Document 4] Japanese Patent No. 6391792

[The problem to be solved by the invention]

The transfer printing and dyeing paper used as white paper before printing the pattern and the transfer printing and dyeing paper with the transfer pattern printed on the transfer printing and dyeing paper need to have two opposite characteristics. That is, the ability to accept ink and the ability to transfer ink. Transfer printing and dyeing paper needs to have a good ability to accept sublimation dye inks and other inks. The transfer printing and dyeing paper needs the ability to transfer the color material contained in the sublimation dye ink to the printed matter well. Generally speaking, if the above-mentioned acceptance ability is increased, the above-mentioned transfer ability is reduced. As a result, the color density of the pattern transferred to the printed matter may decrease.

Moreover, the image quality of the pattern obtained by transferring from the transfer printing paper to the to-be-printed material cannot exceed the image quality of the pattern printed on the transfer printing paper. Therefore, the transfer printing and dyeing paper needs to have the following ability: relative to the image quality of the pattern printed on the transfer printing and dyeing paper, the image quality of the pattern transferred from the transfer printing and dyeing paper to the printed matter does not deteriorate; or Ability to restrain the deterioration of picture quality.

Moreover, in order to efficiently transfer from the transfer printing paper to the to-be-printed material, it is desired that the transfer printing paper has a low affinity with inks such as sublimation dye inks. If the affinity between the transfer printing paper and the sublimation dye ink and other inks is not low, relatively large energy is required to transfer the color material contained in the ink from the transfer printing paper to the printed matter. For example, when performing transfer under the same temperature condition, it takes a relatively long time to transfer the color material contained in the sublimation dye ink from the transfer printing paper to the printed matter.

Inkjet paper has the following types: pigment-based inkjet paper made by coating the coating liquid with the largest content of white pigment on the base paper, and resin made by coating the coating liquid with the largest content of resin on the base paper Department of inkjet paper. Pigment-based inkjet paper is generally characterized in that the absorption speed of ink is fast, but the absorption capacity of ink is poor. Resin-based inkjet paper is generally characterized in that the absorption speed of ink is slow, but the absorption capacity of ink is good. If the absorption speed of the ink becomes slow, the ink spreads on the inkjet paper, and the image quality of the pattern printed on the inkjet paper deteriorates. If the absorption capacity of the ink is insufficient, the solvent of the ink will cause wrinkles in the inkjet paper.

The quality of the sublimation printing and dyeing transfer paper of Patent Document 3 and the sublimation inkjet printing and dyeing transfer paper of Patent Document 4 is hard to say.

In view of the above circumstances, the object of the present invention is to provide a transfer printing and dyeing paper and a transfer printing and dyeing method having the following qualities. (1) It can suppress the wrinkles of transfer printing and dyeing paper (wrinkle resistance) (2) Good transfer efficiency on transfer printing and dyeing paper (transferability) (3) It can suppress the deterioration of the image quality of the printed matter (resistance to image deterioration) (4) It can suppress the decrease of the color density of the printed matter (color rendering) [Technical means to solve the problem]

The inventors of the present invention have made repeated efforts to solve the above-mentioned problems. As a result, the object of the present invention is achieved by the following scheme. [1] A transfer printing and dyeing paper, which is used in a transfer printing and dyeing method using sublimation dye inks, The transfer printing and dyeing paper has a base paper layer and a coating layer on one side of the base paper layer and containing polysaccharides as the main component. The above-mentioned polysaccharides contain at least carboxymethyl cellulose and starches, Regarding the air permeability measured in accordance with ISO5636-5: 2003, the air permeability of the above-mentioned base paper layer is 30 sec or less, and the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is 10 times the air permeability of the base paper layer above.

[2] The transfer printing and dyeing paper as described in [1] above, wherein the amount of the coating layer mainly composed of polysaccharides on the one side is 4 g/m ² or less in terms of dry solid content .

[3] The transfer printing and dyeing paper as described in the above [1] or the above [2], wherein the coating layer containing polysaccharides as a main component does not substantially contain a pigment.

[4] The transfer printing and dyeing paper as described in any one of [1] to [3] above, wherein at least one of the above-mentioned starches is urea phosphorylated starch.

[5] The transfer printing and dyeing paper according to any one of [1] to [4] above, wherein the carboxymethyl cellulose is a low molecular weight type.

[6] The transfer printing and dyeing paper as described in any one of [1] to [5] above, wherein the air permeability of the base paper layer is 12 sec or more and the air permeability measured in accordance with ISO5636-5: 2003 30 sec or less, and the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is 12 times or more and 5450 times or less of the air permeability of the base paper layer.

[7] The transfer printing and dyeing paper as described in [4] above, wherein the urea phosphorylated starch has an average value of urea substitution degree of 0.005 or more and 0.05 or less.

[8] The transfer printing and dyeing paper according to any one of [1] to [7] above, wherein the carboxymethyl cellulose is obtained by gel permeation chromatography in terms of polyethylene glycol The weight average molecular weight of is 27,000 or more and 770,000 or less.

[9] The transfer printing and dyeing paper according to any one of [1] to [7] above, wherein the degree of etherification of the carboxymethyl cellulose is 0.6 or more and 1.27 or less.

[10] The transfer printing and dyeing paper according to any one of [1] to [7] above, wherein the carboxymethyl cellulose is obtained by gel permeation chromatography in terms of polyethylene glycol The weight average molecular weight of is 27,000 or more and 770,000 or less, and the degree of etherification is 0.6 or more and 1.27 or less.

[11] The transfer printing and dyeing paper as described in [4] above, wherein, regarding the air permeability measured in accordance with ISO5636-5:2003, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and the base paper layer The air permeability of the transfer printing and dyeing paper with a coating layer on one side is 12 times or more and 5450 times or less of the air permeability of the base paper layer. The average value of the degree of urea substitution of the urea phosphorylated starch is 0.005 or more and 0.05 or less.

