TWI733592B - Aluminum alloy sheet and method for manufacturing the same - Google Patents
Aluminum alloy sheet and method for manufacturing the same Download PDFInfo
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本揭露是有關於一種金屬合金之製造技術,且特別是有關於一種避免塗油自黏片之鋁合金片及其製造方法。The present disclosure relates to a manufacturing technology of a metal alloy, and particularly relates to an aluminum alloy sheet and a manufacturing method thereof that avoid oiling a self-adhesive sheet.
鋁鎂矽(Al-Mg-Si)合金與鋁鎂(Al-Mg)合金為兩大汽車主要用鋁材。除了對鋁鎂矽合金與鋁鎂合金之基本機械性質有一定要求外,更要求這兩種鋁材具備可自動化生產的要件。Aluminum-Mg-Si (Al-Mg-Si) alloy and Al-Mg (Al-Mg) alloy are the two main aluminum materials for automobiles. In addition to certain requirements for the basic mechanical properties of aluminum-magnesium-silicon alloys and aluminum-magnesium alloys, these two aluminum materials are also required to have the requirements for automatic production.
完成鋁合金片的製作後,通常對鋁合金片的表面進行塗油處理,以防止鋁合金片生鏽與氧化。然而,塗油後之鋁合金片堆疊放置時,二鋁合金片之二鄰接片面之間因真空吸引而彼此黏附,造成黏片現象。After the production of the aluminum alloy sheet is completed, the surface of the aluminum alloy sheet is usually oil-coated to prevent the aluminum alloy sheet from rusting and oxidation. However, when the oiled aluminum alloy sheets are stacked and placed, the two adjacent surfaces of the two aluminum alloy sheets adhere to each other due to vacuum suction, resulting in a sticky sheet phenomenon.
目前,下游加工廠為解決鋁合金片的黏片問題,大多以人工來將相黏之鋁合金片剝離,或者利用氣槍吹氣方式來剝離相黏之鋁合金片。而這樣的情況導致鋁材在生產應用上無法滿足可自動化生產的要求。At present, in order to solve the sticking problem of aluminum alloy sheets, downstream processing plants mostly manually peel off the adhered aluminum alloy sheets, or use air gun blowing to peel off the adhered aluminum alloy sheets. However, this situation has led to the inability of aluminum materials to meet the requirements of automated production in production applications.
因此,本揭露之一目的就是在提供一種鋁合金片及其製造方法,其在鋁捲料之冷軋延步驟中採粗輥軋延方式,以使所形成之鋁合金片的表面具有許多微孔洞,如此可有效避免二鋁合金片的二相鄰片面之間因真空吸引而相黏附。藉此,可免除剝離相黏之鋁合金片的程序,而可提升鋁合金片的應用便利性,進而可降低生產成本。Therefore, one of the objectives of the present disclosure is to provide an aluminum alloy sheet and a manufacturing method thereof, which adopts a rough rolling method in the cold rolling step of aluminum coil material, so that the surface of the formed aluminum alloy sheet has many microstructures. Holes, which can effectively avoid adhesion between two adjacent surfaces of the two aluminum alloy sheets due to vacuum attraction. Thereby, the procedure of peeling off the adhered aluminum alloy sheet can be avoided, and the application convenience of the aluminum alloy sheet can be improved, and the production cost can be reduced.
本揭露之另一目的就是在提供一種鋁合金片及其製造方法,其可有效解決鋁合金片的黏片問題,因此鋁合金片於生產應用上能滿足可自動化生產的需求。Another purpose of the present disclosure is to provide an aluminum alloy sheet and a manufacturing method thereof, which can effectively solve the problem of sticking of the aluminum alloy sheet, so that the aluminum alloy sheet can meet the demand for automated production in production applications.