[12] The transfer printing and dyeing paper as described in [4] above, wherein, regarding the air permeability measured in accordance with ISO5636-5:2003, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and the base paper layer The air permeability of the transfer printing and dyeing paper with a coating layer on one side is 12 times or more and 5450 times or less of the air permeability of the base paper layer. The average value of urea substitution degree of the above-mentioned urea phosphated starch is 0.005 or more and 0.05 or less, The weight average molecular weight of the carboxymethyl cellulose obtained by gel permeation chromatography in terms of polyethylene glycol is 27,000 or more and 770,000 or less, and the degree of etherification is 0.6 or more and 1.27 or less. [13] A transfer printing and dyeing method, which includes the following steps: Steps of obtaining transfer printing and dyeing paper by printing patterns on the transfer printing and dyeing paper described in any one of [1] to [12]; and The step of making the pattern-printed surface of the transfer printing paper and the object to be printed closely adhere to each other. [Effects of the invention]

According to the present invention, it is possible to provide a transfer printing and dyeing paper and a transfer printing method having wrinkle resistance, transferability, resistance to image deterioration, and color development.

Hereinafter, the present invention will be described in detail. In the present invention, "transfer printing and dyeing paper" refers to paper in the state of white paper before the pattern to be transferred is printed. "Transfer printing and dyeing paper" refers to the paper in the state where the pattern to be transferred is printed on the transfer printing and dyeing paper.

[Transfer paper] The first embodiment of the present invention is a transfer printing and dyeing paper. The transfer printing paper has a base paper layer and a coating layer on one side of the base paper layer. The base paper layer is made of papermaking paper obtained by making paper materials, the above-mentioned paper materials are selected from LBKP (Leaf Bleached Kraft Pulp, hardwood bleached kraft pulp), NBKP (Needle Bleached Kraft Pulp, softwood bleached kraft pulp) And other chemical pulp, GP (Groundwood Pulp), PGW (Pressure GroundWood pulp), RMP (Refiner Mechanical Pulp), TMP (ThermoMechanical Pulp), Mechanical pulp such as CTMP (ChemiThermoMechanical Pulp), CMP (ChemiMechanical Pulp), CGP (ChemiGroundwood Pulp), and waste paper pulp such as DIP (DeInked Pulp) At least one of the pulps is blended with various fillers such as calcium carbonate, talc, clay, kaolin, etc., as necessary, and further blended with binders, sizing agents, fixing agents, retention aids, cationizing agents, paper strength enhancers, and pigments Dispersants, tackifiers, fluidity improvers, defoamers, foam inhibitors, mold release agents, foaming agents, penetrants, coloring dyes, coloring pigments, fluorescent brighteners, ultraviolet absorbers, antioxidants, It is made of various additives such as preservatives, antifungal agents, and water-resistant agents. Furthermore, the base paper layer includes calendering papermaking obtained by subjecting the aforementioned papermaking paper to a previously known calendering treatment. In the calendering treatment, a previously known calendering treatment device can be used. Examples of the calender treatment device include: a machine calender, a soft nip calendar, a super calender, a multi-stage calender, and a multi-nip calender.

Papermaking can adjust the paper stock to be acidic, neutral or alkaline, and perform it using a previously known papermaking machine. Examples of paper machines include Fourdrinier paper machines, twin-wire paper machines, combined paper machines, cylinder paper machines, Yankee paper machines, and the like.

The coating layer can be obtained by applying a coating liquid for the coating layer to the base paper layer and drying the base paper layer using a previously known coating device and drying device. In the implementation aspect, the coating layer includes the following states: a state in which the components of the coating liquid for the coating layer are present on the surface of the papermaking paper in the form of the coating layer area, and/or the components of the coating liquid for the coating layer The state in which the form exists in the diffusion layer area inside the papermaking paper. That is, the coating layer is in any of the following states with respect to the base paper layer: a state in the form of a coating layer area, a state in the form of a diffusion layer area, and a state in which both the coating layer area and the diffusion layer area are present. The state of existence in this form. The above-mentioned state of the coating layer can be confirmed by the following method: Observe the section of the transfer printing and dyeing paper with an electron microscope with element analysis function, such as an energy dispersive X-ray spectrometer, and analyze the element distribution. The state existing in the form of the coating layer area and/or the state existing in the form of the diffusion layer area can be based on the type and content of the binder of the base paper layer, the type and content of the sizing agent of the base paper layer, and the paper of the base paper layer The type and content of the strength enhancer, as well as the calendering treatment conditions are controlled.

The coating layer has polysaccharides as a main component. Polysaccharides contain at least carboxymethyl cellulose and starches. Here, "having... as a main component" refers to a state in which the proportion of dry solids constituting the coating layer exceeds 50% by mass. Such a coating layer can be obtained by coating a base paper layer with a coating liquid containing at least carboxymethyl cellulose and starches using a conventionally known coating device and drying device, and drying it. Examples of previously known coating devices include: sizing press, gate roll coater, film transfer coater, knife coater, rod coater, air knife coater, gravure coater Machine, bar coater, E-type bar coater, curtain coater, etc. Examples of previously known drying devices include: linear tunnel dryers, arch dryers, air circulation dryers, sinusoidal air float dryers, and other hot air dryers, infrared heating dryers, and microwave dryers. Various drying devices. After coating and drying the coating layer coating liquid, the coating layer can be subjected to a previously known calendering treatment.

In the embodiment of the transfer printing paper, the coating layer exists on one side of the base paper layer with respect to the base paper layer. The transfer printing and dyeing paper may have a previously known post-coating layer on the side opposite to the side with the coating layer of the base paper layer.

In some embodiments, the amount of the coating layer provided to the base paper layer is 4 g/m ² or less on the one side of the base paper layer in terms of the amount of dry solids. In addition, in some embodiments, the amount of the coating layer provided to the base paper layer is 1.5 g/m ² or more on the one side of the base paper layer in terms of the amount of dry solids. In addition, in some embodiments, the amount of the coating layer provided to the base paper layer is 2.4 g/m ² or more on the one side of the base paper layer in terms of the amount of dry solids. Furthermore, in at least one embodiment, the amount of the coating layer provided to the base paper layer is 1.5 g/m ² or more and 4 g/m ² or less on the one side of the base paper layer in terms of the amount of dry solids. If the amount of the coating layer provided to the base paper layer is within this range, the image quality deterioration resistance becomes better.

Carboxymethyl cellulose is a kind of cellulose ether, which is known in the past and is not particularly limited. Carboxymethyl cellulose includes alkali metal salts of carboxymethyl cellulose. Carboxymethyl cellulose can be obtained, for example, by reacting sodium monochloroacetate (sodium monochloroacetate) and sodium hydroxide using pulp as a raw material (direct method). In addition to the direct method, it can also be obtained by the alkali cellulose method (alkali cellulose method) and the solvent method. Carboxymethyl cellulose can be manufactured with various molecular weights or polymerization degrees according to the properties and manufacturing methods of the pulp used. Generally speaking, carboxymethyl cellulose is industrially produced and sold in the form of an alkali metal salt of carboxymethyl cellulose. Most of the alkali metal salts of carboxymethyl cellulose are sodium carboxymethyl cellulose or potassium carboxymethyl cellulose. In most cases, the description of sodium salt or potassium salt is omitted. In at least one aspect, the alkali metal salt of carboxymethyl cellulose is the sodium salt of carboxymethyl cellulose. The reason is that sodium carboxymethyl cellulose is easily available commercially. Carboxymethyl cellulose is sold, for example, by Sigma-Aldrich, Daicel Miraizu, Daiichi Kogyo Pharmaceutical, CPKelco, Nippon Paper, and Ashland.

In some embodiments, carboxymethyl cellulose is a low molecular weight type obtained by gel permeation chromatography with a weight average molecular weight of less than 1 million in terms of polyethylene glycol. In some embodiments, the weight average molecular weight of carboxymethyl cellulose in terms of polyethylene glycol is 770,000 or less. In addition, in some embodiments, the weight average molecular weight of carboxymethyl cellulose in terms of polyethylene glycol is 27,000 or more. Furthermore, in at least one embodiment, the weight average molecular weight of carboxymethyl cellulose in terms of polyethylene glycol is 27,000 or more and 770,000 or less. If the weight average molecular weight of carboxymethyl cellulose is within this range, the transferability and/or the resistance to deterioration of image quality become better. Furthermore, in at least one embodiment, the weight average molecular weight of carboxymethyl cellulose in terms of polyethylene glycol is 27,000 or more and 360,000 or less. If the weight average molecular weight of carboxymethyl cellulose is within this range, it is easy to manufacture a coating layer coating liquid. In some embodiments, the degree of etherification of carboxymethyl cellulose is 0.6 or more and 1.27 or less. If the degree of etherification of carboxymethyl cellulose is within this range, the resistance to deterioration of image quality becomes better. The degree of etherification refers to the number (average value) of hydroxyl groups substituted by carboxymethyl among the 3 hydroxyl groups on the glucose ring constituting the cellulose. The degree of etherification can theoretically have a value between 0 and 3. Generally speaking, the higher the degree of substitution, the better the hydrophilicity. In at least one embodiment, the weight average molecular weight of carboxymethyl cellulose obtained by gel permeation chromatography in terms of polyethylene glycol is 27,000 or more and 770,000 or less, and the degree of etherification is 0.6 or more and 1.27 or less .

In some embodiments, the content of carboxymethyl cellulose in the coating layer is 0.75 g/m ² or more and 3.5 g/m ² or less. In addition, in at least one embodiment, the content of carboxymethyl cellulose in the coating layer is 1 g/m ² or more and 3.4 g/m ² or less. If the content of carboxymethyl cellulose is within this range, the wrinkle resistance, transferability, and/or resistance to image deterioration become better.

Starch is a previously known polysaccharide in which glucose is polymerized by glycosidic bonds, or a polysaccharide in which glucose is polymerized by glycosidic bonds. The hydroxyl group of glucose is modified by various substituents. A previously known polysaccharide , There is no particular limitation. Examples of starches include: starch, oxidized starch, enzyme-modified starch, etherified starch, cationic starch, amphoteric starch, dialdehyde starch, phosphated starch, urea phosphated starch and other esterified starches, hydroxy Ethyl starch, and hydroxybutyl starch, etc.

In at least one embodiment, at least one kind of starch is urea phosphorylated starch. If the starch is urea phosphated starch, the transferability, resistance to image deterioration, and/or color development are improved. Urea phosphorylated starch is a starch having a phosphate group and a urethane group in glucose. As an example of the method of introducing a phosphate group, a method of separately adding phosphate such as sodium tripolyphosphate to carry out a calcination reaction can be cited. Phosphoric acid is added together to carry out the roasting reaction method. Urea phosphorylated starch can be mainly used to obtain starches with various degrees of urea substitution by the latter method of roasting reaction between inorganic phosphoric acid and urea. Urea phosphated starch is sold by Oji Cornstarch, Japan Food & Chemical Corporation, GSL JAPAN, etc.