根據本揭露之上述目的,提出一種鋁合金片之製造方法。在此方法中,製備鋁胚料。鋁胚料包含0.3wt%至5.0wt%的鎂(Mg)、0.1wt%至1.2wt%的矽(Si)、0.05wt%至0.30wt%的錳(Mn)、0.05wt%至0.35wt%的鐵(Fe)、以及平衡量的鋁(Al)。對鋁胚料進行熱軋延步驟,以形成熱軋鋁捲料。對熱軋鋁捲料進行冷軋延步驟,以形成冷軋鋁捲料。進行冷軋延步驟包含形成數個微孔洞於冷軋鋁捲之表面中。對冷軋鋁捲料進行退火步驟,以形成鋁合金片。According to the above objective of the present disclosure, a method for manufacturing an aluminum alloy sheet is proposed. In this method, aluminum blanks are prepared. The aluminum blank contains 0.3wt% to 5.0wt% of magnesium (Mg), 0.1wt% to 1.2wt% of silicon (Si), 0.05wt% to 0.30wt% of manganese (Mn), 0.05wt% to 0.35wt% The iron (Fe) and the balance of aluminum (Al). The aluminum blank is subjected to a hot rolling step to form a hot rolled aluminum coil. The hot-rolled aluminum coil is subjected to a cold rolling step to form a cold-rolled aluminum coil. The cold-rolling step includes forming a number of micro-holes in the surface of the cold-rolled aluminum coil. The cold-rolled aluminum coil is subjected to an annealing step to form an aluminum alloy sheet.
依據本揭露之一實施例,上述製備鋁胚料包含進行備料步驟,以將鎂、矽、錳、與鐵熔融於鋁中,而製備出處於熔融狀態之鋁合金原料;以及對鋁合金原料進行澆鑄成型步驟,以製得鋁胚料。According to an embodiment of the present disclosure, the above-mentioned preparation of aluminum blanks includes a material preparation step to melt magnesium, silicon, manganese, and iron in aluminum to prepare aluminum alloy raw materials in a molten state; and performing the aluminum alloy raw materials Casting and forming steps to obtain aluminum blanks.
依據本揭露之一實施例,上述進行熱軋延步驟包含對鋁胚料進行預熱處理,其中預熱處理之溫度為約450℃至約540℃;熱軋延鋁胚料,其中熱軋延鋁胚料之溫度為約250℃至約500℃;以及進行盤捲步驟,以獲得熱軋鋁捲料。According to an embodiment of the present disclosure, the above-mentioned hot rolling step includes preheating the aluminum blank, wherein the temperature of the preheating is about 450°C to about 540°C; hot rolling the aluminum blank, wherein The temperature of the aluminum blank is about 250°C to about 500°C; and the coiling step is performed to obtain the hot-rolled aluminum coil.
依據本揭露之一實施例,上述進行預熱處理包含將鋁胚料置於溫度為約450℃至約540℃之預熱爐內保持至少二小時。According to an embodiment of the present disclosure, the above-mentioned pre-heat treatment includes placing the aluminum blank in a pre-heating furnace at a temperature of about 450° C. to about 540° C. for at least two hours.
依據本揭露之一實施例,上述進行冷軋延步驟包含利用軋輥,此軋輥之軋面粗糙度為約2.0μm至約4.0μm。According to an embodiment of the present disclosure, the above-mentioned cold rolling step includes using a roller, and the surface roughness of the roller is about 2.0 μm to about 4.0 μm.
依據本揭露之一實施例,上述進行冷軋延步驟包含控制冷軋量為約50%至約80%。According to an embodiment of the present disclosure, the aforementioned step of performing cold rolling includes controlling the amount of cold rolling to be about 50% to about 80%.
依據本揭露之一實施例,上述之微孔洞的尺寸為50μm至100μm。According to an embodiment of the present disclosure, the size of the above-mentioned micro-holes is 50 μm to 100 μm.
依據本揭露之一實施例,上述進行退火步驟之退火溫度為約300℃至約570℃。According to an embodiment of the present disclosure, the annealing temperature for performing the annealing step is about 300°C to about 570°C.
依據本揭露之一實施例,上述進行退火步驟包含將冷軋鋁捲料加熱至退火溫度,再使冷軋鋁捲料冷卻至室溫。According to an embodiment of the present disclosure, the above annealing step includes heating the cold-rolled aluminum coil to an annealing temperature, and then cooling the cold-rolled aluminum coil to room temperature.