In several embodiments, the average value of urea substitution degree of urea phosphorylated starch is 0.005 or more and 0.09 or less. In at least one embodiment, the average value of urea substitution degree of urea phosphated starch is 0.005 or more and 0.05 or less. If the average value of the degree of urea substitution of the urea phosphorylated starch is within this range, the transferability and/or color rendering property will become better. The so-called "degree of urea substitution" refers to the degree of substitution of carbamate based on the hydroxyl group of the glucose unit constituting starch. For example, urea substitution degree=0.02 means that every 100 glucose units constituting starch have 2 substituents. The degree of urea substitution is a conventional value of starch and can be obtained by a known method. For example, it can be determined from the nitrogen content obtained by thermal decomposition GC (Gas Chromatography) method or CHN element analyzer. Also, you can refer to the "Science Experiment Method of Starch" Shigeo Suzuki and editors of Nakamura Moral. The first edition was published in 1979 and published by Asakura Bookstore.

In several embodiments, the content of starch in the coating layer is 0.5 g/m ² or more and 3 g/m ² or less. Furthermore, in at least one aspect, the content of the urea phosphorylated starch in the coating layer is 0.5 g/m ² or more and 2.7 g/m ² or less. If the content of starches or urea phosphorylated starch is within this range, the wrinkle resistance and/or the resistance to image deterioration become better.

In several embodiments, the content of carboxymethyl cellulose in the coating layer is 0.75 g/m ² or more and 3.5 g/m ² or less, and the starch content in the coating layer is 0.5 g/m ² or more and 3 g/m ² or less. Furthermore, in at least one embodiment, the content of carboxymethyl cellulose in the coating layer is 1 g/m ² or more and 3.4 g/m ² or less, and the content of urea phosphorylated starch in the coating layer is 0.5 g /M ² or more and 2.7 g/m ² or less.

In at least one embodiment, the weight average molecular weight of carboxymethyl cellulose obtained by gel permeation chromatography in terms of polyethylene glycol is 27,000 or more and 770,000 or less, and the degree of etherification is 0.6 or more and 1.27 or less , And at least one kind of starch is urea phosphated starch, and the average value of urea substitution degree of urea phosphated starch is 0.005 or more and 0.05 or less.

In addition to carboxymethyl cellulose and starches, the coating layer may also contain previously known binders. Examples of previously known adhesives include: cellulose derivatives such as hydroxyethyl cellulose other than carboxymethyl cellulose, casein, gelatin, soy protein, triglucosamine, gum arabic, karaya, and Albumin and other natural resins or their derivatives, polyvinylpyrrolidone, polyvinyl alcohol and various modified polyvinyl alcohol, polyacrylamide, polyethyleneimine, polypropylene glycol, polyethylene glycol, Maleic anhydride resin, (meth)acrylic resin, (meth)acrylate resin, (meth)acrylate-butadiene copolymer, styrene-butadiene copolymer, and ethylene-vinyl acetate Copolymers such as ester copolymers, and functional group-modified copolymers formed from monomers containing functional groups such as carboxyl groups, thermosetting synthetic resins such as melamine resins and urea resins, polyurethane resins, and unsaturated polyesters. Resin, polyvinyl butyral, and alkyd resin latex, etc.

In several embodiments, the coating layer contains previously known pigments. Examples of pigments include: kaolin, heavy calcium carbonate, light calcium carbonate, talc, satin white, lithopone, titanium oxide, zinc oxide, silicon dioxide (silica), alumina, Inorganic pigments such as aluminum hydroxide, zinc oxide, activated clay and diatomaceous earth, and organic pigments such as plastic pigments. When the coating layer contains a pigment, the pigment is selected from one or two or more of the above-mentioned pigments. In at least one embodiment, the coating layer contains substantially no pigment. By making the coating layer substantially free of pigments, the wrinkle resistance becomes better. Here, the so-called "substantially free of pigments" means that when an electron microscope with elemental analysis function such as an energy dispersive X-ray spectrometer is used to observe the section of the transfer printing and dyeing paper, the reason why the covering base paper layer cannot be seen The layer of pigments. For example, if the pigment is less than 10% by mass relative to the applied amount of the coating layer on the one side of the base paper layer, the pigment cannot sufficiently cover the base paper layer, and therefore the layer composed of the pigment cannot be seen.

In this manual, the air permeability is the value measured in accordance with ISO5636-5:2003. In this embodiment, the air permeability of the base paper layer is 30 sec or less, and the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is more than 10 times the air permeability of the base paper layer. In several embodiments, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is 11 times or more of the air permeability of the base paper layer. In addition, in several embodiments, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is more than 12 times the air permeability of the base paper layer And less than 6000 times. If it is 6000 times or less, the wrinkle resistance and the resistance to image deterioration become better. In at least one embodiment, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is 12 times or more than the air permeability of the base paper layer and 5450 Less than times. The air permeability of the base paper layer from the transfer printing and dyeing paper can be measured, for example, by observing the cross section of the transfer printing and dyeing paper while cutting off the coating layer and using the exposed base paper layer. When measuring the air permeability of the base paper layer and the transfer printing and dyeing paper with a coating layer on one side of the base paper layer, according to ISO5636-5:2003, half of the test piece is the front side (in the case of transfer printing and dyeing paper, it is coated The side of the cloth layer) face up, and the other half with the back side (in the case of transfer printing and dyeing paper, the side without the coating layer) face up, and fasten it between the fastening plates of the testing machine. Experiment and find the average value.

By adopting a coating layer containing at least carboxymethyl cellulose and starch and the above-mentioned air permeability, the ink solvent in the sublimation dye ink and other inks can be separated from the color material efficiently, and can absorb The ink solvent can hold the colorant on the coating layer at the same time. So that the transfer printing and dyeing paper can have wrinkle resistance, transferability, resistance to image deterioration and color rendering. If the air permeability of the base paper layer exceeds 30 sec, the transfer printing and dyeing paper cannot have wrinkle resistance and resistance to image deterioration. If the air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer is less than 10 times the air permeability of the base paper layer, the transfer printing and dyeing paper cannot have transferability and resistance to image deterioration.

The method of adjusting the air permeability is a method previously known in the field of coated paper. The air permeability of the base paper layer can be adjusted according to the density and thickness of the papermaking, the beating degree of the pulp, the type and content of the filler, the type and content of the binder, and the calendering conditions. Regarding the method of reducing the air permeability of the base paper layer, for example, the following methods can be cited: reducing the density, reducing the thickness, inhibiting pulp beating, reducing the amount of non-flat fillers and fillers, and reducing the use of low-molecular-weight adhesives The amount and bonding amount, as well as suppressing the calender pressure, etc. However, if the thickness is excessively reduced, the absorption capacity of the ink solvent will decrease or wrinkles will occur. The air permeability of the transfer printing and dyeing paper with a coating layer on one side of the base paper layer can be based on the amount of the coating layer coating liquid based on the amount of dry solids, the coating method of the coating layer coating liquid, and the coating layer coating liquid The drying method, drying time, and calendering conditions can be adjusted. Regarding the method of increasing the air permeability value of transfer printing and dyeing paper with a coating layer on one side of the base paper layer, for example, the following methods can be cited: increasing the amount of coating layer coating liquid provided in terms of dry solids; using air knife coating Non-contact coating methods such as cloth machine shorten the drying time of the coating layer coating liquid; increase the calendering pressure, etc. However, if the applied amount is excessively increased, the absorption speed of the ink solvent will decrease.

In at least one embodiment, regarding the air permeability measured in accordance with ISO5636-5:2003 of the transfer printing and dyeing paper, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and one side of the base paper layer has a coating layer. The air permeability of the printing and dyeing paper is 12 times or more and 5450 times or less of the air permeability of the base paper layer, and at least one of the starches in the polysaccharide of the coating layer is urea phosphorylated starch, which is substituted by urea phosphorylated starch. The average degree is 0.005 or more and 0.05 or less.

In at least one embodiment, regarding the air permeability measured in accordance with ISO5636-5:2003 of the transfer printing and dyeing paper, the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and one side of the base paper layer has a coating layer. The air permeability of the printing and dyeing paper is 12 times or more and 5450 times or less of the air permeability of the base paper layer. At least one of the starches in the polysaccharides in the coating layer is urea phosphorylated starch, and the degree of urea substitution of urea phosphorylated starch The average value is 0.005 or more and 0.05 or less, and the weight average molecular weight of carboxymethyl cellulose obtained by gel permeation chromatography in terms of polyethylene glycol is 27,000 or more and 770,000 or less, and the degree of etherification is 0.6 or more And below 1.27.

The coating layer may optionally contain various additives previously known in the field of coated paper. Examples of additives include: dispersants, fixing agents, tackifiers, fluidity improvers, defoamers, mold release agents, foaming agents, penetrants, coloring pigments, coloring dyes, fluorescent whitening agents , UV absorbers, antioxidants, preservatives, antifungal agents, etc. In addition, the coating layer may contain various auxiliary agents conventionally known in the transfer printing and dyeing method. The auxiliary agent is added to optimize the various physical properties of the coating layer coating liquid, or to improve the dyeability of the color material contained in the sublimation dye ink and other inks. Examples of the auxiliary agent include various surfactants, humectants, humectants, pH adjusters, alkali agents, thick dyeing agents, deaerators, reduction inhibitors, and the like. The transfer printing paper can be manufactured by using a previously known coating device and drying device on the base paper layer, applying a coating liquid for the coating layer to the base paper layer and drying, and forming a coating layer on one surface of the base paper layer. The coating liquid contains the components constituting the above-mentioned coating layer in water or alcohol as a solvent, preferably water.

The transfer printing paper can be obtained by printing a pattern on the side of the transfer printing paper with a coating layer using various known printing methods including sublimation dye inks and the like. There are no particular limitations on various previously known printing methods for printing patterns on transfer printing and dyeing paper. Examples of the printing method include a gravure printing method, an inkjet printing method, an electrophotographic printing method, and a screen printing method. In at least one embodiment, the printing method for printing patterns on the transfer printing and dyeing paper is inkjet printing.

[Transfer Printing and Dyeing Method] The second embodiment of the present invention is a transfer printing and dyeing method. The transfer printing and dyeing method is a method having the following steps: a step of printing a pattern on a transfer printing and dyeing paper to obtain a transfer printing and dyeing paper; and a step of making the printed surface of the transfer printing and dyeing paper closely adhere to the object to be printed. The bonding step includes heating and/or pressurization as necessary. The heating and pressurizing conditions in the bonding step are previously known conditions in the transfer printing and dyeing method. The adhesion step may include, for example, the following method: heating and/or pressurizing the transfer printing paper and the to-be-printed material by a pressing machine, a heating roller, or the like. In at least one embodiment, the ink of the transfer printing and dyeing method is a sublimation dye ink.

The printed matter is a fibrous material and is not particularly limited. The fiber material may be any of fiber materials derived from natural materials and fiber materials derived from synthetic resins. Examples of fiber materials derived from natural materials include cellulose fiber materials such as cotton, hemp, lyocell, rayon, acetate, and protein fiber materials such as silk, wool, and animal hair. Examples of fiber materials derived from synthetic resins include polyamide fibers (nylon), vinylon, polyester, and polyacrylic acid. In at least one embodiment, when the sublimation dye ink is used, the fiber material is polyester. Examples of the composition of the fiber material include individual components such as woven fabrics, knitted fabrics, and non-woven fabrics, blended fabrics, blended fabrics, or interwoven fabrics. Furthermore, these structures can be combined. In addition, if necessary, the printed matter can be pre-treated with a chemical agent that promotes dyeing. [Example]

Hereinafter, the present invention will be described in further detail with examples. Furthermore, the present invention is not limited to these embodiments. Here, "parts by mass" and "% by mass" represent the respective "parts by mass" and "% by mass" of the dry solid content or the actual component amount. The applied amount of the coating layer represents the amount of dry solids.