根據本揭露之上述目的,另提出一種鋁合金片,利用上述之鋁合金片之製造方法所製得,其中鋁合金片之片面粗糙度為1μm至2μm。According to the above-mentioned objective of the present disclosure, another aluminum alloy sheet is proposed, which is produced by the above-mentioned manufacturing method of the aluminum alloy sheet, wherein the surface roughness of the aluminum alloy sheet is 1 μm to 2 μm.
以下仔細討論本揭露實施例的製造與應用。然而,可以理解的是,這些實施例提供許多可應用的發明概念,其可實施於各式各樣的特定內容中。因此,所討論之特定實施例僅供說明,並非用以限定本發明之範圍。The manufacturing and application of the embodiments of the disclosure are discussed in detail below. However, it can be understood that these embodiments provide many applicable inventive concepts, which can be implemented in various specific contents. Therefore, the specific embodiments discussed are for illustration only, and are not intended to limit the scope of the present invention.
有鑑於習知解決鋁合金片塗油後產生自黏片問題時所採之人工剝離或氣槍吹氣剝離方式,會導致鋁合金片在生產應用上無法滿足自動化生產的需求。因此,本揭露在此提出一種鋁合金片及其製造方法,其在材料源頭上著手,於冷軋延時使鋁合金片的表面中形成許多微孔洞,藉此可有效避免鋁合金片之相鄰片面之間因真空吸引而發生黏片現象。In view of the conventional manual peeling or air gun blowing peeling method used to solve the problem of self-adhesive sheets after oiling aluminum alloy sheets, the aluminum alloy sheets cannot meet the needs of automated production in production applications. Therefore, the present disclosure proposes an aluminum alloy sheet and a manufacturing method thereof. It starts from the source of the material and causes many micro-holes to be formed in the surface of the aluminum alloy sheet during the cold rolling delay, thereby effectively avoiding the phase of the aluminum alloy sheet Adhesive sheeting occurs due to vacuum attraction between adjacent surfaces.
請參照圖1,其係繪示依照本揭露之一實施方式的一種鋁合金片之製造方法的流程圖。在本實施方式中,製造鋁合金片時,可先進行步驟100,以製備鋁胚料。此鋁胚料可例如為鋁鎂合金胚料。在一些實施例中,鋁胚料主要可包含0.3wt%至5.0wt%的鎂、0.1wt%至1.2wt%的矽、0.05wt%至0.30wt%的錳、0.05wt%至0.35wt%的鐵、以及平衡量的鋁。鋁胚料更可選擇性地包含其他元素,例如可包含約0.02wt%的銅。Please refer to FIG. 1, which is a flowchart of a manufacturing method of an aluminum alloy sheet according to an embodiment of the present disclosure. In this embodiment, when the aluminum alloy sheet is manufactured,
在一些示範例子中,於步驟100製備鋁胚料時,可先進行步驟102,以製備鋁合金原料。製備鋁合金原料時,可將0.3wt%至5.0wt%的鎂、0.1wt%至1.2wt%的矽、0.05wt%至0.30wt%的錳、與0.05wt%至0.35wt%的鐵熔融於平衡量的鋁原料中,而製備出處於熔融狀態的鋁合金原料。接著,進行步驟104,以將鋁合金原料予以澆鑄成型。熔融狀態的鋁合金原料經由澆鑄而成型為鋁胚料。In some exemplary examples, when the aluminum blank is prepared in
製得鋁胚料後,可進行步驟110,以熱軋延鋁胚料,而獲得熱軋鋁捲料。在一些示範例子中,對鋁胚料進行熱軋延時,可先進行步驟112,以對鋁胚料進行預熱處理。預熱處理之溫度可為450℃至540℃。舉例而言,對鋁胚料進行預熱處理時,可將鋁胚料置於溫度為450℃至540℃的預熱爐內,且保持至少二小時。接著,可進行步驟114,以利用熱軋延機對預熱後的鋁胚料軋延。在熱軋延鋁胚料的過程中,溫度可例如控制在250℃至500℃。隨後,可進行步驟116,以將鋁胚料熱軋延後所形成的鋁板材予以盤捲,而獲得熱軋鋁捲料。After the aluminum blank is produced,