(Base paper layer) To the pulp slurry composed of 100 parts by mass of LBKP adjusted to the degree of beating to a degree of drainage between 380 mlcsf and 480 mlcsf, add 20 parts by mass of light calcium carbonate as filler, 1-2 parts by mass of amphoteric starch, and sulfuric acid 0.8 parts by mass of aluminum and 0.1 parts by mass of alkyl ketene dimer type sizing agent were paper-made using a Fourdrinier paper machine, and the obtained paper-made paper was subjected to mechanical calendering treatment to obtain a base paper layer. Here, the beating degree, the addition amount of amphoteric starch, and the calendering conditions were adjusted to produce a base paper layer having the air permeability described in Table 1 and Table 2. The air permeability is measured in accordance with ISO5636-5:2003.

(Coating liquid for coating layer) The coating layer coating liquid was prepared according to the following. Cellulose types and masses are recorded in Table 1 and Table 2 The types and masses of starches are listed in Table 1 and Table 2 The mass of heavy calcium carbonate is recorded in Table 1 and Table 2 The blending is carried out as described above, and the concentration is adjusted to 8-10% by mass by mixing and dispersing with water.

(Transfer printing and dyeing paper) Follow the steps below to make transfer printing and dyeing paper. An air knife coater is used to coat one surface of the base paper layer with the coating liquid for the coating layer and is dried by a hot air dryer to set the coating layer. After drying, calendering treatment was performed to obtain transfer printing and dyeing paper. The amount given is described in Table 1 and Table 2. The application amount of the coating liquid, the drying temperature and time, and the calendering treatment conditions were adjusted to produce a transfer printing and dyeing paper having a coating layer on one side of the base paper layer and having the air permeability described in Tables 1 and 2. The air permeability is measured in accordance with ISO5636-5:2003.

[Table 1] Base paper layer air permeability sec Coating layer Air permeability of transfer printing and dyeing paper sec Permeability ratio Give amount g/m ² Type of cellulose, weight average molecular weight, degree of etherification Mass parts Type of starch urea substitution degree Mass parts Type and mass of pigment Example 1 12 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 862 72 Example 2 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 1307 77 Example 3 twenty four 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 1467 61 Example 4 30 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 1753 58 Example 5 12 1.5 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 129 11 Example 6 12 1.5 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 50 - 142 12 Example 7 17 4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 200 - 13559 798 Example 8 17 4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 15881 934 Example 9 17 4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 25 - 17612 1036 Example 10 17 5 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 85167 5010 Example 11 17 5 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 50 - 92638 5449 Example 12 17 4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 Heavy calcium carbonate 10 14,954 880 Example 13 17 4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 Heavy calcium carbonate 20 11172 657 Example 14 17 4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 Heavy calcium carbonate 100 1164 68 Example 15 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.005 100 - 1294 76 Example 16 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.02 100 - 1321 78 Example 17 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.05 100 - 1321 78 Example 18 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea Phosphate Starch 0.09 100 - 1336 79 Example 19 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 Oxidized starch- 100 - 1313 77

[Table 2] Base paper layer air permeability sec Coating layer Air permeability of transfer printing and dyeing paper sec Permeability ratio Give amount g/m ² Type of cellulose, weight average molecular weight, degree of etherification Mass parts Type of starch urea substitution degree Mass parts Type and mass of pigment Example 20 17 2.4 Carboxymethyl cellulose 10,000 0.65 100 Urea phosphated starch 0.01 100 - 1295 76 Example twenty one 17 2.4 Carboxymethyl cellulose 27,000 0.60 100 Urea phosphated starch 0.01 100 - 1301 77 Example twenty two 17 2.4 Carboxymethyl cellulose 80,000 0.80 100 Urea phosphated starch 0.01 100 - 1307 77 Example twenty three 17 2.4 Carboxymethyl cellulose 120,000 0.80 100 Urea phosphated starch 0.01 100 - 1307 77 Example twenty four 17 2.4 Carboxymethyl cellulose 250,000 0.55 100 Urea phosphated starch 0.01 100 - 1304 77 Example 25 17 2.4 Carboxymethyl cellulose 250,000 0.70 100 Urea phosphated starch 0.01 100 - 1304 77 Example 26 17 2.4 Carboxymethyl cellulose 250,000 1.20 100 Urea phosphated starch 0.01 100 - 1311 77 Example 27 17 2.4 Carboxymethyl cellulose 360,000 1.20 100 Urea phosphated starch 0.01 100 - 1311 77 Example 28 17 2.4 Carboxymethyl cellulose 550,000 1.30 100 Urea phosphated starch 0.01 100 - 1532 90 Example 29 17 2.4 Carboxymethyl cellulose 770,000 1.27 100 Urea phosphated starch 0.01 100 - 1532 90 Example 30 17 2.4 Carboxymethyl cellulose 800,000 0.55 100 Urea phosphated starch 0.01 100 - 1534 90 Example 31 17 2.4 Carboxymethyl cellulose 1400,000 1.10 100 Urea phosphated starch 0.01 100 - 1587 93 Example 32 12 5 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 81763 6814 Example 33 17 5 Carboxymethyl cellulose 250,000 0.90 100 Phosphate starch 0.0 100 - 1317 77 Comparative example 1 39 2.4 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 2167 56 Comparative example 2 10 1.5 Carboxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 90 9 Comparative example 3 17 2.4 Hydroxymethyl cellulose 250,000 0.90 100 Urea phosphated starch 0.01 100 - 1308 77 Comparative example 4 17 2.4 - - Urea phosphated starch 0.01 100 - 1221 72 Comparative example 5 17 2.4 Carboxymethyl cellulose 250,000 0.90 100 - - - 1675 99

(Transfer printing and dyeing paper) On the obtained transfer printing and dyeing paper, the sublimation dye ink (cyan, magenta, yellow, black) was printed by an inkjet printer (JV2-130II, manufactured by Mimaki Engineering) using sublimation dye ink. It is used for evaluating the composition of the single color of each ink, and the mixture of yellow and cyan, that is, the mixture of green, yellow and magenta, that is red, the mixture of cyan and magenta, that is blue, and the mixture of yellow, cyan and magenta, that is black. Pattern to obtain transfer printing paper.

(Wrinkle resistance) Use an inkjet printer to print an evaluation pattern composed of mixed colors, namely green, red, blue, and black on the side of the transfer printing and dyeing paper with the coating layer, including 4 cm×4 cm of each entity image. Thus, transfer printing and dyeing paper is obtained. In the printing section of the obtained transfer printing paper, the wrinkles generated by the solid image were observed and evaluated according to the following criteria. In the present invention, if the evaluation is 3 to 5, it is considered that the transfer printing and dyeing paper has wrinkle resistance. 5: No wrinkles are seen on the pattern. 4: Very few wrinkles are seen on the pattern immediately after printing, but they disappear soon. 3: Some wrinkles are seen on the pattern. But it can be put into practical use. 2: Slight wrinkles are seen on the pattern. According to the pattern of the product, it cannot be put into actual use. 1: Wrinkles that are obviously poor in transfer are seen on the pattern.

(Transfer printing and dyeing) As the printed material, white polyester cloth was used. Make the side surface of the transfer printing and dyeing paper with the coating layer and the white polyester cloth opposingly close. Using a heat transfer press (US INSTA company, heat press model 204), heat the transfer printing paper with the white polyester cloth in close contact at a temperature of 140°C for 10 to 14 minutes.

(Transferability) Change the heating time during transfer printing and dyeing, observe the color density of the pattern in the white polyester cloth with the pattern formed, and evaluate it according to the following criteria. The heating time is set to 10 minutes, 12 minutes, and 14 minutes. In the present invention, if the evaluation is 3 to 5, it is considered that the transfer printing and dyeing paper has transferability. 5: There is no change in color density at 10 minutes, 12 minutes, and 14 minutes. 4: Very little change in color density is seen between 10 minutes and 12 minutes. No change in color density was seen between 12 minutes and 14 minutes. 3: A slight change in color density is seen between 10 minutes and 12 minutes. No change in color density was seen between 12 minutes and 14 minutes. 2: A slight change in color density is seen between 12 minutes and 14 minutes. 1: A change in color density is seen between 12 minutes and 14 minutes.

(Resistance to image deterioration) Set the heating time during transfer printing to 10 minutes. The patterned white polyester cloth was observed from the viewpoint of pattern clarity, and evaluated according to the following criteria. In the present invention, if the evaluation is 2 to 4, it is considered that the transfer printing and dyeing paper has resistance to image quality deterioration. 4: No deterioration in picture quality is seen, which is a good standard. 3: There is almost no deterioration in image quality, which is generally good. 2: There is a little picture quality deterioration, but it is at a level that can be put into practical use. 1: Seeing the deterioration of the picture quality, it is a level that cannot be put into actual use.

(Color rendering) In the pattern formed on the white polyester cloth, the optical density of each entity image of cyan, magenta, and yellow is measured using an optical densitometer (X-RITE (registered trademark) 530, X-RITE Incorporated), And total the color density values of 3 colors. The color rendering property was evaluated according to the following criteria based on the color density value. In the present invention, if the evaluation is 3 to 5, it is considered that the transfer printing and dyeing paper has color development properties. 5: The total value is 4.8 or more. 4: The total value is 4.6 or more and less than 4.8. 3: The total value is 4.4 or more and does not reach 4.6. 2: The total value is 4.2 or more and less than 4.4. 1: The total value does not reach 4.2.

The results of each evaluation are shown in Tables 3 and 4.

[table 3] Wrinkle resistance Transferability Resistance to image deterioration Color rendering Example 1 4 5 3 4 Example 2 5 5 4 4 Example 3 5 5 4 4 Example 4 5 5 4 4 Example 5 3 3 2 4 Example 6 4 4 3 4 Example 7 5 5 4 5 Example 8 5 5 4 5 Example 9 5 5 4 5 Example 10 4 5 3 5 Example 11 3 5 4 4 Example 12 5 5 4 5 Example 13 5 5 4 5 Example 14 3 5 4 5 Example 15 5 5 4 4 Example 16 5 5 4 4 Example 17 5 5 4 5 Example 18 5 4 4 3 Example 19 5 3 3 3

[Table 4] Wrinkle resistance Transferability Resistance to image deterioration Color rendering Example 20 5 4 3 4 Example twenty one 5 5 4 4 Example twenty two 5 5 4 4 Example twenty three 5 5 4 4 Example twenty four 5 5 3 4 Example 25 5 5 4 4 Example 26 5 5 4 4 Example 27 5 5 4 4 Example 28 5 5 3 4 Example 29 5 5 4 4 Example 30 5 3 2 4 Example 31 5 3 3 4 Example 32 3 4 3 4 Example 33 5 3 4 3 Comparative example 1 2 4 1 4 Comparative example 2 3 2 1 4 Comparative example 3 2 2 2 2 Comparative example 4 1 1 1 1 Comparative example 5 2 5 4 2