完成熱軋延步驟後,可進行步驟120,以對熱軋鋁捲料進行冷軋延步驟,而形成冷軋鋁捲料。進行冷軋延步驟前,可先等熱軋鋁捲料之溫度降至室溫後再進行。在本實施方式中,冷軋延熱軋鋁捲料時,在所軋出之冷軋鋁捲料的二表面中形成許多微孔洞。舉例而言,這些微孔洞的尺寸可為50μm至100μm。在一些實施例中,利用軋輥來對熱軋鋁捲料進行冷軋延,其中此軋輥為粗輥軋輥,即軋輥具有粗糙的軋面,藉以在冷軋延過程中在熱軋鋁捲料的表面中形成微孔洞。After the hot-rolling step is completed,
在一些示範例子中,冷軋延時所採用之軋輥的軋面粗糙度為約2.0μm至約4.0μm。發明人發現若軋輥之軋面粗糙度小於2.0μm,在冷軋鋁捲料之表面上製造微孔洞的效果不佳;而若輥面粗糙度大於4.0μm,會導致所軋延出來之冷軋鋁捲料的片面品質不佳。此外,進行冷軋延步驟時,可例如將熱軋鋁捲料的冷軋量控制在約50%至約80%。In some exemplary examples, the rolling surface roughness of the roll used for the cold rolling delay is about 2.0 μm to about 4.0 μm. The inventor found that if the surface roughness of the roll is less than 2.0μm, the effect of making microvoids on the surface of the cold-rolled aluminum coil is not good; and if the surface roughness of the roll is greater than 4.0μm, it will result in cold rolling. The one-sided quality of rolled aluminum coil is poor. In addition, when the cold rolling step is performed, the cold rolling amount of the hot-rolled aluminum coil can be controlled at about 50% to about 80%, for example.
完成冷軋延步驟後,可進行步驟130,以對冷軋鋁捲料進行退火處理,而形成鋁合金片。進行退火步驟之退火溫度可例如控制在約300℃至約570℃。在一些示範例子中,進行退火步驟時,可將冷軋鋁捲料加熱至此退火溫度,再使冷軋鋁捲料以自然冷卻的方式冷卻至室溫。鋁合金片製成後,一般會在其表面上塗油,以防止鋁合金片生鏽與氧化。After the cold-rolling step is completed,
利用此實施方式所製得之鋁合金片的片面粗糙度可例如為1μm至2μm。由於鋁合金片的表面中具有許多的微孔洞,因此在鋁合金片塗油後而彼此堆疊時,二相鄰鋁合金片之表面的部分凸出結構相互接觸的情況下,鋁合金片上的油可流到微孔洞中,藉此可避免相鄰鋁合金片互相黏附。The surface roughness of the aluminum alloy sheet prepared by this embodiment may be, for example, 1 μm to 2 μm. Because there are many micro-holes in the surface of the aluminum alloy sheet, when the aluminum alloy sheets are stacked on each other after being coated with oil, when the protruding structures on the surfaces of two adjacent aluminum alloy sheets are in contact with each other, the The oil can flow into the micro-holes, thereby preventing adjacent aluminum alloy sheets from sticking to each other.
以下利用多個實施例與比較例的實驗結果,來更具體說明利用本揭露之實施方式的技術內容與功效,然其並非用以限定本揭露。The following uses the experimental results of a number of embodiments and comparative examples to more specifically describe the technical content and effects of the embodiments of the present disclosure, but they are not intended to limit the present disclosure.
在二種實驗鋁胚料材質中,A合金的合金成分為鎂含量在4.5wt%、鐵含量在0.20wt%、矽含量在0.15wt%、錳含量在0.25wt%、銅含量在0.02wt%、其餘為鋁含量。,B合金的合金成分為鎂含量在0.45wt%、鐵含量在0.11wt%、矽含量在1.03wt%、錳含量在0.11wt%、銅含量在0.02wt%、其餘為鋁含量。In the two experimental aluminum blank materials, the alloy composition of A alloy is 4.5wt% of magnesium, 0.20wt% of iron, 0.15wt% of silicon, 0.25wt% of manganese, and 0.02wt% of copper. , The rest is aluminum content. The alloy composition of B alloy is 0.45wt% of magnesium, 0.11wt% of iron, 1.03wt% of silicon, 0.11wt% of manganese, 0.02wt% of copper, and the rest of aluminum.