According to the evaluation results of Tables 3 and 4, it can be seen that the transfer printing and dyeing paper according to Examples 1 to 33 of the present invention has wrinkle resistance, transferability, resistance to image deterioration, and color development. However, it is understood that the transfer printing and dyeing papers of Comparative Examples 1 to 5 that do not satisfy the constitution of the present invention cannot achieve at least one of these effects. Mainly from the comparison between Examples 2, 8, and 10, it can be known that the transfer printing and dyeing paper preferably has a coating amount of 4 g/m ² or less. Mainly from the comparison between Examples 8, 12 and 14, it can be known that the transfer printing and dyeing paper preferably has the coating layer substantially free of pigments. Mainly from the comparison of Examples 2 and 19 and the comparison of Examples 10 and 33, it can be known that the transfer printing and dyeing paper is preferably starch-based urea phosphated starch. Mainly from the comparison between Example 2, Examples 15-18 and Example 33, it can be seen that the degree of urea substitution of urea phosphorylated starch is preferably 0.005 or more and 0.05 or less. Mainly from the comparison between Example 2 and Examples 20-23, Example 27, Example 29 and Example 31, it can be known that the transfer printing and dyeing paper is preferably a low molecular weight type of carboxymethyl cellulose. Mainly from the comparison between Examples 1 to 6, Example 11 and Example 32, it can be seen that the transfer printing and dyeing paper is preferably the air permeability of the base paper layer is 12 sec or more and 30 sec or less, and one side of the base paper layer is coated The air permeability of the transfer printing and dyeing paper of the layer is 12 times or more and 5450 times or less of the air permeability of the base paper layer. Mainly from the comparison between Example 2 and Examples 15-18 and Example 33, the transfer printing and dyeing paper is preferably polysaccharide-based urea phosphated starch, and the average value of urea substitution degree of urea phosphated starch is 0.005 Above and below 0.05. Mainly from the comparison of Example 2, Examples 20 to 23 and Examples 25 to 27, Example 29 and Example 31, it can be known that the transfer printing and dyeing paper is preferably, carboxymethyl cellulose by gel permeation chromatography The weight average molecular weight in terms of polyethylene glycol obtained by the method is 27,000 or more and 770,000 or less. Mainly from the comparison between Example 2 and Examples 21-30, it can be known that the transfer printing and dyeing paper preferably has a degree of etherification of carboxymethyl cellulose of 0.6 or more and 1.27 or less.

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Claims (13)

A transfer printing and dyeing paper, which is used in a transfer printing and dyeing method using sublimation dye inks. Sugars contain at least carboxymethyl cellulose and starches. Regarding the air permeability measured in accordance with ISO5636-5: 2003, the air permeability of the base paper layer is 30 sec or less, and the base paper layer has a coating layer on one side of the transfer printing paper. The air permeability is more than 10 times the air permeability of the base paper layer. The transfer printing and dyeing paper according to claim 1, wherein, in terms of dry solid content, the amount of the coating layer mainly composed of polysaccharides on the one side is 4 g/m ² or less. The transfer printing and dyeing paper according to claim 1 or 2, wherein the coating layer mainly composed of polysaccharides does not substantially contain pigments. The transfer printing and dyeing paper according to claim 1 or 2, wherein at least one of the above-mentioned starches is urea phosphorylated starch. The transfer printing and dyeing paper of claim 1 or 2, wherein the carboxymethyl cellulose is a low molecular weight type. Such as the transfer printing and dyeing paper of claim 1 or 2, wherein, regarding the air permeability measured in accordance with ISO5636-5: 2003, the air permeability of the base paper layer is 12sec or more and 30sec or less, and one side of the base paper layer has a coating layer The air permeability of the transfer printing and dyeing paper is 12 times or more and 5450 times or less of the air permeability of the base paper layer. Such as the transfer printing and dyeing paper of claim 4, wherein the average value of the degree of urea substitution of the urea phosphorylated starch is 0.005 or more and 0.05 or less. The transfer printing and dyeing paper of claim 1 or 2, wherein the weight average molecular weight of the carboxymethyl cellulose obtained by gel permeation chromatography in terms of polyethylene glycol is 27,000 or more and Below 770,000. The transfer printing and dyeing paper of claim 1 or 2, wherein the degree of etherification of the carboxymethyl cellulose is 0.6 or more and 1.27 or less. The transfer printing and dyeing paper of claim 1 or 2, wherein the weight average molecular weight of the carboxymethyl cellulose obtained by gel permeation chromatography in terms of polyethylene glycol is 27,000 or more and 770,000 or less, and ether The degree of conversion is 0.6 or more and 1.27 or less. Such as the transfer printing and dyeing paper of claim 4, wherein, regarding the air permeability measured in accordance with ISO5636-5:2003, the air permeability of the base paper layer is 12sec or more and 30sec or less, and one side of the base paper layer has a coating layer for transfer The air permeability of the printing and dyeing paper is 12 times or more and 5450 times or less of the air permeability of the base paper layer, and the average value of the urea substitution degree of the above-mentioned urea phosphorylated starch is 0.005 or more and 0.05 or less. Such as the transfer printing and dyeing paper of claim 4, wherein, regarding the air permeability measured in accordance with ISO5636-5:2003, the air permeability of the base paper layer is 12sec or more and 30sec or less, and one side of the base paper layer has a coating layer for transfer The air permeability of the printing and dyeing paper is 12 times or more and 5450 times or less of the air permeability of the base paper layer. The average value of the urea substitution degree of the urea phosphorylated starch is 0.005 or more and 0.05 or less. The carboxymethyl cellulose penetrates through the gel The weight average molecular weight in terms of polyethylene glycol obtained by the chromatography method is 27,000 or more and 770,000 or less, and the degree of etherification is 0.6 or more and 1.27 or less. A transfer printing and dyeing method, comprising the following steps: a step of printing a pattern on the transfer printing and dyeing paper of any one of claims 1 to 12 to obtain a transfer printing and dyeing paper; and printing the pattern on the transfer printing and dyeing paper The step of close contact between the surface and the printed matter.