實驗鋁胚料之合金成分如下表1所列示。
表1
利用上述所揭露之鋁合金片的製造方法,以A合金與B合金來製作鋁合金片,本揭露之實施例採軋面粗糙度為約2.0μm至約4.0μm的軋輥進行冷軋,比較例則採軋面粗糙度小於2.0μm的軋輥進行冷軋。The aluminum alloy sheet is manufactured using the aluminum alloy sheet disclosed above, and the aluminum alloy sheet is made of alloy A and alloy B. In the embodiment of the disclosure, a roll with a rolling surface roughness of about 2.0 μm to about 4.0 μm is used for cold rolling. Comparative example Then, rolls with a rolling surface roughness less than 2.0 μm are used for cold rolling.
經不同粗糙度之軋輥冷軋後之鋁合金片的黏片情況列示於下表2。
表2
由上表2可看出,避免鋁合金片塗油後產生自黏片現象的關鍵在於控制鋁合金片之片面的粗糙度與塗油量。鋁合金片之片面粗糙度愈高,代表鋁合金片之表面的微孔洞數量愈多且深度愈深,因此鋁合金片可容許更高的塗油量。而鋁合金片的片面粗糙度取決於冷軋輥之輥面的粗糙度。因此,本揭露之實施方式為使高塗油量之鋁合金片亦具有可避免塗油自黏片的功效,而將冷軋輥之輥面的粗糙度控制在約2.0μm至約4.0μm。It can be seen from Table 2 above that the key to avoiding the self-adhesive sheet phenomenon after the aluminum alloy sheet is coated with oil is to control the surface roughness and the amount of oil applied to the aluminum alloy sheet. The higher the surface roughness of the aluminum alloy sheet, the greater the number of micro-holes on the surface of the aluminum alloy sheet and the deeper the depth. Therefore, the aluminum alloy sheet can tolerate a higher amount of oil coating. The surface roughness of the aluminum alloy sheet depends on the roughness of the cold roll surface. Therefore, the embodiment of the present disclosure is to make the aluminum alloy sheet with high oil content also have the effect of avoiding the oil-coated self-adhesive sheet, and control the roughness of the cold roll surface to be about 2.0 μm to about 4.0 μm.
由上述之實施方式可知,本揭露之一優點就是因為本揭露之實施方式在鋁捲料之冷軋延步驟中採粗輥軋延方式,以使所形成之鋁合金片的表面具有許多微孔洞。藉由這些微孔洞,可有效避免二鋁合金片的二相鄰片面之間因真空吸引而相黏附。因此,可免除剝離相黏之鋁合金片的程序,而可提升鋁合金片的應用便利性,進而可降低生產成本。It can be seen from the above-mentioned embodiments that one of the advantages of the present disclosure is that the embodiment of the present disclosure adopts a rough rolling method in the cold rolling step of the aluminum coil, so that the surface of the formed aluminum alloy sheet has many micropores. Hole. With these micro-holes, it is possible to effectively avoid adhesion between two adjacent surfaces of the two aluminum alloy sheets due to vacuum attraction. Therefore, the procedure of peeling off the adhered aluminum alloy sheet can be eliminated, and the application convenience of the aluminum alloy sheet can be improved, thereby reducing the production cost.
由上述之實施方式可知,本揭露之另一優點就是因為本揭露可有效解決鋁合金片的黏片問題,因此鋁合金片於生產應用上能滿足可自動化生產的需求。As can be seen from the above-mentioned embodiments, another advantage of the present disclosure is that the present disclosure can effectively solve the sticking problem of the aluminum alloy sheet, so the aluminum alloy sheet can meet the demand for automated production in production applications.
雖然本揭露已以實施例揭示如上,然其並非用以限定本揭露,任何在此技術領域中具有通常知識者,在不脫離本揭露之精神和範圍內,當可作各種之更動與潤飾,因此本揭露之保護範圍當視後附之申請專利範圍所界定者為準。Although the present disclosure has been disclosed in the above embodiments, it is not intended to limit the present disclosure. Anyone with ordinary knowledge in this technical field can make various changes and modifications without departing from the spirit and scope of the present disclosure. Therefore, the scope of protection of this disclosure shall be subject to the scope of the attached patent application.
100:步驟 102:步驟 104:步驟 110:步驟 112:步驟 114:步驟 116:步驟 120:步驟 130:步驟 100: steps 102: Step 104: Step 110: Step 112: Step 114: step 116: step 120: Step 130: steps
為讓本揭露之上述和其他目的、特徵、優點與實施例能更明顯易懂,所附圖式之說明如下: [圖1]係繪示依照本揭露之一實施方式的一種鋁合金片之製造方法的流程圖。 In order to make the above and other objectives, features, advantages and embodiments of the present disclosure more obvious and understandable, the description of the accompanying drawings is as follows: [Fig. 1] is a flowchart showing a manufacturing method of an aluminum alloy sheet according to an embodiment of the present disclosure.
國內寄存資訊(請依寄存機構、日期、號碼順序註記) 無 國外寄存資訊(請依寄存國家、機構、日期、號碼順序註記) 無 Domestic deposit information (please note in the order of deposit institution, date and number) no Foreign hosting information (please note in the order of hosting country, institution, date, and number) no
100:步驟 100: steps
102:步驟 102: Step
104:步驟 104: Step
110:步驟 110: Step
112:步驟 112: Step
114:步驟 114: step
116:步驟 116: step
120:步驟 120: Step
130:步驟 130: steps
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Cited By (1)
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TWI801143B (en) * | 2022-02-21 | 2023-05-01 | 中國鋼鐵股份有限公司 | Method for producing aluminum-magnesium alloy with high elongation and high strength for construction |
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TW313591B (en) * | 1994-07-21 | 1997-08-21 | China Steel Co Ltd | A manufacturing method for low earing ratio aluminum can body stocks |
CN1289275A (en) * | 1998-02-13 | 2001-03-28 | 皮西尼何纳吕公司 | Aluminium alloy strips with high surface homogenity, and method for making same |
US6231809B1 (en) * | 1998-02-20 | 2001-05-15 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Al-Mg-Si aluminum alloy sheet for forming having good surface properties with controlled texture |
CN104073690A (en) * | 2014-06-18 | 2014-10-01 | 厦门厦顺铝箔有限公司 | Aluminum alloy product and manufacture method thereof |
WO2020045401A1 (en) * | 2018-08-27 | 2020-03-05 | 古河電気工業株式会社 | Aluminum alloy material, and braided shield wire, electroconductive member, member for cell, fastening component, component for spring, component for structure, and cabtire cable using same |
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TW313591B (en) * | 1994-07-21 | 1997-08-21 | China Steel Co Ltd | A manufacturing method for low earing ratio aluminum can body stocks |
CN1289275A (en) * | 1998-02-13 | 2001-03-28 | 皮西尼何纳吕公司 | Aluminium alloy strips with high surface homogenity, and method for making same |
US6231809B1 (en) * | 1998-02-20 | 2001-05-15 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Al-Mg-Si aluminum alloy sheet for forming having good surface properties with controlled texture |
CN104073690A (en) * | 2014-06-18 | 2014-10-01 | 厦门厦顺铝箔有限公司 | Aluminum alloy product and manufacture method thereof |
WO2020045401A1 (en) * | 2018-08-27 | 2020-03-05 | 古河電気工業株式会社 | Aluminum alloy material, and braided shield wire, electroconductive member, member for cell, fastening component, component for spring, component for structure, and cabtire cable using same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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TWI801143B (en) * | 2022-02-21 | 2023-05-01 | 中國鋼鐵股份有限公司 | Method for producing aluminum-magnesium alloy with high elongation and high strength for construction |
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